Conventional rolled Mg-Al alloy sheets typically exhibit strong basal textures that remain and may even strengthen after recrystallization annealing due to the preferential growth of basal-oriented grains,resulting in...Conventional rolled Mg-Al alloy sheets typically exhibit strong basal textures that remain and may even strengthen after recrystallization annealing due to the preferential growth of basal-oriented grains,resulting in poor formability at room temperature.Therefore,the knowledge of recrystallization and grain growth is critical for modifying textures of Mg-Al alloy sheets.The static recrystallization and texture evolution in a cold-rolled dilute Mg-1Al(wt.%)alloy during various annealed temperatures ranging from 300℃ to 450℃,have been investigated using the quasi in-situ electron backscatter diffraction(EBSD)method.The as-rolled Mg-1Al alloy shows a dominant basal texture,which weakens and broadens in the rolling direction(RD)during the subsequent annealing,accompanied by the formation of{1010}texture component.Particularly,the {1010} texture component is more pronounced after annealing at high temperatures.The quasi in-situ EBSD results show that recrystallized grains are mainly induced by shear bands,which exhibit a wide spectrum of orientations with c-axis tilt angles ranging 20°-45°from the normal direction(ND).Orientations of shear band-induced recrystallized grains are retained during the entire recrystallization process,resulting in a reduction in the texture intensity.Moreover,recrystallized grains belonging to the {1010}texture component grow preferentially compared to those with other orientations,which is attributed to low energy grain boundaries,especially grain boundaries with∼30°misorientation angles.Furthermore,the high temperature annealing facilitates the rapid growth of grain boundaries having a 30°misorientation angle,leading to the occurrence of distinct {1010} texture after annealing at 450℃ for 1 h.The results provide insights for texture modification of rare earth-free low-alloyed Mg alloys by controlling annealing parameters.展开更多
Preferential oxidation of CO(CO-PROX)in H_(2)-rich streams is highly important for purifying the industrial grade H_(2)used in proton-exchange-membrane fuel cells(PEMFC),but it is still limited to a relatively narrow ...Preferential oxidation of CO(CO-PROX)in H_(2)-rich streams is highly important for purifying the industrial grade H_(2)used in proton-exchange-membrane fuel cells(PEMFC),but it is still limited to a relatively narrow operation temperature window.In this study,the trace amounts of Cu are used to modify a Pt/Al_(2)O_(3)catalyst.The introduced Cu_(2+)species are atomically anchored on Pt nanoparticles through strong electrostatic adsorption.展开更多
Aqueous zinc-ion batteries have emerged as promising candidates in next-generation energy storage sys-tems.However,their practical implementation is significantly hindered by interfacial side reactions,par-ticularly t...Aqueous zinc-ion batteries have emerged as promising candidates in next-generation energy storage sys-tems.However,their practical implementation is significantly hindered by interfacial side reactions,par-ticularly the hydrogen evolution reaction(HER)at the Zn metal anode interface.Herein,this study presents an innovative approach to address this challenge through the construction of an interfacial pref-erential coordination layer on the Zn anode surface.The proposed layer effectively terminates the conti-nuity of interfacial hydrogen-bond networks and blocks proton transport,thereby mitigating the HER.Specifically,2-phenylbenzimidazole-5-sulfonic acid(PBSA)with zincophilic groups was introduced as an electrolyte additive,which would be preferentially and selectively anchored on the Zn surface through its zincophilic nitrogen and sulfonic acid,forming the interfacial coordination layer.This coordination layer serves as a protective barrier,repelling water molecules from the Zn electrode surface and alleviat-ing water decomposition.Crucially,the interfacial coordination layer features stronger hydrogen-bonding interactions with interfacial water molecules,terminates the hydrogen-bonding network between water molecules,hinders the transportation and electro-reduction of proton,and ultimately inhibits HER at the interface.As a result,the Zn symmetric cell with PBSA/ZnSO_(4)delivered higher cycling stability of 2500 h at 1 mA cm^(-2)and Zn/NH_(4)V_(4)O_(10)full cells with PBSA/ZnSO_(4)possessed enhanced capac-ity retention.This interfacial hydrogen-bond regulation strategy provided valuable insight for designing HER-free interfacial protective layer in high-performance aqueous batteries.展开更多
A thorough understanding of the source and infiltration mechanism of soil water is of great significance to the stable supply of regional water resources and the protection of ecological environment.To solve this cruc...A thorough understanding of the source and infiltration mechanism of soil water is of great significance to the stable supply of regional water resources and the protection of ecological environment.To solve this crucial scientific problem,a total of 1980 samples of various water bodies in Qilian Mountains were collected in early,heavy and end ablation period in 2012-2019 to determine the source of soil water with endmember mixing analysis.Double isotope mass balance was used to calculate the relative contribution of piston flow and preferred flow to groundwater.The results of the study show that precipitation dominated the soil water in the study region,and it contributes 78%,89%and 91%of soil water in early,heavy and end ablation periods,respectively.Ground ice meltwater is also an important source of soil water,its contribution was 16%,11%and 7%in early,heavy and end ablation period,respectively.Snowmelt contributed to soil water only during the early(6%)and late(2%)ablation periods.Groundwater is replenished through the combined effects of preferential flow and piston flow.According to double isotope mass balance,the contribution of priority flow to shallow groundwater is 34%,45%and 34%,respectively in early,heavy and end ablation periods.This study identified the sources of soil water and water transport mechanisms in the Qilian Mountains,providing scientific and technological support for water resource conservation and sustainable utilization in cold regions.展开更多
