Portland cement is the most common type of cement in general use around the world as a basic ingredient of concrete, mortar, stucco, and non-speciality grout. Dicalcium silicate （Ca2SiO4） is the primary constituent ...Portland cement is the most common type of cement in general use around the world as a basic ingredient of concrete, mortar, stucco, and non-speciality grout. Dicalcium silicate （Ca2SiO4） is the primary constituent of a number of different types of cement. The β-Ca2SiO4 phase is metastable at room temperature and will transform into β-Ca2SiO4 at 663K. In this work, Portland cement is annealed at a temperature of 950K under pressures in the range of 0-5.5 CPa. The high pressure experiments are carried out in an apparatus with six anvil tops. The effect of high pressure on the obtaining nano-size β-Ca2SiO4 （C2S） process is investigated by x-ray diffraction and transmission electron microscopy. Experimental results show that the grain size of the C2S decreases with the increase of pressure. The volume fraction of the C2S phase increases with the pressure as the pressure is below 3 CPa, and then decreases （P 〉 3 GPa）. The nano-effect is very important to the stabilization of β-Ca2SiO4. The mechanism for the effects of the high pressure on the annealing process of the Portland cement is also discussed.展开更多
The influence of the pressure transmission medium（PTM）on the excitonic interband transitions in monolayer tungsten diselenide（WSe2）is investigated using photoluminescence（PL）spectra under hydrostatic pressure up...The influence of the pressure transmission medium（PTM）on the excitonic interband transitions in monolayer tungsten diselenide（WSe2）is investigated using photoluminescence（PL）spectra under hydrostatic pressure up to 5GPa.Three kinds of PTMs,condensed argon（Ar）,1：1 n-pentane and isopentane mixture（PM）,and4：1 methanol and ethanol mixture（MEM,a PTM with polarity）,are used.It is found that when either Ar or PM is used as the PTM,the PL peak of exciton related to the direct K-K interband transition shows a pressure-induced blue-shift at a rate of 32±4 or 32±1 meV/GPa,while it turns to be 50±9meV/GPa when MEM is used as the PTM.The indirect A-K interband transition presents almost no shift with increasing pressure up to approximatel.y 5 GPa when Ar and PM are used as the PTM,while it shows a red-shift at the rate of-17±7meV/GPa by using MEM as the PTM.These results reveal that the optical interband transitions of monolayer WSe2 are very sensitive to the polarity of the PTM.The anomalous pressure coefficient obtained using the polar PTM of MEM is ascribed to the existence of hydrogen-like bonds between hydroxyl in MEM and Se atoms under hydrostatic pressure.展开更多
In this study, a flume experiment was designed to investigate the characteristics of wave-induced pore water pressure in the soil of a silty seabed with different clay contents, soil layer buried depths and wave heigh...In this study, a flume experiment was designed to investigate the characteristics of wave-induced pore water pressure in the soil of a silty seabed with different clay contents, soil layer buried depths and wave heights respectively. The study showed that water waves propagating over silty seabed can induce significant change of pore water pressure, and the amplitude of pore pressure depends on depth of buried soil layer, clay content and wave height, which are considered as the three influencing factors for pore water pressure change. The pressure will attenuate according to exponential law with increase of soil layer buried depth, and the attenuation being more rapid in those soil layers with higher clay content and greater wave height. The pore pressure in silty seabed increases rapidly in the initial stage of wave action, then decreases gradually to a stable value, depending on the depth of buried soil layer, clay content and wave height. The peak value of pore pressure will increase if clay content or depth of buried soil layer decreases, or wave height increases. The analysis indicated that these soils with 5% clay content and waves with higher wave height produce instability in bed easier, and that the wave energy is mostly dissipated near the surface of soils and 5% clay content in soils can prevent pore pressure from dissipating immediately.展开更多
A line contact model of elastic coated solids is presented based on the influence coefficients(ICs) of surface displacement and stresses of coating-substrate system and the traditional contact model. The ICs of displa...A line contact model of elastic coated solids is presented based on the influence coefficients(ICs) of surface displacement and stresses of coating-substrate system and the traditional contact model. The ICs of displacement and stresses are obtained from their corresponding frequency response functions(FRF) by using a conversion method based on fast Fourier transformation(FFT). The contact pressure and the stress field in the subsurface are obtained by employing conjugate gradient method(CGM) and discrete convolution fast Fourier transformation(DC-FFT). Comparison of the contact pressure and subsurface stresses obtained by the numerical method with the exact analytical solutions for Hertz contact is conducted, and the results show that the numerical solution has a very high accuracy and verify the validity of the contact model. The effect of the stiffness and thickness of coatings is further numerically studied. The result shows that the effects on contact pressure and contact width are opposite for hard and soft coatings and are intensified with the increase of coating thickness; the locations of crack initiation and propagation are different for soft and hard coatings; the risk of cracks and delaminations of coatings can be brought down by improving the lubrication condition or optimizing the non-dimensional parameter h/bh. This research offers a tool to numerically analyze the problem of elastic coated solids in line contact and make the blindness and randomness of trial-type coating design less.展开更多
