Electromagnetic interference(EMI)shielding materials principally attain shielding by reflecting electromagnetic waves through impedance mismatch caused by high conductivity,which inevitably leads to secondary electrom...Electromagnetic interference(EMI)shielding materials principally attain shielding by reflecting electromagnetic waves through impedance mismatch caused by high conductivity,which inevitably leads to secondary electromagnetic wave pollution.Consequently,the development of multifunctional,low-reflection electromagnetic shielding materials remains a significant challenge.Materials that are lightweight,possess high mechanical strength,exhibit excellent electromagnetic shielding absorption,and demonstrate low reflectivity have historically been the focus of significant interest.Natural silk,lightweight and strong,is an ideal composite matrix.Regenerated silk fibroin(RSF)synthesized via a bottom-up approach and cross-linked with polyvinyl alcohol(PVA)forms an aerogel matrix with remarkable compressive strength.In accordance with the principle of integrating functional design with structural design,spherical NiFe_(2)O_(4)particles were grown on the MXene surface via electrostatic self-assembly and combined with RSF/PVA as the aerogel absorptive layer,while RSF/PVA/MXene served as the reflective layer.A vertically oriented structure of Janus aerogel was prepared through sequential directed freezing.The resulting aerogel with 0.058 g/cm^(3) reveals the high compression strength(3.52 MPa).Reasonable functional and structural design enables aerogel to effectively dissipate incident electromagnetic waves through absorption,reflection,and reabsorption processes,achieving an average SET value of 48.05±1.75 dB and reaching a minimum reflection coefficient of 0.19.Furthermore,the aerogel displays remarkable infrared stealth capabilities.This lightweight,rigid,multifunctional aerogel is poised to play a significant role in the field of next-generation electronic devices.展开更多
The Global Precipitation Measurement(GPM)dual-frequency precipitation radar(DPR)products(Version 07A)are employed for a rigorous comparative analysis with ground-based operational weather radar(GR)networks.The reflect...The Global Precipitation Measurement(GPM)dual-frequency precipitation radar(DPR)products(Version 07A)are employed for a rigorous comparative analysis with ground-based operational weather radar(GR)networks.The reflectivity observed by GPM Ku PR is compared quantitatively against GR networks from CINRAD of China and NEXRAD of the United States,and the volume matching method is used for spatial matching.Additionally,a novel frequency correction method for all phases as well as precipitation types is used to correct the GPM Ku PR radar frequency to the GR frequency.A total of 20 GRs(including 10 from CINRAD and 10 from NEXRAD)are included in this comparative analysis.The results indicate that,compared with CINRAD matched data,NEXRAD exhibits larger biases in reflectivity when compared with the frequency-corrected Ku PR.The root-mean-square difference for CINRAD is calculated at 2.38 d B,whereas for NEXRAD it is 3.23 d B.The mean bias of CINRAD matched data is-0.16 d B,while the mean bias of NEXRAD is-2.10 d B.The mean standard deviation of bias for CINRAD is 2.15 d B,while for NEXRAD it is 2.29 d B.This study effectively assesses weather radar data in both the United States and China,which is crucial for improving the overall consistency of global precipitation estimates.展开更多
Designing and fabricating a compatible low-reflectivity electromagnetic interference(EMI)shielding/high-temperature resistant infrared stealth material possesses a critical significance in the field of military.Hence,...Designing and fabricating a compatible low-reflectivity electromagnetic interference(EMI)shielding/high-temperature resistant infrared stealth material possesses a critical significance in the field of military.Hence,a hierarchical polyimide(PI)nonwoven fabric is fabricated by alkali treatment,in-situ growth of magnetic particles and"self-activated"electroless Ag plating process.Especially,the hierarchical impedance matching can be constructed by systematically assembling Fe_(3)O_(4)/Ag-loaded PI nonwoven fabric(PFA)and pure Ag-coated PI nonwoven fabric(PA),endowing it with an ultralowreflectivity EMI shielding performance.In addition,thermal insulation of fluffy three-dimensional(3D)space structure in PFA and low infrared emissivity of PA originated from Ag plating bring an excellent infrared stealth performance.More importantly,the strong bonding interaction between Fe_(3)O_(4),Ag,and PI fiber improves thermal stability in EMI shielding and high-temperature resistant infrared stealth performance.Such excellent comprehensive performance makes it promising for military tents to protect internal equipment from electromagnetic interference stemmed from adjacent equipment and/or enemy,and inhibit external infrared detection.展开更多
