This paper focuses on the performance analysis of flexible reactive systems. The performance analysis consists of two phases： first system modeling, second performance evalua-tion. The paper models the flexible react...This paper focuses on the performance analysis of flexible reactive systems. The performance analysis consists of two phases： first system modeling, second performance evalua-tion. The paper models the flexible reactive system by the stochas-tic statecharts method, and uses the simulation method to evalu-ate the performance. To make use of the feature of event-triggered state transitions in the statecharts, a new method of simulation is proposed based on the techniques of the discrete-event system simulation. The new method solves the problem of computer imple-mentation of stochastic events, probabilistic transition, concurrent states, paral el actions, and broadcast communication mechanism in the stochastic statecharts. An example of a flexible manufactur-ing system is presented. The simulation result of the example is consistent with the analytical result, which shows the feasibility of the proposed new simulation method.展开更多
A wind-turbine power system is often challenged by voltage instability,reactive power imbalance,and limited fault ride-through capability under grid disturbances.Doubly Fed Induction Generator based wind farms,owing t...A wind-turbine power system is often challenged by voltage instability,reactive power imbalance,and limited fault ride-through capability under grid disturbances.Doubly Fed Induction Generator based wind farms,owing to their partial coupling with the grid,are particularly vulnerable to voltage dips and excessive reactive power absorption during fault events.This study proposes an adaptive control strategy based on Model Reference Adaptive Control integrated with stator flux-oriented vector control to regulate active and reactive power of a DFIG-based wind farm connected to a standard IEEE 9-bus power system under fault conditions.The proposed control scheme is developed and validated using detailed MATLAB/Simulink modeling under normal operation,symmetrical three-phase fault conditions,and post-fault recovery scenarios.A three-phase-to-ground fault is applied at the wind farm interconnection bus for a duration of 150 ms to evaluate transient performance.Simulation results demonstrate that the adaptive controller ensures fast power tracking,effective reactive power support,and enhanced voltage recovery compared to a conventional proportional–integral controller.Quantitatively,the proposed method improves voltage recovery time by approximately 45%,reduces active power overshoot by 38%,and lowers total harmonic distortion by 52% following fault clearance.Furthermore,the adaptive controller maintains stable operation under variations in wind speed and machine parameters without requiring retuning,highlighting its robustness against system uncertainties.The results confirm that the proposed control strategy significantly enhances fault ride-through capability,power quality,and dynamic stability of grid-interfaced wind farms.These findings demonstrate the practical applicability of adaptive control techniques for improving the reliability and resilience of modern power systems with high wind energy penetration.展开更多
The reactive materials filled structure(RMFS)is a structural penetrator that replaces high explosive(HE)with reactive materials,presenting a novel self-distributed initiation,multiple deflagrations behavior during pen...The reactive materials filled structure(RMFS)is a structural penetrator that replaces high explosive(HE)with reactive materials,presenting a novel self-distributed initiation,multiple deflagrations behavior during penetrating multi-layered plates,and generating a multipeak overpressure behind the plates.Here analytical models of RMFS self-distributed energy release and equivalent deflagration are developed.The multipeak overpressure formation model based on the single deflagration overpressure expression was promoted.The impact tests of RMFS on multi-layered plates at 584 m/s,616 m/s,and819 m/s were performed to validate the analytical model.Further,the influence of a single overpressure peak and time intervals versus impact velocity is discussed.The analysis results indicate that the deflagration happened within 20.68 mm behind the plate,the initial impact velocity and plate thickness are the crucial factors that dominate the self-distributed multipeak overpressure effect.Three formation patterns of multipeak overpressure are proposed.展开更多
Hybrid commutation converters(HCCs)utilizing reverse-blocking integrated gate commutation thyristors(IGCTs)have gained significant attention due to their immunity to commutation failure.Leveraging the recovery enhance...Hybrid commutation converters(HCCs)utilizing reverse-blocking integrated gate commutation thyristors(IGCTs)have gained significant attention due to their immunity to commutation failure.Leveraging the recovery enhancement characteristics of IGCTs,HCCs demonstrate superior performance at reduced extinction angles,thereby minimizing reactive power consumption.This study presents a comprehensive investigation into reactive power control strategies for HCCs operating at small extinction angles.First,the topological configuration and commutation principle of HCC are elucidated.Subsequently,the mechanism of HCC reactive power control is analyzed,and a reactive power control strategy is proposed by combining the converter transformer taps with extinction angles.Moreover,the relationship between transformer taps and reactive power exchange under different rated extinction angles is calculated,and the theoretically rated extinction angle is proposed.Finally,to validate the proposed control strategy,a four-terminal ultra-high voltage direct current power grid incorporating HCC technology is modeled and sim-ulated using PSCAD/EMTDC.The simulation results demonstrate that the proposed strategy effectively supports AC systems by reducing reactive power absorption in HCCs,while simultaneously exhibiting enhanced reli-ability and economic efficiency.展开更多
Rubber-toughened thermoplastic materials have become ubiquitous in modern society owing to their lightweight nature and desirable combination of advantageous performances.Despite the ever-increasing demand,the develop...Rubber-toughened thermoplastic materials have become ubiquitous in modern society owing to their lightweight nature and desirable combination of advantageous performances.Despite the ever-increasing demand,the development of polymer alloys that are lightweight,high-strength,and high-toughness remains an ongoing challenge.Inspired by the unique“salami”microstructure from commercial acrylonitrile butadiene styrene copolymer(ABS)and high-impact polystyrene(HIPS),a facile approach was developed to overcome the trade-off between enhancing the toughness and rigidity of fully polymer-based alloys by virtue of elastomeric salami particles.This strategy entails pre-grafting rigid poly(lactic acid)(PLLA)chains with glycidyl methacrylate-grafted octene ethylene copolymer(POE-g-GMA)using complementary reactive groups.It can be envisaged that the PLLA grafts featuring strong incompatibility with polypropylene(PP)remain fixed in elastomer phase upon the subsequent melt compounding,facilitating the in situ formation of“hard core(PLLA)-soft shell(polyolefin elastomer,POE)”particles in polypropylene(PP)matrix.The all-polymer alloys containing elastomeric salami particles demonstrated unprecedented performance combinations,including upper notched impact strengths(56.8 kJ/m2),even higher tensile strength(36.8 MPa),and Young’s modulus(0.93 GPa)than that of the PP matrix.Furthermore,these materials are lightweight without the incorporation of reinforcing nano-fillers,which is competitive with industrial engineering plastics.It is highly anticipated that this universal and highly efficient protocol will be appropriate for arbitrary rubber toughened/reinforced systems,offering a paradigm in the design of advanced all-polymer alloys.展开更多
