This study aims at determining the optimal CO2 separation technology for Chinese refineries, based on current available technologies, by the method of comprehensive evaluation. Firstly, according to the characteristic...This study aims at determining the optimal CO2 separation technology for Chinese refineries, based on current available technologies, by the method of comprehensive evaluation. Firstly, according to the characteristics of flue gas from Chinese refineries, three feasible CO2 separation technologies are selected. These are pressure swing adsorption （PSA）, chemical absorption （CA）, and membrane absorption （MA）. Secondly, an economic assessment of these three techniques is carried out in accordance with cash flow analysis. The results show that these three techniques all have economic feasibility and the PSA technique is the best. Finally, to further optimize the three techniques, a two-level fuzzy comprehensive evaluation model is established, including economic, technological, and environmental factors. Considering all the factors, PSA is optimal for Chinese refineries, followed by CA and MA. Therefore, to reduce Chinese refineries carbon emission, it is suggested that CO2 should be captured from off-gases using PSA.展开更多
The aim of this paper is to review previous works on the performance appraisal of Nigerian government-owned refineries. The review has been done in a general sense, covering appraisal works by engineers, scientists, m...The aim of this paper is to review previous works on the performance appraisal of Nigerian government-owned refineries. The review has been done in a general sense, covering appraisal works by engineers, scientists, management experts, economists, sociologists and even historians. The outcome indicates that while there seems to be several works directly and/or indirectly assessing the performance of the refineries in a general sense, there is a dearth of such in the specific area of energy consumption. There also appears to be no single one appraising energy utilisation of all the refineries at the same time in the open literature. This is in spite of the fact that refining processes are energy intensive. Despite popularisation of exergy analysis as a veritable tool, the only energy utilisation appraisal within our reach which was carried out on just one of the refineries has not been done exergetically. However, the work still reveals, within the limitations of 1st Law energy analysis that the energy consumption patterns are below international benchmarks in the oil and gas industry. Some suggestions have also been offered to take care of the energy efficiency challenges in these refineries. These include plant to plant analyses of energy utilisation patterns in the four refineries, periodical determination of GHG emission levels in the refineries using current international best practices as benchmarks, use of exergy analysis to check avoidable energy wastage in the refining processes, shifting refinery fuelling pattern in favour of low carbon content fuels like natural gas and ensuring regular turnaround maintenance of the system.展开更多
A strategy for the integration of production planning and scheduling in refineries is proposed. This strategy relies on rolling horizon strategy and a two-level decomposition strategy. This strategy involves an upper ...A strategy for the integration of production planning and scheduling in refineries is proposed. This strategy relies on rolling horizon strategy and a two-level decomposition strategy. This strategy involves an upper level multiperiod mixed integer linear programming （MILP） model and a lower level simulation system, which is extended from our previous framework for short-term scheduling problems [Luo, C.E, Rong, G, ＂Hierarchical apthis extended framework is to reduce the number of variables and the size of the optimization model and, to quickly find the optimal solution for the integrated planning/scheduling problem in refineries. Uncertainties are also considered in this article. An integrated robust optimization approach is introduced to cope with uncertain parameters with both continuous and discrete probability distribution.展开更多
This study investigates the effects of sampling conditions on volatile organic compound(VOC)compositions including different flow restrictors,SUMMA volumes,sampling heights,and wind speeds.Results show that at the six...This study investigates the effects of sampling conditions on volatile organic compound(VOC)compositions including different flow restrictors,SUMMA volumes,sampling heights,and wind speeds.Results show that at the six sampling heights the concentrations of main VOC species were slightly different,while the wind speed had a greater impact on the VOC composition of source profiles.With the increase of wind speed,the weighted percentage of high-carbon aromatic hydrocarbons was higher.Besides,there was an extremely different profile between the normal production and shutdown conditions of the delayed coking unit.To compare the emission characteristics of VOCs in various process units of the S and the C refineries,the samples were collected from the catalytic cracking unit,the continuous catalytic reforming unit,and the delayed coking unit.In the continuous catalytic reforming unit,C3-C5 alkanes