To overcome the shortcomings of the traditional passive ranging technology based on image, such as poor ranging accuracy, low reliability and complex system, a new visual passive ranging method based on re-entrant coa...To overcome the shortcomings of the traditional passive ranging technology based on image, such as poor ranging accuracy, low reliability and complex system, a new visual passive ranging method based on re-entrant coaxial optical path is presented. The target image is obtained using double cameras with coaxial optical path. Since there is imaging optical path difference between the cameras, the images are different. In comparison of the image differences, the target range could be reversed. The principle of the ranging method and the ranging model are described. The relationship among parameters in the ranging process is analyzed quantitatively. Meanwhile,the system composition and technical realization scheme are also presented. Also, the principle of the method is verified by the equivalent experiment. The experimental results show that the design scheme is correct and feasible with good robustness. Generally, the ranging error is less than 10% with good convergence. The optical path is designed in a re-entrant mode to reduce the volume and weight of the system. Through the coaxial design,the visual passive range of the targets with any posture can be obtained in real time. The system can be widely used in electro-optical countermeasure and concealed photoelectric detection.展开更多
Optical phase transfer via fiber optics is the most effective method for optical frequency standard comparison on the scale below thousands of kilometers.However,the monotonic phase discrimination range of conventiona...Optical phase transfer via fiber optics is the most effective method for optical frequency standard comparison on the scale below thousands of kilometers.However,the monotonic phase discrimination range of conventional optical phase-locked loops is limited,and link delays restrict the control bandwidth,which makes it a challenge to achieve a continuously reliable optical link.This paper presents an event-timing-based phase detection method that overcomes the monotonic phase discrimination range limitation of conventional phase-locked loops through dual-edge timestamp recording,achieving an optical phase measurement resolution on the order of 10 attoseconds.With such a technique,we established a 7-segment-cascaded optical link over 1402km of commercial fiber while sharing dense wavelength division multiplexing(DWDM)channels with live telecom traffic.The system maintained continuous operation for 11.7 days without phase cycle slips despite encountering 15 km aerial fiber noise up to 21000 rad^(2)·Hz^(−1)·km^(−1)at 1 Hz.Relative instabilities of the link are 3.7×10^(−15)at 1 s and 3.9×10^(−20)at 100000 s.展开更多
A new and enantioselective liquid chromatographic method was developed for estimation of S-Linagliptin in Linagliptin (LINA) drug substances. The desired enantiomeric separation was achieved on Chiralpak AD-H (250*4.6...A new and enantioselective liquid chromatographic method was developed for estimation of S-Linagliptin in Linagliptin (LINA) drug substances. The desired enantiomeric separation was achieved on Chiralpak AD-H (250*4.6 mm*5 μm) column with the mobile phase composition of ethanol, methanol and diethylamine in a ratio of 90:10:0.1 (v/v/v) with flow rate of 0.5 mL·min<sup>-</sup><sup>1</sup> and column oven temperature 30°C and the eluted compounds were monitored at 225 nm. In the proposed chiral method, USP resolutions between both the enantiomers were more than 5.0. Limit of detection and Limit of quantitation of S-LINA was found to be 0.03 μg·mL<sup>-1</sup> and 0.10 μg·mL<sup>-1</sup> respectively. Linearity study was conducted from LOQ to 150% and correlation coefficient found to be 0.9997. Accuracy was within the range of 98.6% to 101.5%. To prove selectivity power of the method specificity study was conducted by subjecting drug substance to acid, base, hydrolysis, oxidation and photolysis and ensured the peak purity of analyte in degraded samples. Moreover, the method has been fully validated as per ICH guidelines. The proposed method is precise, accurate, linear, rugged, robust and suitable for accurate quantification of S-LINA in LINA drug substance.展开更多
Wavelet method is often used in analyzing trend and period of time sequence. When using wavelet method one serious problem is different chosen wavelet basis and scale would lead to different results. Sometimes, the re...Wavelet method is often used in analyzing trend and period of time sequence. When using wavelet method one serious problem is different chosen wavelet basis and scale would lead to different results. Sometimes, the results vary greatly. To overcome this problem and to improve the accuracy and efficiency, a new method denoted by Natural-based Wavelet Method is introduced and extended. It can be proved that the proposed method in fact is a special class of discrete wavelet. At first, two numerical examples are designed to show the capacity of the novel method. Second, this method is applied to a precipitation series. According to wavelet analysis and short-range precipitation prediction, this precipitation exists a faintly increasing trend. Through the analysis, the studied precipitation has two major periods: 11 and 41 years. The results validate that the Natural-based Wavelet Method used in application of multi-complicated observed data is suitable. It is easy to write the source code of the proposed method. When new information appears, new information can be easily added into the original sequence, this is another advantage of the proposed method.展开更多
