Reductive soil disinfestation(RSD)is commonly employed for soil remediation in greenhouse cultivation.However,its influence on antibiotic resistance genes(ARGs)in soil remains uncertain.This study investigated the dyn...Reductive soil disinfestation(RSD)is commonly employed for soil remediation in greenhouse cultivation.However,its influence on antibiotic resistance genes(ARGs)in soil remains uncertain.This study investigated the dynamic changes in soil communities,potential bacterial pathogens,and ARG profiles under various organicmaterial treatments during RSD,including distillers’grains,potato peel,peanut vine,and peanut vine combined with charcoal.Results revealed that applying diverse organic materials in RSD significantly altered bacterial community composition and diminished the relative abundance of potential bacterial pathogens(P<0.05).The relative abundance of high-risk ARGs decreased by 10.7%-30.6%after RSD treatments,the main decreased ARG subtypeswere AAC(3)_Via,dfrA1,ErmB,lnuB,aadA.Actinobacteria was the primary host of ARGs and was suppressed by RSD.Soil physicochemical properties,such as total nitrogen,soil pH,total carbon,were crucial factors affecting ARG profiles.Our findings demonstrated that RSD treatment inhibited pathogenic bacteria and could be an option for reducing high-risk ARG proliferation in soil.展开更多
The Early Cambrian Yuertusi Formation(Є_(1)y)in the Tarim Basin of China deposits a continuously developed suite of organic-rich black mudstones,which constitute an important source of oil and gas reservoirs in the Pa...The Early Cambrian Yuertusi Formation(Є_(1)y)in the Tarim Basin of China deposits a continuously developed suite of organic-rich black mudstones,which constitute an important source of oil and gas reservoirs in the Paleozoic.However,its hydrocarbon generation and evolution characteristics and resource potential have long been constrained by deeply buried strata and previous research.In this paper,based on the newly obtained ultra-deep well drilling data,the hydrocarbon generation and expulsion model ofЄ_(1)y shale was established by using data-driven Monte Carlo simulation,upon which the hydrocarbon generation,expulsion,and retention amounts were calculated by using the diagenetic method.The research indicates that theЄ_(1)y shale reaches the hydrocarbon generation and expulsion threshold at equivalent vitrinite reflectances of 0.46%and 0.72%,respectively.The cumulative hydrocarbon generation is 68.88×10^(10)t,the cumulative hydrocarbon expulsion is 35.59×10^(10)t,and the cumulative residual hydrocarbon is 33.29×10^(10)t.This paper systematically and quantitatively calculates the hydrocarbon expulsion at various key geological periods for theЄ_(1)y source rocks in the study area for the first time,more precisely confirming that the black shale of theЄ_(1)y is the most significant source rock contributing to the marine oil and gas resources in the Tarim Basin,filling the gap in hydrocarbon expulsion calculation in the study area,and providing an important basis for the formation and distribution of Paleozoic hydrocarbon reservoirs.The prospect of deep ultra-deep oil and gas exploration in the Tarim Basin is promising.Especially,the large area of dolomite reservoirs under the Cambrian salt and source rock interiors are the key breakthrough targets for the next exploration in the Tarim Basin.展开更多
The toxicity of PM_(2.5)does not necessarily change synchronously with its mass concentration.In this study,the chemical composition(carbonaceous species,water-soluble ions,and metals)and oxidative potential(dithiothr...The toxicity of PM_(2.5)does not necessarily change synchronously with its mass concentration.In this study,the chemical composition(carbonaceous species,water-soluble ions,and metals)and oxidative potential(dithiothreitol assay,DTT)of PM_(2.5)were investigated in 2017/2018 and 2022 in Xiamen,China.The decrease rate of volume-normalized DTT(DTTv)(38%)was lower than that of PM_(2.5)(55%)between the two sampling periods.However,the mass-normalized DTT(DTTm)increased by 44%.Clear seasonal patterns with higher levels in winter were found for PM_(2.5),most chemical constituents and DTTv but not for DTTm.The large decrease in DTT activity(84%−92%)after the addition of EDTA suggested that watersoluble metals were the main contributors to DTT in Xiamen.The increased gap between the reconstructed and measured DTTv and the stronger correlations between the reconstructed/measured DTT ratio and carbonaceous species in 2022were observed.The decrease rates of the hazard index(32.5%)and lifetime cancer risk(9.1%)differed from those of PM_(2.5)and DTTv due to their different main contributors.The PMF-MLR model showed that the contributions(nmol/(min·m^(3)))of vehicle emission,coal+biomass burning,ship emission and secondary aerosol to DTTv in 2022 decreased by 63.0%,65.2%,66.5%,and 22.2%,respectively,compared to those in 2017/2018,which was consistent with the emission reduction of vehicle exhaust and coal consumption,the adoption of low-sulfur fuel oil used on board ships and the reduced production of WSOC.However,the contributions of dust+sea salt and industrial emission increased.展开更多
