In order to produce the hear-resistant inner layer of hot-forging die, the plasma spraying and plasma re-melting and plasma spray welding were adopted. Substrate material was W6Mo5Cr4V2, including 10%, 20%, 30% tungst...In order to produce the hear-resistant inner layer of hot-forging die, the plasma spraying and plasma re-melting and plasma spray welding were adopted. Substrate material was W6Mo5Cr4V2, including 10%, 20%, 30% tungsten carbide （WC） ceramic powder used as coating material to obtain different Nickel-based WC alloys coating. Micro-structure and micro-hardness analysis of the coating layer are conducted, as well as thermophysical properties for the coating layer were measured. The experimental results show that the coating prepared with 70%Ni60, 30%WC powder has the best properties with plasma spray welding, in which the micro-hardness can achieve 900HV, meanwhile it can improve the thermal property of hot-forging die dramatically.展开更多
Al_(0.2) CrFeNiCo and Al_(0.2) CrFeNiCu high entropy alloys were deposited with high velocity oxygen fuel(HVOF)on 316 L substrate.Later,a laser re-melting(LR)process was applied to enhancing the coating microstructure...Al_(0.2) CrFeNiCo and Al_(0.2) CrFeNiCu high entropy alloys were deposited with high velocity oxygen fuel(HVOF)on 316 L substrate.Later,a laser re-melting(LR)process was applied to enhancing the coating microstructure.LR process effects on dry sliding wear and oxidation behaviors were investigated.The mixture of powders with free elements led to the formation of inner oxides in HVOF coatings.The oxide and porosity were eliminated using LR.After LR,FCC was the dominant phase in both alloys,while BCC,sigma and Cr2 O3 phases were observed in Al_(0.2) CrFeNiCo alloy.The hardnesses of the Al_(0.2) CrFeNiCo and Al_(0.2) CrFeNiCu coatings after HVOF were HV 591 and HV 361,respectively.After LR,the hardnesses decreased to HV 259 and HV 270,respectively.Although HVOF coatings were most affected by increased load,they showed the highest wear resistance compared to other samples.The lowest wear resistance could be seen in the substrate.After the oxidation tests,HVOF coating layer was completely oxidized and also,the coating layer was delaminated from the substrate after 50 h oxidation due to its porous structure.LR coatings exhibited better oxidation performance.Al_(0.2) CrFeNiCo was dominantly composed of Cr2 O3,exhibiting a slower-growing tendency at the end of the oxidation tests,while Al_(0.2) CrFeNiCu was composed of spinel phases.展开更多
Further research on metallic materials for the super critical rotator and the main pipe line of a nuclear power station is very important for developing the nuclear power industry. In this study, the mathematical mode...Further research on metallic materials for the super critical rotator and the main pipe line of a nuclear power station is very important for developing the nuclear power industry. In this study, the mathematical model for 120 t large ingot was established, and the computer program ESR3D was developed to simulate the whole electro-slag re-melting (ESR) process. This includes the electrode melting, metallic droplet falling, metal pool forming, metal pool and slag pool rising and moving, installation of top crystallizer, ingot solidifying, etc. The simulated average melting rate of the electrode was in good agreement with that in practical production. The optimized parameters were used to produce 80-120 t large ingots, and the quality of the ingots satisfied the specifications of nuclear power and the super critical generating unit.展开更多
In order to produce the hear-resistant inner layer of hot-forging die, plasma spraying and plasma re-melting and plasma spray welding were adopted. Substrate material was W6Mo5Cr4V2, including 10%, 20%, 30% SiC cerami...In order to produce the hear-resistant inner layer of hot-forging die, plasma spraying and plasma re-melting and plasma spray welding were adopted. Substrate material was W6Mo5Cr4V2, including 10%, 20%, 30% SiC ceramic powder used as coating material to obtain different Ni-based SiC alloys coating. Micro-structure and micro-hardness analysis of the coating layer were followed, as well as thermophysical properties for the coating layer were measured. The experimental results show that the coating prepared with 70% Ni60, 30% SiC powder has best properties with plasma spray welding, in which the micro-hardness can achieve 1100 HV, meanwhile can improve the thermal property of hot-forging die dramatically.展开更多
FeCoCrNiAl high entropy alloy coatings were prepared by supersonic air-plasma spraying.The coatings were post-treated by vacuum heat treatment at 600 and 900°C,and laser re-melting with 300 W,respectively,to stud...FeCoCrNiAl high entropy alloy coatings were prepared by supersonic air-plasma spraying.The coatings were post-treated by vacuum heat treatment at 600 and 900°C,and laser re-melting with 300 W,respectively,to study the influence of different treatments on the structure and properties of the coatings.The phase constitution,microstructure and microhardness of the coatings after treatments were investigated using X-ray diffraction,scanning electron microscopy and energy dispersive spectrometry.Results showed that the as-sprayed coatings consisted of pure metal and Fe-Cr.The AlNi;phase was obtained after the vacuum heat treatment process.A body-centered cubic structure with less AlNi;could be found in the coating after the laser re-melting process.The average hardness values of the as-sprayed coating and the coatings with two different temperature vacuum heat treatments and with laser re-melting were 177,227,266 and 682 HV,respectively.This suggests that the vacuum heat treatment promoted the alloying process of the coatings,and contributed to the enhancement of the coating wear resistance.The laser re-melted coating showed the best wear resistance.展开更多