and low-carbon aromatic hydrocarbons were the main components collected from the S and the C refineries,accounting for 67.1%and 34.9%,respectively.For the delayed coking unit,the total weighted percentage of high carbon C6-C12 alkanes was significantly higher than other units in the S and the C refineries,accounting for 30.5%and 24.4%,respectively.In the catalytic cracking unit,the low-carbon C2-C5 alkanes were abundant,and the weighted percentage of propylene was higher.The emission characteristics obtained were consistent with the processing technology of production units.The results indicate that the VOC emission characteristics from the same production unit in different refineries have similarities and significant differences which are related to the technological process.The emission characteristics of VOCs could provide the data support for source apportionment work in the production units.展开更多
<span style="font-family:Verdana;">This study investigates the economic benefits of energy efficiency to petroleum refineries regarding Tema Oil Refinery (TOR), Ghana. The study explores lessons relati...<span style="font-family:Verdana;">This study investigates the economic benefits of energy efficiency to petroleum refineries regarding Tema Oil Refinery (TOR), Ghana. The study explores lessons relating to the cost of production, energy recovery levels and economic fortunes of the refinery activities and designs a conceptual framework for improving the energy efficiency of Tema Oil Refinery (TOR). The study adopted a descriptive design using a quantitative approach to provide a statistical background to investigate the economic benefits of energy efficiency. A sample of 84 was adopted for study from a staff population of 520 working at Tema Oil refinery. In addition to primary data, secondary data on energy supply and consumption values from 2008 to 2019 was gathered. For the primary survey, 84 respondents were sampled from TOR and a structured questionnaire was used to retrieve information. A correlation analysis at P < 0.05 was conducted to test the relationship and significance of energy efficiency and economic benefits to the refinery. The study concludes that there is a linear trend between energy production (supply) and energy consumption. The energy generated in the entire economy of Ghana far exceeds the amount of energy consumed thus raising issues of waste or excesses that calls for better policies and management plan to improve EE. The study also identified that issues of lost energy are critical to the operations of the petroleum industry as the situation is compounded by the inability of the refineries to explore better ways to reduce and manage the waste. The study concludes that a significant and positive correlation between energy efficiency and the economic fortunes of Tema Oil Refinery is necessary for its economic fortunes. The supply of energy should have equivalence to the public consumption of energy.展开更多
The dispersion models were used to estimate or predict the concentration of air pollutants or toxins emitted from sources such as industrial plants, vehicular traffic or accidental chemical releases. In this study, th...The dispersion models were used to estimate or predict the concentration of air pollutants or toxins emitted from sources such as industrial plants, vehicular traffic or accidental chemical releases. In this study, the Industrial Source Complex Short Term (ISCST3) emission dispersion model was used to measure the ground level concentration of criteria air pollutants within 50 km radius of location. This model considered emissions from major point sources of pollutants in four existing and twenty-three proposed Nigeria petroleum refineries. The obtained ground level concentration for 24-hr averaging periods of the criteria air pollutants at sensitive receptor around each of the refineries was compared with the National Ambient Air Quality Standards (NAAQS) of Nigeria, World Bank and World Health Organization (WHO) to determine their level of compliance. The highest ground level concentration predicted to be 450 - 1875 μg/m3 for 24-h averaging period was obtained at Tonwei Oil Refinery, Ekeremor Local Government, Bayelsa State, while the lowest ground level concentration predicted to be 0.0099 - 0.1 μg/m3 for 24-h averaging period was obtained at Amakpe International Refinery, Eket Local Government, Akwa Ibom State. Percentage set limits of criteria air pollutants ranging from 0.02% to 94.5% are within the set standard limits and no health risk is associated with areas around the plant’s locations while percentage set limits of criteria pollutants ranging from 1.1 to 55.6 folds of the standards exceed the maximum permitted limits, hence affecting areas around the plants. The air quality standards guiding petroleum refinery emissions must be strictly considered, in order to ensure that the ground level concentrations do not exceed the required standard limits and prevent the adverse effects of air pollution in the Nigeria airshed.展开更多
