Liquid nitrogen(LN_(2))and microwave are the alternative methods for reservoir fracturing,which are rarely combined.To investigate the combined effects,sandstone is frozen with LN_(2)before microwave heating(MI),and n...Liquid nitrogen(LN_(2))and microwave are the alternative methods for reservoir fracturing,which are rarely combined.To investigate the combined effects,sandstone is frozen with LN_(2)before microwave heating(MI),and nuclear magnetic resonance(NMR),ultrasonic wave,and infrared thermal imaging(ITI)are used to understand the pore structures,moisture change,and surface temperature of the sandstone samples.With the heating time,the average surface temperature of the combining-treatment samples firstly increases from the room temperature(25℃)to 144.7℃(65 s)fast,and then increases slowly to 176.6℃(95 s).For the individual MI,the temperature increases to 146.7℃at 65 s.As 30 min of LN_(2)freezing,the samples perform well in removing pore water during heating.The NMR results show that after LN_(2)freezing,the seepage pores and total pores increase by 2.93%and 4.11%,respectively,and the pore connectivity enhances.However,the individual MI performs weak in enhancing the pore structures,forming a high vapor pressure(0.428 MPa at 65 s)and causing burst after 65 s.Due to the improved pore connectivity,the vapor pressure(0.378 MPa)and temperature are small at 65 s,and burst can be avoided.After freezing,the wave velocity decreases by 13.48%and the damage variable reaches 0.251.The velocity attenuation rates and damage variable gradually increase with heating time;under the same duration,the two variables of the combining treatments are greater than that of the individual treatments.This can prove a reference for gas production in sandstone reservoirs.展开更多
Porous Ni3Al intermetallics were fabricated by elemental powder reactive synthesis method, using carbamide powders as space holders. Corrosion behavior of porous Ni3Al intermetallics was investigated in a 6 mol/L KOH ...Porous Ni3Al intermetallics were fabricated by elemental powder reactive synthesis method, using carbamide powders as space holders. Corrosion behavior of porous Ni3Al intermetallics was investigated in a 6 mol/L KOH solution using electrochemical methods and immersion test. Effect of porous structures on the corrosion behavior of the porous Ni3Al intermetallics was studied. The results indicate that the porous Ni3Al intermetallics with higher porosities suffer more serious corrosion than the ones with lower porosities because the complicated interconnected porous structures and the large true surface areas exist in the samples with a higher porosity. But the corrosion rates of the porous Ni3Al intermetallics are not proportional to the true surface areas. The reason is that the pore size, pore size distribution and pore shape of the porous Ni3Al intermetallics change with the increasing porosity. All the porous Ni3Al intermetallics with different porosities exhibit excellent corrosion resistance in a strong alkali solution.展开更多
We developed an anisotropic effective theoretical model for modeling the elastic behavior of anisotropic carbonate reservoirs by combining the anisotropic self-consistent approximation and differential effective mediu...We developed an anisotropic effective theoretical model for modeling the elastic behavior of anisotropic carbonate reservoirs by combining the anisotropic self-consistent approximation and differential effective medium models.By analyzing the measured data from carbonate samples in the TL area,a carbonate pore-structure model for estimating the elastic parameters of carbonate rocks is proposed,which is a prerequisite in the analysis of carbonate reservoirs.A workflow for determining elastic properties of carbonate reservoirs is established in terms of the anisotropic effective theoretical model and the pore-structure model.We performed numerical experiments and compared the theoretical prediction and measured data.The result of the comparison suggests that the proposed anisotropic effective theoretical model can account for the relation between velocity and porosity in carbonate reservoirs.The model forms the basis for developing new tools for predicting and evaluating the properties of carbonate reservoirs.展开更多
Hydrophilic characteristics of rocks are affected by their microscopic pore structures,which clearly change after water absorption.Water absorption tests and scanning electron microscopic（SEM） experiments on rock sa...Hydrophilic characteristics of rocks are affected by their microscopic pore structures,which clearly change after water absorption.Water absorption tests and scanning electron microscopic（SEM） experiments on rock samples,located at a site in Tibet,China,were carried out Changes of rock pore structures before and after water absorption were studied with the distribution of pore sizes and fractal characteristics of pores.The results show that surface porosities,fractal dimensions of pores and the complexity of pore structures increased because the number of new small pores produced increased or the original macropore flow channels were expanded after rocks absorbed water.There were points of inflection on their water absorption curves.After water absorption of other rocks,surface porosities and fractal dimensions of pores and complexity of pore structures decreased as the original pore flow channels became filled.Water absorption curves did not change.Surface porosity and the pore fractal dimensions of rocks have good linear relationships before and after water absorption.展开更多
Co–Mo catalysts applied on the hydrodesulfurization（HDS） for FCC gasoline were prepared with Zn–Al layered double hydroxides（LDHs） to improve their performances,and the effects of pore structures and acidity on ...Co–Mo catalysts applied on the hydrodesulfurization（HDS） for FCC gasoline were prepared with Zn–Al layered double hydroxides（LDHs） to improve their performances,and the effects of pore structures and acidity on HDS performances were studied in detail. A series of Zn–Al/LDHs samples with different pore structures and acidities are synthesized on the bases of co-precipitation of OH-,CO2-,Al3＋,and Zn2＋. The neutralization p H is a main factor to affect the pore structures and acidity of Zn–Al/LDHs,and a series of Zn–Al/LDHs with different pore structures and acidities are obtained. Based on the representative samples with different specific surface areas（SBET） and acidities,three Co Mo/LDHs catalysts were prepared,and their HDS performances were compared with traditional Co Mo/Al2O3 catalysts. The results indicated that catalysts prepared with high SBETpossessed high HDS activity,and Br？nsted acid sites could reduce the thiol content in the product to some extent. All the three catalysts prepared with LDHs displayed little lower HDS activity but higher selectivity than Co Mo/Al2O3,and could restrain the reactions of re-combination between olefin and H2 S which could be due to the existence of Br？nsted acid sites.展开更多
Three cement samples were prepared, includi ng OPC consisted of 100wt% portland cement, PFA consisted of 70wt% portland cemen t and 30wt% fly-ash, and CA consisted of 70wt% portland cement and 30wt% modifi ed fly ash...Three cement samples were prepared, includi ng OPC consisted of 100wt% portland cement, PFA consisted of 70wt% portland cemen t and 30wt% fly-ash, and CA consisted of 70wt% portland cement and 30wt% modifi ed fly ash. The strength of hardened cement paste of these samples was tested an d their pore structures were determined by a mercury intrusion porosimeter. More over,the data of the pore structures of three samples were comprehensively analy zed. The relations between the pore structures and the compressive strength of t he three samples were studied. The experimental results show that the relations between the porosity determined by the mercury intrusion porosimeter and the com pressive strength are not notable, and the total pore surface area, the average pore diameter and the median pore diameter could be used to explain the differen ce of the strength of the tested samples.展开更多
