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Feasibility study of a process for the reduction of sulfur oxides in flue gas of fluid catalytic cracking unit using the riser reactor
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作者 Fa-Lu Dang Gang Wang +2 位作者 Jing-Cun Lian Yu Yang Mei-Jia Liu 《Petroleum Science》 2025年第2期909-924,共16页
In this work,a new process for achieving the recovery of elemental sulfur by utilizing a fluidized catalytic cracking(FCC) riser reactor for SOxtreatment(FCC-DeSOx) is proposed.The process leverages the high temperatu... In this work,a new process for achieving the recovery of elemental sulfur by utilizing a fluidized catalytic cracking(FCC) riser reactor for SOxtreatment(FCC-DeSOx) is proposed.The process leverages the high temperatures and hydrocarbon concentrations in the FCC riser reactor to convert SOxinto H_(2)S.Subsequently,H_(2)S,along with the cracked gas,is processed downstream to produce sulfur.Thermodynamic analysis of the key reduction reactions in the FCC-DeSOxprocess revealed that complete conversion of SOxto H_(2)S is feasible in the dry gas(hydrogen-rich) prelift zone,as well as the upper and lower zones of the riser,upon achieving thermodynamic equilibrium.Experimental studies were conducted to replicate the conditions of these reaction zones using a low concentration of hydrogen gas as the reducing agent.Through process optimization,investigation of the minimum reaction time,and kinetic studies,the potential of this method for the complete reduction of SOxwas further confirmed. 展开更多
关键词 Sulfur oxides New catalytic cracking process Thermodynamic analysis Kinetic analysis Sulfur recovery
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Cracking and fragmentation in percussive drilling:Insight from FDEM simulation
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作者 Xiaowei Yang Jiansheng Xiang +2 位作者 John-Paul Latham Sadjad Naderi Yanghua Wang 《Journal of Rock Mechanics and Geotechnical Engineering》 2025年第10期6095-6110,共16页
Percussive drilling is gaining interest for both shallow and deep applications due to its potential for higher drilling rates in hard rocks.Therefore,for efficient rock breaking,the development of advanced percussive ... Percussive drilling is gaining interest for both shallow and deep applications due to its potential for higher drilling rates in hard rocks.Therefore,for efficient rock breaking,the development of advanced percussive drilling simulation tools has the potential to be transformative.Such tools must accurately capture the rock’s response to enable an effective analysis of the fragmentation process.Traditional continuum numerical methods,such as the finite element method(FEM),do not simulate discrete cracks or the contact interaction between rock fragments.The finite-discrete element method(FDEM)is a three-dimensional hybrid method that combines FEM with the discrete element method(DEM)that addresses these limitations.New FDEM simulation results of impacts on Kuru Grey granite show good agreement with published experimental data.The interpretation focuses on two significant processes in percussive drilling:crack propagation and chipping generation.FDEM successfully simulates the evolution of cracks,including radial,side,and inclined cracks,as well as crushed and cracked zones.The simulation also reproduces the coalescence of adjacent craters to generate more chippings.Additionally,the stress state,velocity field and discrete fractures simulated by FDEM provide detailed insights into the different fracture patterns for Kuru Grey granite,enhancing understanding of the fundamental underlying mechanisms. 展开更多
关键词 Percussive drilling Finite discrete element method(FDEM) cracking process Chipping formation Failure mechanism
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Microstructure effect of mechanical and cracking behaviors on brittle rocks using image-based fast Fourier transform method
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作者 Mingyao Li Lei Peng +1 位作者 Dejun Liu Jianping Zuo 《Journal of Rock Mechanics and Geotechnical Engineering》 2025年第1期399-413,共15页
The internal microstructures of rock materials, including mineral heterogeneity and intrinsic microdefects, exert a significant influence on their nonlinear mechanical and cracking behaviors. It is of great significan... The internal microstructures of rock materials, including mineral heterogeneity and intrinsic microdefects, exert a significant influence on their nonlinear mechanical and cracking behaviors. It is of great significance to accurately characterize the actual microstructures and their influence on stress and damage evolution inside the rocks. In this study, an image-based fast Fourier transform (FFT) method is developed for reconstructing the actual rock microstructures by combining it with the digital image processing (DIP) technique. A series of experimental investigations were conducted to acquire information regarding the actual microstructure and the mechanical