Fractured karst geothermal reservoir is a kind of typical geothermal reservoirs with the advantages of abundant storage water and easy reinjection of tail water during the period of geothermal utilization.Such geother...Fractured karst geothermal reservoir is a kind of typical geothermal reservoirs with the advantages of abundant storage water and easy reinjection of tail water during the period of geothermal utilization.Such geothermal system is also one of the geothermal reservoirs with the greatest potential for the development and utilization of geothermal energy in China.However,its geological structures are diverse(e.g.pore,fracture and vug),exhibiting complex characteristics of multiple scales,strong heterogeneity and various flow regimes.Therefore,the fluid-heat transfer processes and geothermal production performance of fractured karst geothermal reservoirs are not clarified.In this paper,a numerical model considering thermoehydraulic coupling processes based on the discrete fractureevug network approach is put forward,according to the characteristics of fracturedevuggy geothermal reservoirs.In addition,the accuracy of the numerical model is verified.The results obtained from this research are as follows.First,the numerical model considering the thermoehydraulic coupling process is put forward,in which the Darcy's law is used to describe the flow zone of porous medium,the NaviereStokes equation is used to illustrate the free flow zone of vugs,and the BeaverseJosepheSaffman boundary condition is used to couple the fluid flow between these two zones.Second,the connectivity of fracture network is the key parameter to control and evaluate the flow and heat transfer effects in fractured vuggy geothermal reservoirs.The existence of vugs plays an important role in the fluid flow and heat transfer in geothermal reservoirs.Third,the thermoehydraulic coupling model based on the discrete fractureevug network can effectively describe the fluid flow and heat transfer processes in fractured vuggy geothermal reservoirs.The connectivity of fracture networks controls the thermoehydraulic coupling processes in fractured vuggy geothermal reservoirs.Fourth,the existence of vugs seriously impacts the thermoehydraulic coupling processes in geothermal reservoirs.For instance,on the one hand,it increases the number of high-speed flow channels spanning across the system and even makes the system get connected.On the other hand,it increases the speed of local flow channels inside the system.In conclusion,this proposed method is of great significance for studying the development characteristics and optimizing their geothermal production performance of fractured vuggy geothermal reservoirs.展开更多
The relativistic neutrino emissivity of the nucleonic direct URCA processes in neutron star matter is investigated within the relativistic Hartree-Fock approximation. We particularly study the influences of the tensor...The relativistic neutrino emissivity of the nucleonic direct URCA processes in neutron star matter is investigated within the relativistic Hartree-Fock approximation. We particularly study the influences of the tensor couplings of vector mesons ω and ρ on the nucleonic direct URCA processes. It is found that the inclusion of the tensor couplings of vector mesons w and p can slightly increase the maximum mass of neutron stars. In addition, the results indicate that the tensor couplings of vector mesons ω and ρ lead to obvious enhancement of the total neutrino emissivity for the nucleonic direct URCA processes, which must accelerate the cooling rate of the non- superfluid neutron star matter. However, when considering only the tensor coupling of vector meson ρ, the neutrino emissivity for the nucleonic direct URCA processes slightly declines at low densities and significantly increases at high densities. That is, the tensor coupling of vector meson ρ leads to the slow cooling rate of a low-mass neutron star and rapid cooling rate of a massive neutron star.展开更多
As a crucial component of the Earth’s climate system,Antarctic sea ice has demonstrated significant variability over the satellite era.Here,we identify a remarkable decadal transition in the total Antarctic Sea Ice E...As a crucial component of the Earth’s climate system,Antarctic sea ice has demonstrated significant variability over the satellite era.Here,we identify a remarkable decadal transition in the total Antarctic Sea Ice Extent(SIE).The stage from 1979 to 2006 is characterized by high-frequency(i.e.,seasonal to interannual)temporal variability in SIE and zonal asymmetry in Sea Ice Concentration(SIC),which is primarily under the control of the Amundsen Sea Low(ASL).After 2007,however,sea ice changes exhibit a more spatially homogeneous pattern in SIC and a more temporally long-lasting mode in SIE.Further analysis reveals that sea ice-ocean interaction plays a major role in the low-frequency(i.e.,multiannual)variability of Antarctic sea ice from 2007−22.The related physical process is inferred to manifest as a strong coupling between the surface and the subsurface ocean layers,involving enhanced vertical convection and the downward delivery of the surface anomalies related to ice melting and freezing processes,thus maintaining the SIE anomalies for a longer time.Furthermore,this process mainly occurs in the Amundsen-Bellingshausen Sea(ABS)sector,and the weakened subsurface ocean stratification is the key factor triggering the coupling process in this region.We find that the Circumpolar Deep Water(CDW)over the ABS sector continued to shoal before 2007 and remained stable thereafter.It is speculated that the shoaling of the CDW may be a possible driver leading to the weakening of the subsurface stratification.展开更多
This study presents a fully coupled thermo-hydro-mechanical (THM) constitutive model for clay rocks. The model is formulated within the elastic-viscoplasticity framework, which considers nonlinearity and softening aft...This study presents a fully coupled thermo-hydro-mechanical (THM) constitutive model for clay rocks. The model is formulated within the elastic-viscoplasticity framework, which considers nonlinearity and softening after peak strength, anisotropy of stiffness and strength, as well as permeability variation due to damage. In addition, the mechanical properties are coupled with thermal phenomena and accumulated plastic strains. The adopted nonlocal and viscoplastic approaches enhance numerical efficiency and provide the possibility to simulate localization phenomena. The model is validated against experimental data from laboratory tests conducted on Callovo-Oxfordian (COx) claystone samples that are initially unsaturated and under suction. The tests include a thermal phase where the COx specimens are subjected to different temperature increases. A good agreement with experimental data is obtained. In addition, parametric analyses are carried out to investigate the influence of the hydraulic boundary conditions (B.C.) and post-failure behavior models on the THM behavior evolution. It is shown that different drainage conditions affect the thermally induced pore pressures that, in turn, influence the onset of softening. The constitutive model presented constitutes a promising approach for simulating the most important features of the THM behavior of clay rocks. It is a tool with a high potential for application to several relevant case studies, such as thermal fracturing analysis of nuclear waste disposal systems.展开更多