Based on the experiments of nitrogen gas adsorption(N_2 GA) and nuclear magnetic resonance(NMR),the multifractal characteristics of pore structures in shale and tight s andstone from the Chang 7 member of Trias sic Ya...Based on the experiments of nitrogen gas adsorption(N_2 GA) and nuclear magnetic resonance(NMR),the multifractal characteristics of pore structures in shale and tight s andstone from the Chang 7 member of Trias sic Yanchang Formation in Ordos Basin,NW China,are investigated.The multifractal spectra obtained from N2 GA and NMR are analyzed with pore throat structure parameters.The results show that the pore size distributions obtained from N2 GA and NMR are different,and the obtained multifractal characteristics vary from each other.The specific surface and total pore volume obtained by N2 GA experiment have correlations with multifractal characteristics.For the core samples with the similar specific surface,the value of the deviation of multifractal spectra Rd increases with the increase in the proportion of large pores.When the proportion of macropores is small,the Rd value will increase with the increase in specific surface.The multifractal characteristics of pore structures are influenced by specific surface area,average pore size and adsorption volume measured from N2 GA experiment.The multifractal characteristic parameters of tight sandstone measured from NMR spectra are larger than those of shale,which may be caused by the differences in pore size distribution and porosity of shale and tight sandstone.展开更多
The adsorption of methane onto five dry coal samples was measured at 298 K over the pressure range from 0 to 3.5 MPa using a volumetric method.The isotherm data were fitted to the Langmuir and the Freundlich equations...The adsorption of methane onto five dry coal samples was measured at 298 K over the pressure range from 0 to 3.5 MPa using a volumetric method.The isotherm data were fitted to the Langmuir and the Freundlich equations.The kinetic data were fitted to a pseudo second order equation,the linear driving force equation(LDF),and an intra-particle diffusion model.These results showed that higher methane adsorption is correlated with larger micro-pore volumes and specific surface areas.The adsorption was related to the narrow micro-pore size distribution when the previous two parameters are large.The kinetics study showed that the kinetics of methane adsorption onto these five dry coal samples followed a pseudo second order model very well.Methane adsorption rates are controlled by intra-particle diffusion.The faster the intra-particle diffusion,the faster the methane adsorption rate will be.展开更多
Microcosmic details of pore structure are the essential factors affecting the elastic properties of tight sandstone reservoirs,while the relationships in between are still incompletely clear due to the fact that quant...Microcosmic details of pore structure are the essential factors affecting the elastic properties of tight sandstone reservoirs,while the relationships in between are still incompletely clear due to the fact that quantitative or semi-quantitative experiments are hard to achieve.Here,three sets of tight sandstone samples from the Junggar Basin are selected elaborately based on casting thin sections,XRD detection,and petro-physical measurement,and each set is characterized by a single varied microcosmic factor(pore connectedness,pore type,and grain size)of the pore structure.An ultrasonic pulse transmission technique is conducted to study the response of elastic properties to the varied microcosmic details of pore structure in the situation of different pore fluid(gas,brine,and oil)saturation and confining pressure.Observations show samples with less connectedness,inter-granular dominant pores,and smaller grain size showed greater velocities in normal conditions.Vpis more sensitive to the variations of pore type,while Vsis more sensitive to the variations of grain size.Samples with better connectedness at fluid saturation(oil or brine)show greater sensitivity to the confining pressure than those with gas saturation with a growth rate of 6.9%-11.9%,and the sensitivity is more likely controlled by connectedness.The pore types(inter-granular or intra-granular)can be distinguished by the sensitivity of velocities to the variation of pore fluid at high confining pressure(>60 MPa).The samples with small grain sizes tend to be more sensitive to the variations of confining pressure.With this knowledge,we can semi-quantitatively distinguish the complex pore structures with different fluids by the variation of elastic properties,which can help improve the precision of seismic reservoir prediction for tight sandstone reservoirs.展开更多
The wave-induced local fluid flow mechanism is relevant to the complex heterogeneity of pore structures in rocks.The analysis of the local fluid flow mechanism is useful for accurately describing the wave propagation ...The wave-induced local fluid flow mechanism is relevant to the complex heterogeneity of pore structures in rocks.The analysis of the local fluid flow mechanism is useful for accurately describing the wave propagation characteristics in reservoir rocks.In the exploration and production of hydrocarbon reservoirs,the real stratum may be partially saturated with a multi-phase fluid mixture in general.Therefore,it is of great significance to investigate the wave velocity dispersion and attenuation features in relation to pore structures and fluids.In this work,the characteristics of fabric microstructures are obtained on the basis of pressure dependency of dry rock moduli using the effective medium theory.A novel anelasticity theoretical model for the wave propagation in a partially-saturated medium is presented by combining the extended Gurevich squirt-flow model and White patchysaturation theory.Numerical simulations are used to analyze wave propagation characteristics that depend on water saturation,external patchy diameter,and viscosity.We consider a tight sandstone from the Qingyang area of the Ordos Basin in west China and perform ultrasonic measurements under partial saturation states and different confining pressures,where the basic properties of the rock are obtained at the full gas saturation.The comparison of experimental data and theoretical modeling results shows a fairly good agreement,indicating that the new theory is effective.展开更多
A green biocompatible foaming method utilizing natural coconut oil and cornstarch was developed to fabricate highly porous functional ceramics with controllable strengths and pore structures. The poros- ity of A1203 c...A green biocompatible foaming method utilizing natural coconut oil and cornstarch was developed to fabricate highly porous functional ceramics with controllable strengths and pore structures. The poros- ity of A1203 ceramics prepared via this method reached 79.6%-86.9% while these ceramics maintained high compressive strengths of 2.2-5.5 MPa. More importantly, porous A1203 ceramic with a pore size gra- dient was also readily fabricated by casting serial layers of foams that were set for different time periods. The potential applications of porous Al2O3 and HA ceramics fabricated by this green foaming method in- cluding scaffolds for oil cleaning and cell culture, respectively, were also demonstrated.展开更多
