Dissimilar AZ31B magnesium alloy and DC56D steel were welded via AA1060 aluminum alloy by magnetic pulse welding.The effects of primary and secondary welding processes on the welded interface were comparatively invest...Dissimilar AZ31B magnesium alloy and DC56D steel were welded via AA1060 aluminum alloy by magnetic pulse welding.The effects of primary and secondary welding processes on the welded interface were comparatively investigated.Macroscopic morphology,microstructure,and interfacial structure of the joints were analyzed using scanning electron microscope,energy dispersive spectrometer,and X-ray diffractometer(XRD).The results show that magnetic pulse welding of dissimilar Mg/Fe metals is achieved using an Al interlayer,which acts as a bridge for deformation and diffusion.Specifically,the AZ31B/AA1060 interface exhibits a typical wavy morphology,and a transition zone exists at the joint interface,which may result in an extremely complex microstructure.The microstructure of this transition zone differs from that of AZ31B magnesium and 1060 Al alloys,and it is identified as brittle intermetallic compounds(IMCs)Al_(3)Mg_(2) and Al_(12)Mg_(17).The transition zone is mainly distributed on the Al side,with the maximum thickness of Al-side transition layer reaching approximately 13.53μm.Incomplete melting layers with varying thicknesses are observed at the primary weld interface,while micron-sized hole defects appear in the transition zone of the secondary weld interface.The AA1060/DC56D interface is mainly straight,with only a small number of discontinuous transition zones distributed intermittently along the interface.These transition zones are characterized by the presence of the brittle IMC FeAl_(3),with a maximum thickness of about 4μm.展开更多
Low-density short-duration pulsed current-assisted aging treatment was applied to the Ti-6Al-4V-0.5Mo-0.5Zr alloy subjected to different solution treatments.The results show that numerous α_(p) phases redissolve into...Low-density short-duration pulsed current-assisted aging treatment was applied to the Ti-6Al-4V-0.5Mo-0.5Zr alloy subjected to different solution treatments.The results show that numerous α_(p) phases redissolve into the new β phase during the pulsed current-assisted aging process,and then the newly formed β phase is mainly transformed into the β_(t) phase,with occasional transition to new α_(p) phase,leading to a remarkable grain refinement,especially for the lamellarαs phases.In comparison to conventional aging treatment,the pulsed current-assisted aging approach achieves a significant enhancement in strength without degrading ductility,yielding an excellent mechanical property combination:a yield strength of 932 MPa,a tensile strength of 1042 MPa,and an elongation of 12.2%.It is primarily ascribed to the increased fraction of β_(t) phases,the obvious grain refinement effect,and the slip block effect induced by the multiple-variantαs colonies distributed within β_(t) phases.展开更多
The paper is an introduction to the front-end pulse acquisition and the back-end pulse biomimetic reproduction system.This system is capable of faithfully replicating the complete pulse waveform collected at the front...The paper is an introduction to the front-end pulse acquisition and the back-end pulse biomimetic reproduction system.This system is capable of faithfully replicating the complete pulse waveform collected at the front end.Traditional Chinese Medicine(TCM)practitioners analyze and diagnose the pulse patterns at the replication end.Meanwhile,the obtained pulse waveforms are analyzed and learnt by a neural network based on key diagnostic points in TCM pulse taking,which enables the determination of the corresponding relationships between different pulse waveforms and various pulse patterns in TCM pulse taking.With the support of clinical samples,an auxiliary diagnostic system for TCM pulse patterns ensures the accuracy of pulse pattern replication.展开更多
We propose an all-optical,single-laser-pulse scheme for generating a dense relativistic strongly magnetized electron-positron pair plasma.The scheme involves the interaction of an extremely intense(I■10^(24) W/cm^(2)...We propose an all-optical,single-laser-pulse scheme for generating a dense relativistic strongly magnetized electron-positron pair plasma.The scheme involves the interaction of an extremely intense(I■10^(24) W/cm^(2))circularly polarized laser pulse with a solid-density target containing a conical cavity.Through full-scale three-dimensional particle-in-cell simulations that account for quantum electrodynamic effects,it is shown that this interaction results in two significant outcomes:first,the generation of quasi-static magnetic fields reaching tens of gigagauss,and,second,the production of large quantities of electron-positron pairs(up to 10^(13))via the Breit-Wheeler process.The e^(-)e^(+)plasma becomes trapped in the magnetic field and remains confined in a small volume for hundreds of femtoseconds,far exceeding the laser timescale.The dependence of pair plasma parameters,as well as the efficiency of plasma production and confinement,is discussed in relation to the properties of the laser pulse and the target.Realizing this scheme experimentally would enable the investigation of physical processes relevant to extreme astrophysical environments.展开更多
Precise experimental control and characterization of electron wave packet dynamics driven by external optical fields remain a fundamental challenge,particularly at ultrafast temporal and sub-microscopic spatial scales...Precise experimental control and characterization of electron wave packet dynamics driven by external optical fields remain a fundamental challenge,particularly at ultrafast temporal and sub-microscopic spatial scales.To overcome these challenges,we introduce a photon-based simulation platform employing a traveling-wave electrooptic phase-modulated waveguide.In our setup,the incident electromagnetic pulse serves as an analog to the electron wave packet,while the traveling-wave modulation simulates the external optical driving field.Our experimental study systematically explores pulse evolution under three distinct regimes defined by the relation between the pulse duration(Δt)and the modulation period(T).When the pulse duration is significantly shorter than the modulation period,we observe a uniform spectral shift analogous to electron acceleration in dielectric laser accelerators,where spectral phase gradients represent electron momentum accumulation.Conversely,when the pulse duration greatly exceeds the modulation period,discrete diffraction patterns emerge,closely resembling the discrete sideband features of electron-photon coupling observed in photon-induced near-field electron microscopy.Notably,in the intermediate regime(T/4<Δt<T/2),the pulse spectrum exhibits Airy-function-type characteristics with self-healing effects.These experimental results provide critical insights into electron-wave interactions under external optical fields and establish a robust,programmable framework for further investigation.展开更多
Doping with Ga effectively enhances the crystal quality and optical detection efficiency of zinc oxide(Zn O)single crystals,which has attracted considerable research interest in radiation detection.The application of ...Doping with Ga effectively enhances the crystal quality and optical detection efficiency of zinc oxide(Zn O)single crystals,which has attracted considerable research interest in radiation detection.The application of Zn O:Ga(GZO)in nuclear energy is particularly significant and fascinating at the fundamental level,enabling neutron/gamma discrimination while preserving the response time properties of the single crystal in sub-nanoseconds,maximizing the effective counting rate of the pulsed radiation field.In this study,the single-particle waveform discrimination characteristics of GZO were evaluated for five charged particles(α,β,H^(+),Li^(+),and O^(8+)and two prevalent uncharged particles(neutrons and gamma rays).Based on the timecorrelation single-photon counting(TCSPC)method,the luminescence decay time constants of the charged particles in the GZO crystal were determined as follows:1.21 ns for H^(+),1.50 ns for Li^(+),1.70 ns for O^(8+),1.56 ns forαparticles,and 1.09 ns forβparticles.Visible differences in the excitation time spectra curves were observed.Using the conventional time-domain or frequency-domain waveform discrimination techniques,waveform discrimination of 14.9 Me V neutrons and secondary gamma rays generated by the CPNG-6 device based on GZO scintillation was successfully implemented.The neutron signal constituted 77.93%of the total,indicating that GZO exhibited superior neutron/gamma discrimination sensitivity compared with that of a commercial stilbene crystal.Using the neutron/gamma screening outcomes,we reconstructed the voltage pulse height,charge height,and neutron multiplication time spectra of the pulsed neutron radiation field.The reconstructed neutron multiplication time spectrum exhibited a deviation of less than 3%relative to the result obtained using a commercial stilbene scintillator.This is the first report in the open literature on the neutron/gamma discrimination and reconstruction of Zn O pulsed radiation-field information.展开更多
