This paper covers the detailed version of the potential raw material deposits at Darukhula and the adjacent areas of Nizampur, the manufacturing of high-strength Portland cement samples from the same material and comp...This paper covers the detailed version of the potential raw material deposits at Darukhula and the adjacent areas of Nizampur, the manufacturing of high-strength Portland cement samples from the same material and comparison of the physical and chemical parameters for resulting cement with British and Pakistan standard specifications, which include compressive strength, setting time, consistency, lechatelier expansion, Blaine and insoluble residue. It was found that the raw material available in the study area meets the standard specifications and the area is feasible for the cement plant installation. The area can provide raw material which is quite sufficient for the running of a cement plant.展开更多
Laser-induced breakdown spectroscopy(LIBS) is a qualitative and quantitative analytical technique with great potential in the cement industrial analysis. Calibration curve(CC) and support vector regression(SVR) method...Laser-induced breakdown spectroscopy(LIBS) is a qualitative and quantitative analytical technique with great potential in the cement industrial analysis. Calibration curve(CC) and support vector regression(SVR) methods coupled with LIBS technology were applied for the quantification of three types of cement raw meal samples to compare their analytical concentration range and the ability to reduce matrix effects, respectively. To reduce the effects of fluctuations of the pulse-to-pulse, the unstable ablation and improve the reproducibility, all of the analysis line intensities were normalized on a per-detector basis. The prediction results of the elements of interest in the three types of samples, Ca, Si, Fe, Al, Mg, Na, K and Ti, were compared with the results of the wet chemical analysis. The average relative error(ARE),relative standard deviation(RSD) and root mean squared error of prediction(RMSEP) were employed to investigate and evaluate the prediction accuracy and stability of the two prediction methods. The maximum average ARE of the CC and SVR methods is 34.62% instead of 6.13%,RSD is 40.89% instead of 7.60% and RMSEP is 1.34% instead of 0.43%. The results show that SVR method can accurately analyze samples within a wider concentration range and reduce the matrix effects, and LIBS coupled with it for a rapid, stable and accurate quantification of different types of cement raw meal samples is promising.展开更多
Resource modeling plays a crucial role in raw material quality management for cement manufacturing.Research has shown that geological uncertainty in resource modeling is inevitable and results in risk to future extrac...Resource modeling plays a crucial role in raw material quality management for cement manufacturing.Research has shown that geological uncertainty in resource modeling is inevitable and results in risk to future extraction planning and operations of the cement plant.This study aims to assess the geological uncertainty and associated risk in modeling a cement raw material deposit in southern Vietnam.For this deposit,soil,clay,laterite,and limestone are the four primary rock types,controlling the occurrence and spatial distribution of chemical grades.In this study,hierarchical simulation method was used to evaluate the uncertainty.Rock types were first simulated,and the chemical grades conditioning to the rock types were then generated.The results demonstrated the capability of the hierarchical simulation approach to incorporate the uncertainty of rock types in resource modeling and to allow evaluating the risks in providing the desired raw material for the cement plant in the form of grade-tonnage curves.展开更多
X-ray fluorescence (XRF) analysis utilizes particle size which is resulted from milling of a material. The milling ensures uniform and fine grained powder. The finer and more uniform the particle size is, the better t...X-ray fluorescence (XRF) analysis utilizes particle size which is resulted from milling of a material. The milling ensures uniform and fine grained powder. The finer and more uniform the particle size is, the better the result and easier it is for material quality control. To ensure uniformity in particle size and finer powder, a comparative analysis was conducted with different grinding aids and pressed pellet method was used in obtaining analysis results. Pressed pellets of cement raw meal sample milled with different grinding aids (graphite, aspirin and lithium borate) were subjected to XRF. Graphite produced better particle size uniformity with a corresponding standard deviation that made quality control of raw meal easier and better than aspirin and lithium borate.展开更多
Cement is a kind of colloid material. This paper introduces a model of raw material proportion and quadratic programming for solving the model when three kinds of raw materials are mixed. The calculation of the raw ma...Cement is a kind of colloid material. This paper introduces a model of raw material proportion and quadratic programming for solving the model when three kinds of raw materials are mixed. The calculation of the raw material proportion is easy, and its result is reliable. This model is apt to be realized on micro-computer. This paper indicates the defects of the least square method and compares these two methods through existing instance.展开更多
