In this study,two copper(II)salts with different configurations,2[H_(3)LCuCl_(4)][Cu_(2)Cl_(6)](1)and[H_(4)L][CuCl_(4)]_(2)Cl(2)(L=(1R,2R)-N,N’-bis(pyridin-4-ylmethyl)cyclohexane-1,2-diamine),have been synthesized an...In this study,two copper(II)salts with different configurations,2[H_(3)LCuCl_(4)][Cu_(2)Cl_(6)](1)and[H_(4)L][CuCl_(4)]_(2)Cl(2)(L=(1R,2R)-N,N’-bis(pyridin-4-ylmethyl)cyclohexane-1,2-diamine),have been synthesized and applied in the following solid–gas and solid–solid reactions.Both salts 1 and 2 gave rise to the salt([H_(4)L][Cu_(2)Cl_(8)]H_(2)O(3)upon exposure to HCl gas or grinding with equal moles of CuCl_(2)·2H_(2)O.展开更多
基金supported by the National Natural Science Foundation of China(No.21571090)the Liaoning BaiQianWan Talents Program,and the Liaoning Provincial Department of Education Innovation Team Project(LT2017010)We thank the BL17B beamline of the National Facility for Protein Science Shanghai(NFPS)at Shanghai Synchrotron Radiation Facility(SSRF),for assistance with X-ray data collection.
文摘In this study,two copper(II)salts with different configurations,2[H_(3)LCuCl_(4)][Cu_(2)Cl_(6)](1)and[H_(4)L][CuCl_(4)]_(2)Cl(2)(L=(1R,2R)-N,N’-bis(pyridin-4-ylmethyl)cyclohexane-1,2-diamine),have been synthesized and applied in the following solid–gas and solid–solid reactions.Both salts 1 and 2 gave rise to the salt([H_(4)L][Cu_(2)Cl_(8)]H_(2)O(3)upon exposure to HCl gas or grinding with equal moles of CuCl_(2)·2H_(2)O.