As a critical component of pulse solid rocket motors(SRMs),the soft pulse separation device(PSD)is vital in enabling multi-pulse propulsion and has become a breakthrough in SRM engineering applications.To investigate ...As a critical component of pulse solid rocket motors(SRMs),the soft pulse separation device(PSD)is vital in enabling multi-pulse propulsion and has become a breakthrough in SRM engineering applications.To investigate the opening performance of the PSD,an axial PSD incorporating a star-shaped prefabricated defect was designed.The opening process was simulated using peridynamics,yielding the strain field distribution and the corresponding failure mode.A single-opening verification test was conducted.The simulation results showed good agreement with the experimental data,demonstrating the reliability of the peridynamic modeling approach.Furthermore,the effects of the prefabricated defect shape and depth on the opening performance of the PSD were analyzed through simulation.The research results indicate that the established constitutive model and failure criteria based on peridynamics can reasonably predict the failure location and the opening pressure of the soft PSD.Under the impact loading,the weak zone of the soft PSD firstly ruptures,and the damaged area gradually propagates along with the prefabricated defect,eventually leading to complete separation.A smaller prefabricated defect depth or a wider prefabricated defect distribution can cause a reduction in opening pressure.These research results provide valuable guidance for the preliminary design and optimization of PSDs in pulse solid rocket motors.展开更多
A mid-infrared femtosecond pulse laser with a single cycle and high intensity is an ideal driving light source for generating isolated attosecond pulses. Due to current experimental limitations, it is difficult to dir...A mid-infrared femtosecond pulse laser with a single cycle and high intensity is an ideal driving light source for generating isolated attosecond pulses. Due to current experimental limitations, it is difficult to directly achieve this type of laser light source in the laboratory. In this paper, we obtain such an ideal light source by adding a Ti sapphire pulse to the combined pulse laser consisting of two mid-infrared pulses. Specifically, by combining the synthesized pulse consisting of 8 fs/1200 nm/1.62 × 10^(14)W cm^(-2)and 12 fs/1800 nm/2.71 × 10^(14)W cm^(-2)with an additional 8 fs/800 nm/1.26 × 10^(14)W cm^(-2)Ti sapphire pulse, the resulting electric field waveform is very close to that of a 1170 nm femtosecond pulse with an intensity of 1.4 × 10^(15)W cm^(-2), a single-cycle pulse width, and a carrier-envelope phase of 0.25π. Numerical simulations show that both cases produce high-order harmonic emission spectra with broadband supercontinuum spectra, however, the bandwidth of the supercontinuum spectra and the harmonic intensities in the synthesized pulses are significantly better than those in the single1170 nm pulse. After inverse Fourier transform, we obtain 66 as a high-intensity isolated attosecond pulse, whose intensity is five orders of magnitude higher than that of a monochromatic field. Here, the phase differences between three combined pulse lasers have little effect on the numerical simulation results when they vary in the range of 0.3π.展开更多
Pulsed magnet technology is the only way to generate ultra-strong magnetic fields higher than 45 T so far.However,the inherently fast-changing field strength(typically on the order of 1000 T/s)poses significant challe...Pulsed magnet technology is the only way to generate ultra-strong magnetic fields higher than 45 T so far.However,the inherently fast-changing field strength(typically on the order of 1000 T/s)poses significant challenges for spectroscopic measurements which rely on time integration of signals to improve spectral qualities.In this work,we report high-sensitivity spectroscopic measurements under pulsed high magnetic fields employing the long flat-top pulsed magnetic field technique.By means of a multiple-capacitor power supply,we were able to generate pulsed high magnetic fields with controllable flat-top pulse width and field stabilities.By synchronizing spectroscopic measurements with the waveform of the flattop magnetic field,the integration time of each spectrum can be increased by up to 100 times compared with that of the conventional spectroscopic measurements under pulsed magnetic fields,thus enabling high-sensitivity spectroscopic measurements under ultra-strong pulsed magnetic fields.These findings promise an efficient way to significantly improve the performance and extend the application of optical measurements under pulsed high magnetic fields.展开更多
Attosecond light pulses have revolutionized the study of electron dynamics in materials by enabling the observation of ultrafast processes with unprecedented attosecond temporal resolution.They are primarily generated...Attosecond light pulses have revolutionized the study of electron dynamics in materials by enabling the observation of ultrafast processes with unprecedented attosecond temporal resolution.They are primarily generated through the process of high-order harmonic generation.This paper presents a comprehensive setup for attosecond pulse generation and measurement.Using a 900 nm,7 mJ,and 7 fs femtosecond laser with stabilized carrier-envelope phase,we employ polarization gating to generate a near single-cycle,linearly polarized pulse that interacts with neon gas to produce a broadband extreme-ultraviolet continuum with a cutoff photon energy of∼120 eV.The temporal and spectral characteristics of the generated single attosecond pulses are measured using an attosecond streak camera,and the pulse duration is determined to be 59 as through the frequency-resolved optical gating for complete reconstruction of attosecond bursts retrieval algorithm.As part of the Synergetic Extreme Condition User Facility,this setup will facilitate ultrafast research in transient absorption and photoelectron spectroscopy,providing global users with a powerful tool for studying electron dynamics in various materials.展开更多
A singlet diatomic molecule naturally carries doubly degenerate ±Λ states when the projection of the total electronic angular momentum onto the internuclear axis is nonzero. These doubly degenerate states contri...A singlet diatomic molecule naturally carries doubly degenerate ±Λ states when the projection of the total electronic angular momentum onto the internuclear axis is nonzero. These doubly degenerate states contribute equally in conventional measurements and are thus treated the same in corresponding simulations. In this study, we demonstrate that in resonant excitation by intense laser pulses, the doubly degenerate ±Λ states must be clearly identified. This is exemplified in the X^(1)Σ → A^(1)Π transition of CO molecules. This distinction becomes especially important in the case of circularly polarized radiation. We attribute this phenomenon to the interference of electron-rotational pathways in the strong-field coupled transition with the ±Λ-state of the excited Π state. This research sheds light on the fundamental aspects of intense laser-molecule interactions when extending conventional theories.展开更多