Rationally regulating the porosity of hard carbon(HC),especially the closed pores matching the low potential plateau and the ultra-microporous structure suitable for Na+embedding,has been shown to be the key to improv...Rationally regulating the porosity of hard carbon(HC),especially the closed pores matching the low potential plateau and the ultra-microporous structure suitable for Na+embedding,has been shown to be the key to improving the sodium storage performance and initial coulombic efficiency(ICE).However,the preparation of such HC materials with specific pore structures still faces great challenges.Herein,a simple pre-oxidation strategy is employed to construct abundant closed ultra-microporous structures in soy protein powder-derived HC material,achieving a significant improvement in its ICE and platform capacity.The pre-oxidation process promotes the cross-linking degree of the soy protein,thereby hindering the directional growth of graphite domains during the carbonization process.The optimized HC exhibits ultra-high platform capacity(329 mAh g^(-1))and considerable energy density(148.5 Wh kg^(-1)).Based on the ex-situ Raman and X-ray photoelectron spectroscopy characterization results,the excellent sodium storage capacity of the HC material is attributed to the synergistic effect of adsorption-intercalation/filling.The presented work provides novel insights into the synthesis of other biomass-derived HC materials with abundant closed ultra-micro pores.展开更多
Due to advantages of high power-conversion efficiency(PCE), large power-to-weight ratio(PWR), low cost and solution processibility, flexible perovskite solar cells(f-PSCs) have attracted extensive attention in recent ...Due to advantages of high power-conversion efficiency(PCE), large power-to-weight ratio(PWR), low cost and solution processibility, flexible perovskite solar cells(f-PSCs) have attracted extensive attention in recent years. The PCE of f-PSCs has developed rapidly to over 25%, showing great application prospects in aerospace and wearable electronic devices. This review systematically sorts device structures and compositions of f-PSCs, summarizes various methods to improve its efficiency and stability recent years. In addition, the applications and potentials of f-PSCs in space vehicle and aircraft was discussed. At last, we prospect the key scientific and technological issues that need to be addressed for f-PSCs at current stage.展开更多
Sodium-ion batteries (SIBs) with organic electrodes are an emerging research direction due to the sustainability of organic materials based on elements like C,H,O,and sodium ions.Currently,organic electrode materials ...Sodium-ion batteries (SIBs) with organic electrodes are an emerging research direction due to the sustainability of organic materials based on elements like C,H,O,and sodium ions.Currently,organic electrode materials for SIBs are mainly used as cathodes because of their relatively high redox potentials(>1 V).Organic electrodes with low redox potential that can be used as anode are rare.Herein,a novel organic anode material (tetrasodium 1,4,5,8-naphthalenetetracarboxylate,Na_(4)TDC) has been developed with low redox potential (<0.7 V) and excellent cyclic stability.Its three-sodium storage mechanism was demonstrated with various in-situ/ex-situ spectroscopy and theoretical calculations,showing a high capacity of 208 mAh/g and an average decay rate of merely 0.022%per cycle.Moreover,the Na_(4)TDC-hard carbon composite can further acquire improved capacity and cycling stability for 1200 cycles even with a high mass loading of up to 20 mg cm^(-2).By pairing with a thick Na_(3)V_(2)(PO_(4))_(3)cathode (20.6 mg cm^(-2)),the as-fabricated full cell exhibited high operating voltage (2.8 V),excellent rate performance and cycling stability with a high capacity retention of 88.7% after 200 cycles,well highlighting the Na_(4)TDC anode material for SIBs.展开更多
With the rapid economic development and continuous expansion of human activities,forest degradation—characterized by reduced forest stock within the forest including declining carbon storage—poses significant threat...With the rapid economic development and continuous expansion of human activities,forest degradation—characterized by reduced forest stock within the forest including declining carbon storage—poses significant threats to ecosystem stability.Understanding the current status of forest degradation and assessing potential carbon stocks in China are of strategic importance for making forest restoration efforts and enhancing carbon sequestration capacity.In this study,we used the national forest inventory data from 2009 to 2018 to develop a set of standard measures for assessing degraded forests across China,based on five key indicators:forest accumulation growth rate(FAGR),forest recruitment rate(FRR),tree species reduction rate(TSRR),forest canopy cover reduction rate(FCCRR),and forest disaster level(FDL).Additionally,we estimated standing carbon stock,potential carbon stock,and theoretical space to grow by developing a stand growth model,which accounts for stand density across different site classes,to evaluate the restoration potential of degraded forests.The results indicate that degraded forest area in China is 36.15 million hectares,accounting for 20.10% of a total forest area.Standing carbon stock and potential carbon stock of degraded forests in China are 23.93 million tons and 61.90 million tons,respectively.Overall,degraded forest varies significantly across different regions.The results highlight the important trade-offs among environmental factors,policy decisions,and forest conditions,providing a robust foundation for developing measures to enhance forest quality.展开更多
The local structure and thermophysical behavior of Mg-La liquid alloys were in-depth understood using deep potential molecular dynamic(DPMD) simulation driven via machine learning to promote the development of Mg-La a...The local structure and thermophysical behavior of Mg-La liquid alloys were in-depth understood using deep potential molecular dynamic(DPMD) simulation driven via machine learning to promote the development of Mg-La alloys. The robustness of the trained deep potential(DP) model was thoroughly evaluated through several aspects, including root-mean-square errors(RMSEs), energy and force data, and structural information comparison results;the results indicate the carefully trained DP model is reliable. The component and temperature dependence of the local structure in the Mg-La liquid alloy was analyzed. The effect of Mg content in the system on the first coordination shell of the atomic pairs is the same as that of temperature. The pre-peak demonstrated in the structure factor indicates the presence of a medium-range ordered structure in the Mg-La liquid alloy, which is particularly pronounced in the 80at% Mg system and disappears at elevated temperatures. The density, self-diffusion coefficient, and shear viscosity for the Mg-La liquid alloy were predicted via DPMD simulation, the evolution patterns with Mg content and temperature were subsequently discussed, and a database was established accordingly. Finally, the mixing enthalpy and elemental activity of the Mg-La liquid alloy at 1200 K were reliably evaluated,which provides new guidance for related studies.展开更多