Li plating behavior of the Li metal anode and its compatibility with electrolytes play a decisive role in the electrochemical performance of the Li metal batteries(LMBs),while the intrinsic highly reactive Li would in...Li plating behavior of the Li metal anode and its compatibility with electrolytes play a decisive role in the electrochemical performance of the Li metal batteries(LMBs),while the intrinsic highly reactive Li would induce serious results especially under deep Li plating/stripping depth and with lean electrolytes.Herein,we propose an innovative strategy to simultaneously regulate the bulk construction and the preferential orientation of Li deposition by introducing Li22Sn5/Li-Mg alloys to realize ultra-stable thin Li anodes with long lifespan.The alloys can form a continuous framework with high lithiophilicity and fast ion-diffusion to enable homogenous Li flux,and meanwhile tune the preferential orientation of Li from the conventional(110)plane to(200)to lower the Li reactivity with electrolytes and optimize Li deposition.Therefore,the thin Li-Sn-Mg alloy anode showcases ultra-stable cycling without volume changes and dendrites under a deep Li plating/stripping depth of 89.1%(5 mAh cm^(-2))for over 1200 h in commercial carbonate electrolytes.Moreover,a multilayered NCM811pouch cell with a high energy density of403.6 Wh kg^(-1)is achieved under the harsh conditions of low N/P ratio(0.769)and lean electrolytes(~2.1 g Ah^(-1)).Synchronously,the thin alloy anode shows improved air stability which benefits the manufacturing process and performance of LMBs,displaying the great application potential of these alloy anodes.展开更多
In lead-cooled fast reactor(LFR)systems,the liquid lead-bismuth eutectic(LBE)coolant provides a cor-rosive environment that damages the steel components during high-temperature operation.This study investigated the mi...In lead-cooled fast reactor(LFR)systems,the liquid lead-bismuth eutectic(LBE)coolant provides a cor-rosive environment that damages the steel components during high-temperature operation.This study investigated the microstructural deterioration of 9Cr ferritic/martensitic(F/M)steel under thermal aging at 550℃for 2,000,10,000,or 20,000 h and its effect on oxidation corrosion in an LBE environment using multiscale characterization techniques.The results indicated that the thickness of the internal oxidation zone(IOZ)increased significantly with extended thermal aging,whereas that of the spinel layer remained relatively constant.The abundant subgrain boundaries that emerged during extensive thermal aging facil-itated Fe diffusion,and the enlarged Cr-rich M23C6 carbides contributed to the formation of preferential oxidation regions,accelerating IOZ layer growth.The spinel layer formed from the IOZ was influenced by microstructural defects within the IOZ.A theoretical model describing the accelerated oxide layer growth due to thermal aging was developed.These findings support the advancement of LFR technology.展开更多
Preferential oxidation of CO is an effective process to clean up CO in hydrogen for proton exchange membrane fuel cells(PEMFCs).Herein,we synthesis a highly efficient catalyst for preferential oxidation(PROX)of CO thr...Preferential oxidation of CO is an effective process to clean up CO in hydrogen for proton exchange membrane fuel cells(PEMFCs).Herein,we synthesis a highly efficient catalyst for preferential oxidation(PROX)of CO through the deposition of Ru/Ir nanojunctions on Fe_(2)O_(3) nanoparticles.The as-prepared catalyst shows 90%CO conversion at 80℃ within the working temperature of PEMFCs and the total CO conversion in the temperature range of 140℃ to 160℃under gas flow velocity of 36000 mL·g^(−1)h^(−1) while maintaining good stability for 24 h.Density functional theory calculations reveal that the substrate Fe_(2)O_(3) not only serves as a source of lattice oxygen atoms for the catalytic process but also acts as an electron acceptor from Ru/Ir,thereby regulating its valence state.This regulation is beneficial for the adsorption of reaction intermediates and reduces the activation energy of PROX.展开更多
The identification of igneous rock in sedimentary basins serves as the basis for the exploration of igneous oil and gas reservoirs.The implementation of magnetic exploration in the identification and delineation of ig...The identification of igneous rock in sedimentary basins serves as the basis for the exploration of igneous oil and gas reservoirs.The implementation of magnetic exploration in the identification and delineation of igneous rock can often achieve good results.However,when igneous rock and deep magnetic layers are under the influence of remanence,the reduction to the pole of magnetic anomaly and conventional magnetic inversion methods,which require clear magnetization directions,is limited,and special magnetic anomaly processing and inversion methods are necessary.We present a case study on igneous rock imaging through a strategy involving the joint use of a preferential filtering method and amplitude inversion affected by remanence in the Qikou depression in China.We first extract the weak anomalies of igneous rock from the observed total-field anomaly via preferential filtering and calculate their amplitude data.We then perform amplitude inversion to determine the underground three-dimensional magnetism distribution and propose a reasonable interpretation by combining seismic and other data.This work demonstrates the feasibility and effectiveness of the above strategy in delineating the igneous rock buried deep in sedimentary basins.展开更多