The current work addresses the challenge of elucidating the performance of fluoroelastomers within the HMX(octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine)based polymer-bonded explosives(PBXs).To simulate the confine...The current work addresses the challenge of elucidating the performance of fluoroelastomers within the HMX(octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine)based polymer-bonded explosives(PBXs).To simulate the confined interface in PBXs,bilayer films of F2314/HMX and F2311/HMX were designed.Neutron reflectivity(NR),nanoindentation,and X-ray reflectivity(XRR)were employed to examine the layer thickness,interface characteristics,diffusion behavior,and surface morphology of the bilayers.NR measurements revealed interface thicknesses of 45Å and 98Å for F2314/HMX and F2311/HMX,respectively,indicating deeper penetration of F2311 into the HMX matrix.NR also suggested a denser polymer network with a higher scattering length density(SLD)near the HMX interface for both fluoroelastomers,while the bound layer of F2311 was notably thicker.Nanoindentation cross-checks and confirms the presence of a bound layer,highlighting the differences in stiffness and diffusion ability between the two polymers.The consistency between the NR and nanoindentation results suggests that F2311 demonstrates better flexibility and elasticity,whereas F2314 is stiffer and more plastic.Accordingly,the structures and performances of different fluoroelastomers at the HMX interface are discussed,which can provide valuable insights into the selection of binders for PBX formulations tailored to specific applications.展开更多
Synchrotron method of resonant X-ray reflectivity 2D mapping has been applied to study ultrathin epitaxial layers of WS_(2)grown by pulsed laser deposition on Al_(2)O_(3)(0001)substrates.The measurements were carried ...Synchrotron method of resonant X-ray reflectivity 2D mapping has been applied to study ultrathin epitaxial layers of WS_(2)grown by pulsed laser deposition on Al_(2)O_(3)(0001)substrates.The measurements were carried out across the L absorption edge of tungsten to perform depth-dependent element-selective analysis sensitive to potential chemical modification of the WS_(2)layer in ambient conditions.Despite the few monolayer thickness of the studied film,the experimentally measured maps of reflectance as a function of incident angle and photon energy turned out to be quite informative showing well-pronounced interference effects near W absorption edge at 10210 eV.The synchrotron studies were complemented with conventional non-resonant reflectance measurements carried out in the laboratory at a fixed photon energy corresponding to Cu Kαemission.The reconstruction of the depth and energy dependent scattering length density within the studied multilayers was carried out using the OpenCL empowered fitting software utilizing spectral shaping algorithm which does not rely on the pre-measured reference absorption spectra.A thin WO_(x) layer has been revealed at the surface of the WS_(2)layer pointing out to the effect of water assisted photo-oxidation reported in a number of works related to ultrathin layers of transition metal dichalcogenides.展开更多
Currently, the deghosting of towed streamer seismic data assumes a flat sea level and a sea-surface reflection coefficient of-1; this decreases the precision of deghosting. A new method that considers the rough sea su...Currently, the deghosting of towed streamer seismic data assumes a flat sea level and a sea-surface reflection coefficient of-1; this decreases the precision of deghosting. A new method that considers the rough sea surface is proposed to suppress ghost reflections. The proposed deghosting method obtains the rough sea surface reflection coefficient using Gaussian statistics, and calculates the optimized deghosting operator in the r/p domain. The proposed method is closer to the actual sea conditions, offers an improved deghosting operator, removes the ghost reflections from marine towed seismic data, widens the bandwidth and restores the low-frequency information, and finally improves the signal-to- noise ratio and resolution of the seismic data.展开更多