Bio-carbonation of reactive MgO has been regarded as a promising and eco-friendly method for construction and demolition waste(CDW)cementation in various geotechnical engineering applications.However,the beneficial ef...Bio-carbonation of reactive MgO has been regarded as a promising and eco-friendly method for construction and demolition waste(CDW)cementation in various geotechnical engineering applications.However,the beneficial effect of bio-carbonation of reactive MgO cemented CDW(BCM-samples)can be altered when exposed to wetting-drying cycles induced by extreme climate changes or groundwater fluctuations.To better understand the durability of BCM-samples and their underlying deterioration mechanisms,a series of BCM-samples was prepared to investigate their physical-mechanical performance and microstructure evolution subjected to the wetting-drying cycles.The results indicated that the wetting-drying cycles can deteriorate the BCM-samples,and their physical-mechanical behaviors change quickly at the cycle beginning and then smoothly after 2 cycles.With the increase in cycling,the apparent deterioration with efflorescence and microcrack development can be observed.The mass loss and water absorption rates increased while the dry density,compressional wave velocity,and unconfined compression strength decreased.Urea pre-hydrolysis treatment can significantly improve the durability of BCM-samples,as the more hydrated magnesia carbonates(HMCs)enhance the cementing effects.After 10 cycles,the UCS of pre-hydrolyzed samples decreased 25.4%to 4.45 MPa,while that of ordinary samples decreased 50.7%to 1.20 MPa.The deterioration of BCM-samples caused by wetting-drying cycles can be attributed to two factors.One of the main factors is the structural integrity changes caused by the rapid loss of soluble material at the initial cycling stages.Another factor is the decrease in cementation induced by the loss of brucite and HMCs at the following cycle stages.展开更多
Biochar and zero-valent iron are promising materials for the removal of trichloroethylene(TCE)from groundwater,but further research is still required on the synergistic mechanism and hydraulic performance in the perme...Biochar and zero-valent iron are promising materials for the removal of trichloroethylene(TCE)from groundwater,but further research is still required on the synergistic mechanism and hydraulic performance in the permeable reactive barriers(PRBs)with biochar-iron composites.In this work,biochar-iron composites were synthesized by two different methods,and subjected to the microscopic analysis,batch experiments and the PRB’s model tests.The results indicated that the removal rates of TCE on biochar-iron composites reached above 90%,and the optimal removal conditions were the initial pH of 6.0 and a biochar/iron mass ratio of 5:1.The removal of TCE on biochar-iron composites followed the pseudo-second-order and Freundlich models,and the maximum adsorption capacity of TCE was 25.95 mg/g.The adsorption of biochar and dechlorination of nZVI dominated the removal of TCE.Biochar significantly enhanced the dechlorination of TCE on nZVI through modifying the electrochemical characteristics to lower its corrosion potential of nZVI,promote direct electron transfer,and improve electronic transfer capability.M-5BC-1nZVI exhibited excellent hydraulic performance for maintaining an adequate permeability coefficient(10^(−6)to 10^(−5)m/s).展开更多
Vacuum-ultraviolet(VUV)radiation is high-energy UV radiation with a wavelength of 100-200 nm capable of decomposing/mineralizing hazardous emerging organic pollutants(EPs)in water through direct photolysis and/or by g...Vacuum-ultraviolet(VUV)radiation is high-energy UV radiation with a wavelength of 100-200 nm capable of decomposing/mineralizing hazardous emerging organic pollutants(EPs)in water through direct photolysis and/or by generating reactive free radicals(RFRs)during photolysis.However,due to the unsatisfactory photoelectric conversion rate,strong absorption by oxygen and water molecules,and other characteristics of VUV radiation,its application and development are hindered,leading to misconceptions regarding high energy consumption and insufficient free radical yield.The objectives of our assessment in this review are as follows:The illumination of the photochemical characteristics of VUV and the reactivity of aqueous solutions.Summarization of accurate UV dose and energy evaluation criteria.Comparison and analysis of the photochemical mechanisms and reaction kinetics of different types of EPs via VUV direct photolysis,as well as the interference origins of typical substrates in water for VUV decontamination.We found that quantities typically reported in VUV photochemical reactions of engineered systems are underreported in low-pressure mercury lamp(LPUV)photochemical reactions,especially a quantitative indicator of the species or energy that induces a chemical reaction.The absence of these quantities has made it difficult to assess the fundamental performance of VUV photolysis fully compared with that of UV-C.Some studies have sought to optimize VUV-advanced reduction processes(VUV-ARP)or VUV reactor treatment of these contaminants;however,an abundant evaluation of the reaction origins and processes between VUV-derived main RFRs and reactants(H_(2)O,O_(2),organic matter,inorganic ions,etc.)is essential,cause these scientific elements will provide the possibility to break the application gap for VUV in the field of EPs treating.Overall,the data compilation,analysis,and research recommendations provided in this review will form the basis for all photochemical reactions initiated by VUV radiation with water as the backing agent.展开更多
We are sorry for the mistakes of Affiliation,"a State Key Laboratory of Advanced Fiber Materials,Center for Advanced Low-Dimension Materials,Donghua University,Shanghai 201620,China"should be replaced by&quo...We are sorry for the mistakes of Affiliation,"a State Key Laboratory of Advanced Fiber Materials,Center for Advanced Low-Dimension Materials,Donghua University,Shanghai 201620,China"should be replaced by"a State Key Laboratory of Advanced Fiber Materials,Center for Advanced Low-Dimension Materials,College of Materials Science and Engineering,Donghua University,Shanghai 201620,China".We apologized for the inconvenience caused by this error.展开更多
Achieving high selectivity to 2,5-furandicarboxylic acid(FDCA)in the photocatalytic oxidation of 5-hydroxymethylfurfural(HMF)in aqueous solution advocates the principle of green and sustainable chemistry,but still rem...Achieving high selectivity to 2,5-furandicarboxylic acid(FDCA)in the photocatalytic oxidation of 5-hydroxymethylfurfural(HMF)in aqueous solution advocates the principle of green and sustainable chemistry,but still remains a significant challenge.Herein,manipulating the reactive oxygen species(ROS)has been realized and dramatically promotes the selective photocatalytic oxidation of HMF in aqueous solution.A high FDCAyield of 98.6% has been achieved after 3 h of visible light irradiation over the as-prepared FeO_(x)-Au/TiO_(2) catalyst,being one of the leading photocatalytic performances.Furthermore,satisfactory FDCA yields of higher than 80%could be realized even in the outdoor environment under natural sunlight irradiation,regardless of sunny or cloudy weather.A combination study including physical characterization,kinetic analysis,radical trapping experiments and density functional theory calculations unveils the rate-determining step(oxidation of hydroxyl group)and respective contributions of the generated ROS(1O_(2) and·O_(2)-)in each step of the entire reaction network.The present work would push ahead the understanding of HMF photocatalytic oxidation and contribute to the rational design of high-performance photocatalysts.展开更多
