Oxygen evolution reaction(OER)is widely recognized as a bottleneck of water electrolysis.To determine the underlying reaction mechanisms,particularly the relative contribution of the adsorbate evolution mechanism(AEM)...Oxygen evolution reaction(OER)is widely recognized as a bottleneck of water electrolysis.To determine the underlying reaction mechanisms,particularly the relative contribution of the adsorbate evolution mechanism(AEM)and lattice-oxygen participation mechanism(LOM),we conduct a comprehensive investigation combining Density Functional Theory(DFT)calculations and experimental validation.Our theoretical analysis of doped RuO_(2)catalysts reveals that heteroatom doping(Ni,Cu,and Zn)induces significant local charge transfer,leading to the increased charge state of Ru and the downshifted d-band center.This,in turn,enables the mechanism switching from the conventional AEM to the more efficient LOM,and finally improves OER activity.We also establish a simple yet powerful descriptor,Ne of Ru(representing charge density of Ru sites),which enables accurate prediction of both catalytic activity and stability.Guided by these theoretical predictions,we successfully synthesize a Ni-doped RuO_(2)catalyst,which exhibits excellent OER activity and stability in acidic media,achieving an overpotential of just 156 mV and maintaining stability for 4000 h at 10 mA cm^(−2),significantly surpassing the performance of the commercial RuO_(2).These findings not only provide fundamental insights into the mechanism-switching behavior in OER catalysis but also offer a practical strategy for designing high-performance,stable electrocatalysts for acidic water electrolysis.展开更多
We propose a digital rights management （DRM） system based on mobile agent to protect the copyrights of content providers. In the system, the content provider creates a time limited blackbox out of an original agent ...We propose a digital rights management （DRM） system based on mobile agent to protect the copyrights of content providers. In the system, the content provider creates a time limited blackbox out of an original agent and dispatches it to the user end to enforce DRM functions. The blackbox is an agent that can resist the attacks from the malicious user in a certain time interval. Owing to digital rights redistribution support, the user whose rights belong to redistribution category can transfer his rights to other users. Moreover, by introducing public key infrastructure （PKI） and certificate authority （CA） role, the security of the session can be ensured. An analysis of system security and performance and a comparison with traditional DRM system is given.展开更多
This study aimed to investigate the moment redistribution in continuous glass fiber reinforced polymer(GFRP)-concrete composite slabs caused by concrete cracking and steel bar yielding in the negative bending moment z...This study aimed to investigate the moment redistribution in continuous glass fiber reinforced polymer(GFRP)-concrete composite slabs caused by concrete cracking and steel bar yielding in the negative bending moment zone.An experimental bending moment redistribution test was conducted on continuous GFRP-concrete composite slabs,and a calculation method based on the conjugate beam method was proposed.The composite slabs were formed by combining GFRP profiles with a concrete layer and supported on steel beams to create two-span continuous composite slab specimens.Two methods,epoxy resin bonding,and stud connection,were used to connect the composite slabs with the steel beams.The experimental findings showed that the specimen connected with epoxy resin exhibited two moments redistribution phenomena during the loading process:concrete cracking and steel bar yielding at the internal support.In contrast,the composite slab connected with steel beams by studs exhibited only one-moment redistribution phenomenon throughout the loading process.As the concrete at the internal support cracked,the bending moment decreased in the internal support section and increased in the midspan section.When the steel bars yielded,the bending moment further decreased in the internal support section and increased in the mid-span section.Since GFRP profiles do not experience cracking,there was no significant decrease in the bending moment of the mid-span section.All test specimens experienced compressive failure of concrete at the mid-span section.Calculation results showed good agreement between the calculated and experimental values of bending moments in the mid-span section and internal support section.The proposed model can effectively predict the moment redistribution behavior of continuous GFRP-concrete composite slabs.展开更多
Hydroxyl radical(·OH)formation from Fe(Ⅱ)-bearing clay mineral oxygenation in the shallow subsurface has been well documented under moderate environmental conditions.However,the impact of freezing processes on t...Hydroxyl radical(·OH)formation from Fe(Ⅱ)-bearing clay mineral oxygenation in the shallow subsurface has been well documented under moderate environmental conditions.However,the impact of freezing processes on the·OH production capability of Fe(Ⅱ)-bearing clay minerals for organic contaminant degradation,particularly in seasonally frozen soils,remains unclear.In this study,we investigated the influence of pre-freezing durations on the mineral proprieties,·OH production,and phenol degradation during the oxygenation of reduced Fe-rich nontronite(rNAu-2)and Fe-poor montmorillonite(rSWy-3).During the freezing process of reduced clay minerals(1 mM Fe(Ⅱ)),the content of edge surface Fe and Fe(Ⅱ)decreased by up to 46%and 58%,respectively,followed by a slight increased as clay mineral particles aggregated and subsequently partially disaggregated.As the edge surface Fe(Ⅱ)is effective in O_(2) activation but less effective in the transformation of H_(2)O_(2) to·OH,the redistribution of edge surface Fe(Ⅱ)leads to that·OH production and phenol degradation increased initially and then decreased with pre-freezing durations ranging from 0 to 20 days.Moreover,the rate constants of phenol degradation for both the rapid and slow reaction phases also first increase and then decrease with freezing time.However,pre-freezing significantly influenced the rapid phase of phenol degradation by rNAu-2 but affected the slow phase by rSWy-3 due to the much higher edge-surface Fe(Ⅱ)content in rNAu-2.Overall,these findings provide novel insights into the mechanism of·OH production and contaminant degradation during the freeze-thaw processes in clay-rich soils.展开更多
With the upgrade of armor protection materials,higher requirements are put forward for the penetration performance of tungsten alloy kinetic energy armor-piercing projectiles,and the penetration performance is closely...With the upgrade of armor protection materials,higher requirements are put forward for the penetration performance of tungsten alloy kinetic energy armor-piercing projectiles,and the penetration performance is closely related to the adiabatic shear band under extreme stress conditions.Here,the detailed analysis of the adiabatic shear band microstructure evolution of a dual-phase 90W-Ni-Fe alloy under a high strain rate was conducted by combining advanced electron microscopic characterization,while discussing shear fracture from a mechanical perspective under thermoplastic instability.The high temperature and high stress environment inside the adiabatic shear band led to the refinement of the W phase andγ-(Ni,Fe)phase grains to the submicron level,and induced the elements redistribution of W,Ni,and Fe to precipitate W nanocrystalline with hardness as high as 11.7 GPa along the recrystallization grain boundaries of theγ-(Ni,Fe)phase.Mechanical incompatibility caused by the hardness difference between W nanocrystalline andγ-(Ni,Fe)phases led to a strain gradient at the interface.The microvoids preferentially nucleated at the W nanocrystalline/γ-(Ni,Fe)phase interface,then merged to form microcracks and grew further,leading to shear failure.展开更多
