The simultaneous nitrification and denitrification in step-feeding biological nitrogen removal process were investigated under different influent substrate concentrations and aeration flow rates. Biological occurrence...The simultaneous nitrification and denitrification in step-feeding biological nitrogen removal process were investigated under different influent substrate concentrations and aeration flow rates. Biological occurrence of simultaneous nitrification and denitrification was verified in the aspect of nitrogen mass balance and alkalinity. The experimental results also showed that there was a distinct linear relationship between simultaneous nitrification and denitrification and DO concentration under the conditions of low and high aeration flow rate. In each experimental run the floc sizes of activated sludge were also measured and the results showed that simultaneous nitrification and denitrification could occur with very small size of floc.展开更多
The optimal condition for a one-step process removing organic compounds from coking wastewater by simultaneously synthesized organobentonite as a pretreatment was investigated.Results showed that sorption of organic c...The optimal condition for a one-step process removing organic compounds from coking wastewater by simultaneously synthesized organobentonite as a pretreatment was investigated.Results showed that sorption of organic compounds by organobentonite was positively correlated to the cation surfactant exchange on the bentonite and the octanol-water partition coefficient（Kow） of the solutes.With 0.75 g/L bentonite and 180 mg/L（60% of bentonite cation exchange capacity） cetyltrimethylammonium bromide,the removal efficiencies of the 16 polycyclic aromatic hydrocarbon（PAHs） specified by the US Environmental Protection Agency in coking wastewater except naphthalene were more than 90%,and that of benzo（a）pyrene was 99.5%.At the same time,the removal efficiencies of CODCr,NH3-N,volatile phenols,colour and turbidity were 28.6%,13.2%,8.9%,55% and 84.3%,respectively,and the ratio of BOD5/CODCr increased from 0.31 to 0.41.These results indicated that the one-step process had high removal efficiency for toxic and refractory hydrophobic organic compounds,and could improve the biodegradability of the coking wastewater.Therefore it could be a promising technology for the pretreatment of toxic and refractory organic wastewater.展开更多
Evaluation on nitrogen removal of step-feed anoxic/oxic activated sludge process at the standpoint of reaction kinetics and process kinetics was conducted. Theoretical biological nitrogen removal efficiency was deduce...Evaluation on nitrogen removal of step-feed anoxic/oxic activated sludge process at the standpoint of reaction kinetics and process kinetics was conducted. Theoretical biological nitrogen removal efficiency was deduced based on the mass balance of nitrate in the last stage. The comparison of pre-denitrification process and step feed process in the aspects of nitrogen removal efficiency, volume of reactor and building investment was studied, and the results indicated that step-feed anoxic/oxic activated sludge process was superior to pre-denitrification process in these aspects.展开更多
Control of sludge age and mixed liquid suspended solids concentration in the activated sludge process is critical for ensuring effective wastewater treatment. A nonlinear dynamic model for a step-feed activated sludge...Control of sludge age and mixed liquid suspended solids concentration in the activated sludge process is critical for ensuring effective wastewater treatment. A nonlinear dynamic model for a step-feed activated sludge process was developed in this study. The system is based on the control of the sludge age and mixed liquor suspended solids in the aerator of last stage by adjusting the sludge recycle and wastage flow rates respectively. The simulation results showed that the sludge age remained nearly constant at a value of 16 d in the variation of the influent characteristics. The mixed liquor suspended solids in the aerator of last stage were also maintained to a desired value of 2500 g/m3 by adjusting wastage flow rates.展开更多
In this study, a two-step heating process is introduced for transient liquid phase ( TLP) diffusion bonding fo r sound joints with T91 heat resistant steels. At first, a short-time higher temperature heating ...In this study, a two-step heating process is introduced for transient liquid phase ( TLP) diffusion bonding fo r sound joints with T91 heat resistant steels. At first, a short-time higher temperature heating step is addressed to melt the interlayer, followed by the second step to complete isothermal solidification at a low temperature. The most critical feature of our new method is producing a non-planar interface at the T9/ heat resistant steels joint. We propose a transitional liquid phase bonding of T91 heat resistant steels by this approach. Since joint microstructures have been studied, we tested the tensile strength to assess joint mechanical property. The result indicates that the solidified bond may contain a primary solid-solution, similar composition to the parent metal and free from precipitates. Joint tensile strength of the joint is not lower than parent materials. Joint bend's strengths are enhanced due to the higher metal-to-metal junction producing a non-planar bond lines. Nevertheless, the traditional transient liquid phase diffusion bonding produces planar ones. Bonding parameters of new process are 1 260 °C for 0. 5 min and 1 230 °C fo r 4 min.展开更多
