The 137Cs vertical distributions in uncultivated and cultivated soils, developed from Quaternary red clay, granite, argillaceous shale, and red sandstone, were studied to develop reliable guidelines for selecting refe...The 137Cs vertical distributions in uncultivated and cultivated soils, developed from Quaternary red clay, granite, argillaceous shale, and red sandstone, were studied to develop reliable guidelines for selecting reference sites in southeastern China, which is dominated by strong acidic and/or clay-textured soils, and examine their reliability by comparing them to the reported 137Cs reference inventory data to see whether they agreed with the global distribution pattern. It was observed that a relatively high proportion of 137Cs was concentrated in the surface layers of soils with relatively high clay content. In the paddy soils developed from granite more 137Cs penetrated to depths below the plow layer (about 45.3%), when compared to those from the other three parent materials. The relatively low soil 137Cs inventories on crests excluded using the crest as the 137Cs reference site; instead the paddy field on the hillock plain was selected. Furthermore, within a specific county characterized by great systematic spatial variations of rainfall and topography across the landscape, a significant (P<0.01) and positive linear relationship (r2=0.81) between local 137Cs inventory and corresponding local annual rainfall was observed. Thus, for areas with large variations in rainfall, a single uniform value of local 137Cs reference inventory should be used with caution.展开更多
A land surface model driven by the continuous three-year observed meteorological data with a time interval of 30 minutes at the Tongyu station, a reference site of the Coordinated Enhanced Observing Period （CEOP）, w...A land surface model driven by the continuous three-year observed meteorological data with a time interval of 30 minutes at the Tongyu station, a reference site of the Coordinated Enhanced Observing Period （CEOP）, was used to evaluate the observation bias of soil moisture （SM） data and analyze the variation of SM at different time scales. The saline-alkaline soil of the grassland at the Tongyu site makes the measured SM too high, especially in boreal summer of 2003-05. The simulated annual mean SM has the lowest value in 2004 and its three-year variation corresponds to the change of precipitation, whereas the observation shows the increasing trend from 2003 to 2005. Compared to the variation range between -60% and 40% for the anomaly percentage of the simulated daily mean SM during May-October of 2004, the measured data show the higher values more than 40%. The magnitude of the variation trend of the observed daily mean SM in 2003 and 2005 is generally consistent with the simulation. The largest deficiency for the soil moisture observation of the grassland is the overestimated value in the drought year with less precipitation. The simulated monthly mean SM has the lowest value in March due to the large contribution of evaporation relative to precipitation and this phenomenon can not be reproduced in the observation.展开更多
Generic polymer models capturing the chain connectivity and excluded-volume interactions between polymer segments can be classified, according to whether or not the 3D integral of the latter diverges, into hard- and s...Generic polymer models capturing the chain connectivity and excluded-volume interactions between polymer segments can be classified, according to whether or not the 3D integral of the latter diverges, into hard- and soft-core models. Taking homogeneous systems of compressible homopolymer melts (or equivalently homopolymer solutions in an implicit, good solvent) in the continuum as an example, we recently compared the correlation effects on the structural and thermodynamic properties of the hard- and soft-core models given by the polymer reference interaction site model (PRISM) theory with the Percus-Yevick (PY) closure (Polymers 2023, 15, 1180). Here we analyzed in detail the numerical errors and behavior of the interchain pair correlation functions (PCFs) given by the PRISM-PY calculations of these models using an efficient numerical approach that we proposed. Our numerical approach has the least number of independent variables to be iteratively solved, analytically treats the discontinuities caused by the non-bonded pair potential (such as that of the hard spheres) and takes only the inverse Fourier transform of the interchain indirect PCF between polymer segments (which is continuous and decays towards 0 with increasing wavenumber much faster than both the interchain direct and total PCFs), and is essential for us to accurately solve the PRISM-PY theory for chain length N as large as 106. To capture the correlation-hole effect, the real-space cut-off in the PRISM calculations should be proportional to the square root of N.展开更多
Time-dependent diffusion coefficient and conventional diffusion constant are calculated and analyzed to study diffusion of nanoparticles in polymer melts. A generalized Langevin equa- tion is adopted to describe the d...Time-dependent diffusion coefficient and conventional diffusion constant are calculated and analyzed to study diffusion of nanoparticles in polymer melts. A generalized Langevin equa- tion is adopted to describe the diffusion dynamics. Mode-coupling theory is employed to calculate the memory kernel of friction. For simplicity, only microscopic terms arising from binary collision and coupling to the solvent density fluctuation are included in the formalism. The equilibrium structural information functions of the polymer nanocomposites required by mode-coupling theory are calculated on the basis of polymer reference interaction site model with Percus-Yevick closure. The effect of nanoparticle size and that of the polymer size are clarified explicitly. The structural functions, the friction kernel, as well as the diffusion coefficient show a rich variety with varying nanoparticle radius and polymer chain length. We find that for small nanoparticles or short chain polymers, the characteristic short time non-Markov diffusion dynamics becomes more prominent, and the diffusion coefficient takes longer time to approach asymptotically the conventional diffusion constant. This constant due to the microscopic contributions will decrease with the increase of nanoparticle size, while increase with polymer size. Furthermore, our result of diffusion constant from mode- coupling theory is compared with the value predicted from the Stokes-Einstein relation. It shows that the microscopic contributions to the diffusion constant are dominant for small nanoparticles or long chain polymers. Inversely, when nanonparticle is big, or polymer chain is short, the hydrodynamic contribution might play a significant role.展开更多
