Supercritical carbon dioxide(S-CO_(2))Brayton power cycle power generation technology,has attracted more and more scholars'attention in recent years because of its advantages of high efficiency and flexibility.Com...Supercritical carbon dioxide(S-CO_(2))Brayton power cycle power generation technology,has attracted more and more scholars'attention in recent years because of its advantages of high efficiency and flexibility.Compared with conventional steam boilers,S-CO_(2) has different heat transfer characteristics,it is easy to cause the temperature of the cooling wall of the boiler to rise,which leads to higher combustion gas temperature in the furnace,higher NOX generation concentration.The adoption of flue gas recirculation has a significance impact on the combustion process of pulverized coal in the boiler,and it is the most effective ways to reduce the emission of NOX and the combustion temperature in the boiler.This paper takes 1000MW S-CO_(2) T-type coal-fired boiler as the research target to investigate the combustion and NOX generation characteristics of S-CO_(2) coal-fired boilers under flue gas recirculation condition,the influence of recirculated flue gas distribution along the furnace height on the characteristics of NOX formation and the combustion of pulverized coal.The results show that the recirculated flue gas distribution has the great impact on the concentration of NOX at the boiler outlet.When the bottom recirculation flue gas rate is gradually increased,the average temperature of the lower boiler decreases and the average temperature of the upper boiler increases slightly;The concentration of NOx at the furnace outlet increases.展开更多
A pre-reduction sintering process with flue gas recirculation(PSP_(fsg)-FGR)was developed to mitigate alkalis harm to the blast furnace and reduce the flue gas emission in the whole ironmaking process.The results indi...A pre-reduction sintering process with flue gas recirculation(PSP_(fsg)-FGR)was developed to mitigate alkalis harm to the blast furnace and reduce the flue gas emission in the whole ironmaking process.The results indicated that the pre-reduction sintering process(PSP)can effectively remove 58.02%of K and 30.68%of Na from raw mixtures and improve yield and tumbler index to 74.40%and 68.69%,respectively.Moreover,PSP was conducive to reducing NO_(x) and SO_(2)emissions and simultaneously increasing CO content in flue gas.Circulating CO-containing flue gas to sintering bed effectively recycled CO and further improved K and Na removal ratio to 74.11%and 32.92%,respectively.Microstructural analysis revealed that the pre-reduced sinter mainly consisted of magnetite,wustite and a small quantity of metallic iron,and very few silicate glass phase was also formed.This process can simultaneously realize alkali metal elements removal as well as flue gas emission reduction from the integrated ironmaking process.展开更多
In view of the situation of multi-temperature,multi-medium and multi-discharge equipment on the integrated exhaust end platform of a natural gas distributed energy station,which is compact in layout,mutual influence,c...In view of the situation of multi-temperature,multi-medium and multi-discharge equipment on the integrated exhaust end platform of a natural gas distributed energy station,which is compact in layout,mutual influence,complex aerodynamic field and complex heat and mass transfer field,the temperature field and aerodynamic field of the platform were comprehensively studied through field experiments and numerical simulation.The research results show that the high temperature flue gas discharged from the chimney is hindered by the chimney cap and returns downward.The noise reduction walls around the chimney make the top of the platform pressurized under the crosswind,as a result,the inlet air temperature of each cooling equipment is generally higher than the ambient temperature,and the cooling efficiency is extremely low.According to the numerical simulation results,the effect of hot gas recirculation is intensified by the ambient crosswind.With the increase of the ambient crosswind,the flue gases coverage expands.The influence of ambient crosswind on inlet air temperature first increases and then decreases within the range of 1–8 m/s,showing a nearly normal distribution.Secondly,this study innovatively designed a new V-shaped chimney cap,compared with the A-shaped chimney cap,the new chimney cap effectively reduces its own obstruction to the smoke and changes the flow path of the smoke.After the smoke rises for a certain distance,the smoke returns downward,which effectively reduces the temperature of the smoke and thus reduces its impact on the air inlet of the cooling equipment.On-site measurement found that the cooling efficiency of various cooling equipment has increased by an average of 27.3%compared to before the renovation,and centrifuge’s refrigeration capacity increased by 0.78 GJ/h.展开更多
The properties of circulating gas have a significant effect on sintering with flue gas recirculation,and the influence of CO in sintering process was investigated.The results show that the post-combustion of CO conduc...The properties of circulating gas have a significant effect on sintering with flue gas recirculation,and the influence of CO in sintering process was investigated.The results show that the post-combustion of CO conducts in sinter zone when flue gas passes through the sintering bed,which releases much heat and reduces the consumption of solid fuel.The ratio of coke breeze can be reduced from 5% to 4.7% with 2% CO in circulating flue gas.In addition,with the increase of CO content in circulating flue gas,the combustion efficiency of fuel is improved,and the flame front is increased slightly while still matches with the heat transfer front.These are beneficial to increasing the maximum temperature and prolonging the high temperature duration,especially in the upper layer of sintering bed.As a consequence,the productivity,vertical sintering velocity and quality of sinter are improved.展开更多
Achieving simultaneous reduction of NOx,CO and unburned hydrocarbon(UHC) emissions without compromising engine performance at part loads is the current focus of dual fuel engine research.The present work focuses on an...Achieving simultaneous reduction of NOx,CO and unburned hydrocarbon(UHC) emissions without compromising engine performance at part loads is the current focus of dual fuel engine research.The present work focuses on an experimental investigation conducted on a dual fuel(diesel-natural gas) engine to examine the simultaneous effect of inlet air pre-heating and exhaust gas recirculation(EGR) ratio on performance and emission characteristics at part loads.The use of EGR at high levels seems to be unable to improve the engine performance at part loads.However,it is shown that EGR combined with pre-heating of inlet air can slightly increase thermal efficiency,resulting in reduced levels of both unburned hydrocarbon and NOx emissions.CO and UHC emissions are reduced by 24% and 31%,respectively,The NOx emissions decrease by 21% because of the lower combustion temperature due to the much inert gas brought by EGR and decreased oxygen concentration in the cylinder.展开更多