Overpressure prediction for exploratory drilling has become robust in most basins with increasing well control,high-quality seismic datasets,and proactive real-time overpressure monitoring while drilling.However,accur...Overpressure prediction for exploratory drilling has become robust in most basins with increasing well control,high-quality seismic datasets,and proactive real-time overpressure monitoring while drilling.However,accurate overpressure prediction remains challenging in offshore Northwest Borneo despite several decades of drilling experience.This paper focuses on two exploration wells drilled by Brunei Shell Petroleum 40 years apart that faced similar challenges with overpressure prediction and well control.An integrated lookback study is attempted using seismic and well-log data to explore the causes of the unsatisfactory Pore Pressure Prediction(PPP)outcome in pre-drill and real-time operation settings for thesewells.Our study indicates that the misprediction of overpressures is due to real differences in shale pressure(basis of pre-drill work and monitoring)and sand pressure(source of drill kick and well control chal-lenges)due to large-scale vertical leak or expulsion of deep-seated fluids into pre-compacted normally pressured overlying sediments in several regions through a mix of shear and tensile failure mechanisms.Such migrated fluids inflate the sand pressure in the normally compacted shallower sequences with the shale pressure remaining low.A predictive framework for upward fluid expulsion was attempted but found impracticable due to complex spatial and temporal variations in the horizontal stress field responsible for such leakage.As such,it is proposed that these migratory overpressures are essentially'unpredictable'from conventional PPP workflows viewed in the broad bucket of compaction disequi-librium(undercompaction)and fluid expansion(unloading)mechanisms.Further study is recommended to understand if such migrated overpressures in the sand can produce a discernible and predictable geophysical or petrophysical signature in the abutting normally compacted shales.The study highlights the possibility of large lateral variability in the sand overpressure within the same stratigraphic unit in regions with complex tectonostratigraphic evolution like Northwest Borneo.展开更多
Intense rainfall infiltration is one of the primary triggers for landslides.Developing a robust model for rainfall infiltration analysis is crucial for mitigating landslide disasters.Although the numerical solution of...Intense rainfall infiltration is one of the primary triggers for landslides.Developing a robust model for rainfall infiltration analysis is crucial for mitigating landslide disasters.Although the numerical solution of Richard's equation provides high computational accuracy,it often encounters convergence issues.In contrast,the Green-Ampt(GA)model,which is more computationally efficient,lacks accuracy in dealing with the non-uniform distribution of the initial volumetric water content(VWC)and the pore-water redistribution process.Therefore,this study proposes a novel model for analyzing the slope rainfall infiltration process based on the GA model.The proposed model discretizes both the geological layers of the slope and the rainfall event in spatial and temporal scales,respectively,improving accuracy by adjusting step sizes of discretization adaptively.The proposed model is applied to analyze the permeability,stability and reliability of heterogeneous infinite slopes considering uncertainties in multiple parameters.Comparative studies with the numerical solution of Richard's equation and other models demonstrate that the proposed model can provide high computational accuracy and superior analysis convergence in rainfall infiltration modeling.It also indicates that neglecting the pore-water redistribution underestimates the probability of slope failure,overestimates the factor of safety(FOS)of the slope,and inaccurately estimates the depth of the critical slip surface.Moreover,the uncertainties in shear strength parameters may overshadow the influence of initial VWC uncertainties on the slope reliability.This study provides a theoretical basis for the analysis of rainfall infiltration on heterogeneous slopes and the formulation of strategies for landslide disaster prevention.展开更多
With the evolution of nickel-based single crystal superalloys,there is an increase in heavy elements such as Re and Ru.This has made solutal convection more pronounced during the directional solidification process,lea...With the evolution of nickel-based single crystal superalloys,there is an increase in heavy elements such as Re and Ru.This has made solutal convection more pronounced during the directional solidification process,leading to solute redistribution and increasing the risk of casting defects such as low-angle grain boundaries.To avoid casting defects,downward directional solidification(DWS)method is adopted to eliminate solutal convection and change solute redistribution.However,there is currently no in-situ characterization or quantitative simulation studying the solute redistribution during DWS and upward directional solidification(UWS)processes.A multicomponent phase field simulation coupled with lattice Boltzmann method was employed to quantitatively investigate changes in dendrite morphology,solutal convection and deviation of dendrite tips from the perspective of solute redistribution during UWS and DWS processes.The simulation of microstructure agrees well with the experimental results.The mechanism that explains how solutal convection affects side branching behavior is depicted.A novel approach is introduced to characterize dendrite deviation,elucidating the reasons why defects are prone to occur under the influence of natural convection and solute redistribution.展开更多
Compared with Zn^(2+),the current mainly reported charge carrier for zinc hybrid capacitors,small-hydrated-sized and light-weight NH_(4)^(+)is expected as a better one to mediate cathodic interfacial electrochemical b...Compared with Zn^(2+),the current mainly reported charge carrier for zinc hybrid capacitors,small-hydrated-sized and light-weight NH_(4)^(+)is expected as a better one to mediate cathodic interfacial electrochemical behaviors,yet has not been unraveled.Here we propose an NH_(4)^(+)-modulated cationic solvation strategy to optimize cathodic spatial charge distribution and achieve dynamic Zn^(2+)/NH_(4)^(+)co-storage for boosting Zinc hybrid capacitors.Owing to the hierarchical cationic solvated structure in hybrid Zn(CF_(3)SO_(3))_(2)–NH_4CF_(3)SO_(3)electrolyte,high-reactive Zn^(2+)and small-hydrate-sized NH_4(H_(2)O))(4)^(+)induce cathodic interfacial Helmholtz plane reconfiguration,thus effectively enhancing the spatial charge density to activate 20%capacity enhancement.Furthermore,cathodic interfacial adsorbed hydrated NH_(4)^(+)ions afford high-kinetics and ultrastable C···H(NH_(4)^(+))charge storage process due to a much lower desolvation energy barrier compared with heavy and rigid Zn(H_(2)O)_6^(2+)(5.81 vs.14.90 eV).Consequently,physical uptake and multielectron redox of Zn^(2+)/NH_(4)^(+)in carbon cathode enable the zinc capacitor to deliver high capacity(240 mAh g^(-1)at 0.5 A g^(-1)),large-current tolerance(130 mAh g^(-1)at 50 A g^(-1))and ultralong lifespan(400,000cycles).This study gives new insights into the design of cathode–electrolyte interfaces toward advanced zinc-based energy storage.展开更多
Correction to:Nano-Micro Letters(2025)17:117 https://doi.org/10.1007/s40820-025-01660-0 Following publication of the original article[1],the authors reported that the supplementary file needed to be updated because th...Correction to:Nano-Micro Letters(2025)17:117 https://doi.org/10.1007/s40820-025-01660-0 Following publication of the original article[1],the authors reported that the supplementary file needed to be updated because they mistakenly used the incorrect version.The original article[1]has been corrected.展开更多
