The reaction behavior between CaO–Al_(2)O_(3)–La_(2)O_(3)-based slags and La-bearing FeCrAl melt was quantitatively characterized,which was further compared with the reaction behavior of CaO–SiO_(2)-based slags.Bas...The reaction behavior between CaO–Al_(2)O_(3)–La_(2)O_(3)-based slags and La-bearing FeCrAl melt was quantitatively characterized,which was further compared with the reaction behavior of CaO–SiO_(2)-based slags.Based on this,the new type of mold flux for La-bearing FeCrAl alloy continuous casting was designed and its basic properties were evaluated.The results showed that the order of reaction degree of fluxing agents in CaO–Al_(2)O_(3)–La_(2)O_(3)-based slags is(Na_(2)O)>(B_(2)O_(3))>(Li_(2)O),and the percentages of mass change of fluxing agents were 85.8,54.29 and 42.35 wt.%,respectively.Moreover,the addition of(Li_(2)O)and(Na_(2)O)promoted the reaction between(CaO)and[Al],and the reaction degree of the former was weaker than that of the latter,which was due to the greater effect of(Na_(2)O)on the activity of(CaO)and(Al_(2)O_(3))than(Li_(2)O).Compared with the reactivity of CaO–SiO_(2)-based slags,the percentages of mass change of Al and La caused by slag–steel reaction decreased by 10.63–14.36 and 39.78–50.49 wt.%,respectively.The percentages of mass change of(Al_(2)O_(3)),(La_(2)O_(3))and(CaO)in slags highest increased by 17.71,17.98,and 7.81 wt.%,respectively.The reactivity of CaO–Al_(2)O_(3)–La_(2)O_(3)-based slags was significantly weakened.Ultimately,the new type of mold flux was designed and the composition range was determined.The fundamental properties of new mold flux basically meet the theoretical requirements for La-bearing FeCrAl alloy continuous casting.展开更多
The Ordovician fracture-vug carbonate reservoirs of Tarim Basin,are featured by developed vugs,caves and fractures.The strong heterogeneity results in huge uncertainty when these reservoirs are quantitatively characte...The Ordovician fracture-vug carbonate reservoirs of Tarim Basin,are featured by developed vugs,caves and fractures.The strong heterogeneity results in huge uncertainty when these reservoirs are quantitatively characterized using merely static seismic data.The effective quantitative characterization of the reservoirs has been an urgent problem to be solved.This study creatively proposes the"second quantitative characterization"technique with the combination of dynamic and static data based on the primary static quantitative characterization and fully considering lots of key influence factors when conducting characterization.In this technique,dynamic analysis methods such as well testing,production rate transient analysis,dynamic reserve evaluation and dynamic connectivity evaluation are used to get understandings on this kind of reservoir.These understandings are used as statistical parameters to constrain the inversion of seismic wave impedance to improve the relationship between wave impedance and porosity and determine the fracture-vug morphology,calculate dynamic reserves,and then a more accurate fracture-vugmodel can be selected and used to calculate the oil-water contact inversely based on the results of"second quantitative characterization".This method can lower the uncertainties in the primary quantitative characterization of fracture-vug reservoirs,enhance the accuracy of characterization results significantly,and has achieved good application results in the fracture-vug carbonate reservoirs of Tarim Basin.展开更多
Microstructural classification is typically done manually by human experts,which gives rise to uncertainties due to subjectivity and reduces the overall efficiency.A high-throughput characterization is proposed based ...Microstructural classification is typically done manually by human experts,which gives rise to uncertainties due to subjectivity and reduces the overall efficiency.A high-throughput characterization is proposed based on deep learning,rapid acquisition technology,and mathematical statistics for the recognition,segmentation,and quantification of microstructure in weathering steel.The segmentation results showed that this method was accurate and efficient,and the segmentation of inclusions and pearlite phase achieved accuracy of 89.95%and 90.86%,respectively.The time required for batch processing by MIPAR software involving thresholding segmentation,morphological processing,and small area deletion was 1.05 s for a single image.By comparison,our system required only 0.102 s,which is ten times faster than the commercial software.The quantification results were extracted from large volumes of sequential image data(150 mm^(2),62,216 images,1024×1024 pixels),which ensure comprehensive statistics.Microstructure information,such as three-dimensional density distribution and the frequency of the minimum spatial distance of inclusions on the sample surface of 150 mm^(2),were quantified by extracting the coordinates and sizes of individual features.A refined characterization method for two-dimensional structures and spatial information that is unattainable when performing manually or with software is provided.That will be useful for understanding properties or behaviors of weathering steel,and reducing the resort to physical testing.展开更多
Weathering crust reservoirs have obvious vertical zonation,which is the focus of weathering crust reservoir research,but there is a lack of quantitative characterization indexes.To achieve the quantitative characteriz...Weathering crust reservoirs have obvious vertical zonation,which is the focus of weathering crust reservoir research,but there is a lack of quantitative characterization indexes.To achieve the quantitative characterization of granite weathering crust reservoir and provide the basis for oil exploration of granite weathering crust buried hill reservoir,in this paper,the vertical zonation of granite weathering crust reservoir is quantitatively divided by testing and analyzing the uniaxial compressive strength(UCS),magnetic susceptibility(MS),permeability,and chemical index of alteration(CIA)of the Mesozoic granite weathering crust in the coastal area of eastern Fujian.The results show that the granite weathering crust reservoir can be divided into four zones vertically:a soil zone(SZ),weathered and dissolved zone(WDZ),fracture zone(FZ),and bedrock zone(BZ).A cataclastic area is developed in the FZ and BZ,in which structural fractures are well-developed,the fracture surface density is usually greater than 200 m/m^(2),and the contribution to the fractures in the rock mass is up to about 50%,making this the sweet spot of the reservoir.In the SZ,the rocks are loose,and the pores are well-developed.The UCS is less than 10 MPa,and the average rate of change of the UCS(Δ_(σ))is 0.90.The average permeability is 2823.00 mD,and the average rate of change of the permeability(Δ_(κ))is 5.13.The average CIA is 74.9%.The average clay mineral content is 7%.The rocks in the WDZ have been significantly weathered by physical and chemical processes,and the weathering fractures and dissolution pores are well-developed.The average UCS is 18.2 MPa,and the averageΔ_(σ)is 0.70.The average permeability is 143.80 mD,and averageΔ_(κ)is 4.17.The average CIA is 65.3%.The average clay mineral content is 4%.Under the influence of tectonic movement and physical weathering,the rocks in the FZ have developed structural fractures and a few weathered fractures.The average UCS is 57.9 MPa,and the averageΔ_(σ)is 0.18.The average permeability is 5.50 mD,and the averageΔ_(κ)is 2.55.The average CIA is 61.6%.The average clay mineral content is 2%.In the BZ,the rocks are intact and hard.The average UCS is 69.9 MPa,and the average Ds is 0.13.The average permeability is 1.46 mD,and the averageΔ_(κ)is 1.43.The average CIA is 57.8%.The average clay mineral content is less than 1%.The multi-parameter combination of the UCS,Δ_(σ),permeability,Δ_(κ),CIA,and clay mineral content achieved good results in the division of the zones of the weathering crust.The UCS increases gradually from top to bottom,while Ds,permeability,Δ_(κ),CIA,and clay mineral content all decrease gradually.In addition,based on the petrophysical parameters of the rocks,including the density,resistivity,and acoustic velocity,a good division effect was also achieved,which can provide a basis for the vertical zonation of the granite buried-hill weathering crust reservoir.展开更多