Open-celled porous （TiB2-Al2O3）/NiAl composites were successfully fabricated by using spherical carbamide as space holders via self-propagating high-temperature synthesis （SHS）. Effects of 10Al-3B2O3-3TiO2 conten...Open-celled porous （TiB2-Al2O3）/NiAl composites were successfully fabricated by using spherical carbamide as space holders via self-propagating high-temperature synthesis （SHS）. Effects of 10Al-3B2O3-3TiO2 contents （0-20 wt%） on the pore structures and the quasi-static compressive behaviors of the resultant materials were investigated. The porous （TiBE-Al2O3）/NiAl composites exhibit composite pore structure consisting of homogeneously distributed and interconnected millimeter pores and micropores. The millimeter pores virtually inherit the shape and size of carbamide particles, while the pore size of micropores increases with increasing the 10Al-3BEO3-3TiO2 content. Depending on the volume fraction of the carbamide, the porosity of the porous materials can be easily controlled in a range of 55%-85%. When the porosity is about 72%, the compressive strengths of porous NiAl and porous （TiBE-Al203）/NiAl composite with 15% 10Al-3B2O3-3TiO2 in green compact are 19 and 32 MPa, and the corresponding strains are 2.9% and 5.7%, respectively. Furthermore, the quasi-static compressive behavior of porous （TiB2-AlEO3）/NiAl composites can be estimated by Gibson-Ashby model.展开更多
Pore structures in shales are a main factor affecting the storage capacity and production performance of shale gas reservoirs.Taking Longmaxi Shales in the Jiaoshiba area of the Sichuan Basin as a study object,we syst...Pore structures in shales are a main factor affecting the storage capacity and production performance of shale gas reservoirs.Taking Longmaxi Shales in the Jiaoshiba area of the Sichuan Basin as a study object,we systematically study the microscopic pore structures of shales by using Argon-ion polishing Scanning Electron Microscope(SEM),high-pressure mercury injection and low-temperature nitrogen adsorption and desorption experiments.The study results show that:the Longmaxi Shale in this area are dominated by nano-scale pores which can be classified into organic pores,inorganic pores(intergranular pores,intragranular pores,inter-crystalline pores and dissolution pores),microfractures(intragranular structure fractures,interlayer sliding fractures,diagenetic shrinkage joints and abnormal-pressure fractures from organic evolution),among which organic pores and clay mineral pores are predominant and organic pores are the most common;a TOC value shows an obvious positive correlation with the content of organic pores,which account for up to 50%in the lower-quality shales with a TOC of over 2%where they are most developed;microscopic pore structures are very complex and open,with pores being mainly in cylinder shape with two ends open,or in parallel tabular shape with four sides open and 2–30 nm in diameter,being mostly medium pores.On this basis,factors affecting the micropore structures of shales in this area are studied.It is concluded that organic matter abundance and thermal maturity are the major factors controlling the microscopic pore structures of shales,while the effects of clay mineral content are relatively insignificant.展开更多
High-temperature infrared-regulating ceramics are essentialfoerxtreme-environmentapplicationsrequiring broadband infrared reflection(1-6μm),such as spacecraft thermal protection,military stealth systems,and related f...High-temperature infrared-regulating ceramics are essentialfoerxtreme-environmentapplicationsrequiring broadband infrared reflection(1-6μm),such as spacecraft thermal protection,military stealth systems,and related fields.Precise control of pore structures is crucial for enhancing ceramic infrared reflectance,as pores directly influence the scattering intensity and scattering path of radiation.However,achieving broadband reflectance above 0.9 remains challenging because of unclear pore-radiation interaction mechanisms and insufficient structural control.This study employs optical simulations to systematically analyze how pore parameters enhance infrared reflectance.The results demonstrate that pore sizes matching the infrared wavelength,highaspect ratios,and aligned orientations synergistically enhance reflection.Guided by simulations,directional pore-structured yttria-stabilized zirconia(YSZ)ceramics were fabricated via a rolling extrusion method using graphite flakes as sacrificial templates.The optimized ceramics exhibited tailored pore parameters(size:0.2-6μm,aspect ratio:3.2-3.9,orientation angle:<30°),achieving exceptional infrared reflectance(>0.9).This study clarifies pore-radiation interactions and presents a scalable strategy to produce advanced thermal shielding materials.展开更多
The Lower Cambrian shales in the Sichuan Basin are considered one of the most promising shale gas resources in China.However,large-scale commercial development has not been achieved due to the relatively low and signi...The Lower Cambrian shales in the Sichuan Basin are considered one of the most promising shale gas resources in China.However,large-scale commercial development has not been achieved due to the relatively low and significantly variable gas contents of the drilled shales.Excitingly,the first major breakthrough in deep and ultra-deep Lower Cambrian shale gas was made recently in the well Z201 in the southern Sichuan Basin,with a gas yield exceeding 73×10^(4)m^(3)/d.The success of well Z201 provides a favorable geological case to reveal the distinct enrichment mechanism of deep and ultra-deep Lower Cambrian shale gas.In this study,at drilling site of well Z201,fresh shale core samples with different gasin-place contents were collected,and their geochemical,pore development and water-bearing characteristics were analyzed systematically.The results showed that the Z201 organic-rich shales reached an overmature stage,with an average Raman maturity of 3.70%.The Z201 shales with high gas-in-place contents are mainly located in the Qiongzhusi 12section and the upper Qiongzhusi 11section,with an average gas-in-place content of 10.08 cm^(3)/g.Compared to the shales with low gas-in-place contents,the shales with high gas-in-place contents exhibit higher total organic carbon contents,greater porosities,and lower water saturations,providing more effective pore spaces for shale gas enrichment.The effective pore structures of the deep and ultra-deep Lower Cambrian shales are the primary factors affecting their gas-in-place contents.Similar to the shales with high gas-in-place contents of well Z201,the deep and ultra-deep Lower Cambrian shales in the Mianyang-Changning intracratonic sag,especially in the Ziyang area,generally developed in deep-water shelf facies with high total organic carbon contents and thick sedimentary thickness,providing favorable conditions for the development and preservation of effective pores.Therefore,they are the most promising targets for Lower Cambrian shale gas exploration.展开更多