Poly(phenylene oxide)(PPO)exhibits excellent dielectric properties,making it an ideal substrate for high-frequency,high-speed copper-clad laminates.The phenolic hydroxyl group at the end of PPO plays a key role in its...Poly(phenylene oxide)(PPO)exhibits excellent dielectric properties,making it an ideal substrate for high-frequency,high-speed copper-clad laminates.The phenolic hydroxyl group at the end of PPO plays a key role in its reactivity.Accurately quantifying the phenolic hydroxyl content in PPO is essential but challenging.In this study,we proposed a method for measuring the phenolic hydroxyl content of PPO using differential UV absorption spectroscopy.In alkaline solutions,the phenolic hydroxyl in PPO completely ionizes to form phenoxide ions,leading to a significant increase in UV absorbance at approximately 250 and 300 nm.Notably,the differential UV absorbance at approximately 300 nm was directly proportional to the phenolic hydroxyl concentration.Using 2,6-dimethylphenol as a standard,a calibration curve was established to relate the phenolic hydroxyl concentration to differential UV absorbance at approximately 300 nm,providing a precise and straightforward method for phenolic hydroxyl quantification in PPO with distinct advantages over conventional techniques.展开更多
Redistribution of iron during directional solidification of metallurgical-grade silicon (MG-Si) was conducted at low growth rate. Concentrations of iron were examined by ICP-MS and figured in solid and liquid phases, ...Redistribution of iron during directional solidification of metallurgical-grade silicon (MG-Si) was conducted at low growth rate. Concentrations of iron were examined by ICP-MS and figured in solid and liquid phases, at grain boundary and in growth direction. Concentrations are significantly different between solid and liquid phases. The thickness of the solute boundary layer is about 4 mm verified by mass balance law, and the effective distribution coefficient is 2.98×10?4. Iron element easily segregates at grain boundary at low growth rate. In growth direction, concentrations are almost constant until 86% ingot height, and they do not meet the Scheil equation completely, which is caused by the low growth rate. The effect of convection on the redistribution of iron was discussed in detail. Especially, the “dead zone” of convection plays an important role in the iron redistribution.展开更多
During long term storage at 25℃ in the dark,a large number of cell content were transferred from the senescing scape to the developing cloves,and the transfer from the basal part of scape was earlier than that from t...During long term storage at 25℃ in the dark,a large number of cell content were transferred from the senescing scape to the developing cloves,and the transfer from the basal part of scape was earlier than that from the apical part in the excised garlic scape ( Allium sativum var Taichang).Levels of H 2O 2 decreased in the cloves and significantly increased up to 10 folds and then declined quickly in the scape.Levels of H 2O 2 were enhanced early in the basal part of scape.In the treatment of GA 3 at the cloves,levels of H 2O 2 were strongly enhanced in the cloves and inhibited in the scape,coinciding with the distinct inhibition of cell content tansfer.The results indicated that H 2O 2 may be involved in cell content redistribution and its regulation.3-Amino-1,2,4-triazole (AT) is a specific inhibitor of catalase.Effects of AT on cell content redistribution and levels of H 2O 2 were almost similar to those of GA 3,It further proved the above concept.According to the changes of H 2O 2 leves and activities of peroxidase and catalase in the cloves and in the scape,we suggest that the accumulation of H 2O 2 in the scape was transducted from the cloves,and the decline of H 2O 2 level in the scape with GA 3 or AT at the cloves was mainly through the inhibition of H 2O 2 synthesis in the cloves.展开更多
Sequential extraction procedure was applied to assess the dynamics of solid-phase transformation of added Cu, Pb, Cd, and Hg in a typical Chinese paddy soil incubated under three moisture regimes （75% field capacity,...Sequential extraction procedure was applied to assess the dynamics of solid-phase transformation of added Cu, Pb, Cd, and Hg in a typical Chinese paddy soil incubated under three moisture regimes （75% field capacity, wetting-drying cycle, and flooding）. The heavy metals spiked in the soil were time-dependently transferred from the easily extractable fraction （the exchangeable fraction） into less labile fractions （Fe-Mn oxide- and organic matter-bound fractions）, and thus reduced lability of the metals. No significant changes were found for the carbonate-bound and residual fractions of the heavy metals in the soil during the whole incubation. Change rate of the mobility factor （MF）, a proportion of weakly bound fractions （exchangeable and carbonate-bound） in the total metal of soil, reflected the transformation rate of metal speciation from the labile fractions toward stable fractions. It was found that soil moisture regime did not change the direction and pathways of transformation of metal speciation, but it significantly affected the transformation rate. In general, the paddy soil under flooding regime had higher metal reactivity compared with 75% field capacity and wetting-drying cycle regimes, resulting in the more complete movement of metals toward stable fractions. This might be related to the increased pH, precipitation of the metals with sulfides and higher concentration of amorphous Fe oxides under submerged condition.展开更多
The leaching and redistribution of nutrients in the surface layer of 4 types of red soils in SoutheastChina were studied with a lysimeter experiment under field conditions. Results showed that the leachingconcentrated...The leaching and redistribution of nutrients in the surface layer of 4 types of red soils in SoutheastChina were studied with a lysimeter experiment under field conditions. Results showed that the leachingconcentrated in the rainy season (from April to June). Generaily, the leaching of soil nutrients from thesurface layer of red soils was in the order of Ca > Mg > K > NO3-N. In fertilization treatment, the totalamount of soil nutrients leached out of the surface layer in a red soil derived from granite was the highest inall soils. The uptake by grass decreased the leaching of fertilizer ions in surface layer, particularly for NO3-N.Soil total N and exchangeable K, Ca and Mg in the surface layer decreased with leaching and grass uptakeduring the 2 years without new fertilization of urea, Ca(H2PO4)2, KCl, CaCO3 and MgCO3. Ca movedfrom the application layer (0~5 cm) of fertilizer and accumulated in the 10~30 cm depth in the soils studiedexcept that derived from Quaternary red clay. The deficiency of soil exchangeable K will become a seriousdegradation process facing the Southeast China.展开更多
The efficiency of EDTA, HNO3 and CaCl2 as extractants to remove Pb, Zn and Cu from tailing soils without varying soil pH was investigated with distributions of Pb, Zn and Cu being determined before and after extractio...The efficiency of EDTA, HNO3 and CaCl2 as extractants to remove Pb, Zn and Cu from tailing soils without varying soil pH was investigated with distributions of Pb, Zn and Cu being determined before and after extraction using the sequential extraction procedure of the optimized European Community Bureau of Reference (BCR). Results indicated that EDTA and HNO3 were both effective extracting agents.The extractability of extractants for Pb and Zn was in the order EDTA > HNO3 > CaCl2, while for Cu it was HNO3 > EDTA > CaCl2. After EDTA extraction, the proportion of Pb, Zn and Cu in the four fractions varied greatly, which was related to the strong extraction and complexation ability. Before and after extraction with HNO3 and CaCl2, the percentages of Pb, Zn and Cu in the reducible, oxidizable and residual fractions changed little compared to the acid-extractable fraction. The lability of metal in the soil and the kinds of extractants were the factors controlling the effects of metal extraction.展开更多