X oilfield is a typical layered reservoir with a large vertical span and many oil-bearing formations. There are significant differences in reservoir types and fluid properties among various formations. The interlayer ...X oilfield is a typical layered reservoir with a large vertical span and many oil-bearing formations. There are significant differences in reservoir types and fluid properties among various formations. The interlayer interference is severe in the development process. At present, the interlayer interference research based on dynamic monitoring data cannot meet development adjustment needs. Combined with the field test results, through the indoor physical simulation experiment method, dynamic inversion method, and reservoir engineering method, this paper analyzes the main control factors and interference mechanism of interlayer interference, studies the variation law of interference coefficient, improves and forms the quantitative characteristic Theory of interlayer interference in multi-layer commingled production, and provides theoretical guidance for the total adjustment of the middle strata division in the oilfield.展开更多
The quantitative description of the sequence structure of emulsion-processed SBR and solution-processed SBR (by lithium catalyst)was carried out based on their spectral data Of ^(13)C-NMR.The calculating formulae whic...The quantitative description of the sequence structure of emulsion-processed SBR and solution-processed SBR (by lithium catalyst)was carried out based on their spectral data Of ^(13)C-NMR.The calculating formulae which could be used to obtain diad concentration from the peak intensifies of carbon spectra, average block length, average number of block, and the microstructure composition of the molecular chain were derived. The quantitative result showed that on the molecular chain styrene unit had the tendency to attach to trans-1,4 butadiene unit. The calculated result of the microstructure was in good agreement with that obtained through IR measurement.展开更多
Seismic characterizing of tight gas sandstone (TGS) reservoirs is essential for identifying promising gas-bearing regions. However, exploring the petrophysical significance of seismic-inverted elastic properties is ch...Seismic characterizing of tight gas sandstone (TGS) reservoirs is essential for identifying promising gas-bearing regions. However, exploring the petrophysical significance of seismic-inverted elastic properties is challenging due to the complex microstructures in TGSs. Meanwhile, interbedded structures of sandstone and mudstone intensify the difficulty in accurately extracting the crucial tight sandstone properties. An integrated rock-physics-based framework is proposed to estimate the reservoir quality of TGSs from seismic data. TGSs with complex pore structures are modeled using the double-porosity model, providing a practical tool to compute rock physics templates for reservoir parameter estimation. The VP/VS ratio is utilized to predict the cumulative thickness of the TGS reservoirs within the target range via the threshold value evaluated from wireline logs for lithology discrimination. This approach also facilitates better capturing the elastic properties of the TGSs for quantitative seismic interpretation. Total porosity is estimated from P-wave impedance using the correlation obtained based on wireline log analysis. After that, the three-dimensional rock-physics templates integrated with the estimated total porosity are constructed to interpret microfracture porosity and gas saturation from velocity ratio and bulk modulus. The integrated framework can optimally estimate the parameters dominating the reservoir quality. The results of the indicator proposed based on the obtained parameters are in good agreement with the gas productions and can be utilized to predict promising TGS reservoirs. Moreover, the results suggest that considering microfracture porosity allows a more accurate prediction of high-quality reservoirs, further validating the applicability of the proposed method in the studied region.展开更多
Granular size segregation is an inevitable phenomenon in both natural and industrial processes.To understand the underlying mechanisms and develop effective optimization strategies,it is essential to employ robust met...Granular size segregation is an inevitable phenomenon in both natural and industrial processes.To understand the underlying mechanisms and develop effective optimization strategies,it is essential to employ robust methodologies that can quantitatively characterize and evaluate size segregation behaviors in granular systems.This review critically examines a wide variety of state-of-the-art methodologies from recent studies to quantify granular size segregation.The features of these methodologies are extracted and organized into a comprehensive framework.Four key questions are thoroughly discussed:evaluation criteria for identical segregation states,sensitivity to sample size,the influence of sampling division pattern,and the capability of handling multiple-component system.Finally,we provide an outlook on the future development of advanced and effective methodologies for granular size segregation characterization.展开更多
Characterization of filamentous fungal regulatory elements remains challenging because of time-consuming transformation technologies and limited quantitative methods.Here we established a method for quantitative asses...Characterization of filamentous fungal regulatory elements remains challenging because of time-consuming transformation technologies and limited quantitative methods.Here we established a method for quantitative assessment of filamentous fungal promoters based on flow cytometry detection of the superfolder green fluorescent protein at single-cell resolution.Using this quantitative method,we acquired a library of 93 native promoter elements from Aspergillus nidulans in a high-throughput format.The strengths of identified promoters covered a 37-fold range by flow cytometry.P_(zipA) and P_(sltA)were identified as the strongest promoters,which were 2.9-and 1.5-fold higher than that of the commonly used constitutive promoter P_(gpdA).Thus,we applied P_(zipA)and P_(sltA)to activate the silent nonribosomal peptide synthetase gene Afpes1 from Aspergillus fumigatus in its native host and the heterologous host A.nidulans.The metabolic products of Afpes1 were identified as new cyclic tetrapeptide derivatives,namely,fumiganins A and B.Our method provides an innovative strategy for natural product discovery in fungi.展开更多
The occurrence of hydrocarbon migration in petroliferous basins depends on the balance of driving force and resistance of carriers, which restricts mostly the quantity and positions of hydrocarbon accumulation. The dr...The occurrence of hydrocarbon migration in petroliferous basins depends on the balance of driving force and resistance of carriers, which restricts mostly the quantity and positions of hydrocarbon accumulation. The driving forces of hydrocarbon migration have been quantitatively studied, whereas the migration pathways and carriers were only qualitatively discussed up to now. Establishing a compound hydrocarbon carrier system and quantitatively characterizing its transport capability are significant for understanding the dynamic process of hydrocarbon migration and revealing the hydrocarbon accumulation characteristics. It has become an innovatory trend and also a difficult topic in study of hydrocarbon migration. In this article, a method is described for using displacement pressure to quantitatively characterize the transport capability of the compound carrier system, which composed of sandstone carriers, unconformities and faults. When the weathered and leached zone rarely developed, the basal conglomerate or transgressive sandstone of unconformities can be treated as part of sandstone carriers. An empirical relationship among core porosity, air permeability, and the pore aperture radius corresponding to a mercury saturation of 10% (r 10 ) can be obtained by multiple regression. Using porosity and permeability inversed by seismic data, the displacement pressure of sandstone carriers can be calculated by the empirical relationship and Washburn Equation. Displacement pressure of fault plane can be estimated by the regression formula between fault opening index (FOI) and hydrocarbon column height it can support. This method is applied in the eastern part of south slope in Dongying (东营) depression, Bohai (渤海) Bay Basin, China, to quantitatively characterize thetransport capability of the compound carrier system of Shahejie (沙河街) Formation. The results have good agreement with data from drilling wells. This method may be a step further in study of compound hydrocarbon carrier system in petroliferous basins. It may provide the basis of coupling expulsion quantity, migration driving force and hydrocarbon carrier system to simulate hydrocarbon migration and accumulation. Therefore this will help predict hydrocarbon migration pathways and the locations ofhydrocarbon accumulation.展开更多