The generation and reconnection of magneticflux ropes in a plasma irradiated by two Laguerre–Gaussian laser pulses with different frequen-cies and opposite topological charges are investigated numerically by particle-...The generation and reconnection of magneticflux ropes in a plasma irradiated by two Laguerre–Gaussian laser pulses with different frequen-cies and opposite topological charges are investigated numerically by particle-in-cell simulations.It is shown that twisted plasma currents and hence magneticflux ropes can be effectively generated as long as the laser frequency difference matches the electron plasma frequency.More importantly,subsequent reconnection of magneticflux ropes can occur.Typical signatures of magnetic reconnection,such as magnetic island formation and plasma heating,are identified in the reconnection of magneticflux ropes.Notably,it is found that a strong axial magneticfield can be generated on the axis,owing to the azimuthal current induced during the reconnection of the ropes.This indicates that in the reconnection of magneticflux ropes,the energy can be transferred not only from the magneticfield to the plasma but also from the plasma current back to the magneticfield.This work opens a new avenue to the study of magneticflux ropes,which helps in understanding magnetic topology changes,and resultant magnetic energy dissipation,plasma heating,and particle acceleration found in solarflares,and magnetic confinement fusion devices.展开更多
A self-pulsed Tm:GdScO_(3)laser was experimentally demonstrated by using a compact linear resonant cavity.When the pump power was 19.6 W,an average output power of 1771 m W was achieved from the self-pulsed Tm:GdScO_(...A self-pulsed Tm:GdScO_(3)laser was experimentally demonstrated by using a compact linear resonant cavity.When the pump power was 19.6 W,an average output power of 1771 m W was achieved from the self-pulsed Tm:GdScO_(3)laser with a pulse width of 158.1 ns and a pulse repetition frequency of 112.8 kHz,corresponding to an optical-to-optical conversion efficiency of 9.0%.Moreover,a single pulse energy of 15.7μJ and a pulse peak power of 99.3 W were acquired from the self-pulsed Tm:GdScO_(3)laser.This is,as we know,the first time that the self-pulsed laser output at 2-μm waveband range was obtained by utilizing a Tm:GdScO_(3)crystal so far.展开更多
OBJECTIVE:To analyze the Doppler ultrasound blood flow of Renying(carotid artery)pulse,Cunkou(radial artery)pulse,and Fuyang(anterior tibial artery)pulse in the normal group and the functional constipation with gastro...OBJECTIVE:To analyze the Doppler ultrasound blood flow of Renying(carotid artery)pulse,Cunkou(radial artery)pulse,and Fuyang(anterior tibial artery)pulse in the normal group and the functional constipation with gastrointestinal heat(FCGH)group,and to compare and explore the differences of Renying,Cunkou and Fuyang pulses.METHODS:Sixty normal subjects and 60 patients with gastrointestinal heat constipation were collected in the department of ultrasound,Beijing Anzhen Hospital,Capital Medical University.Doppler ultrasound was used to observe the blood flow indexes including maximum systolic velocity(Vp),maximum diastolic velocity(Vd),mean velocity(Vm),pulse index(PI),resistance index(RI),vascular diameter(D),and circulation blood flow cycle(ET)of Renying pulse,Cunkou pulse and Fuyang pulse in the normal group and patients with gastrointestinal heat constipation.The differences of these three pulses were compared between the normal group and the FCGH group.RESULTS:The PI,Vp,Vm,RI,and D of the three pulses in the normal group were statistically significant different(P<0.01).In the comparison of Doppler flow diagram of three pulses in the FCGH group,there were significant differences in PI,Vd,Vp,Vm,RI,and D(P<0.01).CONCLUSION:Under normal conditions,the indexes of Renying pulse Doppler flow diagram,Cunkou pulse Doppler flow diagram,and Fuyang pulse Doppler flow diagram are significantly different.In the FCGH group,most of the indexes of Renying pulse Doppler flow diagram,Cunkou pulse Doppler flow diagram,and Fuyang pulse Doppler flow diagram are different.This result verified the necessity of simultaneous examinations of all Renying,Cunkou,and Fuyang pulses in modern Chinese medicine.展开更多
Non-metallic inclusions in steel are a significant challenge,affecting material properties and leading to issues such as stress concentration,cracking,and accelerated corrosion.Current methods for removing inclusions,...Non-metallic inclusions in steel are a significant challenge,affecting material properties and leading to issues such as stress concentration,cracking,and accelerated corrosion.Current methods for removing inclusions,including bubble,electromagnetic stirring,filtration separation,fluid flow,and sedimentation,often struggle with the removal of fine inclusions.Apart from these known methods,pulsed electric current(PEC),as an emerging technology,has demonstrated immense potential and environmental advantages.PEC offers adjustable current parameters and simple equipment,making it an attractive alternative to traditional methods.Its green energy-saving features and excellent results in regulating inclusion morphology and migration,as well as inhibiting submerged entry nozzle(SEN)clogging,make it a promising technology.In comparison to continuous current technology,PEC has shown significant advantages in regulating inclusions,not only improving purification efficiency but also demonstrating outstanding performance in flow stability and energy consumption.The ability of PEC to efficiently reduce inclusion numbers enhances the purity and quality of molten steel,improving its mechanical properties.Currently,the theoretical basis for controlling the movement of inclusions by current is mainly composed of three major theories:the double electric layer theory,electromagnetic force reverse separation theory,and electric free energy drive theory.These theories together form an important framework for researchers to understand and optimize the behavior of impurity movement controlled by electric current.Looking ahead,PEC is expected to pave the way for new solutions in directional regulation of inclusion migration,efficient inclusion removal,SEN clogging prevention,and the purification of molten steel.展开更多
The transition of hydrogen sourcing from carbon-intensive to water-based methodologies is underway,with renewable energy-powered proton exchange membrane water electrolysis(PEMWE)emerging as the preeminent pathway for...The transition of hydrogen sourcing from carbon-intensive to water-based methodologies is underway,with renewable energy-powered proton exchange membrane water electrolysis(PEMWE)emerging as the preeminent pathway for hydrogen production.Despite remarkable advancements in this field,confronting the sluggish electrochemical kinetics and inherent high-energy consumption arising from deteriorated mass transport within PEMWE systems remains a formidable obstacle.This impediment stems primarily from the hindered protons mass transfer and the untimely hydrogen bubbles detachment.To address these challenges,we harness the inherent variability of electrical energy and introduce an innovative pulsed dynamic water electrolysis system.Compared to constant voltage electrolysis(hydrogen production rate:51.6 m L h^(-1),energy consumption:5.37 kWh Nm-^(3)H_(2)),this strategy(hydrogen production rate:66 m L h^(-1),energy consumption:3.83 kWh Nm-^(3)H_(2))increases the hydrogen production rate by approximately 27%and reduces the energy consumption by about 28%.Furthermore,we demonstrate the practicality of this system by integrating it with an off-grid photovoltaic(PV)system designed for outdoor operation,successfully driving a hydrogen production current of up to 500 mA under an average voltage of approximately 2 V.The combined results of in-situ characterization and finite element analysis reveal the performance enhancement mechanism:pulsed dynamic electrolysis(PDE)dramatically accelerates the enrichment of protons at the electrode/solution interface and facilitates the release of bubbles on the electrode surface.As such,PDE-enhanced PEMWE represents a synergistic advancement,concurrently enhancing both the hydrogen generation reaction and associated transport processes.This promising technology not only redefines the landscape of electrolysis-based hydrogen production but also holds immense potential for broadening its application across a diverse spectrum of electrocatalytic endeavors.展开更多