properties. Based on these experimental evidences, the processed microstructure information, in conjunction with the proposed micromechanical model, is incorporated into the numerical calculation. The proposed image-based FFT method was firstly validated through uniaxial compression tests. Subsequently, it was employed to predict and analyze the influence of microstructure on macroscopic mechanical behaviors, local stress distribution and the internal crack evolution process in brittle rocks. The distribution of feldspar is considerably more heterogeneous and scattered than that of quartz, which results in a greater propensity for the formation of cracks in feldspar. It is observed that initial cracks and new cracks, including intragranular and boundary ones, ultimately coalesce and connect as the primary through cracks, which are predominantly distributed along the boundary of the feldspar. This phenomenon is also predicted by the proposed numerical method. The results indicate that the proposed numerical method provides an effective approach for analyzing, understanding and predicting the nonlinear mechanical and cracking behaviors of brittle rocks by taking into account the actual microstructure characteristics. 展开更多
关键词 Rock microstructure cracking process Brittle rocks Fast Fourier transform(FFT) Digital image processing(DIP)
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A Numerical Study of Wave Propagation and Cracking Processes in Rock-Like Material under Seismic Loading Based on the Bonded-Particle Model Approach 被引量:1
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作者 Xiaoping Zhang Qi Zhang +1 位作者 Quansheng Liu Ruihua Xiao 《Engineering》 SCIE EI CAS 2022年第10期140-150,共11页
An earthquake is usually followed by a considerable number of aftershocks that play a significant role in earthquake-induced landslides,During the aftershock,the cracking process in rocks becomes more complex because ... An earthquake is usually followed by a considerable number of aftershocks that play a significant role in earthquake-induced landslides,During the aftershock,the cracking process in rocks becomes more complex because of the formation of faults.In order to investigate the effects of seismic loading on the cracking processes in a specimen containing a single flaw,a numerical approach based on the bonded-particle model(BPM)was adopted to study the seismic loading applied in two orthogonal directions.The results reveal that no transmission and reflection phenomena were observable in the small specimens(76 mm×152 mm)because they were considerably smaller than the wavelength of the P-wave.Furthermore,under seismic loading,the induced crack was solely tensile in nature.Repeated axial seismic loading did not induce crack propagation after the first axial seismic loading.Cracks began to propagate only when the seismic loading direction was changed from axial to lateral,and then back to axial,ultimately resulting in the failure of the specimen. 展开更多
关键词 Seismic wave Cyclic loading cracking processes Bonded-particle model
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Examining the influence of the loading path on the cracking characteristics of a pre-fractured rock specimen with discrete element method simulation 被引量:1
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作者 Kang DUAN Ri-hua JIANG +2 位作者 Xue-jian LI Lu-chao WANG Ze-ying YANG 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2023年第4期332-349,共18页
Damage in a rock mass is heavily dependent on the existence and growth of joints,which are also influenced by the complex stress states induced by human activities(e.g.,tunneling and excavation).A proper representatio... Damage in a rock mass is heavily dependent on the existence and growth of joints,which are also influenced by the complex stress states induced by human activities(e.g.,tunneling and excavation).A proper representation of the loading path is essential for understanding the mechanical behaviors of rock masses.Based on the discrete element method(DEM),the influence of the loading path on the cracking process of a rock specimen containing an open flaw is examined.The effectiveness of the model is confirmed by comparing the simulation results under a uniaxial compression test to existing research findings,where wing crack initiates first and secondary cracks contribute to the failure of the specimen.Simulation results confirm that the cracking process is dependent upon both the confining pressure and the loading path.Under the axial loading test,a higher confining pressure suppresses the development of tensile wing cracks and forces the formation of secondary cracks in the form of shear bands perpendicular to the flaw.Increase of confining pressure also decreases the influence of the loading path on the cracking process.Reduction of confining pressure during an unloading test amplifies the concentration of tensile stress and ultimately promotes the appearance of a tensile splitting fracture at meso-scale.Confining pressure at the failure stage is well predicted by the Hoek-Brown failure criterion under quasi-static conditions. 展开更多
