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An Analytical Model of Drain Current for Ultra-Thin Body and Double-Gate Schottky Source/Drain MOSFETs Accounting for Quantum Effects 被引量:2
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作者 栾苏珍 刘红侠 +3 位作者 贾仁需 蔡乃琼 王瑾 匡潜玮 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2008年第5期869-874,共6页
A compact drain current including the variation of barrier heights and carrier quantization in ultrathin-body and double-gate Schottky barrier MOSFETs (UTBDG SBFETs) is developed. In this model, Schrodinger's equat... A compact drain current including the variation of barrier heights and carrier quantization in ultrathin-body and double-gate Schottky barrier MOSFETs (UTBDG SBFETs) is developed. In this model, Schrodinger's equation is solved using the triangular potential well approximation. The carrier density thus obtained is included in the space charge density to obtain quantum carrier confinement effects in the modeling of thin-body devices. Due to the quantum effects, the first subband is higher than the conduction band edge, which is equivalent to the band gap widening. Thus, the barrier heights at the source and drain increase and the carrier concentration decreases as the drain current decreases. The drawback of the existing models,which cannot present an accurate prediction of the drain current because they mainly consider the effects of Schottky barrier lowering (SBL) due to image forces,is eliminated. Our research results suggest that for small nonnegative Schottky barrier (SB) heights,even for zero barrier height, the tunneling current also plays a role in the total on-state currents. Verification of the present model was carried out by the device numerical simulator-Silvaco and showed good agreement. 展开更多
关键词 Schottky barrier quantum effects the effective mass electron density
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Quantum Effects on Global Structure of Liquid Water
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作者 林珂 胡乃银 +2 位作者 周晓国 刘世林 罗毅 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2013年第2期127-132,I0003,共7页
The structure difference between light and heavy liquid water has been systematically in- vestigated by high precision Raman spectroscopy over the temperature range of 5-85℃. Distinct difference between the Raman spe... The structure difference between light and heavy liquid water has been systematically in- vestigated by high precision Raman spectroscopy over the temperature range of 5-85℃. Distinct difference between the Raman spectral profiles of two different liquid waters is clearly observed. By analyzing the temperature-dependent Raman spectral contour using global fitting procedure, it is found that the micro-structure of heavy water is more ordered than that of light water at the same temperature, and the structure difference between the light and heavy water decreases with the increase of the temperature. The temperature off- set, an indicator for the structure difference, is determined to vary from 28 ℃ to 18 ℃ for the low-to-high temperature. It indicates that quantum effect is significantly not only at low temperature, but also at room temperature. The interaction energy among water molecules has also been estimated from van't Hoff's relationship. The detailed structural information should help to develop reliable force fields for molecular modeling of liquid water. 展开更多
关键词 Light and heavy water quantum effect Raman spectra STRUCTURE Temperature offset
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Temperature Effects of Parabolic Linear Bound Potential and Coulomb Bound Potential Quantum Dot Qubit 被引量:2
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作者 CHEN Ying-Jie XIAO Jing-Lin 《Communications in Theoretical Physics》 SCIE CAS CSCD 2009年第10期601-605,共5页
On the condition of electric-LO phonon strong coupling in a parabolic quantum dot,we obtain theeigenenergy and the eigenfunctions of the ground state and the first-excited state using the variational method ofPekar ty... On the condition of electric-LO phonon strong coupling in a parabolic quantum dot,we obtain theeigenenergy and the eigenfunctions of the ground state and the first-excited state using the variational method ofPekar type.This system in a quantum dot may be employed as a two-level quantum system-qubit.When the electronis in the superposition state of the ground state and the first-excited state,we obtain the time evolution of the electrondensity.The relations of the probability density of electron on the temperature and the electron-LO-phonon couplingconstant and the relations of the period of oscillation on the temperature,the electron-LO-phonon coupling constant,the Coulomb binding parameter and the confinement length are derived.The results show that the probability densityof electron oscillates with a period when the electron is in the superposition state of the ground and the first-excitedstate,and show that there are different laws that the probability density of electron and the period of oscillation changewith the temperature and the electron-LO-phonon coupling constant when the temperature is lower or higher.Andit is obtained that the period of oscillation decreases with increasing the Coulomb bound potential and increases withincreasing the confinement length not only at lower temperatures but also at higher temperatures. 展开更多