Coupled dissolution-precipitation is one of the critical processes influencing the mineralogical and geochemical evolution of pegmatites.This mechanism involves the simultaneous dissolution of primary mineral phases a...Coupled dissolution-precipitation is one of the critical processes influencing the mineralogical and geochemical evolution of pegmatites.This mechanism involves the simultaneous dissolution of primary mineral phases and the precipitation of secondary phases,driven by changes in the chemical environment,often mediated by hydrothermal fluids.The Bailongshan Li deposit,located in the West Kunlun region of northwest China,is a significant geological formation known for its rich lithium content and associated rare metals such as tantalum,niobium,and tin.This study investigates the coupled dissolution-precipitation processes that have played a crucial role in the mineralization of this deposit,focusing on key minerals,including cassiterite(Cst),columbite-group minerals(CGM),and elbaite(Elb).Using a combination of petrographic analysis,back-scattered electron(BSE)imaging,cathodoluminescence(CL)imaging,and micro X-ray fluorescence(XRF)mapping,we examined the textural and chemical characteristics of these minerals.Our findings reveal intricate patchy zoning patterns and element distributions(indicated by the Nb,Ta,W,Mn,Fe,Hf,Ti for CGM;Hf,Ti Rb,W,Nb,Ta for Cst;Ti,Zn,Fe,W,Hf,Mn,K for Elb)that indicate multiple stages of mineral alteration driven by fluid-mediated processes.The coupled dissolution-precipitation mechanisms observed in the Bailongshan deposit have resulted in significant redistribution and enrichment of economically valuable elements.The study highlights the importance of hydrothermal fluids in altering primary mineral phases and precipitating secondary phases with distinct compositions.These processes not only modified the mineralogical makeup of the pegmatite but also enhanced its economic potential by concentrating rare metals.Signatures of coupled dissolutionprecipitation processes can serve as an essential tool for mineral exploration,guiding the search for high-grade zones within similar pegmatitic formations.展开更多
CS2 removal was obtained by coupling catalytic hyidation on bi-functional catalyst. On the hydrolysis active sites, CS2 is hydrolyzed to HES, while on the oxidation active sites, HES is oxidized to elemental S or sulf...CS2 removal was obtained by coupling catalytic hyidation on bi-functional catalyst. On the hydrolysis active sites, CS2 is hydrolyzed to HES, while on the oxidation active sites, HES is oxidized to elemental S or sulfuric acid deposited on the porous support. The above process can be expressed as follows： CS2 H2O→ COS H2O→ H2S O2→ S/SO4^2-. H2S oxidation eliminates its prohibition on C52 hydrolysis so that the rate of coupling removal CS2 is 5 times higher than that of CS2 hydrolysis. The same active energy of hydrolysis and coupling reaction also indicates that HES oxidation does not change the reaction mechanism of CS2 hydrolysis. Temperature has obvious effect on the process while the mole ratio of O2 concentration to CS2 concentration （O/S） does not, especially in excess of 2.5. The formation of sulfuric acid on the catalyst surface poisons hydrolysis active sites and causes the decrease of left OH^-1 concentration on the catalysts surface. Lower temperature is suggested for this bi-functional catalyst owing to the low yield ratio of S/SO4^2-.展开更多
The greatest challenges of rigorously modeling coupled hydro-mechanical(HM)processes in fractured geological media at different scales are associated with computational geometry.These challenges include dynamic sheari...The greatest challenges of rigorously modeling coupled hydro-mechanical(HM)processes in fractured geological media at different scales are associated with computational geometry.These challenges include dynamic shearing and opening of intersecting fractures at discrete fracture scales as a result of coupled processes,and contact alteration along rough fracture surfaces that triggers structural and physical changes of fractures at micro-asperity scale.In this paper,these challenges are tackled by developing a comprehensive modeling approach for coupled processes in fractured geological media based on numerical manifold method(NMM)at multiple scales.Based on their distinct geometric features,fractures are categorized into three different scales:dominant fracture,discrete fracture,and discontinuum asperity scales.Here the scale is relative,that of the fracture relative to that of the research interest or domain.Different geometric representations of fractures at different scales are used,and different governing equations and constitutive relationships are applied.For dominant fractures,a finite thickness zone model is developed to treat a fracture as a porous nonlinear domain.Nonlinear fracture mechanical behavior is accurately modeled with an implicit approach based on strain energy.For discrete fractures,a zero-dimensional model was developed for analyzing fluid flow and mechanics in fractures that are geometrically treated as boundaries of the rock matrix.With the zero-dimensional model,these fractures can be modeled with arbitrary orientations and intersections.They can be fluid conduits or seals,and can be open,bonded or sliding.For the discontinuum asperity scale,the geometry of rough fracture surfaces is explicitly represented and contacts involving dynamic alteration of contacts among asperities are rigorously calculated.Using this approach,fracture alteration caused by deformation,re-arrangement and sliding of rough surfaces can be captured.Our comprehensive model is able to handle the computational challenges with accurate representation of intersections and shearing of fractures at the discrete fracture scale and rigorously treats contacts along rough fracture surfaces at the discontinuum asperity scale.With future development of three-dimensional(3D)geometric representation of discrete fracture networks in porous rock and contacts among multi-body systems,this model is promising as a basis of 3D fully coupled analysis of fractures at multiple scales,for advancing understanding and optimizing energy recovery and storage in fractured geological media.展开更多
Basin-mountain coupling is a key issue for basin formation and evolution. The analysis of basin-mountain coupling process, as well as quantitative or semiquantitative restoration of prototype basin and the evolution o...Basin-mountain coupling is a key issue for basin formation and evolution. The analysis of basin-mountain coupling process, as well as quantitative or semiquantitative restoration of prototype basin and the evolution of continental margin, can be used to interpret the geological process of basin-range conversion and reconstruct early prototype basins, which is a difficult and leadin~ scientific oroblem of basin research.展开更多
The dehydrogenation of cyclohexanol to cyclohexanone is a crucial industrial process in the production of caprolactam and adipic acid, both of which serve as important precursors in nylon textiles. This endothermic re...The dehydrogenation of cyclohexanol to cyclohexanone is a crucial industrial process in the production of caprolactam and adipic acid, both of which serve as important precursors in nylon textiles. This endothermic reaction is constrained by thermodynamic equilibrium and involves a complex reaction network, leading to a heightened focus on catalysts and process design. Copper-based catalysts have been extensively studied and exhibit exceptional low-temperature catalytic performance in cyclohexanol dehydrogenation, with some being commercially used in the industry. This paper specifically concentrates on research advancement concerning active species, reaction mechanisms, factors influencing product selectivity, and the deactivation behaviors of copper-based catalysts. Moreover, a brief introduction to the new processes that break thermodynamic equilibrium via reaction coupling and their corresponding catalysts is summarized here as well. These reviews may off er guidance and potential avenues for further investigations into catalysts and processes for cyclohexanol dehydrogenation.展开更多
The thermal-mechanical coupling finite element method(FEM)was usedto simulate a non-isothermal sheet metal extrusion process. On thebasis of the finite plasticity consistent with multiplicativedecomposition of the def...The thermal-mechanical coupling finite element method(FEM)was usedto simulate a non-isothermal sheet metal extrusion process. On thebasis of the finite plasticity consistent with multiplicativedecomposition of the deformation gradient, the enhanced as- sumedstrain(EAS)FEM was applied to carry out the numerical simulation. Inorder to make the computation reliable ad avoid hour- glass mode inthe EAS element under large compressive strains, an alterative formof the original enhanced deformation gradient was employed. Inaddition, reduced factors were used in the computation of the elementlocal internal parameters and the enhanced part of elementalstiffness.展开更多