The composition of cement raw materials was detected by near-infrared spectroscopy.It was found that the BiPLS-SiPLS method selected the NIR spectral band of cement raw materials,and the partial least squares regressi...The composition of cement raw materials was detected by near-infrared spectroscopy.It was found that the BiPLS-SiPLS method selected the NIR spectral band of cement raw materials,and the partial least squares regression algorithm was adopted to establish a quantitative correction model of cement raw materials with good prediction effect.The root-mean-square errors of SiO_(2),Al_(2)O_(3),Fe_(2)O_(3) and CaO calibration were 0.142,0.072,0.034 and 0.188 correspondingly.The results show that the NIR spectroscopy method can detect the composition of cement raw meal rapidly and accurately,which provides a new perspective for the composition detection of cement raw meal.展开更多
Limestone and clay samples were collected from Darukhula and adjoining areas of the Nizampur District,Nowshera,N.W.F.P.,Pakistan,and analyzed for different parameters in order to search for new reserves of suitable ma...Limestone and clay samples were collected from Darukhula and adjoining areas of the Nizampur District,Nowshera,N.W.F.P.,Pakistan,and analyzed for different parameters in order to search for new reserves of suitable material for the manufacture of different types of cements in N.W.F.P.It was found that the area under study contains three types of limestones,including high grade limestone,Darukhula limestone and siliceous limestone,which contain 53%,49.03% and 45.19% CaO,respectively,and three types of clay,including maroon color,yellow to yellowish-green color and green color clay containing 57.76%,65.47% and 61.24% SiO2,respectively.Chemical analysis of the limestone and clay samples collected from the deposits in the area under study showed that all the elements found in these samples are within the range of permissible limits for the production of high-strength Portland cement,sulphate resisting cement and white cement.This paper covers the detailed version of the potential raw material deposits at Darukhula and adjoining areas of the Nizampur District.展开更多
The traditional alumina-silicate raw materials, for example, clays, in the precalcining technique of cement production, have been replaced by low grade and high silica content sandstones, shales, and industrial waste ...The traditional alumina-silicate raw materials, for example, clays, in the precalcining technique of cement production, have been replaced by low grade and high silica content sandstones, shales, and industrial waste residues, including fly ashes, slag, and others. The results are the change of compositions and characteristics of raw materials applied and a great effect on cement calcination process and clinker formation. In this work, the cement clinker formation process of different alumina-silicate raw materials to replace clay raw material was studied by chemical analysis, X-ray diffraction, differential thermal analysis, and high temperature microscope based on the characteristics of the alumina-silicate raw materials. The formation heat of the clinker was determined by the acid dissolution method. Influence of different alumina-silicate raw materials on the clinker burnability and formation process was studied. The results show that the changing of alumina- silicate raw materials, especially using industrial waste residues, can reduce the formation temperature of high temperature liquid phases, improve the burnability of raw materials, reduce the formation temperature and formation heat of clinker. And this study also observed the formation temperature and transformation of high temperature liquid phases in the heating process of raw materials by high temperature microscope.展开更多
文摘This paper covers the detailed version of the potential raw material deposits at Darukhula and the adjacent areas of Nizampur, the manufacturing of high-strength Portland cement samples from the same material and comparison of the physical and chemical parameters for resulting cement with British and Pakistan standard specifications, which include compressive strength, setting time, consistency, lechatelier expansion, Blaine and insoluble residue. It was found that the raw material available in the study area meets the standard specifications and the area is feasible for the cement plant installation. The area can provide raw material which is quite sufficient for the running of a cement plant.
基金supported by National Natural Science Foundation of China (Grant Nos. 61505223, 41775128)the Knowledge Innovation Program of the Chinese Academy of Sciences (Grant No. Y03RC21124)+1 种基金the External Cooperation Program of Chinese Academy of Sciences (Grant No. GJHZ1726)the project of China State Key Lab. of Power System (Grant Nos. SKLD18KM11, SKLD18M12)
文摘Laser-induced breakdown spectroscopy(LIBS) is a qualitative and quantitative analytical technique with great potential in the cement industrial analysis. Calibration curve(CC) and support vector regression(SVR) methods coupled with LIBS technology were applied for the quantification of three types of cement raw meal samples to compare their analytical concentration range and the ability to reduce matrix effects, respectively. To reduce the effects of fluctuations of the pulse-to-pulse, the unstable ablation and improve the reproducibility, all of the analysis line intensities were normalized on a per-detector basis. The prediction results of the elements of interest in the three types of samples, Ca, Si, Fe, Al, Mg, Na, K and Ti, were compared with the results of the wet chemical analysis. The average relative error(ARE),relative standard deviation(RSD) and root mean squared error of prediction(RMSEP) were employed to investigate and evaluate the prediction accuracy and stability of the two prediction methods. The maximum average ARE of the CC and SVR methods is 34.62% instead of 6.13%,RSD is 40.89% instead of 7.60% and RMSEP is 1.34% instead of 0.43%. The results show that SVR method can accurately analyze samples within a wider concentration range and reduce the matrix effects, and LIBS coupled with it for a rapid, stable and accurate quantification of different types of cement raw meal samples is promising.