The freeze-thaw process is crucial for forming soil macropore structure to promote movement of water and salt downward by preferential flow in seasonally frozen regions.However,the freeze-thaw process of soil is hinde...The freeze-thaw process is crucial for forming soil macropore structure to promote movement of water and salt downward by preferential flow in seasonally frozen regions.However,the freeze-thaw process of soil is hindered by the snowpack,and the effects of the snowpack on the soil macropore structure and its implications on the formation of preferential flow are not well understood.This study collected soil samples from Da’an City,Northeast China,on July 15 and 16,2022,and conducted an indoor soil column snowpack-freeze-thaw tracing experiment on October 10 to 30,2022,to reveal the impact of snowpack and freeze-thaw cycles(FTC)on the forma-tion of preferential flow.The experiments were carried out with three levels of initial moisture content(IMC)of the soil column,the times of freeze-thaw cycles(T-FTC),and the snowpack thickness(SPT).Results show that increases in both IMC and SPT decreased the max infiltration depth(MID)of preferential flow.Greater T-FTC increased the MID and non-uniformity of the wet front trace and promoted the creation of preferential flow.The T-FTC and IMC both increased the overall variability of preferential flow,but this vari-ability decreased with greater SPT.The length index(LI)had the most significant impact on the preferential flow index(PFI)with an entropy weight of 0.2340,while the height difference of the multifractal spectrum(Δf(α))had the most negligible impact with a weight of 0.0753.Finally,results of redundancy analysis(RDA)and structural equation model(SEM)show that multifractal characteristic in-dicators have a much stronger ability to reflect the degree of preferential flow than developmental characteristic indicators.The T-FTC was the most important factor driving the formation of preferential flow in snowpack-freeze-thaw cycles.Therefore,conducting re-search on preferential flow in cold and arid regions is greatly significant for the utilization of regional water resources and the improve-ment of soil ecological environments.展开更多
Intercalation of rare-earth(RE)into Pt offers an option to optimize the electronic structure of Pt-based catalysts by interaction effect,in which the synergistic catalytic sites are of great significance,yet the under...Intercalation of rare-earth(RE)into Pt offers an option to optimize the electronic structure of Pt-based catalysts by interaction effect,in which the synergistic catalytic sites are of great significance,yet the underpinning mechanism remains elusive.Herein,the introduction of silanol nests enables the alloy formation on the SiO_(2)surface.The amination modification is disclosed to induce the electron transfer from RE to Pt and weaken the adsorption of CO on electron-rich Pt species.In situ/operando spectroscopic analyses in conjunction with density functional theory calculations demonstrate the electronic couple of Pt atoms and adjacent Ce atoms concurrently achieves the enhancement of CO oxidation and suppression of H_(2)oxidation.Additionally,CO_(2)is readily desorbed from the Pt_(5)Ce(111)surface to enhance intrinsic activity and longevity.These findings provide an atomic-level insight into the synergistic catalytic sites on regulating the electronic state of the Pt-RE alloy catalysts toward highly selective oxidation reactions.展开更多
The dynamic monitoring of landslides in engineering geology has focused on the correlation among landslide stability,rainwater infiltration,and subsurface hydrogeology.However,the understanding of this complicated cor...The dynamic monitoring of landslides in engineering geology has focused on the correlation among landslide stability,rainwater infiltration,and subsurface hydrogeology.However,the understanding of this complicated correlation is still poor and inadequate.Thus,in this study,we investigated a typical landslide in southwestern China via time-lapse electrical resistivity tomography（TLERT） in November 2013 and August 2014.We studied landslide mechanisms based on the spatiotemporal characteristics of surface water infiltration and flow within the landslide body.Combined with borehole data,inverted resistivity models accurately defined the interface between Quaternary sediments and bedrock.Preferential flow pathways attributed to fracture zones and fissures were also delineated.In addition,we found that surface water permeates through these pathways into the slipping mass and drains away as fissure water in the fractured bedrock,probably causing the weakly weathered layer to gradually soften and erode,eventually leading to a landslide.Clearly,TLERT dynamic monitoring can provide precursory information of critical sliding and can be used in landslide stability analysis and prediction.展开更多
Igneous rocks in the South China Sea have broad prospects for oil and gas exploration.Integrated geophysical methods are important approaches to study the distribution of igneous rocks and to determine and identify ig...Igneous rocks in the South China Sea have broad prospects for oil and gas exploration.Integrated geophysical methods are important approaches to study the distribution of igneous rocks and to determine and identify igneous rock bodies.Aimed at the characteristics of gravity and magnetic fields in the South China Sea,several potential field processing methods are preferentially selected.Reduction to the pole by variable inclinations in the area of low magnetic latitudes is used to perform reduction processing on magnetic anomalies.The preferential continuation method is used to separate gravity and magnetic anomalies and extract the gravity and magnetic anomaly information of igneous rocks in the shallow part of the South China Sea.The 3D spatial equivalent distribution of igneous rocks in South China Sea is illustrated by the 3 D correlation imaging of magnetic anomalies.Since the local anomaly boundaries are highlighted gravity and magnetic gradients,the distribution characters of different igneous rocks are roughly outlined by gravity and magnetic correlation analysis weighted by gradient.The results show the distribution of igneous rocks is controlled and influenced by deep crustal structure and faulting.展开更多
Ruthenium （Ru）‐based catalysts are widely employed in several types of gas‐solid reactions because of their high catalytic activities. This review provides theoretical research on Ru‐based catalysts and an analys...Ruthenium （Ru）‐based catalysts are widely employed in several types of gas‐solid reactions because of their high catalytic activities. This review provides theoretical research on Ru‐based catalysts and an analysis of their basic properties and oxidation behavior. There is particular emphasis on Ru‐catalyzed gas‐solid catalytic reactions, including the catalytic oxidation of VOCs, preferential oxidation of CO, synthesis of ammonia, oxidation of HCl and partial oxidation of CH4. Recent litera‐ture on catalysis is summarized and compared. Finally, we describe current challenges in the field and propose approaches for future development of Ru‐based catalysts.展开更多
