Many specifications of paving asphalts are closely related to their colloidal stability, which is, however, determined by their exact chemical compositions. The Yumen vacuum residue (YVR), the bottoms of a paraffinic...Many specifications of paving asphalts are closely related to their colloidal stability, which is, however, determined by their exact chemical compositions. The Yumen vacuum residue (YVR), the bottoms of a paraffinic crude oil is unfit for the production of highway paving asphalts directly, Neither are the de-oiled asphalts of the YVR. In this research a blending method and an optimal process of solvent de-asphalts are adopted to investigate the feasibility of formulating highway-paving asphalts from YVR. Results show that highway paving asphalts are formulated by blending solvent de-oiled asphalts with one or more of the materials including YVR, decanted oil from FCC process, and furfural extracts from lubricating base stocks. Further investigations indicate that adding oil decanted from FCC process to the solvent de-asphalting process can increase the de-asphalted oil production, improve the de-oiled asphalts quality, and thus optimize the refinery processes. The methodology of this research can be extended even to refineries processing non-paraffinic crude oils.展开更多
In this work, we examine the impact of crude distillation unit(CDU) model errors on the results of refinery-wide optimization for production planning or feedstock selection. We compare the swing cut + bias CDU model w...In this work, we examine the impact of crude distillation unit(CDU) model errors on the results of refinery-wide optimization for production planning or feedstock selection. We compare the swing cut + bias CDU model with a recently developed hybrid CDU model(Fu et al., 2016). The hybrid CDU model computes material and energy balances, as well as product true boiling point(TBP) curves and bulk properties(e.g., sulfur% and cetane index, and other properties). Product TBP curves are predicted with an average error of 0.5% against rigorous simulation curves. Case studies of optimal operation computed using a planning model that is based on the swing cut + bias CDU model and using a planning model that incorporates the hybrid CDU model are presented. Our results show that significant economic benefits can be obtained using accurate CDU models in refinery production planning.展开更多
文摘Many specifications of paving asphalts are closely related to their colloidal stability, which is, however, determined by their exact chemical compositions. The Yumen vacuum residue (YVR), the bottoms of a paraffinic crude oil is unfit for the production of highway paving asphalts directly, Neither are the de-oiled asphalts of the YVR. In this research a blending method and an optimal process of solvent de-asphalts are adopted to investigate the feasibility of formulating highway-paving asphalts from YVR. Results show that highway paving asphalts are formulated by blending solvent de-oiled asphalts with one or more of the materials including YVR, decanted oil from FCC process, and furfural extracts from lubricating base stocks. Further investigations indicate that adding oil decanted from FCC process to the solvent de-asphalting process can increase the de-asphalted oil production, improve the de-oiled asphalts quality, and thus optimize the refinery processes. The methodology of this research can be extended even to refineries processing non-paraffinic crude oils.
基金supported by the Ontario Research FoundationMc Master Advanced Control ConsortiumImperial Oil
文摘In this work, we examine the impact of crude distillation unit(CDU) model errors on the results of refinery-wide optimization for production planning or feedstock selection. We compare the swing cut + bias CDU model with a recently developed hybrid CDU model(Fu et al., 2016). The hybrid CDU model computes material and energy balances, as well as product true boiling point(TBP) curves and bulk properties(e.g., sulfur% and cetane index, and other properties). Product TBP curves are predicted with an average error of 0.5% against rigorous simulation curves. Case studies of optimal operation computed using a planning model that is based on the swing cut + bias CDU model and using a planning model that incorporates the hybrid CDU model are presented. Our results show that significant economic benefits can be obtained using accurate CDU models in refinery production planning.