The flow characteristics of coalbed methane(CBM)are influenced by the coal rock fracture network,which serves as the primary gas transport channel.This has a significant effect on the permeability performance of coal ...The flow characteristics of coalbed methane(CBM)are influenced by the coal rock fracture network,which serves as the primary gas transport channel.This has a significant effect on the permeability performance of coal reservoirs.In any case,the traditional techniques of coal rock fracture observation are unable to precisely define the flow of CBM.In this study,coal samples were subjected to an in situ loading scanning test in order to create a pore network model(PNM)and determine the pore and fracture dynamic evolution law of the samples in the loading path.On this basis,the structural characteristic parameters of the samples were extracted from the PNM and the impact on the permeability performance of CBM was assessed.The findings demonstrate that the coal samples'internal porosity increases by 2.039%under uniaxial loading,the average throat pore radius increases by 205.5 to 36.1μm,and the loading has an impact on the distribution and morphology of the pores in the coal rock.The PNM was loaded into the finite element program COMSOL for seepage modeling,and the M3 stage showed isolated pore connectivity to produce microscopic fissures,which could serve as seepage channels.In order to confirm the viability of the PNM and COMSOL docking technology,the streamline distribution law of pressure and velocity fields during the coal sample loading process was examined.The absolute permeability of the coal samples was also obtained in order for comparison with the measured results.The macroscopic CBM flow mechanism in complex lowpermeability coal rocks can be revealed through three-dimensional reconstruction of the microscopic fracture structure and seepage simulation.This study lays the groundwork for the fine description and evaluation of coal reservoirs as well as the precise prediction of gas production in CBM wells.展开更多
The permeability in the methane hydrate reservoir is one of the key parameters in estimating the gas production performance and the flow behavior of gas and water during dissociation.In this paper,a three-dimensional ...The permeability in the methane hydrate reservoir is one of the key parameters in estimating the gas production performance and the flow behavior of gas and water during dissociation.In this paper,a three-dimensional cubic pore-network model based on invasion percolation is developed to study the effect of hydrate particle formation and growth habit on the permeability.The variation of permeability in porous media with different hydrate saturation is studied by solving the network problem.The simulation results are well consistent with the experimental data.The proposed model predicts that the permeability will reduce exponentially with the increase of hydrate saturation,which is crucial in developing a deeper understanding of the mechanism of hydrate formation and dissociation in porous media.展开更多
Three-dimensional(3D)bioprinting is a powerful approach that enables the fabrication of 3D tissue constructs that retain complex biological functions.However,the dense hydrogel networks that form after the gelation of...Three-dimensional(3D)bioprinting is a powerful approach that enables the fabrication of 3D tissue constructs that retain complex biological functions.However,the dense hydrogel networks that form after the gelation of bioinks often restrict the migration and proliferation of encapsulated cells.Herein,a sacrificial microgel-laden bioink strategy was designed for directly bioprinting constructs with mesoscale pore networks(MPNs)for enhancing nutrient delivery and cell growth.The sacrificial microgel-laden bioink,which contains cell/gelatin methacryloyl(GelMA)mixture and gelled gelatin microgel,is first thermo-crosslinked to fabricate temporary predesigned cell-laden constructs by extrusion bioprinting onto a cold platform.Then,the construct is permanently stabilized through photo-crosslinking of GelMA.The MPNs inside the printed constructs are formed after subsequent dissolution of the gelatin microgel.These MPNs allowed for effective oxygen/nutrient diffusion,facilitating the generation of bioactive tissues.Specifically,osteoblast and human umbilical vein endothelial cells encapsulated in the bioprinted large-scale constructs(≥1 cm)with MPNs showed enhanced bioactivity during culture.The 3D bioprinting strategy based on the sacrificial microgel-laden bioink provided a facile method to facilitate formation of complex tissue constructs with MPNs and set a foundation for future optimization of MPN-based tissue constructs with applications in diverse areas of tissue engineering.展开更多
The so-called pore network model has great advantages in describing the process of heat and mass transfer in porous media.In order to construct a random two-dimensional(2D)irregular pore network model for an unconsoli...The so-called pore network model has great advantages in describing the process of heat and mass transfer in porous media.In order to construct a random two-dimensional(2D)irregular pore network model for an unconsolidated material,image processing technology was used to extract the required topological and geometric information from a 2D sample of soybean particles,and a dedicated algorithm was elaborated to merge some adjacent small pores.Based on the extracted information,a 2D pore network model including particle information was reconstructed and verified to reflect the pore structure of discrete particles.This method was used to reconstruct a random 2D irregular pore network model of wheat.Accordingly,a multi-scale heat and mass transfer model was implemented to simulate the drying of wheat.The simulation results were consistent with the experimental results,which indicates that the reconstructed irregular pore network model can effectively simulate the real pore structure inside unconsolidated porous media.The present approach may be regarded as the foundation for establishing in the future a three-dimensional pore network model and studying the heat and mass transfer process in a grain pile.展开更多