The results of quantitative characters for anatomy in stems of three varieties tomatoes seedlings showed that the cell population between vascular bundle and epidermis, the cellular layers among vascular bundles and t...The results of quantitative characters for anatomy in stems of three varieties tomatoes seedlings showed that the cell population between vascular bundle and epidermis, the cellular layers among vascular bundles and the cell population in an unit area (mm^2) of no vascular bundle areas were similar and there had small difference among three varieties. On the foundation of these studies, the developmental mechanism of tomato seedling stem was discussed.展开更多
Lonicera edulis is a perennial berry shrub that prefers the cold and wet climate, with high nutritional and medicinal value. In this study, ecological cou- pling capability of L. edulis with light, heat, water and soi...Lonicera edulis is a perennial berry shrub that prefers the cold and wet climate, with high nutritional and medicinal value. In this study, ecological cou- pling capability of L. edulis with light, heat, water and soil resources in cold regions was investigated to analyze comprehensively ecological effects of quantitative characters and genetic effects of parents, aiming at providing a theoretical basis for the breeding, introduction and domestication of fine varieties of L. edulis in cold regions of China. The results showed that fruit characters in L. edulis exhibited certain variations among different habitat types. To be specific, fruit vertical diame- ter varied slightly, fruit horizontal diameter varied greatly and seed number varied maximally, with the average variance coefficients of 9.38%, 11.92% and 20. 64%, respectively; in addition, fruit characters in L. edtdis exhibited moderate herilability, moderate genetic gain and low level of genetic differentiation; the heritability of fruit vertical diameter, fruit horizontal diameter and seed number was 0.825, 0. 559 and 0. 627, respectively; the genetic gain of these three fruit characters was 7.53%, 5.72% and 11. 94%, respectively, resulting in significant economical benefits.展开更多
Stemming from the unique in-plane honeycomb lattice structure and the sp^(2)hybridized carbon atoms bonded by exceptionally strong carbon–carbon bonds,graphene exhibits remarkable anisotropic electrical,mechanical,an...Stemming from the unique in-plane honeycomb lattice structure and the sp^(2)hybridized carbon atoms bonded by exceptionally strong carbon–carbon bonds,graphene exhibits remarkable anisotropic electrical,mechanical,and thermal properties.To maximize the utilization of graphene’s in-plane properties,pre-constructed and aligned structures,such as oriented aerogels,films,and fibers,have been designed.The unique combination of aligned structure,high surface area,excellent electrical conductivity,mechanical stability,thermal conductivity,and porous nature of highly aligned graphene aerogels allows for tailored and enhanced performance in specific directions,enabling advancements in diverse fields.This review provides a comprehensive overview of recent advances in highly aligned graphene aerogels and their composites.It highlights the fabrication methods of aligned graphene aerogels and the optimization of alignment which can be estimated both qualitatively and quantitatively.The oriented scaffolds endow graphene aerogels and their composites with anisotropic properties,showing enhanced electrical,mechanical,and thermal properties along the alignment at the sacrifice of the perpendicular direction.This review showcases remarkable properties and applications of aligned graphene aerogels and their composites,such as their suitability for electronics,environmental applications,thermal management,and energy storage.Challenges and potential opportunities are proposed to offer new insights into prospects of this material.展开更多
Antiferromagnetism has become a promising candidate for the next generation electronic devices due to its thermal stability,low energy consumption,and fast switching speed.However,the canceling of the net magnetic mom...Antiferromagnetism has become a promising candidate for the next generation electronic devices due to its thermal stability,low energy consumption,and fast switching speed.However,the canceling of the net magnetic moment in antiferromagnetic order presents great challenge on quantitative characterization and modulation,hindering its investigation and application.In this work,utilizing the optical second harmonic generation(SHG)in a wide temperature range,the integrated differential phase contrast scanning transmission electron microscopy,and firstprinciples calculations,we performed a quantitative study on the evolution of non-collinear antiferromagnetic order in BiFeO_(3)films with a series of strains.We found that the antiferromagnetic coupling was significantly enhanced,featured by the increase of Néel temperature from 428 K to 646 K,and by one order of enhancement of SHG intensity contributed from the G-type antiferromagnetic order by strain manipulation from-2.4%to+0.6%.We attributed the enhancement of the antiferromagnetic coupling to the enhancement of the superexchange interaction as the Fe-O-Fe bond angle approaches 180°when the in-plane lattice constants increase,which might also result in a tendency from a non-collinear antiferromagnetic order to a collinear one.Our work not only bridges the antiferromagnetic order and the strain manipulation in epitaxial multiferroics,more importantly,also paves a way for quantitative characterization by SHG technology and the precise manipulation of antiferromagnetism.展开更多
Although serving as the workhorse,MS/MS cannot fully satisfy the analytical requirements of quantitative sub-metabolome characterization.Because more information intrinsically correlates to more structural and concent...Although serving as the workhorse,MS/MS cannot fully satisfy the analytical requirements of quantitative sub-metabolome characterization.Because more information intrinsically correlates to more structural and concentration clues,here,efforts were devoted to comprehensively tracing and deciphering MS/MS behaviors through constructing triple three-dimensional(3×3D)-MS/MS spectrum.Ginsenosides-targeted metabolomics of notoginseng,one of the most famous edible medicinal plants,was employed as a proof-of-concept.Serial authentic ginsenosides were deployed to build the correlations between 3×3D-MS/MS spectra and structure/concentration features.Through assaying ginsenosides with progressive concentrations using QTOF-MS to configure 1st 3D spectrum,the generations of MS1 spectral signals,particularly multi-charged multimer anions,e.g.,[2Me2H]^(2-) and[2M+2HCOO]^(2-) ions,relied on both concentration and the amount of sugar chains.By programming progressive collision energies to the front collision cell of Qtrap-MS device to gain 2^(nd) 3D spectrum,optimal collision energy(OCE)corresponding to the glycosidic bond fission was primarily correlated with the masses of precursor and fragment ions and partially governed by the glycosidation site.The quantitative relationships between OCEs and masses of precursor and fragment ions were utilized to build large-scale quantitative program for ginsenosides.After applying progressive exciting energies to the back collision chamber to build 3^(rd) 3D spectrum,the fragment ion and the decomposition product anion exhibited identical dissociation trajectories when they shared the same molecular geometry.After ginsenosides-focused quantitative metabolomics,significant differences occurred for sub-metabolome amongst different parts of notoginseng.The differential ginsenosides were confirmatively identified by applying the correlations between 3×3D-MS/MS spectra and structures.Together,3×3D-MS/MS spectrum covers all MS/MS behaviors and dramatically facilitates sub-metabolome characterization from both quantitative program development and structural identification.展开更多
