1 In Lichuan,Central China's Hubei Province,a family's dedication to preserving cultural heritage has become a beacon(灯塔)of inspiration.The Sun family,comprised of father Sun Hui and son Sun Ru,has been the ...1 In Lichuan,Central China's Hubei Province,a family's dedication to preserving cultural heritage has become a beacon(灯塔)of inspiration.The Sun family,comprised of father Sun Hui and son Sun Ru,has been the backbone of the national cultural relics census in Lichuan since the 1970s,embodying the nation's spirit of protecting cultural treasures.展开更多
Metal nanoclusters(MNCs)possess distinct chemical properties due to their diverse electronic structures.As a class of promising model catalysts,it is of importance to explore the relationship between their structures ...Metal nanoclusters(MNCs)possess distinct chemical properties due to their diverse electronic structures.As a class of promising model catalysts,it is of importance to explore the relationship between their structures and properties.However,it is still challenging to get highly active and stable MNCs as surface ligands can hinder their activities,while a complete lack of surface ligand protection can lead to instability.To address this concern,here a series of Pd_(6)nanoclusters(NCs)with varying ligand amounts were synthesized by using Pd_(6)(SC_(6)(C_(2))H_(17))_(12)as precursor and single-walled carbon nanotube(s-CNT)as carrier through treating the composite at different temperatures and times.展开更多
Deep learning’s widespread dependence on large datasets raises privacy concerns due to the potential presence of sensitive information.Differential privacy stands out as a crucial method for preserving privacy,garner...Deep learning’s widespread dependence on large datasets raises privacy concerns due to the potential presence of sensitive information.Differential privacy stands out as a crucial method for preserving privacy,garnering significant interest for its ability to offer robust and verifiable privacy safeguards during data training.However,classic differentially private learning introduces the same level of noise into the gradients across training iterations,which affects the trade-off between model utility and privacy guarantees.To address this issue,an adaptive differential privacy mechanism was proposed in this paper,which dynamically adjusts the privacy budget at the layer-level as training progresses to resist member inference attacks.Specifically,an equal privacy budget is initially allocated to each layer.Subsequently,as training advances,the privacy budget for layers closer to the output is reduced(adding more noise),while the budget for layers closer to the input is increased.The adjustment magnitude depends on the training iterations and is automatically determined based on the iteration count.This dynamic allocation provides a simple process for adjusting privacy budgets,alleviating the burden on users to tweak parameters and ensuring that privacy preservation strategies align with training progress.Extensive experiments on five well-known datasets indicate that the proposed method outperforms competing methods in terms of accuracy and resilience against membership inference attacks.展开更多
Imine bonds are among the most explored building motifs in dynamic chemistry,polymers,and materials,and yet,their acid-resistance remains a longstanding issue.Herein we demonstrate a concept of internal protecting gro...Imine bonds are among the most explored building motifs in dynamic chemistry,polymers,and materials,and yet,their acid-resistance remains a longstanding issue.Herein we demonstrate a concept of internal protecting groups for improving the kinetic stability of dynamic imine bonds and polymers.Systematic examination of structure-reactivity relationship of a series of aldehydes/imines bearing a neighboring carboxyl allowed uncovering of required structural features for dynamically masking imine bonds with cyclic structures.Mechanistic studies indicated that noncovalent interactions along with sterics control the ringchain equilibrium and the stability of imine bonds.The incorporation of internal protecting groups into imine polymers further enabled their controlled stability in acidic media.Moreover,a combination of dynamic covalent network and coordination supramolecular network provided a facile means for the modulation of luminescent and mechanical properties of polymers.The strategies and results reported should be beneficial to molecular assemblies,dynamic polymers,biological delivery,and intelligent materials.展开更多
Xi Jinping’s discourses on respecting and protect-ing human rights stand as a shining example of the sinicization and modernization of Marxist human rights theory,embodying profound theoretical,political,practical,an...Xi Jinping’s discourses on respecting and protect-ing human rights stand as a shining example of the sinicization and modernization of Marxist human rights theory,embodying profound theoretical,political,practical,and cultural logic.Existing research has conducted comprehensive and systematic theoretical analysis and academic extractions on the following contents:the core essence in-herent in these important discourses,including the“theory of human rights concepts,”the“theory of human rights paths,”the“theory of human rights practices,”the“theory of human rights protection,”and the“theory of human rights governance,”along with their profound theoretical significance,practical significance,and global signifi-cance.In the future,researchers should emphasize efforts on studying the original texts and understanding the original principles.While focusing on the precision of concepts,the scientific nature of the prop-ositions,the maturity of theoretical systems,and the rigor of internal logic related to Xi Jinping’s discourses on respecting and protecting human rights,researchers should also pay attention to constructing a discourse system on human rights from the dimensions of discourse power,discourse cluster,and discourse field.Researchers should be adept at drawing innovative insights into human rights theory from China’s vibrant human rights practices and the vast masses of people.This approach will facilitate the systematic unfolding,academic trans-formation,and innovative development of Xi Jinping’s discourses on respecting and protecting human rights.展开更多
For Chodor,a Tibetan herder living in the remote Shanza County of the Xizang Autonomous Region,protecting nature and wildlife is more than just a job-it's both a responsibility and a source of pride.