Reactive compatibilization has been widely applied to enhance the compatibility of polymer blends,thereby improving their mechanical properties.However,it generally reduces the chain mobility and regularity,often lead...Reactive compatibilization has been widely applied to enhance the compatibility of polymer blends,thereby improving their mechanical properties.However,it generally reduces the chain mobility and regularity,often leading to slower polymer crystallization.Here,we demonstrate that reactive compatibilization in poly(lactic acid)/poly(butylene adipate-co-terephthalate)(PLA/PBAT)blends unexpectedly promotes PLA matrix crystallization during injection molding,in contrast to the retarded kinetics observed in differential scanning calorimetry isothermal crystallization studies.The phase morphology,rheological behavior,and crystalline structure were systematically analyzed to elucidate markedly different crystallization kinetics under static and shear fields.The potential mechanism underlying crystallization enhancement is attributed to PBAT domain refinement and viscosity increase induced by reactive compatibilization,which,under shear flow,create favorable conditions for crystallization by enhancing PBAT fibril nucleation and retarding the relaxation of oriented PLA chains.This study offers new perspectives on the effect of reactive compatibilization on the polymer crystallization behavior.展开更多
The transient synchronization stability of grid-forming converters(GFMCs)is significantly challenged under grid voltage sags.Continuous efforts have been devoted to analyzing the GFMC transient stability,with limited ...The transient synchronization stability of grid-forming converters(GFMCs)is significantly challenged under grid voltage sags.Continuous efforts have been devoted to analyzing the GFMC transient stability,with limited attention paid to the impacts of control loop dynamics.However,the complex control dynamics,especially the interactions between the active/reactive power control loops and the current saturation process(CSP),are crucial for accurately describing the transient behavior and evaluating the stability.Thus,in this study,a new large-signal GFMC model is established,considering the reactive power control(RPC)with different kinds of controllers and the CSP simultaneously.It is revealed that GFMC does not switch to the current-limited mode immediately,and the dynamics of RPC further affect the transient behavior before the current limiting significantly.Hence,the complex control dynamics can alter the mode switching point of current saturation,thereby increasing the risk of loss of synchronization(LOS).Based on the above findings,comprehensive comparisons of typical RPC controllers are presented to facilitate practical engineering applications.A unified stability enhancement method is proposed for solving the problem of LOS.Finally,experiments validate the correctness of the analysis and the effectiveness of the proposed control strategy.展开更多
During sending-end faults in the hybrid cascaded HVDC(HC-HVDC)system,the transient voltage drop characteristics under the interaction of the AC/DC hybrid system remain unclear,and the reactive power support provided b...During sending-end faults in the hybrid cascaded HVDC(HC-HVDC)system,the transient voltage drop characteristics under the interaction of the AC/DC hybrid system remain unclear,and the reactive power support provided by the HC-HVDC to the sending-end AC system requires further investigation.To address this problem,the reactive power interaction coupling mechanism between the sending-end AC system and the HC-HVDC is revealed,and the transient voltage mathematical model considering fault severity and duration is established.Under the dynamic change of the AC system voltage,the difference between the reactive power provided only by the reactive power compensation devices and by the combined modular multilevel converters(MMC)and reactive power compensation devices is analyzed.It is concluded that using MMC to provide a proportion of reactive power enhances the reactive power support to the AC system during faults.Then,the transient voltage model considering the reactive power support of MMC is established,and the critical reactive power consumption of line commutated converter(LCC)is quantified.It is concluded that the reactive power consumption of LCC exceeding its critical value deteriorates the transient voltage.A coordinated support strategy for the sending-end AC system based on reactive power support of MMC and reactive power regulation of LCC is proposed.It can effectively address the challenge of weakened reactive power support to the AC system due to voltage drop,thereby preventing the unbalanced reactive power from deteriorating the transient voltage,and realizing active support of the tran-sient voltage.Finally,a simulation model is established on the PSCAD/EMTDC platform,and the simulation results validate the effectiveness of the proposed strategy in supporting the transient voltage,under different fault types,durations,severities,and locations.展开更多
In real industrial microgrids(MGs),the length of the primary delivery feeder to the connection point of the main substation is sometimes long.This reduces the power factor and increases reactive power absorption along...In real industrial microgrids(MGs),the length of the primary delivery feeder to the connection point of the main substation is sometimes long.This reduces the power factor and increases reactive power absorption along the primary delivery feeder from the external network.Besides,the giant induction electro-motors as the working horse of industries requires remarkable amounts of reactive power for electro-mechanical energy conversions.To reduce power losses and operating costs of the MG as well as to improve the voltage quality,this study aims at providing an insightful model for optimal placement and sizing of reactive power compensation capacitors in an industrial MG.In the presented model,the objective function considers voltage profile and network power factor improvement at the MG connection point.Also,it realizes power flow equations within which all operational security constraints are considered.Various reactive power compensation strategies including distributed group compensation,centralized compensation at the main substation,and distributed compensation along the primary delivery feeder are scrutinized.A real industrial MG,say as Urmia Petrochemical plant,is considered in numerical validations.The obtained results in each scenario are discussed in depth.As seen,the best performance is obtained when the optimal location and sizing of capacitors are simultaneously determined at the main buses of the industrial plants,at the main substation of the MG,and alongside the primary delivery feeder.In this way,74.81%improvement in power losses reduction,1.3%lower active power import from the main grid,23.5%improvement in power factor,and 37.5%improvement in network voltage deviation summation are seen in this case compared to the base case.展开更多
An optimized volt-ampere reactive(VAR)control framework is proposed for transmission-level power systems to simultaneously mitigate voltage deviations and active-power losses through coordinated control of large-scale...An optimized volt-ampere reactive(VAR)control framework is proposed for transmission-level power systems to simultaneously mitigate voltage deviations and active-power losses through coordinated control of large-scale wind/solar farms with shunt static var generators(SVGs).The model explicitly represents reactive-power regulation characteristics of doubly-fed wind turbines and PV inverters under real-time meteorological conditions,and quantifies SVG high-speed compensation capability,enabling seamless transition from localized VAR management to a globally coordinated strategy.An enhanced adaptive gain-sharing knowledge optimizer(AGSK-SD)integrates simulated annealing and diversity maintenance to autonomously tune voltage-control actions,renewable source reactive-power set-points,and SVG output.The algorithm adaptively modulates knowledge factors and ratios across search phases,performs SA-based fine-grained local exploitation,and periodically re-injects population diversity to prevent premature convergence.Comprehensive tests on IEEE 9-bus and 39-bus systems demonstrate AGSK-SD’s superiority over NSGA-II and MOPSO in hypervolume(HV),inverse generative distance(IGD),and spread metrics while maintaining acceptable computational burden.The method reduces network losses from 2.7191 to 2.15 MW(20.79%reduction)and from 15.1891 to 11.22 MW(26.16%reduction)in the 9-bus and 39-bus systems respectively.Simultaneously,the cumulative voltage-deviation index decreases from 0.0277 to 3.42×10^(−4) p.u.(98.77%reduction)in the 9-bus system,and from 0.0556 to 0.0107 p.u.(80.76%reduction)in the 39-bus system.These improvements demonstrate significant suppression of line losses and voltage fluctuations.Comparative analysis with traditional heuristic optimization algorithms confirms the superior performance of the proposed approach.展开更多
