Peng et al.in[Phys.Rev.Research,2020,2(3):033089,11 pp.]formulated one-way fluxes for a general chemical reaction far from equilibrium,with arbitrary complex mechanisms,multiple intermediates,and internal kinetic cycl...Peng et al.in[Phys.Rev.Research,2020,2(3):033089,11 pp.]formulated one-way fluxes for a general chemical reaction far from equilibrium,with arbitrary complex mechanisms,multiple intermediates,and internal kinetic cycles.They defined the limit of the ratio of mesoscopic one-way fluxes and the volume of the tank reactor when the volume tends to infinity as macroscopic one-way fluxes,but a rigorous proof of existence of the limit is still awaiting.In this article,we fill this gap under a mild hypothesis:the Markov chain associated with the chemical master equation has finite states and any two columns in the stoichiometric matrices are not identical.In fact,an explicit expression of the limit is obtained.展开更多
The formation of humins hampers the large-scale production of 5-hydroxymethylfurfural(HMF)in biorefinery.Here,a detailed reaction network of humin formation at the initial stage of fructose-to-HMF dehydration in water...The formation of humins hampers the large-scale production of 5-hydroxymethylfurfural(HMF)in biorefinery.Here,a detailed reaction network of humin formation at the initial stage of fructose-to-HMF dehydration in water is delineated by combined experimental,spectroscopic,and theoretical studies.Three bimolecular reaction pathways to build up soluble humins are demonstrated.That is,the intermolecular etherification of β-furanose at room temperature initiates the C12 path,whereas the C-C cleavage of a-furanose at 130-150℃ leads to C11 path,and that of open-chain fructose at 180℃ to C11' path.The successive intramolecular dehydrations and condensations of the as-formed bimolecular intermediates lead to three types of soluble humins.We show that the C12 path could be restrained by using HCl or AlCl_(3) catalyst,and both the C12 and C110 paths could be effectively inhibited by adding THF as a co-solvent or accelerating heating rate via microwave heating.展开更多
The oxidative esterification of methacrolein(MAL)is an important way to prepare high-valued methyl methacrylate(MMA),but this process is ultra-complex due to the high reactivity of both C=O and C=C bonds in MAL molecu...The oxidative esterification of methacrolein(MAL)is an important way to prepare high-valued methyl methacrylate(MMA),but this process is ultra-complex due to the high reactivity of both C=O and C=C bonds in MAL molecule.In order to further improve MMA selectivity,the reaction network and relevant mechanisms have been proposed and profoundly investigated in this paper.Five kinds of fundamental reactions are involved in this process,including(a)the acetal reaction;(b)the aerobic oxidation of hemiacetal;(c)the alkoxylation of C=C double bond;(d)the Diels-Alder reaction;and(e)the hydrogenation reaction of unsaturated double bond.Among them,the Diels-Alder reaction of MAL is non-catalyzed,and the Brönsted acid sites or the Lewis acid sites favor promoting acetal reaction of MAL with methanol,while the alkoxylation of C=C bond with methanol is enhanced under alkaline condition.In particular,by employing the Pd-based catalysts,hydrogenation products are formed in alkaline methanol solution,hence with lower than those obtained by the Au-based catalysts.Notably,it is necessary to match the hemiacetal fromation and aerobic oxidation of hemiacetal,which is relevant with the amount and strength of acid and redox sites.Consequently,this work can provide a good guidance for the further design of both catalysts and processes in future.展开更多
The treatment of a multicomponent reversible reaction network is extremely complicated because largenumber of rate constants must be precisely determined and because the calculation based on these rateconstants is ted...The treatment of a multicomponent reversible reaction network is extremely complicated because largenumber of rate constants must be precisely determined and because the calculation based on these rateconstants is tedious.In order to reduce the degrees of freedom of the process,the authors propose a methodin which the reactor and the separator are regarded as a whole.Based on this approach,an N-componentreversible reaction system can be dealt with as a two—component system.Consequently,a simple and ac-cessible way of the apparent rate determination is suggested.For fiist-order reactions,an explicit,simplifiedexpression has been derived for both lumped and distributed parameter reaction systems.展开更多
