The accelerated decline of Arctic sea ice since the 1980s has paradoxically amplified greenhouse gas(GHG)emissions through increased shipping activities in this ecologically vulnerable region.This study investigates h...The accelerated decline of Arctic sea ice since the 1980s has paradoxically amplified greenhouse gas(GHG)emissions through increased shipping activities in this ecologically vulnerable region.This study investigates how to reconcile the decarbonization of Arctic shipping with conflicting environmental,economic,and geopolitical interests.Through systematic literature review and interest-balancing analysis,our findings identify three systemic barriers:(1)inadequate adaptation of International Maritime Organization(IMO)regulations to Arctic-specific environmental risks,(2)fragmented enforcement mechanisms among Arctic and non-Arctic States,and(3)technological limitations in clean fuel adoption for ice-class vessels.To address these challenges,a tripartite governance framework is proposed.First,legally binding amendments to International Convention for the Prevention of Pollution from Ships(MARPOL)Annex VI introducing Arctic-specific Energy Efficiency eXisting ship Index(EEXI)standards and extending energy efficiency regulations to fishing vessels.Second,a phased fuel transition prioritizing liquefied natural gas(LNG)and methanol,followed by hydrogen-ammonia synthetics.Third,enhanced multilateral cooperation through an Arctic Climate Shipping Alliance to coordinate joint research and development in cold-adapted technologies and ice-route optimization.By integrating United Nations Convention on the Law of the Sea(UNCLOS)obligations with IMO Polar Code implementation,this study advances a dynamic interest-balancing framework for policymakers,offering actionable pathways to achieve Paris Agreement targets while safeguarding Arctic ecosystems.展开更多
The contamination of wastewater with organic pollutants and nitrogen compounds poses significant environmental challenges.The primary objective of wastewater treatment is the simultaneous denitrification and decarboni...The contamination of wastewater with organic pollutants and nitrogen compounds poses significant environmental challenges.The primary objective of wastewater treatment is the simultaneous denitrification and decarbonization of ammonia nitrogen and organics into harmless by-products.This study presents a novel method for the directional generation of chlorine radical species like·ClO and·Cl using electro-reactive membranes(EMs)known as RuO_(2)@PbO_(2)-M,which were fabricated using an electro-deposition coupled template approach.This method facilitates the rapid and efficient conversion of ammonia to nitrogen and concurrently reduces the chemical oxygen demand in the effluent.Our system achieved ultra-efficient simultaneous denitrification and decarbonization with minimal energy consumption in single-filtration mode,thereby eliminating the need for chemical precursors.We elucidate the formation pathway of·ClO and·Cl during the electrochemical oxidation process involving RuO_(2)@PbO_(2)-M,where·Cl generated from RuO_(2)reacts with·OH from PbO_(2)under hypochlorous acid conditions,thereby enhancing nitrogen and carbon removal.These findings highlight a novel electro-filtration and an innovative reactive membrane design for·ClO synthesis,which provides a new research framework for the concurrent removal of nitrogen and carbon,and offers a promising solution to enhance wastewater treatment efficiency.展开更多
Developing low-carbon and efficient power systems is critical for energy security in the global warming context.We address this issue by focusing on the productivity impact of a decarbonization policy in China’s ther...Developing low-carbon and efficient power systems is critical for energy security in the global warming context.We address this issue by focusing on the productivity impact of a decarbonization policy in China’s thermal power sector—namely,the“Constructing Large Units and Restricting Small Ones”(CLRS)initiative.Utilizing a resource misallocation model,we construct a new theoretical framework to distinguish between technical and allocative efficiency and analyze productivity using plant-level data.The results indicate that the CLRS policy has significantly improved the allocative and technical efficiency of China’s coal-fired power sector,thereby ensuring power security.The closure of outdated and highly distorted small coal-fired units,which have been replaced by technologically advanced large units,primarily drives the enhanced efficiency.The policy’s effects are most pronounced in large-scale power plants and those with high coal combustion efficiency.Furthermore,a comparison of power plants’productivity distribution before and after policy implementation reveals that the CLRS policy not only enhances capital productivity in the coal-fired power sector but also increases rational labor allocation.Our findings have important policy implications for developing countries vis-à-vis building efficient and stable power systems amid climate change.展开更多