Deepwater/deep-marine turbidite lobes are the most distal part of a siliciclastic depositional system and hold the largest sediment accumulation on the seafloor. As many giant hydrocarbon provinces have been discovere...Deepwater/deep-marine turbidite lobes are the most distal part of a siliciclastic depositional system and hold the largest sediment accumulation on the seafloor. As many giant hydrocarbon provinces have been discovered within deepwater lobe deposits, they represent one of the most promising exploration targets for hydrocarbon industry. Deepwater exploration is characterized by high cost, high risk but insufficient data because of the deep/ultra–deepwater depth. A thorough understanding of the deepwater turbidite lobe architecture, hierarchy, stacking pattern and internal facies distribution is thus vital. Recently, detailed outcrop characterizations and high–resolution seismic studies have both revealed that the deepwater lobe deposits are characterized into four–fold hierarchical arrangements from "beds", to "lobe elements", to "lobes" and to "lobe complex". Quantitative compilations have shown that hierarchical components of lobe deposits have similar length to width ratios but different width to thickness ratios depending on different turbidite systems. At all hierarchical scales, sand–prone hierarchical lobe units are always separated by mud–prone bounding units except when the bounding units are eroded by their overlying lobe units thus giving rise to vertical amalgamation and connectivity. Amalgamations often occur at more proximal regions suggesting high flow energy. A mixed flow behavior may occur towards more distal regions, resulting in deposition of "hybrid event beds". These synthesized findings could(1) help understand the lobe reservoir distribution and compartmentalization therefore benefit the exploration and development of turbidite lobes within the deep marine basins(e.g. South China Sea) and(2) provide rules and quantitative constraints on reservoir modeling. In addition, the findings associated with deepwater turbidite lobes might be a good starting point to understand the sedimentology, architecture and hierarchy of turbidites in deep lacustrine environment.展开更多
Morphology of hydraulic fracture surface has significant effects on oil and gas flow,proppant migration and fracture closure,which plays an important role in oil and gas fracturing stimulation.In this paper,we analyze...Morphology of hydraulic fracture surface has significant effects on oil and gas flow,proppant migration and fracture closure,which plays an important role in oil and gas fracturing stimulation.In this paper,we analyzed the fracture surface characteristics induced by supercritical carbon dioxide(SC-CO_(2))and water in open-hole and perforation completion conditions under triaxial stresses.A simple calculation method was proposed to quantitatively analyze the fracture surface area and roughness in macro-level based on three-dimensional(3D)scanning data.In micro-level,scanning electron micrograph(SEM)was used to analyze the features of fracture surface.The results showed that the surface area of the induced fracture increases with perforation angle for both SC-CO_(2)and water fracturing,and the surface area of SC-CO_(2)-induced fracture is 6.49%e58.57%larger than that of water-induced fracture.The fractal dimension and surface roughness of water-induced fractures increase with the increase in perforation angle,while those of SC-CO_(2)-induced fractures decrease with the increasing perforation angle.A considerable number of microcracks and particle peeling pits can be observed on SC-CO_(2)-induced fracture surface while there are more flat particle surfaces in water-induced fracture surface through SEM images,indicating that fractures tend to propagate along the boundary of the particle for SC-CO_(2)fracturing while water-induced fractures prefer to cut through particles.These findings are of great significance for analyzing fracture mechanism and evaluating fracturing stimulation performance.展开更多
Based on analysis of geophysical data such as core observation, rock slices identification, physical property, scanning electron microscope, X-ray diffraction, logging data etc., 16 factors of sedimentation, diagenesi...Based on analysis of geophysical data such as core observation, rock slices identification, physical property, scanning electron microscope, X-ray diffraction, logging data etc., 16 factors of sedimentation, diagenesis, fluid pressure, and their relationships with reservoir physical property were analyzed, and the results indicate sedimentation is the internal factor controlling the reservoir property, diagenesis is the external and final decisive factor and abnormal fluid pressure is an important factor preserving the deep reservoir property. Quantitative characterization of diagenesis indicates that compaction and dissolution are more important than cementation and they respectively cause porosity change of-23.6% and 7.7% and -6.2%. Through optimizing 11 main controlling factors and constructing reservoir evaluation index (REI) according to the hierarchical cluster and principal component analysis, reservoir classification standard was established and reservoirs were divided into four classes. The studies show that Es~ SQ4 consists mainly of class I and II, while Es~ SQ6 is mainly of class III and II; the favorable zone is the north and south slope of Qibei sub-sag and the Liujianfang fault-nose. The successful application of the quantitative and comprehensive evaluation in the Qibei area verifies the advanced, practicable method of less artificial factor is suitable for the low porosity and permeability reservoir.展开更多
The microscopic pore structure of sand-conglomerate rocks plays a decisive role in its exploration and development of such reservoirs.Due to complex gravels-cements configurations and resultant high heterogeneity in s...The microscopic pore structure of sand-conglomerate rocks plays a decisive role in its exploration and development of such reservoirs.Due to complex gravels-cements configurations and resultant high heterogeneity in sand-conglomerate rocks,the conventional fractal dimensions are inadequate to fully characterize the pore space.Based on the Pia Intermingled Fractal Units(IFU)model,this paper presents a new variable-ratio factor IFU model,which takes tortuosity and boundary layer thickness into consideration,to characterize the Triassic Karamay Formation conglomerate reservoirs in the Mahu region of the Junggar Basin,Northwest China.The modified model has a more powerful and flexible ability to simulate pore structures of porous media,and the simulation results are closer to the real conditions of pore space in low-porosity and low-permeability reservoirs than the conventional Pia IFU model.The geometric construction of the model is simplified to allow for an easing of computation.Porosity and spectral distribution of pore diameter,constructed using the modified model,are generally consistent with actual core data.Also,the model-computed permeability correlates well with experimental results,with a relative error of less than 15%.The modified IFU model performs well in quantitatively characterizing the heterogeneity of sand-conglomerate pore structures,and provides a methodology for the study of other similar types of heterogeneous reservoirs.展开更多
At present,Nb_(3) Sn superconductors are becoming more popular in high magnetic fields.The growth law of Nb_(3) Sn phase in a planar CuSn/Nb diffusion couple has been studied,whereas the formation mechanism of Nb_(3) ...At present,Nb_(3) Sn superconductors are becoming more popular in high magnetic fields.The growth law of Nb_(3) Sn phase in a planar CuSn/Nb diffusion couple has been studied,whereas the formation mechanism of Nb_(3) Sn phase in a cylindrical CuSn/Nb diffusion couple is still controversial.The purpose of this work is to investigate the growth exponent of Nb_(3) Sn phase at the initial stage of annealing by use of scanning electron microscopy(SEM)through which the thickness of Nb_(3) Sn layer can be obtained.In this study,bronze-processed Nb_(3) Sn multifilamentary wires with different annealing time were investigated.The Nb_(3) Sn phase was formed during isothermal annealing at 670 ℃ by solid-state diffusion,which was accomplished by the movement of Sn atoms from the CuSn/Nb_(3) Sn interface to Nb_(3) Sn/Nb interface.However,the formation mechanism of Nb_(3) Sn phase at the initial stage of annealing is still not well understood.Microstructural evolution of Nb_(3) Sn phase during isothermal annealing was studied by SEM.The mean thickness of the Nb_(3) Sn layer(Δ(xNn3 Sn)) is expressed as a power function of the annealing time(t) by the equation A_(x^(2)Nb_(3) Sn)=k(t/t0)^(n),where t0 is the unit time,k is the reaction rate constant and n is the growth exponent.The growth exponent has the average value of 0.82,which means that the formation of the Nb_(3) Sn phase is both governed by the interface reaction and the grain boundary diffusion.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.52174321,52274339 and 52074186).