关键词 quantum dot QUBIT Coulomb potential temperature effect
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Quantum Effects of Mesoscopic Inductance and Capacity Coupling Circuits 被引量:2
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作者 LIU Jian-Xin AN Zhan-Yuan SONG Yong-Hua 《Communications in Theoretical Physics》 SCIE CAS CSCD 2006年第6期1126-1130,共5页
Using the quantum theory for a mesoscopic circuit based on the discretenes of electric charges, the finitedifference Schrodinger equation of the non-dlssipative mesoscopic inductance and capacity coupling circuit is a... Using the quantum theory for a mesoscopic circuit based on the discretenes of electric charges, the finitedifference Schrodinger equation of the non-dlssipative mesoscopic inductance and capacity coupling circuit is achieved. The Coulomb blockade effect, which is caused by the discreteness of electric charges, is studied. Appropriately choose the components in the circuits, the finlte-dlfference Schrodinger equation can be divided into two Mathieu equations in representation." With the WKBJ method, the currents quantum fluctuations in the ground states of the two circuits are calculated. The results show that the currents quantum zero-point fluctuations of the two circuits are exist and correlated. 展开更多
关键词 mesoscopic circuit Mathieu equation quantum effect
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Effects of Thermal Lattice Vibration on the Effective Potential of Weak-Coupling Bipolaron in a Quantum Dot 被引量:2
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作者 Eerdunchaolu Wuyunqimuge +2 位作者 XIAO Xin HAN Chao XIN Wei 《Communications in Theoretical Physics》 SCIE CAS CSCD 2012年第1期157-160,共4页
Based on the Huybrechts' linear-combination operator,effects of thermal lattice vibration on the effective potential of weak-coupling bipolaron in semiconductor quantum dots are studied by using the LLP variationa... Based on the Huybrechts' linear-combination operator,effects of thermal lattice vibration on the effective potential of weak-coupling bipolaron in semiconductor quantum dots are studied by using the LLP variational method and quantum statistical theory.The results show that the absolute value of the induced potential of the bipolaron increases with increasing the electron-phonon coupling strength,but decreases with increasing the temperature and the distance of electrons,respectively;the absolute value of the effective potential increases with increasing the radius of the quantum dot,electron-phonon coupling strength and the distance of electrons,respectively,but decreases with increasing the temperature;the temperature and electron-phonon interaction have the important influence on the formation and state properties of the bipolaron:the bipolarons in the bound state are closer and more stable when the electron-phonon coupling strength is larger or the temperature is lower;the confinement potential and coulomb repulsive potential between electrons are unfavorable to the formation of bipolarons in the bound state. 展开更多
关键词 quantum dot BIPOLARON induced potential effective potential thermal lattice vibration polaroneffects
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Finite size effects on helical edge states in HgTe quantum wells with the spin orbit coupling due to bulk- and structure-inversion asymmetries 被引量:1
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作者 成志 周斌 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第3期498-503,共6页