In the new era,the Communist Party of China(CPC)has made historic achievements in respecting and protecting human rights.Building upon the principle of the“two integrations”(integrating the basic tenets of Marxism w...In the new era,the Communist Party of China(CPC)has made historic achievements in respecting and protecting human rights.Building upon the principle of the“two integrations”(integrating the basic tenets of Marxism with China’s specific realities and fine traditional culture),it has nurtured new theories on respecting and protecting human rights in the new era,which can address the fundamental questions of whom and what the human rights protection efforts in the new era are for.Guided by the principle of“taking our own path,”it has charted a distinct course for the development of human rights,diverging from the Western approach.The CPC has maintained the unity between Party leadership and the respect for and protection of human rights,promoting progress in human rights through the pursuit of“high-quality development,”and ensuring various fundamental rights of the people through the rule of law.Building upon the past experience,the CPC has established the“source”of the institutional framework for respecting and protecting human rights in the new era,crafted the“body”of this institutional framework,and introduced its practical“application.”In promoting the comprehensive advancement of human rights protection,the CPC has facilitated the connotative development of human rights protection in China,empowering China in international human rights discourse,and contributing Chinese strength and wisdom to global human rights governance.展开更多
Critical Infrastructures(CIs),which serve as the foundation of our modern society,are facing increasing risks from cyber threats,physical attacks,and natural disasters.Additionally,the interdependencies between CIs th...Critical Infrastructures(CIs),which serve as the foundation of our modern society,are facing increasing risks from cyber threats,physical attacks,and natural disasters.Additionally,the interdependencies between CIs through-out their operational lifespan can also significantly impact their integrity and safety.As a result,enhancing the resilience of CIs has emerged as a top priority for many countries,including the European Union.This involves not only understanding the threats/attacks themselves but also gaining knowledge about the areas and infrastruc-tures that could potentially be affected.A European Union-funded project named PRECINCT(Preparedness and Resilience Enforcement for Critical INfrastructure Cascading Cyber-Physical Threats),under the Horizon 2020 program,tries to connect private and public stakeholders of CIs in a specific geographical area.The key objec-tive of this project is to establish a common cyber-physical security management approach that will ensure the protection of both citizens and infrastructures,creating a secure territory.This paper presents the components of PRECINCT,including a directory of PRECINCT Critical Infrastructure Protection(CIP)blueprints.These blueprints support CI communities in designing integrated ecosystems,operating and replicating PRECINCT components(or toolkits).The integration enables coordinated security and resilience management,incorporating improved’installation-specific’security solutions.Additionally,Serious Games(SG),and Digital Twins(DT)are a significant part of this project,serving as a novel vulnerability evaluation method for analysing complicated multi-system cascading effects in the PRECINCT Living Labs(LLs).The use of SG supports the concentrated advancement of innovative resilience enhancement services.展开更多
At present,the major problems facing the water resource environment worldwide include water pollution,water resource shortage,and water ecosystem degradation.The discharge of industrial wastewater,agricultural non-poi...At present,the major problems facing the water resource environment worldwide include water pollution,water resource shortage,and water ecosystem degradation.The discharge of industrial wastewater,agricultural non-point source pollution,and the discharge of urban sewage lead to a serious decline in water quality,which directly affects the safety of human drinking water and the living environment of aquatic organisms.Additionally,the unbalanced distribution and excessive exploitation of water resources lead to the problem of water shortage in many areas,which then leads to social and economic contradictions and ecological crises.In terms of ecosystems,the phenomena of water ecological degradation and reduction of biodiversity are increasingly obvious,and the carrying capacity of aquatic ecosystems are gradually declining.This paper aims to analyze the natural,social,and economic factors affecting the water resource environment,and propose effective strategies to protect the water ecology.To provide a theoretical basis and practical guidance for the sustainable utilization of water resources and the long-term development of the water ecosystem.展开更多
