The fluorination strategy has been proven effective in significantly enhancing the photovoltaic performance of organic solar cells(OSCs) based on non-fused ring electron acceptors(NFREAs).However,research on the impac...The fluorination strategy has been proven effective in significantly enhancing the photovoltaic performance of organic solar cells(OSCs) based on non-fused ring electron acceptors(NFREAs).However,research on the impact of fluorination positions at side chains on NFREAs device performance remains scant.In this study,we introduce two isomeric NFREAs,designated as GA-2F-E and GA-2F,distinguished by their fluorination positions at the side chains.Both NFREAs share a thiophene[3,2-b]thiophene core,but their side chains differ:GA-2F-E features two(4-butylphenyl)-N-(4-fluorophenyl) amino groups,whereas GA-2F's side chains consist of bis(4-fluorophenyl)amino and bis(4-butylphenyl)amino groups attached to opposite sides of the core.To delve into the influence of fluorination positions on the optoelectronic properties,aggregation behavior,and overall efficiency of the acceptor molecules,a comprehensive investigation was conducted.The findings reveal that,despite similar photophysical properties and comparable absorption bandwidths,GA-2F-E,with fluorine atoms positioned on both sides of the molecular framework,demonstrates more compact π-π stacking,reduced bimolecular recombination,superior exciton transport,and a more balanced,higher mobility.As a result of these advantages,OSCs optimized with D18:GA-2F-E achieve a remarkable power conversion efficiency(PCE) of 16.45 %,surpassing the 15.83 %PCE of devices utilizing D18:GA-2F.This research underscores the potential of NFREAs in future applications and highlights the significance of fluorination positions in enhancing OSC performance,paving the way for the development of more efficient NFREAs.展开更多
AIM:To evaluate and compare alterations in the effective lens position(ELP)and refractive outcomes among three distinct intraocular lens(IOL)types.METHODS:Patients with cataracts were enrolled and allocated to 3 group...AIM:To evaluate and compare alterations in the effective lens position(ELP)and refractive outcomes among three distinct intraocular lens(IOL)types.METHODS:Patients with cataracts were enrolled and allocated to 3 groups:Group A(implanted with the SN6CWS),Group B(implanted with the MI60),and Group C(implanted with the Aspira-aA).ELP measurements were obtained with swept-source optical coherence tomography(SS-OCT)at 1d,1wk,1mo,and 3mo postoperatively.Subjective refraction assessments were conducted at 1wk,1mo,and 3mo following surgery.RESULTS:The study included 189 eyes of 150 cataract patients(66 males).There were 77 eyes in Group A,55 eyes in Group B,and 57 eyes in Group C.The root mean square of the ELP(ELPRMS)within the initial 3mo was significantly lower for Group A than for Groups B and C.Refractive changes within Group A were not significant across the time points of 1wk,1mo,and 3mo.Conversely,both Group B and Group C demonstrated statistically significant shifts toward hyperopia from 1wk to 3mo postsurgery.CONCLUSION:Among the three IOLs examined,the SN6CWS IOL showes the greatest stability during the first 3mo postoperatively.Between 1wk and 3mo after surgery,notable hyperopic shifts are evident in eyes implanted with the MI60 and Aspira-aA IOLs,whereas refractive outcomes remain relatively constant in eyes implanted with SN6CWS IOLs.展开更多
BACKGROUND:Tracheal intubation(TI)is a fundamental procedure for securing the airway or assisting ventilation in emergency medicine.Tracheal intubation in the lateral position(TILP)has been utilized in clinical practi...BACKGROUND:Tracheal intubation(TI)is a fundamental procedure for securing the airway or assisting ventilation in emergency medicine.Tracheal intubation in the lateral position(TILP)has been utilized in clinical practice,demonstrating potential advantages in specific scenarios,including emergency settings.However,there is a lack of comprehensive reviews and practical protocols on TILP application.To address this gap,we performed a narrative review,and provided evidence-based recommendations to formulate a practice protocol,to assist clinicians to effectively apply TILP.METHODS:We conducted a narrative review of TILP applications and developed recommendations based on clinical research evidence and clinical experience.Delphi method was used among the TILP consortium to grade the strength of the recommendations and to help reach consensus.The practice protocols were formulated as warranted by advancements in medical knowledge,technology,and practice.RESULTS:This narrative review summarized the current evidence on TILP application,highlighting its safety,efficacy,challenges,and potential complications.In total,24 recommendations and a clinical protocol for TILP application in emergency patients were established.CONCLUSION:TILP is a valuable technique in emergency medicine.We reviewed its application in emergency settings and formulated recommendations along with a clinical practice protocol.Future studies are needed to evaluate the safety and efficacy of TILP,broaden its scope of application,and explore effective training protocols.展开更多
For multi-vehicle networks,Cooperative Positioning(CP)technique has become a promising way to enhance vehicle positioning accuracy.Especially,the CP performance could be further improved by introducing Sensor-Rich Veh...For multi-vehicle networks,Cooperative Positioning(CP)technique has become a promising way to enhance vehicle positioning accuracy.Especially,the CP performance could be further improved by introducing Sensor-Rich Vehicles(SRVs)into CP networks,which is called SRV-aided CP.However,the CP system may split into several sub-clusters that cannot be connected with each other in dense urban environments,in which the sub-clusters with few SRVs will suffer from degradation of CP performance.Since Unmanned Aerial Vehicles(UAVs)have been widely used to aid vehicular communications,we intend to utilize UAVs to assist sub-clusters in CP.In this paper,a UAV-aided CP network is constructed to fully utilize information from SRVs.First,the inter-node connection structure among the UAV and vehicles is designed to share available information from SRVs.After that,the clustering optimization strategy is proposed,in which the UAV cooperates with the high-precision sub-cluster to obtain available information from SRVs,and then broadcasts this positioning-related information to other low-precision sub-clusters.Finally,the Locally-Centralized Factor Graph Optimization(LC-FGO)algorithm is designed to fuse positioning information from cooperators.Simulation results indicate that the positioning accuracy of the CP system could be improved by fully utilizing positioning-related information from SRVs.展开更多
A rock-drilling jumbo is the main piece of tunneling equipment used in the energy and infrastructure industries in various countries.The positioning accuracy of its drilling boom greatly affects tunneling efficiency a...A rock-drilling jumbo is the main piece of tunneling equipment used in the energy and infrastructure industries in various countries.The positioning accuracy of its drilling boom greatly affects tunneling efficiency and section-forming quality of mine roadways and engineering tunnels.In order to improve the drilling-positioning accuracy of a three-boom drilling jumbo,we established a kinematics model of the multi-degree-of-freedom(multi-DOF)multi-boom system,using the improved Denavit-Hartenberg(D-H)method,and obtained the mapping relationship between the end position and the amount of motion of each joint.The error of the inverse kinematics calculation for the drilling boom is estimated by an analytical method and a global search algorithm based on particle swarm optimization(PSO)for a straight blasting hole and an inclined blasting hole.On this basis,we propose a back-propagation(BP)neural network optimized by an improved sparrow search algorithm(ISSA)to predict the positioning error of the drilling booms of a three-boom drilling jumbo.In order to verify the accuracy of the proposed error compensation model,we built an automatic-control test platform for the boom,and carried out a positioning error compensation test on the boom.The results show that the average drilling-positioning error was reduced from 9.79 to 5.92 cm,and the error was reduced by 39.5%.Therefore,the proposed method effectively reduces the positioning error of the drilling boom,and improves the accuracy and efficiency of rock drilling.展开更多