In the condition of constant speed and light load, an experimental study of a turbocharged and intercooled diesel engine with exhaust gas recirculation （EGR） system focuses on the influence of different EGR rates on...In the condition of constant speed and light load, an experimental study of a turbocharged and intercooled diesel engine with exhaust gas recirculation （EGR） system focuses on the influence of different EGR rates on combustion process, dynamic performance, economic performance and emission performance of a diesel engine. With the increase of EGR rate, the oxygen concentration of the intake-side decreases, the fuel air equivalence ratio increases, and the maximum explosion pressure in the cylinder decreases. Meanwhile, the average temperature in the cylinder drops, the ignition delay is prolonged, the ignition timing delays, and the maximum heat release rate decreases. The increase of EGR rate makes NOx emissions decrease obviously and continue to decline. When EGR is low, the smoke rate enlarges slowly with the increase of EGR rate, and enlarges greatly at the rate higher than 43% and reaches the maximum at the rate of 57%. When EGR rate is higher than 61%, the smoke rate drops rapidly, and the content of CO and hydrocarbon （HC） increases rapidly with high EGR rate.展开更多
To meet increasingly stringent emission standards and lower the brake-specific fuel consumption(BSFC)of marine engines,a collaborative optimization study of exhaust gas recirculation(EGR)and a Miller cycle coupled tur...To meet increasingly stringent emission standards and lower the brake-specific fuel consumption(BSFC)of marine engines,a collaborative optimization study of exhaust gas recirculation(EGR)and a Miller cycle coupled turbocharging system was carried out.In this study,a one-dimensional numerical model of the EGR,Miller cycle,and adjustable two-stage turbocharged engine based on WeiChai 6170 marine diesel engine was established.The particle swarm optimization algorithm was used to achieve multi-input and multi-objective comprehensive optimization,and the effects of EGR-coupled Miller regulation and high-pressure turbine bypass regulation on NO_(x)and BSFC were investigated.The results showed that a medium EGR rate-coupled medium Miller degree was better for the comprehensive optimization of NO_(x)and BSFC.At medium EGR rate and low turbine bypass rates,NO_(x)and BSFC were relatively balanced and acceptable.Finally,an optimal steady-state control strategy under full loads was proposed.With an increase in loads,the optimized turbine bypass rate and Miller degree gradually increased.Compared with the EGRonly system,the optimal system of EGR and Miller cycle coupled turbine bypass reduced NO_(x)by 0.87 g/(kW·h)and BSFC by 17.19 g/(kW·h)at 100%load.Therefore,the EGR and Miller cycle coupled adjustable two-stage turbocharging achieves NO_(x)and BSFC optimization under full loads.展开更多
The effects of cooled external exhaust gas recirculation(EGR)on the combustion and emission performance of diesel fuel homogeneous charge compression ignition(HCCI)are studied.Homogeneous mixture is formed by injectin...The effects of cooled external exhaust gas recirculation(EGR)on the combustion and emission performance of diesel fuel homogeneous charge compression ignition(HCCI)are studied.Homogeneous mixture is formed by injecting fuel in-cylinder in the negative valve overlap(NVO)period.So,the HCCI combustion which has low NOx and smoke emission is achieved.Cooled external EGR can delay the start of combustion effectively,which is very useful for high cetane fuel(diesel)HCCI,because these fuels can easily self-ignition,which makes the start of combustion more early.External EGR can avoid the knock combustion of HCCI at high load which means that the EGR can expand the high load limit.HCCI maintains low smoke emission at various EGR rate and various load compared with conventional diesel engine because there is no fuel-rich area in cylinder.展开更多
It is of great significance for cleaner production to substitute bio-energy for fossil fuels in iron ore sintering. However, with the replacement ratio increasing, the consistency of heat front and flame front is brok...It is of great significance for cleaner production to substitute bio-energy for fossil fuels in iron ore sintering. However, with the replacement ratio increasing, the consistency of heat front and flame front is broken, and the thermal utilizing efficiency of fuel is reduced, which results in the decrease of yield and tumble index of sinter. Circulating flue gas to sintering bed as biochar replacing 40% coke, CO in flue gas can be reused so as to increase the thermal utilizing efficiency of fuels, and the consistency of two fronts is recovered for the circulating flue gas containing certain CO2, H2 O and lower O2, which contributes to increasing the maximum temperature, extending the high temperature duration time of sintering bed, and results in improving the output and quality of sinter. In the condition of circulating 40% flue gas, the sintering with biomass fuels is strengthened, and the sintering indexes with biomass fuel replacing 40% coke breeze are comparative to those of using coke breeze completely.展开更多
This paper presents a nonlinear observer-based control design approach for gasoline engines equipped with exhaust gas recirculation (EGR) system. A mean value engine model is designed for control which includes both t...This paper presents a nonlinear observer-based control design approach for gasoline engines equipped with exhaust gas recirculation (EGR) system. A mean value engine model is designed for control which includes both the in take manifold and exhaust manifold dynamic focused on gas mass flows. Then, the nonlinear feedback controller based on the developed model is designed for the state tracking control, and the stability of the close loop system is guaranteed by a constructed Lyapunov function. Since the exhaust manifold pressure is usually unmeasurable in the production engines, a nonlinear observer-based feedback controller is proposed by using standard sensors equipped on the engine, and the asymptotic stability of the both observer dynamic system and control dynamic system are guaranteed with Lyapunov design assisted by the detail analysis of the model. The experimental validations show that the observer-based nonlinear feedback controller is able to regulate the in take pressure and exhaust pressure state to the desired values during both the steady-state and transient conditions quickly by only using the standard sensors.展开更多