Dry reforming of methane(DRM) is an attractive technology for utilizing the greenhouse gases(CO_(2) and CH_(4)) to produce syngas. However, the catalyst pellets for DRM are heavily plagued by deactivation by coking, w...Dry reforming of methane(DRM) is an attractive technology for utilizing the greenhouse gases(CO_(2) and CH_(4)) to produce syngas. However, the catalyst pellets for DRM are heavily plagued by deactivation by coking, which prevents this technology from commercialization. In this work, a pore network model is developed to probe the catalyst deactivation by coking in a Ni/Al_(2)O_(3) catalyst pellet for DRM. The reaction conditions can significantly change the coking rate and then affect the catalyst deactivation. The catalyst lifetime is higher under lower temperature, pressure, and CH_(4)/CO_(2) molar ratio, but the maximum coke content in a catalyst pellet is independent of these reaction conditions. The catalyst pellet with larger pore diameter, narrower pore size distribution and higher pore connectivity is more robust against catalyst deactivation by coking, as the pores in this pellet are more difficult to be plugged or inaccessible.The maximum coke content is also higher for narrower pore size distribution and higher pore connectivity, as the number of inaccessible pores is lower. Besides, the catalyst pellet radius only slightly affects the coke content, although the diffusion limitation increases with the pellet radius. These results should serve to guide the rational design of robust DRM catalyst pellets against deactivation by coking.展开更多
This study investigates the impact of pore network characteristics on fluid flow through complex and heterogeneous porous media,providing insights into the factors affecting fluid propagation in such systems.Specifica...This study investigates the impact of pore network characteristics on fluid flow through complex and heterogeneous porous media,providing insights into the factors affecting fluid propagation in such systems.Specifically,high-resolution or micro X-ray computed tomography(CT)imaging techniques were utilized to examine outcrop stromatolite samples of the Lagoa Salgada,considered flow analogous to the Brazilian Pre-salt carbonate reservoirs.The petrophysical results comprised two distinct stromatolite depositional facies,the columnar and the fine-grained facies.By generating pore network model(PNM),the study quantified the relationship between key features of the porous system,including pore and throat radius,throat length,coordination number,shape factor,and pore volume.The study found that the less dense pore network of the columnar sample is typically characterized by larger pores and wider and longer throats but with a weaker connection of throats to pores.Both facies exhibited less variability in the radius of the pores and throats in comparison to throat length.Additionally,a series of core flooding experiments coupled with medical CT scanning was designed and conducted in the plug samples to assess flow propagation and saturation fields.The study revealed that the heterogeneity and presence of disconnected or dead-end pores significantly impacted the flow patterns and saturation.Two-phase flow patterns and oil saturation distribution reveal a preferential and heterogeneous displacement that mainly swept displaced fluid in some regions of plugs and bypassed it in others.The relation between saturation profiles,porosity profiles,and the number of fluid flow patterns for the samples was evident.Only for the columnar plug sample was the enhancement in recovery factor after shifting to lower salinity water injection(SB)observed.展开更多
Coalbed methane(CBM)recovery is attracting global attention due to its huge reserve and low carbon burning benefits for the environment.Fully understanding the complex structure of coal and its transport properties is...Coalbed methane(CBM)recovery is attracting global attention due to its huge reserve and low carbon burning benefits for the environment.Fully understanding the complex structure of coal and its transport properties is crucial for CBM development.This study describes the implementation of mercury intrusion and μ-CT techniques for quantitative analysis of 3D pore structure in two anthracite coals.It shows that the porosity is 7.04%-8.47%and 10.88%-12.11%,and the pore connectivity is 0.5422-0.6852 and 0.7948-0.9186 for coal samples 1 and 2,respectively.The fractal dimension and pore geometric tortuosity were calculated based on the data obtained from 3D pore structure.The results show that the pore structure of sample 2 is more complex and developed,with lower tortuosity,indicating the higher fluid deliverability of pore system in sample 2.The tortuosity in three-direction is significantly different,indicating that the pore structure of the studied coals has significant anisotropy.The equivalent pore network model(PNM)was extracted,and the anisotropic permeability was estimated by PNM gas flow simulation.The results show that the anisotropy of permeability is consistent with the slice surface porosity distribution in 3D pore structure.The permeability in the horizontal direction is much greater than that in the vertical direction,indicating that the dominant transportation channel is along the horizontal direction of the studied coals.The research results achieve the visualization of the 3D complex structure of coal and fully capture and quantify pore size,connectivity,curvature,permeability,and its anisotropic characteristics at micron-scale resolution.This provides a prerequisite for the study of mass transfer behaviors and associated transport mechanisms in real pore structures.展开更多
A pore network model was used in this paper to investigate the factors, in particular, throat radius, wettability and initial water saturation, causing water block in low permeability reservoirs. A new term - ＇relati...A pore network model was used in this paper to investigate the factors, in particular, throat radius, wettability and initial water saturation, causing water block in low permeability reservoirs. A new term - ＇relative permeability number＇ （RPN） was firstly defined, and then used to describe the degree of water block. Imbibition process simulations show that the RPN drops in accordance with the extension of the averaged pore throat radius from 0.05 to 1.5 μm, and yet once beyond that point of 1.5 μm, the RPN reaches a higher value, indicating the existence of a critical pore throat radius where water block is the maximum. When the wettability of the samples changes from water-wet to weakly water-wet, weakly gas-wet, or gas（oil）-wet, the gas RPN increases consistently, but this consistency is disturbed by the RPN dropping for weakly water-wet samples for water saturations less than 0.4, which means weakly waterwet media are more easily water blocked than water-wet systems. In the situation where the initial water saturation exceeds 0.05, water block escalates along with an increase in initial water saturation.展开更多