This study investigates the disparities in the deployment of photovoltaic(PV)technology for carbon emissions reduction across different nations,highlighting the mismatch between countries with high economic capacity a...This study investigates the disparities in the deployment of photovoltaic(PV)technology for carbon emissions reduction across different nations,highlighting the mismatch between countries with high economic capacity and those where PV installation would maximize global decarbonization benefits.This mismatch is discussed based on three key factors influencing decarbonization via PV technology:per capita gross domestic product;carbon intensity of the energy system;and solar resource availability.Current PV deployment is predominantly concentrated in economically advanced countries,and does not coincide with regions where the environmental and economic impact of such installations would be most significant.Through a series of thought experiments,it is demonstrated how alternative prioritization strategies could significantly reduce global carbon emissions.Argument is put forward for a globally coordinated approach to PV deployment,particularly targeting high-impact sunbelt regions,to enhance the efficacy of decarbonization efforts and promote equitable energy access.The study underscores the need for international policies that support sustainable energy transitions in economically less developed regions through workforce development and assistance with the activation of capital.展开更多
Decarbonising the building sector,particularly residential heating,represents a critical challenge for achieving carbon-neutral energy systems.Efficient solutions must integrate both technological performance and rene...Decarbonising the building sector,particularly residential heating,represents a critical challenge for achieving carbon-neutral energy systems.Efficient solutions must integrate both technological performance and renewable energy sources while considering operational constraints of existing systems.This study investigates a hybrid heating system combining a natural gas boiler(NGB)with an air-to-water heat pump(AWHP),evaluated through a combination of laboratory experiments and dynamic modelling.A prototype developed in the Electrical and Energy Engineering Laboratory enabled the characterization of both heat generators,the collection of experimental data,and the calibration of a MATLAB/Simulink model,including emissions and exhaust analyses.Sensitivity analyses were performed to identify optimal configurations for energy efficiency and system control,accounting for interactions between subsystems.Results highlight that hybridisation significantly improves primary energy efficiency and reduces fuel consumption compared to conventional NGB-only systems.Environmental performance,assessed through CO_(2) and NOx emissions and renewable energy integration,demonstrates the benefits of partial electrification in the residential sector.Economic assessment further quantifies decarbonization costs and fuel savings,illustrating tradeoffs between low-capital,moderate-performance systems and high-efficiency,high-renewable solutions requiring larger investments.The analysis shows that strategic decisions for residential decarbonisation cannot be separated from system-wide considerations,including control strategies,component integration,and economic feasibility.The study underlines the importance of hybrid and renewable-based solutions as pivotal pathways for energy transition in the residential building sector.展开更多
A crystalline sapphire （Al2O3） boule （Ф10 × 80mm^3） grown by the temperature gradient technique （TGT） is a bit colored due to carbon volatilization from the graphite heater at high temperatures and the abs...A crystalline sapphire （Al2O3） boule （Ф10 × 80mm^3） grown by the temperature gradient technique （TGT） is a bit colored due to carbon volatilization from the graphite heater at high temperatures and the absorption of transitional metal inclusions in the raw material. The sapphire becomes colorless and transparent after decolorization and decarbonization in successive annealings in air and hydrogen at high temperatures. The quality, optical transmissivity,and homogeneity of the sapphire are remarkably improved.展开更多
On the basis of understanding the principle of rotary triboelectrostatic separation, dynamic analysis of charged fly ash particles aimed at determining the key factors and separation experiments to improve decarboniza...On the basis of understanding the principle of rotary triboelectrostatic separation, dynamic analysis of charged fly ash particles aimed at determining the key factors and separation experiments to improve decarbonization efficiency had been carried out Variables of electrode plate voltage and corrected wind speed are the key factors which affect the decarbonization efficiency on the separation of fly ash, The results of separation experiments show that:(1) With the plate voltage increasing, the efficiency of decarbonization continuously rises and in its selected range, the optimal voltage level is 45 KV;(2) The corrected wind speed can impact the efficiency of decarbonization significantly: with the speed increasing, the efficiency of decarbonization shows a trend of first decline, then increase and decrease again, and in its selected range, the optimal speed is 2.0 m/s. This study is of significance for the improvement of rotary triboelectrostatic separation performance and its decarbonization separation efficiency.展开更多