There is a quantum spin Hall state in the inverted HgTe quantum well, characterized by the topologically protected gapless helical edge states lying within the bulk gap. It has been found that for a strip of finite wi... There is a quantum spin Hall state in the inverted HgTe quantum well, characterized by the topologically protected gapless helical edge states lying within the bulk gap. It has been found that for a strip of finite width, the edge states on the two sides can couple together to produce a gap in the spectrum. The phenomenon is called the finite size effect in quantum spin Hall systems. In this paper, we investigate the effects of the spin-orbit coupling due to bulk- and structure-inversion asymmetries on the finite size effect in the HgTe quantum well by means of the numerical diagonalization method. When the bulk-inversion asymmetry is taken into account, it is shown that the energy gap Eg of the edge states due to the finite size effect features an oscillating exponential decay as a function of the strip width of the HgTe quantum well. The origin of this oscillatory pattern on the exponential decay is explained. Furthermore, if the bulk- and structure-inversion asymmetries are considered simultaneously, the structure-inversion asymmetry will induce a shift of the energy gap Eg closing point. Finally, based on the roles of the bulk- and structure-inversion asymmetries on the finite size effects, a way to realize the quantum spin Hall field effect transistor is proposed. 展开更多
关键词 quantum spin Hall state finite size effect spin-orbit coupling
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Influences of Quantum and Disorder Effects on Solitons Excited in Protein Molecules in Improved Model 被引量:1
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作者 PANGXiao-Feng YUJia-Feng LUOYu-Hui 《Communications in Theoretical Physics》 SCIE CAS CSCD 2005年第2期367-376,共10页
Utilizing the improved model with quasi-coherent two-quantum state and new Hamiltonian containing an additional interaction term [Phys. Rev. E62 (2000) 6989 and Euro. Phys. J. B19 (2001) 297] we study numerically the ... Utilizing the improved model with quasi-coherent two-quantum state and new Hamiltonian containing an additional interaction term [Phys. Rev. E62 (2000) 6989 and Euro. Phys. J. B19 (2001) 297] we study numerically the influences of the quantum and disorder effects including distortion of the sequences of masses of amino acid molecules and fluctuations of force constant of molecular chains, and of exciton-phonon coupled constants and of the dipole-dipole interaction constant and of the ground state energy on the properties of the solitons transported the bio-energy in the protein molecules by Runge-Kutta method. The results obtained show that the new soliton is robust against these structure disorders, especially for stronger disorders in the sequence of masses spring constants and coupling constants,except for quite larger fluctuations of the ground state energy and dipole-dipole interaction constant. This means that the new soliton in the improved model is very stable in normal cases and is possibly a carrier of bio-energy transport in the protein molecules. 展开更多
关键词 bio-energy transport protein SOLITON quantum effect disorder effect numerical simulation
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Temperature and hydrogen-like impurity effects on the excited state of the strong coupling bound polaron in a CsI quantum pseudodot 被引量:2
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作者 Jing-Lin Xiao 《Chinese Physics B》 SCIE EI CAS CSCD 2017年第2期399-402,共4页
With hydrogen-like impurity(HLI) located in the center of Cs I quantum pseudodot(QPD) and by using the variational method of Pekar type(VMPT), we investigate the first-excited state energy(FESE), excitation en... With hydrogen-like impurity(HLI) located in the center of Cs I quantum pseudodot(QPD) and by using the variational method of Pekar type(VMPT), we investigate the first-excited state energy(FESE), excitation energy and transition frequency of the strongly-coupled bound polaron in the present paper. Temperature effects on bound polaron properties are calculated by employing the quantum statistical theory(QST). According to the present work's numerical results, the FESE, excitation energy and transition frequency decay(amplify) with raising temperature in the regime of lower(higher)temperature. They are decreasing functions of Coulomb impurity potential strength. 展开更多
关键词 temperature effect bound polaron CsI quantum pseudodot quantum statistical theory excited state
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Temperature Effects of Electric Field on the First Excited State of Strong Coupling Polaron in a CsI Quantum Pseudodot 被引量:1
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作者 孙勇 丁朝华 肖景林 《Communications in Theoretical Physics》 SCIE CAS CSCD 2017年第3期337-340,共4页