To determine the effect of dissolution on pore network development in carbonate rocks, dissolution experiments, X-Ray microtomography, and thin section analysis were conducted on argillaceous limestone and grain limes...To determine the effect of dissolution on pore network development in carbonate rocks, dissolution experiments, X-Ray microtomography, and thin section analysis were conducted on argillaceous limestone and grain limestone samples at different temperatures and constant pH, HCl concentration. The relationship between Ca^(2+) concentration and time was revealed through the experiments; pore size distribution before and after dissolution indicate that there is no correlation between the temperature and pore size variation, but pore size variation in grain limestone is more significant, indicating that the variation is mainly controlled by the heterogeneity of the rock itself(initial porosity and permeability) and the abundance of unstable minerals(related to crystal shape, size and mineral type). At different temperatures, the two kinds of carbonate rocks had very small variation in pore throat radius from 0.003 mm to 0.040 mm, which is 1.3 to 3.5 times more, 1.7 on average of the original pore throat radius. Their pore throat length varied from 0.05 mm to 0.35 mm. The minor changes in the pore throat radius, length and connectivity brought big changes to permeability of up to 1 000×10^(-3) μm^2.展开更多
We characterize the complex pore architecture of four diagenetically altered sandstone samples using micro-CT imaging.By quantifying the pore size and pore connection distributions,we establish that the mean coordinat...We characterize the complex pore architecture of four diagenetically altered sandstone samples using micro-CT imaging.By quantifying the pore size and pore connection distributions,we establish that the mean coordination number follows a power-law function of pore radius.Critically,we derive empirical scaling relations between 2D and 3D pore size distributions,as well as 2D and 3D coordination number distributions,both as a function of pore size.These novel relations allow for the 3D pore size and pore connectivity to be accurately characterized from high-resolution 2D imaging(e.g.,SEM),even when the resolution or field-of-view limitations preclude detailed 3D micro-CT analysis.A new stochastic algorithm is presented in this work to generate a 3D pore network model that honors the derived connectivity function.This algorithm was validated by generating stochastic models equivalent to the four sandstone samples and successfully comparing the calculated single-phase and relative permeability results against those obtained from pore networks directly extracted from the 3D micro-CT images.This methodology offers a computationally efficient and scalable tool for predicting the macroscopic transport properties of complex reservoir rocks based on readily available 2D high rock resolution images.展开更多
Pores among particles provide the main space for the storage and migration of deep underground fluids(such as oil,gas,groundwater,and unconventional natural gas).The pores form a pore structure with complex morphology...Pores among particles provide the main space for the storage and migration of deep underground fluids(such as oil,gas,groundwater,and unconventional natural gas).The pores form a pore structure with complex morphology which is mainly dominated by the shape and distribution of particles.Therefore,the reconstruction of the pore structure or granular porous media and the evaluation of particle roundness have become an important foundation for the study of fluid flow through deep underground rock mass.This research proposes a novel approach for the multi-scale model with angular vertexes.The fractal topology theory and Voronoi space segmentation technology are combinedly used for the reconstruction of fractal granular porous media.The angular shapes are smoothed by using a modified B-spline technique and the particles with varying degrees of roundness are generated.To validate the superiority of our approach,the roundness based on the Wadell roundness calculation method is calculated and compared with the roundness obtained from particles smoothed using the vertex rounding substitution method.Results show that the roundness of particles smoothed with the modified B-spline technique closely aligns with the corresponding set rounded level(a nondimensional variable).Conversely,the vertex rounding substitution method is limited to a single dimensionally rounded radius.This innovative approach can offer a new method for the construction of granular porous media for the fluid flow study in deep underground rock mass.展开更多
Clayey-silt natural gas hydrate reservoirs in the South China Sea exhibit loose and unconsolidated structures, heterogeneous pore structures, high clay mineral contents, and strong hydrophilicity. These characteristic...Clayey-silt natural gas hydrate reservoirs in the South China Sea exhibit loose and unconsolidated structures, heterogeneous pore structures, high clay mineral contents, and strong hydrophilicity. These characteristics complicate the gas-water two-phase flow process in porous media following hydrate decomposition, posing challenges for efficient development. This study examines the transport response of clayey-silt reservoir samples from the Shenhu area using gas-water two-phase flow experiments and CT scanning to explore changes in pore structure, gas-water distribution, and relative permeability under varying flow conditions. The results indicate that pore heterogeneity significantly influences flow characteristics. Gas preferentially displaces water in larger pores, forming fracture-like pores, which serve as preferential flow channels for gas migration. The preferential flow channels enhance gas-phase permeability up to 19 times that of the water phase when fluid pressures exceed total stresses. However,small pores retain liquid, leading to a high residual water saturation of 0.561. CT imaging reveals that these hydro-fractures improve gas permeability but also confine gas flow to specific channels. Pore network analysis shows that gas injection expands the pore-throat network, enhancing connectivity and forming fracture-like pores. Residual water remains trapped in smaller pores and throats, while structural changes, including new fractures, improve gas flow pathways and overall connectivity. Relative permeability curves demonstrate a narrow gas-water cocurrent-flow zone, a right-shifted iso-permeability point and high reservoir capillary pressure, indicating a strong "water-blocking" effect. The findings suggest that optimizing reservoir stimulation techniques to enhance fracture formation, reduce residual water saturation, and improve gas flow capacity is critical for efficient hydrate reservoir development.展开更多
The physical and chemical properties of rocks play a crucial role in understanding fluid-solid flow behavior at the pore level.Thus,studying pore space characteristics is important in evaluating and determining petrop...The physical and chemical properties of rocks play a crucial role in understanding fluid-solid flow behavior at the pore level.Thus,studying pore space characteristics is important in evaluating and determining petrophysical properties of various rock types,including synthetic rocks,which can be designed to mimic natural rocks.This study investigates the petrophysical properties of synthetic car-bonate plugs by using a new approach that correlates the base material and a 3D printing solution with porosity and permeability.The research shows that with precise particle size and morphology,pure mineral materials such as calcite,dolomite,quartz and a non-structural Portland cement may produce a controlled rock matrix.The synthetic plugs developed in this study exhibit controlled macro,meso,and micro porosities,including fractures and vuggys,by the solubilization of materials with controlled morphology by 3D printing,which provides valuable information on regulating pore space in synthetic carbonate rocks.展开更多