Oxygen fuels have broad application prospects and great potential for realizing efficient and clean combustion,and hence this study applies diesel/n-butanol blends to explore the influence of split-injection strategy ...Oxygen fuels have broad application prospects and great potential for realizing efficient and clean combustion,and hence this study applies diesel/n-butanol blends to explore the influence of split-injection strategy on combustion and emission characteristics.Simultaneously,changing the way of exhaust gas recirculation(EGR)gas introduction forms uneven in-cylinder components distribution,and utilizing EGR stratification optimizes the combustion process and allows better emission results.The results show that the split-injection strategy can reduce the NO_(x)emissions and keep smoke opacity low compared with the single injection,but the rise in accumulation mode particles is noticeable.NO_(x)emissions show an upward trend as the injection interval expands,while soot emissions are significantly reduced.The increase in pre-injection proportion causes the apparent low-temperature heat release,and the two-stage heat release can be observed during the process of main combustion heat release.More pre-injection mass makes NO_(x)gradually increase,but smoke opacity reaches the lowest point at 15%pre-injection proportion.EGR stratification can optimize the emission results under the split injection strategy,especially the considerable suppression of accumulation mode particulate emissions.Above all,fuel stratification coupled with EGR stratification is beneficial for further realizing the in-cylinder purification of pollutants.展开更多
Effects of exhaust gas recirculation （EGR） on homogeneous charge combustion of n-heptane was studied through simulation and experiment. Experiments were carried out in a single cylinder, four-stroke, air cooled engi...Effects of exhaust gas recirculation （EGR） on homogeneous charge combustion of n-heptane was studied through simulation and experiment. Experiments were carried out in a single cylinder, four-stroke, air cooled engine and a single cylinder, two-stroke, water cooled engine. In the four-stroke engine, experiments of the effects of EGR were examined using heated N2 addition as a surrogate for external EGR and modifying engine to increase internal EGR. The ignition timing was sensitive to EGR due to thermal and chemical effects. EGR or extra air is a key factor in eliminating knock during mid-load conditions. For higher load operation the only way to avoid knock is to control reaction timing through the use of spark ignition. Experimental and modeling results from the two-stroke engine show that auto-ignition can be avoided by increasing the engine speed. The two-stroke engine experiments indicate that high levels of internal EGR can enable spark ignition at lean conditions. At higher load conditions, increasing the engine speed is an effective method to control transition from homogeneous charge compression ignition （HCCI） operation to non-HCCI operation and successful spark ignition of a highly dilute mixture can avoid serious knock.展开更多
Because of the low temperature, large waste gas volume, high pollutant content, and complicated compositions, waste heat recovery and emission gas treatment of sintering flue gas have always presented a challenge in t...Because of the low temperature, large waste gas volume, high pollutant content, and complicated compositions, waste heat recovery and emission gas treatment of sintering flue gas have always presented a challenge in the steel industry, and this issue has attracted widespread attention both locally and abroad. Recently, based on the first domestic pilot plant and demonstration project, Baosteel has performed a series of innovative research and development investigations on its sintering flue gas recirculating （SFGR） process,in which the system design and optimization, dioxin-related contaminant source suppression, ore matching structure optimization, wear- resistant design of cycling fans and pipelines, high-efficiency dust removal equipment, system control and stable operation strategy, flue gas mixing and switching control, circular hood sealing, oxygen content conditioning, recirculation sintering system process control, and model development have been studied, and a complete set of equipment and technology for the SFGR process has been initially developed. The investigation results suggest that the SFGR process can not only significantly reduce exhaust gas volume and pollutant emissions but also recover low-temperature waste heat and reduce the energy consumption of sintering; therefore, the overall technologies possess great value in energy savings ,pollution emission reduction, and sintering ore quality/yield improvement.展开更多
Anoxic gas recirculation system was applied to control the membrane fouling in pilot-scale 4- stage anoxic membrane bioreactor （MBR）. In the anaerobic-anoxic-anoxic-aerobic flow scheme, hydrophilic polytetrafluoroet...Anoxic gas recirculation system was applied to control the membrane fouling in pilot-scale 4- stage anoxic membrane bioreactor （MBR）. In the anaerobic-anoxic-anoxic-aerobic flow scheme, hydrophilic polytetrafluoroethylene （PTFE） membrane （0.2 μm, 7.2 m2/module） was submerged in the second anoxic zone. During 8 months operation, the average flux of the membrane was 21.3 L/（m2.hr）. Chemical cleaning of the membrane was conducted only once with sodium hydroxide and sodium hypochlorite. Dissolved oxygen （DO） concentration in the second anoxic zone was maintained with an average of 0.19 ± 0.05 mg/L. Gas chromatography analysis showed that the headspace gas in the second anoxic reactor was mainly consisted of N2 （93.0% ± 2.5%）, O2 （3.8% ± 0.6%）, and CO2 （3.0% ± 0.5%）, where the saturation DO concentration in liquid phase was 1.57 mg/L. Atmospheric 02 content （20.5% ± 0.8%） was significantly reduced in the anoxic gas. The average pH in the reactor was 7.2 ± 0.4. As a result, the recirculation of the anoxic gas was successfully applied to control the membrane fouling in the anoxic MBR.展开更多
Rich burn industrial natural gas engines offer best in class post catalyst emissions by using a non-selective catalyst reduction aftertreatment technology. However, they operate with reduced power density when compare...Rich burn industrial natural gas engines offer best in class post catalyst emissions by using a non-selective catalyst reduction aftertreatment technology. However, they operate with reduced power density when compared to lean burn engines. Dedicated exhaust gas recirculation (EGR) offers a possible pathway for rich burn engines to use non-selective catalyst reduction aftertreatment technology without sacrificing power density. In order to achieve best in class post catalyst emissions, the precious metals and washcoat of a non-selective catalyst must be designed according to the expected exhaust composition of an engine. In this work, a rich burn industrial natural gas engine operating with dedicated EGR was paired with a commercially available non-selective catalyst. At rated brake mean effective pressure (BMEP) the air-fuel ratio was swept between rich and lean conditions to compare the catalyst reduction efficiency and post catalyst emissions of rich burn and dedicated EGR combustion. It was found that due to low oxides of nitrogen (NO<sub>x</sub>) emissions across the entire air-fuel ratio range, dedicated EGR offers a much larger range of air-fuel ratios where low regulated emissions can be met. Low engine out NO<sub>x</sub> also points towards a possibility of using an oxidation catalyst rather than a non-selective catalyst for dedicated EGR applications. The location of the NO<sub>x</sub>-CO tradeoff was shifted to more rich conditions using dedicated EGR.展开更多