Employing variational method of Pekar type(VMPT), this paper investigates the first-excited state energy(FESE), excitation energy and transition frequency of the strongly-coupled polaron in the Cs I quantum pseudodot(... Employing variational method of Pekar type(VMPT), this paper investigates the first-excited state energy(FESE), excitation energy and transition frequency of the strongly-coupled polaron in the Cs I quantum pseudodot(QPD)with electric field. The temperature effects on the strong-coupling polaron in electric field are calculated by using the quantum statistical theory(QST). The results from the present investigation show that the FESE, excitation energy and transition frequency increase(decrease) firstly and then at lower(higher) temperature regions. They are decreasing functions of the electric field strength. 展开更多
关键词 temperature effects electric field POLARON CsI quantum pseudodot
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Polaronic Effects of an Exciton in a Cylindrical Quantum Wire 被引量:1
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作者 WANGRui-Qiang XIEHong-Jing GUOKang-Xian YUYou-Bin DENGYong-Qing 《Communications in Theoretical Physics》 SCIE CAS CSCD 2005年第1期169-174,共6页
The effects of exciton-optical phonon interaction on the binding energy and the total and reduced effective masses of an exciton in a cylindrical quantum wire have been investigated. We adopt a perturbative-PLL [T.D. ... The effects of exciton-optical phonon interaction on the binding energy and the total and reduced effective masses of an exciton in a cylindrical quantum wire have been investigated. We adopt a perturbative-PLL [T.D. Lee,F. Low, and D. Pines, Phys. Rev. B90 (1953) 297] technique to construct an effective Hamiltonian and then use a variational solution to deal with the exciton-phonon system. The interactions of exciton with the longitudinal-optical phonon and the surface-optical phonon have been taken into consideration. The numerical calculations for GaAs show that the influences of phonon modes on the exciton in a quasi-one-dimensional quantum wire are considerable and should not be neglected. Moreover the numerical results for heavy- and light-hole exciton are obtained, which show that the polaronic effects on two types of excitons are very different but both depend heavily on the sizes of the wire. 展开更多
关键词 exciton binding energy polaronic effect cylindrical quantum wire
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Revealing the Ubiquitous Effects of Quantum Entanglement—Toward a Notion of God Logic 被引量:1
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作者 Wen-Ran Zhang Karl E. Peace 《Journal of Quantum Information Science》 2013年第4期143-153,共11页
Following Spinoza-Einstein’s interpretation of God or nature, the notion “God Logic” is proposed. This notion is to serve as an elicitation for a consistent set of necessary criteria for: 1) developing the logical ... Following Spinoza-Einstein’s interpretation of God or nature, the notion “God Logic” is proposed. This notion is to serve as an elicitation for a consistent set of necessary criteria for: 1) developing the logical foundation of quantum gravity as envisaged by Einstein, 2) revealing the ubiquitous effects of quantum entanglement as suggested by Roger Penrose, and 3) programming the universe as proposed by Seth Lloyd. An evolving set of eleven criteria is proposed for the notion. The possibility of inventing such a logical system is analyzed. A supersymmetrical candidate logic of negative-positive energy dynamic equilibrium is introduced and assessed against the set of criteria. It is shown that the first 10 criteria are met or partially met by the candidate. But the question whether the 11th criterion has been or can be met is left open for discussion and further research effort. The assessment leads to a few predictions. Notably, it is predicted that, should Boson-Fermion symmetry or broken symmetry be observed, it would be caused by bipolar symmetry or broken symmetry of negative-positive energies. 展开更多
关键词 UBIQUITOUS effects of quantum Entanglement Programming the Universe Negative-Positive Energy SUPERSYMMETRY Scientific Unification UBIQUITOUS quantum Computing quantum Intelligence
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Analysis of atmospheric effects on the continuous variable quantum key distribution 被引量:1
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作者 Tao Liu Shuo Zhao +6 位作者 Ivan B.Djordjevic Shuyu Liu Sijia Wang Tong Wu Bin Li Pingping Wang Rongxiang Zhang 《Chinese Physics B》 SCIE EI CAS CSCD 2022年第11期211-218,共8页