In light of increasingly worsening environmental pollution,this paper,through comparing different attitudes towards the relationship between man and nature in Chinese and the western culture,points out rebuilding a ha...In light of increasingly worsening environmental pollution,this paper,through comparing different attitudes towards the relationship between man and nature in Chinese and the western culture,points out rebuilding a harmonious relationship between man and nature is the common object of human being,and appeals to people to shake off man-centered thinking pattern,and to treat nature as our friend.展开更多
In order to investigate the protective effect of aloe anthraquinones on growth and development of soybean against ultraviolet B radiation stress from the morphological structure and physio-chemical indices. The result...In order to investigate the protective effect of aloe anthraquinones on growth and development of soybean against ultraviolet B radiation stress from the morphological structure and physio-chemical indices. The results showed that, stressed by the enhanced ultraviolet b radiation, the soybean gave a dwarfed plant, shrunken leaf area and decreased photosynthetic pigment, while an ascended MDA content. Spraying aloe anthraquinones effectively relieved the reductions of chloro- phyll content and biomass and decreased the production of MDA under the radia- tion of UV-B. Moreover, under the UV-B radiation, waxy substances on epidermal cells increased remarkably and the stomas showed obvious subsidence, while spraying aloe anthraquinones could maintain the structure and shape of cells similar to that under natural light, and the stomas subsidence as well.展开更多
Focal ischemic stroke(FIS)results from the lack of blood flow in a particular region of the brain and accounts for about 80%of all human strokes.Although tremendous efforts have been made in translational research,t...Focal ischemic stroke(FIS)results from the lack of blood flow in a particular region of the brain and accounts for about 80%of all human strokes.Although tremendous efforts have been made in translational research,the treatment strategies are still limited.Tissue plasminogen activator is the only FDA-approved drug currently available for acute stroke treatment,展开更多
The models of two qubits separately trapped in two independent Markovian or non-Markovian environments have been investigated. The distinction of the two-qubit entanglement dynamics in different environments has also ...The models of two qubits separately trapped in two independent Markovian or non-Markovian environments have been investigated. The distinction of the two-qubit entanglement dynamics in different environments has also been discussed in detail. The results show that, in non-Markovian environments, the possible usage time of entanglement can be extended due to its memory effect. On the other hand, we note that, compared to Markovian environments, the two-qubit entanglement could be protected better in non-Markovian environments by modulating the detuning between qubits and cavities. Finally, an intuitive physicM interpretation for these results is given.展开更多
The intrinsically safe Zn||I_(2) battery,one of the leading candidates aiming to replace traditional Pb-acid batteries,is still seriously suffering from short shelf and cycling lifespan,due to the uncontrolled I_(3)^(...The intrinsically safe Zn||I_(2) battery,one of the leading candidates aiming to replace traditional Pb-acid batteries,is still seriously suffering from short shelf and cycling lifespan,due to the uncontrolled I_(3)^(−)-shuttling and dynamic parasitic reactions on Zn anodes.Considering the fact that almost all these detrimental processes terminate on the surfaces of Zn anodes,modifying Zn anodes’surface with protecting layers should be one of the most straightforward and thorough approaches to restrain these processes.Herein,a facile zeolite-based cation-exchange protecting layer is designed to comprehensively suppress the unfavored parasitic reactions on the Zn anodes.The negatively-charged cavities in the zeolite lattice provide highly accessible migration channels for Zn^(2+),while blocking anions and electrolyte from passing through.This low-cost cation-exchange protecting layer can simultaneously suppress self-discharge,anode corrosion/passivation,and Zn dendrite growth,awarding the Zn||I_(2) batteries with ultra-long cycle life(91.92%capacity retention after 5600 cycles at 2 A g^(−1)),high coulombic efficiencies(99.76%in average)and large capacity(203–196 mAh g^(−1) at 0.2 A g^(−1)).This work provides a highly affordable approach for the construction of high-performance Zn-I_(2) aqueous batteries.展开更多
A new IL-supported diol, 1-(2,3-dihydroxypropyl)-3-methylimidazolium hexafluorophosphate has been synthesized and characterized by Fr-IR, ^1H NMR, ^13C NMR and MS (ESI). Its physical properties such as freezing po...A new IL-supported diol, 1-(2,3-dihydroxypropyl)-3-methylimidazolium hexafluorophosphate has been synthesized and characterized by Fr-IR, ^1H NMR, ^13C NMR and MS (ESI). Its physical properties such as freezing point, solubility and specific gravity and thermal stability were determined. Synthetic utilities of the resultant diol as a protecting group for aldehydes were also investigated.展开更多