The word “senescence” comes from the Latin senescens, meaning “to begin to age”, and is characterized by a long-lasting but reversible block in proliferation, resulting from stress-induced cell cycle arrest of pre...The word “senescence” comes from the Latin senescens, meaning “to begin to age”, and is characterized by a long-lasting but reversible block in proliferation, resulting from stress-induced cell cycle arrest of previously replication-competent cells.展开更多
In this paper,we mainly focus on a type of nonlinear Choquard equations with nonconstant potential.Under appropriate hypotheses on potential function and nonlinear terms,we prove that the above Choquard equation with ...In this paper,we mainly focus on a type of nonlinear Choquard equations with nonconstant potential.Under appropriate hypotheses on potential function and nonlinear terms,we prove that the above Choquard equation with prescribed 2-norm has some normalized solutions by introducing variational methods.展开更多
For the magnetized complex plasma,dependences of modified Yukawa potential on the gov-erning parameters,viz.,mass ratio md/mi,number ratio nd/ne0,charge magnitude Q/e,and temperature ratio Te/Ti are investigated.It is...For the magnetized complex plasma,dependences of modified Yukawa potential on the gov-erning parameters,viz.,mass ratio md/mi,number ratio nd/ne0,charge magnitude Q/e,and temperature ratio Te/Ti are investigated.It is found that md/mi,nd/ne0 and Q/e contribute to the coupling strength of the system,and Te/Ti contributes to the shielding cloud surrounding the charged dust particles.Further analysis shows that the modified Yukawa potential depends on Te/Ti.The consequent structure changes of the system are discussed based on the Langevin dynamics simulation.It is found that the variation of Ham-iltonian contributes to the equilibrium structure of the system.展开更多
Dinosaur discoveries from India have been known since 1844, while dinosaur discoveries from Pakistan have appeared recently since 2000. 3 large and 2 small theropod dinosaurs are known from Pakistan, while 11 large an...Dinosaur discoveries from India have been known since 1844, while dinosaur discoveries from Pakistan have appeared recently since 2000. 3 large and 2 small theropod dinosaurs are known from Pakistan, while 11 large and 4 small theropods are known from India. Pakistani land uncovered many footprints and trackways of Jurassic small and large theropods, Jurassic ankylosaur and Cretaceous hadrosaur ornithischian dinosaurs, while Indian land uncovered a footprint of small and a footprint of large theropod and 1 footprint of stegosaur. Pakistan uncovered a Jurassic bone taxon of ankylosaur ornithischian based on heavily armored synapomorphies. Recently, Pakistan yielded 1 bone taxon and 1 ichno taxon of pterosaurs, while Indian land yielded 1 bone taxon of pterosaur. Pakistani land uncovered 14 bone taxa (and 2 ichno taxa) of herbivorous sauropod dinosaurs, 5 bone taxa (and 2 ichnotaxa) of carnivorous theropod dinosaurs, 1 bone taxon of ankylosaur and 2 (ichnotaxa) of ornithischian (ankylosaur and hadrosaurs) dinosaurs, 1 bone taxon (and 1 ichno taxon) of pterosaurs, 1 plesiosaur, 7 crocodiles, 1 snake, 1 bird, 11 mammals, 3 fishes, 7 invertebrates and 1 plant. This study fills a significant gap in the literature by bringing together paleontological records from an understudied geographical location, enhancing the global understanding of dinosaur paleobiogeography. Pakistan hosts Precambrian to recent sediments igneous and metamorphic rocks. Pakistan is rich in mineral resources/rocks, but it needs more attention for its development to fulfill local requirements and earn foreign exchange.展开更多
By extending the concept of diffusion to the potential energy landscapes(PELs), we introduce the meansquared energy difference(MSED) as a novel quantity to investigate the intrinsic properties of supercooled liquids. ...By extending the concept of diffusion to the potential energy landscapes(PELs), we introduce the meansquared energy difference(MSED) as a novel quantity to investigate the intrinsic properties of supercooled liquids. MSED can provide a clear description of the “energy relaxation” process on a PEL. Through MSED analysis, we have obtained a characteristic time similar to that derived from structure analysis, namely τ_(α)^(*).Further, we establish a connection between MSED and the feature of PELs, providing a concise and quantitative description of PELs. The relaxation behavior of energy has been found to follow a stretched exponential form.As the temperature decreases, the roughness of the accessible PEL changes significantly around a characteristic temperature T_(x), which is 20% higher than the glass transition temperature T_(g) and is comparable to the critical temperature of the mode-coupling theory. More importantly, one of the PEL parameters is closely related to the Adam–Gibbs configurational entropy. The present research, which directly links the PEL to the relaxation process, provides avenues for further research of glasses.展开更多
Chronic pain,characterized by pain lasting for more than three months,is a debilitating condition frequently caused by conditions such as fibromyalgia,arthritis,neuropathy,and migraine[1-3].
