A novel method for preparation of polymer-based magnetic microspheres was proposed by utilizing melt reactive blending, which was based on selective location of Fe3O4 nanoparticles in PA6 domains of polystyrene （PS）...A novel method for preparation of polymer-based magnetic microspheres was proposed by utilizing melt reactive blending, which was based on selective location of Fe3O4 nanoparticles in PA6 domains of polystyrene （PS）/polyamide 6 （PA6） immiscible blends. The morphology of PA6/Fe3O4 composite magnetic mierospheres was studied by scanning electronic microscopy （SEM）. The composite magnetic mierospheres were spherical with a diameter range of 0.5-8 μm; the diameter was sharply decreased with a very narrow distribution by adding terminal maleic anhydride fimctionalized polystyrenes （FPS） for reactive blending. Transmission electron microscopy （TEM） and thermogravimetry analysis （TGA） results showed that most of Fe3O4 was located in the PA6 microspheres. Magnetization data revealed the magnetite content of PA6/Fe3O4 microspheres was about 32 wt% and the saturation magnetization could be up to 17.2 AmE/kg.展开更多
Rubber-toughened thermoplastic materials have become ubiquitous in modern society owing to their lightweight nature and desirable combination of advantageous performances.Despite the ever-increasing demand,the develop...Rubber-toughened thermoplastic materials have become ubiquitous in modern society owing to their lightweight nature and desirable combination of advantageous performances.Despite the ever-increasing demand,the development of polymer alloys that are lightweight,high-strength,and high-toughness remains an ongoing challenge.Inspired by the unique“salami”microstructure from commercial acrylonitrile butadiene styrene copolymer(ABS)and high-impact polystyrene(HIPS),a facile approach was developed to overcome the trade-off between enhancing the toughness and rigidity of fully polymer-based alloys by virtue of elastomeric salami particles.This strategy entails pre-grafting rigid poly(lactic acid)(PLLA)chains with glycidyl methacrylate-grafted octene ethylene copolymer(POE-g-GMA)using complementary reactive groups.It can be envisaged that the PLLA grafts featuring strong incompatibility with polypropylene(PP)remain fixed in elastomer phase upon the subsequent melt compounding,facilitating the in situ formation of“hard core(PLLA)-soft shell(polyolefin elastomer,POE)”particles in polypropylene(PP)matrix.The all-polymer alloys containing elastomeric salami particles demonstrated unprecedented performance combinations,including upper notched impact strengths(56.8 kJ/m2),even higher tensile strength(36.8 MPa),and Young’s modulus(0.93 GPa)than that of the PP matrix.Furthermore,these materials are lightweight without the incorporation of reinforcing nano-fillers,which is competitive with industrial engineering plastics.It is highly anticipated that this universal and highly efficient protocol will be appropriate for arbitrary rubber toughened/reinforced systems,offering a paradigm in the design of advanced all-polymer alloys.展开更多
基金financially supported by the National Natural Science Foundation of China(Nos.50873033,20974033)
文摘A novel method for preparation of polymer-based magnetic microspheres was proposed by utilizing melt reactive blending, which was based on selective location of Fe3O4 nanoparticles in PA6 domains of polystyrene （PS）/polyamide 6 （PA6） immiscible blends. The morphology of PA6/Fe3O4 composite magnetic mierospheres was studied by scanning electronic microscopy （SEM）. The composite magnetic mierospheres were spherical with a diameter range of 0.5-8 μm; the diameter was sharply decreased with a very narrow distribution by adding terminal maleic anhydride fimctionalized polystyrenes （FPS） for reactive blending. Transmission electron microscopy （TEM） and thermogravimetry analysis （TGA） results showed that most of Fe3O4 was located in the PA6 microspheres. Magnetization data revealed the magnetite content of PA6/Fe3O4 microspheres was about 32 wt% and the saturation magnetization could be up to 17.2 AmE/kg.
基金financially supported by the National Natural Science Foundation of China(Nos.52373070,52273071 and U25A20255)the Special Support Plan for High-Level Talents in Zhejiang Province(No.2022R51008)the HZNU scientific research and innovation team project(No.TD2025004).
文摘Rubber-toughened thermoplastic materials have become ubiquitous in modern society owing to their lightweight nature and desirable combination of advantageous performances.Despite the ever-increasing demand,the development of polymer alloys that are lightweight,high-strength,and high-toughness remains an ongoing challenge.Inspired by the unique“salami”microstructure from commercial acrylonitrile butadiene styrene copolymer(ABS)and high-impact polystyrene(HIPS),a facile approach was developed to overcome the trade-off between enhancing the toughness and rigidity of fully polymer-based alloys by virtue of elastomeric salami particles.This strategy entails pre-grafting rigid poly(lactic acid)(PLLA)chains with glycidyl methacrylate-grafted octene ethylene copolymer(POE-g-GMA)using complementary reactive groups.It can be envisaged that the PLLA grafts featuring strong incompatibility with polypropylene(PP)remain fixed in elastomer phase upon the subsequent melt compounding,facilitating the in situ formation of“hard core(PLLA)-soft shell(polyolefin elastomer,POE)”particles in polypropylene(PP)matrix.The all-polymer alloys containing elastomeric salami particles demonstrated unprecedented performance combinations,including upper notched impact strengths(56.8 kJ/m2),even higher tensile strength(36.8 MPa),and Young’s modulus(0.93 GPa)than that of the PP matrix.Furthermore,these materials are lightweight without the incorporation of reinforcing nano-fillers,which is competitive with industrial engineering plastics.It is highly anticipated that this universal and highly efficient protocol will be appropriate for arbitrary rubber toughened/reinforced systems,offering a paradigm in the design of advanced all-polymer alloys.