Oil transport is greatly affected by heterogeneous pore–throat structures present in shale.It is therefore very important to accurately characterize pore–throat structures.Additionally,it remains unclear how pore–t...Oil transport is greatly affected by heterogeneous pore–throat structures present in shale.It is therefore very important to accurately characterize pore–throat structures.Additionally,it remains unclear how pore–throat structures affect oil transport capacity.In this paper,using finite element(FE)simulation and mathematical modeling,we calculated the hydrodynamic resistance for four pore–throat structure.In addition,the influence of pore throat structure on shale oil permeability is analyzed.According to the results,the hydrodynamic resistance of different pore throat structures can vary by 300%.The contribution of additional resistance caused by streamline bending is also in excess of 40%,even without slip length.Fur-thermore,Pore–throat structures can affect apparent permeability by more than 60%on the REV scale,and this influence increases with heterogeneity of pore size distribution,organic matter content,and organic matter number.Clearly,modeling shale oil flow requires consideration of porous–throat structure and additional resistance,otherwise oil recovery and flow capacity may be overestimated.展开更多
Understanding the impact of mining disturbances and creep deformation on the macroscopic deformation and the microscopic pore and fracture structures(MPFS)of coal is paramount for ensuring the secure extraction of coa...Understanding the impact of mining disturbances and creep deformation on the macroscopic deformation and the microscopic pore and fracture structures(MPFS)of coal is paramount for ensuring the secure extraction of coal resources.This study conducts cyclic loading-unloading and creep experiments on coal using a low-field nuclear magnetic resonance(NMR)experimental apparatus which is equipped with mechanical loading units,enabling real-time monitoring the T2spectrum.The experiments indicated that cyclic loading-unloading stress paths initiate internal damage within coal samples.Under identical creep stress conditions,coal samples with more initial damages had more substantial instantaneous deformation and creep deformation during the creep process.After undergoing nearly 35 h of staged creep,the total strains for coal samples CC01,CC02,and CC03 reach 2.160%,2.261%,and 2.282%,respectively.In the creep stage,the peak area ratio of seepage pores and microfractures(SPM)gradually diminishes.A higher degree of initial damage leads to a more pronounced compaction trend in the SPM of coal samples.Considering the porosity evolution of SPM during the creep process,this study proposes a novel fractional derivative model for the porosity evolution of SPM.The efficacy of the proposed model in predicting porosity evolution of SPM is substantiated through experimental validation.Furthermore,an analysis of the impact mechanisms on key parameters in the model was carried out.展开更多
Based on the experimental results of casting thin section,low temperature nitrogen adsorption,high pressure mercury injection,nuclear magnetic resonance T2 spectrum,contact angle and oil-water interfacial tension,the ...Based on the experimental results of casting thin section,low temperature nitrogen adsorption,high pressure mercury injection,nuclear magnetic resonance T2 spectrum,contact angle and oil-water interfacial tension,the relationship between pore throat structure and crude oil mobility characteristics of full particle sequence reservoirs in the Lower Permian Fengcheng Formation of Mahu Sag,Junggar Basin,are revealed.(1)With the decrease of reservoir particle size,the volume of pores connected by large throats and the volume of large pores show a decreasing trend,and the distribution and peak ranges of throat and pore radius shift to smaller size in an orderly manner.The upper limits of throat radius,porosity and permeability of unconventional reservoirs in Fengcheng Formation are approximately 0.7μm,8%and 0.1×10^(−3)μm^(2),respectively.(2)As the reservoir particle size decreases,the distribution and peak ranges of pores hosting retained oil and movable oil are shifted to a smaller size in an orderly manner.With the increase of driving pressure,the amount of retained and movable oil of the larger particle reservoir samples shows a more obvious trend of decreasing and increasing,respectively.(3)With the increase of throat radius,the driving pressure of reservoir with different particle levels presents three stages,namely rapid decrease,slow decrease and stabilization.The oil driving pressures of various reservoirs and the differences of them decrease with the increase of temperature and obviously decrease with the increase of throat radius.According to the above experimental analysis,it is concluded that the deep shale oil of Fengcheng Formation in Mahu Sag has great potential for production under geological conditions.展开更多
The development of sustainable electrode materials for energy storage systems has become very important and porous carbons derived from biomass have become an important candidate because of their tunable pore structur...The development of sustainable electrode materials for energy storage systems has become very important and porous carbons derived from biomass have become an important candidate because of their tunable pore structure,environmental friendliness,and cost-effectiveness.Recent advances in controlling the pore structure of these carbons and its relationship between to is energy storage performance are discussed,emphasizing the critical role of a balanced distribution of micropores,mesopores and macropores in determining electrochemical behavior.Particular attention is given to how the intrinsic components of biomass precursors(lignin,cellulose,and hemicellulose)influence pore formation during carbonization.Carbonization and activation strategies to precisely control the pore structure are introduced.Finally,key challenges in the industrial production of these carbons are outlined,and future research directions are proposed.These include the establishment of a database of biomass intrinsic structures and machine learning-assisted pore structure engineering,aimed at providing guidance for the design of high-performance carbon materials for next-generation energy storage devices.展开更多
Changes to the microstructure of a hard carbon(HC)and its solid electrolyte interface(SEI)can be effective in improving the electrode kinetics.However,achieving fast charging using a simple and inexpensive strategy wi...Changes to the microstructure of a hard carbon(HC)and its solid electrolyte interface(SEI)can be effective in improving the electrode kinetics.However,achieving fast charging using a simple and inexpensive strategy without sacrificing its initial Coulombic efficiency remains a challenge in sodium ion batteries.A simple liquid-phase coating approach has been used to generate a pitch-derived soft carbon layer on the HC surface,and its effect on the porosity of HC and SEI chemistry has been studied.A variety of structural characterizations show a soft carbon coating can increase the defect and ultra-micropore contents.The increase in ultra-micropore comes from both the soft carbon coatings and the larger pores within the HC that are partially filled by pitch,which provides more Na+storage sites.In-situ FTIR/EIS and ex-situ XPS showed that the soft carbon coating induced the formation of thinner SEI that is richer in NaF from the electrolyte,which stabilized the interface and promoted the charge transfer process.As a result,the anode produced fastcharging(329.8 mAh g^(−1)at 30 mA g^(−1)and 198.6 mAh g^(−1)at 300 mA g^(−1))and had a better cycling performance(a high capacity retention of 81.4%after 100 cycles at 150 mA g^(−1)).This work reveals the critical role of coating layer in changing the pore structure,SEI chemistry and diffusion kinetics of hard carbon,which enables rational design of sodium-ion battery anode with enhanced fast charging capability.展开更多
基金supported by National Natural Science Foundation of China(Grant No.52364004)the Guizhou Provincial Science and Technology Foundation(Grant No.GCC[2022]005-1).