The study on the enterprise＇s energy efficiency is one of the most important fields of energy efficiency research. Most studies used DEA and aggregate data to estimate the energy efficiency of enterprises. In this st...The study on the enterprise＇s energy efficiency is one of the most important fields of energy efficiency research. Most studies used DEA and aggregate data to estimate the energy efficiency of enterprises. In this study, based on Cobb-Douglas production function, we make a SFA model which takes the energy input and CO2 emission into account. By using the SFA model, we calculate the refineries＇ total-factor energy efficiency with Sinopec refineries＇ micro-data from 2004 to 2009. Meanwhile, we do empirical study on the factors which influence the energy efficiency. In the last, we put forward some advices so as to improve energy efficiency.展开更多
This study investigated environmental distribution and human exposure of polycyclic aromatic hydrocarbons(PAHs)and their derivatives in one Chinese petroleum refinery facility.It was found that,following with high con...This study investigated environmental distribution and human exposure of polycyclic aromatic hydrocarbons(PAHs)and their derivatives in one Chinese petroleum refinery facility.It was found that,following with high concentrations of 16 EPA PAHs(∑Parent-PAHs)in smelting subarea of studied petroleum refinery facility,total derivatives of PAHs[named as XPAHs,including nitro PAHs(NPAHs),chlorinated PAHs(Cl-PAHs),and brominated PAHs(Br-PAHs)]in gas(mean=1.57×10^(4)ng/m^(3)),total suspended particulate(TSP)(mean=4.33×10^(3) ng/m^(3))and soil(mean=4.37×10^(3) ng/g)in this subarea had 1.76-6.19 times higher levels than those from other subareas of this facility,surrounding residential areas and reference areas,indicating that petroleum refining processes would lead apparent derivation of PAHs.Especially,compared with those in residential and reference areas,gas samples in the petrochemical areas had higher∑NPAH/∑PAHs(mean=2.18),but lower∑Cl-PAH/∑PAHs(mean=1.43×10^(-1))and∑Br-PAH/∑PAHs ratios(mean=7.49×10^(-2)),indicating the richer nitrification of PAHs than chlorination during petrochemical process.The occupational exposure to PAHs and XPAHs in this petroleum refinery facility were 24-343 times higher than non-occupational exposure,and the ILCR(1.04×10^(-4))for petrochemical workers was considered to be potential high risk.Furthermore,one expanded high-resolution screening through GC Orbitrap/MS was performed for soils from petrochemical area,and another 35 PAHs were found,including alkyl-PAHs,phenyl-PAHs and other species,indicat-ing that profiles and risks of PAHs analogs in petrochemical areas deserve further expanded investigation.展开更多
Current ever-accumulating plastic waste can be considered a significant carbon resource for energy conversion and chemical production.The development of new approaches for upcycling plastic waste through chemical degr...Current ever-accumulating plastic waste can be considered a significant carbon resource for energy conversion and chemical production.The development of new approaches for upcycling plastic waste through chemical degradation may enable circularity and promote closed-loop recycling of carbon sources compared to traditional recycling methods.Zeolite,a widely used solid acid catalyst with high industrial potential in petroleum and biomass refining,has been extensively studied for its role in transforming plastics.In this review,we present an overview of zeolite-based catalytic systems for the chemical recycling of plastic waste and discuss how zeolites could potentially contribute to the future development of a circular economy.To provide a comprehensive understanding,we begin with a brief introduction to zeolites,analyzing their key features and exploring their opportunities as well as challenges in processing plastic waste.Subsequently,we delve into the chemistry of catalytic cracking and tandem catalysis using zeolite-based catalysts on plastics.Overall,we emphasize the importance of intelligent catalyst design and lower-energy pathways to incentivize plastic upcycling while alleviating the burden caused by waste plastics.展开更多
Poly(ethylene glycol-co-1,4-cyclohexanedimethanol terephthalate)(PETG)possesses excellent properties and stability than traditional poly(ethylene terephthalate)(PET).However,the production and application of PETG are ...Poly(ethylene glycol-co-1,4-cyclohexanedimethanol terephthalate)(PETG)possesses excellent properties and stability than traditional poly(ethylene terephthalate)(PET).However,the production and application of PETG are restricted by the expensive monomer(1,4-cyclohexanedimethanol,CHDM).Direct upgrading of waste PET to dimethyl cyclohexane-1,4-dicarboxylate(DMCD)can promote the production of CHDM in large scale.In this work,a bifunctional Ru/UiO-66_(def)-SO_(3)H catalyst was synthesized and utilized in coupled methanolysis(of waste PET to dimethyl terephthalate(DMT))and hydrogenation(of DMT to DMCD)under mild condition.Characterizations revealed that Ru/UiO-66_(def)-SO_(3)H possessed mesopores(dominant channels of 2.72 and 3.44 nm),enlarged surface area(998 m^(2)·g^(–1)),enhanced acidity(580μmol·g^(–1)),and Ru nanoparticles(NPs)dispersed highly(45.1%)compared to those of Ru/UiO-66.These combined advantages could accelerate the methanolysis and hydrogenation reactions simultaneously,promoting the performance of direct upgrading of PET to DMCD in one pot.In particular,the conversion of PET and yield of DMCD over Ru/UiO-66_(def)-SO_(3)H reached 100%and 97.7%at 170℃and 3 MPa H_(2)within 6 h.Moreover,Ru/UiO-66_(def)-SO3H was also capable for the upcycling of waste PET-based products including beverage bottles,textile fiber and packaging film to DMCD.展开更多