Micron-scale face-centered cubic titanium phase（named as δ phase） were noticed in the re-melted zone of laser surface re-melted commercially pure titanium plate.The morphology,sub-structure,orientation and distribu...Micron-scale face-centered cubic titanium phase（named as δ phase） were noticed in the re-melted zone of laser surface re-melted commercially pure titanium plate.The morphology,sub-structure,orientation and distribution of δ phase were investigated by scanning electron microscopy,electron back-scattered diffraction and transmission electron microscopy.Three kind formation processes of δ phase were put forward based on the investigation.The first one is α＇→δ transformation which takes place in single α＇grains and leads to the orientation relationship {001}δ//{0001}α＇〈 110 〉 δ//〈 112^-0 〉α＇.The second one is β→α＇＋ δ transformation which takes place at α＇/α＇interfaces and leads to the orientation relationship{001}δ//{11^-0}β〈110〉 δ//〈111〉β.The third one is another kind of β→α＇＋ δ transformation that takes place at α＇/α＇interfaces and leads to the orientation relationship{11^-1}δ//{11^-0}β〈 110 〉 δ//〈 111 〈 β.It is believed that the transformations of δ phase are stress assistant ones and in the present investigation,the phase transformation stress of β→α＇transformation acts as the assistant driving force for the formation of δ phase.展开更多
Re-melting process has been utilized to mitigate the residual stress level in the selective laser melting(SLM)process in recent years.However,the complex consolidation mechanism of powder and the different material be...Re-melting process has been utilized to mitigate the residual stress level in the selective laser melting(SLM)process in recent years.However,the complex consolidation mechanism of powder and the different material behavior after the first laser melting hinder the direct implementation of the re-melting process.In this work,the effects of re-melting on the temperature and residual stress evolution in the SLM process are investigated using a thermo-mechanically coupled finite element model.The degree of consolidation is incorporated in the energy balance equation based on the thermodynamically-consistent phase-field approach.The drastic change of material properties due to the variation of temperature and material state is also considered.Using the proposed simulation framework,the single-track scanning is simulated first to predict the melt pool dimension and validate the proposed model with the existing experimental data.The obtained thermal histories reveal that the highest cooling rate is observed at the end of the local solidification time which acts as an important indicator for the alleviation of temperature gradient.Then,the scanning of a whole single layer that consists of multiple tracks is simulated to observe the stress evolution with several re-melting processes.After the full melting of powder material in the first scanning process,the increase of residual stress level is observed with one remelting cycle.Moreover,the predicted stress level with the re-melting process shows the variation trend attributable to the accumulated heat in the tracks.The numerical issues and the detailed implementation process are also introduced in this paper.展开更多
Polymer coating was widely used as a protective coating on Mg alloy stent due to its excellent deformability. However, the polymer coating with lots of macro-and micro-holes after solvent evaporation during forming pr...Polymer coating was widely used as a protective coating on Mg alloy stent due to its excellent deformability. However, the polymer coating with lots of macro-and micro-holes after solvent evaporation during forming process would make corrosion medium permeate easier and decrease the corrosion resistance of Mg alloy stent. In this study, a novel critical re-melting method was adopted to improve the polymer coating densification, which was evaluated by the surface morphology of coating. The corrosion resistance of Mg alloy stent after critical re-melting treatment was examined by the electrochemical and immersion tests. The results indicated that the corrosion resistance of Mg alloy stent with polymer coating was improved significantly by polymer critical re-melting treatment.展开更多
In order to prepare heatresistant inner layer of hot-forging die, plasma spraying, plasma re- melting and plasma spray welding were adopted. Cr3C2 coatings of Ni-Based were prepared respectively with 10%, 20% and 30% ...In order to prepare heatresistant inner layer of hot-forging die, plasma spraying, plasma re- melting and plasma spray welding were adopted. Cr3C2 coatings of Ni-Based were prepared respectively with 10%, 20% and 30% Cr3C2 powder and W6Mo5Cr4V2 substrate. The coating microstructure analysis, the micro-hardness test, and the measurement of thermal parameters of coating were conducted. The experimental results show that the coating has the better thermo-physical property by using plasma spray welding method with the powder ratio of 90% Ni60 and 10% Cr3C2, and by this way the micro-hardness of coating can achieve 1100 HV.展开更多
基金Funded by the National Natural Science Foundation of China(No.50675165)the National Key Technology R&D Program(No.2006BAF02A29)
文摘In order to produce the hear-resistant inner layer of hot-forging die, the plasma spraying and plasma re-melting and plasma spray welding were adopted. Substrate material was W6Mo5Cr4V2, including 10%, 20%, 30% tungsten carbide （WC） ceramic powder used as coating material to obtain different Nickel-based WC alloys coating. Micro-structure and micro-hardness analysis of the coating layer are conducted, as well as thermophysical properties for the coating layer were measured. The experimental results show that the coating prepared with 70%Ni60, 30%WC powder has the best properties with plasma spray welding, in which the micro-hardness can achieve 900HV, meanwhile it can improve the thermal property of hot-forging die dramatically.