文摘Liquid nitrogen(LN_(2))and microwave are the alternative methods for reservoir fracturing,which are rarely combined.To investigate the combined effects,sandstone is frozen with LN_(2)before microwave heating(MI),and nuclear magnetic resonance(NMR),ultrasonic wave,and infrared thermal imaging(ITI)are used to understand the pore structures,moisture change,and surface temperature of the sandstone samples.With the heating time,the average surface temperature of the combining-treatment samples firstly increases from the room temperature(25℃)to 144.7℃(65 s)fast,and then increases slowly to 176.6℃(95 s).For the individual MI,the temperature increases to 146.7℃at 65 s.As 30 min of LN_(2)freezing,the samples perform well in removing pore water during heating.The NMR results show that after LN_(2)freezing,the seepage pores and total pores increase by 2.93%and 4.11%,respectively,and the pore connectivity enhances.However,the individual MI performs weak in enhancing the pore structures,forming a high vapor pressure(0.428 MPa at 65 s)and causing burst after 65 s.Due to the improved pore connectivity,the vapor pressure(0.378 MPa)and temperature are small at 65 s,and burst can be avoided.After freezing,the wave velocity decreases by 13.48%and the damage variable reaches 0.251.The velocity attenuation rates and damage variable gradually increase with heating time;under the same duration,the two variables of the combining treatments are greater than that of the individual treatments.This can prove a reference for gas production in sandstone reservoirs.
基金Project(2009CB623406)supported by the National Basic Research Program of ChinaProject(12JJ4044)supported by the Natural Science Foundation of Hunan Province,ChinaProject(13C902)supported by the Scientific Research Fund of Hunan Provincial Education Department,China
文摘Porous Ni3Al intermetallics were fabricated by elemental powder reactive synthesis method, using carbamide powders as space holders. Corrosion behavior of porous Ni3Al intermetallics was investigated in a 6 mol/L KOH solution using electrochemical methods and immersion test. Effect of porous structures on the corrosion behavior of the porous Ni3Al intermetallics was studied. The results indicate that the porous Ni3Al intermetallics with higher porosities suffer more serious corrosion than the ones with lower porosities because the complicated interconnected porous structures and the large true surface areas exist in the samples with a higher porosity. But the corrosion rates of the porous Ni3Al intermetallics are not proportional to the true surface areas. The reason is that the pore size, pore size distribution and pore shape of the porous Ni3Al intermetallics change with the increasing porosity. All the porous Ni3Al intermetallics with different porosities exhibit excellent corrosion resistance in a strong alkali solution.
基金supported by the National Natural Science Foundation of China(No.41274136)
文摘We developed an anisotropic effective theoretical model for modeling the elastic behavior of anisotropic carbonate reservoirs by combining the anisotropic self-consistent approximation and differential effective medium models.By analyzing the measured data from carbonate samples in the TL area,a carbonate pore-structure model for estimating the elastic parameters of carbonate rocks is proposed,which is a prerequisite in the analysis of carbonate reservoirs.A workflow for determining elastic properties of carbonate reservoirs is established in terms of the anisotropic effective theoretical model and the pore-structure model.We performed numerical experiments and compared the theoretical prediction and measured data.The result of the comparison suggests that the proposed anisotropic effective theoretical model can account for the relation between velocity and porosity in carbonate reservoirs.The model forms the basis for developing new tools for predicting and evaluating the properties of carbonate reservoirs.
基金Financial support for this work,provided by the Key Basic Research Program of China(Nos.2010CB226800 and 2007CB202200)National Natural Science Foundation of China(No. 50490270)the Innovation Team Development Program of the Ministry of Education of China(No.IRT0656)
文摘Hydrophilic characteristics of rocks are affected by their microscopic pore structures,which clearly change after water absorption.Water absorption tests and scanning electron microscopic（SEM） experiments on rock samples,located at a site in Tibet,China,were carried out Changes of rock pore structures before and after water absorption were studied with the distribution of pore sizes and fractal characteristics of pores.The results show that surface porosities,fractal dimensions of pores and the complexity of pore structures increased because the number of new small pores produced increased or the original macropore flow channels were expanded after rocks absorbed water.There were points of inflection on their water absorption curves.After water absorption of other rocks,surface porosities and fractal dimensions of pores and complexity of pore structures decreased as the original pore flow channels became filled.Water absorption curves did not change.Surface porosity and the pore fractal dimensions of rocks have good linear relationships before and after water absorption.
文摘Co–Mo catalysts applied on the hydrodesulfurization（HDS） for FCC gasoline were prepared with Zn–Al layered double hydroxides（LDHs） to improve their performances,and the effects of pore structures and acidity on HDS performances were studied in detail. A series of Zn–Al/LDHs samples with different pore structures and acidities are synthesized on the bases of co-precipitation of OH-,CO2-,Al3＋,and Zn2＋. The neutralization p H is a main factor to affect the pore structures and acidity of Zn–Al/LDHs,and a series of Zn–Al/LDHs with different pore structures and acidities are obtained. Based on the representative samples with different specific surface areas（SBET） and acidities,three Co Mo/LDHs catalysts were prepared,and their HDS performances were compared with traditional Co Mo/Al2O3 catalysts. The results indicated that catalysts prepared with high SBETpossessed high HDS activity,and Br？nsted acid sites could reduce the thiol content in the product to some extent. All the three catalysts prepared with LDHs displayed little lower HDS activity but higher selectivity than Co Mo/Al2O3,and could restrain the reactions of re-combination between olefin and H2 S which could be due to the existence of Br？nsted acid sites.