A new process for vanadium recovery from stone coal by roasting-flotation was investigated based on the mineralogy. The process comprised four key steps： decarburization, preferential grinding, desliming and flotatio...A new process for vanadium recovery from stone coal by roasting-flotation was investigated based on the mineralogy. The process comprised four key steps： decarburization, preferential grinding, desliming and flotation. In the decarburization stage, roasting at 550 ℃ effectively avoided the negative effect of the carbonaceous materials in raw ore and generation of free CaO from calcite decomposition during roasting. Through preferential grinding, the high acid-consuming minerals were enriched in the middle fractions, while mica was enriched in the fine and coarse fractions. Through flotation, the final concentrate can be obtained with V2O5 grade of 1.07% and recovery of 83.30%. Moreover, the vanadium leaching rate of the final concentrate increased 13.53% compared to that of the feed. The results reveal that the decarburization by roasting at 550 ℃ is feasible and has little negative impact on mica flotation, and vanadium recovery from stone coal is conducive to reducing handling quantity, acid consumption and production cost.展开更多
Based on the data base of 1285 mineral deposits of 22 commodities in 121 countries of 6 continents of the world, the authors use the linear trend analysis for their reserves to determine the cut-off limited order of r...Based on the data base of 1285 mineral deposits of 22 commodities in 121 countries of 6 continents of the world, the authors use the linear trend analysis for their reserves to determine the cut-off limited order of reserves to select 36 exceptional superlarge （as peak mineral）, 95 superlarge and 314 large deposits as new recognized intellect for their quantitative change. We have projected above 445 large-superlarge deposits on （1：5 M） global tectonic background map and divided 4 metallogenic domains, 21 metallogenic belts. Global metallogeny of large-superlarge deposits are： unity by endogenic, exogenic metamorphic and epigenetic in origin; speciality in different metallogenic domains and belts; preferentiality to ore-forming elements of Cu, Au, Fe, Ag, Cr, Mn, Zn, Pb, Sb, Hg, to continental margins or plate convergent belts, to Intra-continental tectono-magmatic complex belts and Large ductile shear zones; abnormality by the global oxyatmversion （excess oxygen atmospheric event） in Archean, redoxyatmversion （lack oxygen atmospheric event） in Proterozoic-Paleozoic, and tectonosphere thermal erosion （great amount of tectonic magmatic event） in Mesozoic-Cenozoic.展开更多
The tidal current duration （TCD） and velocity （TCV） and suspended sediment concentration （SSC） were measured in the dry season in December, 2011 and in the flood season in June, 2012 at the upper part of the Nor...The tidal current duration （TCD） and velocity （TCV） and suspended sediment concentration （SSC） were measured in the dry season in December, 2011 and in the flood season in June, 2012 at the upper part of the North Channel of Changjiang Estuary. They were assimilated with the measured data in 2003, 2004, 2006 and 2007, using the tidal range＇s proportion conversion. Variations in TCD and TCV, preferential flow and SSC have been calculated. Influences of typical engineering projects such as Qingcaosha fresh water reservoir, Yangtze River Bridge, and land reclamation on the ebb and flood TCD, TCV and SSC in the North Channel for the last 10 years are discussed. The results show that： （1） currently, in the upper part of North Channel, the ebb tide dominates; after the construction of the typical projects, ebb TCD and TCV tends to be larger and the vertical average ebb and flood SSC decrease during the flood season while SSC increases during the dry season; （2） changes in the vertical average TCV are mainly contributed by seasonal runoff variation during the flood season, which is larger in the flood season than that in the dry season; the controlling parameters of increasing ebb TCD and TCV are those large-scale engineering projects in the North Channel; variation in SSC may result mainly from the reduction of basin annual sediment loads, large-scale nearshore projects and so on.展开更多
Binary mixtures of 1,3-dialkylimidazolium based ionic liquids （ILs） and water were selected as solvent systems to investigate the solute-solvent and solvent-solvent interactions on the preferential solvation of solv...Binary mixtures of 1,3-dialkylimidazolium based ionic liquids （ILs） and water were selected as solvent systems to investigate the solute-solvent and solvent-solvent interactions on the preferential solvation of solvatochromic indicators at 25 ℃. Empirical solvatochromic pa- rameters, dipolarity/polarizability （π^＊）, hydrogen-bond donor acidity （α）, hydrogen-bond acceptor basicity （β）, and Reichardt＇s polarity parameters （ET^N） were measured from the ultraviolet-visible spectral shifts of 4-nitroaniline, 4-nitroanisole, and Reichardt＇s dye. The solvent properties of the IL-water mixtures were found to be influenced by IL type and IL mole fraction （XIL）. All these studied systems showed the non-ideal behavior. The max- imum deviation to ideality for the solvatochromic parameters can be obtained in the XIL range from 0.i to 0.3. For most of the binary mixtures, the π^＊ values showed the synergistic effects instead of the ETN, α and β values. The observed synergy extent was dependent on the studied systems, such as the dye indicator and IL type. A preferential solvation model was utilized to gather information on the molecular interactions in the mixtures. The dye indicator was preferentially solvated on the following trend： IL〉IL-water complex〉water.展开更多
基金by National Natural Science Foundation of China(Nos.52271103,52334010 and 52271031)Jilin Scientific and Technological Development Program(Nos.20220301026GX,20210201115GX and 20210301041GX).