Precise coseismic displacements in earthquake/tsunamic early warning are necessary to characterize earthquakes in real time in order to enable decision-makers to issue alerts for public safety.Real-time global navigat...Precise coseismic displacements in earthquake/tsunamic early warning are necessary to characterize earthquakes in real time in order to enable decision-makers to issue alerts for public safety.Real-time global navigation satellite systems(GNSSs)have been a valuable tool in monitoring seismic motions,allowing permanent displacement computation to be unambiguously achieved.As a valuable tool presented to the seismic commu nity,the GSeisRT software developed by Wuhan University(China)can realize multi-GNSS precise point positioning with ambiguity resolution(PPP-AR)and achieve centimeterlevel to sub-centimeter-level precision in real time.While the stable maintenance of a global precise point positioning(PPP)service is challenging,this software is capable of estimating satellite clocks and phase biases in real time using a regional GNSS network.This capability makes GSeisRT especially suitable for proprietary GNSS networks and,more importantly,the highest possible positio ning precision and reliability can be obtained.According to real-time results from the Network of the Americas,the mean root mean square(RMS)errors of kinematic PPP-AR over a 24 h span are as low as 1.2,1.3,and 3.0 cm in the east,north,and up components,respectively.Within the few minutes that span a typical seismic event,a horizontal displacement precision of 4 mm can be achieved.The positioning precision of the GSeisRT regional PPP/PPP-AR is 30%-40%higher than that of the global PPP/PPP-AR.Since 2019,GSeisRT has successfully recorded the static,dynamic,and peak ground displacements for the 2020Oaxaca,Mexico moment magnitude(Mw)7.4 event;the 2020 Lone Pine,California Mw 5.8 event;and the 2021 Qinghai,China Mw 7.3 event in real time.The resulting immediate magnitude estimates have an error of around 0.1 only.The GSeisRT software is open to the scientific community and has been applied by the China Earthquake Ne tworks Center,the EarthScope Consortium of the United States,the National Seismological Center of Chile,Institute of Geological and Nuclear Sciences Limited(GNS Science Te PūAo)of New Zealand,and the Geospatial Information Agency of Indonesia.展开更多
The accuracy of spot centroid positioning has a significant impact on the tracking accuracy of the system and the stability of the laser link construction.In satellite laser communication systems,the use of short-wave...The accuracy of spot centroid positioning has a significant impact on the tracking accuracy of the system and the stability of the laser link construction.In satellite laser communication systems,the use of short-wave infrared wavelengths as beacon light can reduce atmospheric absorption and signal attenuation.However,there are strong non-uniformity and blind pixels in the short-wave infrared image,which makes the image distorted and leads to the decrease of spot centroid positioning accuracy.Therefore,the high-precision localization of the spot centroid of the short-wave infrared images is of great research significance.A high-precision spot centroid positioning model for short-wave infrared is proposed to correct for non-uniformity and blind pixels in short-wave infrared images and quantify the localization errors caused by the two,further model-based localization error simulations are performed,and a novel spot centroid positioning payload for satellite laser communications has been designed using the latest 640×512 planar array InGaAs shortwave infrared detector.The experimental results show that the non-uniformity of the corrected image is reduced from 7%to 0.6%,the blind pixels rejection rate reaches 100%,the frame rate can be up to 2000 Hz,and the spot centroid localization accuracy is as high as 0.1 pixel point,which realizes high-precision spot centroid localization of high-frame-frequency short-wave infrared images.展开更多
Dear Editor,As the Internet of things(IoT)and autonomous driving continue to evolve,positioning technology faces increasing demands for higher accuracy and reliability.Traditional positioning methods often struggle in...Dear Editor,As the Internet of things(IoT)and autonomous driving continue to evolve,positioning technology faces increasing demands for higher accuracy and reliability.Traditional positioning methods often struggle in complex signal environments with multipath interference and non-line-of-sight(NLOS)conditions.Reconfigurable intelligent surfaces(RIS),an innovative technology that can flexibly control signal propagation,offer new possibilities for positioning systems.展开更多
Sunflower leaf photosynthesis strongly depends on the leaf position in the plant stem conditioning,which directly affects other physiological processes.Therefore,a study of the leaf’s physiological status regarding t...Sunflower leaf photosynthesis strongly depends on the leaf position in the plant stem conditioning,which directly affects other physiological processes.Therefore,a study of the leaf’s physiological status regarding the leaf position in the stem was performed on sunflowers in the flowering stage.Eight differently positioned leaves were investigated,starting with the youngest leaf on the top of the stem to the leaves of the stem bottom,assigned as the oldest senescent leaves.According to chlorophyll fluorescence(ChlF)parameters connected to photosystem II(PSII)processes,significant changes in PSII functioning occurred only in the senescent leaves,while photosystem I(PSI)describing parameters showed a linear decrease with leaf age,i.e.,position on the stem.The antioxidative status of the leaves was dynamic,as stress indicators(lipid peroxidation and hydrogen peroxide content)fluctuated regarding leaf position on the stem,but no link was found between the activities of antioxidative enzymes and oxidative stress indicators.Linear decrease trend of secondary metabolites(mainly phenolic compounds)correlated with antioxidant activity,except for some phenolic acids(caffeic and ferulic acid),which increased in senescent leaves.The most changes in the physiological status of the leaves were confirmed in senescent leaves,which stand out the importance of younger leaves in maintaining the plant’s vitality after flowering,which is the most important for sunflower yield.展开更多
The existing Low-Earth-Orbit(LEO)positioning performance cannot meet the requirements of Unmanned Aerial Vehicle(UAV)clusters for high-precision real-time positioning in the Global Navigation Satellite System(GNSS)den...The existing Low-Earth-Orbit(LEO)positioning performance cannot meet the requirements of Unmanned Aerial Vehicle(UAV)clusters for high-precision real-time positioning in the Global Navigation Satellite System(GNSS)denial conditions.Therefore,this paper proposes a UAV Clusters Information Geometry Fusion Positioning(UC-IGFP)method using pseudoranges from the LEO satellites.A novel graph model for linking and computing between the UAV clusters and LEO satellites was established.By utilizing probability to describe the positional states of UAVs and sensor errors,the distributed multivariate Probability Fusion Cooperative Positioning(PF-CP)algorithm is proposed to achieve high-precision cooperative positioning and integration of the cluster.Criteria to select the centroid of the cluster were set.A new Kalman filter algorithm that is suitable for UAV clusters was designed based on the global benchmark and Riemann information geometry theory,which overcomes the discontinuity problem caused by the change of cluster centroids.Finally,the UC-IGFP method achieves the LEO continuous highprecision positioning of UAV clusters.The proposed method effectively addresses the positioning challenges caused by the strong direction of signal beams from LEO satellites and the insufficient constraint quantity of information sources at the edge nodes of the cluster.It significantly improves the accuracy and reliability of LEO-UAV cluster positioning.The results of comprehensive simulation experiments show that the proposed method has a 30.5%improvement in performance over the mainstream positioning methods,with a positioning error of 14.267 m.展开更多
Forest ecosystems can be characterized by a set of catenas arranged along the slope in mountainous areas as these affect microhabitat features,which in turn influence soil properties.Heretofore,few studies have examin...Forest ecosystems can be characterized by a set of catenas arranged along the slope in mountainous areas as these affect microhabitat features,which in turn influence soil properties.Heretofore,few studies have examined how topographic variables affect soil properties and quality in semiarid regions.This study aimed to provide important insights into how catena position and shape influence soil properties,soil quality,and their interrelationships in a semiarid protected oak forest in western Iran.Basic soil properties were measured in the laboratory.In addition,the soil quality index(SQI)was calculated at different topographic positions along both convex(Λ-shaped)and concave(V-shaped)catenas at two soil depths(0-15 and 15-30 cm).The findings indicated that soil organic carbon and total nitrogen declined in the lower depth in both V-andΛ-shaped catenas and at all catena positions.The lowest porosity was observed in the lower depth at toeslope positions(TS)of both catenas.Substrate-induced respiration(SIR),microbial biomass carbon(MBC),and basal respiration(BR)were higher in the upper depths at TS positions on V-shaped catenas than onΛ-shaped catenas.These biological indices were consistently higher in the upper depths than in the lower depths across all positions of both catenas.SQI had the highest values at TS positions on both catenas and in the upper depths across all positions.Pearson correlations between soil properties indicated that SQI was most strongly and positively correlated with biological properties in both catenas.The nutrient levels,microbial activity,and soil porosity in both catena shapes and at both soil depths displayed a relatively downward trend with increasing elevation from toeslope to summit positions.The results showed that catena topographic sequence shape and position affected most of the soil properties,providing evidence of the important role of topography in creating pedodiversity in oak forest ecosystems.展开更多