A novel high reflectivity type of semiconductor saturable absorption mirror grown by metal organic chemical vapor deposition is presented.Using the mirror as well as an end mirror,passively mode locked Yb∶YAB laser i...A novel high reflectivity type of semiconductor saturable absorption mirror grown by metal organic chemical vapor deposition is presented.Using the mirror as well as an end mirror,passively mode locked Yb∶YAB laser is realized,which produces a pulse as short as 3 05ps at 1 044μm.The pulse frequency is 375MHz;the output power is 45mW.展开更多
针对天气雷达网中的不同波段雷达反射率因子整体偏差较大,太阳法强度标定仅能测试接收通道一致性,无法测量发射双通道引入误差等问题,该文利用无人机高精度RTK或激光测距功能,实时获取金属球位置,设计了“粗调、细调、凝视”的雷达目标...针对天气雷达网中的不同波段雷达反射率因子整体偏差较大,太阳法强度标定仅能测试接收通道一致性,无法测量发射双通道引入误差等问题,该文利用无人机高精度RTK或激光测距功能,实时获取金属球位置,设计了“粗调、细调、凝视”的雷达目标锁定方法,确定目标的最佳观测位置,通过计算金属球反射率因子实测值与理论值的偏差,实现了双偏振天气雷达全链路真值标定。结合襄阳S波段双偏振多普勒天气雷达在2025年4月25日开展了3次金属球标定试验,验证标定技术的可行性。试验结果表明,金属球反射率因子平均偏差ΔZ约0.27 d B,满足ΔZ≤0.5 dB的技术指标要求,雷达系统探测精度总体良好。使用无人机悬吊金属球标定反射率因子可以作为双偏振天气雷达全链路测试的重要手段,也为在线监测雷达健康状态提供了定期交叉检验依据。展开更多
In this study,polyacrylic acid(PAA)films were employed as a model system,and a series of PAA films with tunable water wettability was systematically prepared by varying molecular weight and curing temperature.Using at...In this study,polyacrylic acid(PAA)films were employed as a model system,and a series of PAA films with tunable water wettability was systematically prepared by varying molecular weight and curing temperature.Using attenuated total reflectance Fourier-transform infrared spectroscopy(ATR-FTIR),the molecular configurations of surface carboxyl groups(COOH),free carboxyl(COOH_(f))and hydrogen-bonded carboxyl(COOH_(HB),were directly correlated with the polar component of surface energy(γ^(s,p)).By decomposing theγ^(s,p)values of the PAA thin films as a sum of the contributions of COOH_(f)and COOH_(H B),the intrinsic polar component of surface energy of COOH_(H B)(γ_(H B)^(s,p*))was quantified for the first time as 8.34 mN/m,significantly lower than that of COOH_(f)(γ_(f)^(s,p*)=34 mN/m).This result highlights that hydrogen bonding markedly reduces theγ^(s,p),providing a rational explanation for the relatively large water contact angle observed on PAA thin films.Furthermore,it establishes a thermodynamic basis for estimating the fraction of surface COOH_(H B)groups(f H B)from wettability measurements.Further extension of the model to carboxyl-terminated self-assembled monolayers(COOH-SAMs)revealed that surface COOH density(ΣCOOH)critically regulates wetting behavior:whenΣCOOH ranges from 4.30 to 5.25 nm^(-2),COOH groups predominantly exist in a free state and facilitate effective hydration layers,thereby promoting superhydrophilicity.Overall,this study not only establishes a unified thermodynamic framework linking surface COOH configurations to macroscopic wettability,but also validates its universality by extending it to COOH-SAMs systems,thereby providing a unified theoretical framework for the controllable design of hydrophilicity in various COOH-functionalized surfaces.展开更多
基金supported by Key R&D Program of Shandong Province,China(No.2025CXGC010407).
文摘Electromagnetic interference(EMI)shielding materials principally attain shielding by reflecting electromagnetic waves through impedance mismatch caused by high conductivity,which inevitably leads to secondary electromagnetic wave pollution.Consequently,the development of multifunctional,low-reflection electromagnetic shielding materials remains a significant challenge.Materials that are lightweight,possess high mechanical strength,exhibit excellent electromagnetic shielding absorption,and demonstrate low reflectivity have historically been the focus of significant interest.Natural silk,lightweight and strong,is an ideal composite matrix.Regenerated silk fibroin(RSF)synthesized via a bottom-up approach and cross-linked with polyvinyl alcohol(PVA)forms an aerogel matrix with remarkable compressive strength.In accordance with the principle of integrating functional design with structural design,spherical NiFe_(2)O_(4)particles were grown on the MXene surface via electrostatic self-assembly and combined with RSF/PVA as the aerogel absorptive layer,while RSF/PVA/MXene served as the reflective layer.A vertically oriented structure of Janus aerogel was prepared through sequential directed freezing.The resulting aerogel with 0.058 g/cm^(3) reveals the high compression strength(3.52 MPa).Reasonable functional and structural design enables aerogel to effectively dissipate incident electromagnetic waves through absorption,reflection,and reabsorption processes,achieving an average SET value of 48.05±1.75 dB and reaching a minimum reflection coefficient of 0.19.Furthermore,the aerogel displays remarkable infrared stealth capabilities.This lightweight,rigid,multifunctional aerogel is poised to play a significant role in the field of next-generation electronic devices.