The basic principle of fly ash triboelectrification is analysed. The mineral electrical index and test method are introduced. The electric difference of different mineral composition of fly ash is discussed by analysi...The basic principle of fly ash triboelectrification is analysed. The mineral electrical index and test method are introduced. The electric difference of different mineral composition of fly ash is discussed by analysis of chemical and mineral composition of fly ash in Xinwen power plant. The dielectric constant and charge-mass ratio of carbon and ash of fly ash are tested. Combined with the experimental study on rotary triboelectrostatic separation, the charged characteristic of fly ash particles with different size is gained. The results show that the dielectric constant of fly ash with different grain size decreased with the decrease of particle size, which lead to the poor electrical conductivity, Thus it can be seen that par- ticle size plays a leading role in conductivity, The charge of carbon and ash with each size increased with the decreased of particle size; and the charge-mass ratio between carbon and ash with the same size lar- ger with the decrease of size, which indicated that the finer particle size, the more favorable for triboelec- trification separation. In the same conditions, the best decarburization effect is realized when the particle size ranges from 0.038 to 0.074 ram, whose decarbonization rate and efficiency index reached 38.93% and 120.83% respectively.展开更多
Climate change is becoming an important issue in all fields of infrastructure development.Electricity plays a core role in the decarbonized energy system’s path to a regional zero-emission pattern.A well-built trans-...Climate change is becoming an important issue in all fields of infrastructure development.Electricity plays a core role in the decarbonized energy system’s path to a regional zero-emission pattern.A well-built trans-Mediterranean backbone grid can hedge the profound evolution of regional power generation,transmission,and consumption.To date,only Turkey and the Maghreb countries(i.e.,Morocco,Algeria,and Tunisia)are connected with the Continental European Synchronous Area.Other south-and east-shore countries have insufficient interconnection infrastructures and synchronization difficulties that have proven to be major hurdles to the implementation of large-scale solar and wind projects and achievement of climate goals.This study analyzes the current trans-boundary grid interconnections and power and carbon emission portfolios in the Mediterranean region.To align with the recently launched new climate target‘Fit for 55’program and the accelerated large-scale renewables target,a holistic review of projected trans-Mediterranean grids and their market,technical,and financial obstacles of implementation was conducted.For south-and east-shore countries,major legal and regulatory barriers encompassing non-liberalized market structure,regulation gaps of taxation and transmission tariffs,and the private sector’s access rights need to be removed.Enhancement of domestic grids,substations,and harmonized grid codes and frequency,voltage,and communication technology standards among all trans-Mediterranean countries are physical prerequisites for implementing the Trans-Mediterranean Electricity Market.In addition,the mobilization of capital instruments along with private and international investments is indispensable for the realization of supranational transmission projects.As the final section of the decarbonization roadmap,the development of electric appliances,equipment,and vehicles with higher efficiency is inevitable in the decarbonized building,transportation,and industry sectors.展开更多
Decarbonization is a critical issue for peaking CO_(2) emissions of energy-intensive industries,such as the iron and steel industry.The decarbonization options of China’s ironmaking and steelmaking sector were discus...Decarbonization is a critical issue for peaking CO_(2) emissions of energy-intensive industries,such as the iron and steel industry.The decarbonization options of China’s ironmaking and steelmaking sector were discussed based on a systematic three-dimensional low-carbon analysis from the aspects of resource utilization(Y),energy utilization(Q),and energy cleanliness which is evaluated by a process general emission factor(PGEF)on all the related processes,including the current blast furnace(BF)-basic oxygen furnace(BOF)integrated process and the specific sub-processes,as well as the electric arc furnace(EAF)process,typical direct reduction(DR)process,and smelting reduction(SR)process.The study indicates that the three-dimensional aspects,particularly the energy structure,should be comprehensively considered to quantitatively evaluate the decarbonization road map based on novel technologies or processes.Promoting scrap utilization(improvement of Y)and the substitution of carbon-based energy(improvement of PGEF)in particular is critical.In terms of process scale,promoting the development of the scrap-based EAF or DR-EAF process is highly encouraged because of their lower PGEF.The three-dimensional method is expected to extend to other processes or industries,such as the cement production and thermal electricity generation industries.展开更多