In this paper,we present a novel particle filter(PF)-based direct position tracking method utilizing multiple distributed observation stations.Traditional passive tracking methods are anchored on repetitive position e...In this paper,we present a novel particle filter(PF)-based direct position tracking method utilizing multiple distributed observation stations.Traditional passive tracking methods are anchored on repetitive position estimation,where the set of consecutive estimates provides the tracking trajectory,such as Two-step and direct position determination methods.However,duplicate estimates can be computationally expensive.In addition,these techniques suffer from data association problems.The PF algorithm is a tracking method that avoids these drawbacks,but the conventional PF algorithm is unable to construct a likelihood function from the received signals of multiple observatories to determine the weights of particles.Therefore,we developed an improved PF algorithm with the likelihood function modified by the projection approximation subspace tracking with deflation(PASTd)algorithm.The proposed algorithm uses the projection subspace and spectral function to replace the likelihood function of PF.Then,the weights of particles are calculated jointly by multiple likelihood functions.Finally,the tracking problem of multiple targets is solved by multiple sets of particles.Simulations demonstrate the effectiveness of the proposed method in terms of computational complexity and tracking accuracy.展开更多
Objectives A systematic review and network meta-analysis was conducted to evaluate the effectiveness of different childbirth positions in reducing the duration of the second stage of labor,providing evidence-based ins...Objectives A systematic review and network meta-analysis was conducted to evaluate the effectiveness of different childbirth positions in reducing the duration of the second stage of labor,providing evidence-based insights for obstetric institutions to guide interventions related to childbirth positions.Methods A comprehensive literature search was conducted in databases,including PubMed,Web of Science,the Cochrane Library,Embase,Wanfang Databases,China National Knowledge Infrastructure Databases(CNKI),China Science and Technology Journal Database(CSTJ),and China Biology Medicine disc(CBMdisc)to identify studies on the effectiveness of different childbirth positions in reducing the duration of the second stage of labor.The search included randomized controlled trials published from database inception to September 30,2024.The Cochrane risk-of-bias tool was used to assess the quality of the studies.Two independent reviewers screened the literature,extracted data,and evaluated study quality.Subsequently,a network meta-analysis was performed using STATA software.The study protocol has been registered in PROSPERO(CRD42023428217).Results This study analyzed data from 25 randomized controlled trials involving 9,844 women.The findings indicated that in comparison to lithotomy position,free position(MD=20.53,95%CI[11.38,29.68])and upright position(MD=−24.13,95%CI[−42.94,-5.32])were found to be superior in reducing the duration of the second stage of labor.Free position outperformed kneeling position(MD=21.48,95%CI[4.67,38.28])and squatting position(MD=23.43,95%CI[1.88,44.97]);upright position was superior to kneeling position(MD=−25.08,95%CI[−46.93,−3.22]);semirecumbent position surpassed squatting position(MD=19.71,95%CI[2.05,37.38]);and upright position was also superior to squatting position(MD=−27.03,95%CI[−51.48,−2.57]).According to the surface under the cumulative ranking curve(SUCRA),the upright position emerged as the most effective for reducing the duration of the second stage of labor(87.4%),followed by free position(81.1%),semirecumbent position(70.0%),and lateral position(62.3%).Conclusion These findings offer valuable insights for midwifery practice and help inform future research directions.Considering the limitations of this review,more larger-scale,multicenter randomized controlled trials are warranted to further evaluate the relative effectiveness of different childbirth positions in reducing the duration of the second stage of labor.展开更多
Four benzocoumarin-based two-photon fluorescent probes(BH1-BH4)are proposed for ra-tiometric detection of hypochlorous acid(HClO)and their two-photon sensing perfor-mance are evaluated by means of time-dependent densi...Four benzocoumarin-based two-photon fluorescent probes(BH1-BH4)are proposed for ra-tiometric detection of hypochlorous acid(HClO)and their two-photon sensing perfor-mance are evaluated by means of time-dependent density func-tional theory and quadratic re-sponse theory.The effects of benzene-fused position on Stokes shift,fluorescence quantum yield and two-photon absorption are discussed comprehensively.The results show that fusing a benzene ring in coumarin can enhance Stokes shift efficiently.The benzene-fused position has important effects on these photophysical properties.The benzo[g]coumarins(BH1)and benzo[f]coumarins(BH2)derivatives have larger Stokes shifts in comparison with benzo[h]coumarins(BH3)and dihydrophenazine(BH4)derivatives.The two-photon absorp-tion of benzo[f]coumarins(BH2)derivative is much smaller than those of other benzo-coumarins derivatives.The large Stokes shift and increased two-photon action cross section can be achieved simultaneously in the dihydrophenazine(BH4)derivative.Therefore,the de-signed BH4 is expected to have superior performance for the ratiometric detection of HClO.To explore the reasons behind these effects,the intramolecular charge transfer degrees are il-lustrated quantitatively by plotting the hole-electron isosurface map,and the relation be-tween charge transfer and Stokes shift is revealed.A two-state model analysis is employed to understand two-photon absorption ability.Moreover,the fluorescence near-quenching mecha-nism of the product molecules B1 and B3 is explained by analyzing reorganization energy and Huang-Rhys factor,as well as related normal mode.Our research could contribute to the effi-cient design of ratiometric two-photon fluorescent probes with large Stokes shift and signifi-cant two-photon action cross section.展开更多
Granite residual soil slope is often destroyed,which poses great threats to Rong County in southeastern Guangxi,China.Heavy rainfall and fissures are the major triggering and internal factors.The fissure that controls...Granite residual soil slope is often destroyed,which poses great threats to Rong County in southeastern Guangxi,China.Heavy rainfall and fissures are the major triggering and internal factors.The fissure that controls the slope stability and the associated failure mechanisms remain unclear.The purpose of this study was to identify the controlling fissures through field investigation,elucidate the effect of its position,and analyze the failure process and hydrological response of residual soil slope through artificial flume model tests.The results comprised five aspects.(1)Surface weathering and unloading fissures could affect slope stability.(2)The failure processes with different fissure positions exhibited inconsistent characteristics.(3)The volume moisture content(VMC)had the most direct response at the fissure tip.The corresponding infiltration rate was the highest.The response time of pore water pressure(PWP)was longer than that of VMC.Fluctuations in PWP were associated with VMC and changes in the soil microstructure due to local deformation.(4)Slope failure was accompanied by serious soil erosion.This could be attributed to the infiltration direction and the interaction between soil and water.(5)Fissured soil slopes experienced five similar failure processes:sheet erosion and partial failure of the slope foot,occurrence of preferential flow and enlargement of the sliding area,creep deformation and tension fissure emergence,block sliding and gully erosion,and flow-slip.展开更多
Potassium(K)is a highly mobile nutrient element that continuously adjusts its demand strategy among and within cotton leaves through redistribution,indirectly leading to variations in the leaf potassium content(LKC,%)...Potassium(K)is a highly mobile nutrient element that continuously adjusts its demand strategy among and within cotton leaves through redistribution,indirectly leading to variations in the leaf potassium content(LKC,%)at different leaf positions.However,due to the interaction between light and leaf age,leaf sensitivity to this change varies at different positions,including the reflection and absorption of the spectrum.Selecting the optimal leaf position for monitoring is a crucial factor in the rapid and accurate evaluation of cotton LKC using spectral remote sensing technology.Therefore,this study proposes a comprehensive multi-leaf position estimation model based on the vertical distribution characteristics of LKC from top to bottom,aiming to achieve an accurate estimation of cotton LKC and optimize the strategy for selecting the monitored leaf position.Between 2020 and 2021,we collected hyperspectral imaging data of the main stem leaves at different positions from top to bottom(Li,i=1,2,3,...,n)during the cotton budding,flowering,and boll-setting stages.Vertical distribution characteristics,sensitivity differences,and spectral correlations of LKC at different leaf positions were investigated.Additionally,the optimal range of the dominant leaf position for monitoring was determined.Partial least squares regression(PLSR),random forest regression(RFR),support vector machine regression(SVR),and the entropy weight method(EWM)were employed to develop LKC estimation models for single-and multi-leaf positions.The results showed a vertical heterogeneous distribution of cotton LKC,with LKC initially increasing and then gradually decreasing from top to bottom;the average LKC of cotton reached its maximum value at the flowering stage.The upper leaf position demonstrated greater sensitivity to K and exhibited a stronger correlation with the spectrum.The selected dominant leaf positions for the three growth stages were L1-L5,L1-L4,and L1-L2,respectively.Based on the dominant leaf position monitoring range,the optimal single leaf position models for estimating LKC during the three growth stages were PLSR-L4,PLSR-L1,and SVR-L2,with the coefficient of determination of the validation set(R2val)being 0.786,0.580,and 0.768,and the root-mean-square error of the validation set(RMSEval)being 0.168,0.197,and 0.191,respectively.The multi-leaf position LKC estimation model was constructed by EWM with R2val being 0.887,0.728,and 0.703,and RMSEval being 0.134,0.172,and 0.209,respectively.In contrast,the newly developed multi-leaf position comprehensive estimation model yielded superior results,improving the model’s stability based on high accuracy,especially during the budding and flowering stages.These findings hold significant importance for investigating cotton LKC spectral models and selecting suitable leaf positions for field monitoring.展开更多