The first round of rectification action of the Central Environmental Inspection Group will be fully implemented in the near future.Six Central Environmental Inspection Groups will successively station in 10 provinces,...The first round of rectification action of the Central Environmental Inspection Group will be fully implemented in the near future.Six Central Environmental Inspection Groups will successively station in 10 provinces,including Henan,Hebei,Inner Mongolia,Heilongjiang,Jiangsu,Jiangxi,Guangdong,Guangxi。展开更多
Shandong Fuel Oil Association conducted by Sinopec Group was established in Jinan,the capital of Shandong province,on Janu-ary 28th.The forthcoming uniform supply of oil products by Sinopec to "local" refin-...Shandong Fuel Oil Association conducted by Sinopec Group was established in Jinan,the capital of Shandong province,on Janu-ary 28th.The forthcoming uniform supply of oil products by Sinopec to "local" refin-eries(not owned by Sinopec,CNPC or CNOOC) in Shandong has received wide-spread applause.As Qingdao Refinery constructed展开更多
Refinery sour water primarily originates from the tops of towers in various units and coker condensate,and cannot be discharged directly to a wastewater treatment plant due to high levels of chemical oxygen demand(COD...Refinery sour water primarily originates from the tops of towers in various units and coker condensate,and cannot be discharged directly to a wastewater treatment plant due to high levels of chemical oxygen demand(COD)and organic sulfur contents.Even after the recovery of H_(2)S from the sour water by the stripping process,the effluent still contains a high concentration of dissolved organic sulfur(DOS),which can have a huge bad influence.While chemical composition of dissolved organic matter(DOM)in refinery wastewater has been extensively studied,the investigation of recalcitrant DOS from sour waters remains unclear.In the present study,chemical composition of sour water DOMs(especially DOS)was investigated using fluorescence spectroscopy(excitation-emission matrix,EEM)and mass spectrometry,including gas chromatography-mass spectrometry(GC-MS)and high-resolution Orbitrap MS.The GC-MS and EEM results showed that volatile and low-aromaticity compounds were effectively removed during the stripping process,while compounds with high hydrophilicity and humification degree were found to be more recalcitrant.The Orbitrap MS results showed that weak-polar oxygenated sulfur compounds were easier to be removed than oxygenated compounds.However,the effluent still contained significant amounts of sulfur-containing compounds with multiple sulfur atoms,particularly in the form of highly unsaturated and aromatic compounds.The Orbitrap MS/MS results of CHOS-containing compounds from the effluent indicate that the sulfur atoms may exist as sulfonates,disulfide bonds,thioethers.Understanding the composition and structure of sour water DOS is crucial for the development of effective treatment processes that can target polysulfide compounds and minimize their impact on the environment.展开更多
Many specifications of paving asphalts are closely related to their colloidal stability, which is, however, determined by their exact chemical compositions. The Yumen vacuum residue (YVR), the bottoms of a paraffinic...Many specifications of paving asphalts are closely related to their colloidal stability, which is, however, determined by their exact chemical compositions. The Yumen vacuum residue (YVR), the bottoms of a paraffinic crude oil is unfit for the production of highway paving asphalts directly, Neither are the de-oiled asphalts of the YVR. In this research a blending method and an optimal process of solvent de-asphalts are adopted to investigate the feasibility of formulating highway-paving asphalts from YVR. Results show that highway paving asphalts are formulated by blending solvent de-oiled asphalts with one or more of the materials including YVR, decanted oil from FCC process, and furfural extracts from lubricating base stocks. Further investigations indicate that adding oil decanted from FCC process to the solvent de-asphalting process can increase the de-asphalted oil production, improve the de-oiled asphalts quality, and thus optimize the refinery processes. The methodology of this research can be extended even to refineries processing non-paraffinic crude oils.展开更多