In this paper, we have demonstrated an Er-doped ultrafast laser with a single mode fiber-gradient index multimode fiber-single mode fiber(SMF-GIMF-SMF, SMS) structure as saturable absorber(SA), which can generate not ...In this paper, we have demonstrated an Er-doped ultrafast laser with a single mode fiber-gradient index multimode fiber-single mode fiber(SMF-GIMF-SMF, SMS) structure as saturable absorber(SA), which can generate not only stable single-pulse state, but also special mode-locked pulses with the characteristics of high energy and noisy behaviors at proper pump power and cavity polarization state. In addition, we have deeply investigated the real-time spectral evolutions of the mode-locked pulses through the dispersive Fourier transformation(DFT) technique. It can be found that the pulse regime can actually consist of a lot of small noise pulses with randomly varying intensities. We believe that these results will further enrich the nonlinear dynamical processes in the ultrafast lasers.展开更多
Green hydrogen production by alkaline water electrolysis is an important technology in the decarbonization of the current industry.However,its large-scale application is limited by mediocre performance of conventional...Green hydrogen production by alkaline water electrolysis is an important technology in the decarbonization of the current industry.However,its large-scale application is limited by mediocre performance of conventional Raney Ni electrocatalysts.Herein,high-performance NiMoZn alloy catalysts of the Raney Ni type are developed by pulse electrodeposition for the hydrogen evolution reaction(HER).The optimized catalyst,NMZ-CA,exhibits an overpotential of 37 mV at 10 mA·cm^(-2) and a Tafel slope of 27 mV·dec^(-1) in 1 mol·L^(-1) KOH.Tafel slope measurements,X-ray photoelectron spectroscopy,and H_(2) temperatureprogrammed desorption experiments show that the incorporation of Mo and Zn in Ni weakens the binding of HER intermediate(H_(ads))on strongly adsorbing sites,leading to improved electrochemical kinetics.Electron microscopy and X-ray diffraction study reveals that a phase-pure Mo-doped Ni2Zn11 intermetallic precatalyst formed via pulse electrodeposition and subsequent heat treatment is key to the structure integrity and performance of the catalyst after activation by alkaline leaching.Modificationof NMZ-CA with PTFE enhances its HER performance by facilitating gas removal and improving structure integrity.A practical alkaline water electrolyzer built on the modifiedNMZ/PTFE-CA electrode delivers 2.0 A·cm^(-2) at 1.92 V cell voltage and operates for 250 h without decay.This work provides insights into the synergy between Ni,Mo,and Zn in Raney Ni-type catalysts,and demonstrates the hydrophobic modification as an effective strategy for electrode development in high-performance alkaline water electrolysis.展开更多
Polymethyl methacrylate(PMMA)is an optically transparent thermoplastic with favorable processing conditions.In this study,a series of plastic scintillators are prepared via thermal polymerization,and the impact of PMM...Polymethyl methacrylate(PMMA)is an optically transparent thermoplastic with favorable processing conditions.In this study,a series of plastic scintillators are prepared via thermal polymerization,and the impact of PMMA content on their transparency and pulse shape discrimination(PSD)ability is investigated.The fabricated samples,comprising a polystyrene(PS)-PMMA matrix,30.0 wt%2,5-diphenyloxazole(PPO),and 0.2 wt%9,10-diphenylanthracene(DPA),exhibit high transparency with transmissivity ranging from 70.0 to 90.0%(above 415.0 nm)and demonstrate excellent n/γdiscrimination capability.Transparency increased with increasing PMMA content across the entire visible light spectrum.However,the PSD performance gradually deteriorated when the aromatic matrix was replaced with PMMA.The scintillator containing 20.0 wt%PMMA demonstrated the best stability concerning PSD properties and relative light yields.展开更多
Objective To develop an onset risk prediction nomogram for patients with homocysteine-type(H-type)hypertension(HTH)based on pulse diagram parameters to assist early clinical prediction and diagnosis of HTH.Methods Pat...Objective To develop an onset risk prediction nomogram for patients with homocysteine-type(H-type)hypertension(HTH)based on pulse diagram parameters to assist early clinical prediction and diagnosis of HTH.Methods Patients diagnosed with essential hypertension and admitted to Shanghai Shuguang Hospital Affiliated to Shanghai University of Traditional Chinese Medicine,Shang-hai Hospital of Traditional Chinese Medicine,and Shanghai Hospital of Integrated Tradition-al Chinese and Western Medicine from July 6th 2020 to June 16th 2021,and from August 11th 2023 to January 22nd 2024,were enrolled in this retrospective research.The baselines and clinical biochemical indicators of patients were collected.The SMART-I TCM pulse instru-ment was applied to gather pulse diagram parameters.Multivariate logistic regression was adopted to analyze the risk factors for HTH.RStudio was employed to construct the nomo-gram model,receiver operating characteristic(ROC)curve,and calibration curve(bootstrap self-sampling 200 times),and clinical decision curve were drawn to evaluate the model’s dis-crimination and clinical effectiveness.Results A total of 168 hospitalized patients with essential hypertension were selected and di-vided into non-HTH group(n=29)and HTH group(n=139).Compared with non-HTH group,HTH group had a lower body mass index(BMI),and higher proportions of male pa-tients and drinkers(P<0.05).The ventricular wall thickening(VWT)could not be deter-mined.The proportions of left common carotid intima-media wall thickness(LCCIMWT)and serum creatinine(SCR)were higher in HTH group(P<0.05).The pulse diagram parameter As was significantly higher,and H4/H1 and T1/T were lower in HTH group(P<0.05).Gender,al-cohol consumption,serum creatinine,and the pulse diagram parameter H4/H1 were identi-fied as independent risk factors for HTH(P<0.05).The nomogram’s area under the ROC curve(AUC)was 0.795[95%confidence interval(CI):(0.7066,0.8828)],with a specificity of 0.724 and sensitivity of 0.799.After 200 times repeated bootstrap self-samplings,the calibra-tion curve showed that the simulated curve fits well with the actual curve(x^(2)=9.5002,P=0.3019).The clinical decision curve indicated that the nomogram’s applicability was optimal when the threshold for predicting HTH was between 0.38 and 1.00.Conclusion The nomogram model could be valuable for predicting the onset risk of HTH and pulse diagram parameters can facilitate early screening and prevention of HTH.展开更多
文摘Dissimilar AZ31B magnesium alloy and DC56D steel were welded via AA1060 aluminum alloy by magnetic pulse welding.The effects of primary and secondary welding processes on the welded interface were comparatively investigated.Macroscopic morphology,microstructure,and interfacial structure of the joints were analyzed using scanning electron microscope,energy dispersive spectrometer,and X-ray diffractometer(XRD).The results show that magnetic pulse welding of dissimilar Mg/Fe metals is achieved using an Al interlayer,which acts as a bridge for deformation and diffusion.Specifically,the AZ31B/AA1060 interface exhibits a typical wavy morphology,and a transition zone exists at the joint interface,which may result in an extremely complex microstructure.The microstructure of this transition zone differs from that of AZ31B magnesium and 1060 Al alloys,and it is identified as brittle intermetallic compounds(IMCs)Al_(3)Mg_(2) and Al_(12)Mg_(17).The transition zone is mainly distributed on the Al side,with the maximum thickness of Al-side transition layer reaching approximately 13.53μm.Incomplete melting layers with varying thicknesses are observed at the primary weld interface,while micron-sized hole defects appear in the transition zone of the secondary weld interface.The AA1060/DC56D interface is mainly straight,with only a small number of discontinuous transition zones distributed intermittently along the interface.These transition zones are characterized by the presence of the brittle IMC FeAl_(3),with a maximum thickness of about 4μm.