As the world shift towards sustainable energy solutions,solid oxide fuel cells(SOFCs)using non-carbon fuels like ammonia and hydrogen emerge as promising pathways to produce clean energy and enhance conversion efficie...As the world shift towards sustainable energy solutions,solid oxide fuel cells(SOFCs)using non-carbon fuels like ammonia and hydrogen emerge as promising pathways to produce clean energy and enhance conversion efficiency.However,current implementations encounter challenges such as nitriding effects from direct ammonia injection to the stack,overestimated benefits of anode off-gas(AOG)recirculation,and a sole focus on electrical efficiency that overlooks the thermal advantages of SOFCs.This study addresses these gaps through a comprehensive multi-objective optimization of SOFC systems fueled by ammonia and hydrogen,assessing their efficiency,fuel utilization,and heat exergy.The research translates material phenomena into mathematical constraints and quantifies the effects of control variables through systematic parameter variation.Results indicate that ammonia-fueled SOFC systems slightly outperform hydrogen,achieving an electrical efficiency of about 65% compared to 62% for hydrogen systems,although hydrogen demonstrates superior fuel utilization and exergy efficiency.Optimal AOG recirculation and NH3cracking fraction that do not compromise stack lifetime and stay in the safe operating zone of nitriding are identified.It also challenges the assumptions that a higher AOG recirculation can benefit performance,suggesting that more extensive AOG recirculation might not always enhance it.Soft sensors are provided to predict system’s performance and enable proactive adjustments to facilitate industrial applications where some parameters,such as high-temperature stack’s pressure drop,are costly or difficult to measure.This study significantly advances the practical deployment of SOFC technologies,enhancing their feasibility for sustainable energy development.展开更多
The EGR (exhaust gas recirculation) technique can greatly reduce the NOx emission of diesel engines, especially when an EGR cooler is employed. Numerical simulations are applied to study the flow field and temperature...The EGR (exhaust gas recirculation) technique can greatly reduce the NOx emission of diesel engines, especially when an EGR cooler is employed. Numerical simulations are applied to study the flow field and temperature distributions inside the EGR cooler. Three different models of EGR cooler are investigated, among which model A is a traditional one, and models B and C are improved by adding a helical baffle in the cooling area. In models B and C the entry directions of cooling water are different, which mostly influences the flow resistance. The results show that the improved structures not only lengthen the flow path of the cooling water, but also enhance the heat exchange rate between the cool and hot media. In conclusion we suggest that the improved structures are more powerful than the traditional one.展开更多
Knock in spark-ignition(SI)engines severely limits engine performance and thermal efficiency.The researches on knock of downsized SI engine have mainly focused on structural design,performance optimization and advance...Knock in spark-ignition(SI)engines severely limits engine performance and thermal efficiency.The researches on knock of downsized SI engine have mainly focused on structural design,performance optimization and advanced combustion modes,however there is little for simulation study on the effect of cooled exhaust gas recirculation(EGR)combined with downsizing technologies on SI engine performance.On the basis of mean pressure and oscillating pressure during combustion process,the effect of different levels of cooled EGR ratio,supercharging and compression ratio on engine dynamic and knock characteristic is researched with three-dimensional KIVA-3V program coupled with pressure wave equation.The cylinder pressure,combustion temperature,ignition delay timing,combustion duration,maximum mean pressure,and maximum oscillating pressure at different initial conditions are discussed and analyzed to investigate potential approaches to inhibiting engine knock while improving power output.The calculation results of the effect of just cooled EGR on knock characteristic show that appropriate levels of cooled EGR ratio can effectively suppress cylinder high-frequency pressure oscillations without obvious decrease in mean pressure.Analysis of the synergistic effect of cooled EGR,supercharging and compression ratio on knock characteristic indicates that under the condition of high supercharging and compression ratio,several times more cooled EGR ratio than that under the original condition is necessarily utilized to suppress knock occurrence effectively.The proposed method of synergistic effect of cooled EGR and downsizing technologies on knock characteristic,analyzed from the aspects of mean pressure and oscillating pressure,is an effective way to study downsized SI engine knock and provides knock inhibition approaches in practical engineering.展开更多
The influence of expansion joints on the welding residual stress at the tube-plate junction of an exhaust gas recirculation(EGR)cooler was studied by numerical simulation method.The simulation results show that the ex...The influence of expansion joints on the welding residual stress at the tube-plate junction of an exhaust gas recirculation(EGR)cooler was studied by numerical simulation method.The simulation results show that the expansion joints set on the housing of the EGR cooler mainly for the sake of protecting the tube-plate joints from bearing additional heating stress can also reduce the welding residual tensile stress.The expansion joints set on the EGR cooler can mitigate the tensile force acting on the edges of the main plates through its elastic extension,and thus reduce the magnitude of welding residual tensile stress at the tube-plate junction.展开更多
A turbocharged diesel engine model was built with the GT-Power software,and experimentally verified.Then two different control variables for the control of the variable geometry turbocharger（VGT）were described,and t...A turbocharged diesel engine model was built with the GT-Power software,and experimentally verified.Then two different control variables for the control of the variable geometry turbocharger（VGT）were described,and their distinct effects on engine performance,i.e.NOxand soot emissions and fuel consumption,were simulated and compared on the basis of this model.The results showed that NOxemissions decreased obviously with the increase of exhaust gas recirculation（EGR）rate at constant boost pressure condition,but soot emissions and fuel consumption considerably increased.It was a good way to reduce NOxemissions without increasing fuel consumption and soot emissions when VGT was controlled to maintain the excess oxygen ratio unchanged as EGR rate increases.展开更多
基金This paper is supported by the National Key R&D Program of China(2017YFB0601805).