Atmospheric effects have significant influence on the performance of a free-space optical continuous variable quantum key distribution(CVQKD)system.In this paper,we investigate how the transmittance,excess noise and i... Atmospheric effects have significant influence on the performance of a free-space optical continuous variable quantum key distribution(CVQKD)system.In this paper,we investigate how the transmittance,excess noise and interruption probability caused by atmospheric effects affect the secret-key rate(SKR)of the CVQKD.Three signal wavelengths,two weather conditions,two detection schemes,and two types of attacks are considered in our investigation.An expression aims at calculating the interruption probability is proposed based on the Kolmogorov spectrum model.The results show that a signal using long working wavelength can propagate much further than that of using short wavelength.Moreover,as the wavelength increases,the influence of interruption probability on the SKR becomes more significant,especially within a certain transmission distance.Therefore,interruption probability must be considered for CVQKD by using long-signal wavelengths.Furthermore,different detection schemes used by the receiver will result in different transmission distances when subjected to individual attacks and collective attacks,respectively. 展开更多
关键词 atmospheric effect continuous variable key distribution free space quantum communication secret-key rate
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Temperature Effects on the Self-trapping Energy of a Polaron in a GaAs Parabolic Quantum Dot 被引量:1
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作者 Kadi ZHU and Shiwei GU (Institute of Condensed Matter Physics, Shanghai Jiaotong University, Shanghai, 200030, China)(To whom correspondence should be addressed) 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 1994年第2期131-134,共4页
The temperature and the size dependences of the self-trapping energy of a polaron in a GaAs parabolic quantum dot are investigated by the second order Rayleigh-Schrodinger perturbation method using the framework of th... The temperature and the size dependences of the self-trapping energy of a polaron in a GaAs parabolic quantum dot are investigated by the second order Rayleigh-Schrodinger perturbation method using the framework of the effective mass approximation. The numerical results show that the self-trapping energies of polaron in GaAs parabolic quantum dots shrink with the enhancement of temperature and the size of the quantum dot. The results also indicate that the temperature effect becomes obvious in small quantum dots 展开更多
关键词 GAAS REV Temperature effects on the Self-trapping Energy of a Polaron in a GaAs Parabolic quantum Dot
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Inflationary Cosmology with Quantum Gravitational Effects and Swampland Conjectures
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作者 Qiang Wu Tao Zhu 《Communications in Theoretical Physics》 SCIE CAS CSCD 2019年第9期1115-1120,共6页
Recently proposed two swampland criteria that arising from string theory landscape leads to the important challenge of the realization of single-field inflationary models. Especially one of swampland criteria which im... Recently proposed two swampland criteria that arising from string theory landscape leads to the important challenge of the realization of single-field inflationary models. Especially one of swampland criteria which implies a large tensor-to-scalar ratio is strongly in tension with recent observational results. In this paper, we explore the possibility the swampland conjectures could be compatible with single-field inflationary scenarios if the effects due to the quantum theory of gravity are considered. We show that the quantum gravitational effects due to the nonlinear dispersion relation provides significant modifications on the amplitude of both the scalar and tensor perturbation spectra. Such modifications could be either raise or reduce the perturbation spectra depending on the values of the parameters in the nonlinear terms of the dispersion relations. Therefore, these effects can reduce the tensor-to-scalar ratio to a smaller value, which helps to relax the tension between the swampland conjecture and observational data. 展开更多
关键词 INFLATION quantum GRAVITATIONAL effects swampland CONJECTURES UNIFORM ASYMPTOTIC approximation
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Piezo-phototronic effect on intersubband optical absorption in ZnO/MgZnO quantum wells
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作者 Yuchang Liu Jiuzhou Chen +5 位作者 Yonglong Yang Xiaolong Pan Xin Xue Minjiang Dan Zhengwei Xiong Zhipeng Gao 《Chinese Physics B》 2025年第8期729-733,共5页