Tamarix spp. （Saltcedar） is a facultative phreatophyte that can tolerate drought when groundwater is not accessed. In addition to deep water uptake, hydraulic redistribution （HR） is another factor contributing to ...Tamarix spp. （Saltcedar） is a facultative phreatophyte that can tolerate drought when groundwater is not accessed. In addition to deep water uptake, hydraulic redistribution （HR） is another factor contributing to the drought tolerance of Tarnarix spp. In this study, data on soil volumetric moisture content （0）, lateral root sap flow, and relevant climate variables were used to investigate the patterns, magnitude, and controlling factors of HR of soil water by roots of Tamarix ramosissima Ledeb. in an extremely arid land in Northwest China. Results showed evident diurnal fluctuations in 0 at the depths of 30 and 50 cm, indicating ＂hydraulic lift＂ （HL）. 0 increased remarkably at 10 and 140 cm but decreased at 30 and 50 cm and slightly changed at 80 cm after rainfall, suggesting a possible ＂hydraulic descent＂ （HD）. However, no direct evidence was observed in the negative flow of lateral roots, supporting HR （including HL and HD） of T. ramosissima. The HR pathway unlikely occurred via lateral roots; instead, HR possibly occurred through adventitious roots with a diameter of 2-5 mm and a length of 60-100 cm. HR at depths of 20-60 cm ranged from 0.01-1.77 mm/d with an average of 0.43 mm/d, which accounted for an average of 22% of the estimated seasonal total water depletion at 0-160 cm during the growing season. The climate factors, particularly vapor pressure deficit and soil water potential gradient, accounted for at least 33% and 45% of HR variations with depths and years, respectively. In summary, T. ramosissima can be added to the wide list of existing species involved in HR. High levels of HR may represent a considerable fraction of daily soil water depletion and substantially improve plant water status. HR could vary tremendously in terms of years and depths, and this variation could be attributed to climate factors and soil water potential gradient.展开更多
Mixed contaminated brownfield sites have brought serious risks to human health and environmental safety. With the purpose of removing polycyclic aromatic hydrocarbons （PAHs） and heavy metals from a coking plant site...Mixed contaminated brownfield sites have brought serious risks to human health and environmental safety. With the purpose of removing polycyclic aromatic hydrocarbons （PAHs） and heavy metals from a coking plant site, an innovative technology for ex-situ washing was developed in the present work. The combination of 15.0 mLL-1 soybean oil and 7.5 g L-1 tea saponin proved an effective method to extract co-pollutants from soil. After two consecutive washing cycles, the efficiency rates of removal for 3-, 4-, 5（＋6）-ring, and total PAHs, Cd, and Ni were approximately 98.2%, 96.4%, 92.3%, 96.3%, 94.1%, and 89.4%, respectively. Meanwhile, as evaluated by Tenax extraction method and metal stability indices, the residual PAHs and heavy metals after consecutive washing mainly existed in the form with extremely low bioaccessibility in the soil. Thus, in the soil after two washing cycles, there appeared limited environmental transfer risk of co-pollutants. Moreover, a subsequent precipitation method with alkaline solution and PAH- degrading strain Sphingobium sp. PHE9 inoculation effectively removed 84.6%-100% of Cd, 82.5%-91.7% of Ni, and 92.6%-98.4% of PAHs from the first and second washing solvents. The recovered solvents also exhibited a high recycling effectiveness. Therefore, the combined cleanup strategy proposed in this study proved environmentally friendly, which also played a major role in risk assessment and marlagement in mixed polluted sites.展开更多
Atmospheric deposition(dry and wet deposition)is one of the primary sources of chemical inputs to terrestrial ecosystems and replenishes the nutrient pool in forest ecosystems.Precipitation often acts as a primary tra...Atmospheric deposition(dry and wet deposition)is one of the primary sources of chemical inputs to terrestrial ecosystems and replenishes the nutrient pool in forest ecosystems.Precipitation often acts as a primary transporting agent and solvent;thus,nutrient cycles in forests are closely linked to hydrological processes.We collected precipitation data during a growing season to explore variations in nutrient cycling and nutrient balances in the rainfall redistribution process(wet deposition)in a larch plantation in northeast China.We measured nutrient(NO_(3)^(-),PO_(4)^(3−),Cl^(−),K,Ca,Na,and Mg)inputs via bulk precipitation,throughfall and stemfl ow,and used a canopy budget model to estimate nutrient fl uxes via canopy exchange.Our results suggest that the average concentrations of the base cation(K,Ca,Na,and Mg)showed the following order:stemfl ow>throughfall>bulk precipitation.Throughfall and stemfl ow chemistry dramatically fl uctuated over the growing season when net fl uxes(throughfall+stemfl ow—bulk precipitation)of NO−3,PO3−4,SO2−4,Cl−,K,Ca,Na,and Mg were−6.676 kg·ha^(-1),−1.094 kg·ha^(-1),−2.371 kg·ha^(-1),1.975 kg·ha^(-1),0.470 kg·ha^(-1),−5.202 kg·ha^(-1),−0.336 kg·ha^(-1),and 1.397 kg·ha^(-1),respectively.These results suggest that NO−3,PO3−4,SO2−4,Ca,and Na were retained,while Cl−,K,and Mg were washed off by throughfall and stemfl ow.展开更多
Soil infiltration and redistribution are important processes in field water cycle, and it is necessary to develop a simple model to describe the processes. In this study, an algebraic solution for one-dimensional wate...Soil infiltration and redistribution are important processes in field water cycle, and it is necessary to develop a simple model to describe the processes. In this study, an algebraic solution for one-dimensional water infiltration and redistribution without evaporation in unsaturated soil was developed based on Richards equation. The algebraic solution had three parameters, namely, the saturated water conductivity, the comprehensive shape coefficient of the soil water content distribution, and the soil suction allocation coefficient. To analyze the physical features of these parameters, a relationship between the Green-Ampt model and the algebraic solution was established. The three parameters were estimated based on experimental observations, whereas the soil water content and the water infiltration duration were calculated using the algebraic solution. The calculated soil water content and infiltration duration were compared with the experimental observations, and the results indicated that the algebraic solution accurately described the unsaturated soil water flow processes.展开更多
基金supported by the National Natural Science Foundation of China(22472104)Guangdong Basic and Applied Basic Research Foundation(2024A1515012075,2024A1515010028)the Postdoctoral Fellowship Program of CPS Funder(GZC20241083,2025M771117)。
文摘Oxygen evolution reaction(OER)is widely recognized as a bottleneck of water electrolysis.To determine the underlying reaction mechanisms,particularly the relative contribution of the adsorbate evolution mechanism(AEM)and lattice-oxygen participation mechanism(LOM),we conduct a comprehensive investigation combining Density Functional Theory(DFT)calculations and experimental validation.Our theoretical analysis of doped RuO_(2)catalysts reveals that heteroatom doping(Ni,Cu,and Zn)induces significant local charge transfer,leading to the increased charge state of Ru and the downshifted d-band center.This,in turn,enables the mechanism switching from the conventional AEM to the more efficient LOM,and finally improves OER activity.We also establish a simple yet powerful descriptor,Ne of Ru(representing charge density of Ru sites),which enables accurate prediction of both catalytic activity and stability.Guided by these theoretical predictions,we successfully synthesize a Ni-doped RuO_(2)catalyst,which exhibits excellent OER activity and stability in acidic media,achieving an overpotential of just 156 mV and maintaining stability for 4000 h at 10 mA cm^(−2),significantly surpassing the performance of the commercial RuO_(2).These findings not only provide fundamental insights into the mechanism-switching behavior in OER catalysis but also offer a practical strategy for designing high-performance,stable electrocatalysts for acidic water electrolysis.