文摘Supercritical carbon dioxide(S-CO_(2))Brayton power cycle power generation technology,has attracted more and more scholars'attention in recent years because of its advantages of high efficiency and flexibility.Compared with conventional steam boilers,S-CO_(2) has different heat transfer characteristics,it is easy to cause the temperature of the cooling wall of the boiler to rise,which leads to higher combustion gas temperature in the furnace,higher NOX generation concentration.The adoption of flue gas recirculation has a significance impact on the combustion process of pulverized coal in the boiler,and it is the most effective ways to reduce the emission of NOX and the combustion temperature in the boiler.This paper takes 1000MW S-CO_(2) T-type coal-fired boiler as the research target to investigate the combustion and NOX generation characteristics of S-CO_(2) coal-fired boilers under flue gas recirculation condition,the influence of recirculated flue gas distribution along the furnace height on the characteristics of NOX formation and the combustion of pulverized coal.The results show that the recirculated flue gas distribution has the great impact on the concentration of NOX at the boiler outlet.When the bottom recirculation flue gas rate is gradually increased,the average temperature of the lower boiler decreases and the average temperature of the upper boiler increases slightly;The concentration of NOx at the furnace outlet increases.
基金Project(52274290)supported by the National Natural Science Foundation of ChinaProject(72088101)supported by the Basic Science Center Project for National Natural Science Foundation of China。
文摘A pre-reduction sintering process with flue gas recirculation(PSP_(fsg)-FGR)was developed to mitigate alkalis harm to the blast furnace and reduce the flue gas emission in the whole ironmaking process.The results indicated that the pre-reduction sintering process(PSP)can effectively remove 58.02%of K and 30.68%of Na from raw mixtures and improve yield and tumbler index to 74.40%and 68.69%,respectively.Moreover,PSP was conducive to reducing NO_(x) and SO_(2)emissions and simultaneously increasing CO content in flue gas.Circulating CO-containing flue gas to sintering bed effectively recycled CO and further improved K and Na removal ratio to 74.11%and 32.92%,respectively.Microstructural analysis revealed that the pre-reduced sinter mainly consisted of magnetite,wustite and a small quantity of metallic iron,and very few silicate glass phase was also formed.This process can simultaneously realize alkali metal elements removal as well as flue gas emission reduction from the integrated ironmaking process.
基金support from the Shandong Provincial Science and Technology SMEs Innovation Capacity Improvement Project(2023TSGC0087)the Shandong Natural Science Foundation(Grant No.ZR2022ME008)China Postdoctoral Science Foundation(2023M732102).
文摘In view of the situation of multi-temperature,multi-medium and multi-discharge equipment on the integrated exhaust end platform of a natural gas distributed energy station,which is compact in layout,mutual influence,complex aerodynamic field and complex heat and mass transfer field,the temperature field and aerodynamic field of the platform were comprehensively studied through field experiments and numerical simulation.The research results show that the high temperature flue gas discharged from the chimney is hindered by the chimney cap and returns downward.The noise reduction walls around the chimney make the top of the platform pressurized under the crosswind,as a result,the inlet air temperature of each cooling equipment is generally higher than the ambient temperature,and the cooling efficiency is extremely low.According to the numerical simulation results,the effect of hot gas recirculation is intensified by the ambient crosswind.With the increase of the ambient crosswind,the flue gases coverage expands.The influence of ambient crosswind on inlet air temperature first increases and then decreases within the range of 1–8 m/s,showing a nearly normal distribution.Secondly,this study innovatively designed a new V-shaped chimney cap,compared with the A-shaped chimney cap,the new chimney cap effectively reduces its own obstruction to the smoke and changes the flow path of the smoke.After the smoke rises for a certain distance,the smoke returns downward,which effectively reduces the temperature of the smoke and thus reduces its impact on the air inlet of the cooling equipment.On-site measurement found that the cooling efficiency of various cooling equipment has increased by an average of 27.3%compared to before the renovation,and centrifuge’s refrigeration capacity increased by 0.78 GJ/h.
基金Projects(51174253,51304245)supported by the National Natural Science Foundation of ChinaProject(2013bjjxj015)supported by the Outstanding and Creative Doctor Scholarship of Central South University,ChinaProject supported by the Hunan Provincial Innovation Foundation for Postgraduate,China
文摘The properties of circulating gas have a significant effect on sintering with flue gas recirculation,and the influence of CO in sintering process was investigated.The results show that the post-combustion of CO conducts in sinter zone when flue gas passes through the sintering bed,which releases much heat and reduces the consumption of solid fuel.The ratio of coke breeze can be reduced from 5% to 4.7% with 2% CO in circulating flue gas.In addition,with the increase of CO content in circulating flue gas,the combustion efficiency of fuel is improved,and the flame front is increased slightly while still matches with the heat transfer front.These are beneficial to increasing the maximum temperature and prolonging the high temperature duration,especially in the upper layer of sintering bed.As a consequence,the productivity,vertical sintering velocity and quality of sinter are improved.