Subsurface rocks,as complex porous media,exhibit multiscale pore structures and intricate physical properties.Digital rock physics technology has become increasingly influential in the study of subsurface rock propert...Subsurface rocks,as complex porous media,exhibit multiscale pore structures and intricate physical properties.Digital rock physics technology has become increasingly influential in the study of subsurface rock properties.Given the multiscale characteristics of rock pore structures,direct three-dimensional imaging at sub-micrometer and nanometer scales is typically infeasible.This study introduces a method for reconstructing porous media using multidimensional data,which combines one-dimensional pore structure parameters with two-dimensional images to reconstruct three-dimensional models.The pore network model(PNM)is stochastically reconstructed using one-dimensional parameters,and a generative adversarial network(GAN)is utilized to equip the PNM with pore morphologies derived from two-dimensional images.The digital rocks generated by this method possess excellent controllability.Using Berea sandstone and Grosmont carbonate samples,we performed digital rock reconstructions based on PNM extracted by the maximum ball algorithm and compared them with stochastically reconstructed PNM.Pore structure parameters,permeability,and formation factors were calculated.The results show that the generated samples exhibit good consistency with real samples in terms of pore morphology,pore structure,and physical properties.Furthermore,our method effectively supplements the micropores not captured in CT images,demonstrating its potential in multiscale carbonate samples.Thus,the proposed reconstruction method is promising for advancing porous media property research.展开更多
Disintegrated dolomite slope and tunnel disasters occur frequently due to poor water stability of disintegrated dolomite,primarily in a form of seepage failure.For engineering purposes,it is critical to determine the ...Disintegrated dolomite slope and tunnel disasters occur frequently due to poor water stability of disintegrated dolomite,primarily in a form of seepage failure.For engineering purposes,it is critical to determine the seepage properties of disintegrated dolomite within the strata.However,conventional experimental methods are time-consuming and expensive and may not be effective in investigating seepage characteristics due to the heterogeneity of disintegrated dolomite.In this study,pore network model(PNM)was established by the computerized tomography(CT)scanning technology to characterize the pores.Meanwhile,the seepage and coefficient of permeability under different inlet stress conditions based on the accurate pore model were realized by linking the commercial image processing software Avizo with the commercial multi-physics modeling package Comsol.The results show that the porosities of severely and completely disintegrated dolomites are 29.17% and 45.37%,respectively.The grade of pore development increases with disintegration grade,which facilitates seepage failure.Severely and completely disintegrated dolomites have the coefficients of permeability of 9.67×10^(-7) m/s and 1.61×10^(-6) m/s,respectively.Under conventional conditions,severely and completely disintegrated dolomites undergo seepage failure above a pressure difference of 6×10^(3) Pa and 5×10^(3) Pa,respectively.These results are consistent with both in situ water pressure tests in the borehole and laboratory tests with the constant-head method,demonstrating that CT scanning is an effective method for observing fractures and pores in disintegrated dolomite for seepage evaluation.展开更多
Experiments of proppant conductivity and fluid flow in proppant cost a large amount of time and money,and also require complex devices.Hence,this article puts forward an artificial fracture numerical model based on pr...Experiments of proppant conductivity and fluid flow in proppant cost a large amount of time and money,and also require complex devices.Hence,this article puts forward an artificial fracture numerical model based on proppant arrangement analysis and the basic principles of the pore network model.Predictions by the model are made consistent with the experimental results through adjusting the model parameters.It is shown that the established model is effective in making predictions on the permeability of proppant.This model is also used to study the non-Newtonian fluid flow characteristics in artificial fracture.展开更多
基金The National Key R&D Program,Grant/Award Number:2023YFC2907203National Natural Science Foundation of China,Grant/Award Numbers:52374121,52074121。
文摘The flow characteristics of coalbed methane(CBM)are influenced by the coal rock fracture network,which serves as the primary gas transport channel.This has a significant effect on the permeability performance of coal reservoirs.In any case,the traditional techniques of coal rock fracture observation are unable to precisely define the flow of CBM.In this study,coal samples were subjected to an in situ loading scanning test in order to create a pore network model(PNM)and determine the pore and fracture dynamic evolution law of the samples in the loading path.On this basis,the structural characteristic parameters of the samples were extracted from the PNM and the impact on the permeability performance of CBM was assessed.The findings demonstrate that the coal samples'internal porosity increases by 2.039%under uniaxial loading,the average throat pore radius increases by 205.5 to 36.1μm,and the loading has an impact on the distribution and morphology of the pores in the coal rock.The PNM was loaded into the finite element program COMSOL for seepage modeling,and the M3 stage showed isolated pore connectivity to produce microscopic fissures,which could serve as seepage channels.In order to confirm the viability of the PNM and COMSOL docking technology,the streamline distribution law of pressure and velocity fields during the coal sample loading process was examined.The absolute permeability of the coal samples was also obtained in order for comparison with the measured results.The macroscopic CBM flow mechanism in complex lowpermeability coal rocks can be revealed through three-dimensional reconstruction of the microscopic fracture structure and seepage simulation.This study lays the groundwork for the fine description and evaluation of coal reservoirs as well as the precise prediction of gas production in CBM wells.