The Lake Hazar basin,located along the Palu segment of the East Anatolian Fault System(EAFS),provides a key natural laboratory for examining transtensional deformation in a major intracontinental strike-slip zone.Inte...The Lake Hazar basin,located along the Palu segment of the East Anatolian Fault System(EAFS),provides a key natural laboratory for examining transtensional deformation in a major intracontinental strike-slip zone.Integrated field mapping,fault-slip analysis,and focal mechanism inversion reveal a polyphase tectonic history involving sequential compressional,strike-slip,and extensional regimes.Rigorous discrimination of heterogeneous fault-slip datasets into homogeneous subsets enabled reconstruction of geologically consistent stress tensors and clarified the temporal transition from strike-slip to transtensional deformation.Paleostress results indicate NNE–SSW compression and NW–SE extension,consistent with present-day seismotectonic and geomorphic patterns.Variations in stress ratio Rvalues(0.26–0.57 for strike-slip;0.28–0.33 for extensional domains)and low misfit angles(<15°)reflect localized strain partitioning and reactivation of inherited faults.The Lake Hazar basin thus evolved from a pull-apart structure into a negative flower geometry through successive deformation and fault linkage.These findings highlight that discriminating polyphase fault-slip data is essential for resolving deformation dynamics in complex fault systems.The integrated structural,paleostress,and seismotectonic framework presented here refines understanding of strain localization,fault reactivation,and stress transfer along the East Anatolian Fault System.展开更多
The reactive diffusion in Mg-Gd binary system was studied at 773 K by optical microscopy（OM）, scanning electron microscopy（SEM） and electron probe micro-analysis（EPMA）. After annealing at 773 K for 12-48 h, four...The reactive diffusion in Mg-Gd binary system was studied at 773 K by optical microscopy（OM）, scanning electron microscopy（SEM） and electron probe micro-analysis（EPMA）. After annealing at 773 K for 12-48 h, four different intermetallic layers, Mg5 Gd, Mg3 Gd, Mg2 Gd and Mg Gd, form at the Mg/Gd interfaces in the diffusion couples. The thicknesses of intermetallic layers δi（i stands for the phases of Mg5 Gd, Mg3 Gd, Mg2 Gd and Mg Gd, respectively） are proportional to the square root of annealing time t1/2, which indicates that the growth behavior of the intermetallics is controlled by the diffusion rate. The ratio of thickness of each intermetallic layer to the total thickness is constant with increasing the annealing time, which means that the growth behavior is constant at a certain annealing temperature. The diffusion coefficient of Gd in different intermetallics was calculated by Matano method.展开更多
Rice is one of the main staple food crops in the world, but it may suffer serious water stress during growth period. Water stress during grain filling results in decreased grain yeild, but its mechanism generating and...Rice is one of the main staple food crops in the world, but it may suffer serious water stress during growth period. Water stress during grain filling results in decreased grain yeild, but its mechanism generating and scavenging the active oxygen is unclear under continuance of the water stress. The experiment was carried out in growth chamber to investigate the effects of water stress on the production of superoxide free radical （O2）, hydrogen peroxide （H202）, malondialdehyde （MDA）, reduced glutathione （GSH）, ascorbic acid （AsA）, and antioxidative enzyme activities in three rice hybrids with differing drought resistant under both normal and drought conditions during grain-filling stage. The results showed that water stress aggravated the membrane lipid peroxidation in rice leaves, which was more severe in less drought resistant hybrids than that in more tolerant ones. Also O2＇ and H2O2 accumulated more rapidly in less drought resistant hybrids than that in more tolerant ones. During water stress, decreases of GSH, AsA, chlorophyll, and relative water contents in more drought resistant hybrids were obvious less than those in less tolerant ones. Activities of superoxide dismutase （SOD）, catalase （CAT） and peroxidase （POD） in/eaves increased obviously in 0-14 d after heading and subsequently decreased rapidly, and those in more drought resistant hybrids were more than those in less tolerant ones. The results showed that changes of O2, H2O2, MDA, GSH, and AsA contents and antioxidative enzyme activities correlated significantly to drought resistance of rice hybrids, and more drought resistant hybrids possessed high ant oxidation capacity.展开更多
In this study, monoglycidyl silyl etherated eugenol(GSE) was synthesized as reactive epoxy diluent, and the chemical structure of GSE, intermediates, and products were characterized by Fourier transform infrared spect...In this study, monoglycidyl silyl etherated eugenol(GSE) was synthesized as reactive epoxy diluent, and the chemical structure of GSE, intermediates, and products were characterized by Fourier transform infrared spectroscopy(FTIR) and nuclear magnetic resonance(~1 H-NMR). GSE existed as a potential bio-based reactive diluent for petroleum-based epoxy resin. The curing kinetics of EP/HHPA/GSE system was studied by non-isothermal DSC method. The kinetics parameters were calculated by using the Kissinger model, Crane model, Ozawa model, and β-T(temperature-heating rate) extrapolation, respectively. In addition, the effects of GSE on the thermo-mechanical properties and thermal stability of EP/HHPA/GSE systems were studied, indicating that GSE can effectively improve the toughness and thermal decomposition temperature of the epoxy system.展开更多
Composition estimation plays very important role in plant operation and control.Extended Kalman filter(EKF) is one of the most common estimators,which has been used in composition estimation of reactive batch distilla...Composition estimation plays very important role in plant operation and control.Extended Kalman filter(EKF) is one of the most common estimators,which has been used in composition estimation of reactive batch distillation,but its performance is heavily dependent on the thermodynamic modeling of vapor-liquid equilibrium,which is difficult to initialize and tune.In this paper an inferential state estimation scheme based on adaptive neuro-fuzzy inference system(ANFIS) ,which is a model base estimator,is employed for composition estimation by using temperature measurements in multicomponent reactive batch distillation.The state estimator is supported by data from a complete dynamic model that includes component and energy balance equations accompanied with thermodynamic relations and reaction kinetics.The mathematical model is verified by pilot plant data.The simulation results show that the ANFIS estimator provides reliable and accurate estimation for component concentrations in reactive batch distillation.The estimated states form a basis for improving the performance of reactive batch distillation either through decision making of an operator or through an automatic closed-loop control scheme.展开更多
基金supported by the National Natural Science Foundation of China(61171120)
文摘This paper focuses on the performance analysis of flexible reactive systems. The performance analysis consists of two phases： first system modeling, second performance evalua-tion. The paper models the flexible reactive system by the stochas-tic statecharts method, and uses the simulation method to evalu-ate the performance. To make use of the feature of event-triggered state transitions in the statecharts, a new method of simulation is proposed based on the techniques of the discrete-event system simulation. The new method solves the problem of computer imple-mentation of stochastic events, probabilistic transition, concurrent states, paral el actions, and broadcast communication mechanism in the stochastic statecharts. An example of a flexible manufactur-ing system is presented. The simulation result of the example is consistent with the analytical result, which shows the feasibility of the proposed new simulation method.