The main objective of this paper is to investigate and analyse the thermo-hydro-mechanical（THM） coupling phenomena and their influences on the repository safety.In this paper,the high-level waste（HLW） disposal con...The main objective of this paper is to investigate and analyse the thermo-hydro-mechanical（THM） coupling phenomena and their influences on the repository safety.In this paper,the high-level waste（HLW） disposal concept in drifts in clay formation with backfilled bentonite buffer is represented numerically using the CODE BRIGHT developed by the Technical University of Catalonia in Barcelona.The parameters of clay and bentonite used in the simulation are determined by laboratory and in situ experiments.The calculation results are presented to show the hydro-mechanical（HM） processes during the operation phase and the THM processes in the after-closure phase.According to the simulation results,the most probable critical processes for the disposal project have been represented and analyzed.The work also provides an input for additional development regarding the design,assessment and validation of the HLW disposal concept.展开更多
The West Antarctic Peninsula(WAP)region is one of the most productive marine ecosystems in the Southern Ocean that support the food web for phytoplankton,krill spawning or recruitment and several krill consumers at hi...The West Antarctic Peninsula(WAP)region is one of the most productive marine ecosystems in the Southern Ocean that support the food web for phytoplankton,krill spawning or recruitment and several krill consumers at higher-trophic level like penguins and Antarctic fur seals.Characterized by channels and islands,the complex topography of the WAP generates interconnected circulation patterns,strongly influencing vertical stratification,nutrient availability and distribution of marine organisms.Additionally,rapid climate change associated with major climate modes like the Southern Annular Mode(SAM)and El Niño-Southern Oscillation(ENSO)has significant effects on long-term variations of physical environments and biological production.The objective of this study is to reveal the spatial-temporal variations of phytoplankton biomass in the WAP region and the modulating physical-ecological processes.By using 9-year hydrographic and ecological data of five transects collected by the Palmer Long-Term Ecosystem Research,the horizontal and vertical distributions of several physical and ecological properties,with a particular focus on chlorophyll(Chl)concentration were explored.Regression analysis among area-averaged properties and properties at single stations was performed to reveal the relationship between the interannual variations of physical and ecological processes.The correlation results showed that Chl concentration exhibited a positive relationship with both the circumpolar deep water(CDW)intrusion and vertical stratification,but showed a negative correlation with SAM at some specific stations.However,certain processes or mechanisms may only be dominant for specific stations and not applicable to the entire region.No single physical or ecological factors have been found to significantly influence the Chl distribution throughout the WAP region,which may be attributed to the heterogeneity of sea ice conditions,geometry and hydrodynamic features as well as variations in nutrient sources.展开更多
The dynamic effect is a very important issue widely debated by scholars when studying the genetic and disaster-causing mechanisms of earthquake-triggered landslides.First,the dynamic effect mechanism and phenomena of ...The dynamic effect is a very important issue widely debated by scholars when studying the genetic and disaster-causing mechanisms of earthquake-triggered landslides.First,the dynamic effect mechanism and phenomena of earthquake-triggered landslides were summarized in this paper.Then,the primary types of dynamic effects were further used to interpret the Mogangling landslide in Moxi Town of Luding County,China.A field investigation,remote sensing,numerical calculation and theoretical analysis were carried out to illustrate the failure mechanism of slope rock masses affected by earthquakes.The interaction between seismic waves and slope rock masses and the induced dynamic effect of slope rock masses were primarily accounted for in the analysis.The slope topography,rock mass weathering and unloading characteristics,river erosion,regional seismogenic structure,and rock mass structure characteristics were also discussed.The results showed that the formation of the Mogangling landslide was mainly related to the high amplification effect of seismic acceleration and back slope effects,interface dynamic stress effects,and double-sided slope effects of seismic waves caused by the catastrophic Ms 7.75 Moxi Earthquake in 1786.The principles for the site and route selection of large-scale infrastructure in the planning stage and the scientific prevention of seismic geological disasters were proposed on the basis of the dynamic effect of earthquake-induced landslides.展开更多
Seepage flow through soils,rocks and geotechnical structures has a great influence on their stabilities and performances,and seepage control is a critical technological issue in engineering practices.The physical mech...Seepage flow through soils,rocks and geotechnical structures has a great influence on their stabilities and performances,and seepage control is a critical technological issue in engineering practices.The physical mechanisms associated with various engineering measures for seepage control are investigated from a new perspective within the framework of continuum mechanics;and an equation-based classification of seepage control mechanisms is proposed according to their roles in the mathematical models for seepage flow,including control mechanisms by coupled processes,initial states,boundary conditions and hydraulic properties.The effects of each mechanism on seepage control are illustrated with examples in hydroelectric engineering and radioactive waste disposal,and hence the reasonability of classification is demonstrated.Advice on performance assessment and optimization design of the seepage control systems in geotechnical engineering is provided,and the suggested procedure would serve as a useful guidance for cost-effective control of seepage flow in various engineering practices.展开更多
The widespread organic pollutants in wastewater are one of the global environmental problems.Advanced oxidation processes(AOPs)are widely used because of their characteristics of high efficiency and strong oxidation.H...The widespread organic pollutants in wastewater are one of the global environmental problems.Advanced oxidation processes(AOPs)are widely used because of their characteristics of high efficiency and strong oxidation.However,AOPs may have some defects,such as incomplete mineralization of organic pollutants and the generation of toxic by-products during the degradation process,thus it is essential to seek efficient and green wastewater treatment technologies.Coupling different AOPs or other processes is beneficial for the mineralization of pollutants and reduces ecological risks to the environment.It is worth noting that carbonaceous materials(CMs)have received widespread attention and application in the degradation of organic pollutants in water by advanced oxidation coupling processes(C-AOPs)due to their excellent physicochemical properties in recent years.However,the behaviors and mechanisms of C-AOPs based on CMs on the degradation of organic pollutants are still unknown.Therefore,it is essential to comprehensively summarize the recent research progress.In this review,the applications of different CMs in C-AOPs were reviewed first.Secondly,the synergistic mechanisms of the C-AOPs based on different CMs were discussed.Then,toxic intermediates were explored and important toxicity assessment methods were proposed.Finally,the application potential of the C-AOPs in the future and the challenges were proposed.This review provides an important reference for the application and optimization of the C-AOPs in organic wastewater treatment in the future.展开更多