基金supported by the National High Technology Research and Development (863) Program of China (Grant Nos.2006AA09A209-5)the National Natural Science Foundation of China (Grant Nos. 90510003)the Major Research Project of the Ministry of Education (Grant Nos. 306005)
文摘The permeability in the methane hydrate reservoir is one of the key parameters in estimating the gas production performance and the flow behavior of gas and water during dissociation.In this paper,a three-dimensional cubic pore-network model based on invasion percolation is developed to study the effect of hydrate particle formation and growth habit on the permeability.The variation of permeability in porous media with different hydrate saturation is studied by solving the network problem.The simulation results are well consistent with the experimental data.The proposed model predicts that the permeability will reduce exponentially with the increase of hydrate saturation,which is crucial in developing a deeper understanding of the mechanism of hydrate formation and dissociation in porous media.
基金sponsored by the National Nature Science Foundation of China(Nos.U1609207,81827804).
文摘Three-dimensional(3D)bioprinting is a powerful approach that enables the fabrication of 3D tissue constructs that retain complex biological functions.However,the dense hydrogel networks that form after the gelation of bioinks often restrict the migration and proliferation of encapsulated cells.Herein,a sacrificial microgel-laden bioink strategy was designed for directly bioprinting constructs with mesoscale pore networks(MPNs)for enhancing nutrient delivery and cell growth.The sacrificial microgel-laden bioink,which contains cell/gelatin methacryloyl(GelMA)mixture and gelled gelatin microgel,is first thermo-crosslinked to fabricate temporary predesigned cell-laden constructs by extrusion bioprinting onto a cold platform.Then,the construct is permanently stabilized through photo-crosslinking of GelMA.The MPNs inside the printed constructs are formed after subsequent dissolution of the gelatin microgel.These MPNs allowed for effective oxygen/nutrient diffusion,facilitating the generation of bioactive tissues.Specifically,osteoblast and human umbilical vein endothelial cells encapsulated in the bioprinted large-scale constructs(≥1 cm)with MPNs showed enhanced bioactivity during culture.The 3D bioprinting strategy based on the sacrificial microgel-laden bioink provided a facile method to facilitate formation of complex tissue constructs with MPNs and set a foundation for future optimization of MPN-based tissue constructs with applications in diverse areas of tissue engineering.
基金by the National Natural Science Foundation of China on the project:The construction of 3D pore network of heat and mass transfer model in bulk grain pile(No.31171772).
文摘The so-called pore network model has great advantages in describing the process of heat and mass transfer in porous media.In order to construct a random two-dimensional(2D)irregular pore network model for an unconsolidated material,image processing technology was used to extract the required topological and geometric information from a 2D sample of soybean particles,and a dedicated algorithm was elaborated to merge some adjacent small pores.Based on the extracted information,a 2D pore network model including particle information was reconstructed and verified to reflect the pore structure of discrete particles.This method was used to reconstruct a random 2D irregular pore network model of wheat.Accordingly,a multi-scale heat and mass transfer model was implemented to simulate the drying of wheat.The simulation results were consistent with the experimental results,which indicates that the reconstructed irregular pore network model can effectively simulate the real pore structure inside unconsolidated porous media.The present approach may be regarded as the foundation for establishing in the future a three-dimensional pore network model and studying the heat and mass transfer process in a grain pile.