文摘Achieving simultaneous reduction of NOx,CO and unburned hydrocarbon(UHC) emissions without compromising engine performance at part loads is the current focus of dual fuel engine research.The present work focuses on an experimental investigation conducted on a dual fuel(diesel-natural gas) engine to examine the simultaneous effect of inlet air pre-heating and exhaust gas recirculation(EGR) ratio on performance and emission characteristics at part loads.The use of EGR at high levels seems to be unable to improve the engine performance at part loads.However,it is shown that EGR combined with pre-heating of inlet air can slightly increase thermal efficiency,resulting in reduced levels of both unburned hydrocarbon and NOx emissions.CO and UHC emissions are reduced by 24% and 31%,respectively,The NOx emissions decrease by 21% because of the lower combustion temperature due to the much inert gas brought by EGR and decreased oxygen concentration in the cylinder.
基金Supported by the Major Plan Projects of Science and Technology of Jiangxi Provincial Department of Education(GJJ151145)the Youth Science Fund Project Science and Technology of Jiangxi Provincial Department of Science and Technology(20114BAB216002)the Plan Projects of Science and Technology of Jiangxi Provincial Department of Science and Technology(2016BBE50074)
文摘In the condition of constant speed and light load, an experimental study of a turbocharged and intercooled diesel engine with exhaust gas recirculation （EGR） system focuses on the influence of different EGR rates on combustion process, dynamic performance, economic performance and emission performance of a diesel engine. With the increase of EGR rate, the oxygen concentration of the intake-side decreases, the fuel air equivalence ratio increases, and the maximum explosion pressure in the cylinder decreases. Meanwhile, the average temperature in the cylinder drops, the ignition delay is prolonged, the ignition timing delays, and the maximum heat release rate decreases. The increase of EGR rate makes NOx emissions decrease obviously and continue to decline. When EGR is low, the smoke rate enlarges slowly with the increase of EGR rate, and enlarges greatly at the rate higher than 43% and reaches the maximum at the rate of 57%. When EGR rate is higher than 61%, the smoke rate drops rapidly, and the content of CO and hydrocarbon （HC） increases rapidly with high EGR rate.
基金Project(K16011)supported by the Marine Low-speed Engine Project-Phase I,China。
文摘To meet increasingly stringent emission standards and lower the brake-specific fuel consumption(BSFC)of marine engines,a collaborative optimization study of exhaust gas recirculation(EGR)and a Miller cycle coupled turbocharging system was carried out.In this study,a one-dimensional numerical model of the EGR,Miller cycle,and adjustable two-stage turbocharged engine based on WeiChai 6170 marine diesel engine was established.The particle swarm optimization algorithm was used to achieve multi-input and multi-objective comprehensive optimization,and the effects of EGR-coupled Miller regulation and high-pressure turbine bypass regulation on NO_(x)and BSFC were investigated.The results showed that a medium EGR rate-coupled medium Miller degree was better for the comprehensive optimization of NO_(x)and BSFC.At medium EGR rate and low turbine bypass rates,NO_(x)and BSFC were relatively balanced and acceptable.Finally,an optimal steady-state control strategy under full loads was proposed.With an increase in loads,the optimized turbine bypass rate and Miller degree gradually increased.Compared with the EGRonly system,the optimal system of EGR and Miller cycle coupled turbine bypass reduced NO_(x)by 0.87 g/(kW·h)and BSFC by 17.19 g/(kW·h)at 100%load.Therefore,the EGR and Miller cycle coupled adjustable two-stage turbocharging achieves NO_(x)and BSFC optimization under full loads.
基金supported by National Basic Research Program of China(973Program,No.2001CB209205)National Natural Science Foundation ofChina(No.50406016)
文摘The effects of cooled external exhaust gas recirculation(EGR)on the combustion and emission performance of diesel fuel homogeneous charge compression ignition(HCCI)are studied.Homogeneous mixture is formed by injecting fuel in-cylinder in the negative valve overlap(NVO)period.So,the HCCI combustion which has low NOx and smoke emission is achieved.Cooled external EGR can delay the start of combustion effectively,which is very useful for high cetane fuel(diesel)HCCI,because these fuels can easily self-ignition,which makes the start of combustion more early.External EGR can avoid the knock combustion of HCCI at high load which means that the EGR can expand the high load limit.HCCI maintains low smoke emission at various EGR rate and various load compared with conventional diesel engine because there is no fuel-rich area in cylinder.
基金Projects(51174253,51304245) supported by National Natural Science Foundation of China
文摘It is of great significance for cleaner production to substitute bio-energy for fossil fuels in iron ore sintering. However, with the replacement ratio increasing, the consistency of heat front and flame front is broken, and the thermal utilizing efficiency of fuel is reduced, which results in the decrease of yield and tumble index of sinter. Circulating flue gas to sintering bed as biochar replacing 40% coke, CO in flue gas can be reused so as to increase the thermal utilizing efficiency of fuels, and the consistency of two fronts is recovered for the circulating flue gas containing certain CO2, H2 O and lower O2, which contributes to increasing the maximum temperature, extending the high temperature duration time of sintering bed, and results in improving the output and quality of sinter. In the condition of circulating 40% flue gas, the sintering with biomass fuels is strengthened, and the sintering indexes with biomass fuel replacing 40% coke breeze are comparative to those of using coke breeze completely.
文摘This paper presents a nonlinear observer-based control design approach for gasoline engines equipped with exhaust gas recirculation (EGR) system. A mean value engine model is designed for control which includes both the in take manifold and exhaust manifold dynamic focused on gas mass flows. Then, the nonlinear feedback controller based on the developed model is designed for the state tracking control, and the stability of the close loop system is guaranteed by a constructed Lyapunov function. Since the exhaust manifold pressure is usually unmeasurable in the production engines, a nonlinear observer-based feedback controller is proposed by using standard sensors equipped on the engine, and the asymptotic stability of the both observer dynamic system and control dynamic system are guaranteed with Lyapunov design assisted by the detail analysis of the model. The experimental validations show that the observer-based nonlinear feedback controller is able to regulate the in take pressure and exhaust pressure state to the desired values during both the steady-state and transient conditions quickly by only using the standard sensors.