This work attempts to extend the fundamental theory for classic gas dynamics to viscous compressible flow,of which aeroacoustics will naturally be a special branch.As a continuation of Part I.Unbounded fluid(Mao et al...This work attempts to extend the fundamental theory for classic gas dynamics to viscous compressible flow,of which aeroacoustics will naturally be a special branch.As a continuation of Part I.Unbounded fluid(Mao et al.,2022),this paper studies the source of longitudinal field at solid boundary,caused by the on-wall kinematic and viscous dynamic coupling of longitudinal and transverse processes.We find that at this situation the easiest choice for the two independent thermodynamic variables is the dimensionless pressure P and temperature T.The two-level structure of boundary dynamics of longitudinal field is obtained by applying the continuity equation and its normal derivative to the surface.We show that the boundary dilatation flux represents faithfully the boundary production of vortex sound and entropy sound,and the mutual generation mechanism of the longitudinal and transverse fields on the boundary does not occur symmetrically"at the samc level,but appears along a zigzag route.At the first level,it is the pressure gradient that generates vorticity unidirectionally;while at the second level,it is the vorticity that generates dilatation unidirectionally.展开更多
This paper presents a deep reflection on the advective wave equations for velocity vector and dilatation discovered in the past decade.We show that these equations can form the theoretical basis of modern gas dynamics...This paper presents a deep reflection on the advective wave equations for velocity vector and dilatation discovered in the past decade.We show that these equations can form the theoretical basis of modern gas dynamics,because they dominate not only various complex viscous and heat-conducting gas flows but also their associated longitudinal waves,including aero-generated sound.Current aeroacoustics theory has been developing in a manner quite independently of gas dynamics;it is based on the advective wave equations for thermodynamic variables,say the exact Phillips equation of relative disturbance pressure as a representative one.However,these equations do not cover the fluid flow that generates and propagates sound waves.In using them,one has to assume simplified base-flow models,which we argue is the main theoretical obstacle to identifying sound source and achieving effective noise control.Instead,we show that the Phillips equation and alike is nothing but the first integral of the dilatation equation that also governs the longitudinal part of the flow field.Therefore,we conclude that modern aeroacoustics should merge back into the general unsteady gas dynamics as a special branch of it,with dilatation of multiple sources being a new additional and sharper sound variable.展开更多
In order to produce natural gas hydrate safely and efficiently,it is quite crucial to research the stability of hydrate reservoir in the process of its exploitation.The coupled thermal-hydrodynamic-mechanical(THM)nume...In order to produce natural gas hydrate safely and efficiently,it is quite crucial to research the stability of hydrate reservoir in the process of its exploitation.The coupled thermal-hydrodynamic-mechanical(THM)numerical simulation can clearly present the mechanical response laws in the process of hydrate exploitation by horizontal well,but the model is often simplified as a profile vertical to the production well,so the evolution characteristics of real formation deformation space cannot be described sufficiently.To this end,this paper develops a coupled THM simulator applicable to the large-scale hydrate exploitation by horizontal well by introducing interactive interface to the FLAC mechanics program based on the hydrate exploitation program TOUGHþHYDRATE.Then,based on the field data of second hydrate production test in South China Sea,the gas and water production and formation deformation laws under the middle-and long-term development conditions of horizontal wells are studied by taking the actual gas production of horizontal well during the production test as the constraint of coupled THM model.And the following research results are obtained.First,when the production pressure is 7 MPa and the horizontal well length is 300 m,the gas production of horizontal well can reach 1190×10^(4)m^(3),the pressure drop has a larger influence range in the free gas layer,the produced gas mainly comes from the free gas layer and the hydrate layer and the hydrate dissociation range is not large.Second,it is predicted that the seafloor settlement is about 0.16 m after 60 days'production test and 0.52 m after osne year's production.In conclusion,hydrate exploitation by horizontal well can cause a large range of seafloor settlement.The seafloor surface settles linearly and continuously and the spatial settlement distribute is in the shape of ellipse.What's more,the greatest deformation(vertical displacement)occurs at the horizontal well and above it,where formation damage happens the easiest.It is recommended to study seafloor deformation and landslip risk under the conditions of middle and long-term production based on seafloor topography,valley distribution and nonuniform spatial thickness of mineral ores.展开更多
The removal of 17β-estradiol （E2） in laccase catalyzed oxidative coupling processes was systematically studied in this work. We focused on the influence of pH and natural organic matter （NOM） on the performance o...The removal of 17β-estradiol （E2） in laccase catalyzed oxidative coupling processes was systematically studied in this work. We focused on the influence of pH and natural organic matter （NOM） on the performance of the enzymatic treatment processes. It was found that the optimal pH for E2 removal was between 4 and 6. The removal of E2 was slightly inhibited in the presence of NOM. Enzymatic transformation of E2 was second-order in kinetics with first-order to both the concentrations of the enzyme and contaminant. Mass spectrum （MS） analysis suggested that coupling products were formed through radical-radical coupling mechanism. The results of this study demonstrated that laccase catalyzed oxidative coupling process could potentially serve as a treatment strategy to control steroid estrogens.展开更多
As a kind of clean renewable energy,the production and utilization of geothermal resources can make a great contribution to optimizing the energy structure and energy conservation and emission reduction.The circulatin...As a kind of clean renewable energy,the production and utilization of geothermal resources can make a great contribution to optimizing the energy structure and energy conservation and emission reduction.The circulating heat extraction process of working fluid will disturb the equilibrium state of physical and chemical fields inside the reservoir,and involve the mutual coupling of heat transfer,flow,stress,and chemical reaction.Revealing the coupling mechanism of flow and heat transfer inside the reservoir during geothermal exploitation can provide important theoretical support for the efficient exploitation of geothermal resources.This paper reviews the research advances of the multi-field coupling model in the reservoir during geothermal production over the past 40 years.The thrust of this paper is on objective analysis and evaluation of the importance of each coupling process and its influence on reservoir heat extraction performance.Finally,we discuss the existing challenges and perspectives to promote the future development of the geothermal reservoir multi-field coupling model.An accurate understanding of the multi-field coupling mechanism,an efficient cross-scale modeling method,as well as the accurate characterization of reservoir fracture morphology,are crucial for the multi-field coupling model of geothermal production.展开更多
基金Major science and technology projects of PetroChina“Study on production mechanism and reservoir numerical simulation technology of deep carbonate reservoir”(Serial number:ZD2019-183-008)Project sponsored by the National Natural Science Foundation of China“Study on fluid-solid coupling seepage theory and numerical simulation of condensate gas reservoir in fractured-vuggy carbonate rocks”(Serial number:52074336)Key project of the National Natural Science Foundation of China“Study on heat and mass transfer mechanism in coupled heat,fluid,dynamic and chemical fields of enhanced geothermal system”(Serial number:51936001).