In a recent article, we have corrected the traditional derivation of the Schwarzschild metric, thus obtaining the formulation of the correct Schwarzschild metric, which is different from the traditional Schwarzschild ...In a recent article, we have corrected the traditional derivation of the Schwarzschild metric, thus obtaining the formulation of the correct Schwarzschild metric, which is different from the traditional Schwarzschild metric. Then, in another article by starting from this correct Schwarzschild metric, we have corrected also the Reissner-Nordstrøm, Kerr and Kerr-Newman metrics. On the other hand, in a third article, always by starting from this correct Schwarzschild metric, we have obtained the formulas of the correct gravitational potential and of the correct gravitational force in the case described by this metric. Now, in this article, by starting from these correct Reissner-Nordstrøm, Kerr and Kerr-Newman metrics and proceeding in a manner analogous to this third article, we obtain the formulas of the correct gravitational potential and of the correct gravitational force in the cases described by these metrics. Moreover, we analyze these correct results and their consequences. Finally, we propose some possible crucial experiments between the commonly accepted theory and the same theory corrected according to this article.展开更多
Cropland suitability analysis is a vital tool for ensuring food security and sustainable agriculture,coordinating ecological space with human activity space on the Qinghai-Tibet Plateau(QTP).However,there are few stud...Cropland suitability analysis is a vital tool for ensuring food security and sustainable agriculture,coordinating ecological space with human activity space on the Qinghai-Tibet Plateau(QTP).However,there are few studies on complete and accurate cropland suitability assessments on the QTP,let alone on identifying key potential areas for cropland development.We used a novel assessment model to generate a 30-m cropland suitability map for the QTP.The identification of areas with cropland development potential and the evaluation of potentially available cropland were further integrated into a unified analytical framework.We found that only 10.18%of the study area is suitable for large-scale and permanent cropland.Moreover,approximately 72.75%of the existing cropland was found to be distributed in suitable or marginally suitable areas.Considering the trade-offs related to irrigation water supply convenience,approximately 1.07%of the study area was identified as having high potential for cropland development.Four key potential areas were further identified:the Shannan Valley,the Nyingchi Valley,the Zanda Valley,and the Gonghe Basin.These areas boast abundant potentially available cropland resources and ecological resettlement capacities,which leads us to recommend strategic priorities for comprehensive land consolidation and water development.This study has practical significance for optimizing land resource allocation and guiding decision-making related to ecological migration on the QTP.展开更多
Global exhibitors tap China’s dynamic market for ideas,growth and resilience China will continue to seek high-quality growth and unswervingly promote high-standard opening up,making new contributions to the world eco...Global exhibitors tap China’s dynamic market for ideas,growth and resilience China will continue to seek high-quality growth and unswervingly promote high-standard opening up,making new contributions to the world economy.Chinese Premier Li Qiang made the remark at the opening ceremony of the eighth China International Import Expo(CIIE)and the Hongqiao International Economic Forum in Shanghai on 5 November.展开更多
Green roofs play a vital role in promoting sustainable urban development and achieving carbon neutrality by enhancing carbon sequestration, oxygen release, and efficiency of land use. Despite these benefits, living ro...Green roofs play a vital role in promoting sustainable urban development and achieving carbon neutrality by enhancing carbon sequestration, oxygen release, and efficiency of land use. Despite these benefits, living roof coverage in China remains limited. To address the challenges in policy formulation, operational monitoring, and the absence of multi-scale retrofit strategies supported by robust assessment methods, this study develops a comprehensive evaluation framework. The framework integrates vector data, building age information, and point-of-interest(POI) data, and applies an optimized Prophet model to classify six major climate zones. This approach facilitates the selection of appropriate plant species and substrates while quantifying the potential for carbon sequestration and oxygen release. An assessment of 90 cities reveals approximately 1.3861 billion square meters of rooftop area suitable for green roof implementation, with an estimated annual carbon sequestration potential of 67.30 million tons and oxygen release of 30.36 million tons. Commercial buildings contribute significantly, comprising 65% of the total suitable area. Climate zones 2 and 3 exhibit the most favorable outcomes. The current study provides a reliable quantitative reference for evaluating the carbon sequestration and oxygen release capacities of green roofs and supports the formulation of effective retrofit policies.展开更多
A substantial body of research has been conducted with the objective of enhancing the understanding of Non-Timber Forest Products (NTFP) in Central Africa. A significant proportion of the studies focus on medicinal pl...A substantial body of research has been conducted with the objective of enhancing the understanding of Non-Timber Forest Products (NTFP) in Central Africa. A significant proportion of the studies focus on medicinal plants, in contrast to those that examine food products. Nevertheless, studies on edible wild mushrooms as NTFPs and cultivated mushrooms, on their economic potential and value chains in the Great Lakes Region, remain scarce and largely absent for some NTFPs. In light of the aforementioned considerations, the present study aims to examine the economic potential and value chain of the production sector of wild edible mushrooms (WEM) and cultivated mushrooms (CM) within the Virunga National Park (PNVi) and its surrounding areas in North Kivu, Democratic Republic of the Congo (DRC). To this end, a sample of 432 respondents was selected, distributed equitably among the actors of the Goma-Kitshanga-Mweso value chain, the Goma-Rutshuru chain, the Beni-Mutwanga chain, and the Beni-Mangina chain. A digital questionnaire consisting of open and closed questions was administered, and observations were carried out concurrently. The quantities of mushrooms sold were weighed and photographed. The results demonstrated that, when the eight-month fruiting period of wild and cultivated mushrooms was considered as a single year for all actors within the value chain, a picker could sell 6.1 kg at $2 and earn $12. A seller could sell 16 kg at $4 and earn $64, while a grower could sell 502 kg at $3 and earn $1506. Consequently, the CM grower generates a significantly higher profit than other participants in the value chain, despite the expenses he incurs. Ultimately, the domestication of WEM, highly prized by the local population of the Virunga National Park, has the potential to enhance their household incomes, as evidenced by the findings of this study.展开更多
We study the confinement of a spinless charged particle to a spherical quantum dot under the influence of a linear electric field.The spherical quantum dot is described by a short-range potential given by the power-ex...We study the confinement of a spinless charged particle to a spherical quantum dot under the influence of a linear electric field.The spherical quantum dot is described by a short-range potential given by the power-exponential potential.Then,by analysing the region near the spherical quantum dot centre,we discuss two cases where the energy levels can be obtained for s-waves and how the linear electric field modifies the spectrum of energy of the spherical quantum dot.展开更多
基金supported by the Key Research and Development Program of Shandong Province,China(No 2021CXGC010803)Pan’an County Chinese Medicine Industry Project(No.PZYF202103).