Position sensors are indispensable in robotic joint servo systems for acquiring mechanical positions, yet their installation inevitably occupies an axial space and increases system complexity, limiting their applicabi...Position sensors are indispensable in robotic joint servo systems for acquiring mechanical positions, yet their installation inevitably occupies an axial space and increases system complexity, limiting their applicability in compact robot design where spatial constraints and integration efficiency are critical. Sensorless control reduces mechanical and circuit complexity through hardware simplification, but inherently estimates only the electrical instead of mechanical rotor position information, thus remaining constrained in robot joint control applications. Based on the previously proposed dual-gap dualpole composite machine(DDCM), this paper systematically analyzes the causes of mechanical position estimation errors and proposes a correction method that utilizes a correction coefficient to reduce these errors and enhance estimation accuracy. Furthermore, this paper derives the applicability constraints of the proposed scheme, demonstrating that its requirements for electrical angle position errors are not stringent, thus enabling wide applicability in conventional sensorless control scenarios. The effectiveness of the proposed method is verified by conducting experiments on a 0.75 kW prototype.展开更多
The intensified kernel position effect is a common phenomenon in maize production under higher plant density,which limits crop productivity.Subsoiling is an effective agronomic practice for improving crop productivity...The intensified kernel position effect is a common phenomenon in maize production under higher plant density,which limits crop productivity.Subsoiling is an effective agronomic practice for improving crop productivity.To clarify the effect of subsoiling before winter wheat on the kernel position effect of densely grown summer maize and its regulatory mechanism,field experiments were conducted during the 2020-2021 and 2021-2022 growing seasons using a split-plot design.The main plots included two tillage practices:conventional tillage practice(CT)and subsoiling before the sowing of winter wheat(SS);and the subplots consisted of three plant densities(D1-D3 at 6.0×10~4,7.5×10~4,and 9.0×10~4 plants ha-1).Compared with CT,SS alleviated the kernel position effect by increasing the weight ratio of inferior to superior kernels(WR)in the D2 and D3 treated plants.The higher WR of SS treated plants contributed largely to the improved flling of inferior kernels.Under the same plant density,SS signifcantly improved the root dry matter accumulation(DMA)and antioxidant enzyme activities(superoxide dismutase(SOD)and peroxidase(POD)),and it reduced the malondialdehyde(MDA)content,especially for the plants grown under higher plant densities.These results indicated that SS delayed the root senescence,which is associated with the reduced soil bulk density.In addition,compared with CT,SS increased the leaf chlorophyll content from 20 days after silking to physiological maturity and the post-silking leaf area duration,and it reduced the post-silking leaf chlorophyll reduction rate and leaf area reduction rate,indicating that the post-silking leaf senescence had been alleviated.Under the same plant density,the post-silking DMA of SS was obviously higher than that of CT,which was probably related to the improved leaf area duration and photosynthetic enzyme activities(phosphoenolpyruvate carboxylase(PEPC)and Rubisco).The correlation analysis revealed that the main mechanism of SS in alleviating the kernel position effect of densely grown summer maize is as follows:SS delays the post-silking root-shoot senescence by regulating soil physical properties,and further improves the post-silking DMA and flling of inferior kernels,which ultimately alleviates the kernel position effect and improves grain yield.The results of this study provide new theoretical support for the promotion of summer maize yield by subsoiling before winter wheat.展开更多
To solve the problem of identification and measurement of two projectiles hitting the target at the same time,this paper proposes a projectile coordinate test method combining three photoelectric encoder detection scr...To solve the problem of identification and measurement of two projectiles hitting the target at the same time,this paper proposes a projectile coordinate test method combining three photoelectric encoder detection screens,and establishes a coordinate calculation model for two projectiles to reach the same detection screen at the same time.The design method of three photoelectric encoder detection screens and the position coordinate recognition algorithm of the blocked array photoelectric detector when projectile passing through the photoelectric encoder detection screen are studied.Using the screen projection method,the intersected linear equation of the projectile and the line laser with the main detection screen as the core coordinate plane is established,and the projectile coordinate data set formed by any two photoelectric encoder detection screens is constructed.The principle of minimum error of coordinate data set is used to determine the coordinates of two projectiles hitting the target at the same time.The rationality and feasibility of the proposed test method are verified by experiments and comparative tests.展开更多
In this paper,a novel train positioning method considering satellite raw observation data was proposed,which aims to promote train positioning performance from an innovative perspective of the train satellite-based po...In this paper,a novel train positioning method considering satellite raw observation data was proposed,which aims to promote train positioning performance from an innovative perspective of the train satellite-based positioning error sources.The method focused on overcoming the abnormal observations in satellite observation data caused by railway environment rather than the positioning results.Specifically,the relative positioning experimental platform was built and the zero-baseline method was firstly employed to evaluate the carrier phase data quality,and then,GNSS combined observation models were adopted to construct the detection values,which were applied to judge abnormal-data through the dual-frequency observations.Further,ambiguity fixing optimization was investigated based on observation data selection in partly-blocked environments.The results show that the proposed method can effectively detect and address abnormal observations and improve positioning stability.Cycle slips and gross errors can be detected and identified based on dual-frequency global navigation satellite system data.After adopting the data selection strategy,the ambiguity fixing percentage was improved by 29.2%,and the standard deviation in the East,North,and Up components was enhanced by 12.7%,7.4%,and 12.5%,respectively.The proposed method can provide references for train positioning performance optimization in railway environments from the perspective of positioning error sources.展开更多
基金financially supported by the National Natural Science Foundation of China (Nos.22375024,21975031,51933001,and 21734009)。
文摘The fluorination strategy has been proven effective in significantly enhancing the photovoltaic performance of organic solar cells(OSCs) based on non-fused ring electron acceptors(NFREAs).However,research on the impact of fluorination positions at side chains on NFREAs device performance remains scant.In this study,we introduce two isomeric NFREAs,designated as GA-2F-E and GA-2F,distinguished by their fluorination positions at the side chains.Both NFREAs share a thiophene[3,2-b]thiophene core,but their side chains differ:GA-2F-E features two(4-butylphenyl)-N-(4-fluorophenyl) amino groups,whereas GA-2F's side chains consist of bis(4-fluorophenyl)amino and bis(4-butylphenyl)amino groups attached to opposite sides of the core.To delve into the influence of fluorination positions on the optoelectronic properties,aggregation behavior,and overall efficiency of the acceptor molecules,a comprehensive investigation was conducted.The findings reveal that,despite similar photophysical properties and comparable absorption bandwidths,GA-2F-E,with fluorine atoms positioned on both sides of the molecular framework,demonstrates more compact π-π stacking,reduced bimolecular recombination,superior exciton transport,and a more balanced,higher mobility.As a result of these advantages,OSCs optimized with D18:GA-2F-E achieve a remarkable power conversion efficiency(PCE) of 16.45 %,surpassing the 15.83 %PCE of devices utilizing D18:GA-2F.This research underscores the potential of NFREAs in future applications and highlights the significance of fluorination positions in enhancing OSC performance,paving the way for the development of more efficient NFREAs.