文摘Fractured karst geothermal reservoir is a kind of typical geothermal reservoirs with the advantages of abundant storage water and easy reinjection of tail water during the period of geothermal utilization.Such geothermal system is also one of the geothermal reservoirs with the greatest potential for the development and utilization of geothermal energy in China.However,its geological structures are diverse(e.g.pore,fracture and vug),exhibiting complex characteristics of multiple scales,strong heterogeneity and various flow regimes.Therefore,the fluid-heat transfer processes and geothermal production performance of fractured karst geothermal reservoirs are not clarified.In this paper,a numerical model considering thermoehydraulic coupling processes based on the discrete fractureevug network approach is put forward,according to the characteristics of fracturedevuggy geothermal reservoirs.In addition,the accuracy of the numerical model is verified.The results obtained from this research are as follows.First,the numerical model considering the thermoehydraulic coupling process is put forward,in which the Darcy's law is used to describe the flow zone of porous medium,the NaviereStokes equation is used to illustrate the free flow zone of vugs,and the BeaverseJosepheSaffman boundary condition is used to couple the fluid flow between these two zones.Second,the connectivity of fracture network is the key parameter to control and evaluate the flow and heat transfer effects in fractured vuggy geothermal reservoirs.The existence of vugs plays an important role in the fluid flow and heat transfer in geothermal reservoirs.Third,the thermoehydraulic coupling model based on the discrete fractureevug network can effectively describe the fluid flow and heat transfer processes in fractured vuggy geothermal reservoirs.The connectivity of fracture networks controls the thermoehydraulic coupling processes in fractured vuggy geothermal reservoirs.Fourth,the existence of vugs seriously impacts the thermoehydraulic coupling processes in geothermal reservoirs.For instance,on the one hand,it increases the number of high-speed flow channels spanning across the system and even makes the system get connected.On the other hand,it increases the speed of local flow channels inside the system.In conclusion,this proposed method is of great significance for studying the development characteristics and optimizing their geothermal production performance of fractured vuggy geothermal reservoirs.
基金Supported by the National Natural Science Foundation of China under Grant Nos 11447165,11373047 and 11265009the Youth Innovation Promotion Association of Chinese Academy of Sciences under Grant No 2016056
文摘The relativistic neutrino emissivity of the nucleonic direct URCA processes in neutron star matter is investigated within the relativistic Hartree-Fock approximation. We particularly study the influences of the tensor couplings of vector mesons ω and ρ on the nucleonic direct URCA processes. It is found that the inclusion of the tensor couplings of vector mesons w and p can slightly increase the maximum mass of neutron stars. In addition, the results indicate that the tensor couplings of vector mesons ω and ρ lead to obvious enhancement of the total neutrino emissivity for the nucleonic direct URCA processes, which must accelerate the cooling rate of the non- superfluid neutron star matter. However, when considering only the tensor coupling of vector meson ρ, the neutrino emissivity for the nucleonic direct URCA processes slightly declines at low densities and significantly increases at high densities. That is, the tensor coupling of vector meson ρ leads to the slow cooling rate of a low-mass neutron star and rapid cooling rate of a massive neutron star.
基金supported by the National Natural Science Foundation China(Grant No.42176222).
文摘As a crucial component of the Earth’s climate system,Antarctic sea ice has demonstrated significant variability over the satellite era.Here,we identify a remarkable decadal transition in the total Antarctic Sea Ice Extent(SIE).The stage from 1979 to 2006 is characterized by high-frequency(i.e.,seasonal to interannual)temporal variability in SIE and zonal asymmetry in Sea Ice Concentration(SIC),which is primarily under the control of the Amundsen Sea Low(ASL).After 2007,however,sea ice changes exhibit a more spatially homogeneous pattern in SIC and a more temporally long-lasting mode in SIE.Further analysis reveals that sea ice-ocean interaction plays a major role in the low-frequency(i.e.,multiannual)variability of Antarctic sea ice from 2007−22.The related physical process is inferred to manifest as a strong coupling between the surface and the subsurface ocean layers,involving enhanced vertical convection and the downward delivery of the surface anomalies related to ice melting and freezing processes,thus maintaining the SIE anomalies for a longer time.Furthermore,this process mainly occurs in the Amundsen-Bellingshausen Sea(ABS)sector,and the weakened subsurface ocean stratification is the key factor triggering the coupling process in this region.We find that the Circumpolar Deep Water(CDW)over the ABS sector continued to shoal before 2007 and remained stable thereafter.It is speculated that the shoaling of the CDW may be a possible driver leading to the weakening of the subsurface stratification.
基金funded by the European Union's Horizon 2020 research and innovation programme under a grant agreement (Grant No.847593)partially supported by the Fundamental Research Funds for the Central Universities (Grant No.22120240029).
文摘This study presents a fully coupled thermo-hydro-mechanical (THM) constitutive model for clay rocks. The model is formulated within the elastic-viscoplasticity framework, which considers nonlinearity and softening after peak strength, anisotropy of stiffness and strength, as well as permeability variation due to damage. In addition, the mechanical properties are coupled with thermal phenomena and accumulated plastic strains. The adopted nonlocal and viscoplastic approaches enhance numerical efficiency and provide the possibility to simulate localization phenomena. The model is validated against experimental data from laboratory tests conducted on Callovo-Oxfordian (COx) claystone samples that are initially unsaturated and under suction. The tests include a thermal phase where the COx specimens are subjected to different temperature increases. A good agreement with experimental data is obtained. In addition, parametric analyses are carried out to investigate the influence of the hydraulic boundary conditions (B.C.) and post-failure behavior models on the THM behavior evolution. It is shown that different drainage conditions affect the thermally induced pore pressures that, in turn, influence the onset of softening. The constitutive model presented constitutes a promising approach for simulating the most important features of the THM behavior of clay rocks. It is a tool with a high potential for application to several relevant case studies, such as thermal fracturing analysis of nuclear waste disposal systems.