基金Projects(51476069,51676084)supported by the National Natural Science Foundation of ChinaProject(2019C058-3)supported by the Jilin Provincial Industrial Innovation Special Guidance Fund Project,China+1 种基金Project(20180101059JC)supported by the Jilin Provincial Science and Technology Development Plan Project,ChinaProject(2020C025-2)supported by the Jilin Provincial Specific Project of Industrial Technology Research&Development,China。
文摘Oxygen fuels have broad application prospects and great potential for realizing efficient and clean combustion,and hence this study applies diesel/n-butanol blends to explore the influence of split-injection strategy on combustion and emission characteristics.Simultaneously,changing the way of exhaust gas recirculation(EGR)gas introduction forms uneven in-cylinder components distribution,and utilizing EGR stratification optimizes the combustion process and allows better emission results.The results show that the split-injection strategy can reduce the NO_(x)emissions and keep smoke opacity low compared with the single injection,but the rise in accumulation mode particles is noticeable.NO_(x)emissions show an upward trend as the injection interval expands,while soot emissions are significantly reduced.The increase in pre-injection proportion causes the apparent low-temperature heat release,and the two-stage heat release can be observed during the process of main combustion heat release.More pre-injection mass makes NO_(x)gradually increase,but smoke opacity reaches the lowest point at 15%pre-injection proportion.EGR stratification can optimize the emission results under the split injection strategy,especially the considerable suppression of accumulation mode particulate emissions.Above all,fuel stratification coupled with EGR stratification is beneficial for further realizing the in-cylinder purification of pollutants.
基金Supported by National Natural Science Foundation and GM Fund (No.50322261).
文摘Effects of exhaust gas recirculation （EGR） on homogeneous charge combustion of n-heptane was studied through simulation and experiment. Experiments were carried out in a single cylinder, four-stroke, air cooled engine and a single cylinder, two-stroke, water cooled engine. In the four-stroke engine, experiments of the effects of EGR were examined using heated N2 addition as a surrogate for external EGR and modifying engine to increase internal EGR. The ignition timing was sensitive to EGR due to thermal and chemical effects. EGR or extra air is a key factor in eliminating knock during mid-load conditions. For higher load operation the only way to avoid knock is to control reaction timing through the use of spark ignition. Experimental and modeling results from the two-stroke engine show that auto-ignition can be avoided by increasing the engine speed. The two-stroke engine experiments indicate that high levels of internal EGR can enable spark ignition at lean conditions. At higher load conditions, increasing the engine speed is an effective method to control transition from homogeneous charge compression ignition （HCCI） operation to non-HCCI operation and successful spark ignition of a highly dilute mixture can avoid serious knock.
文摘Because of the low temperature, large waste gas volume, high pollutant content, and complicated compositions, waste heat recovery and emission gas treatment of sintering flue gas have always presented a challenge in the steel industry, and this issue has attracted widespread attention both locally and abroad. Recently, based on the first domestic pilot plant and demonstration project, Baosteel has performed a series of innovative research and development investigations on its sintering flue gas recirculating （SFGR） process,in which the system design and optimization, dioxin-related contaminant source suppression, ore matching structure optimization, wear- resistant design of cycling fans and pipelines, high-efficiency dust removal equipment, system control and stable operation strategy, flue gas mixing and switching control, circular hood sealing, oxygen content conditioning, recirculation sintering system process control, and model development have been studied, and a complete set of equipment and technology for the SFGR process has been initially developed. The investigation results suggest that the SFGR process can not only significantly reduce exhaust gas volume and pollutant emissions but also recover low-temperature waste heat and reduce the energy consumption of sintering; therefore, the overall technologies possess great value in energy savings ,pollution emission reduction, and sintering ore quality/yield improvement.
文摘Anoxic gas recirculation system was applied to control the membrane fouling in pilot-scale 4- stage anoxic membrane bioreactor （MBR）. In the anaerobic-anoxic-anoxic-aerobic flow scheme, hydrophilic polytetrafluoroethylene （PTFE） membrane （0.2 μm, 7.2 m2/module） was submerged in the second anoxic zone. During 8 months operation, the average flux of the membrane was 21.3 L/（m2.hr）. Chemical cleaning of the membrane was conducted only once with sodium hydroxide and sodium hypochlorite. Dissolved oxygen （DO） concentration in the second anoxic zone was maintained with an average of 0.19 ± 0.05 mg/L. Gas chromatography analysis showed that the headspace gas in the second anoxic reactor was mainly consisted of N2 （93.0% ± 2.5%）, O2 （3.8% ± 0.6%）, and CO2 （3.0% ± 0.5%）, where the saturation DO concentration in liquid phase was 1.57 mg/L. Atmospheric 02 content （20.5% ± 0.8%） was significantly reduced in the anoxic gas. The average pH in the reactor was 7.2 ± 0.4. As a result, the recirculation of the anoxic gas was successfully applied to control the membrane fouling in the anoxic MBR.
文摘Rich burn industrial natural gas engines offer best in class post catalyst emissions by using a non-selective catalyst reduction aftertreatment technology. However, they operate with reduced power density when compared to lean burn engines. Dedicated exhaust gas recirculation (EGR) offers a possible pathway for rich burn engines to use non-selective catalyst reduction aftertreatment technology without sacrificing power density. In order to achieve best in class post catalyst emissions, the precious metals and washcoat of a non-selective catalyst must be designed according to the expected exhaust composition of an engine. In this work, a rich burn industrial natural gas engine operating with dedicated EGR was paired with a commercially available non-selective catalyst. At rated brake mean effective pressure (BMEP) the air-fuel ratio was swept between rich and lean conditions to compare the catalyst reduction efficiency and post catalyst emissions of rich burn and dedicated EGR combustion. It was found that due to low oxides of nitrogen (NO<sub>x</sub>) emissions across the entire air-fuel ratio range, dedicated EGR offers a much larger range of air-fuel ratios where low regulated emissions can be met. Low engine out NO<sub>x</sub> also points towards a possibility of using an oxidation catalyst rather than a non-selective catalyst for dedicated EGR applications. The location of the NO<sub>x</sub>-CO tradeoff was shifted to more rich conditions using dedicated EGR.