In coordination with Global Cryosphere Watch （GCW） initiated by World Meteorology Administration （WMO）, a regional ob- servation network is proposed based on existing stations/sites over High Asia and cryospberic ...In coordination with Global Cryosphere Watch （GCW） initiated by World Meteorology Administration （WMO）, a regional ob- servation network is proposed based on existing stations/sites over High Asia and cryospberic elements required by GCW. Thus, High Asian Cryosphere （HAC） network is preliminary designed, composing of seven ＂supersites＂, each containing several refer- ence sites. The network covers major mountain ranges in High Asia, such as East Tianshan, Qilian, Tanggula, Nyainqentanglha, Himalayas as well as the central and eastern Qinghai-Xizang （Tibet） Plateau. Although multiple cryospberic elements were ob- served at the existing HAC network, many others, which are required by Integrated Global Observation System-Cryosphere Theme （IGOS-Cryosphere）, are not yet included. More comprehensive observations are necessary to be included into ＂supersites＂ of HAC, so that the basic requirements for validation of satellite data, assimilation and coupled regional models can be met.展开更多
The seven co-located sites of the Crustal Movement Observation Network of China（CMONOC） in Shanghai, Wuhan, Kunming, Beijing, Xi＇an, Changchun, and Urumqi are equipped with Global Navigation Satellite System（GNSS...The seven co-located sites of the Crustal Movement Observation Network of China（CMONOC） in Shanghai, Wuhan, Kunming, Beijing, Xi＇an, Changchun, and Urumqi are equipped with Global Navigation Satellite System（GNSS）, very long baseline interferometry（VLBI）, and satellite laser ranging（SLR） equipment. Co-location surveying of these sites was performed in 2012 and the accuracies of the solved tie vectors are approximately 5 mm.This paper proposes a mathematical model that handles the least squares adjustment of the 3D control network and calculates the tie vectors in one step, using all the available constraints in the adjustment. Using the new mathematical model, local tie vectors can be more precisely determined and their covariance more reasonably estimated.展开更多
基金Project supported by the National Key Basic Research Support Foundation of China (No. G1999011801) the National Natural Science Foundation of China (No. 49973027)and Japan Society for the Promotion of Science (No. P04575).
文摘The 137Cs vertical distributions in uncultivated and cultivated soils, developed from Quaternary red clay, granite, argillaceous shale, and red sandstone, were studied to develop reliable guidelines for selecting reference sites in southeastern China, which is dominated by strong acidic and/or clay-textured soils, and examine their reliability by comparing them to the reported 137Cs reference inventory data to see whether they agreed with the global distribution pattern. It was observed that a relatively high proportion of 137Cs was concentrated in the surface layers of soils with relatively high clay content. In the paddy soils developed from granite more 137Cs penetrated to depths below the plow layer (about 45.3%), when compared to those from the other three parent materials. The relatively low soil 137Cs inventories on crests excluded using the crest as the 137Cs reference site; instead the paddy field on the hillock plain was selected. Furthermore, within a specific county characterized by great systematic spatial variations of rainfall and topography across the landscape, a significant (P<0.01) and positive linear relationship (r2=0.81) between local 137Cs inventory and corresponding local annual rainfall was observed. Thus, for areas with large variations in rainfall, a single uniform value of local 137Cs reference inventory should be used with caution.
基金the National Basic Research Program of China (Grant No. 2006CB400500)the Knowledge Innovation Program of the Chinese Academy of Sciences (Grant No. IAP 07114)the National Natural Science Foundation of China (Grant Nos. 40605025, 40730106)
文摘A land surface model driven by the continuous three-year observed meteorological data with a time interval of 30 minutes at the Tongyu station, a reference site of the Coordinated Enhanced Observing Period （CEOP）, was used to evaluate the observation bias of soil moisture （SM） data and analyze the variation of SM at different time scales. The saline-alkaline soil of the grassland at the Tongyu site makes the measured SM too high, especially in boreal summer of 2003-05. The simulated annual mean SM has the lowest value in 2004 and its three-year variation corresponds to the change of precipitation, whereas the observation shows the increasing trend from 2003 to 2005. Compared to the variation range between -60% and 40% for the anomaly percentage of the simulated daily mean SM during May-October of 2004, the measured data show the higher values more than 40%. The magnitude of the variation trend of the observed daily mean SM in 2003 and 2005 is generally consistent with the simulation. The largest deficiency for the soil moisture observation of the grassland is the overestimated value in the drought year with less precipitation. The simulated monthly mean SM has the lowest value in March due to the large contribution of evaporation relative to precipitation and this phenomenon can not be reproduced in the observation.
