Polymerization-induced self-assembly(PISA)has become one of the most versatile approaches for scalable preparation of linear block copolymer nanoparticles with various morphologies.However,the controlled introduction ...Polymerization-induced self-assembly(PISA)has become one of the most versatile approaches for scalable preparation of linear block copolymer nanoparticles with various morphologies.However,the controlled introduction of branching into the core-forming block and the effect on the morphologies of block copolymer nanoparticles under PISA conditions have rarely been explored.Herein,a series of multifunctional macromolecular chain transfer agents(macro-CTAs)were first synthesized by a two-step green light-activated photoiniferter polymerization using two types of chain transfer monomers(CTMs).These macro-CTAs were then used to mediate reversible addition-fragmentation chain transfer(RAFT)dispersion polymerization of styrene(St)to prepare block copolymers with different core-forming block structures and the assemblies.The effect of the core-forming block structure on the morphology of block copolymer nanoparticles was investigated in detail.Transmission electron microscopy(TEM)analysis indicated that the brush-like core-forming block structure facilitated the formation of higher-order morphologies,while the branched core-forming block structure favored the formation of lower-order morphologies.Moreover,it was found that using macroCTAs with a shorter length also promoted the formation of higher-order morphologies.Finally,structures of block copolymers and the assemblies were further controlled by changing the structure of macro-CTA or using a binary mixture of two different macro-CTAs.We expect that this work not only sheds light on the synthesis of block copolymer nanoparticles but also provide important mechanistic insights into PISA of nonlinear block copolymers.展开更多
在基于三副本策略的分布式存储系统中,当存储节点上的硬盘出现故障时,常见的处理方式是等待系统预设的时间.如果该故障硬盘超时未恢复,才开始恢复故障硬盘上的副本.这种处理方式存在的问题是,当三副本组中存在故障副本时,如果该副本组...在基于三副本策略的分布式存储系统中,当存储节点上的硬盘出现故障时,常见的处理方式是等待系统预设的时间.如果该故障硬盘超时未恢复,才开始恢复故障硬盘上的副本.这种处理方式存在的问题是,当三副本组中存在故障副本时,如果该副本组再有一个副本所在的硬盘发生故障,将导致系统无法继续提供服务,且不能自动恢复.本文提出一种基于日志副本的改进的Raft共识算法,即LR-Raft (log replica based Raft),日志副本没有完整状态机,可以快速加入集群,并参与投票与共识,提升了存在故障硬盘时系统的可用性;可以解决短时间内三副本中两个副本故障导致集群不可用和丢失数据的问题.实验结果表明,在副本组中引入日志副本后,与原Raft相比,LR-Raft在不同的工作负载下读写时延均明显降低,吞吐量显著提升.展开更多
基金financially supported by the National Natural Science Foundation of China(Nos.22171055 and 52222301)the Guangdong Natural Science Foundation for Distinguished Young Scholar(No.2022B1515020078)the Science and Technology Program of Guangzhou(No.2024A04J2821)。
文摘Polymerization-induced self-assembly(PISA)has become one of the most versatile approaches for scalable preparation of linear block copolymer nanoparticles with various morphologies.However,the controlled introduction of branching into the core-forming block and the effect on the morphologies of block copolymer nanoparticles under PISA conditions have rarely been explored.Herein,a series of multifunctional macromolecular chain transfer agents(macro-CTAs)were first synthesized by a two-step green light-activated photoiniferter polymerization using two types of chain transfer monomers(CTMs).These macro-CTAs were then used to mediate reversible addition-fragmentation chain transfer(RAFT)dispersion polymerization of styrene(St)to prepare block copolymers with different core-forming block structures and the assemblies.The effect of the core-forming block structure on the morphology of block copolymer nanoparticles was investigated in detail.Transmission electron microscopy(TEM)analysis indicated that the brush-like core-forming block structure facilitated the formation of higher-order morphologies,while the branched core-forming block structure favored the formation of lower-order morphologies.Moreover,it was found that using macroCTAs with a shorter length also promoted the formation of higher-order morphologies.Finally,structures of block copolymers and the assemblies were further controlled by changing the structure of macro-CTA or using a binary mixture of two different macro-CTAs.We expect that this work not only sheds light on the synthesis of block copolymer nanoparticles but also provide important mechanistic insights into PISA of nonlinear block copolymers.
文摘在基于三副本策略的分布式存储系统中,当存储节点上的硬盘出现故障时,常见的处理方式是等待系统预设的时间.如果该故障硬盘超时未恢复,才开始恢复故障硬盘上的副本.这种处理方式存在的问题是,当三副本组中存在故障副本时,如果该副本组再有一个副本所在的硬盘发生故障,将导致系统无法继续提供服务,且不能自动恢复.本文提出一种基于日志副本的改进的Raft共识算法,即LR-Raft (log replica based Raft),日志副本没有完整状态机,可以快速加入集群,并参与投票与共识,提升了存在故障硬盘时系统的可用性;可以解决短时间内三副本中两个副本故障导致集群不可用和丢失数据的问题.实验结果表明,在副本组中引入日志副本后,与原Raft相比,LR-Raft在不同的工作负载下读写时延均明显降低,吞吐量显著提升.