文摘A wind-turbine power system is often challenged by voltage instability,reactive power imbalance,and limited fault ride-through capability under grid disturbances.Doubly Fed Induction Generator based wind farms,owing to their partial coupling with the grid,are particularly vulnerable to voltage dips and excessive reactive power absorption during fault events.This study proposes an adaptive control strategy based on Model Reference Adaptive Control integrated with stator flux-oriented vector control to regulate active and reactive power of a DFIG-based wind farm connected to a standard IEEE 9-bus power system under fault conditions.The proposed control scheme is developed and validated using detailed MATLAB/Simulink modeling under normal operation,symmetrical three-phase fault conditions,and post-fault recovery scenarios.A three-phase-to-ground fault is applied at the wind farm interconnection bus for a duration of 150 ms to evaluate transient performance.Simulation results demonstrate that the adaptive controller ensures fast power tracking,effective reactive power support,and enhanced voltage recovery compared to a conventional proportional–integral controller.Quantitatively,the proposed method improves voltage recovery time by approximately 45%,reduces active power overshoot by 38%,and lowers total harmonic distortion by 52% following fault clearance.Furthermore,the adaptive controller maintains stable operation under variations in wind speed and machine parameters without requiring retuning,highlighting its robustness against system uncertainties.The results confirm that the proposed control strategy significantly enhances fault ride-through capability,power quality,and dynamic stability of grid-interfaced wind farms.These findings demonstrate the practical applicability of adaptive control techniques for improving the reliability and resilience of modern power systems with high wind energy penetration.
基金the support received from the National Natural Science Foundation of China(Grant No.12302460)the State Key Laboratory of Explosion Science and Safety Protection(Grant No.YBKT24-02)。
文摘The reactive materials filled structure(RMFS)is a structural penetrator that replaces high explosive(HE)with reactive materials,presenting a novel self-distributed initiation,multiple deflagrations behavior during penetrating multi-layered plates,and generating a multipeak overpressure behind the plates.Here analytical models of RMFS self-distributed energy release and equivalent deflagration are developed.The multipeak overpressure formation model based on the single deflagration overpressure expression was promoted.The impact tests of RMFS on multi-layered plates at 584 m/s,616 m/s,and819 m/s were performed to validate the analytical model.Further,the influence of a single overpressure peak and time intervals versus impact velocity is discussed.The analysis results indicate that the deflagration happened within 20.68 mm behind the plate,the initial impact velocity and plate thickness are the crucial factors that dominate the self-distributed multipeak overpressure effect.Three formation patterns of multipeak overpressure are proposed.
文摘Hybrid commutation converters(HCCs)utilizing reverse-blocking integrated gate commutation thyristors(IGCTs)have gained significant attention due to their immunity to commutation failure.Leveraging the recovery enhancement characteristics of IGCTs,HCCs demonstrate superior performance at reduced extinction angles,thereby minimizing reactive power consumption.This study presents a comprehensive investigation into reactive power control strategies for HCCs operating at small extinction angles.First,the topological configuration and commutation principle of HCC are elucidated.Subsequently,the mechanism of HCC reactive power control is analyzed,and a reactive power control strategy is proposed by combining the converter transformer taps with extinction angles.Moreover,the relationship between transformer taps and reactive power exchange under different rated extinction angles is calculated,and the theoretically rated extinction angle is proposed.Finally,to validate the proposed control strategy,a four-terminal ultra-high voltage direct current power grid incorporating HCC technology is modeled and sim-ulated using PSCAD/EMTDC.The simulation results demonstrate that the proposed strategy effectively supports AC systems by reducing reactive power absorption in HCCs,while simultaneously exhibiting enhanced reli-ability and economic efficiency.
基金financially supported by the National Natural Science Foundation of China(Nos.52373070,52273071 and U25A20255)the Special Support Plan for High-Level Talents in Zhejiang Province(No.2022R51008)the HZNU scientific research and innovation team project(No.TD2025004).
文摘Rubber-toughened thermoplastic materials have become ubiquitous in modern society owing to their lightweight nature and desirable combination of advantageous performances.Despite the ever-increasing demand,the development of polymer alloys that are lightweight,high-strength,and high-toughness remains an ongoing challenge.Inspired by the unique“salami”microstructure from commercial acrylonitrile butadiene styrene copolymer(ABS)and high-impact polystyrene(HIPS),a facile approach was developed to overcome the trade-off between enhancing the toughness and rigidity of fully polymer-based alloys by virtue of elastomeric salami particles.This strategy entails pre-grafting rigid poly(lactic acid)(PLLA)chains with glycidyl methacrylate-grafted octene ethylene copolymer(POE-g-GMA)using complementary reactive groups.It can be envisaged that the PLLA grafts featuring strong incompatibility with polypropylene(PP)remain fixed in elastomer phase upon the subsequent melt compounding,facilitating the in situ formation of“hard core(PLLA)-soft shell(polyolefin elastomer,POE)”particles in polypropylene(PP)matrix.The all-polymer alloys containing elastomeric salami particles demonstrated unprecedented performance combinations,including upper notched impact strengths(56.8 kJ/m2),even higher tensile strength(36.8 MPa),and Young’s modulus(0.93 GPa)than that of the PP matrix.Furthermore,these materials are lightweight without the incorporation of reinforcing nano-fillers,which is competitive with industrial engineering plastics.It is highly anticipated that this universal and highly efficient protocol will be appropriate for arbitrary rubber toughened/reinforced systems,offering a paradigm in the design of advanced all-polymer alloys.