基金the National Natural Science Foundation of China (60502024)the Electronic Development Fund of Ministry of Informa-tion Industry of China ([2007]329)the Natural Science Foundation of Hubei Province (2005ABA267)
文摘We propose a digital rights management （DRM） system based on mobile agent to protect the copyrights of content providers. In the system, the content provider creates a time limited blackbox out of an original agent and dispatches it to the user end to enforce DRM functions. The blackbox is an agent that can resist the attacks from the malicious user in a certain time interval. Owing to digital rights redistribution support, the user whose rights belong to redistribution category can transfer his rights to other users. Moreover, by introducing public key infrastructure （PKI） and certificate authority （CA） role, the security of the session can be ensured. An analysis of system security and performance and a comparison with traditional DRM system is given.
基金supported by National Natural Science Foundation of China(Project No.51878156,received by Wen-Wei Wang) and EPC Innovation Consulting Project for Longkou Nanshan LNG Phase I Receiving Terminal(Z2000LGENT0399,received by Wen-Wei Wang and ZhaoJun Zhang).
文摘This study aimed to investigate the moment redistribution in continuous glass fiber reinforced polymer(GFRP)-concrete composite slabs caused by concrete cracking and steel bar yielding in the negative bending moment zone.An experimental bending moment redistribution test was conducted on continuous GFRP-concrete composite slabs,and a calculation method based on the conjugate beam method was proposed.The composite slabs were formed by combining GFRP profiles with a concrete layer and supported on steel beams to create two-span continuous composite slab specimens.Two methods,epoxy resin bonding,and stud connection,were used to connect the composite slabs with the steel beams.The experimental findings showed that the specimen connected with epoxy resin exhibited two moments redistribution phenomena during the loading process:concrete cracking and steel bar yielding at the internal support.In contrast,the composite slab connected with steel beams by studs exhibited only one-moment redistribution phenomenon throughout the loading process.As the concrete at the internal support cracked,the bending moment decreased in the internal support section and increased in the midspan section.When the steel bars yielded,the bending moment further decreased in the internal support section and increased in the mid-span section.Since GFRP profiles do not experience cracking,there was no significant decrease in the bending moment of the mid-span section.All test specimens experienced compressive failure of concrete at the mid-span section.Calculation results showed good agreement between the calculated and experimental values of bending moments in the mid-span section and internal support section.The proposed model can effectively predict the moment redistribution behavior of continuous GFRP-concrete composite slabs.
基金supported by the National Natural Science Foundation of China(Nos.U22A20591,42077185,42107217)the Sichuan Province Science and Technology Program for Distinguished Young Scholars(No.2022JDJQ0010)+1 种基金the Sichuan Science and Technology Program(No.2024NSFSC0842)the State Key Laboratory of Geohazard Prevention and Geoenvironment Protection(No.SKLGP2020Z002)。
文摘Hydroxyl radical(·OH)formation from Fe(Ⅱ)-bearing clay mineral oxygenation in the shallow subsurface has been well documented under moderate environmental conditions.However,the impact of freezing processes on the·OH production capability of Fe(Ⅱ)-bearing clay minerals for organic contaminant degradation,particularly in seasonally frozen soils,remains unclear.In this study,we investigated the influence of pre-freezing durations on the mineral proprieties,·OH production,and phenol degradation during the oxygenation of reduced Fe-rich nontronite(rNAu-2)and Fe-poor montmorillonite(rSWy-3).During the freezing process of reduced clay minerals(1 mM Fe(Ⅱ)),the content of edge surface Fe and Fe(Ⅱ)decreased by up to 46%and 58%,respectively,followed by a slight increased as clay mineral particles aggregated and subsequently partially disaggregated.As the edge surface Fe(Ⅱ)is effective in O_(2) activation but less effective in the transformation of H_(2)O_(2) to·OH,the redistribution of edge surface Fe(Ⅱ)leads to that·OH production and phenol degradation increased initially and then decreased with pre-freezing durations ranging from 0 to 20 days.Moreover,the rate constants of phenol degradation for both the rapid and slow reaction phases also first increase and then decrease with freezing time.However,pre-freezing significantly influenced the rapid phase of phenol degradation by rNAu-2 but affected the slow phase by rSWy-3 due to the much higher edge-surface Fe(Ⅱ)content in rNAu-2.Overall,these findings provide novel insights into the mechanism of·OH production and contaminant degradation during the freeze-thaw processes in clay-rich soils.
基金supported by the National Natural Science Foundation of China(No.51931012)the Science and Technology Innovation Program of Hunan Province(No.2023RC3068).
文摘With the upgrade of armor protection materials,higher requirements are put forward for the penetration performance of tungsten alloy kinetic energy armor-piercing projectiles,and the penetration performance is closely related to the adiabatic shear band under extreme stress conditions.Here,the detailed analysis of the adiabatic shear band microstructure evolution of a dual-phase 90W-Ni-Fe alloy under a high strain rate was conducted by combining advanced electron microscopic characterization,while discussing shear fracture from a mechanical perspective under thermoplastic instability.The high temperature and high stress environment inside the adiabatic shear band led to the refinement of the W phase andγ-(Ni,Fe)phase grains to the submicron level,and induced the elements redistribution of W,Ni,and Fe to precipitate W nanocrystalline with hardness as high as 11.7 GPa along the recrystallization grain boundaries of theγ-(Ni,Fe)phase.Mechanical incompatibility caused by the hardness difference between W nanocrystalline andγ-(Ni,Fe)phases led to a strain gradient at the interface.The microvoids preferentially nucleated at the W nanocrystalline/γ-(Ni,Fe)phase interface,then merged to form microcracks and grew further,leading to shear failure.