文摘The reaction behavior between CaO–Al_(2)O_(3)–La_(2)O_(3)-based slags and La-bearing FeCrAl melt was quantitatively characterized,which was further compared with the reaction behavior of CaO–SiO_(2)-based slags.Based on this,the new type of mold flux for La-bearing FeCrAl alloy continuous casting was designed and its basic properties were evaluated.The results showed that the order of reaction degree of fluxing agents in CaO–Al_(2)O_(3)–La_(2)O_(3)-based slags is(Na_(2)O)>(B_(2)O_(3))>(Li_(2)O),and the percentages of mass change of fluxing agents were 85.8,54.29 and 42.35 wt.%,respectively.Moreover,the addition of(Li_(2)O)and(Na_(2)O)promoted the reaction between(CaO)and[Al],and the reaction degree of the former was weaker than that of the latter,which was due to the greater effect of(Na_(2)O)on the activity of(CaO)and(Al_(2)O_(3))than(Li_(2)O).Compared with the reactivity of CaO–SiO_(2)-based slags,the percentages of mass change of Al and La caused by slag–steel reaction decreased by 10.63–14.36 and 39.78–50.49 wt.%,respectively.The percentages of mass change of(Al_(2)O_(3)),(La_(2)O_(3))and(CaO)in slags highest increased by 17.71,17.98,and 7.81 wt.%,respectively.The reactivity of CaO–Al_(2)O_(3)–La_(2)O_(3)-based slags was significantly weakened.Ultimately,the new type of mold flux was designed and the composition range was determined.The fundamental properties of new mold flux basically meet the theoretical requirements for La-bearing FeCrAl alloy continuous casting.
基金Supported by the General Program of Natural Science Foundation of China(51874346).
文摘The Ordovician fracture-vug carbonate reservoirs of Tarim Basin,are featured by developed vugs,caves and fractures.The strong heterogeneity results in huge uncertainty when these reservoirs are quantitatively characterized using merely static seismic data.The effective quantitative characterization of the reservoirs has been an urgent problem to be solved.This study creatively proposes the"second quantitative characterization"technique with the combination of dynamic and static data based on the primary static quantitative characterization and fully considering lots of key influence factors when conducting characterization.In this technique,dynamic analysis methods such as well testing,production rate transient analysis,dynamic reserve evaluation and dynamic connectivity evaluation are used to get understandings on this kind of reservoir.These understandings are used as statistical parameters to constrain the inversion of seismic wave impedance to improve the relationship between wave impedance and porosity and determine the fracture-vug morphology,calculate dynamic reserves,and then a more accurate fracture-vugmodel can be selected and used to calculate the oil-water contact inversely based on the results of"second quantitative characterization".This method can lower the uncertainties in the primary quantitative characterization of fracture-vug reservoirs,enhance the accuracy of characterization results significantly,and has achieved good application results in the fracture-vug carbonate reservoirs of Tarim Basin.
基金supported by the National Key Research and Development Program of China(No.2017YFB0702303).
文摘Microstructural classification is typically done manually by human experts,which gives rise to uncertainties due to subjectivity and reduces the overall efficiency.A high-throughput characterization is proposed based on deep learning,rapid acquisition technology,and mathematical statistics for the recognition,segmentation,and quantification of microstructure in weathering steel.The segmentation results showed that this method was accurate and efficient,and the segmentation of inclusions and pearlite phase achieved accuracy of 89.95%and 90.86%,respectively.The time required for batch processing by MIPAR software involving thresholding segmentation,morphological processing,and small area deletion was 1.05 s for a single image.By comparison,our system required only 0.102 s,which is ten times faster than the commercial software.The quantification results were extracted from large volumes of sequential image data(150 mm^(2),62,216 images,1024×1024 pixels),which ensure comprehensive statistics.Microstructure information,such as three-dimensional density distribution and the frequency of the minimum spatial distance of inclusions on the sample surface of 150 mm^(2),were quantified by extracting the coordinates and sizes of individual features.A refined characterization method for two-dimensional structures and spatial information that is unattainable when performing manually or with software is provided.That will be useful for understanding properties or behaviors of weathering steel,and reducing the resort to physical testing.
基金supported by the Key Research and Development Program of Jilin Province(grant No.20230203107SF)the National Natural Science Foundation of China(Grant No.41790453)+1 种基金the National Key Research and Development Program of China(Grant No.2019YFC0605402)the National Major Science and Technology Project of the Ministry of Science and Technology of China(Grant No.2016ZX05026-004-001).
文摘Weathering crust reservoirs have obvious vertical zonation,which is the focus of weathering crust reservoir research,but there is a lack of quantitative characterization indexes.To achieve the quantitative characterization of granite weathering crust reservoir and provide the basis for oil exploration of granite weathering crust buried hill reservoir,in this paper,the vertical zonation of granite weathering crust reservoir is quantitatively divided by testing and analyzing the uniaxial compressive strength(UCS),magnetic susceptibility(MS),permeability,and chemical index of alteration(CIA)of the Mesozoic granite weathering crust in the coastal area of eastern Fujian.The results show that the granite weathering crust reservoir can be divided into four zones vertically:a soil zone(SZ),weathered and dissolved zone(WDZ),fracture zone(FZ),and bedrock zone(BZ).A cataclastic area is developed in the FZ and BZ,in which structural fractures are well-developed,the fracture surface density is usually greater than 200 m/m^(2),and the contribution to the fractures in the rock mass is up to about 50%,making this the sweet spot of the reservoir.In the SZ,the rocks are loose,and the pores are well-developed.The UCS is less than 10 MPa,and the average rate of change of the UCS(Δ_(σ))is 0.90.The average permeability is 2823.00 mD,and the average rate of change of the permeability(Δ_(κ))is 5.13.The average CIA is 74.9%.The average clay mineral content is 7%.The rocks in the WDZ have been significantly weathered by physical and chemical processes,and the weathering fractures and dissolution pores are well-developed.The average UCS is 18.2 MPa,and the averageΔ_(σ)is 0.70.The average permeability is 143.80 mD,and averageΔ_(κ)is 4.17.The average CIA is 65.3%.The average clay mineral content is 4%.Under the influence of tectonic movement and physical weathering,the rocks in the FZ have developed structural fractures and a few weathered fractures.The average UCS is 57.9 MPa,and the averageΔ_(σ)is 0.18.The average permeability is 5.50 mD,and the averageΔ_(κ)is 2.55.The average CIA is 61.6%.The average clay mineral content is 2%.In the BZ,the rocks are intact and hard.The average UCS is 69.9 MPa,and the average Ds is 0.13.The average permeability is 1.46 mD,and the averageΔ_(κ)is 1.43.The average CIA is 57.8%.The average clay mineral content is less than 1%.The multi-parameter combination of the UCS,Δ_(σ),permeability,Δ_(κ),CIA,and clay mineral content achieved good results in the division of the zones of the weathering crust.The UCS increases gradually from top to bottom,while Ds,permeability,Δ_(κ),CIA,and clay mineral content all decrease gradually.In addition,based on the petrophysical parameters of the rocks,including the density,resistivity,and acoustic velocity,a good division effect was also achieved,which can provide a basis for the vertical zonation of the granite buried-hill weathering crust reservoir.