文摘Conventional rolled Mg-Al alloy sheets typically exhibit strong basal textures that remain and may even strengthen after recrystallization annealing due to the preferential growth of basal-oriented grains,resulting in poor formability at room temperature.Therefore,the knowledge of recrystallization and grain growth is critical for modifying textures of Mg-Al alloy sheets.The static recrystallization and texture evolution in a cold-rolled dilute Mg-1Al(wt.%)alloy during various annealed temperatures ranging from 300℃ to 450℃,have been investigated using the quasi in-situ electron backscatter diffraction(EBSD)method.The as-rolled Mg-1Al alloy shows a dominant basal texture,which weakens and broadens in the rolling direction(RD)during the subsequent annealing,accompanied by the formation of{1010}texture component.Particularly,the {1010} texture component is more pronounced after annealing at high temperatures.The quasi in-situ EBSD results show that recrystallized grains are mainly induced by shear bands,which exhibit a wide spectrum of orientations with c-axis tilt angles ranging 20°-45°from the normal direction(ND).Orientations of shear band-induced recrystallized grains are retained during the entire recrystallization process,resulting in a reduction in the texture intensity.Moreover,recrystallized grains belonging to the {1010}texture component grow preferentially compared to those with other orientations,which is attributed to low energy grain boundaries,especially grain boundaries with∼30°misorientation angles.Furthermore,the high temperature annealing facilitates the rapid growth of grain boundaries having a 30°misorientation angle,leading to the occurrence of distinct {1010} texture after annealing at 450℃ for 1 h.The results provide insights for texture modification of rare earth-free low-alloyed Mg alloys by controlling annealing parameters.
基金financially supported by the National Key Research and Development Program of China(No.2022YFB3504200)the National Natural Science Foundation of China(Nos.U21A20326 and 22376063)+4 种基金the fund of the National Engineering Laboratory for Mobile Source Emission Control Technology(No.NELMS2020A05)the Fundamental Research Funds for the Central Universitiesthe funding received from the European Union's Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement No 897197.Y.L.(CSC No.202006740085)is grateful for thegrant from the China Scholarship Councilthe ICREA Academia program and grants MICINN/FEDER PID2021124572OB-C31 and GC 2021 SGR 01061part of Maria de Maeztu Units of Excellence Programme CEX2023-001300-M/funded by MCIN/AEI/https://doi.org/10.13039/501100011033
文摘Preferential oxidation of CO(CO-PROX)in H_(2)-rich streams is highly important for purifying the industrial grade H_(2)used in proton-exchange-membrane fuel cells(PEMFC),but it is still limited to a relatively narrow operation temperature window.In this study,the trace amounts of Cu are used to modify a Pt/Al_(2)O_(3)catalyst.The introduced Cu_(2+)species are atomically anchored on Pt nanoparticles through strong electrostatic adsorption.
基金supported by financial support from the National Natural Science Foundation of China(Grant No.22225801 and 22461142137).
文摘Aqueous zinc-ion batteries have emerged as promising candidates in next-generation energy storage sys-tems.However,their practical implementation is significantly hindered by interfacial side reactions,par-ticularly the hydrogen evolution reaction(HER)at the Zn metal anode interface.Herein,this study presents an innovative approach to address this challenge through the construction of an interfacial pref-erential coordination layer on the Zn anode surface.The proposed layer effectively terminates the conti-nuity of interfacial hydrogen-bond networks and blocks proton transport,thereby mitigating the HER.Specifically,2-phenylbenzimidazole-5-sulfonic acid(PBSA)with zincophilic groups was introduced as an electrolyte additive,which would be preferentially and selectively anchored on the Zn surface through its zincophilic nitrogen and sulfonic acid,forming the interfacial coordination layer.This coordination layer serves as a protective barrier,repelling water molecules from the Zn electrode surface and alleviat-ing water decomposition.Crucially,the interfacial coordination layer features stronger hydrogen-bonding interactions with interfacial water molecules,terminates the hydrogen-bonding network between water molecules,hinders the transportation and electro-reduction of proton,and ultimately inhibits HER at the interface.As a result,the Zn symmetric cell with PBSA/ZnSO_(4)delivered higher cycling stability of 2500 h at 1 mA cm^(-2)and Zn/NH_(4)V_(4)O_(10)full cells with PBSA/ZnSO_(4)possessed enhanced capac-ity retention.This interfacial hydrogen-bond regulation strategy provided valuable insight for designing HER-free interfacial protective layer in high-performance aqueous batteries.
基金supported by The National Science Foundation For Distinguished Young Scholars(42425107)Self-financed science and technology projects of Qinghai 906 Engineering Survey and Design Institute Co.Ltd(2024-KJ-04)+2 种基金Gansu Province Young Talent Program(2025QNGR53)Gansu Science and Technology Program(25JRRA537)the Top Talent Project of Gansu province,Chinese Academy of Sciences Young Crossover Team Project(JCTD-2022-18).
文摘A thorough understanding of the source and infiltration mechanism of soil water is of great significance to the stable supply of regional water resources and the protection of ecological environment.To solve this crucial scientific problem,a total of 1980 samples of various water bodies in Qilian Mountains were collected in early,heavy and end ablation period in 2012-2019 to determine the source of soil water with endmember mixing analysis.Double isotope mass balance was used to calculate the relative contribution of piston flow and preferred flow to groundwater.The results of the study show that precipitation dominated the soil water in the study region,and it contributes 78%,89%and 91%of soil water in early,heavy and end ablation periods,respectively.Ground ice meltwater is also an important source of soil water,its contribution was 16%,11%and 7%in early,heavy and end ablation period,respectively.Snowmelt contributed to soil water only during the early(6%)and late(2%)ablation periods.Groundwater is replenished through the combined effects of preferential flow and piston flow.According to double isotope mass balance,the contribution of priority flow to shallow groundwater is 34%,45%and 34%,respectively in early,heavy and end ablation periods.This study identified the sources of soil water and water transport mechanisms in the Qilian Mountains,providing scientific and technological support for water resource conservation and sustainable utilization in cold regions.