On-surface synthesis of semiconducting graphdiyne nanowires usually suffer severe side reactions owing to the high reactivity of the butadiynylene units at noble metal surfaces,limiting the production of isolated nano...On-surface synthesis of semiconducting graphdiyne nanowires usually suffer severe side reactions owing to the high reactivity of the butadiynylene units at noble metal surfaces,limiting the production of isolated nanowires. In this work, we report the high-yield synthesis of branchless graphdiyne nanowires [-C≡C-Ph2-C≡C-]nvia on-surface Ullmann coupling of 1,4-bis(4-bromophenyl)-1,3-butadiyne molecules with chemical vapor deposition method.Non-contact atomic force microscopy with single-bond resolution reveals that single gold adatoms act as effective protecting groups for butadiynylene units by forming Au-π ligand bonds, preventing unwanted branched coupling reactions and enabling the synthesis of ultralong isolated graphdiyne nanowires. This study will stimulate further investigation on the role of various surface adatoms in protecting on-surface reactions.展开更多
Objective To study the protecting effects and mechanism of betaine hydrochloride on hepatic ischemia-reperfusion injury in rats.Methods Fourty SD rats were randomly divided into 5 groups(8 animals in each group):sham-...Objective To study the protecting effects and mechanism of betaine hydrochloride on hepatic ischemia-reperfusion injury in rats.Methods Fourty SD rats were randomly divided into 5 groups(8 animals in each group):sham-operated control group(A),hepatic ischemia-reperfusion group(B),200 mg·kg-1 400 mg·kg-1 800 mg·kg-1 betaine hydrochloride+hepatic ischemia-reperfusion group(C、D、E).betaine hydrochloride was administered to animals byoral route in group C、D、E for 7 days before ischemia.A、B group was administered with NS.Made the animal model of part hepatic ischemia-reperfusion.Serum alanine aminotransferase(ALT),aspartate aminotransferase(AST)levels in the blood and themalondialdehyde(MDA),superoxide dismutase(SOD),protein content in hepatic tissue were determined after the liver had been reperfused for 24 hours;the hepatic tissue was examined under lightmicroscope and the cell apoptosis was demonstrated with flow cytometry.Results ALT,AST,MDA increased and SOD decreased significantly in B group when compared those in the A group(P<0.05),Hepatic apoptosis was significantly increased;ALT,AST,MDA decreased and SOD increased significantly in betaine hydrochloride 200 mg·kg-1(C)group when compared those in the B group(P<0.05).Hepatic apoptosis was significantly lower,The histologic changes of the liver tissue under lightmicroscope in the C group was more easer than in the I/R group(B).Conclusions Betaine hydrochloride has the ability to scavenge oxygen free radical(OFR),reduce lipid peroxidation and inhibition of apoptosis.So it can protect the rats liver damaged by ischemia-reperfusion.展开更多
A novel polymer-bound 1,2-diol, 3-polystyrylsulfonyl-1,2-propanediol (6) had been prepared by the reaction of sodium polystyrylsulfinate with allyl bromide, followed by oxidation and. hydrolysis or directly with 3-chl...A novel polymer-bound 1,2-diol, 3-polystyrylsulfonyl-1,2-propanediol (6) had been prepared by the reaction of sodium polystyrylsulfinate with allyl bromide, followed by oxidation and. hydrolysis or directly with 3-chloro-1,2-propanediol in the presence of a phase transfer catalyst, n-tetrabutylammonium iodide. The capacity of resin 6 for terephthaidehyde reached 1.43 mmol/g. The aldehydic groups attached to polymer 6 reacted with hydroxylamine hydrochloride or reduced by sodium borohydride giving p-formylbenzaldoxime (yield: 89%)and p-formyl-benzalcohol (yield: 734%), respectively. The high yields of these polymer-supported reactions showed that the polymer 6 possessed the effective isolation of its reactive sites.展开更多
The pharmacodynamic active parts of protecting liver of Peristrope japonica (thunb.)Bremek were identified. Rat acute liver injury model was induced by D-galactosamine (D-GlaN). The active parts were identified on the...The pharmacodynamic active parts of protecting liver of Peristrope japonica (thunb.)Bremek were identified. Rat acute liver injury model was induced by D-galactosamine (D-GlaN). The active parts were identified on the whole extraction and 4 fractions. The results showed that the pharmacodynamic active parts of Peristrope japonica were the n-BuOH fraction.展开更多
With the control mode of value-added network services equipment changing from bypass intervention to serial control, in order to minimize the security problems which are caused by the failure of the network equipment,...With the control mode of value-added network services equipment changing from bypass intervention to serial control, in order to minimize the security problems which are caused by the failure of the network equipment, this paper proposes a stable, fast and intelligent network bypass protection system combined with the ARM embedded system—Linux platform. In practical application, the system can automatically skip the broken-down device node to protect the network to be unobstructed. With the features of fast response, stable operation, low power consumption, and the flexible of combination, the scheme is proved to have large practical value.展开更多
文摘1 In Lichuan,Central China's Hubei Province,a family's dedication to preserving cultural heritage has become a beacon(灯塔)of inspiration.The Sun family,comprised of father Sun Hui and son Sun Ru,has been the backbone of the national cultural relics census in Lichuan since the 1970s,embodying the nation's spirit of protecting cultural treasures.