基金financially supported by Scientific Research Funds of Bart?n University(No.2019-FEN-A-012,2019-FEN-A-013)。
文摘Al_(0.2) CrFeNiCo and Al_(0.2) CrFeNiCu high entropy alloys were deposited with high velocity oxygen fuel(HVOF)on 316 L substrate.Later,a laser re-melting(LR)process was applied to enhancing the coating microstructure.LR process effects on dry sliding wear and oxidation behaviors were investigated.The mixture of powders with free elements led to the formation of inner oxides in HVOF coatings.The oxide and porosity were eliminated using LR.After LR,FCC was the dominant phase in both alloys,while BCC,sigma and Cr2 O3 phases were observed in Al_(0.2) CrFeNiCo alloy.The hardnesses of the Al_(0.2) CrFeNiCo and Al_(0.2) CrFeNiCu coatings after HVOF were HV 591 and HV 361,respectively.After LR,the hardnesses decreased to HV 259 and HV 270,respectively.Although HVOF coatings were most affected by increased load,they showed the highest wear resistance compared to other samples.The lowest wear resistance could be seen in the substrate.After the oxidation tests,HVOF coating layer was completely oxidized and also,the coating layer was delaminated from the substrate after 50 h oxidation due to its porous structure.LR coatings exhibited better oxidation performance.Al_(0.2) CrFeNiCo was dominantly composed of Cr2 O3,exhibiting a slower-growing tendency at the end of the oxidation tests,while Al_(0.2) CrFeNiCu was composed of spinel phases.
文摘Further research on metallic materials for the super critical rotator and the main pipe line of a nuclear power station is very important for developing the nuclear power industry. In this study, the mathematical model for 120 t large ingot was established, and the computer program ESR3D was developed to simulate the whole electro-slag re-melting (ESR) process. This includes the electrode melting, metallic droplet falling, metal pool forming, metal pool and slag pool rising and moving, installation of top crystallizer, ingot solidifying, etc. The simulated average melting rate of the electrode was in good agreement with that in practical production. The optimized parameters were used to produce 80-120 t large ingots, and the quality of the ingots satisfied the specifications of nuclear power and the super critical generating unit.
基金Funded by the National Natural Science Foundation of China (No. 50675165)
文摘In order to produce the hear-resistant inner layer of hot-forging die, plasma spraying and plasma re-melting and plasma spray welding were adopted. Substrate material was W6Mo5Cr4V2, including 10%, 20%, 30% SiC ceramic powder used as coating material to obtain different Ni-based SiC alloys coating. Micro-structure and micro-hardness analysis of the coating layer were followed, as well as thermophysical properties for the coating layer were measured. The experimental results show that the coating prepared with 70% Ni60, 30% SiC powder has best properties with plasma spray welding, in which the micro-hardness can achieve 1100 HV, meanwhile can improve the thermal property of hot-forging die dramatically.
基金financially supported by National Natural Science Foundation of China (Nos.51301112 and 51401129)China Postdoctoral Science Foundation (2015M571327)+1 种基金the Natural Science Foundation of Liaoning Province(No.201602553)the Science Research Program of Education Department in Liaoning Province(No.L2014048)
文摘FeCoCrNiAl high entropy alloy coatings were prepared by supersonic air-plasma spraying.The coatings were post-treated by vacuum heat treatment at 600 and 900°C,and laser re-melting with 300 W,respectively,to study the influence of different treatments on the structure and properties of the coatings.The phase constitution,microstructure and microhardness of the coatings after treatments were investigated using X-ray diffraction,scanning electron microscopy and energy dispersive spectrometry.Results showed that the as-sprayed coatings consisted of pure metal and Fe-Cr.The AlNi;phase was obtained after the vacuum heat treatment process.A body-centered cubic structure with less AlNi;could be found in the coating after the laser re-melting process.The average hardness values of the as-sprayed coating and the coatings with two different temperature vacuum heat treatments and with laser re-melting were 177,227,266 and 682 HV,respectively.This suggests that the vacuum heat treatment promoted the alloying process of the coatings,and contributed to the enhancement of the coating wear resistance.The laser re-melted coating showed the best wear resistance.