In this work,we extend the recently proposed adaptive phase field method to model fracture in orthotropic functionally graded materials(FGMs).A recovery type error indicator combined with quadtree decomposition is emp...In this work,we extend the recently proposed adaptive phase field method to model fracture in orthotropic functionally graded materials(FGMs).A recovery type error indicator combined with quadtree decomposition is employed for adaptive mesh refinement.The proposed approach is capable of capturing the fracture process with a localized mesh refinement that provides notable gains in computational efficiency.The implementation is validated against experimental data and other numerical experiments on orthotropic materials with different material orientations.The results reveal an increase in the stiffness and the maximum force with increasing material orientation angle.The study is then extended to the analysis of orthotropic FGMs.It is observed that,if the gradation in fracture properties is neglected,the material gradient plays a secondary role,with the fracture behaviour being dominated by the orthotropy of the material.However,when the toughness increases along the crack propagation path,a substantial gain in fracture resistance is observed.展开更多
The thermodynamic properties and the phase diagrams of the systems Ga-M (M = In, Sb, Ph) were critically re-assessed and optimized employing the software package ChemSage for the calculation of thermodynamicequilibria...The thermodynamic properties and the phase diagrams of the systems Ga-M (M = In, Sb, Ph) were critically re-assessed and optimized employing the software package ChemSage for the calculation of thermodynamicequilibria. The Redlich-Kister/Margules formalism was employed for all solution phases and sets of self-consistentthermodynamic parameters were obtained. The results of re-assessment and optimization are compared with previous work, they are in excellent agreement with most experimental data.展开更多
The complex Red River fault zone(RRFZ),which is situated in the southwestern region of China and separates the Indochina plate and South China blocks,has diverse seismic activities in different segments.To reveal the ...The complex Red River fault zone(RRFZ),which is situated in the southwestern region of China and separates the Indochina plate and South China blocks,has diverse seismic activities in different segments.To reveal the detailed geometric characteristics of the RRFZ at different sections and to better understand the seismogenic environment,in 2022 and 2023 we deployed 7 seismic dense linear arrays,consisting of 574 nodal stations,across the RRFZ in the northern and southern segments near the towns Midu,Gasa,Zhega,Dazhai,Xinzhai,and Taoyuan.The linear arrays,which extend from 2.4 to 12.5 km in length with station intervals ranging between 40 and140 m,recorded seismic ambient noise for approximately one month.Using the extended range phase shift method,we extract the phase velocity dispersion curves of the Rayleigh waves between 0.9 and 10 Hz,which are then used to invert for the high resolution shearwave velocity structures across the RRFZ beneath the linear arrays.The key findings are:(1)the 7 imaged sections of the RRFZ exhibit quite similar structures,with higher velocities on the SW side and lower velocities on the NE side;the velocity variation is consistent with the surface geological structures along the RRFZ;(2)the shear-wave velocities on the SW side of the RRFZ at the northern Midu section and southern Gasa-Dazhai sections are generally higher than their counterparts in the southern Xinzhai-Taoyuan sections,which reflects lithological variations from the marble-dominated Paleoproterozoic Along basement to the gneiss dominated Paleoproterozoic Qingshuihe basement;(3)from the northern Midu section to the southern region where the RRFZ intersects with the Xiaojiang Fault,the major faults of the RRFZ exhibit a consistent high-angle,NE-dipping structure;(4)the low shear-wave velocities immediately to the NE of the velocity boundary may indicate a faulted zone due to long-term shearing,where excessive amplifications of ground motions could occur.This study provides new insights into the characteristics of the shallow structures of the RRFZ.展开更多
间接飞行时间(indirect time of flight,iTOF)相机在三维环境感知领域有着广泛的应用前景。根据iTOF相机成像原理,当曝光时间过大导致相机工作在非线性区时,解算的深度信息也会引入额外的偏差,从而影响测量准确度。为了进一步提高飞行...间接飞行时间(indirect time of flight,iTOF)相机在三维环境感知领域有着广泛的应用前景。根据iTOF相机成像原理,当曝光时间过大导致相机工作在非线性区时,解算的深度信息也会引入额外的偏差,从而影响测量准确度。为了进一步提高飞行时间相机的应用精度,根据飞行时间相机的光学成像机理,提出一种针对飞行时间相机的性能参数测量方法,通过实验和计算间接得到飞行时间深度相机的系统增益等性能参数,将其代入飞行时间相机的光学成像模型,即可得到距离与相机输出灰度值的对应曲线。建模与实验结果的相对误差可以达到20%以内,平均相对误差为0.16%。这些性能参数和仿真模型用于指导iTOF相机在不同场景使用时的积分时间选择,可以有效解决因使用不当引入非线性误差而降低距离测量精度的问题。展开更多
基金Supported by the National Basic Research Program of China under Grant No 2014CB340102
文摘To overcome the shortcomings of the traditional passive ranging technology based on image, such as poor ranging accuracy, low reliability and complex system, a new visual passive ranging method based on re-entrant coaxial optical path is presented. The target image is obtained using double cameras with coaxial optical path. Since there is imaging optical path difference between the cameras, the images are different. In comparison of the image differences, the target range could be reversed. The principle of the ranging method and the ranging model are described. The relationship among parameters in the ranging process is analyzed quantitatively. Meanwhile,the system composition and technical realization scheme are also presented. Also, the principle of the method is verified by the equivalent experiment. The experimental results show that the design scheme is correct and feasible with good robustness. Generally, the ranging error is less than 10% with good convergence. The optical path is designed in a re-entrant mode to reduce the volume and weight of the system. Through the coaxial design,the visual passive range of the targets with any posture can be obtained in real time. The system can be widely used in electro-optical countermeasure and concealed photoelectric detection.