基金the donors of The American Chemical Society Petroleum Research Fund for partial support of this research
文摘Generic polymer models capturing the chain connectivity and excluded-volume interactions between polymer segments can be classified, according to whether or not the 3D integral of the latter diverges, into hard- and soft-core models. Taking homogeneous systems of compressible homopolymer melts (or equivalently homopolymer solutions in an implicit, good solvent) in the continuum as an example, we recently compared the correlation effects on the structural and thermodynamic properties of the hard- and soft-core models given by the polymer reference interaction site model (PRISM) theory with the Percus-Yevick (PY) closure (Polymers 2023, 15, 1180). Here we analyzed in detail the numerical errors and behavior of the interchain pair correlation functions (PCFs) given by the PRISM-PY calculations of these models using an efficient numerical approach that we proposed. Our numerical approach has the least number of independent variables to be iteratively solved, analytically treats the discontinuities caused by the non-bonded pair potential (such as that of the hard spheres) and takes only the inverse Fourier transform of the interchain indirect PCF between polymer segments (which is continuous and decays towards 0 with increasing wavenumber much faster than both the interchain direct and total PCFs), and is essential for us to accurately solve the PRISM-PY theory for chain length N as large as 106. To capture the correlation-hole effect, the real-space cut-off in the PRISM calculations should be proportional to the square root of N.
基金This work was supported by the National Natural Science Foundation of China （No.21173152）, the Ministry of Education of China （No.NCET-11-0359 and No.2011SCU04B31）, and the Science and Technology Department of Sichuan Province （No.2011HH0005）.
文摘Time-dependent diffusion coefficient and conventional diffusion constant are calculated and analyzed to study diffusion of nanoparticles in polymer melts. A generalized Langevin equa- tion is adopted to describe the diffusion dynamics. Mode-coupling theory is employed to calculate the memory kernel of friction. For simplicity, only microscopic terms arising from binary collision and coupling to the solvent density fluctuation are included in the formalism. The equilibrium structural information functions of the polymer nanocomposites required by mode-coupling theory are calculated on the basis of polymer reference interaction site model with Percus-Yevick closure. The effect of nanoparticle size and that of the polymer size are clarified explicitly. The structural functions, the friction kernel, as well as the diffusion coefficient show a rich variety with varying nanoparticle radius and polymer chain length. We find that for small nanoparticles or short chain polymers, the characteristic short time non-Markov diffusion dynamics becomes more prominent, and the diffusion coefficient takes longer time to approach asymptotically the conventional diffusion constant. This constant due to the microscopic contributions will decrease with the increase of nanoparticle size, while increase with polymer size. Furthermore, our result of diffusion constant from mode- coupling theory is compared with the value predicted from the Stokes-Einstein relation. It shows that the microscopic contributions to the diffusion constant are dominant for small nanoparticles or long chain polymers. Inversely, when nanonparticle is big, or polymer chain is short, the hydrodynamic contribution might play a significant role.
基金supported by Chinese 973 Project (2007CB411503)Chinese COPES(GYHY200706005)Hundred Talent Project of Chinese Academy of Sciences
文摘In coordination with Global Cryosphere Watch （GCW） initiated by World Meteorology Administration （WMO）, a regional ob- servation network is proposed based on existing stations/sites over High Asia and cryospberic elements required by GCW. Thus, High Asian Cryosphere （HAC） network is preliminary designed, composing of seven ＂supersites＂, each containing several refer- ence sites. The network covers major mountain ranges in High Asia, such as East Tianshan, Qilian, Tanggula, Nyainqentanglha, Himalayas as well as the central and eastern Qinghai-Xizang （Tibet） Plateau. Although multiple cryospberic elements were ob- served at the existing HAC network, many others, which are required by Integrated Global Observation System-Cryosphere Theme （IGOS-Cryosphere）, are not yet included. More comprehensive observations are necessary to be included into ＂supersites＂ of HAC, so that the basic requirements for validation of satellite data, assimilation and coupled regional models can be met.
基金sponsored by the Crustal Movement Observation Network of China(CMONOC)partially supported by the Natural Science Foundation of China(41274035,41174023)
文摘The seven co-located sites of the Crustal Movement Observation Network of China（CMONOC） in Shanghai, Wuhan, Kunming, Beijing, Xi＇an, Changchun, and Urumqi are equipped with Global Navigation Satellite System（GNSS）, very long baseline interferometry（VLBI）, and satellite laser ranging（SLR） equipment. Co-location surveying of these sites was performed in 2012 and the accuracies of the solved tie vectors are approximately 5 mm.This paper proposes a mathematical model that handles the least squares adjustment of the 3D control network and calculates the tie vectors in one step, using all the available constraints in the adjustment. Using the new mathematical model, local tie vectors can be more precisely determined and their covariance more reasonably estimated.