基金supported by the National Natural Science Foundation of China(Grant Nos.42525201 and 42230710).
文摘Bio-carbonation of reactive MgO has been regarded as a promising and eco-friendly method for construction and demolition waste(CDW)cementation in various geotechnical engineering applications.However,the beneficial effect of bio-carbonation of reactive MgO cemented CDW(BCM-samples)can be altered when exposed to wetting-drying cycles induced by extreme climate changes or groundwater fluctuations.To better understand the durability of BCM-samples and their underlying deterioration mechanisms,a series of BCM-samples was prepared to investigate their physical-mechanical performance and microstructure evolution subjected to the wetting-drying cycles.The results indicated that the wetting-drying cycles can deteriorate the BCM-samples,and their physical-mechanical behaviors change quickly at the cycle beginning and then smoothly after 2 cycles.With the increase in cycling,the apparent deterioration with efflorescence and microcrack development can be observed.The mass loss and water absorption rates increased while the dry density,compressional wave velocity,and unconfined compression strength decreased.Urea pre-hydrolysis treatment can significantly improve the durability of BCM-samples,as the more hydrated magnesia carbonates(HMCs)enhance the cementing effects.After 10 cycles,the UCS of pre-hydrolyzed samples decreased 25.4%to 4.45 MPa,while that of ordinary samples decreased 50.7%to 1.20 MPa.The deterioration of BCM-samples caused by wetting-drying cycles can be attributed to two factors.One of the main factors is the structural integrity changes caused by the rapid loss of soluble material at the initial cycling stages.Another factor is the decrease in cementation induced by the loss of brucite and HMCs at the following cycle stages.
基金supported by the National Key R&D Program of China(No.2023YFC3707900)the National Natural Science Foundation of China(No.51978157).
文摘Biochar and zero-valent iron are promising materials for the removal of trichloroethylene(TCE)from groundwater,but further research is still required on the synergistic mechanism and hydraulic performance in the permeable reactive barriers(PRBs)with biochar-iron composites.In this work,biochar-iron composites were synthesized by two different methods,and subjected to the microscopic analysis,batch experiments and the PRB’s model tests.The results indicated that the removal rates of TCE on biochar-iron composites reached above 90%,and the optimal removal conditions were the initial pH of 6.0 and a biochar/iron mass ratio of 5:1.The removal of TCE on biochar-iron composites followed the pseudo-second-order and Freundlich models,and the maximum adsorption capacity of TCE was 25.95 mg/g.The adsorption of biochar and dechlorination of nZVI dominated the removal of TCE.Biochar significantly enhanced the dechlorination of TCE on nZVI through modifying the electrochemical characteristics to lower its corrosion potential of nZVI,promote direct electron transfer,and improve electronic transfer capability.M-5BC-1nZVI exhibited excellent hydraulic performance for maintaining an adequate permeability coefficient(10^(−6)to 10^(−5)m/s).
基金supported by the National Key R&D Program of China(No.2023YFC3210100).
文摘Vacuum-ultraviolet(VUV)radiation is high-energy UV radiation with a wavelength of 100-200 nm capable of decomposing/mineralizing hazardous emerging organic pollutants(EPs)in water through direct photolysis and/or by generating reactive free radicals(RFRs)during photolysis.However,due to the unsatisfactory photoelectric conversion rate,strong absorption by oxygen and water molecules,and other characteristics of VUV radiation,its application and development are hindered,leading to misconceptions regarding high energy consumption and insufficient free radical yield.The objectives of our assessment in this review are as follows:The illumination of the photochemical characteristics of VUV and the reactivity of aqueous solutions.Summarization of accurate UV dose and energy evaluation criteria.Comparison and analysis of the photochemical mechanisms and reaction kinetics of different types of EPs via VUV direct photolysis,as well as the interference origins of typical substrates in water for VUV decontamination.We found that quantities typically reported in VUV photochemical reactions of engineered systems are underreported in low-pressure mercury lamp(LPUV)photochemical reactions,especially a quantitative indicator of the species or energy that induces a chemical reaction.The absence of these quantities has made it difficult to assess the fundamental performance of VUV photolysis fully compared with that of UV-C.Some studies have sought to optimize VUV-advanced reduction processes(VUV-ARP)or VUV reactor treatment of these contaminants;however,an abundant evaluation of the reaction origins and processes between VUV-derived main RFRs and reactants(H_(2)O,O_(2),organic matter,inorganic ions,etc.)is essential,cause these scientific elements will provide the possibility to break the application gap for VUV in the field of EPs treating.Overall,the data compilation,analysis,and research recommendations provided in this review will form the basis for all photochemical reactions initiated by VUV radiation with water as the backing agent.
文摘We are sorry for the mistakes of Affiliation,"a State Key Laboratory of Advanced Fiber Materials,Center for Advanced Low-Dimension Materials,Donghua University,Shanghai 201620,China"should be replaced by"a State Key Laboratory of Advanced Fiber Materials,Center for Advanced Low-Dimension Materials,College of Materials Science and Engineering,Donghua University,Shanghai 201620,China".We apologized for the inconvenience caused by this error.
基金supported by the National Natural Science Foundation of China(22278021)State Key Laboratory of Chemical Engineering(No.SKL-ChE-23A01).
文摘Achieving high selectivity to 2,5-furandicarboxylic acid(FDCA)in the photocatalytic oxidation of 5-hydroxymethylfurfural(HMF)in aqueous solution advocates the principle of green and sustainable chemistry,but still remains a significant challenge.Herein,manipulating the reactive oxygen species(ROS)has been realized and dramatically promotes the selective photocatalytic oxidation of HMF in aqueous solution.A high FDCAyield of 98.6% has been achieved after 3 h of visible light irradiation over the as-prepared FeO_(x)-Au/TiO_(2) catalyst,being one of the leading photocatalytic performances.Furthermore,satisfactory FDCA yields of higher than 80%could be realized even in the outdoor environment under natural sunlight irradiation,regardless of sunny or cloudy weather.A combination study including physical characterization,kinetic analysis,radical trapping experiments and density functional theory calculations unveils the rate-determining step(oxidation of hydroxyl group)and respective contributions of the generated ROS(1O_(2) and·O_(2)-)in each step of the entire reaction network.The present work would push ahead the understanding of HMF photocatalytic oxidation and contribute to the rational design of high-performance photocatalysts.
