Molecular magnetism is reaching a degree of development that will allow for the rational design of sophisticated systems.Among these,here we will focus on those that display single-molecule magnetic behaviour,i.e.clas...Molecular magnetism is reaching a degree of development that will allow for the rational design of sophisticated systems.Among these,here we will focus on those that display single-molecule magnetic behaviour,i.e.classical memories,and on magnetic molecules that can be used as molecular spin qubits,the irreducible components of any quantum technology.Compared with candidates developed from physics,a major advantage of molecular spin qubits stems from the power of chemistry for the tailored and inexpensive synthesis of new systems for their experimental study;in particular,the so-called lanthanoid-based single-ion magnets,which have for a long time been one of the hottest topics in molecular magnetism.展开更多
基金funded by the EU(ERC Advanced Grant SPINMOL and ERC Consolidator Grant DECRESIM),the Spanish MINECO(grant MAT2014-56143-R,CTQ2014-52758-P and Unidad de Excelencia María de Maeztu MDM-2015-0538 granted to ICMol)the Generalitat Valenciana(Prometeo and ISIC Programmes of Excellence)+1 种基金A.G.-A.acknowledges funding by the MINECO(Ramón y Cajal contract)J.J.B.acknowledge the Blaise Pascal International Chair for financial support.J.J.B.also thanks the Spanish MECD for an FPU predoctoral grant.L.E.M.acknowledges the Generalitat Valenciana for a VALi+D predoctoral grant.S.C.-S.acknowledges the Generalitat Valenciana for a VALi+D postdoctoral grant.
文摘Molecular magnetism is reaching a degree of development that will allow for the rational design of sophisticated systems.Among these,here we will focus on those that display single-molecule magnetic behaviour,i.e.classical memories,and on magnetic molecules that can be used as molecular spin qubits,the irreducible components of any quantum technology.Compared with candidates developed from physics,a major advantage of molecular spin qubits stems from the power of chemistry for the tailored and inexpensive synthesis of new systems for their experimental study;in particular,the so-called lanthanoid-based single-ion magnets,which have for a long time been one of the hottest topics in molecular magnetism.