基金Supported by the Zhejiang Medical Health Science and Technology Project(No.2021KY217)the Basic Public Welfare Research Project of Wenzhou Municipal Science and Technology Bureau(No.2024Y1221).
文摘AIM:To evaluate and compare alterations in the effective lens position(ELP)and refractive outcomes among three distinct intraocular lens(IOL)types.METHODS:Patients with cataracts were enrolled and allocated to 3 groups:Group A(implanted with the SN6CWS),Group B(implanted with the MI60),and Group C(implanted with the Aspira-aA).ELP measurements were obtained with swept-source optical coherence tomography(SS-OCT)at 1d,1wk,1mo,and 3mo postoperatively.Subjective refraction assessments were conducted at 1wk,1mo,and 3mo following surgery.RESULTS:The study included 189 eyes of 150 cataract patients(66 males).There were 77 eyes in Group A,55 eyes in Group B,and 57 eyes in Group C.The root mean square of the ELP(ELPRMS)within the initial 3mo was significantly lower for Group A than for Groups B and C.Refractive changes within Group A were not significant across the time points of 1wk,1mo,and 3mo.Conversely,both Group B and Group C demonstrated statistically significant shifts toward hyperopia from 1wk to 3mo postsurgery.CONCLUSION:Among the three IOLs examined,the SN6CWS IOL showes the greatest stability during the first 3mo postoperatively.Between 1wk and 3mo after surgery,notable hyperopic shifts are evident in eyes implanted with the MI60 and Aspira-aA IOLs,whereas refractive outcomes remain relatively constant in eyes implanted with SN6CWS IOLs.
基金National Natural Science Foundation of China(U24A20714 to XMF and 82102238 to PC)。
文摘BACKGROUND:Tracheal intubation(TI)is a fundamental procedure for securing the airway or assisting ventilation in emergency medicine.Tracheal intubation in the lateral position(TILP)has been utilized in clinical practice,demonstrating potential advantages in specific scenarios,including emergency settings.However,there is a lack of comprehensive reviews and practical protocols on TILP application.To address this gap,we performed a narrative review,and provided evidence-based recommendations to formulate a practice protocol,to assist clinicians to effectively apply TILP.METHODS:We conducted a narrative review of TILP applications and developed recommendations based on clinical research evidence and clinical experience.Delphi method was used among the TILP consortium to grade the strength of the recommendations and to help reach consensus.The practice protocols were formulated as warranted by advancements in medical knowledge,technology,and practice.RESULTS:This narrative review summarized the current evidence on TILP application,highlighting its safety,efficacy,challenges,and potential complications.In total,24 recommendations and a clinical protocol for TILP application in emergency patients were established.CONCLUSION:TILP is a valuable technique in emergency medicine.We reviewed its application in emergency settings and formulated recommendations along with a clinical practice protocol.Future studies are needed to evaluate the safety and efficacy of TILP,broaden its scope of application,and explore effective training protocols.
基金supported by the National Natural Science Foundation of China(No.62271399)the National Key Research and Development Program of China(No.2022YFB1807102)。
文摘For multi-vehicle networks,Cooperative Positioning(CP)technique has become a promising way to enhance vehicle positioning accuracy.Especially,the CP performance could be further improved by introducing Sensor-Rich Vehicles(SRVs)into CP networks,which is called SRV-aided CP.However,the CP system may split into several sub-clusters that cannot be connected with each other in dense urban environments,in which the sub-clusters with few SRVs will suffer from degradation of CP performance.Since Unmanned Aerial Vehicles(UAVs)have been widely used to aid vehicular communications,we intend to utilize UAVs to assist sub-clusters in CP.In this paper,a UAV-aided CP network is constructed to fully utilize information from SRVs.First,the inter-node connection structure among the UAV and vehicles is designed to share available information from SRVs.After that,the clustering optimization strategy is proposed,in which the UAV cooperates with the high-precision sub-cluster to obtain available information from SRVs,and then broadcasts this positioning-related information to other low-precision sub-clusters.Finally,the Locally-Centralized Factor Graph Optimization(LC-FGO)algorithm is designed to fuse positioning information from cooperators.Simulation results indicate that the positioning accuracy of the CP system could be improved by fully utilizing positioning-related information from SRVs.
基金National Natural Science Foundation of China(No.12472038)Natural Science Foundation of Jiangsu Province(No.BK20230688)+2 种基金Natural Science Foundation of the Jiangsu Higher Education Institutions of China(No.22KJB440004)Key Research and Development Program of Xuzhou(No.KC22404)Research Fund for Doctoral Degree Teachers of Jiangsu Normal University of China(No.22XFRS011).
文摘A rock-drilling jumbo is the main piece of tunneling equipment used in the energy and infrastructure industries in various countries.The positioning accuracy of its drilling boom greatly affects tunneling efficiency and section-forming quality of mine roadways and engineering tunnels.In order to improve the drilling-positioning accuracy of a three-boom drilling jumbo,we established a kinematics model of the multi-degree-of-freedom(multi-DOF)multi-boom system,using the improved Denavit-Hartenberg(D-H)method,and obtained the mapping relationship between the end position and the amount of motion of each joint.The error of the inverse kinematics calculation for the drilling boom is estimated by an analytical method and a global search algorithm based on particle swarm optimization(PSO)for a straight blasting hole and an inclined blasting hole.On this basis,we propose a back-propagation(BP)neural network optimized by an improved sparrow search algorithm(ISSA)to predict the positioning error of the drilling booms of a three-boom drilling jumbo.In order to verify the accuracy of the proposed error compensation model,we built an automatic-control test platform for the boom,and carried out a positioning error compensation test on the boom.The results show that the average drilling-positioning error was reduced from 9.79 to 5.92 cm,and the error was reduced by 39.5%.Therefore,the proposed method effectively reduces the positioning error of the drilling boom,and improves the accuracy and efficiency of rock drilling.