关键词 cracking process Loading path Fractured rock mass Discrete element method(DEM) Local stress concentration
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Dual-radiation-chamber coordinated overall energy efficiency scheduling solution for ethylene cracking process regarding multi-parameter setting and multi-flow allocation 被引量:1
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作者 Di Meng Cheng Shao Li Zhu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2021年第6期180-197,共18页
Ethylene cracking process is the core production process in ethylene industry,and is paid more attention to reduce high energy consumption.Because of the interdependent relationships between multi-flow allocation and ... Ethylene cracking process is the core production process in ethylene industry,and is paid more attention to reduce high energy consumption.Because of the interdependent relationships between multi-flow allocation and multi-parameter setting in cracking process,it is difficult to find the overall energy efficiency scheduling for the purpose of saving energy.The traditional scheduling solutions with optimal economic benefit are not applicable for energy efficiency scheduling issue due to the neglecting of recycle and lost energy,as well as critical operation parameters as coil outlet pressure(COP)and dilution ratio.In addition,the scheduling solutions mostly regard each cracking furnace as an elementary unit,regardless of the coordinated operation of internal dual radiation chambers(DRC).Therefore,to improve energy utilization and production operation,a novel energy efficiency scheduling solution for ethylene cracking process is proposed in this paper.Specifically,steam heat recycle and exhaust heat loss are considered in cracking process based on 6 types of extreme learning machine(ELM)based cracking models incorporating DRC operation and three operation parameters as coil outlet temperature(COT),COP,and dilution ratio according to semi-mechanism analysis.Then to provide long-term decision-making basis for energy efficiency scheduling,overall energy efficiency indexes,including overall output per unit net energy input(OONE),output-input ratio per unit net energy input(ORNE),exhaust gas heat loss ratio(EGHL),are designed based on input-output analysis in terms of material and energy flows.Finally,a multiobjective evolutionary algorithm based on decomposition(MOEA/D)is employed to solve the formulated multi-objective mixed-integer nonlinear programming(MOMINLP)model.The validities of the proposed scheduling solution are illustrated through a case study.The scheduling results demonstrate that an optimal balance between multi-flow allocation,multi-parameter setting,and DRC coordinated operation is reached,which achieves 3.37%and 2.63%decreases in net energy input for same product output and conversion ratio,as well as the 1.56%decrease in energy loss ratio. 展开更多
关键词 Ethylene cracking process Energy efficiency scheduling Overall energy efficiency indexes Dual radiation chamber Multiple operation parameters Multiple energy flows
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Solid state crack repair by friction stir processing in 304L stainless steel 被引量:5
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作者 C.Gunter M.P.Miles +1 位作者 F.C.Liu T.W Nelson 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2018年第1期140-147,共8页
Friction stir processing (FSP) was investigated as a method of repairing cracks in 12 mm thick 304L stainless steel plate. Healing feasibility was demonstrated by processing a tapered crack using a PCBN/W- Re tool w... Friction stir processing (FSP) was investigated as a method of repairing cracks in 12 mm thick 304L stainless steel plate. Healing feasibility was demonstrated by processing a tapered crack using a PCBN/W- Re tool with a 25 mm diameter shoulder and a pin length of 6.4 mm. The experiment showed that it was possible to heal a crack that begins narrow and then progressively grows up to a width of 2 mm. Bead on plate experiments were used to find the best parameters for creating a consolidated stir zone with the least amount of hardness difference compared to the base metal. Grain refinement in some specimens resulted in much higher stir zone hardness, compared to base metal, A plot of grain size versus microhardness showed a very strong inverse correlation between grain size and hardness, as expected from the Hall- Perch relationship. Corrosion testing was carried out in order to evaluate the effect of FSP on potential sensitization of the stir zone. After 1000 h of intermittent immersion in 3.5% saline solution at room temperature it was found that no corrosion products formed on the base material controls or on any of the friction stir processed specimens. 展开更多
关键词 Stainless steel Crack healing Friction stir processing Corrosion resistance
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Effects of confining pressure on deformation failure behavior of jointed rock 被引量:9