Fischer-Tropsch synthesis(FTS)wax is a mixture of linear hydrocarbons with carbon number from C7 to C70+.Converting FTS wax into high-quality diesel(no sulfur and nitrogen contents)by hydrocracking technology is attra...Fischer-Tropsch synthesis(FTS)wax is a mixture of linear hydrocarbons with carbon number from C7 to C70+.Converting FTS wax into high-quality diesel(no sulfur and nitrogen contents)by hydrocracking technology is attractive in economy and practicability.Kinetic study of the hydrocracking of FTS wax in elementary step level is very challenging because of the huge amounts of reactions and species involved.Generation of reaction networks for hydrocracking of FTS wax in which the chain length goes up to C70 is described on the basis of Boolean adjacency matrixes.Each of the species(including paraffins,olefins and carbenium ions)involved in the elementary steps is represented digitally by using a(N+3)N matrix,in which a group of standardized numbering rules are designed to guarantee the unique identity of the species.Subsequently,the elementary steps are expressed by computer-aided matrix transformations in terms of proposed reaction rules.Dynamic memory allocation is used in species storage and a characteristic vector with nine elements is designed to store the key information of a(N+3)N matrix,which obviously reduces computer memory consumption and improves computing efficiency.The detailed reaction networks of FTS wax hydrocracking can be generated smoothly and accurately by the current method.The work is the basis of advanced elementary-step-level kinetic modeling.展开更多
Biological systems use intricate networks of chemical reactions to exchange information. How to simulate complex systems with simple strand-displacement reactions is crucial to broaden the application scenario of the ...Biological systems use intricate networks of chemical reactions to exchange information. How to simulate complex systems with simple strand-displacement reactions is crucial to broaden the application scenario of the DNA reaction network. Here, we report the artificial DNA reaction network to mimic the operation and function of biological information transfer via strand-displacement reaction. DNA is used as simple artificial analogs to schematize structures and transmit information. Using chemical synapses in neural networks as an example, we show that the proposed network enables core functions of biological systems, such as the long-term potential of synapses, which underpin learning and memory. Also, we performed the simple “silicon mimetic” to link electronic circuits to chemical network-based biological structures. As such, synaptic communication simulated by the DNA reaction network provides a complete demonstration for designing artificial reaction networks based on the essence of information interaction.展开更多
This paper investigates the global exponential stability of reaction-diffusion neural networks with discrete and distributed time-varying delays. By constructing a more general type of Lyapunov-Krasovskii functional c...This paper investigates the global exponential stability of reaction-diffusion neural networks with discrete and distributed time-varying delays. By constructing a more general type of Lyapunov-Krasovskii functional combined with a free-weighting matrix approach and analysis techniques, delay-dependent exponential stability criteria are derived in the form of linear matrix inequalities. The obtained results are dependent on the size of the time-vaxying delays and the measure of the space, which are usually less conservative than delay-independent and space-independent ones. These results are easy to check, and improve upon the existing stability results. Some remarks are given to show the advantages of the obtained results over the previous results. A numerical example has been presented to show the usefulness of the derived linear matrix inequality （LMI）-based stability conditions.展开更多
In this paper, the influence of the noise and delay upon the stability property of reaction-diffusion recurrent neural networks （RNNs） with the time-varying delay is discussed. The new and easily verifiable conditio...In this paper, the influence of the noise and delay upon the stability property of reaction-diffusion recurrent neural networks （RNNs） with the time-varying delay is discussed. The new and easily verifiable conditions to guarantee the mean value exponential stability of an equilibrium solution are derived. The rate of exponential convergence can be estimated by means of a simple computation based on these criteria.展开更多
The self-condensation of n-butanal is an important reaction for carbon-chain extension in the commercial production of 2-ethylhexanol.Moreover,aldol condensation is one of the important reactions for the synthesis of ...The self-condensation of n-butanal is an important reaction for carbon-chain extension in the commercial production of 2-ethylhexanol.Moreover,aldol condensation is one of the important reactions for the synthesis of valuable organic chemicals or transportation fuels from biomass-derived platform compounds.So the investigation of the self-condensation of n-butanal is of significance in both academia and industry.This contribution reviewed the catalytic performance of heterogeneous catalysts in the self-condensation of n-butanal and the related reaction mechanism,network,and kinetics.The purpose of this review is to dedicate some help for further development of environmentally friendly catalysts and for a thorough comprehension of aldol condensation.展开更多
基金partially supported by NSFC(Nos.11701265,11961033).