文摘X oilfield is a typical layered reservoir with a large vertical span and many oil-bearing formations. There are significant differences in reservoir types and fluid properties among various formations. The interlayer interference is severe in the development process. At present, the interlayer interference research based on dynamic monitoring data cannot meet development adjustment needs. Combined with the field test results, through the indoor physical simulation experiment method, dynamic inversion method, and reservoir engineering method, this paper analyzes the main control factors and interference mechanism of interlayer interference, studies the variation law of interference coefficient, improves and forms the quantitative characteristic Theory of interlayer interference in multi-layer commingled production, and provides theoretical guidance for the total adjustment of the middle strata division in the oilfield.
文摘The quantitative description of the sequence structure of emulsion-processed SBR and solution-processed SBR (by lithium catalyst)was carried out based on their spectral data Of ^(13)C-NMR.The calculating formulae which could be used to obtain diad concentration from the peak intensifies of carbon spectra, average block length, average number of block, and the microstructure composition of the molecular chain were derived. The quantitative result showed that on the molecular chain styrene unit had the tendency to attach to trans-1,4 butadiene unit. The calculated result of the microstructure was in good agreement with that obtained through IR measurement.
基金supported by the National Natural Science Foundation of China(Grant numbers 42274160 and 42074153).
文摘Seismic characterizing of tight gas sandstone (TGS) reservoirs is essential for identifying promising gas-bearing regions. However, exploring the petrophysical significance of seismic-inverted elastic properties is challenging due to the complex microstructures in TGSs. Meanwhile, interbedded structures of sandstone and mudstone intensify the difficulty in accurately extracting the crucial tight sandstone properties. An integrated rock-physics-based framework is proposed to estimate the reservoir quality of TGSs from seismic data. TGSs with complex pore structures are modeled using the double-porosity model, providing a practical tool to compute rock physics templates for reservoir parameter estimation. The VP/VS ratio is utilized to predict the cumulative thickness of the TGS reservoirs within the target range via the threshold value evaluated from wireline logs for lithology discrimination. This approach also facilitates better capturing the elastic properties of the TGSs for quantitative seismic interpretation. Total porosity is estimated from P-wave impedance using the correlation obtained based on wireline log analysis. After that, the three-dimensional rock-physics templates integrated with the estimated total porosity are constructed to interpret microfracture porosity and gas saturation from velocity ratio and bulk modulus. The integrated framework can optimally estimate the parameters dominating the reservoir quality. The results of the indicator proposed based on the obtained parameters are in good agreement with the gas productions and can be utilized to predict promising TGS reservoirs. Moreover, the results suggest that considering microfracture porosity allows a more accurate prediction of high-quality reservoirs, further validating the applicability of the proposed method in the studied region.
基金support from the Natural Science Foundation of Chongqing,China (grant Nos.Cstc2021ycjhbgzxm0165,CSTB2023NSCQ-MSX0514)the Fundamental Research Funds for the Central Universities (grant No.2020CDJQY-A005).
文摘Granular size segregation is an inevitable phenomenon in both natural and industrial processes.To understand the underlying mechanisms and develop effective optimization strategies,it is essential to employ robust methodologies that can quantitatively characterize and evaluate size segregation behaviors in granular systems.This review critically examines a wide variety of state-of-the-art methodologies from recent studies to quantify granular size segregation.The features of these methodologies are extracted and organized into a comprehensive framework.Four key questions are thoroughly discussed:evaluation criteria for identical segregation states,sensitivity to sample size,the influence of sampling division pattern,and the capability of handling multiple-component system.Finally,we provide an outlook on the future development of advanced and effective methodologies for granular size segregation characterization.
基金supported by the National Key Research and Development Program of China(2020YFA0907800)the National Natural Science Foundation of China(31861133004,81872771)+2 种基金the Key Research Program of Frontier Sciences,CAS(ZDBS-LY-SM016)the Biological Resources Programme,Chinese Academy of Sciences(KFJBRP-009-005)the China Postdoctoral Science Foundation(YJ20200201,2020M680720,2022T150689)。
文摘Characterization of filamentous fungal regulatory elements remains challenging because of time-consuming transformation technologies and limited quantitative methods.Here we established a method for quantitative assessment of filamentous fungal promoters based on flow cytometry detection of the superfolder green fluorescent protein at single-cell resolution.Using this quantitative method,we acquired a library of 93 native promoter elements from Aspergillus nidulans in a high-throughput format.The strengths of identified promoters covered a 37-fold range by flow cytometry.P_(zipA) and P_(sltA)were identified as the strongest promoters,which were 2.9-and 1.5-fold higher than that of the commonly used constitutive promoter P_(gpdA).Thus,we applied P_(zipA)and P_(sltA)to activate the silent nonribosomal peptide synthetase gene Afpes1 from Aspergillus fumigatus in its native host and the heterologous host A.nidulans.The metabolic products of Afpes1 were identified as new cyclic tetrapeptide derivatives,namely,fumiganins A and B.Our method provides an innovative strategy for natural product discovery in fungi.
基金supported by the Chinese National Major Fundamental Research Developing Project(No.2011ZX08005-004)the National Natural Science Foundation of China(No.41102078)
文摘The occurrence of hydrocarbon migration in petroliferous basins depends on the balance of driving force and resistance of carriers, which restricts mostly the quantity and positions of hydrocarbon accumulation. The driving forces of hydrocarbon migration have been quantitatively studied, whereas the migration pathways and carriers were only qualitatively discussed up to now. Establishing a compound hydrocarbon carrier system and quantitatively characterizing its transport capability are significant for understanding the dynamic process of hydrocarbon migration and revealing the hydrocarbon accumulation characteristics. It has become an innovatory trend and also a difficult topic in study of hydrocarbon migration. In this article, a method is described for using displacement pressure to quantitatively characterize the transport capability of the compound carrier system, which composed of sandstone carriers, unconformities and faults. When the weathered and leached zone rarely developed, the basal conglomerate or transgressive sandstone of unconformities can be treated as part of sandstone carriers. An empirical relationship among core porosity, air permeability, and the pore aperture radius corresponding to a mercury saturation of 10% (r 10 ) can be obtained by multiple regression. Using porosity and permeability inversed by seismic data, the displacement pressure of sandstone carriers can be calculated by the empirical relationship and Washburn Equation. Displacement pressure of fault plane can be estimated by the regression formula between fault opening index (FOI) and hydrocarbon column height it can support. This method is applied in the eastern part of south slope in Dongying (东营) depression, Bohai (渤海) Bay Basin, China, to quantitatively characterize thetransport capability of the compound carrier system of Shahejie (沙河街) Formation. The results have good agreement with data from drilling wells. This method may be a step further in study of compound hydrocarbon carrier system in petroliferous basins. It may provide the basis of coupling expulsion quantity, migration driving force and hydrocarbon carrier system to simulate hydrocarbon migration and accumulation. Therefore this will help predict hydrocarbon migration pathways and the locations ofhydrocarbon accumulation.