基金National Key Research and Development Program of China(2021YFB3700801)。
文摘Low-density short-duration pulsed current-assisted aging treatment was applied to the Ti-6Al-4V-0.5Mo-0.5Zr alloy subjected to different solution treatments.The results show that numerous α_(p) phases redissolve into the new β phase during the pulsed current-assisted aging process,and then the newly formed β phase is mainly transformed into the β_(t) phase,with occasional transition to new α_(p) phase,leading to a remarkable grain refinement,especially for the lamellarαs phases.In comparison to conventional aging treatment,the pulsed current-assisted aging approach achieves a significant enhancement in strength without degrading ductility,yielding an excellent mechanical property combination:a yield strength of 932 MPa,a tensile strength of 1042 MPa,and an elongation of 12.2%.It is primarily ascribed to the increased fraction of β_(t) phases,the obvious grain refinement effect,and the slip block effect induced by the multiple-variantαs colonies distributed within β_(t) phases.
基金Key R&D Plan of Liaoning Province(No.202000357-JH13/103):Construction of Liaoning Traditional Chinese Medicine Industry Technology Innovation Research InstituteNational Key Research and Development Plan Special Project(No.2019JH2/10300040)。
文摘The paper is an introduction to the front-end pulse acquisition and the back-end pulse biomimetic reproduction system.This system is capable of faithfully replicating the complete pulse waveform collected at the front end.Traditional Chinese Medicine(TCM)practitioners analyze and diagnose the pulse patterns at the replication end.Meanwhile,the obtained pulse waveforms are analyzed and learnt by a neural network based on key diagnostic points in TCM pulse taking,which enables the determination of the corresponding relationships between different pulse waveforms and various pulse patterns in TCM pulse taking.With the support of clinical samples,an auxiliary diagnostic system for TCM pulse patterns ensures the accuracy of pulse pattern replication.
基金supported by BMBF-Project No.05P24PF1DFG Project No.PU 213/6-3.
文摘We propose an all-optical,single-laser-pulse scheme for generating a dense relativistic strongly magnetized electron-positron pair plasma.The scheme involves the interaction of an extremely intense(I■10^(24) W/cm^(2))circularly polarized laser pulse with a solid-density target containing a conical cavity.Through full-scale three-dimensional particle-in-cell simulations that account for quantum electrodynamic effects,it is shown that this interaction results in two significant outcomes:first,the generation of quasi-static magnetic fields reaching tens of gigagauss,and,second,the production of large quantities of electron-positron pairs(up to 10^(13))via the Breit-Wheeler process.The e^(-)e^(+)plasma becomes trapped in the magnetic field and remains confined in a small volume for hundreds of femtoseconds,far exceeding the laser timescale.The dependence of pair plasma parameters,as well as the efficiency of plasma production and confinement,is discussed in relation to the properties of the laser pulse and the target.Realizing this scheme experimentally would enable the investigation of physical processes relevant to extreme astrophysical environments.
基金supported by the National Natural Science Foundation of China(Grant No.12174260)the Shanghai Rising-Star Program(Grant No.21QA1406400)+1 种基金the Shanghai Science and Technology Development Fund(Grant Nos.21ZR1443500 and 21ZR1443600)supported by Research Grants Council,University Grants Committee(Grant Nos.STG3/E-704/23-N,CityU 11212721,and CityU 11204523).
文摘Precise experimental control and characterization of electron wave packet dynamics driven by external optical fields remain a fundamental challenge,particularly at ultrafast temporal and sub-microscopic spatial scales.To overcome these challenges,we introduce a photon-based simulation platform employing a traveling-wave electrooptic phase-modulated waveguide.In our setup,the incident electromagnetic pulse serves as an analog to the electron wave packet,while the traveling-wave modulation simulates the external optical driving field.Our experimental study systematically explores pulse evolution under three distinct regimes defined by the relation between the pulse duration(Δt)and the modulation period(T).When the pulse duration is significantly shorter than the modulation period,we observe a uniform spectral shift analogous to electron acceleration in dielectric laser accelerators,where spectral phase gradients represent electron momentum accumulation.Conversely,when the pulse duration greatly exceeds the modulation period,discrete diffraction patterns emerge,closely resembling the discrete sideband features of electron-photon coupling observed in photon-induced near-field electron microscopy.Notably,in the intermediate regime(T/4<Δt<T/2),the pulse spectrum exhibits Airy-function-type characteristics with self-healing effects.These experimental results provide critical insights into electron-wave interactions under external optical fields and establish a robust,programmable framework for further investigation.
基金supported by the National Natural Science Foundation of China(Nos.12205370,62204198,12305205,and 12105230)Young Talents Promotion Program of Shaanxi Provincial Science and Technology Association(No.20220514)。
文摘Doping with Ga effectively enhances the crystal quality and optical detection efficiency of zinc oxide(Zn O)single crystals,which has attracted considerable research interest in radiation detection.The application of Zn O:Ga(GZO)in nuclear energy is particularly significant and fascinating at the fundamental level,enabling neutron/gamma discrimination while preserving the response time properties of the single crystal in sub-nanoseconds,maximizing the effective counting rate of the pulsed radiation field.In this study,the single-particle waveform discrimination characteristics of GZO were evaluated for five charged particles(α,β,H^(+),Li^(+),and O^(8+)and two prevalent uncharged particles(neutrons and gamma rays).Based on the timecorrelation single-photon counting(TCSPC)method,the luminescence decay time constants of the charged particles in the GZO crystal were determined as follows:1.21 ns for H^(+),1.50 ns for Li^(+),1.70 ns for O^(8+),1.56 ns forαparticles,and 1.09 ns forβparticles.Visible differences in the excitation time spectra curves were observed.Using the conventional time-domain or frequency-domain waveform discrimination techniques,waveform discrimination of 14.9 Me V neutrons and secondary gamma rays generated by the CPNG-6 device based on GZO scintillation was successfully implemented.The neutron signal constituted 77.93%of the total,indicating that GZO exhibited superior neutron/gamma discrimination sensitivity compared with that of a commercial stilbene crystal.Using the neutron/gamma screening outcomes,we reconstructed the voltage pulse height,charge height,and neutron multiplication time spectra of the pulsed neutron radiation field.The reconstructed neutron multiplication time spectrum exhibited a deviation of less than 3%relative to the result obtained using a commercial stilbene scintillator.This is the first report in the open literature on the neutron/gamma discrimination and reconstruction of Zn O pulsed radiation-field information.