基金funded by National Science Foundation of China(42025401)National Key Research and Development Program of China(2022YFB3903800)。
文摘Precise coseismic displacements in earthquake/tsunamic early warning are necessary to characterize earthquakes in real time in order to enable decision-makers to issue alerts for public safety.Real-time global navigation satellite systems(GNSSs)have been a valuable tool in monitoring seismic motions,allowing permanent displacement computation to be unambiguously achieved.As a valuable tool presented to the seismic commu nity,the GSeisRT software developed by Wuhan University(China)can realize multi-GNSS precise point positioning with ambiguity resolution(PPP-AR)and achieve centimeterlevel to sub-centimeter-level precision in real time.While the stable maintenance of a global precise point positioning(PPP)service is challenging,this software is capable of estimating satellite clocks and phase biases in real time using a regional GNSS network.This capability makes GSeisRT especially suitable for proprietary GNSS networks and,more importantly,the highest possible positio ning precision and reliability can be obtained.According to real-time results from the Network of the Americas,the mean root mean square(RMS)errors of kinematic PPP-AR over a 24 h span are as low as 1.2,1.3,and 3.0 cm in the east,north,and up components,respectively.Within the few minutes that span a typical seismic event,a horizontal displacement precision of 4 mm can be achieved.The positioning precision of the GSeisRT regional PPP/PPP-AR is 30%-40%higher than that of the global PPP/PPP-AR.Since 2019,GSeisRT has successfully recorded the static,dynamic,and peak ground displacements for the 2020Oaxaca,Mexico moment magnitude(Mw)7.4 event;the 2020 Lone Pine,California Mw 5.8 event;and the 2021 Qinghai,China Mw 7.3 event in real time.The resulting immediate magnitude estimates have an error of around 0.1 only.The GSeisRT software is open to the scientific community and has been applied by the China Earthquake Ne tworks Center,the EarthScope Consortium of the United States,the National Seismological Center of Chile,Institute of Geological and Nuclear Sciences Limited(GNS Science Te PūAo)of New Zealand,and the Geospatial Information Agency of Indonesia.
基金Supported by the Short-wave Infrared Camera Systems(B025F40622024)。
文摘The accuracy of spot centroid positioning has a significant impact on the tracking accuracy of the system and the stability of the laser link construction.In satellite laser communication systems,the use of short-wave infrared wavelengths as beacon light can reduce atmospheric absorption and signal attenuation.However,there are strong non-uniformity and blind pixels in the short-wave infrared image,which makes the image distorted and leads to the decrease of spot centroid positioning accuracy.Therefore,the high-precision localization of the spot centroid of the short-wave infrared images is of great research significance.A high-precision spot centroid positioning model for short-wave infrared is proposed to correct for non-uniformity and blind pixels in short-wave infrared images and quantify the localization errors caused by the two,further model-based localization error simulations are performed,and a novel spot centroid positioning payload for satellite laser communications has been designed using the latest 640×512 planar array InGaAs shortwave infrared detector.The experimental results show that the non-uniformity of the corrected image is reduced from 7%to 0.6%,the blind pixels rejection rate reaches 100%,the frame rate can be up to 2000 Hz,and the spot centroid localization accuracy is as high as 0.1 pixel point,which realizes high-precision spot centroid localization of high-frame-frequency short-wave infrared images.
基金supported by the Open Fund Project of Key Laboratory of Ocean Observation Technology,MNR(2023klootA01).
文摘Dear Editor,As the Internet of things(IoT)and autonomous driving continue to evolve,positioning technology faces increasing demands for higher accuracy and reliability.Traditional positioning methods often struggle in complex signal environments with multipath interference and non-line-of-sight(NLOS)conditions.Reconfigurable intelligent surfaces(RIS),an innovative technology that can flexibly control signal propagation,offer new possibilities for positioning systems.
文摘Sunflower leaf photosynthesis strongly depends on the leaf position in the plant stem conditioning,which directly affects other physiological processes.Therefore,a study of the leaf’s physiological status regarding the leaf position in the stem was performed on sunflowers in the flowering stage.Eight differently positioned leaves were investigated,starting with the youngest leaf on the top of the stem to the leaves of the stem bottom,assigned as the oldest senescent leaves.According to chlorophyll fluorescence(ChlF)parameters connected to photosystem II(PSII)processes,significant changes in PSII functioning occurred only in the senescent leaves,while photosystem I(PSI)describing parameters showed a linear decrease with leaf age,i.e.,position on the stem.The antioxidative status of the leaves was dynamic,as stress indicators(lipid peroxidation and hydrogen peroxide content)fluctuated regarding leaf position on the stem,but no link was found between the activities of antioxidative enzymes and oxidative stress indicators.Linear decrease trend of secondary metabolites(mainly phenolic compounds)correlated with antioxidant activity,except for some phenolic acids(caffeic and ferulic acid),which increased in senescent leaves.The most changes in the physiological status of the leaves were confirmed in senescent leaves,which stand out the importance of younger leaves in maintaining the plant’s vitality after flowering,which is the most important for sunflower yield.
基金supported in part by the National Natural Science Foundation of China(Nos.62171375,62271397,62001392,62101458,62173276,61803310 and 61801394)the Shenzhen Science and Technology Innovation ProgramChina(No.JCYJ20220530161615033)。
文摘The existing Low-Earth-Orbit(LEO)positioning performance cannot meet the requirements of Unmanned Aerial Vehicle(UAV)clusters for high-precision real-time positioning in the Global Navigation Satellite System(GNSS)denial conditions.Therefore,this paper proposes a UAV Clusters Information Geometry Fusion Positioning(UC-IGFP)method using pseudoranges from the LEO satellites.A novel graph model for linking and computing between the UAV clusters and LEO satellites was established.By utilizing probability to describe the positional states of UAVs and sensor errors,the distributed multivariate Probability Fusion Cooperative Positioning(PF-CP)algorithm is proposed to achieve high-precision cooperative positioning and integration of the cluster.Criteria to select the centroid of the cluster were set.A new Kalman filter algorithm that is suitable for UAV clusters was designed based on the global benchmark and Riemann information geometry theory,which overcomes the discontinuity problem caused by the change of cluster centroids.Finally,the UC-IGFP method achieves the LEO continuous highprecision positioning of UAV clusters.The proposed method effectively addresses the positioning challenges caused by the strong direction of signal beams from LEO satellites and the insufficient constraint quantity of information sources at the edge nodes of the cluster.It significantly improves the accuracy and reliability of LEO-UAV cluster positioning.The results of comprehensive simulation experiments show that the proposed method has a 30.5%improvement in performance over the mainstream positioning methods,with a positioning error of 14.267 m.
文摘Forest ecosystems can be characterized by a set of catenas arranged along the slope in mountainous areas as these affect microhabitat features,which in turn influence soil properties.Heretofore,few studies have examined how topographic variables affect soil properties and quality in semiarid regions.This study aimed to provide important insights into how catena position and shape influence soil properties,soil quality,and their interrelationships in a semiarid protected oak forest in western Iran.Basic soil properties were measured in the laboratory.In addition,the soil quality index(SQI)was calculated at different topographic positions along both convex(Λ-shaped)and concave(V-shaped)catenas at two soil depths(0-15 and 15-30 cm).The findings indicated that soil organic carbon and total nitrogen declined in the lower depth in both V-andΛ-shaped catenas and at all catena positions.The lowest porosity was observed in the lower depth at toeslope positions(TS)of both catenas.Substrate-induced respiration(SIR),microbial biomass carbon(MBC),and basal respiration(BR)were higher in the upper depths at TS positions on V-shaped catenas than onΛ-shaped catenas.These biological indices were consistently higher in the upper depths than in the lower depths across all positions of both catenas.SQI had the highest values at TS positions on both catenas and in the upper depths across all positions.Pearson correlations between soil properties indicated that SQI was most strongly and positively correlated with biological properties in both catenas.The nutrient levels,microbial activity,and soil porosity in both catena shapes and at both soil depths displayed a relatively downward trend with increasing elevation from toeslope to summit positions.The results showed that catena topographic sequence shape and position affected most of the soil properties,providing evidence of the important role of topography in creating pedodiversity in oak forest ecosystems.