文摘Reductive soil disinfestation(RSD)is commonly employed for soil remediation in greenhouse cultivation.However,its influence on antibiotic resistance genes(ARGs)in soil remains uncertain.This study investigated the dynamic changes in soil communities,potential bacterial pathogens,and ARG profiles under various organicmaterial treatments during RSD,including distillers’grains,potato peel,peanut vine,and peanut vine combined with charcoal.Results revealed that applying diverse organic materials in RSD significantly altered bacterial community composition and diminished the relative abundance of potential bacterial pathogens(P<0.05).The relative abundance of high-risk ARGs decreased by 10.7%-30.6%after RSD treatments,the main decreased ARG subtypeswere AAC(3)_Via,dfrA1,ErmB,lnuB,aadA.Actinobacteria was the primary host of ARGs and was suppressed by RSD.Soil physicochemical properties,such as total nitrogen,soil pH,total carbon,were crucial factors affecting ARG profiles.Our findings demonstrated that RSD treatment inhibited pathogenic bacteria and could be an option for reducing high-risk ARG proliferation in soil.
基金supported by the CNPC Science and Technology Major Project of the Fourteenth Five-Year Plan(2021DJ0101)the National Natural Science Foundation of China(U19B600302,41872148)。
文摘The Early Cambrian Yuertusi Formation(Є_(1)y)in the Tarim Basin of China deposits a continuously developed suite of organic-rich black mudstones,which constitute an important source of oil and gas reservoirs in the Paleozoic.However,its hydrocarbon generation and evolution characteristics and resource potential have long been constrained by deeply buried strata and previous research.In this paper,based on the newly obtained ultra-deep well drilling data,the hydrocarbon generation and expulsion model ofЄ_(1)y shale was established by using data-driven Monte Carlo simulation,upon which the hydrocarbon generation,expulsion,and retention amounts were calculated by using the diagenetic method.The research indicates that theЄ_(1)y shale reaches the hydrocarbon generation and expulsion threshold at equivalent vitrinite reflectances of 0.46%and 0.72%,respectively.The cumulative hydrocarbon generation is 68.88×10^(10)t,the cumulative hydrocarbon expulsion is 35.59×10^(10)t,and the cumulative residual hydrocarbon is 33.29×10^(10)t.This paper systematically and quantitatively calculates the hydrocarbon expulsion at various key geological periods for theЄ_(1)y source rocks in the study area for the first time,more precisely confirming that the black shale of theЄ_(1)y is the most significant source rock contributing to the marine oil and gas resources in the Tarim Basin,filling the gap in hydrocarbon expulsion calculation in the study area,and providing an important basis for the formation and distribution of Paleozoic hydrocarbon reservoirs.The prospect of deep ultra-deep oil and gas exploration in the Tarim Basin is promising.Especially,the large area of dolomite reservoirs under the Cambrian salt and source rock interiors are the key breakthrough targets for the next exploration in the Tarim Basin.
基金supported by the Science and Technology Program of Fujian Province,China(No.2023R1014002)the National Natural Science Foundation of China(No.41471390).
文摘The toxicity of PM_(2.5)does not necessarily change synchronously with its mass concentration.In this study,the chemical composition(carbonaceous species,water-soluble ions,and metals)and oxidative potential(dithiothreitol assay,DTT)of PM_(2.5)were investigated in 2017/2018 and 2022 in Xiamen,China.The decrease rate of volume-normalized DTT(DTTv)(38%)was lower than that of PM_(2.5)(55%)between the two sampling periods.However,the mass-normalized DTT(DTTm)increased by 44%.Clear seasonal patterns with higher levels in winter were found for PM_(2.5),most chemical constituents and DTTv but not for DTTm.The large decrease in DTT activity(84%−92%)after the addition of EDTA suggested that watersoluble metals were the main contributors to DTT in Xiamen.The increased gap between the reconstructed and measured DTTv and the stronger correlations between the reconstructed/measured DTT ratio and carbonaceous species in 2022were observed.The decrease rates of the hazard index(32.5%)and lifetime cancer risk(9.1%)differed from those of PM_(2.5)and DTTv due to their different main contributors.The PMF-MLR model showed that the contributions(nmol/(min·m^(3)))of vehicle emission,coal+biomass burning,ship emission and secondary aerosol to DTTv in 2022 decreased by 63.0%,65.2%,66.5%,and 22.2%,respectively,compared to those in 2017/2018,which was consistent with the emission reduction of vehicle exhaust and coal consumption,the adoption of low-sulfur fuel oil used on board ships and the reduced production of WSOC.However,the contributions of dust+sea salt and industrial emission increased.