基金supported by the National Natural Science Foundation of China(No.12202011)the Youth Research fund of Shanghai Academy of Spaceflight Technology(KJW-KT-QNKYJJ-2022-25)China Postdoctoral Science Foundation(Nos.2024T170009,2022M710190).
文摘As a critical component of pulse solid rocket motors(SRMs),the soft pulse separation device(PSD)is vital in enabling multi-pulse propulsion and has become a breakthrough in SRM engineering applications.To investigate the opening performance of the PSD,an axial PSD incorporating a star-shaped prefabricated defect was designed.The opening process was simulated using peridynamics,yielding the strain field distribution and the corresponding failure mode.A single-opening verification test was conducted.The simulation results showed good agreement with the experimental data,demonstrating the reliability of the peridynamic modeling approach.Furthermore,the effects of the prefabricated defect shape and depth on the opening performance of the PSD were analyzed through simulation.The research results indicate that the established constitutive model and failure criteria based on peridynamics can reasonably predict the failure location and the opening pressure of the soft PSD.Under the impact loading,the weak zone of the soft PSD firstly ruptures,and the damaged area gradually propagates along with the prefabricated defect,eventually leading to complete separation.A smaller prefabricated defect depth or a wider prefabricated defect distribution can cause a reduction in opening pressure.These research results provide valuable guidance for the preliminary design and optimization of PSDs in pulse solid rocket motors.
基金supported by the Natural Science Foundation of Jilin Province under Grant No. 20220101028JC。
文摘A mid-infrared femtosecond pulse laser with a single cycle and high intensity is an ideal driving light source for generating isolated attosecond pulses. Due to current experimental limitations, it is difficult to directly achieve this type of laser light source in the laboratory. In this paper, we obtain such an ideal light source by adding a Ti sapphire pulse to the combined pulse laser consisting of two mid-infrared pulses. Specifically, by combining the synthesized pulse consisting of 8 fs/1200 nm/1.62 × 10^(14)W cm^(-2)and 12 fs/1800 nm/2.71 × 10^(14)W cm^(-2)with an additional 8 fs/800 nm/1.26 × 10^(14)W cm^(-2)Ti sapphire pulse, the resulting electric field waveform is very close to that of a 1170 nm femtosecond pulse with an intensity of 1.4 × 10^(15)W cm^(-2), a single-cycle pulse width, and a carrier-envelope phase of 0.25π. Numerical simulations show that both cases produce high-order harmonic emission spectra with broadband supercontinuum spectra, however, the bandwidth of the supercontinuum spectra and the harmonic intensities in the synthesized pulses are significantly better than those in the single1170 nm pulse. After inverse Fourier transform, we obtain 66 as a high-intensity isolated attosecond pulse, whose intensity is five orders of magnitude higher than that of a monochromatic field. Here, the phase differences between three combined pulse lasers have little effect on the numerical simulation results when they vary in the range of 0.3π.
基金financially supported by the National Key Research and Development Program of China(Grant No.2022YFA1602700)the National Natural Science Foundation of China(Grant No.12274159)。
文摘Pulsed magnet technology is the only way to generate ultra-strong magnetic fields higher than 45 T so far.However,the inherently fast-changing field strength(typically on the order of 1000 T/s)poses significant challenges for spectroscopic measurements which rely on time integration of signals to improve spectral qualities.In this work,we report high-sensitivity spectroscopic measurements under pulsed high magnetic fields employing the long flat-top pulsed magnetic field technique.By means of a multiple-capacitor power supply,we were able to generate pulsed high magnetic fields with controllable flat-top pulse width and field stabilities.By synchronizing spectroscopic measurements with the waveform of the flattop magnetic field,the integration time of each spectrum can be increased by up to 100 times compared with that of the conventional spectroscopic measurements under pulsed magnetic fields,thus enabling high-sensitivity spectroscopic measurements under ultra-strong pulsed magnetic fields.These findings promise an efficient way to significantly improve the performance and extend the application of optical measurements under pulsed high magnetic fields.
基金supported by the National Natural Science Foundation of China(Grant Nos.12174435,12034020,and 92250303)the Chinese Academy of Sciences Project for Young Scientists in Basic Research(Grant No.YSBR-091)the National Key R&D Program of China(Grant No.2022YFA1604200).
文摘Attosecond light pulses have revolutionized the study of electron dynamics in materials by enabling the observation of ultrafast processes with unprecedented attosecond temporal resolution.They are primarily generated through the process of high-order harmonic generation.This paper presents a comprehensive setup for attosecond pulse generation and measurement.Using a 900 nm,7 mJ,and 7 fs femtosecond laser with stabilized carrier-envelope phase,we employ polarization gating to generate a near single-cycle,linearly polarized pulse that interacts with neon gas to produce a broadband extreme-ultraviolet continuum with a cutoff photon energy of∼120 eV.The temporal and spectral characteristics of the generated single attosecond pulses are measured using an attosecond streak camera,and the pulse duration is determined to be 59 as through the frequency-resolved optical gating for complete reconstruction of attosecond bursts retrieval algorithm.As part of the Synergetic Extreme Condition User Facility,this setup will facilitate ultrafast research in transient absorption and photoelectron spectroscopy,providing global users with a powerful tool for studying electron dynamics in various materials.
基金supported by the National Natural Science Foundation of China(Grant No.12374238)the Postdoctoral Science Foundation of Shaanxi Province (Grant No.2024BSHSDZZ148)Ministry of Science and Higher Education of Russian Federation (Grant No.FSRZ 2023-0006)。
文摘A singlet diatomic molecule naturally carries doubly degenerate ±Λ states when the projection of the total electronic angular momentum onto the internuclear axis is nonzero. These doubly degenerate states contribute equally in conventional measurements and are thus treated the same in corresponding simulations. In this study, we demonstrate that in resonant excitation by intense laser pulses, the doubly degenerate ±Λ states must be clearly identified. This is exemplified in the X^(1)Σ → A^(1)Π transition of CO molecules. This distinction becomes especially important in the case of circularly polarized radiation. We attribute this phenomenon to the interference of electron-rotational pathways in the strong-field coupled transition with the ±Λ-state of the excited Π state. This research sheds light on the fundamental aspects of intense laser-molecule interactions when extending conventional theories.