基金supported by the Jilin Province Science and Technology Department Major Science and Technology project[grant numbers 20220301004GX,20220301005GX]Key Subject Construction of Physical Chemistry of Northeast Normal Universitythe Fundamental Research Funds for the Central Universities[grant number 2412023QD014]。
文摘Li plating behavior of the Li metal anode and its compatibility with electrolytes play a decisive role in the electrochemical performance of the Li metal batteries(LMBs),while the intrinsic highly reactive Li would induce serious results especially under deep Li plating/stripping depth and with lean electrolytes.Herein,we propose an innovative strategy to simultaneously regulate the bulk construction and the preferential orientation of Li deposition by introducing Li22Sn5/Li-Mg alloys to realize ultra-stable thin Li anodes with long lifespan.The alloys can form a continuous framework with high lithiophilicity and fast ion-diffusion to enable homogenous Li flux,and meanwhile tune the preferential orientation of Li from the conventional(110)plane to(200)to lower the Li reactivity with electrolytes and optimize Li deposition.Therefore,the thin Li-Sn-Mg alloy anode showcases ultra-stable cycling without volume changes and dendrites under a deep Li plating/stripping depth of 89.1%(5 mAh cm^(-2))for over 1200 h in commercial carbonate electrolytes.Moreover,a multilayered NCM811pouch cell with a high energy density of403.6 Wh kg^(-1)is achieved under the harsh conditions of low N/P ratio(0.769)and lean electrolytes(~2.1 g Ah^(-1)).Synchronously,the thin alloy anode shows improved air stability which benefits the manufacturing process and performance of LMBs,displaying the great application potential of these alloy anodes.
基金supported by the Natural Science Foundation of Shandong Province with grant No.ZR2023ME196the Science and Technology Support Plan for Young Innovation of Colleges and Universities of Shandong Province with grant No.2022KJ273+1 种基金the Youth Innovation Promotion Association of the Chinese Academy of Sciences with grant No.2017486the Patent Navigation Project of Shandong Province with grant No.D202327.
文摘In lead-cooled fast reactor(LFR)systems,the liquid lead-bismuth eutectic(LBE)coolant provides a cor-rosive environment that damages the steel components during high-temperature operation.This study investigated the microstructural deterioration of 9Cr ferritic/martensitic(F/M)steel under thermal aging at 550℃for 2,000,10,000,or 20,000 h and its effect on oxidation corrosion in an LBE environment using multiscale characterization techniques.The results indicated that the thickness of the internal oxidation zone(IOZ)increased significantly with extended thermal aging,whereas that of the spinel layer remained relatively constant.The abundant subgrain boundaries that emerged during extensive thermal aging facil-itated Fe diffusion,and the enlarged Cr-rich M23C6 carbides contributed to the formation of preferential oxidation regions,accelerating IOZ layer growth.The spinel layer formed from the IOZ was influenced by microstructural defects within the IOZ.A theoretical model describing the accelerated oxide layer growth due to thermal aging was developed.These findings support the advancement of LFR technology.
基金financially supported by the National Natural Science Foundation of China(No.22072140,No.22272155,and No.22102169)the National Key R&D Program of China(No.2021YFA1600202)。
文摘Preferential oxidation of CO is an effective process to clean up CO in hydrogen for proton exchange membrane fuel cells(PEMFCs).Herein,we synthesis a highly efficient catalyst for preferential oxidation(PROX)of CO through the deposition of Ru/Ir nanojunctions on Fe_(2)O_(3) nanoparticles.The as-prepared catalyst shows 90%CO conversion at 80℃ within the working temperature of PEMFCs and the total CO conversion in the temperature range of 140℃ to 160℃under gas flow velocity of 36000 mL·g^(−1)h^(−1) while maintaining good stability for 24 h.Density functional theory calculations reveal that the substrate Fe_(2)O_(3) not only serves as a source of lattice oxygen atoms for the catalytic process but also acts as an electron acceptor from Ru/Ir,thereby regulating its valence state.This regulation is beneficial for the adsorption of reaction intermediates and reduces the activation energy of PROX.
基金supported by the National Natural Science Foundation of China(No.41074095)the Scientific Research Foundation of China University of Petroleum(Beijing)at Karamay(NO:XQZX20230005).
文摘The identification of igneous rock in sedimentary basins serves as the basis for the exploration of igneous oil and gas reservoirs.The implementation of magnetic exploration in the identification and delineation of igneous rock can often achieve good results.However,when igneous rock and deep magnetic layers are under the influence of remanence,the reduction to the pole of magnetic anomaly and conventional magnetic inversion methods,which require clear magnetization directions,is limited,and special magnetic anomaly processing and inversion methods are necessary.We present a case study on igneous rock imaging through a strategy involving the joint use of a preferential filtering method and amplitude inversion affected by remanence in the Qikou depression in China.We first extract the weak anomalies of igneous rock from the observed total-field anomaly via preferential filtering and calculate their amplitude data.We then perform amplitude inversion to determine the underground three-dimensional magnetism distribution and propose a reasonable interpretation by combining seismic and other data.This work demonstrates the feasibility and effectiveness of the above strategy in delineating the igneous rock buried deep in sedimentary basins.