基金jointly supported by the National Natural Science Foundation of China(Nos.42250202,92162323,42272075)the Fundamental Research Funds for the Central Universities,Sun Yat-sen University(No.24lgqb001)+1 种基金the Natural Science Foundation Project of Guangdong Province(No.2022A1515010003)the Guangdong Province Introduced Innovative R&D Team of Big Data—Mathematical Earth Sciences and Extreme Geological Events Team(No.2021ZT09H399)。
文摘Coupled dissolution-precipitation is one of the critical processes influencing the mineralogical and geochemical evolution of pegmatites.This mechanism involves the simultaneous dissolution of primary mineral phases and the precipitation of secondary phases,driven by changes in the chemical environment,often mediated by hydrothermal fluids.The Bailongshan Li deposit,located in the West Kunlun region of northwest China,is a significant geological formation known for its rich lithium content and associated rare metals such as tantalum,niobium,and tin.This study investigates the coupled dissolution-precipitation processes that have played a crucial role in the mineralization of this deposit,focusing on key minerals,including cassiterite(Cst),columbite-group minerals(CGM),and elbaite(Elb).Using a combination of petrographic analysis,back-scattered electron(BSE)imaging,cathodoluminescence(CL)imaging,and micro X-ray fluorescence(XRF)mapping,we examined the textural and chemical characteristics of these minerals.Our findings reveal intricate patchy zoning patterns and element distributions(indicated by the Nb,Ta,W,Mn,Fe,Hf,Ti for CGM;Hf,Ti Rb,W,Nb,Ta for Cst;Ti,Zn,Fe,W,Hf,Mn,K for Elb)that indicate multiple stages of mineral alteration driven by fluid-mediated processes.The coupled dissolution-precipitation mechanisms observed in the Bailongshan deposit have resulted in significant redistribution and enrichment of economically valuable elements.The study highlights the importance of hydrothermal fluids in altering primary mineral phases and precipitating secondary phases with distinct compositions.These processes not only modified the mineralogical makeup of the pegmatite but also enhanced its economic potential by concentrating rare metals.Signatures of coupled dissolutionprecipitation processes can serve as an essential tool for mineral exploration,guiding the search for high-grade zones within similar pegmatitic formations.
文摘CS2 removal was obtained by coupling catalytic hyidation on bi-functional catalyst. On the hydrolysis active sites, CS2 is hydrolyzed to HES, while on the oxidation active sites, HES is oxidized to elemental S or sulfuric acid deposited on the porous support. The above process can be expressed as follows： CS2 H2O→ COS H2O→ H2S O2→ S/SO4^2-. H2S oxidation eliminates its prohibition on C52 hydrolysis so that the rate of coupling removal CS2 is 5 times higher than that of CS2 hydrolysis. The same active energy of hydrolysis and coupling reaction also indicates that HES oxidation does not change the reaction mechanism of CS2 hydrolysis. Temperature has obvious effect on the process while the mole ratio of O2 concentration to CS2 concentration （O/S） does not, especially in excess of 2.5. The formation of sulfuric acid on the catalyst surface poisons hydrolysis active sites and causes the decrease of left OH^-1 concentration on the catalysts surface. Lower temperature is suggested for this bi-functional catalyst owing to the low yield ratio of S/SO4^2-.
基金supported by Laboratory Directed Research and Development(LDRD)funding from Berkeley Labsupported by Open Fund of the State Key Laboratory of Geomechanics and Geotechnical Engineering,Institute of Rock and Soil Mechanics,Chinese Academy of Sciences(Grant No.Z017004)。
文摘The greatest challenges of rigorously modeling coupled hydro-mechanical(HM)processes in fractured geological media at different scales are associated with computational geometry.These challenges include dynamic shearing and opening of intersecting fractures at discrete fracture scales as a result of coupled processes,and contact alteration along rough fracture surfaces that triggers structural and physical changes of fractures at micro-asperity scale.In this paper,these challenges are tackled by developing a comprehensive modeling approach for coupled processes in fractured geological media based on numerical manifold method(NMM)at multiple scales.Based on their distinct geometric features,fractures are categorized into three different scales:dominant fracture,discrete fracture,and discontinuum asperity scales.Here the scale is relative,that of the fracture relative to that of the research interest or domain.Different geometric representations of fractures at different scales are used,and different governing equations and constitutive relationships are applied.For dominant fractures,a finite thickness zone model is developed to treat a fracture as a porous nonlinear domain.Nonlinear fracture mechanical behavior is accurately modeled with an implicit approach based on strain energy.For discrete fractures,a zero-dimensional model was developed for analyzing fluid flow and mechanics in fractures that are geometrically treated as boundaries of the rock matrix.With the zero-dimensional model,these fractures can be modeled with arbitrary orientations and intersections.They can be fluid conduits or seals,and can be open,bonded or sliding.For the discontinuum asperity scale,the geometry of rough fracture surfaces is explicitly represented and contacts involving dynamic alteration of contacts among asperities are rigorously calculated.Using this approach,fracture alteration caused by deformation,re-arrangement and sliding of rough surfaces can be captured.Our comprehensive model is able to handle the computational challenges with accurate representation of intersections and shearing of fractures at the discrete fracture scale and rigorously treats contacts along rough fracture surfaces at the discontinuum asperity scale.With future development of three-dimensional(3D)geometric representation of discrete fracture networks in porous rock and contacts among multi-body systems,this model is promising as a basis of 3D fully coupled analysis of fractures at multiple scales,for advancing understanding and optimizing energy recovery and storage in fractured geological media.
基金supported by the National Science Foundation of China(grant No.41476053)the China Geological Project(grants No.GZH201400214 and DD20160153)
文摘Basin-mountain coupling is a key issue for basin formation and evolution. The analysis of basin-mountain coupling process, as well as quantitative or semiquantitative restoration of prototype basin and the evolution of continental margin, can be used to interpret the geological process of basin-range conversion and reconstruct early prototype basins, which is a difficult and leadin~ scientific oroblem of basin research.
基金the support from Clariant International Ltd.the National Natural Science Foundation of China (Nos.22022811,21938008,and U21B2096)the Haihe Laboratory of Sustainable Chemical Transformations。
文摘The dehydrogenation of cyclohexanol to cyclohexanone is a crucial industrial process in the production of caprolactam and adipic acid, both of which serve as important precursors in nylon textiles. This endothermic reaction is constrained by thermodynamic equilibrium and involves a complex reaction network, leading to a heightened focus on catalysts and process design. Copper-based catalysts have been extensively studied and exhibit exceptional low-temperature catalytic performance in cyclohexanol dehydrogenation, with some being commercially used in the industry. This paper specifically concentrates on research advancement concerning active species, reaction mechanisms, factors influencing product selectivity, and the deactivation behaviors of copper-based catalysts. Moreover, a brief introduction to the new processes that break thermodynamic equilibrium via reaction coupling and their corresponding catalysts is summarized here as well. These reviews may off er guidance and potential avenues for further investigations into catalysts and processes for cyclohexanol dehydrogenation.
基金[This work was financially supported by a research grant from the Hong Kong Polytechnic University (No.G-V694).]
文摘The thermal-mechanical coupling finite element method(FEM)was usedto simulate a non-isothermal sheet metal extrusion process. On thebasis of the finite plasticity consistent with multiplicativedecomposition of the deformation gradient, the enhanced as- sumedstrain(EAS)FEM was applied to carry out the numerical simulation. Inorder to make the computation reliable ad avoid hour- glass mode inthe EAS element under large compressive strains, an alterative formof the original enhanced deformation gradient was employed. Inaddition, reduced factors were used in the computation of the elementlocal internal parameters and the enhanced part of elementalstiffness.