基金supported by China NSF Grants(62371225,62371227)Postgraduate Research&Practice Innovation Program of Jiangsu Province(KYCX250590).
文摘In this paper,we present a novel particle filter(PF)-based direct position tracking method utilizing multiple distributed observation stations.Traditional passive tracking methods are anchored on repetitive position estimation,where the set of consecutive estimates provides the tracking trajectory,such as Two-step and direct position determination methods.However,duplicate estimates can be computationally expensive.In addition,these techniques suffer from data association problems.The PF algorithm is a tracking method that avoids these drawbacks,but the conventional PF algorithm is unable to construct a likelihood function from the received signals of multiple observatories to determine the weights of particles.Therefore,we developed an improved PF algorithm with the likelihood function modified by the projection approximation subspace tracking with deflation(PASTd)algorithm.The proposed algorithm uses the projection subspace and spectral function to replace the likelihood function of PF.Then,the weights of particles are calculated jointly by multiple likelihood functions.Finally,the tracking problem of multiple targets is solved by multiple sets of particles.Simulations demonstrate the effectiveness of the proposed method in terms of computational complexity and tracking accuracy.
基金the Obstetrics and Gynecology Hospital of Fudan University for supporting this project。
文摘Objectives A systematic review and network meta-analysis was conducted to evaluate the effectiveness of different childbirth positions in reducing the duration of the second stage of labor,providing evidence-based insights for obstetric institutions to guide interventions related to childbirth positions.Methods A comprehensive literature search was conducted in databases,including PubMed,Web of Science,the Cochrane Library,Embase,Wanfang Databases,China National Knowledge Infrastructure Databases(CNKI),China Science and Technology Journal Database(CSTJ),and China Biology Medicine disc(CBMdisc)to identify studies on the effectiveness of different childbirth positions in reducing the duration of the second stage of labor.The search included randomized controlled trials published from database inception to September 30,2024.The Cochrane risk-of-bias tool was used to assess the quality of the studies.Two independent reviewers screened the literature,extracted data,and evaluated study quality.Subsequently,a network meta-analysis was performed using STATA software.The study protocol has been registered in PROSPERO(CRD42023428217).Results This study analyzed data from 25 randomized controlled trials involving 9,844 women.The findings indicated that in comparison to lithotomy position,free position(MD=20.53,95%CI[11.38,29.68])and upright position(MD=−24.13,95%CI[−42.94,-5.32])were found to be superior in reducing the duration of the second stage of labor.Free position outperformed kneeling position(MD=21.48,95%CI[4.67,38.28])and squatting position(MD=23.43,95%CI[1.88,44.97]);upright position was superior to kneeling position(MD=−25.08,95%CI[−46.93,−3.22]);semirecumbent position surpassed squatting position(MD=19.71,95%CI[2.05,37.38]);and upright position was also superior to squatting position(MD=−27.03,95%CI[−51.48,−2.57]).According to the surface under the cumulative ranking curve(SUCRA),the upright position emerged as the most effective for reducing the duration of the second stage of labor(87.4%),followed by free position(81.1%),semirecumbent position(70.0%),and lateral position(62.3%).Conclusion These findings offer valuable insights for midwifery practice and help inform future research directions.Considering the limitations of this review,more larger-scale,multicenter randomized controlled trials are warranted to further evaluate the relative effectiveness of different childbirth positions in reducing the duration of the second stage of labor.
基金supported by the Shandong Provincial Natural Science Foundation,China(No.ZR2020MA078)。
文摘Four benzocoumarin-based two-photon fluorescent probes(BH1-BH4)are proposed for ra-tiometric detection of hypochlorous acid(HClO)and their two-photon sensing perfor-mance are evaluated by means of time-dependent density func-tional theory and quadratic re-sponse theory.The effects of benzene-fused position on Stokes shift,fluorescence quantum yield and two-photon absorption are discussed comprehensively.The results show that fusing a benzene ring in coumarin can enhance Stokes shift efficiently.The benzene-fused position has important effects on these photophysical properties.The benzo[g]coumarins(BH1)and benzo[f]coumarins(BH2)derivatives have larger Stokes shifts in comparison with benzo[h]coumarins(BH3)and dihydrophenazine(BH4)derivatives.The two-photon absorp-tion of benzo[f]coumarins(BH2)derivative is much smaller than those of other benzo-coumarins derivatives.The large Stokes shift and increased two-photon action cross section can be achieved simultaneously in the dihydrophenazine(BH4)derivative.Therefore,the de-signed BH4 is expected to have superior performance for the ratiometric detection of HClO.To explore the reasons behind these effects,the intramolecular charge transfer degrees are il-lustrated quantitatively by plotting the hole-electron isosurface map,and the relation be-tween charge transfer and Stokes shift is revealed.A two-state model analysis is employed to understand two-photon absorption ability.Moreover,the fluorescence near-quenching mecha-nism of the product molecules B1 and B3 is explained by analyzing reorganization energy and Huang-Rhys factor,as well as related normal mode.Our research could contribute to the effi-cient design of ratiometric two-photon fluorescent probes with large Stokes shift and signifi-cant two-photon action cross section.
基金financially supported by the National Natural Science Foundation of China(No.41901132)the Natural Scientific Project of Guangxi Zhuang Autonomous Region(Nos.2019GXNSFAA185015,2021GXNSFBA220025)+1 种基金the Interdisciplinary Scientific Research Foundation of Guangxi University(No.2022JCC026)the Project of Key Laboratory of Early Rapid Identification,Prevention and Control of Geological Diseases in Traffic Corridor of High Intensity Earthquake Mountainous Area of Yunnan Province(No.KLGDTC-2021-01)。
文摘Granite residual soil slope is often destroyed,which poses great threats to Rong County in southeastern Guangxi,China.Heavy rainfall and fissures are the major triggering and internal factors.The fissure that controls the slope stability and the associated failure mechanisms remain unclear.The purpose of this study was to identify the controlling fissures through field investigation,elucidate the effect of its position,and analyze the failure process and hydrological response of residual soil slope through artificial flume model tests.The results comprised five aspects.(1)Surface weathering and unloading fissures could affect slope stability.(2)The failure processes with different fissure positions exhibited inconsistent characteristics.(3)The volume moisture content(VMC)had the most direct response at the fissure tip.The corresponding infiltration rate was the highest.The response time of pore water pressure(PWP)was longer than that of VMC.Fluctuations in PWP were associated with VMC and changes in the soil microstructure due to local deformation.(4)Slope failure was accompanied by serious soil erosion.This could be attributed to the infiltration direction and the interaction between soil and water.(5)Fissured soil slopes experienced five similar failure processes:sheet erosion and partial failure of the slope foot,occurrence of preferential flow and enlargement of the sliding area,creep deformation and tension fissure emergence,block sliding and gully erosion,and flow-slip.
基金supported by the Corps Leading Talents Program,China(2023YZ01)the Tianshan Talent Training Program,China(2023TS05)the Crop Smart Production Innovation Team,China(2023TD01).