Intersubband transition in ZnO/MgZnO quantum well has been exploited for infrared and terahertz optoelectronic applications due to its large band offset and fascinating material properties.Here,we theoretically demons... Intersubband transition in ZnO/MgZnO quantum well has been exploited for infrared and terahertz optoelectronic applications due to its large band offset and fascinating material properties.Here,we theoretically demonstrate piezophototronic effect as another way to control the intersubband absorption wavelength through quantum-confined Stark effect.The intersubband optical absorption properties under different stresses are obtained by solving the eight-band k·p Hamiltonian and coupled Schr¨odinger-Poisson equations self-consistently.By combining stress control and quantum well structure,the absorption wavelength can show infrared blueshift or redshift phenomena in a wide range.This work can provide an effective avenue to control and utilize quantum-confined Stark effect in intersubband infrared absorption and promote the relative potential optoelectronic devices. 展开更多
关键词 ZnO/MgZnO quantum well intersubband transition piezo-phototronic effect optical absorption
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Temperature effects on atmospheric continuous-variable quantum key distribution
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作者 Shu-Jing Zhang Hong-Xin Ma +3 位作者 Xiang Wang Chun Zhou Wan-Su Bao Hai-Long Zhang 《Chinese Physics B》 SCIE EI CAS CSCD 2019年第8期56-61,共6页
Compared with the fiber channel,the atmospheric channel offers the possibility of a broader geographical coverage and more flexible transmission for continuous-variable quantum key distribution(CVQKD).However,the fluc... Compared with the fiber channel,the atmospheric channel offers the possibility of a broader geographical coverage and more flexible transmission for continuous-variable quantum key distribution(CVQKD).However,the fluctuation of atmospheric conditions will lead to the loss of performance in atmospheric quantum communication.In this paper,we study how temperature affects atmospheric CVQKD.We mainly consider the temperature effects on the transmittance and interruption probability.From the numerical simulation analysis,it can be shown that the performance of atmospheric CVQKD is improved as temperature increases,with the other factors fixed.Moreover,the results in this work can be used to evaluate the feasibility of the experimental implementation of the atmospheric CVQKD protocols. 展开更多
关键词 ATMOSPHERIC continuous-variable quantum KEY distribution temperature effects performance SECRET KEY rate
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Tunable resonant radiation force exerted on semiconductor quantum well nanostructures: Nonlocal effects
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作者 王光辉 颜雄硕 张金珂 《Chinese Physics B》 SCIE EI CAS CSCD 2017年第10期389-394,共6页
Resonant radiation force exerted on a semiconductor quantum well nanostructure (QWNS) from intersubband transition of electrons is investigated by taking the nonlocal coupling between the polarizability of electrons... Resonant radiation force exerted on a semiconductor quantum well nanostructure (QWNS) from intersubband transition of electrons is investigated by taking the nonlocal coupling between the polarizability of electrons and applied optical fields into account for two kinds of polarized states. The numerical results show the spatial nonlocality of optical response can induce the spectral peak position of the exerted force to have a blueshift, which is sensitively dependent on the polarized state and the QWNS width. It is also demonstrated that resonant radiation force is controllable by the polarization and incident directions of applied light waves. This work provides effective methods for controlling optical force and manipulating nano-objects, and observing radiation forces in experiment. This nonlocal interaction mechanism can also be used to probe and predominate internal quantum properties of nanostructures, and to manipulate collective behavior of nano-objects. 展开更多
关键词 nonlocal effect radiation force quantum well NANOSTRUCTURE
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Quantum spin Hall and quantum valley Hall effects in trilayer graphene and their topological structures
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作者 Majeed Ur Rehman A A Abid 《Chinese Physics B》 SCIE EI CAS CSCD 2017年第12期481-490,共10页
The present study pertains to the trilayer graphene in the presence of spin orbit coupling to probe the quantum spin/valley Hall effect. The spin Chern-number Cs for energy-bands of trilayer graphene having the essenc... The present study pertains to the trilayer graphene in the presence of spin orbit coupling to probe the quantum spin/valley Hall effect. The spin Chern-number Cs for energy-bands of trilayer graphene having the essence of intrinsic spin-orbit coupling is analytically calculated. We find that for each valley and spin, Cs is three times larger in trilayer graphene as compared to single layer graphene. Since the spin Chern-number corresponds to the number of edge states, consequently the trilayer graphene has