An experimental investigation was conducted to study the cavitation inception of six isolated irregularities for negative and positive pressure gradients.The relationship between the root-mean-square of pressure fluct...An experimental investigation was conducted to study the cavitation inception of six isolated irregularities for negative and positive pressure gradients.The relationship between the root-mean-square of pressure fluctuation and the oscillating radius of gas bubble was determined in this paper.The results of the experiment show that the incipi- ent cavitation numbers for the same protrusions are higher and the intensities of pressure fluctuation are lower in negative gradient flows than that in positive pressure gradient flows.The peaks of pressure fluctuation are seven to twelve times that of the root-mean-square values of pressure fluctuation.展开更多
Determining the saturated vapor pressure(SVP)of LNG requires detailed thermodynamic calculations based on compositional data.Yet LNG compositions and SVPs evolve constantly for LNG stored in tanks.Moreover,the SVP of ...Determining the saturated vapor pressure(SVP)of LNG requires detailed thermodynamic calculations based on compositional data.Yet LNG compositions and SVPs evolve constantly for LNG stored in tanks.Moreover,the SVP of the LNG in a tank influences boil-off rates and tank pressure trends.In order to make improved tank pressure control decisions it would be beneficial for LNG tank operators to be made more constantly aware of the SVP of the LNG in a tank.Machine learning models that accurately estimate LNG SVP from density and temperature inputs offer the potential to provide such information.A dataset of five distinct,internationally traded LNG cargoes is compiled with 305 data records representing a range of temperature and density conditions.This can be used graphically to interpolate LNG SVP.However,two machine learning methods are applied to this dataset to automate the SVP predictions.A simple multi-layer perceptron artificial neural network(MLP-ANN)predicts SVP of the dataset with root mean square error(RMSE)=6.34 kPaA and R^(2)=0.975.The transparent open-box learning network(TOB),a regression-free optimized data matching algorithm predicts SVP of the dataset with RMSE=0.59 kPaA and R^(2)=0.999.When applied to infill unknown LNG compositions the superior TOB method achieves prediction accuracy of RMSE~3kPaA and R^(2)=0.996.Predicting LNG SVP to this level of accuracy is beneficial for tank-pressure management decision making.展开更多
基金Supported by the National Natural Science Foundation of China under Grant No 11674274
文摘Portland cement is the most common type of cement in general use around the world as a basic ingredient of concrete, mortar, stucco, and non-speciality grout. Dicalcium silicate （Ca2SiO4） is the primary constituent of a number of different types of cement. The β-Ca2SiO4 phase is metastable at room temperature and will transform into β-Ca2SiO4 at 663K. In this work, Portland cement is annealed at a temperature of 950K under pressures in the range of 0-5.5 CPa. The high pressure experiments are carried out in an apparatus with six anvil tops. The effect of high pressure on the obtaining nano-size β-Ca2SiO4 （C2S） process is investigated by x-ray diffraction and transmission electron microscopy. Experimental results show that the grain size of the C2S decreases with the increase of pressure. The volume fraction of the C2S phase increases with the pressure as the pressure is below 3 CPa, and then decreases （P 〉 3 GPa）. The nano-effect is very important to the stabilization of β-Ca2SiO4. The mechanism for the effects of the high pressure on the annealing process of the Portland cement is also discussed.
基金Supported by the National Key Research and Development Program of China under Grant No 2016YFA0301202the National Natural Science Foundation of China under Grant Nos 11474275,61674135 and 91536101+1 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences under Grant No XDPB0603the China Postdoctoral Science Foundation under Grant No 2017M622400
文摘The influence of the pressure transmission medium（PTM）on the excitonic interband transitions in monolayer tungsten diselenide（WSe2）is investigated using photoluminescence（PL）spectra under hydrostatic pressure up to 5GPa.Three kinds of PTMs,condensed argon（Ar）,1：1 n-pentane and isopentane mixture（PM）,and4：1 methanol and ethanol mixture（MEM,a PTM with polarity）,are used.It is found that when either Ar or PM is used as the PTM,the PL peak of exciton related to the direct K-K interband transition shows a pressure-induced blue-shift at a rate of 32±4 or 32±1 meV/GPa,while it turns to be 50±9meV/GPa when MEM is used as the PTM.The indirect A-K interband transition presents almost no shift with increasing pressure up to approximatel.y 5 GPa when Ar and PM are used as the PTM,while it shows a red-shift at the rate of-17±7meV/GPa by using MEM as the PTM.These results reveal that the optical interband transitions of monolayer WSe2 are very sensitive to the polarity of the PTM.The anomalous pressure coefficient obtained using the polar PTM of MEM is ascribed to the existence of hydrogen-like bonds between hydroxyl in MEM and Se atoms under hydrostatic pressure.