The effect of Cu content on the microstructures and mechanical properties (yield strength, ultimate tensile strength, impact energy, fracture toughness) of austempering ductile iron (ADI) treated by two-step austemper...The effect of Cu content on the microstructures and mechanical properties (yield strength, ultimate tensile strength, impact energy, fracture toughness) of austempering ductile iron (ADI) treated by two-step austempering process were investigated. High Cu content in nodular cast irons leads to a significant volume fraction of retained austenite in the iron after austempering treatment, but the carbon content of austenite decreases with the increasing of Cu content. Moreover, austenitic stability reaches its maximum when the Cu content is 1.4% and then drops rapidly with further increase of Cu. The ultimate tensile strength and yield strength of the ADI firstly increases and then decreases with increasing the Cu content. The elongation keeps constant at 6.5% as the Cu content increases from 0.2% to 1.4%, and then increases rapidly to 10.0% with further increase Cu content to 2.0%. Impact toughness is enhanced with Cu increasing at first, and reaches a maximum 122.9 J at 1.4% Cu, then decreases with the further increase of Cu. The fracture toughness of ADI shows a constant increase with the increase of Cu content. The influencing mechanism of Cu on austempered ductile iron (ADI) can be classified into two aspects. On the one hand, Cu dissolves into the matrix and functions as solid solution strengthening. On the other hand, Cu reduces solubility of C in austenite and contributes more stable retained austenite.展开更多
Due to the heavy congestion in HF bands, HF radars are restricted to operating within narrow frequency bands. To improve the system bandwidth and avoid heavy interference bands, a quasi-random step frequency signal wi...Due to the heavy congestion in HF bands, HF radars are restricted to operating within narrow frequency bands. To improve the system bandwidth and avoid heavy interference bands, a quasi-random step frequency signal with discontinuous bands is presented. A novel two-dimensional signal processing scheme for this signal is proposed on the basis of delicate signal analysis. Simulation results demonstrate that the scheme could successfully realize the resolutions by decoupling the range-Doppler ambiguity, and effectively suppress the maximal sidelobe. Moreover, the scheme is simple and has good numerical stability.展开更多
The main types of defect in the (Tb_(0.3)Dy_(0.7))Fe_(1.95) alloys with the 'one-step' directional solidification process were investigated. The effect of the dendrite, grain boundaries, twin boundaries, and R...The main types of defect in the (Tb_(0.3)Dy_(0.7))Fe_(1.95) alloys with the 'one-step' directional solidification process were investigated. The effect of the dendrite, grain boundaries, twin boundaries, and REFe_3 precipitates on the magnetostrictive response of the (Tb_(0.3)Dy_(0.7))Fe_(1.95) alloys was analyzed respectively. The experiment results demonstrate that the dendrite, twin boundaries, and REFe_3 precipitates can be avoided by modifying alloying ingredient, solidification parameters and annealing technique. The dendritic growth front often leads to dendrite sheet, rare earth-rich phase, and twin boundaries. The lower proportion of rare earth, or slow solidification rate, results in the occurrence of REFe_3 precipitatates. It is vital for diminishing the defects to control the undercooling of solid-liquid interface at (2.4～5.1)×10~4 K·s·cm^(-2) so that the crystal grows in cellular growth front.展开更多
The two-step catalyzing process for biodiesel production from waste vegetable oil was assisted by both co-solvent and microwave irradiation. Central composite design (CCD) was employed to optimize the reaction conditi...The two-step catalyzing process for biodiesel production from waste vegetable oil was assisted by both co-solvent and microwave irradiation. Central composite design (CCD) was employed to optimize the reaction conditions. Optimal reaction conditions of the first step were alcohol to oil molar ratio of 9:1, catalyst (H2SO4) amount 1 wt%, reaction temperature 333 K, and reaction time 7.5 minutes;while for the second step, optimal reaction conditions were alcohol to oil molar ratio 12:1, catalyst (NaOH) amount 1 wt%, reaction temperature 333 K, and reaction time 2.0 minutes. The total reaction time was 9.5 min and the conversion rate of fatty acid methyl esters (FAMEs) achieved was 97.4%. The total reaction time was shorter than previous studies. Therefore, the co-solvent and microwave assisted two-step catalyzing process has a potential application in producing biodiesel from waste vegetable oil.展开更多
The non-equilibrium grain-boundary segregation of phosphorus in step cooling process in an industrial steel, 12CrlMoV, is studied based on the effective-time-method and compared with that in isothermal holding process...The non-equilibrium grain-boundary segregation of phosphorus in step cooling process in an industrial steel, 12CrlMoV, is studied based on the effective-time-method and compared with that in isothermal holding process. The non-equilibrium grain-boundary segregation concentration of phosphorus was measured with Auger Electron Spectroscopy (AES) and calculated based on the kinetic equations of non-equilibrium grain-boundary segregation. Results show that the calculated result is in good accordance with the experimental observation.展开更多