Today we live in a world of Hydrocarbon Energy Carriers, where Carbon is always used as a Carrier for Hydrogen 1) Biomass (CH1.44O0.66 or C6H12O6);2) Natural Gas [NG] (CH4);3) Water Gas [C+H2O];4) Gasoline (C6H12, C7H...Today we live in a world of Hydrocarbon Energy Carriers, where Carbon is always used as a Carrier for Hydrogen 1) Biomass (CH1.44O0.66 or C6H12O6);2) Natural Gas [NG] (CH4);3) Water Gas [C+H2O];4) Gasoline (C6H12, C7H18, C8H18, etc.);5) Kerosene (C17H36, C18H38, C19H40, C20H42, C21H44, C22H46, etc.) and;6) Crude Oil. The Carbon aggregates are all storable and have worthwhile, logistically manageable energy densities. But whenever recovering Energy from the Carbon molarities, CO2 gets emitted into the atmosphere, while separate use of Hydrogen Energy contents carried by the Carbon moieties would just generate water vapor. Hydrogen is also the most important intermediary in Refineries, hydrogenating lower grade Hydrocarbons into higher potencies, or for removing Sulfur by the formation of Hydrogen Sulfur, that can be dissociated after its segregation from the Hydrocarbon products. But most of the internal Hydrogen yields in Refineries today is used for onsite production of Ammonia as a basis for Energy fertilizers in high performance agriculture. Because Hydrogen is awkward to store and transport, most of it is currently used captive within large size centralized plants as a reactant for producing Hydrocarbon energy carriers, using the Carbon as a carrier for the Hydrogen moieties, to then be distributed over big enough areas for consumption of the such large scale plants’ volumes. With recently proven achievements of Hydrogen production from excess Wind & Solar Power by electrolysis, Hydrogen could become available in abundant quantities, to be distributed locally within the coverage area of the transmission grid such Wind & Solar installations are feeding into. In combination with Carbon as a reactant such abundant Hydrogen could also be synthesized into Hydrocarbon Energy Carriers and substitute fossil commodities.展开更多
基金the China University of Petroleum Foundationthe Research Institute of Safety and Environment TechnologyChina National Petroleum Corporation
文摘This study aims at determining the optimal CO2 separation technology for Chinese refineries, based on current available technologies, by the method of comprehensive evaluation. Firstly, according to the characteristics of flue gas from Chinese refineries, three feasible CO2 separation technologies are selected. These are pressure swing adsorption （PSA）, chemical absorption （CA）, and membrane absorption （MA）. Secondly, an economic assessment of these three techniques is carried out in accordance with cash flow analysis. The results show that these three techniques all have economic feasibility and the PSA technique is the best. Finally, to further optimize the three techniques, a two-level fuzzy comprehensive evaluation model is established, including economic, technological, and environmental factors. Considering all the factors, PSA is optimal for Chinese refineries, followed by CA and MA. Therefore, to reduce Chinese refineries carbon emission, it is suggested that CO2 should be captured from off-gases using PSA.
文摘The aim of this paper is to review previous works on the performance appraisal of Nigerian government-owned refineries. The review has been done in a general sense, covering appraisal works by engineers, scientists, management experts, economists, sociologists and even historians. The outcome indicates that while there seems to be several works directly and/or indirectly assessing the performance of the refineries in a general sense, there is a dearth of such in the specific area of energy consumption. There also appears to be no single one appraising energy utilisation of all the refineries at the same time in the open literature. This is in spite of the fact that refining processes are energy intensive. Despite popularisation of exergy analysis as a veritable tool, the only energy utilisation appraisal within our reach which was carried out on just one of the refineries has not been done exergetically. However, the work still reveals, within the limitations of 1st Law energy analysis that the energy consumption patterns are below international benchmarks in the oil and gas industry. Some suggestions have also been offered to take care of the energy efficiency challenges in these refineries. These include plant to plant analyses of energy utilisation patterns in the four refineries, periodical determination of GHG emission levels in the refineries using current international best practices as benchmarks, use of exergy analysis to check avoidable energy wastage in the refining processes, shifting refinery fuelling pattern in favour of low carbon content fuels like natural gas and ensuring regular turnaround maintenance of the system.
基金Supported by the National Natural Science Foundation of China （60421002） and the National High Technology R＆D Program of China （2007AA04Z191）.
文摘A strategy for the integration of production planning and scheduling in refineries is proposed. This strategy relies on rolling horizon strategy and a two-level decomposition strategy. This strategy involves an upper level multiperiod mixed integer linear programming （MILP） model and a lower level simulation system, which is extended from our previous framework for short-term scheduling problems [Luo, C.E, Rong, G, ＂Hierarchical apthis extended framework is to reduce the number of variables and the size of the optimization model and, to quickly find the optimal solution for the integrated planning/scheduling problem in refineries. Uncertainties are also considered in this article. An integrated robust optimization approach is introduced to cope with uncertain parameters with both continuous and discrete probability distribution.
基金This study was funded by the Natural Key Research and Development Program(Grant No.2016YFC0801301)the SINOPEC Program(Grant No.319022-10).