基金supported by the National Natural Science Foundation of China(42167068,22269020)the Gansu Province Higher Education Industry Support Plan Project(2023CYZC-68)the Central Guidance for Local Science and Technology Development Funds Project(YDZX20216200001007)。
文摘Rationally regulating the porosity of hard carbon(HC),especially the closed pores matching the low potential plateau and the ultra-microporous structure suitable for Na+embedding,has been shown to be the key to improving the sodium storage performance and initial coulombic efficiency(ICE).However,the preparation of such HC materials with specific pore structures still faces great challenges.Herein,a simple pre-oxidation strategy is employed to construct abundant closed ultra-microporous structures in soy protein powder-derived HC material,achieving a significant improvement in its ICE and platform capacity.The pre-oxidation process promotes the cross-linking degree of the soy protein,thereby hindering the directional growth of graphite domains during the carbonization process.The optimized HC exhibits ultra-high platform capacity(329 mAh g^(-1))and considerable energy density(148.5 Wh kg^(-1)).Based on the ex-situ Raman and X-ray photoelectron spectroscopy characterization results,the excellent sodium storage capacity of the HC material is attributed to the synergistic effect of adsorption-intercalation/filling.The presented work provides novel insights into the synthesis of other biomass-derived HC materials with abundant closed ultra-micro pores.
基金supported by National Natural Science Foundation of China (Grant Nos. 62204104, 42005138, 12274190, 12274189, 62275115)Shandong Province High Education Youth Innovation Team Program (Grant No. 2023KJ210)Science and Technology Program of Yantai (Grant No. 2023JCYJ047)。
文摘Due to advantages of high power-conversion efficiency(PCE), large power-to-weight ratio(PWR), low cost and solution processibility, flexible perovskite solar cells(f-PSCs) have attracted extensive attention in recent years. The PCE of f-PSCs has developed rapidly to over 25%, showing great application prospects in aerospace and wearable electronic devices. This review systematically sorts device structures and compositions of f-PSCs, summarizes various methods to improve its efficiency and stability recent years. In addition, the applications and potentials of f-PSCs in space vehicle and aircraft was discussed. At last, we prospect the key scientific and technological issues that need to be addressed for f-PSCs at current stage.
基金National Key Research and Development Program of China (2022YFB2402200)National Natural Science Foundation of China (22225201,22379028)+2 种基金Fundamental Research Funds for the Central Universities (20720220010)Shanghai Pilot Program for Basic Research–Fudan University 21TQ1400100 (21TQ009)Key Basic Research Program of Science and Technology Commission of Shanghai Municipality (23520750400)。
文摘Sodium-ion batteries (SIBs) with organic electrodes are an emerging research direction due to the sustainability of organic materials based on elements like C,H,O,and sodium ions.Currently,organic electrode materials for SIBs are mainly used as cathodes because of their relatively high redox potentials(>1 V).Organic electrodes with low redox potential that can be used as anode are rare.Herein,a novel organic anode material (tetrasodium 1,4,5,8-naphthalenetetracarboxylate,Na_(4)TDC) has been developed with low redox potential (<0.7 V) and excellent cyclic stability.Its three-sodium storage mechanism was demonstrated with various in-situ/ex-situ spectroscopy and theoretical calculations,showing a high capacity of 208 mAh/g and an average decay rate of merely 0.022%per cycle.Moreover,the Na_(4)TDC-hard carbon composite can further acquire improved capacity and cycling stability for 1200 cycles even with a high mass loading of up to 20 mg cm^(-2).By pairing with a thick Na_(3)V_(2)(PO_(4))_(3)cathode (20.6 mg cm^(-2)),the as-fabricated full cell exhibited high operating voltage (2.8 V),excellent rate performance and cycling stability with a high capacity retention of 88.7% after 200 cycles,well highlighting the Na_(4)TDC anode material for SIBs.
基金supported by National Key Research and Development Program of China(No.2021YFD2200405(S.R.L.))Natural Science Foundation of China(Grant No.31971653).
文摘With the rapid economic development and continuous expansion of human activities,forest degradation—characterized by reduced forest stock within the forest including declining carbon storage—poses significant threats to ecosystem stability.Understanding the current status of forest degradation and assessing potential carbon stocks in China are of strategic importance for making forest restoration efforts and enhancing carbon sequestration capacity.In this study,we used the national forest inventory data from 2009 to 2018 to develop a set of standard measures for assessing degraded forests across China,based on five key indicators:forest accumulation growth rate(FAGR),forest recruitment rate(FRR),tree species reduction rate(TSRR),forest canopy cover reduction rate(FCCRR),and forest disaster level(FDL).Additionally,we estimated standing carbon stock,potential carbon stock,and theoretical space to grow by developing a stand growth model,which accounts for stand density across different site classes,to evaluate the restoration potential of degraded forests.The results indicate that degraded forest area in China is 36.15 million hectares,accounting for 20.10% of a total forest area.Standing carbon stock and potential carbon stock of degraded forests in China are 23.93 million tons and 61.90 million tons,respectively.Overall,degraded forest varies significantly across different regions.The results highlight the important trade-offs among environmental factors,policy decisions,and forest conditions,providing a robust foundation for developing measures to enhance forest quality.