基金financially supported by the Natural Science Foundation of Beijing (Grant No.Z140002)
文摘Micron-scale face-centered cubic titanium phase（named as δ phase） were noticed in the re-melted zone of laser surface re-melted commercially pure titanium plate.The morphology,sub-structure,orientation and distribution of δ phase were investigated by scanning electron microscopy,electron back-scattered diffraction and transmission electron microscopy.Three kind formation processes of δ phase were put forward based on the investigation.The first one is α＇→δ transformation which takes place in single α＇grains and leads to the orientation relationship {001}δ//{0001}α＇〈 110 〉 δ//〈 112^-0 〉α＇.The second one is β→α＇＋ δ transformation which takes place at α＇/α＇interfaces and leads to the orientation relationship{001}δ//{11^-0}β〈110〉 δ//〈111〉β.The third one is another kind of β→α＇＋ δ transformation that takes place at α＇/α＇interfaces and leads to the orientation relationship{11^-1}δ//{11^-0}β〈 110 〉 δ//〈 111 〈 β.It is believed that the transformations of δ phase are stress assistant ones and in the present investigation,the phase transformation stress of β→α＇transformation acts as the assistant driving force for the formation of δ phase.
基金the Korea Evaluation Institute of Industrial Technology(KEIT)grant funded by the Korea government(MOTIE,https://itech.keit.re.kr/index.do#00010000)(No.20004662,Industrial Technology Innovation Program,Grantee:GJY)Institute of Engineering Research(Grantee:GJY)at Seoul National University(https://www.snu.ac.kr/).The authors are grateful for their supports.
文摘Re-melting process has been utilized to mitigate the residual stress level in the selective laser melting(SLM)process in recent years.However,the complex consolidation mechanism of powder and the different material behavior after the first laser melting hinder the direct implementation of the re-melting process.In this work,the effects of re-melting on the temperature and residual stress evolution in the SLM process are investigated using a thermo-mechanically coupled finite element model.The degree of consolidation is incorporated in the energy balance equation based on the thermodynamically-consistent phase-field approach.The drastic change of material properties due to the variation of temperature and material state is also considered.Using the proposed simulation framework,the single-track scanning is simulated first to predict the melt pool dimension and validate the proposed model with the existing experimental data.The obtained thermal histories reveal that the highest cooling rate is observed at the end of the local solidification time which acts as an important indicator for the alleviation of temperature gradient.Then,the scanning of a whole single layer that consists of multiple tracks is simulated to observe the stress evolution with several re-melting processes.After the full melting of powder material in the first scanning process,the increase of residual stress level is observed with one remelting cycle.Moreover,the predicted stress level with the re-melting process shows the variation trend attributable to the accumulated heat in the tracks.The numerical issues and the detailed implementation process are also introduced in this paper.
基金financially supported by National Key Research and Development Program of China(No.2016YFC1102404)
文摘Polymer coating was widely used as a protective coating on Mg alloy stent due to its excellent deformability. However, the polymer coating with lots of macro-and micro-holes after solvent evaporation during forming process would make corrosion medium permeate easier and decrease the corrosion resistance of Mg alloy stent. In this study, a novel critical re-melting method was adopted to improve the polymer coating densification, which was evaluated by the surface morphology of coating. The corrosion resistance of Mg alloy stent after critical re-melting treatment was examined by the electrochemical and immersion tests. The results indicated that the corrosion resistance of Mg alloy stent with polymer coating was improved significantly by polymer critical re-melting treatment.
文摘In order to prepare heatresistant inner layer of hot-forging die, plasma spraying, plasma re- melting and plasma spray welding were adopted. Cr3C2 coatings of Ni-Based were prepared respectively with 10%, 20% and 30% Cr3C2 powder and W6Mo5Cr4V2 substrate. The coating microstructure analysis, the micro-hardness test, and the measurement of thermal parameters of coating were conducted. The experimental results show that the coating has the better thermo-physical property by using plasma spray welding method with the powder ratio of 90% Ni60 and 10% Cr3C2, and by this way the micro-hardness of coating can achieve 1100 HV.