基金funded by the National Key Research and Development Program of China(Grant No.2023YFB3907500)the National Natural Science Foundation(Grant No.42330602)the“Fengyun Satellite Remote Sensing Product Validation and Verification”Youth Innovation Team of the China Meteorological Administration(Grant No.CMA2023QN12)。
文摘The Global Precipitation Measurement(GPM)dual-frequency precipitation radar(DPR)products(Version 07A)are employed for a rigorous comparative analysis with ground-based operational weather radar(GR)networks.The reflectivity observed by GPM Ku PR is compared quantitatively against GR networks from CINRAD of China and NEXRAD of the United States,and the volume matching method is used for spatial matching.Additionally,a novel frequency correction method for all phases as well as precipitation types is used to correct the GPM Ku PR radar frequency to the GR frequency.A total of 20 GRs(including 10 from CINRAD and 10 from NEXRAD)are included in this comparative analysis.The results indicate that,compared with CINRAD matched data,NEXRAD exhibits larger biases in reflectivity when compared with the frequency-corrected Ku PR.The root-mean-square difference for CINRAD is calculated at 2.38 d B,whereas for NEXRAD it is 3.23 d B.The mean bias of CINRAD matched data is-0.16 d B,while the mean bias of NEXRAD is-2.10 d B.The mean standard deviation of bias for CINRAD is 2.15 d B,while for NEXRAD it is 2.29 d B.This study effectively assesses weather radar data in both the United States and China,which is crucial for improving the overall consistency of global precipitation estimates.
基金support from the National Natural Science Foundation of China(52373077,52003106,52103074,52233006,52161135302)the Research Foundation Flanders(G0F2322N)Innovation Program of Shanghai Municipal Education Commission(2021-01-07-00-03-E00108).
文摘Designing and fabricating a compatible low-reflectivity electromagnetic interference(EMI)shielding/high-temperature resistant infrared stealth material possesses a critical significance in the field of military.Hence,a hierarchical polyimide(PI)nonwoven fabric is fabricated by alkali treatment,in-situ growth of magnetic particles and"self-activated"electroless Ag plating process.Especially,the hierarchical impedance matching can be constructed by systematically assembling Fe_(3)O_(4)/Ag-loaded PI nonwoven fabric(PFA)and pure Ag-coated PI nonwoven fabric(PA),endowing it with an ultralowreflectivity EMI shielding performance.In addition,thermal insulation of fluffy three-dimensional(3D)space structure in PFA and low infrared emissivity of PA originated from Ag plating bring an excellent infrared stealth performance.More importantly,the strong bonding interaction between Fe_(3)O_(4),Ag,and PI fiber improves thermal stability in EMI shielding and high-temperature resistant infrared stealth performance.Such excellent comprehensive performance makes it promising for military tents to protect internal equipment from electromagnetic interference stemmed from adjacent equipment and/or enemy,and inhibit external infrared detection.
基金supported in part by the National Natural Science Foundation of China(Nos.12335018,12105264,and 12275248)NSAF Joint Fund Project(Nos.U2230107,U1730244,U2130207)+1 种基金Innovation and Development Fund of China Academy of Engineering Physics(No.CXKS20240052)Central Guidance for Local Science and Technology Development Fund Project(No.2023ZYDF075).
文摘The current work addresses the challenge of elucidating the performance of fluoroelastomers within the HMX(octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine)based polymer-bonded explosives(PBXs).To simulate the confined interface in PBXs,bilayer films of F2314/HMX and F2311/HMX were designed.Neutron reflectivity(NR),nanoindentation,and X-ray reflectivity(XRR)were employed to examine the layer thickness,interface characteristics,diffusion behavior,and surface morphology of the bilayers.NR measurements revealed interface thicknesses of 45Å and 98Å for F2314/HMX and F2311/HMX,respectively,indicating deeper penetration of F2311 into the HMX matrix.NR also suggested a denser polymer network with a higher scattering length density(SLD)near the HMX interface for both fluoroelastomers,while the bound layer of F2311 was notably thicker.Nanoindentation cross-checks and confirms the presence of a bound layer,highlighting the differences in stiffness and diffusion ability between the two polymers.The consistency between the NR and nanoindentation results suggests that F2311 demonstrates better flexibility and elasticity,whereas F2314 is stiffer and more plastic.Accordingly,the structures and performances of different fluoroelastomers at the HMX interface are discussed,which can provide valuable insights into the selection of binders for PBX formulations tailored to specific applications.