基金financially supported by the Natural Science Foundation of Guangxi,China(Nos.2019GXNSFGA245003 and 2021GXNSFBA220058)the National Natural Science Foundation of China(Nos.22272036 and 22362008)+2 种基金Guangxi Technology Base and Talent Subject,China(GUIKE AD23026272)Guangxi Normal University Research Grant,China(No.2022TD)Innovation Project of Guangxi Graduate Education(No.XYCSR2023018)。
文摘Metal nanoclusters(MNCs)possess distinct chemical properties due to their diverse electronic structures.As a class of promising model catalysts,it is of importance to explore the relationship between their structures and properties.However,it is still challenging to get highly active and stable MNCs as surface ligands can hinder their activities,while a complete lack of surface ligand protection can lead to instability.To address this concern,here a series of Pd_(6)nanoclusters(NCs)with varying ligand amounts were synthesized by using Pd_(6)(SC_(6)(C_(2))H_(17))_(12)as precursor and single-walled carbon nanotube(s-CNT)as carrier through treating the composite at different temperatures and times.
基金supported by the National Natural Science Foundation of China(Grant No.62462022)the Hainan Province Science and Technology Special Fund(Grants No.ZDYF2022GXJS229).
文摘Deep learning’s widespread dependence on large datasets raises privacy concerns due to the potential presence of sensitive information.Differential privacy stands out as a crucial method for preserving privacy,garnering significant interest for its ability to offer robust and verifiable privacy safeguards during data training.However,classic differentially private learning introduces the same level of noise into the gradients across training iterations,which affects the trade-off between model utility and privacy guarantees.To address this issue,an adaptive differential privacy mechanism was proposed in this paper,which dynamically adjusts the privacy budget at the layer-level as training progresses to resist member inference attacks.Specifically,an equal privacy budget is initially allocated to each layer.Subsequently,as training advances,the privacy budget for layers closer to the output is reduced(adding more noise),while the budget for layers closer to the input is increased.The adjustment magnitude depends on the training iterations and is automatically determined based on the iteration count.This dynamic allocation provides a simple process for adjusting privacy budgets,alleviating the burden on users to tweak parameters and ensuring that privacy preservation strategies align with training progress.Extensive experiments on five well-known datasets indicate that the proposed method outperforms competing methods in terms of accuracy and resilience against membership inference attacks.
基金the National Natural Science Foundation of China(NSFC,Nos.22071247,92156010,22101283,and 22101284)the Key Research Program of Frontier Sciences(No.QYZDBSSW-SLH030)of the CAS+1 种基金Natural Science Foundation of Fujian Province(Nos.2020J06035 and 2022J05085)Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China(No.2021ZR112)for support.
文摘Imine bonds are among the most explored building motifs in dynamic chemistry,polymers,and materials,and yet,their acid-resistance remains a longstanding issue.Herein we demonstrate a concept of internal protecting groups for improving the kinetic stability of dynamic imine bonds and polymers.Systematic examination of structure-reactivity relationship of a series of aldehydes/imines bearing a neighboring carboxyl allowed uncovering of required structural features for dynamically masking imine bonds with cyclic structures.Mechanistic studies indicated that noncovalent interactions along with sterics control the ringchain equilibrium and the stability of imine bonds.The incorporation of internal protecting groups into imine polymers further enabled their controlled stability in acidic media.Moreover,a combination of dynamic covalent network and coordination supramolecular network provided a facile means for the modulation of luminescent and mechanical properties of polymers.The strategies and results reported should be beneficial to molecular assemblies,dynamic polymers,biological delivery,and intelligent materials.