基金supported by the National Natural Science Foundation of China(Grant Nos.12375236 and 12135009)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant Nos.XDA25050100 and XDA25010100).
文摘The generation and reconnection of magneticflux ropes in a plasma irradiated by two Laguerre–Gaussian laser pulses with different frequen-cies and opposite topological charges are investigated numerically by particle-in-cell simulations.It is shown that twisted plasma currents and hence magneticflux ropes can be effectively generated as long as the laser frequency difference matches the electron plasma frequency.More importantly,subsequent reconnection of magneticflux ropes can occur.Typical signatures of magnetic reconnection,such as magnetic island formation and plasma heating,are identified in the reconnection of magneticflux ropes.Notably,it is found that a strong axial magneticfield can be generated on the axis,owing to the azimuthal current induced during the reconnection of the ropes.This indicates that in the reconnection of magneticflux ropes,the energy can be transferred not only from the magneticfield to the plasma but also from the plasma current back to the magneticfield.This work opens a new avenue to the study of magneticflux ropes,which helps in understanding magnetic topology changes,and resultant magnetic energy dissipation,plasma heating,and particle acceleration found in solarflares,and magnetic confinement fusion devices.
基金Project supported by the Key Research and Development Plan of Xinjiang Uygur Autonomous Region,China(Grant Nos.2022B01040 and 2022B01040-2)the Key Project of Heilongjiang Natural Science Foundation(Grant No.ZD2021F002)。
文摘A self-pulsed Tm:GdScO_(3)laser was experimentally demonstrated by using a compact linear resonant cavity.When the pump power was 19.6 W,an average output power of 1771 m W was achieved from the self-pulsed Tm:GdScO_(3)laser with a pulse width of 158.1 ns and a pulse repetition frequency of 112.8 kHz,corresponding to an optical-to-optical conversion efficiency of 9.0%.Moreover,a single pulse energy of 15.7μJ and a pulse peak power of 99.3 W were acquired from the self-pulsed Tm:GdScO_(3)laser.This is,as we know,the first time that the self-pulsed laser output at 2-μm waveband range was obtained by utilizing a Tm:GdScO_(3)crystal so far.
基金Supported by the Fundamental Research Funds for the Central Public Welfare Research Institutes:Theoretical Study of Combination of of Facial Color and Pulses Mode in Traditional Chinese Medicine(No.KJ-202013),Objective Study of“Wei Qi”in Pulse Based on Color Doppler Flow Imaging(CDFI)Technology(No.YZ-202124)。
文摘OBJECTIVE:To analyze the Doppler ultrasound blood flow of Renying(carotid artery)pulse,Cunkou(radial artery)pulse,and Fuyang(anterior tibial artery)pulse in the normal group and the functional constipation with gastrointestinal heat(FCGH)group,and to compare and explore the differences of Renying,Cunkou and Fuyang pulses.METHODS:Sixty normal subjects and 60 patients with gastrointestinal heat constipation were collected in the department of ultrasound,Beijing Anzhen Hospital,Capital Medical University.Doppler ultrasound was used to observe the blood flow indexes including maximum systolic velocity(Vp),maximum diastolic velocity(Vd),mean velocity(Vm),pulse index(PI),resistance index(RI),vascular diameter(D),and circulation blood flow cycle(ET)of Renying pulse,Cunkou pulse and Fuyang pulse in the normal group and patients with gastrointestinal heat constipation.The differences of these three pulses were compared between the normal group and the FCGH group.RESULTS:The PI,Vp,Vm,RI,and D of the three pulses in the normal group were statistically significant different(P<0.01).In the comparison of Doppler flow diagram of three pulses in the FCGH group,there were significant differences in PI,Vd,Vp,Vm,RI,and D(P<0.01).CONCLUSION:Under normal conditions,the indexes of Renying pulse Doppler flow diagram,Cunkou pulse Doppler flow diagram,and Fuyang pulse Doppler flow diagram are significantly different.In the FCGH group,most of the indexes of Renying pulse Doppler flow diagram,Cunkou pulse Doppler flow diagram,and Fuyang pulse Doppler flow diagram are different.This result verified the necessity of simultaneous examinations of all Renying,Cunkou,and Fuyang pulses in modern Chinese medicine.
基金supported by the Fundamental Research Funds for the Central Universities(No.FRF-BD-23-01).
文摘Non-metallic inclusions in steel are a significant challenge,affecting material properties and leading to issues such as stress concentration,cracking,and accelerated corrosion.Current methods for removing inclusions,including bubble,electromagnetic stirring,filtration separation,fluid flow,and sedimentation,often struggle with the removal of fine inclusions.Apart from these known methods,pulsed electric current(PEC),as an emerging technology,has demonstrated immense potential and environmental advantages.PEC offers adjustable current parameters and simple equipment,making it an attractive alternative to traditional methods.Its green energy-saving features and excellent results in regulating inclusion morphology and migration,as well as inhibiting submerged entry nozzle(SEN)clogging,make it a promising technology.In comparison to continuous current technology,PEC has shown significant advantages in regulating inclusions,not only improving purification efficiency but also demonstrating outstanding performance in flow stability and energy consumption.The ability of PEC to efficiently reduce inclusion numbers enhances the purity and quality of molten steel,improving its mechanical properties.Currently,the theoretical basis for controlling the movement of inclusions by current is mainly composed of three major theories:the double electric layer theory,electromagnetic force reverse separation theory,and electric free energy drive theory.These theories together form an important framework for researchers to understand and optimize the behavior of impurity movement controlled by electric current.Looking ahead,PEC is expected to pave the way for new solutions in directional regulation of inclusion migration,efficient inclusion removal,SEN clogging prevention,and the purification of molten steel.
基金National Natural Science Foundation of China(No.52476192,No.52106237)Natural Science Foundation of Heilongjiang Province(No.YQ2022E027)。
文摘The transition of hydrogen sourcing from carbon-intensive to water-based methodologies is underway,with renewable energy-powered proton exchange membrane water electrolysis(PEMWE)emerging as the preeminent pathway for hydrogen production.Despite remarkable advancements in this field,confronting the sluggish electrochemical kinetics and inherent high-energy consumption arising from deteriorated mass transport within PEMWE systems remains a formidable obstacle.This impediment stems primarily from the hindered protons mass transfer and the untimely hydrogen bubbles detachment.To address these challenges,we harness the inherent variability of electrical energy and introduce an innovative pulsed dynamic water electrolysis system.Compared to constant voltage electrolysis(hydrogen production rate:51.6 m L h^(-1),energy consumption:5.37 kWh Nm-^(3)H_(2)),this strategy(hydrogen production rate:66 m L h^(-1),energy consumption:3.83 kWh Nm-^(3)H_(2))increases the hydrogen production rate by approximately 27%and reduces the energy consumption by about 28%.Furthermore,we demonstrate the practicality of this system by integrating it with an off-grid photovoltaic(PV)system designed for outdoor operation,successfully driving a hydrogen production current of up to 500 mA under an average voltage of approximately 2 V.The combined results of in-situ characterization and finite element analysis reveal the performance enhancement mechanism:pulsed dynamic electrolysis(PDE)dramatically accelerates the enrichment of protons at the electrode/solution interface and facilitates the release of bubbles on the electrode surface.As such,PDE-enhanced PEMWE represents a synergistic advancement,concurrently enhancing both the hydrogen generation reaction and associated transport processes.This promising technology not only redefines the landscape of electrolysis-based hydrogen production but also holds immense potential for broadening its application across a diverse spectrum of electrocatalytic endeavors.