基金Under the auspices of the Natural Science Foundation of China(No.42272299)The Key Projects of Jilin Provincial Department of Science and Technology(No.20240203004NC)+1 种基金National Key Research and Development Program of China(No.2022YFD1500500)Graduate Innovation Fund of Jilin University(No.2024CX111)。
文摘The freeze-thaw process is crucial for forming soil macropore structure to promote movement of water and salt downward by preferential flow in seasonally frozen regions.However,the freeze-thaw process of soil is hindered by the snowpack,and the effects of the snowpack on the soil macropore structure and its implications on the formation of preferential flow are not well understood.This study collected soil samples from Da’an City,Northeast China,on July 15 and 16,2022,and conducted an indoor soil column snowpack-freeze-thaw tracing experiment on October 10 to 30,2022,to reveal the impact of snowpack and freeze-thaw cycles(FTC)on the forma-tion of preferential flow.The experiments were carried out with three levels of initial moisture content(IMC)of the soil column,the times of freeze-thaw cycles(T-FTC),and the snowpack thickness(SPT).Results show that increases in both IMC and SPT decreased the max infiltration depth(MID)of preferential flow.Greater T-FTC increased the MID and non-uniformity of the wet front trace and promoted the creation of preferential flow.The T-FTC and IMC both increased the overall variability of preferential flow,but this vari-ability decreased with greater SPT.The length index(LI)had the most significant impact on the preferential flow index(PFI)with an entropy weight of 0.2340,while the height difference of the multifractal spectrum(Δf(α))had the most negligible impact with a weight of 0.0753.Finally,results of redundancy analysis(RDA)and structural equation model(SEM)show that multifractal characteristic in-dicators have a much stronger ability to reflect the degree of preferential flow than developmental characteristic indicators.The T-FTC was the most important factor driving the formation of preferential flow in snowpack-freeze-thaw cycles.Therefore,conducting re-search on preferential flow in cold and arid regions is greatly significant for the utilization of regional water resources and the improve-ment of soil ecological environments.
基金financially supported by the National Natural Science Foundation of China(22468034)the Natural Science Foundation of Inner Mongolia(2021MS02008 and 2022MS02011)the Key Research and Development Project of Ordos(YF20240062)。
文摘Intercalation of rare-earth(RE)into Pt offers an option to optimize the electronic structure of Pt-based catalysts by interaction effect,in which the synergistic catalytic sites are of great significance,yet the underpinning mechanism remains elusive.Herein,the introduction of silanol nests enables the alloy formation on the SiO_(2)surface.The amination modification is disclosed to induce the electron transfer from RE to Pt and weaken the adsorption of CO on electron-rich Pt species.In situ/operando spectroscopic analyses in conjunction with density functional theory calculations demonstrate the electronic couple of Pt atoms and adjacent Ce atoms concurrently achieves the enhancement of CO oxidation and suppression of H_(2)oxidation.Additionally,CO_(2)is readily desorbed from the Pt_(5)Ce(111)surface to enhance intrinsic activity and longevity.These findings provide an atomic-level insight into the synergistic catalytic sites on regulating the electronic state of the Pt-RE alloy catalysts toward highly selective oxidation reactions.
基金funded by the National Basic Research Program of China(973 Program)(No.2013CB733203)the National Natural Science Foundation of China(No.41474055)
文摘The dynamic monitoring of landslides in engineering geology has focused on the correlation among landslide stability,rainwater infiltration,and subsurface hydrogeology.However,the understanding of this complicated correlation is still poor and inadequate.Thus,in this study,we investigated a typical landslide in southwestern China via time-lapse electrical resistivity tomography（TLERT） in November 2013 and August 2014.We studied landslide mechanisms based on the spatiotemporal characteristics of surface water infiltration and flow within the landslide body.Combined with borehole data,inverted resistivity models accurately defined the interface between Quaternary sediments and bedrock.Preferential flow pathways attributed to fracture zones and fissures were also delineated.In addition,we found that surface water permeates through these pathways into the slipping mass and drains away as fissure water in the fractured bedrock,probably causing the weakly weathered layer to gradually soften and erode,eventually leading to a landslide.Clearly,TLERT dynamic monitoring can provide precursory information of critical sliding and can be used in landslide stability analysis and prediction.
基金the National 863 Projects(Nos.2006AA06Z111,2006AA06201-3,and 2006AA09A101-3)National Special Project(No.SinoProbe-01-05)Open Project of the National Key Laboratory for Geological Processes and Mineral Resources(No.GPMR0942).
文摘Igneous rocks in the South China Sea have broad prospects for oil and gas exploration.Integrated geophysical methods are important approaches to study the distribution of igneous rocks and to determine and identify igneous rock bodies.Aimed at the characteristics of gravity and magnetic fields in the South China Sea,several potential field processing methods are preferentially selected.Reduction to the pole by variable inclinations in the area of low magnetic latitudes is used to perform reduction processing on magnetic anomalies.The preferential continuation method is used to separate gravity and magnetic anomalies and extract the gravity and magnetic anomaly information of igneous rocks in the shallow part of the South China Sea.The 3D spatial equivalent distribution of igneous rocks in South China Sea is illustrated by the 3 D correlation imaging of magnetic anomalies.Since the local anomaly boundaries are highlighted gravity and magnetic gradients,the distribution characters of different igneous rocks are roughly outlined by gravity and magnetic correlation analysis weighted by gradient.The results show the distribution of igneous rocks is controlled and influenced by deep crustal structure and faulting.