基金Supported by Committee of Nature Science Foundation of Heilongjiang Province (C2005-32)Post-doctoral Science Committee of China (LRB04-217)Scientific Research Start Committee of Northeast Agricultural University
文摘The results of quantitative characters for anatomy in stems of three varieties tomatoes seedlings showed that the cell population between vascular bundle and epidermis, the cellular layers among vascular bundles and the cell population in an unit area (mm^2) of no vascular bundle areas were similar and there had small difference among three varieties. On the foundation of these studies, the developmental mechanism of tomato seedling stem was discussed.
基金Supported by Project of Running Service of National Forest Tree Germplasm Resource Platform(2011DKA21003-07)Special Fund for Forest Scientific Research in the Public Welfare(201204307-07)Science and Technology Support Program of Heilongjiang Province(GB06B306,GB06B306-02)
文摘Lonicera edulis is a perennial berry shrub that prefers the cold and wet climate, with high nutritional and medicinal value. In this study, ecological cou- pling capability of L. edulis with light, heat, water and soil resources in cold regions was investigated to analyze comprehensively ecological effects of quantitative characters and genetic effects of parents, aiming at providing a theoretical basis for the breeding, introduction and domestication of fine varieties of L. edulis in cold regions of China. The results showed that fruit characters in L. edulis exhibited certain variations among different habitat types. To be specific, fruit vertical diame- ter varied slightly, fruit horizontal diameter varied greatly and seed number varied maximally, with the average variance coefficients of 9.38%, 11.92% and 20. 64%, respectively; in addition, fruit characters in L. edtdis exhibited moderate herilability, moderate genetic gain and low level of genetic differentiation; the heritability of fruit vertical diameter, fruit horizontal diameter and seed number was 0.825, 0. 559 and 0. 627, respectively; the genetic gain of these three fruit characters was 7.53%, 5.72% and 11. 94%, respectively, resulting in significant economical benefits.
基金The financial support by the National Natural Science Foundation of China(No.52002020)is acknowledged.
文摘Stemming from the unique in-plane honeycomb lattice structure and the sp^(2)hybridized carbon atoms bonded by exceptionally strong carbon–carbon bonds,graphene exhibits remarkable anisotropic electrical,mechanical,and thermal properties.To maximize the utilization of graphene’s in-plane properties,pre-constructed and aligned structures,such as oriented aerogels,films,and fibers,have been designed.The unique combination of aligned structure,high surface area,excellent electrical conductivity,mechanical stability,thermal conductivity,and porous nature of highly aligned graphene aerogels allows for tailored and enhanced performance in specific directions,enabling advancements in diverse fields.This review provides a comprehensive overview of recent advances in highly aligned graphene aerogels and their composites.It highlights the fabrication methods of aligned graphene aerogels and the optimization of alignment which can be estimated both qualitatively and quantitatively.The oriented scaffolds endow graphene aerogels and their composites with anisotropic properties,showing enhanced electrical,mechanical,and thermal properties along the alignment at the sacrifice of the perpendicular direction.This review showcases remarkable properties and applications of aligned graphene aerogels and their composites,such as their suitability for electronics,environmental applications,thermal management,and energy storage.Challenges and potential opportunities are proposed to offer new insights into prospects of this material.
基金supported by the National Key Basic Research Program of China(Grant No.2019YFA0308500,2020YFA0309100,and 2021YFA1400701)the National Natural Science Foundation of China(Grant No.12174437,No.12222414,No.12074416,and No.12104054)+4 种基金the Strategic Priority Research Program(B)of the Chinese Academy of Sciences(Grant No.XDB33030200)the Youth Innovation Promotion Association of the Chinese Academy of Sciences(Grant No.Y2022003)the China Postdoctoral Innovative Talent Support Program(Grant No.BX20240409)the China Postdoctoral Science Foundation(Grant No.2024M763507)the Beijing Natural Science Foundation(Grant No.1222035).
文摘Antiferromagnetism has become a promising candidate for the next generation electronic devices due to its thermal stability,low energy consumption,and fast switching speed.However,the canceling of the net magnetic moment in antiferromagnetic order presents great challenge on quantitative characterization and modulation,hindering its investigation and application.In this work,utilizing the optical second harmonic generation(SHG)in a wide temperature range,the integrated differential phase contrast scanning transmission electron microscopy,and firstprinciples calculations,we performed a quantitative study on the evolution of non-collinear antiferromagnetic order in BiFeO_(3)films with a series of strains.We found that the antiferromagnetic coupling was significantly enhanced,featured by the increase of Néel temperature from 428 K to 646 K,and by one order of enhancement of SHG intensity contributed from the G-type antiferromagnetic order by strain manipulation from-2.4%to+0.6%.We attributed the enhancement of the antiferromagnetic coupling to the enhancement of the superexchange interaction as the Fe-O-Fe bond angle approaches 180°when the in-plane lattice constants increase,which might also result in a tendency from a non-collinear antiferromagnetic order to a collinear one.Our work not only bridges the antiferromagnetic order and the strain manipulation in epitaxial multiferroics,more importantly,also paves a way for quantitative characterization by SHG technology and the precise manipulation of antiferromagnetism.
基金the National Natural Science Foundation of China(No.81973444)National Administration of Traditional Chinese Medicine High level Key Discipline Construction Project of Traditional Chinese MedicinedChemistry of Chinese Materia Medica.
文摘Although serving as the workhorse,MS/MS cannot fully satisfy the analytical requirements of quantitative sub-metabolome characterization.Because more information intrinsically correlates to more structural and concentration clues,here,efforts were devoted to comprehensively tracing and deciphering MS/MS behaviors through constructing triple three-dimensional(3×3D)-MS/MS spectrum.Ginsenosides-targeted metabolomics of notoginseng,one of the most famous edible medicinal plants,was employed as a proof-of-concept.Serial authentic ginsenosides were deployed to build the correlations between 3×3D-MS/MS spectra and structure/concentration features.Through assaying ginsenosides with progressive concentrations using QTOF-MS to configure 1st 3D spectrum,the generations of MS1 spectral signals,particularly multi-charged multimer anions,e.g.,[2Me2H]^(2-) and[2M+2HCOO]^(2-) ions,relied on both concentration and the amount of sugar chains.By programming progressive collision energies to the front collision cell of Qtrap-MS device to gain 2^(nd) 3D spectrum,optimal collision energy(OCE)corresponding to the glycosidic bond fission was primarily correlated with the masses of precursor and fragment ions and partially governed by the glycosidation site.The quantitative relationships between OCEs and masses of precursor and fragment ions were utilized to build large-scale quantitative program for ginsenosides.After applying progressive exciting energies to the back collision chamber to build 3^(rd) 3D spectrum,the fragment ion and the decomposition product anion exhibited identical dissociation trajectories when they shared the same molecular geometry.After ginsenosides-focused quantitative metabolomics,significant differences occurred for sub-metabolome amongst different parts of notoginseng.The differential ginsenosides were confirmatively identified by applying the correlations between 3×3D-MS/MS spectra and structures.Together,3×3D-MS/MS spectrum covers all MS/MS behaviors and dramatically facilitates sub-metabolome characterization from both quantitative program development and structural identification.