文摘Peng et al.in[Phys.Rev.Research,2020,2(3):033089,11 pp.]formulated one-way fluxes for a general chemical reaction far from equilibrium,with arbitrary complex mechanisms,multiple intermediates,and internal kinetic cycles.They defined the limit of the ratio of mesoscopic one-way fluxes and the volume of the tank reactor when the volume tends to infinity as macroscopic one-way fluxes,but a rigorous proof of existence of the limit is still awaiting.In this article,we fill this gap under a mild hypothesis:the Markov chain associated with the chemical master equation has finite states and any two columns in the stoichiometric matrices are not identical.In fact,an explicit expression of the limit is obtained.
基金the National Natural Science Foundation of China(No.21875149)111 project(B17030)the Basal Research Fund of the Central University.
文摘The formation of humins hampers the large-scale production of 5-hydroxymethylfurfural(HMF)in biorefinery.Here,a detailed reaction network of humin formation at the initial stage of fructose-to-HMF dehydration in water is delineated by combined experimental,spectroscopic,and theoretical studies.Three bimolecular reaction pathways to build up soluble humins are demonstrated.That is,the intermolecular etherification of β-furanose at room temperature initiates the C12 path,whereas the C-C cleavage of a-furanose at 130-150℃ leads to C11 path,and that of open-chain fructose at 180℃ to C11' path.The successive intramolecular dehydrations and condensations of the as-formed bimolecular intermediates lead to three types of soluble humins.We show that the C12 path could be restrained by using HCl or AlCl_(3) catalyst,and both the C12 and C110 paths could be effectively inhibited by adding THF as a co-solvent or accelerating heating rate via microwave heating.
基金The authors acknowledge supports from the National Key Basic Research Development Plan“973”Project(2006CB202508)the SINOPEC Project(411058,413025)the National Natural Science Foundation(21808244).
文摘The oxidative esterification of methacrolein(MAL)is an important way to prepare high-valued methyl methacrylate(MMA),but this process is ultra-complex due to the high reactivity of both C=O and C=C bonds in MAL molecule.In order to further improve MMA selectivity,the reaction network and relevant mechanisms have been proposed and profoundly investigated in this paper.Five kinds of fundamental reactions are involved in this process,including(a)the acetal reaction;(b)the aerobic oxidation of hemiacetal;(c)the alkoxylation of C=C double bond;(d)the Diels-Alder reaction;and(e)the hydrogenation reaction of unsaturated double bond.Among them,the Diels-Alder reaction of MAL is non-catalyzed,and the Brönsted acid sites or the Lewis acid sites favor promoting acetal reaction of MAL with methanol,while the alkoxylation of C=C bond with methanol is enhanced under alkaline condition.In particular,by employing the Pd-based catalysts,hydrogenation products are formed in alkaline methanol solution,hence with lower than those obtained by the Au-based catalysts.Notably,it is necessary to match the hemiacetal fromation and aerobic oxidation of hemiacetal,which is relevant with the amount and strength of acid and redox sites.Consequently,this work can provide a good guidance for the further design of both catalysts and processes in future.
文摘The treatment of a multicomponent reversible reaction network is extremely complicated because largenumber of rate constants must be precisely determined and because the calculation based on these rateconstants is tedious.In order to reduce the degrees of freedom of the process,the authors propose a methodin which the reactor and the separator are regarded as a whole.Based on this approach,an N-componentreversible reaction system can be dealt with as a two—component system.Consequently,a simple and ac-cessible way of the apparent rate determination is suggested.For fiist-order reactions,an explicit,simplifiedexpression has been derived for both lumped and distributed parameter reaction systems.