基金financially supported by the National Natural Science Foundation of China (22078090 and 92034301)the Shanghai Rising-Star Program (21QA1402000)+1 种基金the Natural Science Foundation of Shanghai (21ZR1418100)the Open Project of State Key Laboratory of Chemical Engineering (SKL-ChE-21C02)。
文摘Dry reforming of methane(DRM) is an attractive technology for utilizing the greenhouse gases(CO_(2) and CH_(4)) to produce syngas. However, the catalyst pellets for DRM are heavily plagued by deactivation by coking, which prevents this technology from commercialization. In this work, a pore network model is developed to probe the catalyst deactivation by coking in a Ni/Al_(2)O_(3) catalyst pellet for DRM. The reaction conditions can significantly change the coking rate and then affect the catalyst deactivation. The catalyst lifetime is higher under lower temperature, pressure, and CH_(4)/CO_(2) molar ratio, but the maximum coke content in a catalyst pellet is independent of these reaction conditions. The catalyst pellet with larger pore diameter, narrower pore size distribution and higher pore connectivity is more robust against catalyst deactivation by coking, as the pores in this pellet are more difficult to be plugged or inaccessible.The maximum coke content is also higher for narrower pore size distribution and higher pore connectivity, as the number of inaccessible pores is lower. Besides, the catalyst pellet radius only slightly affects the coke content, although the diffusion limitation increases with the pellet radius. These results should serve to guide the rational design of robust DRM catalyst pellets against deactivation by coking.
基金the support of EPIC—Energy Production Innovation Center,hosted by the University of Campinas(UNICAMP)sponsored by FAPESP—Sao Paulo Research Foundation(2017/15736—3 process)+2 种基金the support and funding from Equinor Brazil and the support of ANP(Brazil's National Oil,Natural Gas and Biofuels Agency)through the R&D levy regulationthe Center of Energy and Petroleum Studies(CEPETRO)the School of Mechanical Engineering(FEM)。
文摘This study investigates the impact of pore network characteristics on fluid flow through complex and heterogeneous porous media,providing insights into the factors affecting fluid propagation in such systems.Specifically,high-resolution or micro X-ray computed tomography(CT)imaging techniques were utilized to examine outcrop stromatolite samples of the Lagoa Salgada,considered flow analogous to the Brazilian Pre-salt carbonate reservoirs.The petrophysical results comprised two distinct stromatolite depositional facies,the columnar and the fine-grained facies.By generating pore network model(PNM),the study quantified the relationship between key features of the porous system,including pore and throat radius,throat length,coordination number,shape factor,and pore volume.The study found that the less dense pore network of the columnar sample is typically characterized by larger pores and wider and longer throats but with a weaker connection of throats to pores.Both facies exhibited less variability in the radius of the pores and throats in comparison to throat length.Additionally,a series of core flooding experiments coupled with medical CT scanning was designed and conducted in the plug samples to assess flow propagation and saturation fields.The study revealed that the heterogeneity and presence of disconnected or dead-end pores significantly impacted the flow patterns and saturation.Two-phase flow patterns and oil saturation distribution reveal a preferential and heterogeneous displacement that mainly swept displaced fluid in some regions of plugs and bypassed it in others.The relation between saturation profiles,porosity profiles,and the number of fluid flow patterns for the samples was evident.Only for the columnar plug sample was the enhancement in recovery factor after shifting to lower salinity water injection(SB)observed.
基金This work was supported by the National Natural Science Foundation of China(52204206,52274246)the Open Fund Project Funded by State Key Laboratory of Gas Disaster Detecting,Preventing and Emergency Controlling(2021SKLFF03)the Natural Science Foundation of Chongqing(cstc2021jcyj-msxmX1149).
文摘Coalbed methane(CBM)recovery is attracting global attention due to its huge reserve and low carbon burning benefits for the environment.Fully understanding the complex structure of coal and its transport properties is crucial for CBM development.This study describes the implementation of mercury intrusion and μ-CT techniques for quantitative analysis of 3D pore structure in two anthracite coals.It shows that the porosity is 7.04%-8.47%and 10.88%-12.11%,and the pore connectivity is 0.5422-0.6852 and 0.7948-0.9186 for coal samples 1 and 2,respectively.The fractal dimension and pore geometric tortuosity were calculated based on the data obtained from 3D pore structure.The results show that the pore structure of sample 2 is more complex and developed,with lower tortuosity,indicating the higher fluid deliverability of pore system in sample 2.The tortuosity in three-direction is significantly different,indicating that the pore structure of the studied coals has significant anisotropy.The equivalent pore network model(PNM)was extracted,and the anisotropic permeability was estimated by PNM gas flow simulation.The results show that the anisotropy of permeability is consistent with the slice surface porosity distribution in 3D pore structure.The permeability in the horizontal direction is much greater than that in the vertical direction,indicating that the dominant transportation channel is along the horizontal direction of the studied coals.The research results achieve the visualization of the 3D complex structure of coal and fully capture and quantify pore size,connectivity,curvature,permeability,and its anisotropic characteristics at micron-scale resolution.This provides a prerequisite for the study of mass transfer behaviors and associated transport mechanisms in real pore structures.
基金support from the National Key Technology R&D Program in the 11th Five-Year Plan Period (Grant No: 2008ZX05054)the Non-main Petroleum Subject Cultivating Fund of China University of Petroleum.