基金financed and supported by the German research institute "Gesellschaft für Anlagen-und Reaktorsicherheit (GRS) mbH"
文摘The main objective of this paper is to investigate and analyse the thermo-hydro-mechanical（THM） coupling phenomena and their influences on the repository safety.In this paper,the high-level waste（HLW） disposal concept in drifts in clay formation with backfilled bentonite buffer is represented numerically using the CODE BRIGHT developed by the Technical University of Catalonia in Barcelona.The parameters of clay and bentonite used in the simulation are determined by laboratory and in situ experiments.The calculation results are presented to show the hydro-mechanical（HM） processes during the operation phase and the THM processes in the after-closure phase.According to the simulation results,the most probable critical processes for the disposal project have been represented and analyzed.The work also provides an input for additional development regarding the design,assessment and validation of the HLW disposal concept.
基金supported by the National Natural Science Foundation of China(Grant nos.41941008 and 41876221)the National Key Research and Development Program of China(Grant no.2022YFC2807601).
文摘The West Antarctic Peninsula(WAP)region is one of the most productive marine ecosystems in the Southern Ocean that support the food web for phytoplankton,krill spawning or recruitment and several krill consumers at higher-trophic level like penguins and Antarctic fur seals.Characterized by channels and islands,the complex topography of the WAP generates interconnected circulation patterns,strongly influencing vertical stratification,nutrient availability and distribution of marine organisms.Additionally,rapid climate change associated with major climate modes like the Southern Annular Mode(SAM)and El Niño-Southern Oscillation(ENSO)has significant effects on long-term variations of physical environments and biological production.The objective of this study is to reveal the spatial-temporal variations of phytoplankton biomass in the WAP region and the modulating physical-ecological processes.By using 9-year hydrographic and ecological data of five transects collected by the Palmer Long-Term Ecosystem Research,the horizontal and vertical distributions of several physical and ecological properties,with a particular focus on chlorophyll(Chl)concentration were explored.Regression analysis among area-averaged properties and properties at single stations was performed to reveal the relationship between the interannual variations of physical and ecological processes.The correlation results showed that Chl concentration exhibited a positive relationship with both the circumpolar deep water(CDW)intrusion and vertical stratification,but showed a negative correlation with SAM at some specific stations.However,certain processes or mechanisms may only be dominant for specific stations and not applicable to the entire region.No single physical or ecological factors have been found to significantly influence the Chl distribution throughout the WAP region,which may be attributed to the heterogeneity of sea ice conditions,geometry and hydrodynamic features as well as variations in nutrient sources.
基金supported by the China Geological Survey Projects(Nos.20160272,20211379)the Second Tibetan Plateau Scientific Expedition and Research Program(No.2019QZKK0904)。
文摘The dynamic effect is a very important issue widely debated by scholars when studying the genetic and disaster-causing mechanisms of earthquake-triggered landslides.First,the dynamic effect mechanism and phenomena of earthquake-triggered landslides were summarized in this paper.Then,the primary types of dynamic effects were further used to interpret the Mogangling landslide in Moxi Town of Luding County,China.A field investigation,remote sensing,numerical calculation and theoretical analysis were carried out to illustrate the failure mechanism of slope rock masses affected by earthquakes.The interaction between seismic waves and slope rock masses and the induced dynamic effect of slope rock masses were primarily accounted for in the analysis.The slope topography,rock mass weathering and unloading characteristics,river erosion,regional seismogenic structure,and rock mass structure characteristics were also discussed.The results showed that the formation of the Mogangling landslide was mainly related to the high amplification effect of seismic acceleration and back slope effects,interface dynamic stress effects,and double-sided slope effects of seismic waves caused by the catastrophic Ms 7.75 Moxi Earthquake in 1786.The principles for the site and route selection of large-scale infrastructure in the planning stage and the scientific prevention of seismic geological disasters were proposed on the basis of the dynamic effect of earthquake-induced landslides.
基金Supported by the National Natural Science Foundation of China(51079107,50839004)the Program for New Century Excellent Talents in University(NCET-09-0610)
文摘Seepage flow through soils,rocks and geotechnical structures has a great influence on their stabilities and performances,and seepage control is a critical technological issue in engineering practices.The physical mechanisms associated with various engineering measures for seepage control are investigated from a new perspective within the framework of continuum mechanics;and an equation-based classification of seepage control mechanisms is proposed according to their roles in the mathematical models for seepage flow,including control mechanisms by coupled processes,initial states,boundary conditions and hydraulic properties.The effects of each mechanism on seepage control are illustrated with examples in hydroelectric engineering and radioactive waste disposal,and hence the reasonability of classification is demonstrated.Advice on performance assessment and optimization design of the seepage control systems in geotechnical engineering is provided,and the suggested procedure would serve as a useful guidance for cost-effective control of seepage flow in various engineering practices.
基金Project of Science and Technology Department of Guizhou Province[ZK(2022)016]Special Fund for Outstanding Youth Talents of Science and Technology of Guizhou Province[YQK[2023]014]+1 种基金Special Research Fund of Natural Science(Special Post)of Guizhou University[(2020)01]Key Cultivation Program of Guizhou University[2019(08)].
文摘The widespread organic pollutants in wastewater are one of the global environmental problems.Advanced oxidation processes(AOPs)are widely used because of their characteristics of high efficiency and strong oxidation.However,AOPs may have some defects,such as incomplete mineralization of organic pollutants and the generation of toxic by-products during the degradation process,thus it is essential to seek efficient and green wastewater treatment technologies.Coupling different AOPs or other processes is beneficial for the mineralization of pollutants and reduces ecological risks to the environment.It is worth noting that carbonaceous materials(CMs)have received widespread attention and application in the degradation of organic pollutants in water by advanced oxidation coupling processes(C-AOPs)due to their excellent physicochemical properties in recent years.However,the behaviors and mechanisms of C-AOPs based on CMs on the degradation of organic pollutants are still unknown.Therefore,it is essential to comprehensively summarize the recent research progress.In this review,the applications of different CMs in C-AOPs were reviewed first.Secondly,the synergistic mechanisms of the C-AOPs based on different CMs were discussed.Then,toxic intermediates were explored and important toxicity assessment methods were proposed.Finally,the application potential of the C-AOPs in the future and the challenges were proposed.This review provides an important reference for the application and optimization of the C-AOPs in organic wastewater treatment in the future.
基金supported by the National Natural Science Foundation of China(Grant Nos.12102365,91752202,11472016,11621202,and 12272371).