Yanbei project of Schlumberger Copower Oilfield Engineering Co.,Ltd.-natural gas purification plant decarbonization unit is equipped with two sets of decarbonization systems(parallel operation).The two sets of systems...Yanbei project of Schlumberger Copower Oilfield Engineering Co.,Ltd.-natural gas purification plant decarbonization unit is equipped with two sets of decarbonization systems(parallel operation).The two sets of systems adopt two tower process,full lean liquid circulation regeneration process,one tower absorption(absorption pressure 5.4mpag),one tower regeneration(regeneration temperature 95℃-110℃),purified natural gas carbon dioxide content≤2.5vol%,single set The treatment capacity is 2300 KM3/d.This paper introduces the problems existing in the decarbonization solution of the decarbonization unit in the natural gas purification plant in recent three years,analyzes the causes of pollutants affecting the quality of the decarbonization solution,and probes into the control measures for the pollution of the decarbonization solution,so as to provide reference.展开更多
This study addresses the critical need for decarbonization in offshore marine logistics by developing an integrated modeling framework to support low-emission operations across complex,multi-echelon vessel networks.It...This study addresses the critical need for decarbonization in offshore marine logistics by developing an integrated modeling framework to support low-emission operations across complex,multi-echelon vessel networks.It focuses on port-to-platform supply chains serving offshore wind farms,oil rigs,and floating logistics hubs.A hybrid analytical approach was adopted,combining Mixed-Integer Linear Programming(MILP)for optimizing emission-minimizing routing,Discrete-Event Simulation(DES)to evaluate offshore scheduling performance under variability,and a Multi-Criteria Decision Analysis(MCDA)model using AHP-TOPSIS to rank alternative marine fuel types.Monte Carlo simulation was also employed to assess cost and delivery fluctuations across uncertain operational scenarios.Data inputs were compiled from real-world offshore fleet specifications,port emissions records,and marine fuel technology benchmarks.MILP-based network flow optimization reduced CO₂emissions by 22%while maintaining service reliability across all demand points.DES simulations revealed congestion-driven scheduling delays during peak vessel utilization.MCDA analysis ranked bio-LNG and hydrogen propulsion systems as optimal choices based on emission,cost,and availability trade-offs.Hypothesis testing confirmed significant relationships between fuel type,network structure,and emission performance.The study demonstrates how multi-echelon logistics planning,integrated with emissions-based modeling,can facilitate environmentally responsible marine supply chain design.The framework offers practical guidance for offshore fleet managers,port authorities,and policy regulators aiming to align operational efficiency with decarbonization objectives under IMO and EU directives.展开更多
Discussions about the future of energy sources and environmental sustainability are becoming critical on a global scale.The energy sector plays a central role in the economy,as the availability and cost of energy infl...Discussions about the future of energy sources and environmental sustainability are becoming critical on a global scale.The energy sector plays a central role in the economy,as the availability and cost of energy influence the competitiveness of economies,while the level of energy consumption impacts the standard of living for individuals.This paper aims to examine environmental challenges and steps for a sustainable transition towards a hydrogen economy,focusing on its potential as an alternative to fossil fuels and the importance of developing the hydrogen paradigm.The research methodology is based on a combination of qualitative and quantitative methods,including an analysis of global and regional trends in the energy transition,the impact of various forms of hydrogen production(green,blue,gray hydrogen)on greenhouse gas emissions,and a comparison of existing policies and strategies in different countries transitioning to a sustainable hydrogen economy.Research results show that green hydrogen,produced via electrolysis using renewable energy sources,holds the greatest potential for reducing greenhouse gas emissions,while gray and blue hydrogen can serve as transitional options.The development of the hydrogen paradigm,rooted in innovative technologies,renewable energy sources,and international cooperation,is crucial for decarbonization and the creation of a sustainable global economy,despite challenges such as high costs and the need for global coordination.The hydrogen paradigm is becoming a cornerstone of these efforts,laying the foundation for a long-term,sustainable global economy.Currently,over 180 hydrogen transport projects,60 distribution projects,80 storage projects,30 terminal and port projects,and more than 220 hydrogen production projects are under development worldwide.The global momentum of the hydrogen transition helps mitigate climate change and build a sustainable future.展开更多
为了提高IF钢的洁净度及可浇性,结合邯钢公司邯宝炼钢厂260 t RH真空炉生产实际,以16炉H-OLTB转炉工艺试验为样本,通过取样、夹杂物扫描电镜和数据分析等手段,对冶炼IF钢时自由脱碳模式和强制脱碳模式的终点碳含量、脱碳时间、顶渣、夹...为了提高IF钢的洁净度及可浇性,结合邯钢公司邯宝炼钢厂260 t RH真空炉生产实际,以16炉H-OLTB转炉工艺试验为样本,通过取样、夹杂物扫描电镜和数据分析等手段,对冶炼IF钢时自由脱碳模式和强制脱碳模式的终点碳含量、脱碳时间、顶渣、夹杂物数量和尺寸进行了研究,以RH精炼结束时顶渣T.Fe和T[O]的质量分数以及夹杂物数量和尺寸为依据,统计分析不同脱碳模式对顶渣氧化性和钢水洁净度的影响。研究表明,自由脱碳模式在脱碳时间和终点碳含量方面优于强制脱碳模式,自由脱碳模式平均缩短脱碳时间约3.15 min;强制脱碳模式顶渣T.Fe和FeO质量分数均低于自由脱碳模式,强制脱碳模式w[T.Fe]、w[FeO]分别为5.68%、5.45%,自由脱碳模式w[T.Fe]、w[FeO]分别为7.26%、6.84%;强制脱碳模式下的IF钢水夹杂物数量更少,自由脱碳模式和强制脱碳模式单位面积内尺寸在15μm以下的夹杂物数量分别为16.2~23.4个和10.6~14.4个。综合来看,建议H-OLTB转炉将RH炉进站初始氧含量控制在(286~408)×10^(-6),RH精炼炉冶炼IF钢采用强制脱碳模式,钢水洁净度更高。展开更多
基金supported by the Major Research Projects of the National Social Science Fund of China(NSFC,Grant no.23VHQ015).