基金financially supported by the National Fundamental Research Program of Ministry of Science & Technology,China (Grant No. 2010CB951202)
文摘In this study, a flume experiment was designed to investigate the characteristics of wave-induced pore water pressure in the soil of a silty seabed with different clay contents, soil layer buried depths and wave heights respectively. The study showed that water waves propagating over silty seabed can induce significant change of pore water pressure, and the amplitude of pore pressure depends on depth of buried soil layer, clay content and wave height, which are considered as the three influencing factors for pore water pressure change. The pressure will attenuate according to exponential law with increase of soil layer buried depth, and the attenuation being more rapid in those soil layers with higher clay content and greater wave height. The pore pressure in silty seabed increases rapidly in the initial stage of wave action, then decreases gradually to a stable value, depending on the depth of buried soil layer, clay content and wave height. The peak value of pore pressure will increase if clay content or depth of buried soil layer decreases, or wave height increases. The analysis indicated that these soils with 5% clay content and waves with higher wave height produce instability in bed easier, and that the wave energy is mostly dissipated near the surface of soils and 5% clay content in soils can prevent pore pressure from dissipating immediately.
基金Project(2013CB632305)supported by the National Basic Research Program of ChinaProject(51375108)supported by the National Natural Science Foundation of China
文摘A line contact model of elastic coated solids is presented based on the influence coefficients(ICs) of surface displacement and stresses of coating-substrate system and the traditional contact model. The ICs of displacement and stresses are obtained from their corresponding frequency response functions(FRF) by using a conversion method based on fast Fourier transformation(FFT). The contact pressure and the stress field in the subsurface are obtained by employing conjugate gradient method(CGM) and discrete convolution fast Fourier transformation(DC-FFT). Comparison of the contact pressure and subsurface stresses obtained by the numerical method with the exact analytical solutions for Hertz contact is conducted, and the results show that the numerical solution has a very high accuracy and verify the validity of the contact model. The effect of the stiffness and thickness of coatings is further numerically studied. The result shows that the effects on contact pressure and contact width are opposite for hard and soft coatings and are intensified with the increase of coating thickness; the locations of crack initiation and propagation are different for soft and hard coatings; the risk of cracks and delaminations of coatings can be brought down by improving the lubrication condition or optimizing the non-dimensional parameter h/bh. This research offers a tool to numerically analyze the problem of elastic coated solids in line contact and make the blindness and randomness of trial-type coating design less.
文摘An experimental investigation was conducted to study the cavitation inception of six isolated irregularities for negative and positive pressure gradients.The relationship between the root-mean-square of pressure fluctuation and the oscillating radius of gas bubble was determined in this paper.The results of the experiment show that the incipi- ent cavitation numbers for the same protrusions are higher and the intensities of pressure fluctuation are lower in negative gradient flows than that in positive pressure gradient flows.The peaks of pressure fluctuation are seven to twelve times that of the root-mean-square values of pressure fluctuation.
文摘Determining the saturated vapor pressure(SVP)of LNG requires detailed thermodynamic calculations based on compositional data.Yet LNG compositions and SVPs evolve constantly for LNG stored in tanks.Moreover,the SVP of the LNG in a tank influences boil-off rates and tank pressure trends.In order to make improved tank pressure control decisions it would be beneficial for LNG tank operators to be made more constantly aware of the SVP of the LNG in a tank.Machine learning models that accurately estimate LNG SVP from density and temperature inputs offer the potential to provide such information.A dataset of five distinct,internationally traded LNG cargoes is compiled with 305 data records representing a range of temperature and density conditions.This can be used graphically to interpolate LNG SVP.However,two machine learning methods are applied to this dataset to automate the SVP predictions.A simple multi-layer perceptron artificial neural network(MLP-ANN)predicts SVP of the dataset with root mean square error(RMSE)=6.34 kPaA and R^(2)=0.975.The transparent open-box learning network(TOB),a regression-free optimized data matching algorithm predicts SVP of the dataset with RMSE=0.59 kPaA and R^(2)=0.999.When applied to infill unknown LNG compositions the superior TOB method achieves prediction accuracy of RMSE~3kPaA and R^(2)=0.996.Predicting LNG SVP to this level of accuracy is beneficial for tank-pressure management decision making.