Flexible rolling is a forming process based on thickness reduction, and the precision of thickness reduction is the key factor affecting bending deformation. The major purpose of the present work is to solve the probl...Flexible rolling is a forming process based on thickness reduction, and the precision of thickness reduction is the key factor affecting bending deformation. The major purpose of the present work is to solve the problem of bending deformation error caused by insufficient thickness reduction. Under the condition of different rolling reductions with the same sheet thickness and the same thickness reduction with different sheet thicknesses, the thickness reduction error of sheet metal is analyzed. In addition, the bending deformation of sheet metal under the same conditions is discussed and the influence of the multi-step forming process on the thickness reduction error is studied. The results show that, under the condition of the same sheet thickness, the thickness reduction error increases with increasing rolling reduction because of an increase in work hardening. As rolling reduction increases, the longitudinal bending deformation decreases because of the decrease of the maximum thickness difference. Under the condition with the same thickness reduction, the thickness reduction error increases because of the decrease of the rolling force with increasing sheet thickness. As the sheet thickness increases, the longitudinal bending deformation increases because of the increase in the maximum thickness difference. A larger bending deformation is divided into a number of small bending deformations in a multi-step forming process, avoiding a sharp increase in the degree of work hardening; the thickness reduction error is effectively reduced in the multi-step forming process. Numerical simulation results agree with the results of the forming experiments.展开更多
2195 aluminum-lithium alloy was widely applied in the aviation and aerospace industry, but it is highly susceptible to pitting and intergranular corrosion undergoing sever corrosive circumstance and moisture atmospher...2195 aluminum-lithium alloy was widely applied in the aviation and aerospace industry, but it is highly susceptible to pitting and intergranular corrosion undergoing sever corrosive circumstance and moisture atmosphere. To solve this problem and consequently to prolong its service life, a multi-step-heating-rate(MSRC) process was carried out. Investigations were carried out to find the effect of the MSRC process on the alloys corrosion resistance. It is found that the MSRC process is more favorable for the uniform phase precipitation by comparing the corrosion resistance of samples treated by traditional heat treatments. The potential difference between phases can be reduced and intergranular corrosion is able to be prohibited efficiently. Besides, the rare earth infiltration is beneficial to improving the corrosion resistance. As heating time increases, the corrosion resistance declines gradually, samples treated by artificial aging and solid solution also exhibit a better corrosion resistance.展开更多
基金Project supported by the Key International Cooperative Program of NSFC(No. 50521140075)the Hi-Tech Research and Development Program(863)of China(No. 2004AA601020)the Attached Projects of"863"Project of Beijing Municipal Science and Technology(No.20005186040421).
文摘The simultaneous nitrification and denitrification in step-feeding biological nitrogen removal process were investigated under different influent substrate concentrations and aeration flow rates. Biological occurrence of simultaneous nitrification and denitrification was verified in the aspect of nitrogen mass balance and alkalinity. The experimental results also showed that there was a distinct linear relationship between simultaneous nitrification and denitrification and DO concentration under the conditions of low and high aeration flow rate. In each experimental run the floc sizes of activated sludge were also measured and the results showed that simultaneous nitrification and denitrification could occur with very small size of floc.
基金supported by the National Natural Science Foundation of China (No. 20890111)
文摘The optimal condition for a one-step process removing organic compounds from coking wastewater by simultaneously synthesized organobentonite as a pretreatment was investigated.Results showed that sorption of organic compounds by organobentonite was positively correlated to the cation surfactant exchange on the bentonite and the octanol-water partition coefficient（Kow） of the solutes.With 0.75 g/L bentonite and 180 mg/L（60% of bentonite cation exchange capacity） cetyltrimethylammonium bromide,the removal efficiencies of the 16 polycyclic aromatic hydrocarbon（PAHs） specified by the US Environmental Protection Agency in coking wastewater except naphthalene were more than 90%,and that of benzo（a）pyrene was 99.5%.At the same time,the removal efficiencies of CODCr,NH3-N,volatile phenols,colour and turbidity were 28.6%,13.2%,8.9%,55% and 84.3%,respectively,and the ratio of BOD5/CODCr increased from 0.31 to 0.41.These results indicated that the one-step process had high removal efficiency for toxic and refractory hydrophobic organic compounds,and could improve the biodegradability of the coking wastewater.Therefore it could be a promising technology for the pretreatment of toxic and refractory organic wastewater.