文摘The accelerated decline of Arctic sea ice since the 1980s has paradoxically amplified greenhouse gas(GHG)emissions through increased shipping activities in this ecologically vulnerable region.This study investigates how to reconcile the decarbonization of Arctic shipping with conflicting environmental,economic,and geopolitical interests.Through systematic literature review and interest-balancing analysis,our findings identify three systemic barriers:(1)inadequate adaptation of International Maritime Organization(IMO)regulations to Arctic-specific environmental risks,(2)fragmented enforcement mechanisms among Arctic and non-Arctic States,and(3)technological limitations in clean fuel adoption for ice-class vessels.To address these challenges,a tripartite governance framework is proposed.First,legally binding amendments to International Convention for the Prevention of Pollution from Ships(MARPOL)Annex VI introducing Arctic-specific Energy Efficiency eXisting ship Index(EEXI)standards and extending energy efficiency regulations to fishing vessels.Second,a phased fuel transition prioritizing liquefied natural gas(LNG)and methanol,followed by hydrogen-ammonia synthetics.Third,enhanced multilateral cooperation through an Arctic Climate Shipping Alliance to coordinate joint research and development in cold-adapted technologies and ice-route optimization.By integrating United Nations Convention on the Law of the Sea(UNCLOS)obligations with IMO Polar Code implementation,this study advances a dynamic interest-balancing framework for policymakers,offering actionable pathways to achieve Paris Agreement targets while safeguarding Arctic ecosystems.
基金supported by the National Natural Science Foundation of China(52270043)the National Key Research and Development Program of China(2023YFE0113800 and 2024YFC3715000)the Natural Science Foundation of Beijing Municipality(8242030).
文摘The contamination of wastewater with organic pollutants and nitrogen compounds poses significant environmental challenges.The primary objective of wastewater treatment is the simultaneous denitrification and decarbonization of ammonia nitrogen and organics into harmless by-products.This study presents a novel method for the directional generation of chlorine radical species like·ClO and·Cl using electro-reactive membranes(EMs)known as RuO_(2)@PbO_(2)-M,which were fabricated using an electro-deposition coupled template approach.This method facilitates the rapid and efficient conversion of ammonia to nitrogen and concurrently reduces the chemical oxygen demand in the effluent.Our system achieved ultra-efficient simultaneous denitrification and decarbonization with minimal energy consumption in single-filtration mode,thereby eliminating the need for chemical precursors.We elucidate the formation pathway of·ClO and·Cl during the electrochemical oxidation process involving RuO_(2)@PbO_(2)-M,where·Cl generated from RuO_(2)reacts with·OH from PbO_(2)under hypochlorous acid conditions,thereby enhancing nitrogen and carbon removal.These findings highlight a novel electro-filtration and an innovative reactive membrane design for·ClO synthesis,which provides a new research framework for the concurrent removal of nitrogen and carbon,and offers a promising solution to enhance wastewater treatment efficiency.
基金supported by the Chengdu Philosophy and Social Science Planning Project[Grant No.2022C05]National Natural Science Foundation of China[Grant No.71904158].
文摘Developing low-carbon and efficient power systems is critical for energy security in the global warming context.We address this issue by focusing on the productivity impact of a decarbonization policy in China’s thermal power sector—namely,the“Constructing Large Units and Restricting Small Ones”(CLRS)initiative.Utilizing a resource misallocation model,we construct a new theoretical framework to distinguish between technical and allocative efficiency and analyze productivity using plant-level data.The results indicate that the CLRS policy has significantly improved the allocative and technical efficiency of China’s coal-fired power sector,thereby ensuring power security.The closure of outdated and highly distorted small coal-fired units,which have been replaced by technologically advanced large units,primarily drives the enhanced efficiency.The policy’s effects are most pronounced in large-scale power plants and those with high coal combustion efficiency.Furthermore,a comparison of power plants’productivity distribution before and after policy implementation reveals that the CLRS policy not only enhances capital productivity in the coal-fired power sector but also increases rational labor allocation.Our findings have important policy implications for developing countries vis-à-vis building efficient and stable power systems amid climate change.