基金supported by the National Key Research and Development Program of China(Grant No.2020YFC2200103)the Shandong Provincial Natural Science Foundation(Grant Nos.ZR2022LLZ006 and ZR2022LLZ011)+1 种基金the Innovation Program for Quantum Science and Technology(Grant Nos.2021ZD0300904 and 2021ZD0300903)the Key R&D Plan of Shandong Province(Grant No.2023CXPT105)。
文摘Optical phase transfer via fiber optics is the most effective method for optical frequency standard comparison on the scale below thousands of kilometers.However,the monotonic phase discrimination range of conventional optical phase-locked loops is limited,and link delays restrict the control bandwidth,which makes it a challenge to achieve a continuously reliable optical link.This paper presents an event-timing-based phase detection method that overcomes the monotonic phase discrimination range limitation of conventional phase-locked loops through dual-edge timestamp recording,achieving an optical phase measurement resolution on the order of 10 attoseconds.With such a technique,we established a 7-segment-cascaded optical link over 1402km of commercial fiber while sharing dense wavelength division multiplexing(DWDM)channels with live telecom traffic.The system maintained continuous operation for 11.7 days without phase cycle slips despite encountering 15 km aerial fiber noise up to 21000 rad^(2)·Hz^(−1)·km^(−1)at 1 Hz.Relative instabilities of the link are 3.7×10^(−15)at 1 s and 3.9×10^(−20)at 100000 s.
文摘A new and enantioselective liquid chromatographic method was developed for estimation of S-Linagliptin in Linagliptin (LINA) drug substances. The desired enantiomeric separation was achieved on Chiralpak AD-H (250*4.6 mm*5 μm) column with the mobile phase composition of ethanol, methanol and diethylamine in a ratio of 90:10:0.1 (v/v/v) with flow rate of 0.5 mL·min<sup>-</sup><sup>1</sup> and column oven temperature 30°C and the eluted compounds were monitored at 225 nm. In the proposed chiral method, USP resolutions between both the enantiomers were more than 5.0. Limit of detection and Limit of quantitation of S-LINA was found to be 0.03 μg·mL<sup>-1</sup> and 0.10 μg·mL<sup>-1</sup> respectively. Linearity study was conducted from LOQ to 150% and correlation coefficient found to be 0.9997. Accuracy was within the range of 98.6% to 101.5%. To prove selectivity power of the method specificity study was conducted by subjecting drug substance to acid, base, hydrolysis, oxidation and photolysis and ensured the peak purity of analyte in degraded samples. Moreover, the method has been fully validated as per ICH guidelines. The proposed method is precise, accurate, linear, rugged, robust and suitable for accurate quantification of S-LINA in LINA drug substance.
基金Sponsored by the National Natural Science Foundation of China(Grant Nos.11461026,11361024,51378206 and 11661036)the Provincial Natural Science Foundation(Grant No.2017BAB201009)
文摘Wavelet method is often used in analyzing trend and period of time sequence. When using wavelet method one serious problem is different chosen wavelet basis and scale would lead to different results. Sometimes, the results vary greatly. To overcome this problem and to improve the accuracy and efficiency, a new method denoted by Natural-based Wavelet Method is introduced and extended. It can be proved that the proposed method in fact is a special class of discrete wavelet. At first, two numerical examples are designed to show the capacity of the novel method. Second, this method is applied to a precipitation series. According to wavelet analysis and short-range precipitation prediction, this precipitation exists a faintly increasing trend. Through the analysis, the studied precipitation has two major periods: 11 and 41 years. The results validate that the Natural-based Wavelet Method used in application of multi-complicated observed data is suitable. It is easy to write the source code of the proposed method. When new information appears, new information can be easily added into the original sequence, this is another advantage of the proposed method.