基金Funded by the National Key Fundamental Research and Develop ment Program of China(2001CB610703)
文摘Three cement samples were prepared, includi ng OPC consisted of 100wt% portland cement, PFA consisted of 70wt% portland cemen t and 30wt% fly-ash, and CA consisted of 70wt% portland cement and 30wt% modifi ed fly ash. The strength of hardened cement paste of these samples was tested an d their pore structures were determined by a mercury intrusion porosimeter. More over,the data of the pore structures of three samples were comprehensively analy zed. The relations between the pore structures and the compressive strength of t he three samples were studied. The experimental results show that the relations between the porosity determined by the mercury intrusion porosimeter and the com pressive strength are not notable, and the total pore surface area, the average pore diameter and the median pore diameter could be used to explain the differen ce of the strength of the tested samples.
基金supported by the National Natural Science Foundation of China(No.51874320)Scientific Research Foundation of China University of Petroleum,Beijing(No.2462017BJB11)。
文摘Based on the experiments of nitrogen gas adsorption(N_2 GA) and nuclear magnetic resonance(NMR),the multifractal characteristics of pore structures in shale and tight s andstone from the Chang 7 member of Trias sic Yanchang Formation in Ordos Basin,NW China,are investigated.The multifractal spectra obtained from N2 GA and NMR are analyzed with pore throat structure parameters.The results show that the pore size distributions obtained from N2 GA and NMR are different,and the obtained multifractal characteristics vary from each other.The specific surface and total pore volume obtained by N2 GA experiment have correlations with multifractal characteristics.For the core samples with the similar specific surface,the value of the deviation of multifractal spectra Rd increases with the increase in the proportion of large pores.When the proportion of macropores is small,the Rd value will increase with the increase in specific surface.The multifractal characteristics of pore structures are influenced by specific surface area,average pore size and adsorption volume measured from N2 GA experiment.The multifractal characteristic parameters of tight sandstone measured from NMR spectra are larger than those of shale,which may be caused by the differences in pore size distribution and porosity of shale and tight sandstone.
基金supported by the State Key Basic Research Program of China(No.2011CB201202)
文摘The adsorption of methane onto five dry coal samples was measured at 298 K over the pressure range from 0 to 3.5 MPa using a volumetric method.The isotherm data were fitted to the Langmuir and the Freundlich equations.The kinetic data were fitted to a pseudo second order equation,the linear driving force equation(LDF),and an intra-particle diffusion model.These results showed that higher methane adsorption is correlated with larger micro-pore volumes and specific surface areas.The adsorption was related to the narrow micro-pore size distribution when the previous two parameters are large.The kinetics study showed that the kinetics of methane adsorption onto these five dry coal samples followed a pseudo second order model very well.Methane adsorption rates are controlled by intra-particle diffusion.The faster the intra-particle diffusion,the faster the methane adsorption rate will be.
基金supported by the Open Fund(PLC2020002,PLC20190507)of the State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation(Chengdu University of Technology)National Natural Science Foundation of China(42004112,42274175,42030812,41974160)+1 种基金sponsored by Special projects of local science and technology development guided by the central government in Sichuan(2021ZYD0030)Natural Science Foundation of Sichuan Province(23NSFSC5311)
文摘Microcosmic details of pore structure are the essential factors affecting the elastic properties of tight sandstone reservoirs,while the relationships in between are still incompletely clear due to the fact that quantitative or semi-quantitative experiments are hard to achieve.Here,three sets of tight sandstone samples from the Junggar Basin are selected elaborately based on casting thin sections,XRD detection,and petro-physical measurement,and each set is characterized by a single varied microcosmic factor(pore connectedness,pore type,and grain size)of the pore structure.An ultrasonic pulse transmission technique is conducted to study the response of elastic properties to the varied microcosmic details of pore structure in the situation of different pore fluid(gas,brine,and oil)saturation and confining pressure.Observations show samples with less connectedness,inter-granular dominant pores,and smaller grain size showed greater velocities in normal conditions.Vpis more sensitive to the variations of pore type,while Vsis more sensitive to the variations of grain size.Samples with better connectedness at fluid saturation(oil or brine)show greater sensitivity to the confining pressure than those with gas saturation with a growth rate of 6.9%-11.9%,and the sensitivity is more likely controlled by connectedness.The pore types(inter-granular or intra-granular)can be distinguished by the sensitivity of velocities to the variation of pore fluid at high confining pressure(>60 MPa).The samples with small grain sizes tend to be more sensitive to the variations of confining pressure.With this knowledge,we can semi-quantitatively distinguish the complex pore structures with different fluids by the variation of elastic properties,which can help improve the precision of seismic reservoir prediction for tight sandstone reservoirs.
基金supported by the National Natural Science Foundation of China(Grant no.41704109)the Jiangsu Province Outstanding Youth Fund Project(Grant no.BK20200021).
文摘The wave-induced local fluid flow mechanism is relevant to the complex heterogeneity of pore structures in rocks.The analysis of the local fluid flow mechanism is useful for accurately describing the wave propagation characteristics in reservoir rocks.In the exploration and production of hydrocarbon reservoirs,the real stratum may be partially saturated with a multi-phase fluid mixture in general.Therefore,it is of great significance to investigate the wave velocity dispersion and attenuation features in relation to pore structures and fluids.In this work,the characteristics of fabric microstructures are obtained on the basis of pressure dependency of dry rock moduli using the effective medium theory.A novel anelasticity theoretical model for the wave propagation in a partially-saturated medium is presented by combining the extended Gurevich squirt-flow model and White patchysaturation theory.Numerical simulations are used to analyze wave propagation characteristics that depend on water saturation,external patchy diameter,and viscosity.We consider a tight sandstone from the Qingyang area of the Ordos Basin in west China and perform ultrasonic measurements under partial saturation states and different confining pressures,where the basic properties of the rock are obtained at the full gas saturation.The comparison of experimental data and theoretical modeling results shows a fairly good agreement,indicating that the new theory is effective.
基金Jiangsu Innovation and Entrepreneurship ProgramJiangsu Provincial Special Program of Medical Science (BL2012004)+3 种基金Jiangsu R&D Innovation Program (BY2014059-07)the Priority Academic Program Development of Jiangsu High Education Institutionsthe National Natural Science Foundation of China (No. 51472279)the Jiangsu Six Peak of Talents Program (2013-WSW-056) for financial supports
文摘A green biocompatible foaming method utilizing natural coconut oil and cornstarch was developed to fabricate highly porous functional ceramics with controllable strengths and pore structures. The poros- ity of A1203 ceramics prepared via this method reached 79.6%-86.9% while these ceramics maintained high compressive strengths of 2.2-5.5 MPa. More importantly, porous A1203 ceramic with a pore size gra- dient was also readily fabricated by casting serial layers of foams that were set for different time periods. The potential applications of porous Al2O3 and HA ceramics fabricated by this green foaming method in- cluding scaffolds for oil cleaning and cell culture, respectively, were also demonstrated.
