Tin oxides(SnO_(2))have been widely utilized in electronics,nanolithography,and catalysis.As the atomically precise models of SnO_(2),tin-oxo clusters(TOCs)not only provide opportunities for mechanism studies,but they...Tin oxides(SnO_(2))have been widely utilized in electronics,nanolithography,and catalysis.As the atomically precise models of SnO_(2),tin-oxo clusters(TOCs)not only provide opportunities for mechanism studies,but they also extend potential applications through structural modulation.However,to date,most of the reported TOCs belong to alkyl organotin complexes,which are usually toxic to the human body and the active sites are difficult to expose for catalysis.展开更多
Objective To investigate therapeutic method f or old rupture of cross ligament and c ollateral ligament of the knee.Method Reduce and fix the tibia migrated to a nterior and posterior anatomically with three sets of C...Objective To investigate therapeutic method f or old rupture of cross ligament and c ollateral ligament of the knee.Method Reduce and fix the tibia migrated to a nterior and posterior anatomically with three sets of Charnley articula ted splints.Reconstruct cross liga ment and collateral ligament with the ten don of semitendinosus.Result Clinical symptoms disappeared in 15cases and normal function resumed;9cases had different degree of sympto ms after following up for 7months to t hree years and 5months.Conclusion It is an effective method to reduce tibia-femoral and patellar-femoral joints anatomically,recon struct cross and collateral ligamen ts and resume biological function.展开更多
基金supported by the National Natural Science Foundation of China(nos.91961108,21922111,and 21973094)the National Key Research and Development Program of China(no.2017YFA0206801)+1 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences(no.XDB20000000)the Natural Science Foundation of Fujian Province(no.2019J01131).
文摘Tin oxides(SnO_(2))have been widely utilized in electronics,nanolithography,and catalysis.As the atomically precise models of SnO_(2),tin-oxo clusters(TOCs)not only provide opportunities for mechanism studies,but they also extend potential applications through structural modulation.However,to date,most of the reported TOCs belong to alkyl organotin complexes,which are usually toxic to the human body and the active sites are difficult to expose for catalysis.
文摘Objective To investigate therapeutic method f or old rupture of cross ligament and c ollateral ligament of the knee.Method Reduce and fix the tibia migrated to a nterior and posterior anatomically with three sets of Charnley articula ted splints.Reconstruct cross liga ment and collateral ligament with the ten don of semitendinosus.Result Clinical symptoms disappeared in 15cases and normal function resumed;9cases had different degree of sympto ms after following up for 7months to t hree years and 5months.Conclusion It is an effective method to reduce tibia-femoral and patellar-femoral joints anatomically,recon struct cross and collateral ligamen ts and resume biological function.