基金supported by the National Key Research&Development Program of China(2020YFB0606404)National Natural Science Foundation of China(21908234)。
文摘Fischer-Tropsch synthesis(FTS)wax is a mixture of linear hydrocarbons with carbon number from C7 to C70+.Converting FTS wax into high-quality diesel(no sulfur and nitrogen contents)by hydrocracking technology is attractive in economy and practicability.Kinetic study of the hydrocracking of FTS wax in elementary step level is very challenging because of the huge amounts of reactions and species involved.Generation of reaction networks for hydrocracking of FTS wax in which the chain length goes up to C70 is described on the basis of Boolean adjacency matrixes.Each of the species(including paraffins,olefins and carbenium ions)involved in the elementary steps is represented digitally by using a(N+3)N matrix,in which a group of standardized numbering rules are designed to guarantee the unique identity of the species.Subsequently,the elementary steps are expressed by computer-aided matrix transformations in terms of proposed reaction rules.Dynamic memory allocation is used in species storage and a characteristic vector with nine elements is designed to store the key information of a(N+3)N matrix,which obviously reduces computer memory consumption and improves computing efficiency.The detailed reaction networks of FTS wax hydrocracking can be generated smoothly and accurately by the current method.The work is the basis of advanced elementary-step-level kinetic modeling.
基金financially supported by the National Natural Science Foundation of China(Nos.82172372 and 21904045)the Fundamental Research Funds for the Central Universities(2019kfyXJS169).
文摘Biological systems use intricate networks of chemical reactions to exchange information. How to simulate complex systems with simple strand-displacement reactions is crucial to broaden the application scenario of the DNA reaction network. Here, we report the artificial DNA reaction network to mimic the operation and function of biological information transfer via strand-displacement reaction. DNA is used as simple artificial analogs to schematize structures and transmit information. Using chemical synapses in neural networks as an example, we show that the proposed network enables core functions of biological systems, such as the long-term potential of synapses, which underpin learning and memory. Also, we performed the simple “silicon mimetic” to link electronic circuits to chemical network-based biological structures. As such, synaptic communication simulated by the DNA reaction network provides a complete demonstration for designing artificial reaction networks based on the essence of information interaction.
基金supported by the National Natural Science Foundation of China (Grant No. 60974139)partially supported by the Fundamental Research Funds for the Central Universities
文摘This paper investigates the global exponential stability of reaction-diffusion neural networks with discrete and distributed time-varying delays. By constructing a more general type of Lyapunov-Krasovskii functional combined with a free-weighting matrix approach and analysis techniques, delay-dependent exponential stability criteria are derived in the form of linear matrix inequalities. The obtained results are dependent on the size of the time-vaxying delays and the measure of the space, which are usually less conservative than delay-independent and space-independent ones. These results are easy to check, and improve upon the existing stability results. Some remarks are given to show the advantages of the obtained results over the previous results. A numerical example has been presented to show the usefulness of the derived linear matrix inequality （LMI）-based stability conditions.
文摘In this paper, the influence of the noise and delay upon the stability property of reaction-diffusion recurrent neural networks （RNNs） with the time-varying delay is discussed. The new and easily verifiable conditions to guarantee the mean value exponential stability of an equilibrium solution are derived. The rate of exponential convergence can be estimated by means of a simple computation based on these criteria.
基金supported by the National Natural Science Foundation of China(21476058,U21A20306,21506046 and 21978066)。
文摘The self-condensation of n-butanal is an important reaction for carbon-chain extension in the commercial production of 2-ethylhexanol.Moreover,aldol condensation is one of the important reactions for the synthesis of valuable organic chemicals or transportation fuels from biomass-derived platform compounds.So the investigation of the self-condensation of n-butanal is of significance in both academia and industry.This contribution reviewed the catalytic performance of heterogeneous catalysts in the self-condensation of n-butanal and the related reaction mechanism,network,and kinetics.The purpose of this review is to dedicate some help for further development of environmentally friendly catalysts and for a thorough comprehension of aldol condensation.