基金a phased achievement of the MOE’s key philosophy and social science research project“Research on General Secretary Xi Jinping’s Discourses on Respecting and Protecting Human Rights”(Project Approval Number 22JZD002)MOE Humanities and Social Sciences Key Research Base’s major project“Research on the Theoretical Structure and Legal Guarantee of Digital Human Rights Governance”(Project Approval Number 21JJD8200014)。
文摘Xi Jinping’s discourses on respecting and protect-ing human rights stand as a shining example of the sinicization and modernization of Marxist human rights theory,embodying profound theoretical,political,practical,and cultural logic.Existing research has conducted comprehensive and systematic theoretical analysis and academic extractions on the following contents:the core essence in-herent in these important discourses,including the“theory of human rights concepts,”the“theory of human rights paths,”the“theory of human rights practices,”the“theory of human rights protection,”and the“theory of human rights governance,”along with their profound theoretical significance,practical significance,and global signifi-cance.In the future,researchers should emphasize efforts on studying the original texts and understanding the original principles.While focusing on the precision of concepts,the scientific nature of the prop-ositions,the maturity of theoretical systems,and the rigor of internal logic related to Xi Jinping’s discourses on respecting and protecting human rights,researchers should also pay attention to constructing a discourse system on human rights from the dimensions of discourse power,discourse cluster,and discourse field.Researchers should be adept at drawing innovative insights into human rights theory from China’s vibrant human rights practices and the vast masses of people.This approach will facilitate the systematic unfolding,academic trans-formation,and innovative development of Xi Jinping’s discourses on respecting and protecting human rights.
文摘For Chodor,a Tibetan herder living in the remote Shanza County of the Xizang Autonomous Region,protecting nature and wildlife is more than just a job-it's both a responsibility and a source of pride.
基金a phased achievement of the National Social Science Foundation’s major bidding project “Research on the Theoretical System and Optimization Path of China’s Human Rights Development Path”(Project Approval Number 23ZDA067)
文摘In the new era,the Communist Party of China(CPC)has made historic achievements in respecting and protecting human rights.Building upon the principle of the“two integrations”(integrating the basic tenets of Marxism with China’s specific realities and fine traditional culture),it has nurtured new theories on respecting and protecting human rights in the new era,which can address the fundamental questions of whom and what the human rights protection efforts in the new era are for.Guided by the principle of“taking our own path,”it has charted a distinct course for the development of human rights,diverging from the Western approach.The CPC has maintained the unity between Party leadership and the respect for and protection of human rights,promoting progress in human rights through the pursuit of“high-quality development,”and ensuring various fundamental rights of the people through the rule of law.Building upon the past experience,the CPC has established the“source”of the institutional framework for respecting and protecting human rights in the new era,crafted the“body”of this institutional framework,and introduced its practical“application.”In promoting the comprehensive advancement of human rights protection,the CPC has facilitated the connotative development of human rights protection in China,empowering China in international human rights discourse,and contributing Chinese strength and wisdom to global human rights governance.
基金funded by the European Commission,Horizon 2020 research and innovation programme under grant agreement No.101021668.
文摘Critical Infrastructures(CIs),which serve as the foundation of our modern society,are facing increasing risks from cyber threats,physical attacks,and natural disasters.Additionally,the interdependencies between CIs through-out their operational lifespan can also significantly impact their integrity and safety.As a result,enhancing the resilience of CIs has emerged as a top priority for many countries,including the European Union.This involves not only understanding the threats/attacks themselves but also gaining knowledge about the areas and infrastruc-tures that could potentially be affected.A European Union-funded project named PRECINCT(Preparedness and Resilience Enforcement for Critical INfrastructure Cascading Cyber-Physical Threats),under the Horizon 2020 program,tries to connect private and public stakeholders of CIs in a specific geographical area.The key objec-tive of this project is to establish a common cyber-physical security management approach that will ensure the protection of both citizens and infrastructures,creating a secure territory.This paper presents the components of PRECINCT,including a directory of PRECINCT Critical Infrastructure Protection(CIP)blueprints.These blueprints support CI communities in designing integrated ecosystems,operating and replicating PRECINCT components(or toolkits).The integration enables coordinated security and resilience management,incorporating improved’installation-specific’security solutions.Additionally,Serious Games(SG),and Digital Twins(DT)are a significant part of this project,serving as a novel vulnerability evaluation method for analysing complicated multi-system cascading effects in the PRECINCT Living Labs(LLs).The use of SG supports the concentrated advancement of innovative resilience enhancement services.
基金The Knowledge Innovation Program of Wuhan-Shuguang Project(Project No.2023020201020361).