基金supported by the Ministry of Science and Higher Education of the Russian Federation(agreement No.075-15-2021-1349)。
文摘Synchrotron method of resonant X-ray reflectivity 2D mapping has been applied to study ultrathin epitaxial layers of WS_(2)grown by pulsed laser deposition on Al_(2)O_(3)(0001)substrates.The measurements were carried out across the L absorption edge of tungsten to perform depth-dependent element-selective analysis sensitive to potential chemical modification of the WS_(2)layer in ambient conditions.Despite the few monolayer thickness of the studied film,the experimentally measured maps of reflectance as a function of incident angle and photon energy turned out to be quite informative showing well-pronounced interference effects near W absorption edge at 10210 eV.The synchrotron studies were complemented with conventional non-resonant reflectance measurements carried out in the laboratory at a fixed photon energy corresponding to Cu Kαemission.The reconstruction of the depth and energy dependent scattering length density within the studied multilayers was carried out using the OpenCL empowered fitting software utilizing spectral shaping algorithm which does not rely on the pre-measured reference absorption spectra.A thin WO_(x) layer has been revealed at the surface of the WS_(2)layer pointing out to the effect of water assisted photo-oxidation reported in a number of works related to ultrathin layers of transition metal dichalcogenides.
基金supported by the 12th Five Year Plan National Science and Technology Major Projects(No.20011ZX05023-003-002)Research projects of CNOOC(No.C/KJF JDCJF 006-2009)
文摘Currently, the deghosting of towed streamer seismic data assumes a flat sea level and a sea-surface reflection coefficient of-1; this decreases the precision of deghosting. A new method that considers the rough sea surface is proposed to suppress ghost reflections. The proposed deghosting method obtains the rough sea surface reflection coefficient using Gaussian statistics, and calculates the optimized deghosting operator in the r/p domain. The proposed method is closer to the actual sea conditions, offers an improved deghosting operator, removes the ghost reflections from marine towed seismic data, widens the bandwidth and restores the low-frequency information, and finally improves the signal-to- noise ratio and resolution of the seismic data.
文摘A novel high reflectivity type of semiconductor saturable absorption mirror grown by metal organic chemical vapor deposition is presented.Using the mirror as well as an end mirror,passively mode locked Yb∶YAB laser is realized,which produces a pulse as short as 3 05ps at 1 044μm.The pulse frequency is 375MHz;the output power is 45mW.
文摘针对天气雷达网中的不同波段雷达反射率因子整体偏差较大,太阳法强度标定仅能测试接收通道一致性,无法测量发射双通道引入误差等问题,该文利用无人机高精度RTK或激光测距功能,实时获取金属球位置,设计了“粗调、细调、凝视”的雷达目标锁定方法,确定目标的最佳观测位置,通过计算金属球反射率因子实测值与理论值的偏差,实现了双偏振天气雷达全链路真值标定。结合襄阳S波段双偏振多普勒天气雷达在2025年4月25日开展了3次金属球标定试验,验证标定技术的可行性。试验结果表明,金属球反射率因子平均偏差ΔZ约0.27 d B,满足ΔZ≤0.5 dB的技术指标要求,雷达系统探测精度总体良好。使用无人机悬吊金属球标定反射率因子可以作为双偏振天气雷达全链路测试的重要手段,也为在线监测雷达健康状态提供了定期交叉检验依据。
文摘In this study,polyacrylic acid(PAA)films were employed as a model system,and a series of PAA films with tunable water wettability was systematically prepared by varying molecular weight and curing temperature.Using attenuated total reflectance Fourier-transform infrared spectroscopy(ATR-FTIR),the molecular configurations of surface carboxyl groups(COOH),free carboxyl(COOH_(f))and hydrogen-bonded carboxyl(COOH_(HB),were directly correlated with the polar component of surface energy(γ^(s,p)).By decomposing theγ^(s,p)values of the PAA thin films as a sum of the contributions of COOH_(f)and COOH_(H B),the intrinsic polar component of surface energy of COOH_(H B)(γ_(H B)^(s,p*))was quantified for the first time as 8.34 mN/m,significantly lower than that of COOH_(f)(γ_(f)^(s,p*)=34 mN/m).This result highlights that hydrogen bonding markedly reduces theγ^(s,p),providing a rational explanation for the relatively large water contact angle observed on PAA thin films.Furthermore,it establishes a thermodynamic basis for estimating the fraction of surface COOH_(H B)groups(f H B)from wettability measurements.Further extension of the model to carboxyl-terminated self-assembled monolayers(COOH-SAMs)revealed that surface COOH density(ΣCOOH)critically regulates wetting behavior:whenΣCOOH ranges from 4.30 to 5.25 nm^(-2),COOH groups predominantly exist in a free state and facilitate effective hydration layers,thereby promoting superhydrophilicity.Overall,this study not only establishes a unified thermodynamic framework linking surface COOH configurations to macroscopic wettability,but also validates its universality by extending it to COOH-SAMs systems,thereby providing a unified theoretical framework for the controllable design of hydrophilicity in various COOH-functionalized surfaces.