edge states, three times more in comparison to single layer graphene. We also study the trilayer graphene in the presence of both electric-field and intrinsic spin-orbit coupling and investigate that the trilayer graphene goes through a phase transition from a quantum spin Hall state to a quantum valley Hall state when the strength of the electric field exceeds the intrinsic spin coupling strength. The robustness of the associated topological bulk-state of the trilayer graphene is evaluated by adding various perturbations such as Rashba spin-orbit (RSO) interaction αR, and exchange-magnetization M. In addition, we consider a theoretical model, where only one of the outer layers in trilayer graphene has the essence of intrinsic spin-orbit coupling, while the other two layers have zero intrinsic spin-orbit coupling. Although the first Chern number is non-zero for individual valleys of trilayer graphene in this model, however, we find that the system cannot be regarded as a topological insulator because the system as a whole is not gaped. 展开更多
关键词 trilayer graphene quantum spin Hall effect topological insulator quantum phase transition
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The ligand effect of graphene quantum dots in NiFeO_(x)/FeNi_(3)heterostructure for enhanced electrocatalytic valorization of poly(ethylene terephthalate)plastics
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作者 Bo Peng Sheng Qian +4 位作者 Shuhui Ma Yi Zhang Huaiguo Xue Tengfei Jiang Jingqi Tian 《Journal of Energy Chemistry》 2025年第8期841-851,共11页
Electrocatalytic valorization of disused poly(ethylene terephthalate)(PET)plastics into value-added chemicals emerges as a potential approach to address plastic pollution and resources upgrading,but it faces challenge... Electrocatalytic valorization of disused poly(ethylene terephthalate)(PET)plastics into value-added chemicals emerges as a potential approach to address plastic pollution and resources upgrading,but it faces challenges in the development of efficient catalysts for PET-derived ethylene glycol(EG)electrooxidation.Herein,we proposed pyramid arrays on sheet Fe-doped NiO/FeNi_(3)(SPA-NiFeO_(x)/FeNi_(3))heterostructure,which is derived from the pyrolysis of MOF-on-MOF heterostructure growth triggered by graphene quantum dots(GQDs).Such SPA-NiFeO_(x)/FeNi_(3)exhibits superior catalytic performance on the electrooxidation of EG(EGOR)from PET hydrolysate,with a formic acid(FA)selectivity of 91.5%and a Faradaic efficiency of 92%.The ligand effect of GQDs in both the catalyst design and improved electrocatalytic performance was studied with combined spectroscopy analysis and theoretical calculations,which revealed that such spatially separated NiFeO_(x)and FeNi_(3)components by GQDs possess more active sites to anticipate in electrocatalytic EGOR,and the large sp2 domains in GQDs possess a strong electron-withdrawing ability to reduce the electron density of bonded Ni and Fe,resulting in high-valenced Ni^(δ+)/Fe^(δ+)in FeNi_(3)and Ni(2+δ)in NiO,respectively.Furthermore,the coordination number of Ni and Fe centers was lowered due to the steric effect of GQDs.Therefore,the adsorption of EG on Ni^(δ+)for cascade dehydrogenation and C–C bond cleavage led to adsorbed FA that transferred to adjacent Fe for desorption,which was promoted by the enrichment of OH−on nearby Ni^((2+δ))sites,along with optimized Gibbs free energy change in the multistep reaction pathway.This work provides an efficient multi-active-site catalyst for disused PET plastics valorization,thereby presenting a new approach to enhance the efficiency of PET plastics valorization reactions. 展开更多
关键词 Poly(ethylene terephthalate)plastic recycling ELECTROCATALYSIS Gaphene quantum dot Ligand effect
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Effects of anisotropy on quantum fluctuation of a three-layer system with mutisublattice
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作者 姜伟 张凡 +1 位作者 关宏宇 梁吉艳 《Chinese Physics B》 SCIE EI CAS CSCD 2010年第12期499-503,共5页
The quantum fluctuations of a three-layer Heisenberg model with six sublattices are studied by the retarded Green's function method and the spin-wave theory. The effects of anisotropy on the quantum fluctuations at z... The quantum fluctuations of a three-layer Heisenberg model with six sublattices are studied by the retarded Green's function method and the spin-wave theory. The effects of anisotropy on the quantum fluctuations at zero temperature are discussed. The results show that the interlayer anisotropy plays an important role in balancing the quantum competitions. 展开更多
关键词 multisublattice three-layer quantum fluctuation effects of anisotropy
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