基金funded by China Postdoctoral Science Foundation (Grant No.2016M591016)
文摘Deepwater/deep-marine turbidite lobes are the most distal part of a siliciclastic depositional system and hold the largest sediment accumulation on the seafloor. As many giant hydrocarbon provinces have been discovered within deepwater lobe deposits, they represent one of the most promising exploration targets for hydrocarbon industry. Deepwater exploration is characterized by high cost, high risk but insufficient data because of the deep/ultra–deepwater depth. A thorough understanding of the deepwater turbidite lobe architecture, hierarchy, stacking pattern and internal facies distribution is thus vital. Recently, detailed outcrop characterizations and high–resolution seismic studies have both revealed that the deepwater lobe deposits are characterized into four–fold hierarchical arrangements from "beds", to "lobe elements", to "lobes" and to "lobe complex". Quantitative compilations have shown that hierarchical components of lobe deposits have similar length to width ratios but different width to thickness ratios depending on different turbidite systems. At all hierarchical scales, sand–prone hierarchical lobe units are always separated by mud–prone bounding units except when the bounding units are eroded by their overlying lobe units thus giving rise to vertical amalgamation and connectivity. Amalgamations often occur at more proximal regions suggesting high flow energy. A mixed flow behavior may occur towards more distal regions, resulting in deposition of "hybrid event beds". These synthesized findings could(1) help understand the lobe reservoir distribution and compartmentalization therefore benefit the exploration and development of turbidite lobes within the deep marine basins(e.g. South China Sea) and(2) provide rules and quantitative constraints on reservoir modeling. In addition, the findings associated with deepwater turbidite lobes might be a good starting point to understand the sedimentology, architecture and hierarchy of turbidites in deep lacustrine environment.
基金National Natural Science Foundation of China(Grant No.51804318)the China Postdoctoral Science Foundation Founded Project(Grant No.2019M650963)National Key Basic Research and Development Program of China(Grant No.2014CB239203).
文摘Morphology of hydraulic fracture surface has significant effects on oil and gas flow,proppant migration and fracture closure,which plays an important role in oil and gas fracturing stimulation.In this paper,we analyzed the fracture surface characteristics induced by supercritical carbon dioxide(SC-CO_(2))and water in open-hole and perforation completion conditions under triaxial stresses.A simple calculation method was proposed to quantitatively analyze the fracture surface area and roughness in macro-level based on three-dimensional(3D)scanning data.In micro-level,scanning electron micrograph(SEM)was used to analyze the features of fracture surface.The results showed that the surface area of the induced fracture increases with perforation angle for both SC-CO_(2)and water fracturing,and the surface area of SC-CO_(2)-induced fracture is 6.49%e58.57%larger than that of water-induced fracture.The fractal dimension and surface roughness of water-induced fractures increase with the increase in perforation angle,while those of SC-CO_(2)-induced fractures decrease with the increasing perforation angle.A considerable number of microcracks and particle peeling pits can be observed on SC-CO_(2)-induced fracture surface while there are more flat particle surfaces in water-induced fracture surface through SEM images,indicating that fractures tend to propagate along the boundary of the particle for SC-CO_(2)fracturing while water-induced fractures prefer to cut through particles.These findings are of great significance for analyzing fracture mechanism and evaluating fracturing stimulation performance.
文摘Based on analysis of geophysical data such as core observation, rock slices identification, physical property, scanning electron microscope, X-ray diffraction, logging data etc., 16 factors of sedimentation, diagenesis, fluid pressure, and their relationships with reservoir physical property were analyzed, and the results indicate sedimentation is the internal factor controlling the reservoir property, diagenesis is the external and final decisive factor and abnormal fluid pressure is an important factor preserving the deep reservoir property. Quantitative characterization of diagenesis indicates that compaction and dissolution are more important than cementation and they respectively cause porosity change of-23.6% and 7.7% and -6.2%. Through optimizing 11 main controlling factors and constructing reservoir evaluation index (REI) according to the hierarchical cluster and principal component analysis, reservoir classification standard was established and reservoirs were divided into four classes. The studies show that Es~ SQ4 consists mainly of class I and II, while Es~ SQ6 is mainly of class III and II; the favorable zone is the north and south slope of Qibei sub-sag and the Liujianfang fault-nose. The successful application of the quantitative and comprehensive evaluation in the Qibei area verifies the advanced, practicable method of less artificial factor is suitable for the low porosity and permeability reservoir.
基金supported by the National Key Basic Research and Development Program(973 Program)of China(No.2014CB239000)the China National Science and Technology Major Projects(No.2017ZX05001)the Petrochina Science and Technology Major Projects(No.2016B-0304).
文摘The microscopic pore structure of sand-conglomerate rocks plays a decisive role in its exploration and development of such reservoirs.Due to complex gravels-cements configurations and resultant high heterogeneity in sand-conglomerate rocks,the conventional fractal dimensions are inadequate to fully characterize the pore space.Based on the Pia Intermingled Fractal Units(IFU)model,this paper presents a new variable-ratio factor IFU model,which takes tortuosity and boundary layer thickness into consideration,to characterize the Triassic Karamay Formation conglomerate reservoirs in the Mahu region of the Junggar Basin,Northwest China.The modified model has a more powerful and flexible ability to simulate pore structures of porous media,and the simulation results are closer to the real conditions of pore space in low-porosity and low-permeability reservoirs than the conventional Pia IFU model.The geometric construction of the model is simplified to allow for an easing of computation.Porosity and spectral distribution of pore diameter,constructed using the modified model,are generally consistent with actual core data.Also,the model-computed permeability correlates well with experimental results,with a relative error of less than 15%.The modified IFU model performs well in quantitatively characterizing the heterogeneity of sand-conglomerate pore structures,and provides a methodology for the study of other similar types of heterogeneous reservoirs.
基金financially supported by the Nuclear Material Technology Innovation Center for National Defense Technology and Industry(No.ICNM-2019-YZ-03)。
文摘At present,Nb_(3) Sn superconductors are becoming more popular in high magnetic fields.The growth law of Nb_(3) Sn phase in a planar CuSn/Nb diffusion couple has been studied,whereas the formation mechanism of Nb_(3) Sn phase in a cylindrical CuSn/Nb diffusion couple is still controversial.The purpose of this work is to investigate the growth exponent of Nb_(3) Sn phase at the initial stage of annealing by use of scanning electron microscopy(SEM)through which the thickness of Nb_(3) Sn layer can be obtained.In this study,bronze-processed Nb_(3) Sn multifilamentary wires with different annealing time were investigated.The Nb_(3) Sn phase was formed during isothermal annealing at 670 ℃ by solid-state diffusion,which was accomplished by the movement of Sn atoms from the CuSn/Nb_(3) Sn interface to Nb_(3) Sn/Nb interface.However,the formation mechanism of Nb_(3) Sn phase at the initial stage of annealing is still not well understood.Microstructural evolution of Nb_(3) Sn phase during isothermal annealing was studied by SEM.The mean thickness of the Nb_(3) Sn layer(Δ(xNn3 Sn)) is expressed as a power function of the annealing time(t) by the equation A_(x^(2)Nb_(3) Sn)=k(t/t0)^(n),where t0 is the unit time,k is the reaction rate constant and n is the growth exponent.The growth exponent has the average value of 0.82,which means that the formation of the Nb_(3) Sn phase is both governed by the interface reaction and the grain boundary diffusion.