基金financially supported by the Natural Science Foundation of Shandong Province (No.ZR2014EMM009)the Public School Visiting Fund of Shandong University of Science and Technology
文摘Open-celled porous （TiB2-Al2O3）/NiAl composites were successfully fabricated by using spherical carbamide as space holders via self-propagating high-temperature synthesis （SHS）. Effects of 10Al-3B2O3-3TiO2 contents （0-20 wt%） on the pore structures and the quasi-static compressive behaviors of the resultant materials were investigated. The porous （TiBE-Al2O3）/NiAl composites exhibit composite pore structure consisting of homogeneously distributed and interconnected millimeter pores and micropores. The millimeter pores virtually inherit the shape and size of carbamide particles, while the pore size of micropores increases with increasing the 10Al-3BEO3-3TiO2 content. Depending on the volume fraction of the carbamide, the porosity of the porous materials can be easily controlled in a range of 55%-85%. When the porosity is about 72%, the compressive strengths of porous NiAl and porous （TiBE-Al203）/NiAl composite with 15% 10Al-3B2O3-3TiO2 in green compact are 19 and 32 MPa, and the corresponding strains are 2.9% and 5.7%, respectively. Furthermore, the quasi-static compressive behavior of porous （TiB2-AlEO3）/NiAl composites can be estimated by Gibson-Ashby model.
文摘Pore structures in shales are a main factor affecting the storage capacity and production performance of shale gas reservoirs.Taking Longmaxi Shales in the Jiaoshiba area of the Sichuan Basin as a study object,we systematically study the microscopic pore structures of shales by using Argon-ion polishing Scanning Electron Microscope(SEM),high-pressure mercury injection and low-temperature nitrogen adsorption and desorption experiments.The study results show that:the Longmaxi Shale in this area are dominated by nano-scale pores which can be classified into organic pores,inorganic pores(intergranular pores,intragranular pores,inter-crystalline pores and dissolution pores),microfractures(intragranular structure fractures,interlayer sliding fractures,diagenetic shrinkage joints and abnormal-pressure fractures from organic evolution),among which organic pores and clay mineral pores are predominant and organic pores are the most common;a TOC value shows an obvious positive correlation with the content of organic pores,which account for up to 50%in the lower-quality shales with a TOC of over 2%where they are most developed;microscopic pore structures are very complex and open,with pores being mainly in cylinder shape with two ends open,or in parallel tabular shape with four sides open and 2–30 nm in diameter,being mostly medium pores.On this basis,factors affecting the micropore structures of shales in this area are studied.It is concluded that organic matter abundance and thermal maturity are the major factors controlling the microscopic pore structures of shales,while the effects of clay mineral content are relatively insignificant.
基金supported by the National Natural Science Foundation of China(No.52371052).
文摘High-temperature infrared-regulating ceramics are essentialfoerxtreme-environmentapplicationsrequiring broadband infrared reflection(1-6μm),such as spacecraft thermal protection,military stealth systems,and related fields.Precise control of pore structures is crucial for enhancing ceramic infrared reflectance,as pores directly influence the scattering intensity and scattering path of radiation.However,achieving broadband reflectance above 0.9 remains challenging because of unclear pore-radiation interaction mechanisms and insufficient structural control.This study employs optical simulations to systematically analyze how pore parameters enhance infrared reflectance.The results demonstrate that pore sizes matching the infrared wavelength,highaspect ratios,and aligned orientations synergistically enhance reflection.Guided by simulations,directional pore-structured yttria-stabilized zirconia(YSZ)ceramics were fabricated via a rolling extrusion method using graphite flakes as sacrificial templates.The optimized ceramics exhibited tailored pore parameters(size:0.2-6μm,aspect ratio:3.2-3.9,orientation angle:<30°),achieving exceptional infrared reflectance(>0.9).This study clarifies pore-radiation interactions and presents a scalable strategy to produce advanced thermal shielding materials.
基金supported by the National Natural Science Foundation of China(41925014).
文摘The Lower Cambrian shales in the Sichuan Basin are considered one of the most promising shale gas resources in China.However,large-scale commercial development has not been achieved due to the relatively low and significantly variable gas contents of the drilled shales.Excitingly,the first major breakthrough in deep and ultra-deep Lower Cambrian shale gas was made recently in the well Z201 in the southern Sichuan Basin,with a gas yield exceeding 73×10^(4)m^(3)/d.The success of well Z201 provides a favorable geological case to reveal the distinct enrichment mechanism of deep and ultra-deep Lower Cambrian shale gas.In this study,at drilling site of well Z201,fresh shale core samples with different gasin-place contents were collected,and their geochemical,pore development and water-bearing characteristics were analyzed systematically.The results showed that the Z201 organic-rich shales reached an overmature stage,with an average Raman maturity of 3.70%.The Z201 shales with high gas-in-place contents are mainly located in the Qiongzhusi 12section and the upper Qiongzhusi 11section,with an average gas-in-place content of 10.08 cm^(3)/g.Compared to the shales with low gas-in-place contents,the shales with high gas-in-place contents exhibit higher total organic carbon contents,greater porosities,and lower water saturations,providing more effective pore spaces for shale gas enrichment.The effective pore structures of the deep and ultra-deep Lower Cambrian shales are the primary factors affecting their gas-in-place contents.Similar to the shales with high gas-in-place contents of well Z201,the deep and ultra-deep Lower Cambrian shales in the Mianyang-Changning intracratonic sag,especially in the Ziyang area,generally developed in deep-water shelf facies with high total organic carbon contents and thick sedimentary thickness,providing favorable conditions for the development and preservation of effective pores.Therefore,they are the most promising targets for Lower Cambrian shale gas exploration.
基金supported by the National Natural Science Foundation of China(52274056,U22B2075).