文摘Evaluation on nitrogen removal of step-feed anoxic/oxic activated sludge process at the standpoint of reaction kinetics and process kinetics was conducted. Theoretical biological nitrogen removal efficiency was deduced based on the mass balance of nitrate in the last stage. The comparison of pre-denitrification process and step feed process in the aspects of nitrogen removal efficiency, volume of reactor and building investment was studied, and the results indicated that step-feed anoxic/oxic activated sludge process was superior to pre-denitrification process in these aspects.
基金The National Hi Tech Development Program (863) of China(No.2003AA601110) and the National Natural Science Foundation Key Item of China(No.50138010)
文摘Control of sludge age and mixed liquid suspended solids concentration in the activated sludge process is critical for ensuring effective wastewater treatment. A nonlinear dynamic model for a step-feed activated sludge process was developed in this study. The system is based on the control of the sludge age and mixed liquor suspended solids in the aerator of last stage by adjusting the sludge recycle and wastage flow rates respectively. The simulation results showed that the sludge age remained nearly constant at a value of 16 d in the variation of the influent characteristics. The mixed liquor suspended solids in the aerator of last stage were also maintained to a desired value of 2500 g/m3 by adjusting wastage flow rates.
基金supported by the Natural Science Foundation of Henan Province(Grant No.152107000047)
文摘In this study, a two-step heating process is introduced for transient liquid phase ( TLP) diffusion bonding fo r sound joints with T91 heat resistant steels. At first, a short-time higher temperature heating step is addressed to melt the interlayer, followed by the second step to complete isothermal solidification at a low temperature. The most critical feature of our new method is producing a non-planar interface at the T9/ heat resistant steels joint. We propose a transitional liquid phase bonding of T91 heat resistant steels by this approach. Since joint microstructures have been studied, we tested the tensile strength to assess joint mechanical property. The result indicates that the solidified bond may contain a primary solid-solution, similar composition to the parent metal and free from precipitates. Joint tensile strength of the joint is not lower than parent materials. Joint bend's strengths are enhanced due to the higher metal-to-metal junction producing a non-planar bond lines. Nevertheless, the traditional transient liquid phase diffusion bonding produces planar ones. Bonding parameters of new process are 1 260 °C for 0. 5 min and 1 230 °C fo r 4 min.
基金financially supported by the National Natural Science Foundation of China(Grant Nos.51374086 and 51674094)
文摘The effect of Cu content on the microstructures and mechanical properties (yield strength, ultimate tensile strength, impact energy, fracture toughness) of austempering ductile iron (ADI) treated by two-step austempering process were investigated. High Cu content in nodular cast irons leads to a significant volume fraction of retained austenite in the iron after austempering treatment, but the carbon content of austenite decreases with the increasing of Cu content. Moreover, austenitic stability reaches its maximum when the Cu content is 1.4% and then drops rapidly with further increase of Cu. The ultimate tensile strength and yield strength of the ADI firstly increases and then decreases with increasing the Cu content. The elongation keeps constant at 6.5% as the Cu content increases from 0.2% to 1.4%, and then increases rapidly to 10.0% with further increase Cu content to 2.0%. Impact toughness is enhanced with Cu increasing at first, and reaches a maximum 122.9 J at 1.4% Cu, then decreases with the further increase of Cu. The fracture toughness of ADI shows a constant increase with the increase of Cu content. The influencing mechanism of Cu on austempered ductile iron (ADI) can be classified into two aspects. On the one hand, Cu dissolves into the matrix and functions as solid solution strengthening. On the other hand, Cu reduces solubility of C in austenite and contributes more stable retained austenite.
文摘Due to the heavy congestion in HF bands, HF radars are restricted to operating within narrow frequency bands. To improve the system bandwidth and avoid heavy interference bands, a quasi-random step frequency signal with discontinuous bands is presented. A novel two-dimensional signal processing scheme for this signal is proposed on the basis of delicate signal analysis. Simulation results demonstrate that the scheme could successfully realize the resolutions by decoupling the range-Doppler ambiguity, and effectively suppress the maximal sidelobe. Moreover, the scheme is simple and has good numerical stability.