基金supported by Beijing Natural Science Foundation (8164063)the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB05050100)~~
文摘Ruthenium （Ru）‐based catalysts are widely employed in several types of gas‐solid reactions because of their high catalytic activities. This review provides theoretical research on Ru‐based catalysts and an analysis of their basic properties and oxidation behavior. There is particular emphasis on Ru‐catalyzed gas‐solid catalytic reactions, including the catalytic oxidation of VOCs, preferential oxidation of CO, synthesis of ammonia, oxidation of HCl and partial oxidation of CH4. Recent litera‐ture on catalysis is summarized and compared. Finally, we describe current challenges in the field and propose approaches for future development of Ru‐based catalysts.
基金Project(2015BAB03B05)supported by the National Key Technology R&D Program during the"12th Five-year Plan"Period,ChinaProject(51404177)supported by the National Natural Science Foundation of China
文摘A new process for vanadium recovery from stone coal by roasting-flotation was investigated based on the mineralogy. The process comprised four key steps： decarburization, preferential grinding, desliming and flotation. In the decarburization stage, roasting at 550 ℃ effectively avoided the negative effect of the carbonaceous materials in raw ore and generation of free CaO from calcite decomposition during roasting. Through preferential grinding, the high acid-consuming minerals were enriched in the middle fractions, while mica was enriched in the fine and coarse fractions. Through flotation, the final concentrate can be obtained with V2O5 grade of 1.07% and recovery of 83.30%. Moreover, the vanadium leaching rate of the final concentrate increased 13.53% compared to that of the feed. The results reveal that the decarburization by roasting at 550 ℃ is feasible and has little negative impact on mica flotation, and vanadium recovery from stone coal is conducive to reducing handling quantity, acid consumption and production cost.
文摘Based on the data base of 1285 mineral deposits of 22 commodities in 121 countries of 6 continents of the world, the authors use the linear trend analysis for their reserves to determine the cut-off limited order of reserves to select 36 exceptional superlarge （as peak mineral）, 95 superlarge and 314 large deposits as new recognized intellect for their quantitative change. We have projected above 445 large-superlarge deposits on （1：5 M） global tectonic background map and divided 4 metallogenic domains, 21 metallogenic belts. Global metallogeny of large-superlarge deposits are： unity by endogenic, exogenic metamorphic and epigenetic in origin; speciality in different metallogenic domains and belts; preferentiality to ore-forming elements of Cu, Au, Fe, Ag, Cr, Mn, Zn, Pb, Sb, Hg, to continental margins or plate convergent belts, to Intra-continental tectono-magmatic complex belts and Large ductile shear zones; abnormality by the global oxyatmversion （excess oxygen atmospheric event） in Archean, redoxyatmversion （lack oxygen atmospheric event） in Proterozoic-Paleozoic, and tectonosphere thermal erosion （great amount of tectonic magmatic event） in Mesozoic-Cenozoic.
文摘The tidal current duration （TCD） and velocity （TCV） and suspended sediment concentration （SSC） were measured in the dry season in December, 2011 and in the flood season in June, 2012 at the upper part of the North Channel of Changjiang Estuary. They were assimilated with the measured data in 2003, 2004, 2006 and 2007, using the tidal range＇s proportion conversion. Variations in TCD and TCV, preferential flow and SSC have been calculated. Influences of typical engineering projects such as Qingcaosha fresh water reservoir, Yangtze River Bridge, and land reclamation on the ebb and flood TCD, TCV and SSC in the North Channel for the last 10 years are discussed. The results show that： （1） currently, in the upper part of North Channel, the ebb tide dominates; after the construction of the typical projects, ebb TCD and TCV tends to be larger and the vertical average ebb and flood SSC decrease during the flood season while SSC increases during the dry season; （2） changes in the vertical average TCV are mainly contributed by seasonal runoff variation during the flood season, which is larger in the flood season than that in the dry season; the controlling parameters of increasing ebb TCD and TCV are those large-scale engineering projects in the North Channel; variation in SSC may result mainly from the reduction of basin annual sediment loads, large-scale nearshore projects and so on.
文摘Binary mixtures of 1,3-dialkylimidazolium based ionic liquids （ILs） and water were selected as solvent systems to investigate the solute-solvent and solvent-solvent interactions on the preferential solvation of solvatochromic indicators at 25 ℃. Empirical solvatochromic pa- rameters, dipolarity/polarizability （π^＊）, hydrogen-bond donor acidity （α）, hydrogen-bond acceptor basicity （β）, and Reichardt＇s polarity parameters （ET^N） were measured from the ultraviolet-visible spectral shifts of 4-nitroaniline, 4-nitroanisole, and Reichardt＇s dye. The solvent properties of the IL-water mixtures were found to be influenced by IL type and IL mole fraction （XIL）. All these studied systems showed the non-ideal behavior. The max- imum deviation to ideality for the solvatochromic parameters can be obtained in the XIL range from 0.i to 0.3. For most of the binary mixtures, the π^＊ values showed the synergistic effects instead of the ETN, α and β values. The observed synergy extent was dependent on the studied systems, such as the dye indicator and IL type. A preferential solvation model was utilized to gather information on the molecular interactions in the mixtures. The dye indicator was preferentially solvated on the following trend： IL〉IL-water complex〉water.