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作者 CHEN Miao ZANG Chuan-wei +4 位作者 DING Zi-wei ZHOU Guang-lei JIANG Bang-you ZHANG Guang-chao ZHANG Cheng-peng 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第4期1305-1319,共15页
For a deeper understanding of the deformation failure behavior of jointed rock, numerical compression simulations are carried out on a rock specimen containing non-persistent joints under confining pressure with the b... For a deeper understanding of the deformation failure behavior of jointed rock, numerical compression simulations are carried out on a rock specimen containing non-persistent joints under confining pressure with the bondedparticle model. The microscopic parameters which can reflect the macroscopic mechanical properties and failure behavior of artificial jointed specimens are firstly calibrated. Then, the influence of joint inclination and confining pressure on stress-strain curves, crack patterns, and contact force distributions of jointed rock are investigated. The simulation results show that both the compressive strength and elastic modulus of the specimens increase with increasing confining pressure, and these two mechanical parameters decrease first and then increase with the increase of joints inclination. The sensitivity of strength and elastic modulus to confining pressure is not the same in different joints inclinations, which has the least impact on specimens with α=90°. Under low confining pressure, the failure modes are controlled by the joint inclination. As the confining pressure increased, the initiation and propagation of tensile crack are gradually inhibited, and the failure mode is transferred from tensile failure to shear-compression failure. Finally, the reinforcement effect of prestressed bolt support on engineering fractured rock mass is discussed. 展开更多
关键词 stability of surrounding rock non-persistent joints confining pressure cracking process discrete element method(DEM)
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Characterization of Loading Rate Effects on the Interactions Between Crack Growth and Inclusions in Cementitious Material 被引量:3
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作者 Shuai Zhou Xiaoying Zhuang 《Computers, Materials & Continua》 SCIE EI 2018年第12期417-446,共30页
The microcapsule-enabled cementitious material is an appealing building material and it has been attracting increasing research interest.By considering microcapsules as dissimilar inclusions in the material,this paper... The microcapsule-enabled cementitious material is an appealing building material and it has been attracting increasing research interest.By considering microcapsules as dissimilar inclusions in the material,this paper employs the discrete element method(DEM)to study the effects of loading rates on the fracturing behavior of cementitious specimens containing the inclusion and the crack.The numerical model was first developed and validated based on experimental results.It is then used to systematically study the initiation,the propagation and the coalescence of cracks in inclusion-enabled cementitious materials.The study reveals that the crack propagation speed,the first crack initiation stress,the coalescence stress,the compressive strength and the ultimate strain increase with the loading rate.The initiation position,the propagation direction,the cracking length and the type of the initiated cracks are influenced by the loading rates.Two new crack coalescence patterns are observed.It is easier to cause the coalescence between the circular void and a propagating crack at a slow loading rate than at a fast loading rate. 展开更多
关键词 MICROCAPSULE loading rate cracking processes DEM compressive loading
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The Interaction between Microcapsules with Different Sizes and Propagating Cracks 被引量:1
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作者 Xiaoying Zhuang Hung Nguyen-Xuan Shuai Zhou 《Computers, Materials & Continua》 SCIE EI 2021年第4期577-593,共17页
The microcapsule-contained self-healing materials are appealing since they can heal the cracks automatically and be effective for a long time.Although many experiments have been carried out,the influence of the size o... The microcapsule-contained self-healing materials are appealing since they can heal the cracks automatically and be effective for a long time.Although many experiments have been carried out,the influence of the size of microcapsules on the self-healing effect is still not well investigated.This study uses the two-dimensional discrete element method(DEM)to investigate the interaction between one microcapsule and one microcrack.The influence of the size of microcapsules is considered.The potential healing time and the influence of the initial damage are studied.The results indicate that the coalescence crack is affected by the size of holes.The elastic modulus,the compressive strength and the coalescence stress decrease with the rising radius of holes.The initial damage in experiments should be greater than 95%of the compressive strength to enhance the self-healing effect.The large microcapsules require slight initial damage.Both a new type of displacement field near the crack and a new category of coalescence crack are observed.The influence of sizes of holes on the cracking behavior of concrete with a circular hole and a pre-existing crack is clarified. 展开更多