文摘At present,the major problems facing the water resource environment worldwide include water pollution,water resource shortage,and water ecosystem degradation.The discharge of industrial wastewater,agricultural non-point source pollution,and the discharge of urban sewage lead to a serious decline in water quality,which directly affects the safety of human drinking water and the living environment of aquatic organisms.Additionally,the unbalanced distribution and excessive exploitation of water resources lead to the problem of water shortage in many areas,which then leads to social and economic contradictions and ecological crises.In terms of ecosystems,the phenomena of water ecological degradation and reduction of biodiversity are increasingly obvious,and the carrying capacity of aquatic ecosystems are gradually declining.This paper aims to analyze the natural,social,and economic factors affecting the water resource environment,and propose effective strategies to protect the water ecology.To provide a theoretical basis and practical guidance for the sustainable utilization of water resources and the long-term development of the water ecosystem.
文摘In light of increasingly worsening environmental pollution,this paper,through comparing different attitudes towards the relationship between man and nature in Chinese and the western culture,points out rebuilding a harmonious relationship between man and nature is the common object of human being,and appeals to people to shake off man-centered thinking pattern,and to treat nature as our friend.
基金Supported by National Natural Science Foundation of China(31270225)~~
文摘In order to investigate the protective effect of aloe anthraquinones on growth and development of soybean against ultraviolet B radiation stress from the morphological structure and physio-chemical indices. The results showed that, stressed by the enhanced ultraviolet b radiation, the soybean gave a dwarfed plant, shrunken leaf area and decreased photosynthetic pigment, while an ascended MDA content. Spraying aloe anthraquinones effectively relieved the reductions of chloro- phyll content and biomass and decreased the production of MDA under the radia- tion of UV-B. Moreover, under the UV-B radiation, waxy substances on epidermal cells increased remarkably and the stomas showed obvious subsidence, while spraying aloe anthraquinones could maintain the structure and shape of cells similar to that under natural light, and the stomas subsidence as well.
基金supported by NIH NS069726 and NS094539America Heart Association 13GRANT17020004(to SD)
文摘Focal ischemic stroke(FIS)results from the lack of blood flow in a particular region of the brain and accounts for about 80%of all human strokes.Although tremendous efforts have been made in translational research,the treatment strategies are still limited.Tissue plasminogen activator is the only FDA-approved drug currently available for acute stroke treatment,
文摘The models of two qubits separately trapped in two independent Markovian or non-Markovian environments have been investigated. The distinction of the two-qubit entanglement dynamics in different environments has also been discussed in detail. The results show that, in non-Markovian environments, the possible usage time of entanglement can be extended due to its memory effect. On the other hand, we note that, compared to Markovian environments, the two-qubit entanglement could be protected better in non-Markovian environments by modulating the detuning between qubits and cavities. Finally, an intuitive physicM interpretation for these results is given.
基金The authors thank the National Natural Science Foundation of China(51502194,22133005,21973107,and 22103093)the Natural Science Foundation of Shandong(ZR2020ME024)+2 种基金the Science and Technology Commission of Shanghai Municipality(21ZR1472900)the Key Laboratory for Palygorskite Science and Applied Technology of Jiangsu Province(HPK202103)for financial supportOpen access funding provided by Shanghai Jiao Tong University
文摘The intrinsically safe Zn||I_(2) battery,one of the leading candidates aiming to replace traditional Pb-acid batteries,is still seriously suffering from short shelf and cycling lifespan,due to the uncontrolled I_(3)^(−)-shuttling and dynamic parasitic reactions on Zn anodes.Considering the fact that almost all these detrimental processes terminate on the surfaces of Zn anodes,modifying Zn anodes’surface with protecting layers should be one of the most straightforward and thorough approaches to restrain these processes.Herein,a facile zeolite-based cation-exchange protecting layer is designed to comprehensively suppress the unfavored parasitic reactions on the Zn anodes.The negatively-charged cavities in the zeolite lattice provide highly accessible migration channels for Zn^(2+),while blocking anions and electrolyte from passing through.This low-cost cation-exchange protecting layer can simultaneously suppress self-discharge,anode corrosion/passivation,and Zn dendrite growth,awarding the Zn||I_(2) batteries with ultra-long cycle life(91.92%capacity retention after 5600 cycles at 2 A g^(−1)),high coulombic efficiencies(99.76%in average)and large capacity(203–196 mAh g^(−1) at 0.2 A g^(−1)).This work provides a highly affordable approach for the construction of high-performance Zn-I_(2) aqueous batteries.
基金the National Natural Science Foundation of China(No.20533010,20673039)the Science&Technology Commission of Shanghai Municipality(No.06JC14023)for financial support.
文摘A new IL-supported diol, 1-(2,3-dihydroxypropyl)-3-methylimidazolium hexafluorophosphate has been synthesized and characterized by Fr-IR, ^1H NMR, ^13C NMR and MS (ESI). Its physical properties such as freezing point, solubility and specific gravity and thermal stability were determined. Synthetic utilities of the resultant diol as a protecting group for aldehydes were also investigated.