文摘Overpressure prediction for exploratory drilling has become robust in most basins with increasing well control,high-quality seismic datasets,and proactive real-time overpressure monitoring while drilling.However,accurate overpressure prediction remains challenging in offshore Northwest Borneo despite several decades of drilling experience.This paper focuses on two exploration wells drilled by Brunei Shell Petroleum 40 years apart that faced similar challenges with overpressure prediction and well control.An integrated lookback study is attempted using seismic and well-log data to explore the causes of the unsatisfactory Pore Pressure Prediction(PPP)outcome in pre-drill and real-time operation settings for thesewells.Our study indicates that the misprediction of overpressures is due to real differences in shale pressure(basis of pre-drill work and monitoring)and sand pressure(source of drill kick and well control chal-lenges)due to large-scale vertical leak or expulsion of deep-seated fluids into pre-compacted normally pressured overlying sediments in several regions through a mix of shear and tensile failure mechanisms.Such migrated fluids inflate the sand pressure in the normally compacted shallower sequences with the shale pressure remaining low.A predictive framework for upward fluid expulsion was attempted but found impracticable due to complex spatial and temporal variations in the horizontal stress field responsible for such leakage.As such,it is proposed that these migratory overpressures are essentially'unpredictable'from conventional PPP workflows viewed in the broad bucket of compaction disequi-librium(undercompaction)and fluid expansion(unloading)mechanisms.Further study is recommended to understand if such migrated overpressures in the sand can produce a discernible and predictable geophysical or petrophysical signature in the abutting normally compacted shales.The study highlights the possibility of large lateral variability in the sand overpressure within the same stratigraphic unit in regions with complex tectonostratigraphic evolution like Northwest Borneo.
基金supported by the National Natural Science Foundation of China(Grant Nos.52179103 and 52222905)Jiangxi Provincial Natural Science Foundation(Grant No.20242BAB24001).
文摘Intense rainfall infiltration is one of the primary triggers for landslides.Developing a robust model for rainfall infiltration analysis is crucial for mitigating landslide disasters.Although the numerical solution of Richard's equation provides high computational accuracy,it often encounters convergence issues.In contrast,the Green-Ampt(GA)model,which is more computationally efficient,lacks accuracy in dealing with the non-uniform distribution of the initial volumetric water content(VWC)and the pore-water redistribution process.Therefore,this study proposes a novel model for analyzing the slope rainfall infiltration process based on the GA model.The proposed model discretizes both the geological layers of the slope and the rainfall event in spatial and temporal scales,respectively,improving accuracy by adjusting step sizes of discretization adaptively.The proposed model is applied to analyze the permeability,stability and reliability of heterogeneous infinite slopes considering uncertainties in multiple parameters.Comparative studies with the numerical solution of Richard's equation and other models demonstrate that the proposed model can provide high computational accuracy and superior analysis convergence in rainfall infiltration modeling.It also indicates that neglecting the pore-water redistribution underestimates the probability of slope failure,overestimates the factor of safety(FOS)of the slope,and inaccurately estimates the depth of the critical slip surface.Moreover,the uncertainties in shear strength parameters may overshadow the influence of initial VWC uncertainties on the slope reliability.This study provides a theoretical basis for the analysis of rainfall infiltration on heterogeneous slopes and the formulation of strategies for landslide disaster prevention.
基金supported by the stable support project and the Major National Science and Technology Project(2017-VII-0008-0101).
文摘With the evolution of nickel-based single crystal superalloys,there is an increase in heavy elements such as Re and Ru.This has made solutal convection more pronounced during the directional solidification process,leading to solute redistribution and increasing the risk of casting defects such as low-angle grain boundaries.To avoid casting defects,downward directional solidification(DWS)method is adopted to eliminate solutal convection and change solute redistribution.However,there is currently no in-situ characterization or quantitative simulation studying the solute redistribution during DWS and upward directional solidification(UWS)processes.A multicomponent phase field simulation coupled with lattice Boltzmann method was employed to quantitatively investigate changes in dendrite morphology,solutal convection and deviation of dendrite tips from the perspective of solute redistribution during UWS and DWS processes.The simulation of microstructure agrees well with the experimental results.The mechanism that explains how solutal convection affects side branching behavior is depicted.A novel approach is introduced to characterize dendrite deviation,elucidating the reasons why defects are prone to occur under the influence of natural convection and solute redistribution.
基金financially supported by the National Natural Science Foundation of China(Nos.22272118,22172111 and 22309134)the Science and Technology Commission of Shanghai Municipality,China(Nos.22ZR1464100,20ZR1460300 and 19DZ2271500)+3 种基金China Postdoctoral Science Foundation(2022M712402)Shanghai Rising-Star Program(23YF1449200)Zhejiang Provincial Science and Technology Project(2022C01182)the Fundamental Research Funds for the Central Universities(22120210529 and 2023-3-YB-07)。
文摘Compared with Zn^(2+),the current mainly reported charge carrier for zinc hybrid capacitors,small-hydrated-sized and light-weight NH_(4)^(+)is expected as a better one to mediate cathodic interfacial electrochemical behaviors,yet has not been unraveled.Here we propose an NH_(4)^(+)-modulated cationic solvation strategy to optimize cathodic spatial charge distribution and achieve dynamic Zn^(2+)/NH_(4)^(+)co-storage for boosting Zinc hybrid capacitors.Owing to the hierarchical cationic solvated structure in hybrid Zn(CF_(3)SO_(3))_(2)–NH_4CF_(3)SO_(3)electrolyte,high-reactive Zn^(2+)and small-hydrate-sized NH_4(H_(2)O))(4)^(+)induce cathodic interfacial Helmholtz plane reconfiguration,thus effectively enhancing the spatial charge density to activate 20%capacity enhancement.Furthermore,cathodic interfacial adsorbed hydrated NH_(4)^(+)ions afford high-kinetics and ultrastable C···H(NH_(4)^(+))charge storage process due to a much lower desolvation energy barrier compared with heavy and rigid Zn(H_(2)O)_6^(2+)(5.81 vs.14.90 eV).Consequently,physical uptake and multielectron redox of Zn^(2+)/NH_(4)^(+)in carbon cathode enable the zinc capacitor to deliver high capacity(240 mAh g^(-1)at 0.5 A g^(-1)),large-current tolerance(130 mAh g^(-1)at 50 A g^(-1))and ultralong lifespan(400,000cycles).This study gives new insights into the design of cathode–electrolyte interfaces toward advanced zinc-based energy storage.