关键词 MICROCAPSULE SIZE cracking processes DEM
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NUMERICAL STUDY ON PROPERTIES OF WEAK INTERLAYER OF LAMINATED COMPOSITE
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作者 Yafang Zhang Chun'an Tang 《Acta Mechanica Solida Sinica》 SCIE EI 2010年第3期231-239,共9页
With assumption of material inhomogeneity on meso level, a three-point bending beam model has been adopted to simulate crack propagation in two dimensional laminated composite and to verify the toughening mechanism of... With assumption of material inhomogeneity on meso level, a three-point bending beam model has been adopted to simulate crack propagation in two dimensional laminated composite and to verify the toughening mechanism of energy dissipation and crack deflection along the weak interlayer. Moreover, the effect of strength, elastic modulus and thickness of the weak interlayer on both strength and toughness of the laminated composite have also been investigated in this paper. 展开更多
关键词 laminated composite INHOMOGENEITY crack process TOUGHENING
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Nonlinear Statistical Process Monitoring Based on Control Charts with Memory Effect and Kernel Independent Component Analysis
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作者 张曦 阎威武 +1 位作者 赵旭 邵惠鹤 《Journal of Shanghai Jiaotong university(Science)》 EI 2007年第5期563-571,共9页
A novel nonlinear combination process monitoring method was proposed based on techniques with memo- ry effect (multivariate exponentially weighted moving average (MEWMA)) and kernel independent component analysis ... A novel nonlinear combination process monitoring method was proposed based on techniques with memo- ry effect (multivariate exponentially weighted moving average (MEWMA)) and kernel independent component analysis (KICA). The method was developed for dealing with nonlinear issues and detecting small or moderate drifts in one or more process variables with autocorrelation. MEWMA charts use additional information from the past history of the process for keeping the memory effect of the process behavior trend. KICA is a recently devel- oped statistical technique for revealing hidden, nonlinear statistically independent factors that underlie sets of mea- surements and it is a two-phase algorithm., whitened kernel principal component analysis (KPCA) plus indepen- dent component analysis (ICA). The application to the fluid catalytic cracking unit (FCCU) simulated process in- dicates that the proposed combined method based on MEWMA and KICA can effectively capture the nonlinear rela- tionship and detect small drifts in process variables. Its performance significantly outperforms monitoring method based on ICA, MEWMA-ICA and KICA, especially for lonu-term performance deterioration. 展开更多
关键词 kernel independent component analysis (KICA) multivariate exponentially weighted moving average(MEWMA) NONLINEAR fault detection process monitoring fluid catalytic cracking unit (FCCU) process
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Micromechanical study of loading rate effects between a hole and a crack 被引量:2
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作者 Shuai Zhou Xiaoying Zhuang 《Underground Space》 SCIE EI 2019年第1期22-30,共9页
The interactions between defects are important in rocks.The micromechanical interactions between a circular hole and a pre-existing crack under uniaxial compression with different loading rates are investigated by the... The interactions between defects are important in rocks.The micromechanical interactions between a circular hole and a pre-existing crack under uniaxial compression with different loading rates are investigated by the discrete element method(DEM).The crack initiation,crack propagation,and crack coalescence at different loading rates are studied.The loading rates influence the primary as well as secondary cracks.Both the primary and secondary cracks disturb the stress field and displacement field.The DEM simulation explains the initiation position of the primary and secondary cracks.The evolution of the displacement field and the stress field at different loading rates is analyzed.A new displacement field type is observed.The hole is easier to be broken by compression at higher loading rates while it tends to be broken by the coalescence crack at lower loading rates.The high loading rates lead to shielding effects of the hole on the pre-existing crack. 展开更多
关键词 ROCK DEFECT Loading rate cracking processes DEM Compressive loading
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