文摘Potassium(K)is a highly mobile nutrient element that continuously adjusts its demand strategy among and within cotton leaves through redistribution,indirectly leading to variations in the leaf potassium content(LKC,%)at different leaf positions.However,due to the interaction between light and leaf age,leaf sensitivity to this change varies at different positions,including the reflection and absorption of the spectrum.Selecting the optimal leaf position for monitoring is a crucial factor in the rapid and accurate evaluation of cotton LKC using spectral remote sensing technology.Therefore,this study proposes a comprehensive multi-leaf position estimation model based on the vertical distribution characteristics of LKC from top to bottom,aiming to achieve an accurate estimation of cotton LKC and optimize the strategy for selecting the monitored leaf position.Between 2020 and 2021,we collected hyperspectral imaging data of the main stem leaves at different positions from top to bottom(Li,i=1,2,3,...,n)during the cotton budding,flowering,and boll-setting stages.Vertical distribution characteristics,sensitivity differences,and spectral correlations of LKC at different leaf positions were investigated.Additionally,the optimal range of the dominant leaf position for monitoring was determined.Partial least squares regression(PLSR),random forest regression(RFR),support vector machine regression(SVR),and the entropy weight method(EWM)were employed to develop LKC estimation models for single-and multi-leaf positions.The results showed a vertical heterogeneous distribution of cotton LKC,with LKC initially increasing and then gradually decreasing from top to bottom;the average LKC of cotton reached its maximum value at the flowering stage.The upper leaf position demonstrated greater sensitivity to K and exhibited a stronger correlation with the spectrum.The selected dominant leaf positions for the three growth stages were L1-L5,L1-L4,and L1-L2,respectively.Based on the dominant leaf position monitoring range,the optimal single leaf position models for estimating LKC during the three growth stages were PLSR-L4,PLSR-L1,and SVR-L2,with the coefficient of determination of the validation set(R2val)being 0.786,0.580,and 0.768,and the root-mean-square error of the validation set(RMSEval)being 0.168,0.197,and 0.191,respectively.The multi-leaf position LKC estimation model was constructed by EWM with R2val being 0.887,0.728,and 0.703,and RMSEval being 0.134,0.172,and 0.209,respectively.In contrast,the newly developed multi-leaf position comprehensive estimation model yielded superior results,improving the model’s stability based on high accuracy,especially during the budding and flowering stages.These findings hold significant importance for investigating cotton LKC spectral models and selecting suitable leaf positions for field monitoring.
基金supported in part by the National Natural Science Foundation of China under Grants 52277057 and U22A20217in part by the Shandong Youth Innovation Team under Grant 2022KJ150。
文摘Position sensors are indispensable in robotic joint servo systems for acquiring mechanical positions, yet their installation inevitably occupies an axial space and increases system complexity, limiting their applicability in compact robot design where spatial constraints and integration efficiency are critical. Sensorless control reduces mechanical and circuit complexity through hardware simplification, but inherently estimates only the electrical instead of mechanical rotor position information, thus remaining constrained in robot joint control applications. Based on the previously proposed dual-gap dualpole composite machine(DDCM), this paper systematically analyzes the causes of mechanical position estimation errors and proposes a correction method that utilizes a correction coefficient to reduce these errors and enhance estimation accuracy. Furthermore, this paper derives the applicability constraints of the proposed scheme, demonstrating that its requirements for electrical angle position errors are not stringent, thus enabling wide applicability in conventional sensorless control scenarios. The effectiveness of the proposed method is verified by conducting experiments on a 0.75 kW prototype.
基金fnancially supported by the Natural Science Foundation of Hebei Province,China(C2021301004)the State Key Laboratory of North China Crop Improvement and Regulation,China(NCCIR2023KF-10)the HAAFS Science and Technology Innovation Special Project,China(2022KJCXZX-LYS-9)。
文摘The intensified kernel position effect is a common phenomenon in maize production under higher plant density,which limits crop productivity.Subsoiling is an effective agronomic practice for improving crop productivity.To clarify the effect of subsoiling before winter wheat on the kernel position effect of densely grown summer maize and its regulatory mechanism,field experiments were conducted during the 2020-2021 and 2021-2022 growing seasons using a split-plot design.The main plots included two tillage practices:conventional tillage practice(CT)and subsoiling before the sowing of winter wheat(SS);and the subplots consisted of three plant densities(D1-D3 at 6.0×10~4,7.5×10~4,and 9.0×10~4 plants ha-1).Compared with CT,SS alleviated the kernel position effect by increasing the weight ratio of inferior to superior kernels(WR)in the D2 and D3 treated plants.The higher WR of SS treated plants contributed largely to the improved flling of inferior kernels.Under the same plant density,SS signifcantly improved the root dry matter accumulation(DMA)and antioxidant enzyme activities(superoxide dismutase(SOD)and peroxidase(POD)),and it reduced the malondialdehyde(MDA)content,especially for the plants grown under higher plant densities.These results indicated that SS delayed the root senescence,which is associated with the reduced soil bulk density.In addition,compared with CT,SS increased the leaf chlorophyll content from 20 days after silking to physiological maturity and the post-silking leaf area duration,and it reduced the post-silking leaf chlorophyll reduction rate and leaf area reduction rate,indicating that the post-silking leaf senescence had been alleviated.Under the same plant density,the post-silking DMA of SS was obviously higher than that of CT,which was probably related to the improved leaf area duration and photosynthetic enzyme activities(phosphoenolpyruvate carboxylase(PEPC)and Rubisco).The correlation analysis revealed that the main mechanism of SS in alleviating the kernel position effect of densely grown summer maize is as follows:SS delays the post-silking root-shoot senescence by regulating soil physical properties,and further improves the post-silking DMA and flling of inferior kernels,which ultimately alleviates the kernel position effect and improves grain yield.The results of this study provide new theoretical support for the promotion of summer maize yield by subsoiling before winter wheat.
基金supported by National Natural Science Foundation of China(Grant No.62073256)Shaanxi Provincial Science and Technology Department(Grant No.2023-YBGY-342)。
文摘To solve the problem of identification and measurement of two projectiles hitting the target at the same time,this paper proposes a projectile coordinate test method combining three photoelectric encoder detection screens,and establishes a coordinate calculation model for two projectiles to reach the same detection screen at the same time.The design method of three photoelectric encoder detection screens and the position coordinate recognition algorithm of the blocked array photoelectric detector when projectile passing through the photoelectric encoder detection screen are studied.Using the screen projection method,the intersected linear equation of the projectile and the line laser with the main detection screen as the core coordinate plane is established,and the projectile coordinate data set formed by any two photoelectric encoder detection screens is constructed.The principle of minimum error of coordinate data set is used to determine the coordinates of two projectiles hitting the target at the same time.The rationality and feasibility of the proposed test method are verified by experiments and comparative tests.
基金Project(52272339)supported by the National Natural Science Foundation of ChinaProject(2023YFB390730303)supported by the National Key Research and Development Program of China+2 种基金Project(L2023G004)supported by the Science and Technology Research and Development Program of China State Railway Group Co.,Ltd.Project(QZKFKT2023-005)supported by the State Key Laboratory of Heavy-duty and Express High-power Electric Locomotive,ChinaProject(2022JZZ05)supported by the Open Foundation of MOE Key Laboratory of Engineering Structures of Heavy Haul Railway(Central South University),China。
文摘In this paper,a novel train positioning method considering satellite raw observation data was proposed,which aims to promote train positioning performance from an innovative perspective of the train satellite-based positioning error sources.The method focused on overcoming the abnormal observations in satellite observation data caused by railway environment rather than the positioning results.Specifically,the relative positioning experimental platform was built and the zero-baseline method was firstly employed to evaluate the carrier phase data quality,and then,GNSS combined observation models were adopted to construct the detection values,which were applied to judge abnormal-data through the dual-frequency observations.Further,ambiguity fixing optimization was investigated based on observation data selection in partly-blocked environments.The results show that the proposed method can effectively detect and address abnormal observations and improve positioning stability.Cycle slips and gross errors can be detected and identified based on dual-frequency global navigation satellite system data.After adopting the data selection strategy,the ambiguity fixing percentage was improved by 29.2%,and the standard deviation in the East,North,and Up components was enhanced by 12.7%,7.4%,and 12.5%,respectively.The proposed method can provide references for train positioning performance optimization in railway environments from the perspective of positioning error sources.