文摘This study investigates the effects of sampling conditions on volatile organic compound(VOC)compositions including different flow restrictors,SUMMA volumes,sampling heights,and wind speeds.Results show that at the six sampling heights the concentrations of main VOC species were slightly different,while the wind speed had a greater impact on the VOC composition of source profiles.With the increase of wind speed,the weighted percentage of high-carbon aromatic hydrocarbons was higher.Besides,there was an extremely different profile between the normal production and shutdown conditions of the delayed coking unit.To compare the emission characteristics of VOCs in various process units of the S and the C refineries,the samples were collected from the catalytic cracking unit,the continuous catalytic reforming unit,and the delayed coking unit.In the continuous catalytic reforming unit,C3-C5 alkanes and low-carbon aromatic hydrocarbons were the main components collected from the S and the C refineries,accounting for 67.1%and 34.9%,respectively.For the delayed coking unit,the total weighted percentage of high carbon C6-C12 alkanes was significantly higher than other units in the S and the C refineries,accounting for 30.5%and 24.4%,respectively.In the catalytic cracking unit,the low-carbon C2-C5 alkanes were abundant,and the weighted percentage of propylene was higher.The emission characteristics obtained were consistent with the processing technology of production units.The results indicate that the VOC emission characteristics from the same production unit in different refineries have similarities and significant differences which are related to the technological process.The emission characteristics of VOCs could provide the data support for source apportionment work in the production units.
文摘<span style="font-family:Verdana;">This study investigates the economic benefits of energy efficiency to petroleum refineries regarding Tema Oil Refinery (TOR), Ghana. The study explores lessons relating to the cost of production, energy recovery levels and economic fortunes of the refinery activities and designs a conceptual framework for improving the energy efficiency of Tema Oil Refinery (TOR). The study adopted a descriptive design using a quantitative approach to provide a statistical background to investigate the economic benefits of energy efficiency. A sample of 84 was adopted for study from a staff population of 520 working at Tema Oil refinery. In addition to primary data, secondary data on energy supply and consumption values from 2008 to 2019 was gathered. For the primary survey, 84 respondents were sampled from TOR and a structured questionnaire was used to retrieve information. A correlation analysis at P < 0.05 was conducted to test the relationship and significance of energy efficiency and economic benefits to the refinery. The study concludes that there is a linear trend between energy production (supply) and energy consumption. The energy generated in the entire economy of Ghana far exceeds the amount of energy consumed thus raising issues of waste or excesses that calls for better policies and management plan to improve EE. The study also identified that issues of lost energy are critical to the operations of the petroleum industry as the situation is compounded by the inability of the refineries to explore better ways to reduce and manage the waste. The study concludes that a significant and positive correlation between energy efficiency and the economic fortunes of Tema Oil Refinery is necessary for its economic fortunes. The supply of energy should have equivalence to the public consumption of energy.
文摘The dispersion models were used to estimate or predict the concentration of air pollutants or toxins emitted from sources such as industrial plants, vehicular traffic or accidental chemical releases. In this study, the Industrial Source Complex Short Term (ISCST3) emission dispersion model was used to measure the ground level concentration of criteria air pollutants within 50 km radius of location. This model considered emissions from major point sources of pollutants in four existing and twenty-three proposed Nigeria petroleum refineries. The obtained ground level concentration for 24-hr averaging periods of the criteria air pollutants at sensitive receptor around each of the refineries was compared with the National Ambient Air Quality Standards (NAAQS) of Nigeria, World Bank and World Health Organization (WHO) to determine their level of compliance. The highest ground level concentration predicted to be 450 - 1875 μg/m3 for 24-h averaging period was obtained at Tonwei Oil Refinery, Ekeremor Local Government, Bayelsa State, while the lowest ground level concentration predicted to be 0.0099 - 0.1 μg/m3 for 24-h averaging period was obtained at Amakpe International Refinery, Eket Local Government, Akwa Ibom State. Percentage set limits of criteria air pollutants ranging from 0.02% to 94.5% are within the set standard limits and no health risk is associated with areas around the plant’s locations while percentage set limits of criteria pollutants ranging from 1.1 to 55.6 folds of the standards exceed the maximum permitted limits, hence affecting areas around the plants. The air quality standards guiding petroleum refinery emissions must be strictly considered, in order to ensure that the ground level concentrations do not exceed the required standard limits and prevent the adverse effects of air pollution in the Nigeria airshed.
文摘The study on the enterprise＇s energy efficiency is one of the most important fields of energy efficiency research. Most studies used DEA and aggregate data to estimate the energy efficiency of enterprises. In this study, based on Cobb-Douglas production function, we make a SFA model which takes the energy input and CO2 emission into account. By using the SFA model, we calculate the refineries＇ total-factor energy efficiency with Sinopec refineries＇ micro-data from 2004 to 2009. Meanwhile, we do empirical study on the factors which influence the energy efficiency. In the last, we put forward some advices so as to improve energy efficiency.
基金supported by the National Key Research and Development Program of China(No.2019YFC1804501)the National Natural Science Foundation of China(Nos.22036007 and 22122611)+1 种基金the Natural Science Foundation of Shandong Province(No.ZR2020ME228)the Introduction and Cultivation Plan for Young Innovative Talents of Colleges and Universities.