基金supported by the Helmholtz Association within the framework of the innovation platform“Solar TAP”[Az:714-62150-3/1(2023)]co-funded by the European Union(ERC,C2C-PV,project number 101088359)。
文摘This study investigates the disparities in the deployment of photovoltaic(PV)technology for carbon emissions reduction across different nations,highlighting the mismatch between countries with high economic capacity and those where PV installation would maximize global decarbonization benefits.This mismatch is discussed based on three key factors influencing decarbonization via PV technology:per capita gross domestic product;carbon intensity of the energy system;and solar resource availability.Current PV deployment is predominantly concentrated in economically advanced countries,and does not coincide with regions where the environmental and economic impact of such installations would be most significant.Through a series of thought experiments,it is demonstrated how alternative prioritization strategies could significantly reduce global carbon emissions.Argument is put forward for a globally coordinated approach to PV deployment,particularly targeting high-impact sunbelt regions,to enhance the efficacy of decarbonization efforts and promote equitable energy access.The study underscores the need for international policies that support sustainable energy transitions in economically less developed regions through workforce development and assistance with the activation of capital.
基金supported by European Commission and is a part of the HORIZON2020 project RES Heatfunding from the European Union’s Horizon 2020 program in the field of research and innovation on the basis of grant agreement No.956255.
文摘Decarbonising the building sector,particularly residential heating,represents a critical challenge for achieving carbon-neutral energy systems.Efficient solutions must integrate both technological performance and renewable energy sources while considering operational constraints of existing systems.This study investigates a hybrid heating system combining a natural gas boiler(NGB)with an air-to-water heat pump(AWHP),evaluated through a combination of laboratory experiments and dynamic modelling.A prototype developed in the Electrical and Energy Engineering Laboratory enabled the characterization of both heat generators,the collection of experimental data,and the calibration of a MATLAB/Simulink model,including emissions and exhaust analyses.Sensitivity analyses were performed to identify optimal configurations for energy efficiency and system control,accounting for interactions between subsystems.Results highlight that hybridisation significantly improves primary energy efficiency and reduces fuel consumption compared to conventional NGB-only systems.Environmental performance,assessed through CO_(2) and NOx emissions and renewable energy integration,demonstrates the benefits of partial electrification in the residential sector.Economic assessment further quantifies decarbonization costs and fuel savings,illustrating tradeoffs between low-capital,moderate-performance systems and high-efficiency,high-renewable solutions requiring larger investments.The analysis shows that strategic decisions for residential decarbonisation cannot be separated from system-wide considerations,including control strategies,component integration,and economic feasibility.The study underlines the importance of hybrid and renewable-based solutions as pivotal pathways for energy transition in the residential building sector.
文摘A crystalline sapphire （Al2O3） boule （Ф10 × 80mm^3） grown by the temperature gradient technique （TGT） is a bit colored due to carbon volatilization from the graphite heater at high temperatures and the absorption of transitional metal inclusions in the raw material. The sapphire becomes colorless and transparent after decolorization and decarbonization in successive annealings in air and hydrogen at high temperatures. The quality, optical transmissivity,and homogeneity of the sapphire are remarkably improved.
基金provided by the National Natural Science Foundation of China(No.51274200)Research Fund for the Doctoral Program of Higher Education of China(No.20130095110010)
文摘On the basis of understanding the principle of rotary triboelectrostatic separation, dynamic analysis of charged fly ash particles aimed at determining the key factors and separation experiments to improve decarbonization efficiency had been carried out Variables of electrode plate voltage and corrected wind speed are the key factors which affect the decarbonization efficiency on the separation of fly ash, The results of separation experiments show that:(1) With the plate voltage increasing, the efficiency of decarbonization continuously rises and in its selected range, the optimal voltage level is 45 KV;(2) The corrected wind speed can impact the efficiency of decarbonization significantly: with the speed increasing, the efficiency of decarbonization shows a trend of first decline, then increase and decrease again, and in its selected range, the optimal speed is 2.0 m/s. This study is of significance for the improvement of rotary triboelectrostatic separation performance and its decarbonization separation efficiency.