文摘The main types of defect in the (Tb_(0.3)Dy_(0.7))Fe_(1.95) alloys with the 'one-step' directional solidification process were investigated. The effect of the dendrite, grain boundaries, twin boundaries, and REFe_3 precipitates on the magnetostrictive response of the (Tb_(0.3)Dy_(0.7))Fe_(1.95) alloys was analyzed respectively. The experiment results demonstrate that the dendrite, twin boundaries, and REFe_3 precipitates can be avoided by modifying alloying ingredient, solidification parameters and annealing technique. The dendritic growth front often leads to dendrite sheet, rare earth-rich phase, and twin boundaries. The lower proportion of rare earth, or slow solidification rate, results in the occurrence of REFe_3 precipitatates. It is vital for diminishing the defects to control the undercooling of solid-liquid interface at (2.4～5.1)×10~4 K·s·cm^(-2) so that the crystal grows in cellular growth front.
文摘The two-step catalyzing process for biodiesel production from waste vegetable oil was assisted by both co-solvent and microwave irradiation. Central composite design (CCD) was employed to optimize the reaction conditions. Optimal reaction conditions of the first step were alcohol to oil molar ratio of 9:1, catalyst (H2SO4) amount 1 wt%, reaction temperature 333 K, and reaction time 7.5 minutes;while for the second step, optimal reaction conditions were alcohol to oil molar ratio 12:1, catalyst (NaOH) amount 1 wt%, reaction temperature 333 K, and reaction time 2.0 minutes. The total reaction time was 9.5 min and the conversion rate of fatty acid methyl esters (FAMEs) achieved was 97.4%. The total reaction time was shorter than previous studies. Therefore, the co-solvent and microwave assisted two-step catalyzing process has a potential application in producing biodiesel from waste vegetable oil.
基金supported by National Natural Science Foundation of China(No.59971042 and No.5033 1020)Basic Research Project of National Defense Science Technology and Industry Commission(No.Jl600E001).
文摘The non-equilibrium grain-boundary segregation of phosphorus in step cooling process in an industrial steel, 12CrlMoV, is studied based on the effective-time-method and compared with that in isothermal holding process. The non-equilibrium grain-boundary segregation concentration of phosphorus was measured with Auger Electron Spectroscopy (AES) and calculated based on the kinetic equations of non-equilibrium grain-boundary segregation. Results show that the calculated result is in good accordance with the experimental observation.
基金financially supported by the National Natural Science Foundation of China(No.51275202)
文摘Flexible rolling is a forming process based on thickness reduction, and the precision of thickness reduction is the key factor affecting bending deformation. The major purpose of the present work is to solve the problem of bending deformation error caused by insufficient thickness reduction. Under the condition of different rolling reductions with the same sheet thickness and the same thickness reduction with different sheet thicknesses, the thickness reduction error of sheet metal is analyzed. In addition, the bending deformation of sheet metal under the same conditions is discussed and the influence of the multi-step forming process on the thickness reduction error is studied. The results show that, under the condition of the same sheet thickness, the thickness reduction error increases with increasing rolling reduction because of an increase in work hardening. As rolling reduction increases, the longitudinal bending deformation decreases because of the decrease of the maximum thickness difference. Under the condition with the same thickness reduction, the thickness reduction error increases because of the decrease of the rolling force with increasing sheet thickness. As the sheet thickness increases, the longitudinal bending deformation increases because of the increase in the maximum thickness difference. A larger bending deformation is divided into a number of small bending deformations in a multi-step forming process, avoiding a sharp increase in the degree of work hardening; the thickness reduction error is effectively reduced in the multi-step forming process. Numerical simulation results agree with the results of the forming experiments.
基金Project(51471050105HK0101) supported by the National Key Laboratory of Precision Thermal Treatment, Harbin Institute of Technology,China
文摘2195 aluminum-lithium alloy was widely applied in the aviation and aerospace industry, but it is highly susceptible to pitting and intergranular corrosion undergoing sever corrosive circumstance and moisture atmosphere. To solve this problem and consequently to prolong its service life, a multi-step-heating-rate(MSRC) process was carried out. Investigations were carried out to find the effect of the MSRC process on the alloys corrosion resistance. It is found that the MSRC process is more favorable for the uniform phase precipitation by comparing the corrosion resistance of samples treated by traditional heat treatments. The potential difference between phases can be reduced and intergranular corrosion is able to be prohibited efficiently. Besides, the rare earth infiltration is beneficial to improving the corrosion resistance. As heating time increases, the corrosion resistance declines gradually, samples treated by artificial aging and solid solution also exhibit a better corrosion resistance.