文摘Oil transport is greatly affected by heterogeneous pore–throat structures present in shale.It is therefore very important to accurately characterize pore–throat structures.Additionally,it remains unclear how pore–throat structures affect oil transport capacity.In this paper,using finite element(FE)simulation and mathematical modeling,we calculated the hydrodynamic resistance for four pore–throat structure.In addition,the influence of pore throat structure on shale oil permeability is analyzed.According to the results,the hydrodynamic resistance of different pore throat structures can vary by 300%.The contribution of additional resistance caused by streamline bending is also in excess of 40%,even without slip length.Fur-thermore,Pore–throat structures can affect apparent permeability by more than 60%on the REV scale,and this influence increases with heterogeneity of pore size distribution,organic matter content,and organic matter number.Clearly,modeling shale oil flow requires consideration of porous–throat structure and additional resistance,otherwise oil recovery and flow capacity may be overestimated.
基金the National Science Fund for Distinguished Young Scholars(No.52225403)the Natural Science Foundation of Shanxi Province(No.202303021212073)the National Natural Science Foundation of China(No.52104210)。
文摘Understanding the impact of mining disturbances and creep deformation on the macroscopic deformation and the microscopic pore and fracture structures(MPFS)of coal is paramount for ensuring the secure extraction of coal resources.This study conducts cyclic loading-unloading and creep experiments on coal using a low-field nuclear magnetic resonance(NMR)experimental apparatus which is equipped with mechanical loading units,enabling real-time monitoring the T2spectrum.The experiments indicated that cyclic loading-unloading stress paths initiate internal damage within coal samples.Under identical creep stress conditions,coal samples with more initial damages had more substantial instantaneous deformation and creep deformation during the creep process.After undergoing nearly 35 h of staged creep,the total strains for coal samples CC01,CC02,and CC03 reach 2.160%,2.261%,and 2.282%,respectively.In the creep stage,the peak area ratio of seepage pores and microfractures(SPM)gradually diminishes.A higher degree of initial damage leads to a more pronounced compaction trend in the SPM of coal samples.Considering the porosity evolution of SPM during the creep process,this study proposes a novel fractional derivative model for the porosity evolution of SPM.The efficacy of the proposed model in predicting porosity evolution of SPM is substantiated through experimental validation.Furthermore,an analysis of the impact mechanisms on key parameters in the model was carried out.
基金Supported by Leading Talent Program of Autonomous Region(2022TSYCLJ0070)PetroChina Prospective and Basic Technological Project(2021DJ0108)Natural Science Foundation for Outstanding Young People in Shandong Province(ZR2022YQ30).
文摘Based on the experimental results of casting thin section,low temperature nitrogen adsorption,high pressure mercury injection,nuclear magnetic resonance T2 spectrum,contact angle and oil-water interfacial tension,the relationship between pore throat structure and crude oil mobility characteristics of full particle sequence reservoirs in the Lower Permian Fengcheng Formation of Mahu Sag,Junggar Basin,are revealed.(1)With the decrease of reservoir particle size,the volume of pores connected by large throats and the volume of large pores show a decreasing trend,and the distribution and peak ranges of throat and pore radius shift to smaller size in an orderly manner.The upper limits of throat radius,porosity and permeability of unconventional reservoirs in Fengcheng Formation are approximately 0.7μm,8%and 0.1×10^(−3)μm^(2),respectively.(2)As the reservoir particle size decreases,the distribution and peak ranges of pores hosting retained oil and movable oil are shifted to a smaller size in an orderly manner.With the increase of driving pressure,the amount of retained and movable oil of the larger particle reservoir samples shows a more obvious trend of decreasing and increasing,respectively.(3)With the increase of throat radius,the driving pressure of reservoir with different particle levels presents three stages,namely rapid decrease,slow decrease and stabilization.The oil driving pressures of various reservoirs and the differences of them decrease with the increase of temperature and obviously decrease with the increase of throat radius.According to the above experimental analysis,it is concluded that the deep shale oil of Fengcheng Formation in Mahu Sag has great potential for production under geological conditions.
文摘The development of sustainable electrode materials for energy storage systems has become very important and porous carbons derived from biomass have become an important candidate because of their tunable pore structure,environmental friendliness,and cost-effectiveness.Recent advances in controlling the pore structure of these carbons and its relationship between to is energy storage performance are discussed,emphasizing the critical role of a balanced distribution of micropores,mesopores and macropores in determining electrochemical behavior.Particular attention is given to how the intrinsic components of biomass precursors(lignin,cellulose,and hemicellulose)influence pore formation during carbonization.Carbonization and activation strategies to precisely control the pore structure are introduced.Finally,key challenges in the industrial production of these carbons are outlined,and future research directions are proposed.These include the establishment of a database of biomass intrinsic structures and machine learning-assisted pore structure engineering,aimed at providing guidance for the design of high-performance carbon materials for next-generation energy storage devices.
基金National Key Research and Development Program of China(2022YFE0206300)National Natural Science Foundation of China(U21A2081,22075074,22209047)+2 种基金Guangdong Basic and Applied Basic Research Foundation(2024A1515011620)Hunan Provincial Natural Science Foundation of China(2024JJ5068)Foundation of Yuelushan Center for Industrial Innovation(2023YCII0119)。
文摘Changes to the microstructure of a hard carbon(HC)and its solid electrolyte interface(SEI)can be effective in improving the electrode kinetics.However,achieving fast charging using a simple and inexpensive strategy without sacrificing its initial Coulombic efficiency remains a challenge in sodium ion batteries.A simple liquid-phase coating approach has been used to generate a pitch-derived soft carbon layer on the HC surface,and its effect on the porosity of HC and SEI chemistry has been studied.A variety of structural characterizations show a soft carbon coating can increase the defect and ultra-micropore contents.The increase in ultra-micropore comes from both the soft carbon coatings and the larger pores within the HC that are partially filled by pitch,which provides more Na+storage sites.In-situ FTIR/EIS and ex-situ XPS showed that the soft carbon coating induced the formation of thinner SEI that is richer in NaF from the electrolyte,which stabilized the interface and promoted the charge transfer process.As a result,the anode produced fastcharging(329.8 mAh g^(−1)at 30 mA g^(−1)and 198.6 mAh g^(−1)at 300 mA g^(−1))and had a better cycling performance(a high capacity retention of 81.4%after 100 cycles at 150 mA g^(−1)).This work reveals the critical role of coating layer in changing the pore structure,SEI chemistry and diffusion kinetics of hard carbon,which enables rational design of sodium-ion battery anode with enhanced fast charging capability.