基金supported by the National Natural Science Foundation of China(Nos.51274200 and 51221462)
文摘The basic principle of fly ash triboelectrification is analysed. The mineral electrical index and test method are introduced. The electric difference of different mineral composition of fly ash is discussed by analysis of chemical and mineral composition of fly ash in Xinwen power plant. The dielectric constant and charge-mass ratio of carbon and ash of fly ash are tested. Combined with the experimental study on rotary triboelectrostatic separation, the charged characteristic of fly ash particles with different size is gained. The results show that the dielectric constant of fly ash with different grain size decreased with the decrease of particle size, which lead to the poor electrical conductivity, Thus it can be seen that par- ticle size plays a leading role in conductivity, The charge of carbon and ash with each size increased with the decreased of particle size; and the charge-mass ratio between carbon and ash with the same size lar- ger with the decrease of size, which indicated that the finer particle size, the more favorable for triboelec- trification separation. In the same conditions, the best decarburization effect is realized when the particle size ranges from 0.038 to 0.074 ram, whose decarbonization rate and efficiency index reached 38.93% and 120.83% respectively.
基金supported by the National Science Foundation of China(Grant No.41701232).
文摘Climate change is becoming an important issue in all fields of infrastructure development.Electricity plays a core role in the decarbonized energy system’s path to a regional zero-emission pattern.A well-built trans-Mediterranean backbone grid can hedge the profound evolution of regional power generation,transmission,and consumption.To date,only Turkey and the Maghreb countries(i.e.,Morocco,Algeria,and Tunisia)are connected with the Continental European Synchronous Area.Other south-and east-shore countries have insufficient interconnection infrastructures and synchronization difficulties that have proven to be major hurdles to the implementation of large-scale solar and wind projects and achievement of climate goals.This study analyzes the current trans-boundary grid interconnections and power and carbon emission portfolios in the Mediterranean region.To align with the recently launched new climate target‘Fit for 55’program and the accelerated large-scale renewables target,a holistic review of projected trans-Mediterranean grids and their market,technical,and financial obstacles of implementation was conducted.For south-and east-shore countries,major legal and regulatory barriers encompassing non-liberalized market structure,regulation gaps of taxation and transmission tariffs,and the private sector’s access rights need to be removed.Enhancement of domestic grids,substations,and harmonized grid codes and frequency,voltage,and communication technology standards among all trans-Mediterranean countries are physical prerequisites for implementing the Trans-Mediterranean Electricity Market.In addition,the mobilization of capital instruments along with private and international investments is indispensable for the realization of supranational transmission projects.As the final section of the decarbonization roadmap,the development of electric appliances,equipment,and vehicles with higher efficiency is inevitable in the decarbonized building,transportation,and industry sectors.
基金supported by the State Key Laboratory of Advanced Metallurgy,China(Project Code:41603006).
文摘Decarbonization is a critical issue for peaking CO_(2) emissions of energy-intensive industries,such as the iron and steel industry.The decarbonization options of China’s ironmaking and steelmaking sector were discussed based on a systematic three-dimensional low-carbon analysis from the aspects of resource utilization(Y),energy utilization(Q),and energy cleanliness which is evaluated by a process general emission factor(PGEF)on all the related processes,including the current blast furnace(BF)-basic oxygen furnace(BOF)integrated process and the specific sub-processes,as well as the electric arc furnace(EAF)process,typical direct reduction(DR)process,and smelting reduction(SR)process.The study indicates that the three-dimensional aspects,particularly the energy structure,should be comprehensively considered to quantitatively evaluate the decarbonization road map based on novel technologies or processes.Promoting scrap utilization(improvement of Y)and the substitution of carbon-based energy(improvement of PGEF)in particular is critical.In terms of process scale,promoting the development of the scrap-based EAF or DR-EAF process is highly encouraged because of their lower PGEF.The three-dimensional method is expected to extend to other processes or industries,such as the cement production and thermal electricity generation industries.
文摘Yanbei project of Schlumberger Copower Oilfield Engineering Co.,Ltd.-natural gas purification plant decarbonization unit is equipped with two sets of decarbonization systems(parallel operation).The two sets of systems adopt two tower process,full lean liquid circulation regeneration process,one tower absorption(absorption pressure 5.4mpag),one tower regeneration(regeneration temperature 95℃-110℃),purified natural gas carbon dioxide content≤2.5vol%,single set The treatment capacity is 2300 KM3/d.This paper introduces the problems existing in the decarbonization solution of the decarbonization unit in the natural gas purification plant in recent three years,analyzes the causes of pollutants affecting the quality of the decarbonization solution,and probes into the control measures for the pollution of the decarbonization solution,so as to provide reference.