文摘Correction to:Nano-Micro Letters(2025)17:117 https://doi.org/10.1007/s40820-025-01660-0 Following publication of the original article[1],the authors reported that the supplementary file needed to be updated because they mistakenly used the incorrect version.The original article[1]has been corrected.
基金the“Pioneer”and“Leading Goose”R&D Program of Zhejiang(No.2023C01072)the Institute of Zhejiang University-Quzhou for their financial support。
文摘Poly(phenylene oxide)(PPO)exhibits excellent dielectric properties,making it an ideal substrate for high-frequency,high-speed copper-clad laminates.The phenolic hydroxyl group at the end of PPO plays a key role in its reactivity.Accurately quantifying the phenolic hydroxyl content in PPO is essential but challenging.In this study,we proposed a method for measuring the phenolic hydroxyl content of PPO using differential UV absorption spectroscopy.In alkaline solutions,the phenolic hydroxyl in PPO completely ionizes to form phenoxide ions,leading to a significant increase in UV absorbance at approximately 250 and 300 nm.Notably,the differential UV absorbance at approximately 300 nm was directly proportional to the phenolic hydroxyl concentration.Using 2,6-dimethylphenol as a standard,a calibration curve was established to relate the phenolic hydroxyl concentration to differential UV absorbance at approximately 300 nm,providing a precise and straightforward method for phenolic hydroxyl quantification in PPO with distinct advantages over conventional techniques.
基金Projects(51334004,51204143)supported by the National Natural Science Foundation of ChinaProject(2006L2003)supported by the Scientific Technological Innovation Platform of Fujian Province,China
文摘Redistribution of iron during directional solidification of metallurgical-grade silicon (MG-Si) was conducted at low growth rate. Concentrations of iron were examined by ICP-MS and figured in solid and liquid phases, at grain boundary and in growth direction. Concentrations are significantly different between solid and liquid phases. The thickness of the solute boundary layer is about 4 mm verified by mass balance law, and the effective distribution coefficient is 2.98×10?4. Iron element easily segregates at grain boundary at low growth rate. In growth direction, concentrations are almost constant until 86% ingot height, and they do not meet the Scheil equation completely, which is caused by the low growth rate. The effect of convection on the redistribution of iron was discussed in detail. Especially, the “dead zone” of convection plays an important role in the iron redistribution.
文摘During long term storage at 25℃ in the dark,a large number of cell content were transferred from the senescing scape to the developing cloves,and the transfer from the basal part of scape was earlier than that from the apical part in the excised garlic scape ( Allium sativum var Taichang).Levels of H 2O 2 decreased in the cloves and significantly increased up to 10 folds and then declined quickly in the scape.Levels of H 2O 2 were enhanced early in the basal part of scape.In the treatment of GA 3 at the cloves,levels of H 2O 2 were strongly enhanced in the cloves and inhibited in the scape,coinciding with the distinct inhibition of cell content tansfer.The results indicated that H 2O 2 may be involved in cell content redistribution and its regulation.3-Amino-1,2,4-triazole (AT) is a specific inhibitor of catalase.Effects of AT on cell content redistribution and levels of H 2O 2 were almost similar to those of GA 3,It further proved the above concept.According to the changes of H 2O 2 leves and activities of peroxidase and catalase in the cloves and in the scape,we suggest that the accumulation of H 2O 2 in the scape was transducted from the cloves,and the decline of H 2O 2 level in the scape with GA 3 or AT at the cloves was mainly through the inhibition of H 2O 2 synthesis in the cloves.
基金supported by the National Basic Research Program (973) of China (No. 2005CB121104)the National Natural Science Foundation of China (No.41071145)
文摘Sequential extraction procedure was applied to assess the dynamics of solid-phase transformation of added Cu, Pb, Cd, and Hg in a typical Chinese paddy soil incubated under three moisture regimes （75% field capacity, wetting-drying cycle, and flooding）. The heavy metals spiked in the soil were time-dependently transferred from the easily extractable fraction （the exchangeable fraction） into less labile fractions （Fe-Mn oxide- and organic matter-bound fractions）, and thus reduced lability of the metals. No significant changes were found for the carbonate-bound and residual fractions of the heavy metals in the soil during the whole incubation. Change rate of the mobility factor （MF）, a proportion of weakly bound fractions （exchangeable and carbonate-bound） in the total metal of soil, reflected the transformation rate of metal speciation from the labile fractions toward stable fractions. It was found that soil moisture regime did not change the direction and pathways of transformation of metal speciation, but it significantly affected the transformation rate. In general, the paddy soil under flooding regime had higher metal reactivity compared with 75% field capacity and wetting-drying cycle regimes, resulting in the more complete movement of metals toward stable fractions. This might be related to the increased pH, precipitation of the metals with sulfides and higher concentration of amorphous Fe oxides under submerged condition.
文摘The leaching and redistribution of nutrients in the surface layer of 4 types of red soils in SoutheastChina were studied with a lysimeter experiment under field conditions. Results showed that the leachingconcentrated in the rainy season (from April to June). Generaily, the leaching of soil nutrients from thesurface layer of red soils was in the order of Ca > Mg > K > NO3-N. In fertilization treatment, the totalamount of soil nutrients leached out of the surface layer in a red soil derived from granite was the highest inall soils. The uptake by grass decreased the leaching of fertilizer ions in surface layer, particularly for NO3-N.Soil total N and exchangeable K, Ca and Mg in the surface layer decreased with leaching and grass uptakeduring the 2 years without new fertilization of urea, Ca(H2PO4)2, KCl, CaCO3 and MgCO3. Ca movedfrom the application layer (0~5 cm) of fertilizer and accumulated in the 10~30 cm depth in the soils studiedexcept that derived from Quaternary red clay. The deficiency of soil exchangeable K will become a seriousdegradation process facing the Southeast China.
基金Project supported by the National High Technology Research and Development Program (863 Program) of China(No. 2001AA644020)the Natural Science Foundation of Hunan Province (No. 04JJ3013)
文摘The efficiency of EDTA, HNO3 and CaCl2 as extractants to remove Pb, Zn and Cu from tailing soils without varying soil pH was investigated with distributions of Pb, Zn and Cu being determined before and after extraction using the sequential extraction procedure of the optimized European Community Bureau of Reference (BCR). Results indicated that EDTA and HNO3 were both effective extracting agents.The extractability of extractants for Pb and Zn was in the order EDTA > HNO3 > CaCl2, while for Cu it was HNO3 > EDTA > CaCl2. After EDTA extraction, the proportion of Pb, Zn and Cu in the four fractions varied greatly, which was related to the strong extraction and complexation ability. Before and after extraction with HNO3 and CaCl2, the percentages of Pb, Zn and Cu in the reducible, oxidizable and residual fractions changed little compared to the acid-extractable fraction. The lability of metal in the soil and the kinds of extractants were the factors controlling the effects of metal extraction.