基金financially supported by the National Natural Science Foundation of China(No.52573053).
文摘Reactive compatibilization has been widely applied to enhance the compatibility of polymer blends,thereby improving their mechanical properties.However,it generally reduces the chain mobility and regularity,often leading to slower polymer crystallization.Here,we demonstrate that reactive compatibilization in poly(lactic acid)/poly(butylene adipate-co-terephthalate)(PLA/PBAT)blends unexpectedly promotes PLA matrix crystallization during injection molding,in contrast to the retarded kinetics observed in differential scanning calorimetry isothermal crystallization studies.The phase morphology,rheological behavior,and crystalline structure were systematically analyzed to elucidate markedly different crystallization kinetics under static and shear fields.The potential mechanism underlying crystallization enhancement is attributed to PBAT domain refinement and viscosity increase induced by reactive compatibilization,which,under shear flow,create favorable conditions for crystallization by enhancing PBAT fibril nucleation and retarding the relaxation of oriented PLA chains.This study offers new perspectives on the effect of reactive compatibilization on the polymer crystallization behavior.
基金supported by the National Natural Science Foundation of China under Grant 52277184 and Grant 52277183.
文摘The transient synchronization stability of grid-forming converters(GFMCs)is significantly challenged under grid voltage sags.Continuous efforts have been devoted to analyzing the GFMC transient stability,with limited attention paid to the impacts of control loop dynamics.However,the complex control dynamics,especially the interactions between the active/reactive power control loops and the current saturation process(CSP),are crucial for accurately describing the transient behavior and evaluating the stability.Thus,in this study,a new large-signal GFMC model is established,considering the reactive power control(RPC)with different kinds of controllers and the CSP simultaneously.It is revealed that GFMC does not switch to the current-limited mode immediately,and the dynamics of RPC further affect the transient behavior before the current limiting significantly.Hence,the complex control dynamics can alter the mode switching point of current saturation,thereby increasing the risk of loss of synchronization(LOS).Based on the above findings,comprehensive comparisons of typical RPC controllers are presented to facilitate practical engineering applications.A unified stability enhancement method is proposed for solving the problem of LOS.Finally,experiments validate the correctness of the analysis and the effectiveness of the proposed control strategy.
基金supported by the National Key Research and Development Program of China(No.2021YFB1507001).
文摘During sending-end faults in the hybrid cascaded HVDC(HC-HVDC)system,the transient voltage drop characteristics under the interaction of the AC/DC hybrid system remain unclear,and the reactive power support provided by the HC-HVDC to the sending-end AC system requires further investigation.To address this problem,the reactive power interaction coupling mechanism between the sending-end AC system and the HC-HVDC is revealed,and the transient voltage mathematical model considering fault severity and duration is established.Under the dynamic change of the AC system voltage,the difference between the reactive power provided only by the reactive power compensation devices and by the combined modular multilevel converters(MMC)and reactive power compensation devices is analyzed.It is concluded that using MMC to provide a proportion of reactive power enhances the reactive power support to the AC system during faults.Then,the transient voltage model considering the reactive power support of MMC is established,and the critical reactive power consumption of line commutated converter(LCC)is quantified.It is concluded that the reactive power consumption of LCC exceeding its critical value deteriorates the transient voltage.A coordinated support strategy for the sending-end AC system based on reactive power support of MMC and reactive power regulation of LCC is proposed.It can effectively address the challenge of weakened reactive power support to the AC system due to voltage drop,thereby preventing the unbalanced reactive power from deteriorating the transient voltage,and realizing active support of the tran-sient voltage.Finally,a simulation model is established on the PSCAD/EMTDC platform,and the simulation results validate the effectiveness of the proposed strategy in supporting the transient voltage,under different fault types,durations,severities,and locations.
文摘In real industrial microgrids(MGs),the length of the primary delivery feeder to the connection point of the main substation is sometimes long.This reduces the power factor and increases reactive power absorption along the primary delivery feeder from the external network.Besides,the giant induction electro-motors as the working horse of industries requires remarkable amounts of reactive power for electro-mechanical energy conversions.To reduce power losses and operating costs of the MG as well as to improve the voltage quality,this study aims at providing an insightful model for optimal placement and sizing of reactive power compensation capacitors in an industrial MG.In the presented model,the objective function considers voltage profile and network power factor improvement at the MG connection point.Also,it realizes power flow equations within which all operational security constraints are considered.Various reactive power compensation strategies including distributed group compensation,centralized compensation at the main substation,and distributed compensation along the primary delivery feeder are scrutinized.A real industrial MG,say as Urmia Petrochemical plant,is considered in numerical validations.The obtained results in each scenario are discussed in depth.As seen,the best performance is obtained when the optimal location and sizing of capacitors are simultaneously determined at the main buses of the industrial plants,at the main substation of the MG,and alongside the primary delivery feeder.In this way,74.81%improvement in power losses reduction,1.3%lower active power import from the main grid,23.5%improvement in power factor,and 37.5%improvement in network voltage deviation summation are seen in this case compared to the base case.
基金supported by Yunnan Power Grid Co.,Ltd.Science and Technology Project:Research and application of key technologies for graphical-based power grid accident reconstruction and simulation(YNKJXM20240333).