基金supported by National Key Research and Development Program of China(2024YFE0207200)financial support from the project AMON。
文摘As the world shift towards sustainable energy solutions,solid oxide fuel cells(SOFCs)using non-carbon fuels like ammonia and hydrogen emerge as promising pathways to produce clean energy and enhance conversion efficiency.However,current implementations encounter challenges such as nitriding effects from direct ammonia injection to the stack,overestimated benefits of anode off-gas(AOG)recirculation,and a sole focus on electrical efficiency that overlooks the thermal advantages of SOFCs.This study addresses these gaps through a comprehensive multi-objective optimization of SOFC systems fueled by ammonia and hydrogen,assessing their efficiency,fuel utilization,and heat exergy.The research translates material phenomena into mathematical constraints and quantifies the effects of control variables through systematic parameter variation.Results indicate that ammonia-fueled SOFC systems slightly outperform hydrogen,achieving an electrical efficiency of about 65% compared to 62% for hydrogen systems,although hydrogen demonstrates superior fuel utilization and exergy efficiency.Optimal AOG recirculation and NH3cracking fraction that do not compromise stack lifetime and stay in the safe operating zone of nitriding are identified.It also challenges the assumptions that a higher AOG recirculation can benefit performance,suggesting that more extensive AOG recirculation might not always enhance it.Soft sensors are provided to predict system’s performance and enable proactive adjustments to facilitate industrial applications where some parameters,such as high-temperature stack’s pressure drop,are costly or difficult to measure.This study significantly advances the practical deployment of SOFC technologies,enhancing their feasibility for sustainable energy development.
文摘The EGR (exhaust gas recirculation) technique can greatly reduce the NOx emission of diesel engines, especially when an EGR cooler is employed. Numerical simulations are applied to study the flow field and temperature distributions inside the EGR cooler. Three different models of EGR cooler are investigated, among which model A is a traditional one, and models B and C are improved by adding a helical baffle in the cooling area. In models B and C the entry directions of cooling water are different, which mostly influences the flow resistance. The results show that the improved structures not only lengthen the flow path of the cooling water, but also enhance the heat exchange rate between the cool and hot media. In conclusion we suggest that the improved structures are more powerful than the traditional one.
基金supported by National Natural Science Foundation of China(Grant No.51176138)Tianjin Municipal Natural Science Foundation of China(Grant No.12TJZDTJ28800)
文摘Knock in spark-ignition(SI)engines severely limits engine performance and thermal efficiency.The researches on knock of downsized SI engine have mainly focused on structural design,performance optimization and advanced combustion modes,however there is little for simulation study on the effect of cooled exhaust gas recirculation(EGR)combined with downsizing technologies on SI engine performance.On the basis of mean pressure and oscillating pressure during combustion process,the effect of different levels of cooled EGR ratio,supercharging and compression ratio on engine dynamic and knock characteristic is researched with three-dimensional KIVA-3V program coupled with pressure wave equation.The cylinder pressure,combustion temperature,ignition delay timing,combustion duration,maximum mean pressure,and maximum oscillating pressure at different initial conditions are discussed and analyzed to investigate potential approaches to inhibiting engine knock while improving power output.The calculation results of the effect of just cooled EGR on knock characteristic show that appropriate levels of cooled EGR ratio can effectively suppress cylinder high-frequency pressure oscillations without obvious decrease in mean pressure.Analysis of the synergistic effect of cooled EGR,supercharging and compression ratio on knock characteristic indicates that under the condition of high supercharging and compression ratio,several times more cooled EGR ratio than that under the original condition is necessarily utilized to suppress knock occurrence effectively.The proposed method of synergistic effect of cooled EGR and downsizing technologies on knock characteristic,analyzed from the aspects of mean pressure and oscillating pressure,is an effective way to study downsized SI engine knock and provides knock inhibition approaches in practical engineering.
基金This work was supported by the Guangdong Innovative and Entrepreneurial Research Team Program(No.2016ZT06G025)Guangdong Natural Science Foundation(NO: 2017B030306014).
文摘The influence of expansion joints on the welding residual stress at the tube-plate junction of an exhaust gas recirculation(EGR)cooler was studied by numerical simulation method.The simulation results show that the expansion joints set on the housing of the EGR cooler mainly for the sake of protecting the tube-plate joints from bearing additional heating stress can also reduce the welding residual tensile stress.The expansion joints set on the EGR cooler can mitigate the tensile force acting on the edges of the main plates through its elastic extension,and thus reduce the magnitude of welding residual tensile stress at the tube-plate junction.
基金Supported by Diesel Engine Development Program of MIIT(DEDP-1004)Natural Science Foundation of BIT(3030012211428)
文摘A turbocharged diesel engine model was built with the GT-Power software,and experimentally verified.Then two different control variables for the control of the variable geometry turbocharger（VGT）were described,and their distinct effects on engine performance,i.e.NOxand soot emissions and fuel consumption,were simulated and compared on the basis of this model.The results showed that NOxemissions decreased obviously with the increase of exhaust gas recirculation（EGR）rate at constant boost pressure condition,but soot emissions and fuel consumption considerably increased.It was a good way to reduce NOxemissions without increasing fuel consumption and soot emissions when VGT was controlled to maintain the excess oxygen ratio unchanged as EGR rate increases.