基金supported by the Key Project of the Chinese Academy of Sciences (KZZD-EW-04-05)the National Natural Science Foundation of China (91025024)the Western Light Project of the Chinese Academy of Sciences
文摘Tamarix spp. （Saltcedar） is a facultative phreatophyte that can tolerate drought when groundwater is not accessed. In addition to deep water uptake, hydraulic redistribution （HR） is another factor contributing to the drought tolerance of Tarnarix spp. In this study, data on soil volumetric moisture content （0）, lateral root sap flow, and relevant climate variables were used to investigate the patterns, magnitude, and controlling factors of HR of soil water by roots of Tamarix ramosissima Ledeb. in an extremely arid land in Northwest China. Results showed evident diurnal fluctuations in 0 at the depths of 30 and 50 cm, indicating ＂hydraulic lift＂ （HL）. 0 increased remarkably at 10 and 140 cm but decreased at 30 and 50 cm and slightly changed at 80 cm after rainfall, suggesting a possible ＂hydraulic descent＂ （HD）. However, no direct evidence was observed in the negative flow of lateral roots, supporting HR （including HL and HD） of T. ramosissima. The HR pathway unlikely occurred via lateral roots; instead, HR possibly occurred through adventitious roots with a diameter of 2-5 mm and a length of 60-100 cm. HR at depths of 20-60 cm ranged from 0.01-1.77 mm/d with an average of 0.43 mm/d, which accounted for an average of 22% of the estimated seasonal total water depletion at 0-160 cm during the growing season. The climate factors, particularly vapor pressure deficit and soil water potential gradient, accounted for at least 33% and 45% of HR variations with depths and years, respectively. In summary, T. ramosissima can be added to the wide list of existing species involved in HR. High levels of HR may represent a considerable fraction of daily soil water depletion and substantially improve plant water status. HR could vary tremendously in terms of years and depths, and this variation could be attributed to climate factors and soil water potential gradient.
基金financially supported by the Leading Project of the Institute of Soil Science, Chinese Academy of Sciences (ISSASIP1655)Jiangsu Municipal Natural Science Foundation, China (Nos. BK20141050 and BK20140723)the National Natural Science Foundation of China (Nos. 2014CB441105, 41401254, 41401347, and 41401345)
文摘Mixed contaminated brownfield sites have brought serious risks to human health and environmental safety. With the purpose of removing polycyclic aromatic hydrocarbons （PAHs） and heavy metals from a coking plant site, an innovative technology for ex-situ washing was developed in the present work. The combination of 15.0 mLL-1 soybean oil and 7.5 g L-1 tea saponin proved an effective method to extract co-pollutants from soil. After two consecutive washing cycles, the efficiency rates of removal for 3-, 4-, 5（＋6）-ring, and total PAHs, Cd, and Ni were approximately 98.2%, 96.4%, 92.3%, 96.3%, 94.1%, and 89.4%, respectively. Meanwhile, as evaluated by Tenax extraction method and metal stability indices, the residual PAHs and heavy metals after consecutive washing mainly existed in the form with extremely low bioaccessibility in the soil. Thus, in the soil after two washing cycles, there appeared limited environmental transfer risk of co-pollutants. Moreover, a subsequent precipitation method with alkaline solution and PAH- degrading strain Sphingobium sp. PHE9 inoculation effectively removed 84.6%-100% of Cd, 82.5%-91.7% of Ni, and 92.6%-98.4% of PAHs from the first and second washing solvents. The recovered solvents also exhibited a high recycling effectiveness. Therefore, the combined cleanup strategy proposed in this study proved environmentally friendly, which also played a major role in risk assessment and marlagement in mixed polluted sites.
基金supported financially by the Natural Science Foundation of Heilongjiang Province of China(LH2020C032)the Fundamental Research Funds for the Central Universities(No.2572018BA10)。
文摘Atmospheric deposition(dry and wet deposition)is one of the primary sources of chemical inputs to terrestrial ecosystems and replenishes the nutrient pool in forest ecosystems.Precipitation often acts as a primary transporting agent and solvent;thus,nutrient cycles in forests are closely linked to hydrological processes.We collected precipitation data during a growing season to explore variations in nutrient cycling and nutrient balances in the rainfall redistribution process(wet deposition)in a larch plantation in northeast China.We measured nutrient(NO_(3)^(-),PO_(4)^(3−),Cl^(−),K,Ca,Na,and Mg)inputs via bulk precipitation,throughfall and stemfl ow,and used a canopy budget model to estimate nutrient fl uxes via canopy exchange.Our results suggest that the average concentrations of the base cation(K,Ca,Na,and Mg)showed the following order:stemfl ow>throughfall>bulk precipitation.Throughfall and stemfl ow chemistry dramatically fl uctuated over the growing season when net fl uxes(throughfall+stemfl ow—bulk precipitation)of NO−3,PO3−4,SO2−4,Cl−,K,Ca,Na,and Mg were−6.676 kg·ha^(-1),−1.094 kg·ha^(-1),−2.371 kg·ha^(-1),1.975 kg·ha^(-1),0.470 kg·ha^(-1),−5.202 kg·ha^(-1),−0.336 kg·ha^(-1),and 1.397 kg·ha^(-1),respectively.These results suggest that NO−3,PO3−4,SO2−4,Ca,and Na were retained,while Cl−,K,and Mg were washed off by throughfall and stemfl ow.
基金supported by the Knowledge Innovation Program of the Chinese Academy of Sciences (No.KSCX2-YW-N-003)the National Basic Research Program of China (No.2005CB121103)the National Natural Science Foundation ofChina (No.50879067).
文摘Soil infiltration and redistribution are important processes in field water cycle, and it is necessary to develop a simple model to describe the processes. In this study, an algebraic solution for one-dimensional water infiltration and redistribution without evaporation in unsaturated soil was developed based on Richards equation. The algebraic solution had three parameters, namely, the saturated water conductivity, the comprehensive shape coefficient of the soil water content distribution, and the soil suction allocation coefficient. To analyze the physical features of these parameters, a relationship between the Green-Ampt model and the algebraic solution was established. The three parameters were estimated based on experimental observations, whereas the soil water content and the water infiltration duration were calculated using the algebraic solution. The calculated soil water content and infiltration duration were compared with the experimental observations, and the results indicated that the algebraic solution accurately described the unsaturated soil water flow processes.