文摘A pore network model was used in this paper to investigate the factors, in particular, throat radius, wettability and initial water saturation, causing water block in low permeability reservoirs. A new term - ＇relative permeability number＇ （RPN） was firstly defined, and then used to describe the degree of water block. Imbibition process simulations show that the RPN drops in accordance with the extension of the averaged pore throat radius from 0.05 to 1.5 μm, and yet once beyond that point of 1.5 μm, the RPN reaches a higher value, indicating the existence of a critical pore throat radius where water block is the maximum. When the wettability of the samples changes from water-wet to weakly water-wet, weakly gas-wet, or gas（oil）-wet, the gas RPN increases consistently, but this consistency is disturbed by the RPN dropping for weakly water-wet samples for water saturations less than 0.4, which means weakly waterwet media are more easily water blocked than water-wet systems. In the situation where the initial water saturation exceeds 0.05, water block escalates along with an increase in initial water saturation.
基金sponsored by PETRONAS and YUTP (Yayasan Universiti Teknologi PETRONAS)
文摘To determine the effect of dissolution on pore network development in carbonate rocks, dissolution experiments, X-Ray microtomography, and thin section analysis were conducted on argillaceous limestone and grain limestone samples at different temperatures and constant pH, HCl concentration. The relationship between Ca^(2+) concentration and time was revealed through the experiments; pore size distribution before and after dissolution indicate that there is no correlation between the temperature and pore size variation, but pore size variation in grain limestone is more significant, indicating that the variation is mainly controlled by the heterogeneity of the rock itself(initial porosity and permeability) and the abundance of unstable minerals(related to crystal shape, size and mineral type). At different temperatures, the two kinds of carbonate rocks had very small variation in pore throat radius from 0.003 mm to 0.040 mm, which is 1.3 to 3.5 times more, 1.7 on average of the original pore throat radius. Their pore throat length varied from 0.05 mm to 0.35 mm. The minor changes in the pore throat radius, length and connectivity brought big changes to permeability of up to 1 000×10^(-3) μm^2.
文摘We characterize the complex pore architecture of four diagenetically altered sandstone samples using micro-CT imaging.By quantifying the pore size and pore connection distributions,we establish that the mean coordination number follows a power-law function of pore radius.Critically,we derive empirical scaling relations between 2D and 3D pore size distributions,as well as 2D and 3D coordination number distributions,both as a function of pore size.These novel relations allow for the 3D pore size and pore connectivity to be accurately characterized from high-resolution 2D imaging(e.g.,SEM),even when the resolution or field-of-view limitations preclude detailed 3D micro-CT analysis.A new stochastic algorithm is presented in this work to generate a 3D pore network model that honors the derived connectivity function.This algorithm was validated by generating stochastic models equivalent to the four sandstone samples and successfully comparing the calculated single-phase and relative permeability results against those obtained from pore networks directly extracted from the 3D micro-CT images.This methodology offers a computationally efficient and scalable tool for predicting the macroscopic transport properties of complex reservoir rocks based on readily available 2D high rock resolution images.
基金Natural Science Foundation of Henan Province of China,Grant/Award Number:232300420438Fundamental Research Funds for the Universities of Henan Province,Grant/Award Numbers:NSFRF220427,NSFRF220204+2 种基金National Natural Science foundation of China,Grant/Award Number:41972175Excellent Youth Foundation of Henan Scientific Committee,Grant/Award Number:232300421025Doctoral Foundation of Henan Polytechnic University,Grant/Award Number:B2021-78。
文摘Pores among particles provide the main space for the storage and migration of deep underground fluids(such as oil,gas,groundwater,and unconventional natural gas).The pores form a pore structure with complex morphology which is mainly dominated by the shape and distribution of particles.Therefore,the reconstruction of the pore structure or granular porous media and the evaluation of particle roundness have become an important foundation for the study of fluid flow through deep underground rock mass.This research proposes a novel approach for the multi-scale model with angular vertexes.The fractal topology theory and Voronoi space segmentation technology are combinedly used for the reconstruction of fractal granular porous media.The angular shapes are smoothed by using a modified B-spline technique and the particles with varying degrees of roundness are generated.To validate the superiority of our approach,the roundness based on the Wadell roundness calculation method is calculated and compared with the roundness obtained from particles smoothed using the vertex rounding substitution method.Results show that the roundness of particles smoothed with the modified B-spline technique closely aligns with the corresponding set rounded level(a nondimensional variable).Conversely,the vertex rounding substitution method is limited to a single dimensionally rounded radius.This innovative approach can offer a new method for the construction of granular porous media for the fluid flow study in deep underground rock mass.
基金the National Natural Science Foundation of China (Nos. 42302143, 42172159)China Geological Survey Project (No. DD20211350)support from the G. Albert Shoemaker endowment
文摘Clayey-silt natural gas hydrate reservoirs in the South China Sea exhibit loose and unconsolidated structures, heterogeneous pore structures, high clay mineral contents, and strong hydrophilicity. These characteristics complicate the gas-water two-phase flow process in porous media following hydrate decomposition, posing challenges for efficient development. This study examines the transport response of clayey-silt reservoir samples from the Shenhu area using gas-water two-phase flow experiments and CT scanning to explore changes in pore structure, gas-water distribution, and relative permeability under varying flow conditions. The results indicate that pore heterogeneity significantly influences flow characteristics. Gas preferentially displaces water in larger pores, forming fracture-like pores, which serve as preferential flow channels for gas migration. The preferential flow channels enhance gas-phase permeability up to 19 times that of the water phase when fluid pressures exceed total stresses. However,small pores retain liquid, leading to a high residual water saturation of 0.561. CT imaging reveals that these hydro-fractures improve gas permeability but also confine gas flow to specific channels. Pore network analysis shows that gas injection expands the pore-throat network, enhancing connectivity and forming fracture-like pores. Residual water remains trapped in smaller pores and throats, while structural changes, including new fractures, improve gas flow pathways and overall connectivity. Relative permeability curves demonstrate a narrow gas-water cocurrent-flow zone, a right-shifted iso-permeability point and high reservoir capillary pressure, indicating a strong "water-blocking" effect. The findings suggest that optimizing reservoir stimulation techniques to enhance fracture formation, reduce residual water saturation, and improve gas flow capacity is critical for efficient hydrate reservoir development.