基金the National Key R&D Program of China(No.2016YFA0200603 No.2017YFA0205004)the Anhui Initiative in Quantum Information Technologies(AHY090300)+2 种基金the National Natural Science Foundation of China(No.21473174)the Fundamental Research Funds for the Central Universities(No.WK2060190084 and No.WK2340000082)Ai-di Zhao acknowledges a fellow-ship from the Youth Innovation Promotion Association of Chinese Academy of Science(2011322).
文摘On-surface synthesis of semiconducting graphdiyne nanowires usually suffer severe side reactions owing to the high reactivity of the butadiynylene units at noble metal surfaces,limiting the production of isolated nanowires. In this work, we report the high-yield synthesis of branchless graphdiyne nanowires [-C≡C-Ph2-C≡C-]nvia on-surface Ullmann coupling of 1,4-bis(4-bromophenyl)-1,3-butadiyne molecules with chemical vapor deposition method.Non-contact atomic force microscopy with single-bond resolution reveals that single gold adatoms act as effective protecting groups for butadiynylene units by forming Au-π ligand bonds, preventing unwanted branched coupling reactions and enabling the synthesis of ultralong isolated graphdiyne nanowires. This study will stimulate further investigation on the role of various surface adatoms in protecting on-surface reactions.
文摘Objective To study the protecting effects and mechanism of betaine hydrochloride on hepatic ischemia-reperfusion injury in rats.Methods Fourty SD rats were randomly divided into 5 groups(8 animals in each group):sham-operated control group(A),hepatic ischemia-reperfusion group(B),200 mg·kg-1 400 mg·kg-1 800 mg·kg-1 betaine hydrochloride+hepatic ischemia-reperfusion group(C、D、E).betaine hydrochloride was administered to animals byoral route in group C、D、E for 7 days before ischemia.A、B group was administered with NS.Made the animal model of part hepatic ischemia-reperfusion.Serum alanine aminotransferase(ALT),aspartate aminotransferase(AST)levels in the blood and themalondialdehyde(MDA),superoxide dismutase(SOD),protein content in hepatic tissue were determined after the liver had been reperfused for 24 hours;the hepatic tissue was examined under lightmicroscope and the cell apoptosis was demonstrated with flow cytometry.Results ALT,AST,MDA increased and SOD decreased significantly in B group when compared those in the A group(P<0.05),Hepatic apoptosis was significantly increased;ALT,AST,MDA decreased and SOD increased significantly in betaine hydrochloride 200 mg·kg-1(C)group when compared those in the B group(P<0.05).Hepatic apoptosis was significantly lower,The histologic changes of the liver tissue under lightmicroscope in the C group was more easer than in the I/R group(B).Conclusions Betaine hydrochloride has the ability to scavenge oxygen free radical(OFR),reduce lipid peroxidation and inhibition of apoptosis.So it can protect the rats liver damaged by ischemia-reperfusion.
基金The project is supported by the National Natural Science Foundation of China.
文摘A novel polymer-bound 1,2-diol, 3-polystyrylsulfonyl-1,2-propanediol (6) had been prepared by the reaction of sodium polystyrylsulfinate with allyl bromide, followed by oxidation and. hydrolysis or directly with 3-chloro-1,2-propanediol in the presence of a phase transfer catalyst, n-tetrabutylammonium iodide. The capacity of resin 6 for terephthaidehyde reached 1.43 mmol/g. The aldehydic groups attached to polymer 6 reacted with hydroxylamine hydrochloride or reduced by sodium borohydride giving p-formylbenzaldoxime (yield: 89%)and p-formyl-benzalcohol (yield: 734%), respectively. The high yields of these polymer-supported reactions showed that the polymer 6 possessed the effective isolation of its reactive sites.
文摘The pharmacodynamic active parts of protecting liver of Peristrope japonica (thunb.)Bremek were identified. Rat acute liver injury model was induced by D-galactosamine (D-GlaN). The active parts were identified on the whole extraction and 4 fractions. The results showed that the pharmacodynamic active parts of Peristrope japonica were the n-BuOH fraction.
文摘With the control mode of value-added network services equipment changing from bypass intervention to serial control, in order to minimize the security problems which are caused by the failure of the network equipment, this paper proposes a stable, fast and intelligent network bypass protection system combined with the ARM embedded system—Linux platform. In practical application, the system can automatically skip the broken-down device node to protect the network to be unobstructed. With the features of fast response, stable operation, low power consumption, and the flexible of combination, the scheme is proved to have large practical value.