文摘This work attempts to extend the fundamental theory for classic gas dynamics to viscous compressible flow,of which aeroacoustics will naturally be a special branch.As a continuation of Part I.Unbounded fluid(Mao et al.,2022),this paper studies the source of longitudinal field at solid boundary,caused by the on-wall kinematic and viscous dynamic coupling of longitudinal and transverse processes.We find that at this situation the easiest choice for the two independent thermodynamic variables is the dimensionless pressure P and temperature T.The two-level structure of boundary dynamics of longitudinal field is obtained by applying the continuity equation and its normal derivative to the surface.We show that the boundary dilatation flux represents faithfully the boundary production of vortex sound and entropy sound,and the mutual generation mechanism of the longitudinal and transverse fields on the boundary does not occur symmetrically"at the samc level,but appears along a zigzag route.At the first level,it is the pressure gradient that generates vorticity unidirectionally;while at the second level,it is the vorticity that generates dilatation unidirectionally.
基金supported by the National Natural Science Foundation of China(Grant Nos.12102365,91752202 and 11472016)Luoqin Liu was supported by the Hundred Talents Program of the Chinese Academy of Sciences(CAS).
文摘This paper presents a deep reflection on the advective wave equations for velocity vector and dilatation discovered in the past decade.We show that these equations can form the theoretical basis of modern gas dynamics,because they dominate not only various complex viscous and heat-conducting gas flows but also their associated longitudinal waves,including aero-generated sound.Current aeroacoustics theory has been developing in a manner quite independently of gas dynamics;it is based on the advective wave equations for thermodynamic variables,say the exact Phillips equation of relative disturbance pressure as a representative one.However,these equations do not cover the fluid flow that generates and propagates sound waves.In using them,one has to assume simplified base-flow models,which we argue is the main theoretical obstacle to identifying sound source and achieving effective noise control.Instead,we show that the Phillips equation and alike is nothing but the first integral of the dilatation equation that also governs the longitudinal part of the flow field.Therefore,we conclude that modern aeroacoustics should merge back into the general unsteady gas dynamics as a special branch of it,with dilatation of multiple sources being a new additional and sharper sound variable.
基金Basic Foresight Research Project of Oil and GasDevelopment from Sinopec Ministry of Science and Technology:“Key technologies of drilling and completion and development of coring equipment for natural gas hydrate”(No.P20040-3)Sinopec Shengli Oilfield Post-doctoral Research Project:“Sand Production Dynamic Prediction and Technical Policy Boundaries in Natural Gas Hydrate Reservoir”(No.YKB2107)Youth Science Fund Project of National Natural Science Foundation of China:“Study on Non-Darcy Flow Characteristics of and Its Impact on Productivity in Low PermeabilityMuddy Silt Hydrate Reservoirs in South China Sea”(No.42102302).
文摘In order to produce natural gas hydrate safely and efficiently,it is quite crucial to research the stability of hydrate reservoir in the process of its exploitation.The coupled thermal-hydrodynamic-mechanical(THM)numerical simulation can clearly present the mechanical response laws in the process of hydrate exploitation by horizontal well,but the model is often simplified as a profile vertical to the production well,so the evolution characteristics of real formation deformation space cannot be described sufficiently.To this end,this paper develops a coupled THM simulator applicable to the large-scale hydrate exploitation by horizontal well by introducing interactive interface to the FLAC mechanics program based on the hydrate exploitation program TOUGHþHYDRATE.Then,based on the field data of second hydrate production test in South China Sea,the gas and water production and formation deformation laws under the middle-and long-term development conditions of horizontal wells are studied by taking the actual gas production of horizontal well during the production test as the constraint of coupled THM model.And the following research results are obtained.First,when the production pressure is 7 MPa and the horizontal well length is 300 m,the gas production of horizontal well can reach 1190×10^(4)m^(3),the pressure drop has a larger influence range in the free gas layer,the produced gas mainly comes from the free gas layer and the hydrate layer and the hydrate dissociation range is not large.Second,it is predicted that the seafloor settlement is about 0.16 m after 60 days'production test and 0.52 m after osne year's production.In conclusion,hydrate exploitation by horizontal well can cause a large range of seafloor settlement.The seafloor surface settles linearly and continuously and the spatial settlement distribute is in the shape of ellipse.What's more,the greatest deformation(vertical displacement)occurs at the horizontal well and above it,where formation damage happens the easiest.It is recommended to study seafloor deformation and landslip risk under the conditions of middle and long-term production based on seafloor topography,valley distribution and nonuniform spatial thickness of mineral ores.
基金This research was funded by the National Natural Science Foundation of China （Grant No. 51178224）, Jiangsu Natural Science Foundation （BIC2010443）, and the Priority Academic Program Development （PAPD） of Jiangsu Higher Education Institute. The content of the paper does not necessarily represent the views of the funding agencies.
文摘The removal of 17β-estradiol （E2） in laccase catalyzed oxidative coupling processes was systematically studied in this work. We focused on the influence of pH and natural organic matter （NOM） on the performance of the enzymatic treatment processes. It was found that the optimal pH for E2 removal was between 4 and 6. The removal of E2 was slightly inhibited in the presence of NOM. Enzymatic transformation of E2 was second-order in kinetics with first-order to both the concentrations of the enzyme and contaminant. Mass spectrum （MS） analysis suggested that coupling products were formed through radical-radical coupling mechanism. The results of this study demonstrated that laccase catalyzed oxidative coupling process could potentially serve as a treatment strategy to control steroid estrogens.
基金the National Natural Science Fund for Major Program of China(Grant No.52192621)the National Natural Science Fund for Major Program of China(Grant No.52192624)+1 种基金the National Key Research and Development Program of China(Grant No.2018YFB1501804)Sichuan Science and Technology Program(2021YJ0389).
文摘As a kind of clean renewable energy,the production and utilization of geothermal resources can make a great contribution to optimizing the energy structure and energy conservation and emission reduction.The circulating heat extraction process of working fluid will disturb the equilibrium state of physical and chemical fields inside the reservoir,and involve the mutual coupling of heat transfer,flow,stress,and chemical reaction.Revealing the coupling mechanism of flow and heat transfer inside the reservoir during geothermal exploitation can provide important theoretical support for the efficient exploitation of geothermal resources.This paper reviews the research advances of the multi-field coupling model in the reservoir during geothermal production over the past 40 years.The thrust of this paper is on objective analysis and evaluation of the importance of each coupling process and its influence on reservoir heat extraction performance.Finally,we discuss the existing challenges and perspectives to promote the future development of the geothermal reservoir multi-field coupling model.An accurate understanding of the multi-field coupling mechanism,an efficient cross-scale modeling method,as well as the accurate characterization of reservoir fracture morphology,are crucial for the multi-field coupling model of geothermal production.