文摘This study addresses the critical need for decarbonization in offshore marine logistics by developing an integrated modeling framework to support low-emission operations across complex,multi-echelon vessel networks.It focuses on port-to-platform supply chains serving offshore wind farms,oil rigs,and floating logistics hubs.A hybrid analytical approach was adopted,combining Mixed-Integer Linear Programming(MILP)for optimizing emission-minimizing routing,Discrete-Event Simulation(DES)to evaluate offshore scheduling performance under variability,and a Multi-Criteria Decision Analysis(MCDA)model using AHP-TOPSIS to rank alternative marine fuel types.Monte Carlo simulation was also employed to assess cost and delivery fluctuations across uncertain operational scenarios.Data inputs were compiled from real-world offshore fleet specifications,port emissions records,and marine fuel technology benchmarks.MILP-based network flow optimization reduced CO₂emissions by 22%while maintaining service reliability across all demand points.DES simulations revealed congestion-driven scheduling delays during peak vessel utilization.MCDA analysis ranked bio-LNG and hydrogen propulsion systems as optimal choices based on emission,cost,and availability trade-offs.Hypothesis testing confirmed significant relationships between fuel type,network structure,and emission performance.The study demonstrates how multi-echelon logistics planning,integrated with emissions-based modeling,can facilitate environmentally responsible marine supply chain design.The framework offers practical guidance for offshore fleet managers,port authorities,and policy regulators aiming to align operational efficiency with decarbonization objectives under IMO and EU directives.
文摘Discussions about the future of energy sources and environmental sustainability are becoming critical on a global scale.The energy sector plays a central role in the economy,as the availability and cost of energy influence the competitiveness of economies,while the level of energy consumption impacts the standard of living for individuals.This paper aims to examine environmental challenges and steps for a sustainable transition towards a hydrogen economy,focusing on its potential as an alternative to fossil fuels and the importance of developing the hydrogen paradigm.The research methodology is based on a combination of qualitative and quantitative methods,including an analysis of global and regional trends in the energy transition,the impact of various forms of hydrogen production(green,blue,gray hydrogen)on greenhouse gas emissions,and a comparison of existing policies and strategies in different countries transitioning to a sustainable hydrogen economy.Research results show that green hydrogen,produced via electrolysis using renewable energy sources,holds the greatest potential for reducing greenhouse gas emissions,while gray and blue hydrogen can serve as transitional options.The development of the hydrogen paradigm,rooted in innovative technologies,renewable energy sources,and international cooperation,is crucial for decarbonization and the creation of a sustainable global economy,despite challenges such as high costs and the need for global coordination.The hydrogen paradigm is becoming a cornerstone of these efforts,laying the foundation for a long-term,sustainable global economy.Currently,over 180 hydrogen transport projects,60 distribution projects,80 storage projects,30 terminal and port projects,and more than 220 hydrogen production projects are under development worldwide.The global momentum of the hydrogen transition helps mitigate climate change and build a sustainable future.
文摘为了提高IF钢的洁净度及可浇性,结合邯钢公司邯宝炼钢厂260 t RH真空炉生产实际,以16炉H-OLTB转炉工艺试验为样本,通过取样、夹杂物扫描电镜和数据分析等手段,对冶炼IF钢时自由脱碳模式和强制脱碳模式的终点碳含量、脱碳时间、顶渣、夹杂物数量和尺寸进行了研究,以RH精炼结束时顶渣T.Fe和T[O]的质量分数以及夹杂物数量和尺寸为依据,统计分析不同脱碳模式对顶渣氧化性和钢水洁净度的影响。研究表明,自由脱碳模式在脱碳时间和终点碳含量方面优于强制脱碳模式,自由脱碳模式平均缩短脱碳时间约3.15 min;强制脱碳模式顶渣T.Fe和FeO质量分数均低于自由脱碳模式,强制脱碳模式w[T.Fe]、w[FeO]分别为5.68%、5.45%,自由脱碳模式w[T.Fe]、w[FeO]分别为7.26%、6.84%;强制脱碳模式下的IF钢水夹杂物数量更少,自由脱碳模式和强制脱碳模式单位面积内尺寸在15μm以下的夹杂物数量分别为16.2~23.4个和10.6~14.4个。综合来看,建议H-OLTB转炉将RH炉进站初始氧含量控制在(286~408)×10^(-6),RH精炼炉冶炼IF钢采用强制脱碳模式,钢水洁净度更高。