基金supported by the Guangdong Basic and Applied Basic Research Foundation (No.2023A1515010093)the Shenzhen Fundamental Research Program (Stable Support Plan Program)(Nos.JCYJ20220809170611004, 20231121110828001 and 20231121113641002)the National Taipei University of Technology-Shenzhen University Joint Research Program (No.2024001)。
文摘In this paper, we have demonstrated an Er-doped ultrafast laser with a single mode fiber-gradient index multimode fiber-single mode fiber(SMF-GIMF-SMF, SMS) structure as saturable absorber(SA), which can generate not only stable single-pulse state, but also special mode-locked pulses with the characteristics of high energy and noisy behaviors at proper pump power and cavity polarization state. In addition, we have deeply investigated the real-time spectral evolutions of the mode-locked pulses through the dispersive Fourier transformation(DFT) technique. It can be found that the pulse regime can actually consist of a lot of small noise pulses with randomly varying intensities. We believe that these results will further enrich the nonlinear dynamical processes in the ultrafast lasers.
基金financial support from the National Natural Science Foundation of China(22494710,22408328)supported by Zhejiang Provincial Natural Science Foundation of China(LQN25B060002).
文摘Green hydrogen production by alkaline water electrolysis is an important technology in the decarbonization of the current industry.However,its large-scale application is limited by mediocre performance of conventional Raney Ni electrocatalysts.Herein,high-performance NiMoZn alloy catalysts of the Raney Ni type are developed by pulse electrodeposition for the hydrogen evolution reaction(HER).The optimized catalyst,NMZ-CA,exhibits an overpotential of 37 mV at 10 mA·cm^(-2) and a Tafel slope of 27 mV·dec^(-1) in 1 mol·L^(-1) KOH.Tafel slope measurements,X-ray photoelectron spectroscopy,and H_(2) temperatureprogrammed desorption experiments show that the incorporation of Mo and Zn in Ni weakens the binding of HER intermediate(H_(ads))on strongly adsorbing sites,leading to improved electrochemical kinetics.Electron microscopy and X-ray diffraction study reveals that a phase-pure Mo-doped Ni2Zn11 intermetallic precatalyst formed via pulse electrodeposition and subsequent heat treatment is key to the structure integrity and performance of the catalyst after activation by alkaline leaching.Modificationof NMZ-CA with PTFE enhances its HER performance by facilitating gas removal and improving structure integrity.A practical alkaline water electrolyzer built on the modifiedNMZ/PTFE-CA electrode delivers 2.0 A·cm^(-2) at 1.92 V cell voltage and operates for 250 h without decay.This work provides insights into the synergy between Ni,Mo,and Zn in Raney Ni-type catalysts,and demonstrates the hydrophobic modification as an effective strategy for electrode development in high-performance alkaline water electrolysis.
基金supported by the National Natural Science Foundation of China(No.12027813)the fund of National Innovation Center of Radiation Application of China(Nos.KFZC2020020501,KFZC2021010101).
文摘Polymethyl methacrylate(PMMA)is an optically transparent thermoplastic with favorable processing conditions.In this study,a series of plastic scintillators are prepared via thermal polymerization,and the impact of PMMA content on their transparency and pulse shape discrimination(PSD)ability is investigated.The fabricated samples,comprising a polystyrene(PS)-PMMA matrix,30.0 wt%2,5-diphenyloxazole(PPO),and 0.2 wt%9,10-diphenylanthracene(DPA),exhibit high transparency with transmissivity ranging from 70.0 to 90.0%(above 415.0 nm)and demonstrate excellent n/γdiscrimination capability.Transparency increased with increasing PMMA content across the entire visible light spectrum.However,the PSD performance gradually deteriorated when the aromatic matrix was replaced with PMMA.The scintillator containing 20.0 wt%PMMA demonstrated the best stability concerning PSD properties and relative light yields.
基金National Natural Science Foundation of China (81973749 and 8143594)State Administration of Traditional Chinese Medicine High-level Chinese Medicine Key Discipline Construction Project (zyyzdxk-2023069)。
文摘Objective To develop an onset risk prediction nomogram for patients with homocysteine-type(H-type)hypertension(HTH)based on pulse diagram parameters to assist early clinical prediction and diagnosis of HTH.Methods Patients diagnosed with essential hypertension and admitted to Shanghai Shuguang Hospital Affiliated to Shanghai University of Traditional Chinese Medicine,Shang-hai Hospital of Traditional Chinese Medicine,and Shanghai Hospital of Integrated Tradition-al Chinese and Western Medicine from July 6th 2020 to June 16th 2021,and from August 11th 2023 to January 22nd 2024,were enrolled in this retrospective research.The baselines and clinical biochemical indicators of patients were collected.The SMART-I TCM pulse instru-ment was applied to gather pulse diagram parameters.Multivariate logistic regression was adopted to analyze the risk factors for HTH.RStudio was employed to construct the nomo-gram model,receiver operating characteristic(ROC)curve,and calibration curve(bootstrap self-sampling 200 times),and clinical decision curve were drawn to evaluate the model’s dis-crimination and clinical effectiveness.Results A total of 168 hospitalized patients with essential hypertension were selected and di-vided into non-HTH group(n=29)and HTH group(n=139).Compared with non-HTH group,HTH group had a lower body mass index(BMI),and higher proportions of male pa-tients and drinkers(P<0.05).The ventricular wall thickening(VWT)could not be deter-mined.The proportions of left common carotid intima-media wall thickness(LCCIMWT)and serum creatinine(SCR)were higher in HTH group(P<0.05).The pulse diagram parameter As was significantly higher,and H4/H1 and T1/T were lower in HTH group(P<0.05).Gender,al-cohol consumption,serum creatinine,and the pulse diagram parameter H4/H1 were identi-fied as independent risk factors for HTH(P<0.05).The nomogram’s area under the ROC curve(AUC)was 0.795[95%confidence interval(CI):(0.7066,0.8828)],with a specificity of 0.724 and sensitivity of 0.799.After 200 times repeated bootstrap self-samplings,the calibra-tion curve showed that the simulated curve fits well with the actual curve(x^(2)=9.5002,P=0.3019).The clinical decision curve indicated that the nomogram’s applicability was optimal when the threshold for predicting HTH was between 0.38 and 1.00.Conclusion The nomogram model could be valuable for predicting the onset risk of HTH and pulse diagram parameters can facilitate early screening and prevention of HTH.