文摘Resource modeling plays a crucial role in raw material quality management for cement manufacturing.Research has shown that geological uncertainty in resource modeling is inevitable and results in risk to future extraction planning and operations of the cement plant.This study aims to assess the geological uncertainty and associated risk in modeling a cement raw material deposit in southern Vietnam.For this deposit,soil,clay,laterite,and limestone are the four primary rock types,controlling the occurrence and spatial distribution of chemical grades.In this study,hierarchical simulation method was used to evaluate the uncertainty.Rock types were first simulated,and the chemical grades conditioning to the rock types were then generated.The results demonstrated the capability of the hierarchical simulation approach to incorporate the uncertainty of rock types in resource modeling and to allow evaluating the risks in providing the desired raw material for the cement plant in the form of grade-tonnage curves.
文摘X-ray fluorescence (XRF) analysis utilizes particle size which is resulted from milling of a material. The milling ensures uniform and fine grained powder. The finer and more uniform the particle size is, the better the result and easier it is for material quality control. To ensure uniformity in particle size and finer powder, a comparative analysis was conducted with different grinding aids and pressed pellet method was used in obtaining analysis results. Pressed pellets of cement raw meal sample milled with different grinding aids (graphite, aspirin and lithium borate) were subjected to XRF. Graphite produced better particle size uniformity with a corresponding standard deviation that made quality control of raw meal easier and better than aspirin and lithium borate.
文摘Cement is a kind of colloid material. This paper introduces a model of raw material proportion and quadratic programming for solving the model when three kinds of raw materials are mixed. The calculation of the raw material proportion is easy, and its result is reliable. This model is apt to be realized on micro-computer. This paper indicates the defects of the least square method and compares these two methods through existing instance.
基金Funded by the National Natural Science Foundation of China (No. 62073153)The Major Scientific and Technological Innovation Projects in Shandong Province (No.2019JZZY010448)The Key Research and Development Plan of Shandong Province of China (No.2019GSF109018)。
文摘The composition of cement raw materials was detected by near-infrared spectroscopy.It was found that the BiPLS-SiPLS method selected the NIR spectral band of cement raw materials,and the partial least squares regression algorithm was adopted to establish a quantitative correction model of cement raw materials with good prediction effect.The root-mean-square errors of SiO_(2),Al_(2)O_(3),Fe_(2)O_(3) and CaO calibration were 0.142,0.072,0.034 and 0.188 correspondingly.The results show that the NIR spectroscopy method can detect the composition of cement raw meal rapidly and accurately,which provides a new perspective for the composition detection of cement raw meal.
文摘Limestone and clay samples were collected from Darukhula and adjoining areas of the Nizampur District,Nowshera,N.W.F.P.,Pakistan,and analyzed for different parameters in order to search for new reserves of suitable material for the manufacture of different types of cements in N.W.F.P.It was found that the area under study contains three types of limestones,including high grade limestone,Darukhula limestone and siliceous limestone,which contain 53%,49.03% and 45.19% CaO,respectively,and three types of clay,including maroon color,yellow to yellowish-green color and green color clay containing 57.76%,65.47% and 61.24% SiO2,respectively.Chemical analysis of the limestone and clay samples collected from the deposits in the area under study showed that all the elements found in these samples are within the range of permissible limits for the production of high-strength Portland cement,sulphate resisting cement and white cement.This paper covers the detailed version of the potential raw material deposits at Darukhula and adjoining areas of the Nizampur District.
基金Funded by the National Basic Research Program of China("973"Program)(No.2009CB623102)the National High Technology Research and Development Program of China("863"Program)(No.2013AA031602)
文摘The traditional alumina-silicate raw materials, for example, clays, in the precalcining technique of cement production, have been replaced by low grade and high silica content sandstones, shales, and industrial waste residues, including fly ashes, slag, and others. The results are the change of compositions and characteristics of raw materials applied and a great effect on cement calcination process and clinker formation. In this work, the cement clinker formation process of different alumina-silicate raw materials to replace clay raw material was studied by chemical analysis, X-ray diffraction, differential thermal analysis, and high temperature microscope based on the characteristics of the alumina-silicate raw materials. The formation heat of the clinker was determined by the acid dissolution method. Influence of different alumina-silicate raw materials on the clinker burnability and formation process was studied. The results show that the changing of alumina- silicate raw materials, especially using industrial waste residues, can reduce the formation temperature of high temperature liquid phases, improve the burnability of raw materials, reduce the formation temperature and formation heat of clinker. And this study also observed the formation temperature and transformation of high temperature liquid phases in the heating process of raw materials by high temperature microscope.