基金financially supported by the National Key R &D Program of China (No.2022YFB3709300)。
文摘The local structure and thermophysical behavior of Mg-La liquid alloys were in-depth understood using deep potential molecular dynamic(DPMD) simulation driven via machine learning to promote the development of Mg-La alloys. The robustness of the trained deep potential(DP) model was thoroughly evaluated through several aspects, including root-mean-square errors(RMSEs), energy and force data, and structural information comparison results;the results indicate the carefully trained DP model is reliable. The component and temperature dependence of the local structure in the Mg-La liquid alloy was analyzed. The effect of Mg content in the system on the first coordination shell of the atomic pairs is the same as that of temperature. The pre-peak demonstrated in the structure factor indicates the presence of a medium-range ordered structure in the Mg-La liquid alloy, which is particularly pronounced in the 80at% Mg system and disappears at elevated temperatures. The density, self-diffusion coefficient, and shear viscosity for the Mg-La liquid alloy were predicted via DPMD simulation, the evolution patterns with Mg content and temperature were subsequently discussed, and a database was established accordingly. Finally, the mixing enthalpy and elemental activity of the Mg-La liquid alloy at 1200 K were reliably evaluated,which provides new guidance for related studies.
基金supported by the Ministry of Science and Innovation and the Spanish Research Agency through FEDER funds (PID2021-1261520B-100) (MICINN/AEI/FEDER, EU)CBM receives an institutional grant from the Fundación Ramón Areces, Spain。
文摘The word “senescence” comes from the Latin senescens, meaning “to begin to age”, and is characterized by a long-lasting but reversible block in proliferation, resulting from stress-induced cell cycle arrest of previously replication-competent cells.
基金Supported by the National Natural Science Foundation of China(11671403,11671236,12101192)Henan Provincial General Natural Science Foundation Project(232300420113)。
文摘In this paper,we mainly focus on a type of nonlinear Choquard equations with nonconstant potential.Under appropriate hypotheses on potential function and nonlinear terms,we prove that the above Choquard equation with prescribed 2-norm has some normalized solutions by introducing variational methods.
基金Supported by National Natural Science Foundation of China(12275354,11805272)the College Students'Innovative Entrepreneurial Training Plan Program of Civil Aviation University of China(202210059080)。
文摘For the magnetized complex plasma,dependences of modified Yukawa potential on the gov-erning parameters,viz.,mass ratio md/mi,number ratio nd/ne0,charge magnitude Q/e,and temperature ratio Te/Ti are investigated.It is found that md/mi,nd/ne0 and Q/e contribute to the coupling strength of the system,and Te/Ti contributes to the shielding cloud surrounding the charged dust particles.Further analysis shows that the modified Yukawa potential depends on Te/Ti.The consequent structure changes of the system are discussed based on the Langevin dynamics simulation.It is found that the variation of Ham-iltonian contributes to the equilibrium structure of the system.
文摘Dinosaur discoveries from India have been known since 1844, while dinosaur discoveries from Pakistan have appeared recently since 2000. 3 large and 2 small theropod dinosaurs are known from Pakistan, while 11 large and 4 small theropods are known from India. Pakistani land uncovered many footprints and trackways of Jurassic small and large theropods, Jurassic ankylosaur and Cretaceous hadrosaur ornithischian dinosaurs, while Indian land uncovered a footprint of small and a footprint of large theropod and 1 footprint of stegosaur. Pakistan uncovered a Jurassic bone taxon of ankylosaur ornithischian based on heavily armored synapomorphies. Recently, Pakistan yielded 1 bone taxon and 1 ichno taxon of pterosaurs, while Indian land yielded 1 bone taxon of pterosaur. Pakistani land uncovered 14 bone taxa (and 2 ichno taxa) of herbivorous sauropod dinosaurs, 5 bone taxa (and 2 ichnotaxa) of carnivorous theropod dinosaurs, 1 bone taxon of ankylosaur and 2 (ichnotaxa) of ornithischian (ankylosaur and hadrosaurs) dinosaurs, 1 bone taxon (and 1 ichno taxon) of pterosaurs, 1 plesiosaur, 7 crocodiles, 1 snake, 1 bird, 11 mammals, 3 fishes, 7 invertebrates and 1 plant. This study fills a significant gap in the literature by bringing together paleontological records from an understudied geographical location, enhancing the global understanding of dinosaur paleobiogeography. Pakistan hosts Precambrian to recent sediments igneous and metamorphic rocks. Pakistan is rich in mineral resources/rocks, but it needs more attention for its development to fulfill local requirements and earn foreign exchange.
基金supported by the National Key Research and Development Program of China (Grant No. 2022YFA1404603)by the National Natural Science Foundation of China (Grant Nos. 12274127 and 12188101)。
文摘By extending the concept of diffusion to the potential energy landscapes(PELs), we introduce the meansquared energy difference(MSED) as a novel quantity to investigate the intrinsic properties of supercooled liquids. MSED can provide a clear description of the “energy relaxation” process on a PEL. Through MSED analysis, we have obtained a characteristic time similar to that derived from structure analysis, namely τ_(α)^(*).Further, we establish a connection between MSED and the feature of PELs, providing a concise and quantitative description of PELs. The relaxation behavior of energy has been found to follow a stretched exponential form.As the temperature decreases, the roughness of the accessible PEL changes significantly around a characteristic temperature T_(x), which is 20% higher than the glass transition temperature T_(g) and is comparable to the critical temperature of the mode-coupling theory. More importantly, one of the PEL parameters is closely related to the Adam–Gibbs configurational entropy. The present research, which directly links the PEL to the relaxation process, provides avenues for further research of glasses.
基金supported by the National Natural Science Foundation of China(T2241028)the STI2030-Major Projects[2021ZD0203000(2021ZD0203003)]the Chinese Academy of Sciences Hundred Talents Program.
文摘Chronic pain,characterized by pain lasting for more than three months,is a debilitating condition frequently caused by conditions such as fibromyalgia,arthritis,neuropathy,and migraine[1-3].