文摘The physical and chemical properties of rocks play a crucial role in understanding fluid-solid flow behavior at the pore level.Thus,studying pore space characteristics is important in evaluating and determining petrophysical properties of various rock types,including synthetic rocks,which can be designed to mimic natural rocks.This study investigates the petrophysical properties of synthetic car-bonate plugs by using a new approach that correlates the base material and a 3D printing solution with porosity and permeability.The research shows that with precise particle size and morphology,pure mineral materials such as calcite,dolomite,quartz and a non-structural Portland cement may produce a controlled rock matrix.The synthetic plugs developed in this study exhibit controlled macro,meso,and micro porosities,including fractures and vuggys,by the solubilization of materials with controlled morphology by 3D printing,which provides valuable information on regulating pore space in synthetic carbonate rocks.
基金supported by the Shandong Provincial Natural Science Foundation(ZR2024MD116)National Natural Science Foundation of China(Grant Nos.42174143,42004098)Technology Innovation Leading Program of Shaanxi(No.2024 ZC-YYDP-27).
文摘Subsurface rocks,as complex porous media,exhibit multiscale pore structures and intricate physical properties.Digital rock physics technology has become increasingly influential in the study of subsurface rock properties.Given the multiscale characteristics of rock pore structures,direct three-dimensional imaging at sub-micrometer and nanometer scales is typically infeasible.This study introduces a method for reconstructing porous media using multidimensional data,which combines one-dimensional pore structure parameters with two-dimensional images to reconstruct three-dimensional models.The pore network model(PNM)is stochastically reconstructed using one-dimensional parameters,and a generative adversarial network(GAN)is utilized to equip the PNM with pore morphologies derived from two-dimensional images.The digital rocks generated by this method possess excellent controllability.Using Berea sandstone and Grosmont carbonate samples,we performed digital rock reconstructions based on PNM extracted by the maximum ball algorithm and compared them with stochastically reconstructed PNM.Pore structure parameters,permeability,and formation factors were calculated.The results show that the generated samples exhibit good consistency with real samples in terms of pore morphology,pore structure,and physical properties.Furthermore,our method effectively supplements the micropores not captured in CT images,demonstrating its potential in multiscale carbonate samples.Thus,the proposed reconstruction method is promising for advancing porous media property research.
基金supported by the National Natural Science Foundation of China(Grant No.42162026)the Basic Research Program in Yunnan Province,China(Grant No.202401AT070328)the Young Talents Project of“Xingdian Talent Support Program"in Yunnan Province,China(Grant No.YNWR-QNBJ-2020-019).
文摘Disintegrated dolomite slope and tunnel disasters occur frequently due to poor water stability of disintegrated dolomite,primarily in a form of seepage failure.For engineering purposes,it is critical to determine the seepage properties of disintegrated dolomite within the strata.However,conventional experimental methods are time-consuming and expensive and may not be effective in investigating seepage characteristics due to the heterogeneity of disintegrated dolomite.In this study,pore network model(PNM)was established by the computerized tomography(CT)scanning technology to characterize the pores.Meanwhile,the seepage and coefficient of permeability under different inlet stress conditions based on the accurate pore model were realized by linking the commercial image processing software Avizo with the commercial multi-physics modeling package Comsol.The results show that the porosities of severely and completely disintegrated dolomites are 29.17% and 45.37%,respectively.The grade of pore development increases with disintegration grade,which facilitates seepage failure.Severely and completely disintegrated dolomites have the coefficients of permeability of 9.67×10^(-7) m/s and 1.61×10^(-6) m/s,respectively.Under conventional conditions,severely and completely disintegrated dolomites undergo seepage failure above a pressure difference of 6×10^(3) Pa and 5×10^(3) Pa,respectively.These results are consistent with both in situ water pressure tests in the borehole and laboratory tests with the constant-head method,demonstrating that CT scanning is an effective method for observing fractures and pores in disintegrated dolomite for seepage evaluation.
基金supported by the National Science and Technology Major Projects of China (Grant No. 2008ZX05024-03-003-004)
文摘Experiments of proppant conductivity and fluid flow in proppant cost a large amount of time and money,and also require complex devices.Hence,this article puts forward an artificial fracture numerical model based on proppant arrangement analysis and the basic principles of the pore network model.Predictions by the model are made consistent with the experimental results through adjusting the model parameters.It is shown that the established model is effective in making predictions on the permeability of proppant.This model is also used to study the non-Newtonian fluid flow characteristics in artificial fracture.