基金E.Martínez-Paneda acknowledges financial support from the Royal Commission for the 1851 Exhibition through their Research Fellowship programme(RF496/2018).
文摘In this work,we extend the recently proposed adaptive phase field method to model fracture in orthotropic functionally graded materials(FGMs).A recovery type error indicator combined with quadtree decomposition is employed for adaptive mesh refinement.The proposed approach is capable of capturing the fracture process with a localized mesh refinement that provides notable gains in computational efficiency.The implementation is validated against experimental data and other numerical experiments on orthotropic materials with different material orientations.The results reveal an increase in the stiffness and the maximum force with increasing material orientation angle.The study is then extended to the analysis of orthotropic FGMs.It is observed that,if the gradation in fracture properties is neglected,the material gradient plays a secondary role,with the fracture behaviour being dominated by the orthotropy of the material.However,when the toughness increases along the crack propagation path,a substantial gain in fracture resistance is observed.
文摘The thermodynamic properties and the phase diagrams of the systems Ga-M (M = In, Sb, Ph) were critically re-assessed and optimized employing the software package ChemSage for the calculation of thermodynamicequilibria. The Redlich-Kister/Margules formalism was employed for all solution phases and sets of self-consistentthermodynamic parameters were obtained. The results of re-assessment and optimization are compared with previous work, they are in excellent agreement with most experimental data.
基金funded by the National Key Research and Development Project of China(Grant No.2021YFC3000600)the China Earthquake Science Experiment Field-Cross-fault Observation Array-Red River Fault Scientific Drilling Project Geophysical Prospecting Site Selection Project+2 种基金Anhui Province Science and Technology Breakthrough Plan Project(Key Project,202423l10050030)the Earthquake Science and Technology Spark Program of the China Earthquake Administration(XH23020YA)the Anhui Mengcheng National Geophysical Observatory Joint Open Fund(MENGO-202307)。
文摘The complex Red River fault zone(RRFZ),which is situated in the southwestern region of China and separates the Indochina plate and South China blocks,has diverse seismic activities in different segments.To reveal the detailed geometric characteristics of the RRFZ at different sections and to better understand the seismogenic environment,in 2022 and 2023 we deployed 7 seismic dense linear arrays,consisting of 574 nodal stations,across the RRFZ in the northern and southern segments near the towns Midu,Gasa,Zhega,Dazhai,Xinzhai,and Taoyuan.The linear arrays,which extend from 2.4 to 12.5 km in length with station intervals ranging between 40 and140 m,recorded seismic ambient noise for approximately one month.Using the extended range phase shift method,we extract the phase velocity dispersion curves of the Rayleigh waves between 0.9 and 10 Hz,which are then used to invert for the high resolution shearwave velocity structures across the RRFZ beneath the linear arrays.The key findings are:(1)the 7 imaged sections of the RRFZ exhibit quite similar structures,with higher velocities on the SW side and lower velocities on the NE side;the velocity variation is consistent with the surface geological structures along the RRFZ;(2)the shear-wave velocities on the SW side of the RRFZ at the northern Midu section and southern Gasa-Dazhai sections are generally higher than their counterparts in the southern Xinzhai-Taoyuan sections,which reflects lithological variations from the marble-dominated Paleoproterozoic Along basement to the gneiss dominated Paleoproterozoic Qingshuihe basement;(3)from the northern Midu section to the southern region where the RRFZ intersects with the Xiaojiang Fault,the major faults of the RRFZ exhibit a consistent high-angle,NE-dipping structure;(4)the low shear-wave velocities immediately to the NE of the velocity boundary may indicate a faulted zone due to long-term shearing,where excessive amplifications of ground motions could occur.This study provides new insights into the characteristics of the shallow structures of the RRFZ.
文摘间接飞行时间(indirect time of flight,iTOF)相机在三维环境感知领域有着广泛的应用前景。根据iTOF相机成像原理,当曝光时间过大导致相机工作在非线性区时,解算的深度信息也会引入额外的偏差,从而影响测量准确度。为了进一步提高飞行时间相机的应用精度,根据飞行时间相机的光学成像机理,提出一种针对飞行时间相机的性能参数测量方法,通过实验和计算间接得到飞行时间深度相机的系统增益等性能参数,将其代入飞行时间相机的光学成像模型,即可得到距离与相机输出灰度值的对应曲线。建模与实验结果的相对误差可以达到20%以内,平均相对误差为0.16%。这些性能参数和仿真模型用于指导iTOF相机在不同场景使用时的积分时间选择,可以有效解决因使用不当引入非线性误差而降低距离测量精度的问题。