文摘In a recent article, we have corrected the traditional derivation of the Schwarzschild metric, thus obtaining the formulation of the correct Schwarzschild metric, which is different from the traditional Schwarzschild metric. Then, in another article by starting from this correct Schwarzschild metric, we have corrected also the Reissner-Nordstrøm, Kerr and Kerr-Newman metrics. On the other hand, in a third article, always by starting from this correct Schwarzschild metric, we have obtained the formulas of the correct gravitational potential and of the correct gravitational force in the case described by this metric. Now, in this article, by starting from these correct Reissner-Nordstrøm, Kerr and Kerr-Newman metrics and proceeding in a manner analogous to this third article, we obtain the formulas of the correct gravitational potential and of the correct gravitational force in the cases described by these metrics. Moreover, we analyze these correct results and their consequences. Finally, we propose some possible crucial experiments between the commonly accepted theory and the same theory corrected according to this article.
基金The Second Tibetan Plateau Scientific Expedition and Research ProgramNo.2019QZKK0406。
文摘Cropland suitability analysis is a vital tool for ensuring food security and sustainable agriculture,coordinating ecological space with human activity space on the Qinghai-Tibet Plateau(QTP).However,there are few studies on complete and accurate cropland suitability assessments on the QTP,let alone on identifying key potential areas for cropland development.We used a novel assessment model to generate a 30-m cropland suitability map for the QTP.The identification of areas with cropland development potential and the evaluation of potentially available cropland were further integrated into a unified analytical framework.We found that only 10.18%of the study area is suitable for large-scale and permanent cropland.Moreover,approximately 72.75%of the existing cropland was found to be distributed in suitable or marginally suitable areas.Considering the trade-offs related to irrigation water supply convenience,approximately 1.07%of the study area was identified as having high potential for cropland development.Four key potential areas were further identified:the Shannan Valley,the Nyingchi Valley,the Zanda Valley,and the Gonghe Basin.These areas boast abundant potentially available cropland resources and ecological resettlement capacities,which leads us to recommend strategic priorities for comprehensive land consolidation and water development.This study has practical significance for optimizing land resource allocation and guiding decision-making related to ecological migration on the QTP.
文摘Global exhibitors tap China’s dynamic market for ideas,growth and resilience China will continue to seek high-quality growth and unswervingly promote high-standard opening up,making new contributions to the world economy.Chinese Premier Li Qiang made the remark at the opening ceremony of the eighth China International Import Expo(CIIE)and the Hongqiao International Economic Forum in Shanghai on 5 November.
文摘Green roofs play a vital role in promoting sustainable urban development and achieving carbon neutrality by enhancing carbon sequestration, oxygen release, and efficiency of land use. Despite these benefits, living roof coverage in China remains limited. To address the challenges in policy formulation, operational monitoring, and the absence of multi-scale retrofit strategies supported by robust assessment methods, this study develops a comprehensive evaluation framework. The framework integrates vector data, building age information, and point-of-interest(POI) data, and applies an optimized Prophet model to classify six major climate zones. This approach facilitates the selection of appropriate plant species and substrates while quantifying the potential for carbon sequestration and oxygen release. An assessment of 90 cities reveals approximately 1.3861 billion square meters of rooftop area suitable for green roof implementation, with an estimated annual carbon sequestration potential of 67.30 million tons and oxygen release of 30.36 million tons. Commercial buildings contribute significantly, comprising 65% of the total suitable area. Climate zones 2 and 3 exhibit the most favorable outcomes. The current study provides a reliable quantitative reference for evaluating the carbon sequestration and oxygen release capacities of green roofs and supports the formulation of effective retrofit policies.
文摘A substantial body of research has been conducted with the objective of enhancing the understanding of Non-Timber Forest Products (NTFP) in Central Africa. A significant proportion of the studies focus on medicinal plants, in contrast to those that examine food products. Nevertheless, studies on edible wild mushrooms as NTFPs and cultivated mushrooms, on their economic potential and value chains in the Great Lakes Region, remain scarce and largely absent for some NTFPs. In light of the aforementioned considerations, the present study aims to examine the economic potential and value chain of the production sector of wild edible mushrooms (WEM) and cultivated mushrooms (CM) within the Virunga National Park (PNVi) and its surrounding areas in North Kivu, Democratic Republic of the Congo (DRC). To this end, a sample of 432 respondents was selected, distributed equitably among the actors of the Goma-Kitshanga-Mweso value chain, the Goma-Rutshuru chain, the Beni-Mutwanga chain, and the Beni-Mangina chain. A digital questionnaire consisting of open and closed questions was administered, and observations were carried out concurrently. The quantities of mushrooms sold were weighed and photographed. The results demonstrated that, when the eight-month fruiting period of wild and cultivated mushrooms was considered as a single year for all actors within the value chain, a picker could sell 6.1 kg at $2 and earn $12. A seller could sell 16 kg at $4 and earn $64, while a grower could sell 502 kg at $3 and earn $1506. Consequently, the CM grower generates a significantly higher profit than other participants in the value chain, despite the expenses he incurs. Ultimately, the domestication of WEM, highly prized by the local population of the Virunga National Park, has the potential to enhance their household incomes, as evidenced by the findings of this study.
文摘We study the confinement of a spinless charged particle to a spherical quantum dot under the influence of a linear electric field.The spherical quantum dot is described by a short-range potential given by the power-exponential potential.Then,by analysing the region near the spherical quantum dot centre,we discuss two cases where the energy levels can be obtained for s-waves and how the linear electric field modifies the spectrum of energy of the spherical quantum dot.