文摘This study investigated environmental distribution and human exposure of polycyclic aromatic hydrocarbons(PAHs)and their derivatives in one Chinese petroleum refinery facility.It was found that,following with high concentrations of 16 EPA PAHs(∑Parent-PAHs)in smelting subarea of studied petroleum refinery facility,total derivatives of PAHs[named as XPAHs,including nitro PAHs(NPAHs),chlorinated PAHs(Cl-PAHs),and brominated PAHs(Br-PAHs)]in gas(mean=1.57×10^(4)ng/m^(3)),total suspended particulate(TSP)(mean=4.33×10^(3) ng/m^(3))and soil(mean=4.37×10^(3) ng/g)in this subarea had 1.76-6.19 times higher levels than those from other subareas of this facility,surrounding residential areas and reference areas,indicating that petroleum refining processes would lead apparent derivation of PAHs.Especially,compared with those in residential and reference areas,gas samples in the petrochemical areas had higher∑NPAH/∑PAHs(mean=2.18),but lower∑Cl-PAH/∑PAHs(mean=1.43×10^(-1))and∑Br-PAH/∑PAHs ratios(mean=7.49×10^(-2)),indicating the richer nitrification of PAHs than chlorination during petrochemical process.The occupational exposure to PAHs and XPAHs in this petroleum refinery facility were 24-343 times higher than non-occupational exposure,and the ILCR(1.04×10^(-4))for petrochemical workers was considered to be potential high risk.Furthermore,one expanded high-resolution screening through GC Orbitrap/MS was performed for soils from petrochemical area,and another 35 PAHs were found,including alkyl-PAHs,phenyl-PAHs and other species,indicat-ing that profiles and risks of PAHs analogs in petrochemical areas deserve further expanded investigation.
文摘Current ever-accumulating plastic waste can be considered a significant carbon resource for energy conversion and chemical production.The development of new approaches for upcycling plastic waste through chemical degradation may enable circularity and promote closed-loop recycling of carbon sources compared to traditional recycling methods.Zeolite,a widely used solid acid catalyst with high industrial potential in petroleum and biomass refining,has been extensively studied for its role in transforming plastics.In this review,we present an overview of zeolite-based catalytic systems for the chemical recycling of plastic waste and discuss how zeolites could potentially contribute to the future development of a circular economy.To provide a comprehensive understanding,we begin with a brief introduction to zeolites,analyzing their key features and exploring their opportunities as well as challenges in processing plastic waste.Subsequently,we delve into the chemistry of catalytic cracking and tandem catalysis using zeolite-based catalysts on plastics.Overall,we emphasize the importance of intelligent catalyst design and lower-energy pathways to incentivize plastic upcycling while alleviating the burden caused by waste plastics.
文摘Poly(ethylene glycol-co-1,4-cyclohexanedimethanol terephthalate)(PETG)possesses excellent properties and stability than traditional poly(ethylene terephthalate)(PET).However,the production and application of PETG are restricted by the expensive monomer(1,4-cyclohexanedimethanol,CHDM).Direct upgrading of waste PET to dimethyl cyclohexane-1,4-dicarboxylate(DMCD)can promote the production of CHDM in large scale.In this work,a bifunctional Ru/UiO-66_(def)-SO_(3)H catalyst was synthesized and utilized in coupled methanolysis(of waste PET to dimethyl terephthalate(DMT))and hydrogenation(of DMT to DMCD)under mild condition.Characterizations revealed that Ru/UiO-66_(def)-SO_(3)H possessed mesopores(dominant channels of 2.72 and 3.44 nm),enlarged surface area(998 m^(2)·g^(–1)),enhanced acidity(580μmol·g^(–1)),and Ru nanoparticles(NPs)dispersed highly(45.1%)compared to those of Ru/UiO-66.These combined advantages could accelerate the methanolysis and hydrogenation reactions simultaneously,promoting the performance of direct upgrading of PET to DMCD in one pot.In particular,the conversion of PET and yield of DMCD over Ru/UiO-66_(def)-SO_(3)H reached 100%and 97.7%at 170℃and 3 MPa H_(2)within 6 h.Moreover,Ru/UiO-66_(def)-SO3H was also capable for the upcycling of waste PET-based products including beverage bottles,textile fiber and packaging film to DMCD.