文摘An optimized volt-ampere reactive(VAR)control framework is proposed for transmission-level power systems to simultaneously mitigate voltage deviations and active-power losses through coordinated control of large-scale wind/solar farms with shunt static var generators(SVGs).The model explicitly represents reactive-power regulation characteristics of doubly-fed wind turbines and PV inverters under real-time meteorological conditions,and quantifies SVG high-speed compensation capability,enabling seamless transition from localized VAR management to a globally coordinated strategy.An enhanced adaptive gain-sharing knowledge optimizer(AGSK-SD)integrates simulated annealing and diversity maintenance to autonomously tune voltage-control actions,renewable source reactive-power set-points,and SVG output.The algorithm adaptively modulates knowledge factors and ratios across search phases,performs SA-based fine-grained local exploitation,and periodically re-injects population diversity to prevent premature convergence.Comprehensive tests on IEEE 9-bus and 39-bus systems demonstrate AGSK-SD’s superiority over NSGA-II and MOPSO in hypervolume(HV),inverse generative distance(IGD),and spread metrics while maintaining acceptable computational burden.The method reduces network losses from 2.7191 to 2.15 MW(20.79%reduction)and from 15.1891 to 11.22 MW(26.16%reduction)in the 9-bus and 39-bus systems respectively.Simultaneously,the cumulative voltage-deviation index decreases from 0.0277 to 3.42×10^(−4) p.u.(98.77%reduction)in the 9-bus system,and from 0.0556 to 0.0107 p.u.(80.76%reduction)in the 39-bus system.These improvements demonstrate significant suppression of line losses and voltage fluctuations.Comparative analysis with traditional heuristic optimization algorithms confirms the superior performance of the proposed approach.
文摘The Lake Hazar basin,located along the Palu segment of the East Anatolian Fault System(EAFS),provides a key natural laboratory for examining transtensional deformation in a major intracontinental strike-slip zone.Integrated field mapping,fault-slip analysis,and focal mechanism inversion reveal a polyphase tectonic history involving sequential compressional,strike-slip,and extensional regimes.Rigorous discrimination of heterogeneous fault-slip datasets into homogeneous subsets enabled reconstruction of geologically consistent stress tensors and clarified the temporal transition from strike-slip to transtensional deformation.Paleostress results indicate NNE–SSW compression and NW–SE extension,consistent with present-day seismotectonic and geomorphic patterns.Variations in stress ratio Rvalues(0.26–0.57 for strike-slip;0.28–0.33 for extensional domains)and low misfit angles(<15°)reflect localized strain partitioning and reactivation of inherited faults.The Lake Hazar basin thus evolved from a pull-apart structure into a negative flower geometry through successive deformation and fault linkage.These findings highlight that discriminating polyphase fault-slip data is essential for resolving deformation dynamics in complex fault systems.The integrated structural,paleostress,and seismotectonic framework presented here refines understanding of strain localization,fault reactivation,and stress transfer along the East Anatolian Fault System.
基金Projects(2013CB6322022013CB632205)supported by the National Basic Research Program of China
文摘The reactive diffusion in Mg-Gd binary system was studied at 773 K by optical microscopy（OM）, scanning electron microscopy（SEM） and electron probe micro-analysis（EPMA）. After annealing at 773 K for 12-48 h, four different intermetallic layers, Mg5 Gd, Mg3 Gd, Mg2 Gd and Mg Gd, form at the Mg/Gd interfaces in the diffusion couples. The thicknesses of intermetallic layers δi（i stands for the phases of Mg5 Gd, Mg3 Gd, Mg2 Gd and Mg Gd, respectively） are proportional to the square root of annealing time t1/2, which indicates that the growth behavior of the intermetallics is controlled by the diffusion rate. The ratio of thickness of each intermetallic layer to the total thickness is constant with increasing the annealing time, which means that the growth behavior is constant at a certain annealing temperature. The diffusion coefficient of Gd in different intermetallics was calculated by Matano method.
基金supported by the National 863 Program of China (2002AA2Z4011)the Foundation for Personnel of Henan University of Science and Technology China.
文摘Rice is one of the main staple food crops in the world, but it may suffer serious water stress during growth period. Water stress during grain filling results in decreased grain yeild, but its mechanism generating and scavenging the active oxygen is unclear under continuance of the water stress. The experiment was carried out in growth chamber to investigate the effects of water stress on the production of superoxide free radical （O2）, hydrogen peroxide （H202）, malondialdehyde （MDA）, reduced glutathione （GSH）, ascorbic acid （AsA）, and antioxidative enzyme activities in three rice hybrids with differing drought resistant under both normal and drought conditions during grain-filling stage. The results showed that water stress aggravated the membrane lipid peroxidation in rice leaves, which was more severe in less drought resistant hybrids than that in more tolerant ones. Also O2＇ and H2O2 accumulated more rapidly in less drought resistant hybrids than that in more tolerant ones. During water stress, decreases of GSH, AsA, chlorophyll, and relative water contents in more drought resistant hybrids were obvious less than those in less tolerant ones. Activities of superoxide dismutase （SOD）, catalase （CAT） and peroxidase （POD） in/eaves increased obviously in 0-14 d after heading and subsequently decreased rapidly, and those in more drought resistant hybrids were more than those in less tolerant ones. The results showed that changes of O2, H2O2, MDA, GSH, and AsA contents and antioxidative enzyme activities correlated significantly to drought resistance of rice hybrids, and more drought resistant hybrids possessed high ant oxidation capacity.
基金the financial support provided by "One Hundred Talented People" of the Chinese Academy of Sciences–China (No. Y60707WR04)Natural Science Foundation of Zhejiang Province (No. Y16B040008)
文摘In this study, monoglycidyl silyl etherated eugenol(GSE) was synthesized as reactive epoxy diluent, and the chemical structure of GSE, intermediates, and products were characterized by Fourier transform infrared spectroscopy(FTIR) and nuclear magnetic resonance(~1 H-NMR). GSE existed as a potential bio-based reactive diluent for petroleum-based epoxy resin. The curing kinetics of EP/HHPA/GSE system was studied by non-isothermal DSC method. The kinetics parameters were calculated by using the Kissinger model, Crane model, Ozawa model, and β-T(temperature-heating rate) extrapolation, respectively. In addition, the effects of GSE on the thermo-mechanical properties and thermal stability of EP/HHPA/GSE systems were studied, indicating that GSE can effectively improve the toughness and thermal decomposition temperature of the epoxy system.
文摘Composition estimation plays very important role in plant operation and control.Extended Kalman filter(EKF) is one of the most common estimators,which has been used in composition estimation of reactive batch distillation,but its performance is heavily dependent on the thermodynamic modeling of vapor-liquid equilibrium,which is difficult to initialize and tune.In this paper an inferential state estimation scheme based on adaptive neuro-fuzzy inference system(ANFIS) ,which is a model base estimator,is employed for composition estimation by using temperature measurements in multicomponent reactive batch distillation.The state estimator is supported by data from a complete dynamic model that includes component and energy balance equations accompanied with thermodynamic relations and reaction kinetics.The mathematical model is verified by pilot plant data.The simulation results show that the ANFIS estimator provides reliable and accurate estimation for component concentrations in reactive batch distillation.The estimated states form a basis for improving the performance of reactive batch distillation either through decision making of an operator or through an automatic closed-loop control scheme.