文摘The first round of rectification action of the Central Environmental Inspection Group will be fully implemented in the near future.Six Central Environmental Inspection Groups will successively station in 10 provinces,including Henan,Hebei,Inner Mongolia,Heilongjiang,Jiangsu,Jiangxi,Guangdong,Guangxi。
文摘Shandong Fuel Oil Association conducted by Sinopec Group was established in Jinan,the capital of Shandong province,on Janu-ary 28th.The forthcoming uniform supply of oil products by Sinopec to "local" refin-eries(not owned by Sinopec,CNPC or CNOOC) in Shandong has received wide-spread applause.As Qingdao Refinery constructed
基金supported by the National Natural Science Foundation of China(42003059)State Key Laboratory of Coal Mining and Clean Utilization(2021-CMCU-KF009)the Science Foundation of China University of Petroleum,Beijing(No.2462023YJRC003)。
文摘Refinery sour water primarily originates from the tops of towers in various units and coker condensate,and cannot be discharged directly to a wastewater treatment plant due to high levels of chemical oxygen demand(COD)and organic sulfur contents.Even after the recovery of H_(2)S from the sour water by the stripping process,the effluent still contains a high concentration of dissolved organic sulfur(DOS),which can have a huge bad influence.While chemical composition of dissolved organic matter(DOM)in refinery wastewater has been extensively studied,the investigation of recalcitrant DOS from sour waters remains unclear.In the present study,chemical composition of sour water DOMs(especially DOS)was investigated using fluorescence spectroscopy(excitation-emission matrix,EEM)and mass spectrometry,including gas chromatography-mass spectrometry(GC-MS)and high-resolution Orbitrap MS.The GC-MS and EEM results showed that volatile and low-aromaticity compounds were effectively removed during the stripping process,while compounds with high hydrophilicity and humification degree were found to be more recalcitrant.The Orbitrap MS results showed that weak-polar oxygenated sulfur compounds were easier to be removed than oxygenated compounds.However,the effluent still contained significant amounts of sulfur-containing compounds with multiple sulfur atoms,particularly in the form of highly unsaturated and aromatic compounds.The Orbitrap MS/MS results of CHOS-containing compounds from the effluent indicate that the sulfur atoms may exist as sulfonates,disulfide bonds,thioethers.Understanding the composition and structure of sour water DOS is crucial for the development of effective treatment processes that can target polysulfide compounds and minimize their impact on the environment.
文摘Many specifications of paving asphalts are closely related to their colloidal stability, which is, however, determined by their exact chemical compositions. The Yumen vacuum residue (YVR), the bottoms of a paraffinic crude oil is unfit for the production of highway paving asphalts directly, Neither are the de-oiled asphalts of the YVR. In this research a blending method and an optimal process of solvent de-asphalts are adopted to investigate the feasibility of formulating highway-paving asphalts from YVR. Results show that highway paving asphalts are formulated by blending solvent de-oiled asphalts with one or more of the materials including YVR, decanted oil from FCC process, and furfural extracts from lubricating base stocks. Further investigations indicate that adding oil decanted from FCC process to the solvent de-asphalting process can increase the de-asphalted oil production, improve the de-oiled asphalts quality, and thus optimize the refinery processes. The methodology of this research can be extended even to refineries processing non-paraffinic crude oils.
文摘Today we live in a world of Hydrocarbon Energy Carriers, where Carbon is always used as a Carrier for Hydrogen 1) Biomass (CH1.44O0.66 or C6H12O6);2) Natural Gas [NG] (CH4);3) Water Gas [C+H2O];4) Gasoline (C6H12, C7H18, C8H18, etc.);5) Kerosene (C17H36, C18H38, C19H40, C20H42, C21H44, C22H46, etc.) and;6) Crude Oil. The Carbon aggregates are all storable and have worthwhile, logistically manageable energy densities. But whenever recovering Energy from the Carbon molarities, CO2 gets emitted into the atmosphere, while separate use of Hydrogen Energy contents carried by the Carbon moieties would just generate water vapor. Hydrogen is also the most important intermediary in Refineries, hydrogenating lower grade Hydrocarbons into higher potencies, or for removing Sulfur by the formation of Hydrogen Sulfur, that can be dissociated after its segregation from the Hydrocarbon products. But most of the internal Hydrogen yields in Refineries today is used for onsite production of Ammonia as a basis for Energy fertilizers in high performance agriculture. Because Hydrogen is awkward to store and transport, most of it is currently used captive within large size centralized plants as a reactant for producing Hydrocarbon energy carriers, using the Carbon as a carrier for the Hydrogen moieties, to then be distributed over big enough areas for consumption of the such large scale plants’ volumes. With recently proven achievements of Hydrogen production from excess Wind & Solar Power by electrolysis, Hydrogen could become available in abundant quantities, to be distributed locally within the coverage area of the transmission grid such Wind & Solar installations are feeding into. In combination with Carbon as a reactant such abundant Hydrogen could also be synthesized into Hydrocarbon Energy Carriers and substitute fossil commodities.
