Electrochemical CO_(2)reduction reaction(CO_(2)RR)on gas diffusion electrodes(GDEs)offers a promising route for carbon-neutral fuel production at commercially relevant current densities(J>200 mA cm^(-2))[1,2].Howev...Electrochemical CO_(2)reduction reaction(CO_(2)RR)on gas diffusion electrodes(GDEs)offers a promising route for carbon-neutral fuel production at commercially relevant current densities(J>200 mA cm^(-2))[1,2].However,under high-rate operation,GDE performance deteriorates due to mass transport limitations[3,4].First,local CO_(2)depletion near the catalyst surface intensifies the competing hydrogen evolution reaction(HER),diminishing the selectivity[5].展开更多
Subsurface water flow velocity influences the hydrodynamic characteristics of soil seepage and the interaction between subsurface water flow and surface runoff during soil erosion and sediment transport.A visualized m...Subsurface water flow velocity influences the hydrodynamic characteristics of soil seepage and the interaction between subsurface water flow and surface runoff during soil erosion and sediment transport.A visualized method and equipment was adopted in this study to observe the subsurface water flow.Quartz sand was used as the test material of subsurface water flow and fluorescent dye was used as the indicator for tracing subsurface water flow.Water was supplied at the same flow discharge to the three parts at the bottom of the test flume,and the subsurface water flow were determined with four slope gradients(4°,8°,10°,and 12°).The results showed that the seepage velocity gradually increased with increasing slope gradient.The pore water velocity at different depths of sand layer profile increased with increasing slope gradient,whereas the thickness of the flow front gradually decreased.For the same slope gradient,the pore water velocity in the lower layer was the largest,whereas the thickness of the flow front was the smallest.Comparative analysis of the relationship between seepage velocity and pore water velocity at different depths of sand layer profile showed that the maximum relative difference between the measured pore water velocity and the computational pore water velocity at different depths of sand profile in the experiment was 4.38%.Thus,the test method for measuring the subsurface water flow velocity of sand layer profile adopted in this study was effective and feasible.The development of this experiment and the exploration of research methods would lay a good test foundation for future studies on the variation law of subsurface water flow velocity and the determination of flow velocity in purple soils,thus contributing to the improvement of the hydrodynamic mechanism of purple soils.展开更多
This study investigated the cause of identified zones of overpressure in some selected wells in a field in the Niger Delta sedimentary basin. Two models were used each for predicting pore pressure and the correspondin...This study investigated the cause of identified zones of overpressure in some selected wells in a field in the Niger Delta sedimentary basin. Two models were used each for predicting pore pressure and the corresponding fracture pressure using well log and drilling data. Shale lithology in Niger Delta is massive and characterized by high pore pressure;hence shale compaction theory is utilized in this study. The petrophysical data were evaluated using Ikon’s Science Rokdoc software. The two major pore pressure prediction techniques employed are the Eaton’s and Bowers’ models while the Eaton’s fracture pressure model and the Hubbert and Willis fracture pressure prediction models were utilized for fracture prediction. The density and sonic logs were used respectively to generate the shale trend and the shale normal compaction trend used for the prediction. The wells studied showed disequilibrium compaction of sediment to be the major mechanism that gave rise to overpressure in the Niger Delta. Clay diagenesis and fluid expansion were also observed as the secondary overpressure generation mechanism in well X-1. This secondary overpressure mechanism was observed to start approximately at depths of 10,000 ft (TVD). The top of overpressure and the pressure range in the wells studied varied from 6000 to 11,017 ft (TVD) and 1796.70 to 5297.00 psi respectively. The Eaton’s model under-predicts pore pressure at the depth interval where unloading mechanism is witnessed. Since the study revealed presence of secondary overpressure generation mechanism, Bowers model was observed to be the most reliable pore pressure prediction model in the area.展开更多
基金supported by the Natural Science Foundation of China(22178394,22376222,and 52404332)the Science and Technology Innovation Program of Hunan Province(2022RC3048 and 2023RC1012)+1 种基金Central South University Research Program of Advanced Interdisciplinary Studies(2023QYJC012)the Postdoctoral Fellowship Program of CPSF(GZB20240860)for financial support。
文摘Electrochemical CO_(2)reduction reaction(CO_(2)RR)on gas diffusion electrodes(GDEs)offers a promising route for carbon-neutral fuel production at commercially relevant current densities(J>200 mA cm^(-2))[1,2].However,under high-rate operation,GDE performance deteriorates due to mass transport limitations[3,4].First,local CO_(2)depletion near the catalyst surface intensifies the competing hydrogen evolution reaction(HER),diminishing the selectivity[5].
基金This work was supported by the Fundamental Research Funds for the National Natural Science Foundation of China(No.41571265,41971244)the Key Research and Development Project of Social Livelihood in Chongqing(cstc2018jscxmszdX0061)the Foundation of Graduate Research and Innovation in Chongqing under project CYB18089.
文摘Subsurface water flow velocity influences the hydrodynamic characteristics of soil seepage and the interaction between subsurface water flow and surface runoff during soil erosion and sediment transport.A visualized method and equipment was adopted in this study to observe the subsurface water flow.Quartz sand was used as the test material of subsurface water flow and fluorescent dye was used as the indicator for tracing subsurface water flow.Water was supplied at the same flow discharge to the three parts at the bottom of the test flume,and the subsurface water flow were determined with four slope gradients(4°,8°,10°,and 12°).The results showed that the seepage velocity gradually increased with increasing slope gradient.The pore water velocity at different depths of sand layer profile increased with increasing slope gradient,whereas the thickness of the flow front gradually decreased.For the same slope gradient,the pore water velocity in the lower layer was the largest,whereas the thickness of the flow front was the smallest.Comparative analysis of the relationship between seepage velocity and pore water velocity at different depths of sand layer profile showed that the maximum relative difference between the measured pore water velocity and the computational pore water velocity at different depths of sand profile in the experiment was 4.38%.Thus,the test method for measuring the subsurface water flow velocity of sand layer profile adopted in this study was effective and feasible.The development of this experiment and the exploration of research methods would lay a good test foundation for future studies on the variation law of subsurface water flow velocity and the determination of flow velocity in purple soils,thus contributing to the improvement of the hydrodynamic mechanism of purple soils.
文摘This study investigated the cause of identified zones of overpressure in some selected wells in a field in the Niger Delta sedimentary basin. Two models were used each for predicting pore pressure and the corresponding fracture pressure using well log and drilling data. Shale lithology in Niger Delta is massive and characterized by high pore pressure;hence shale compaction theory is utilized in this study. The petrophysical data were evaluated using Ikon’s Science Rokdoc software. The two major pore pressure prediction techniques employed are the Eaton’s and Bowers’ models while the Eaton’s fracture pressure model and the Hubbert and Willis fracture pressure prediction models were utilized for fracture prediction. The density and sonic logs were used respectively to generate the shale trend and the shale normal compaction trend used for the prediction. The wells studied showed disequilibrium compaction of sediment to be the major mechanism that gave rise to overpressure in the Niger Delta. Clay diagenesis and fluid expansion were also observed as the secondary overpressure generation mechanism in well X-1. This secondary overpressure mechanism was observed to start approximately at depths of 10,000 ft (TVD). The top of overpressure and the pressure range in the wells studied varied from 6000 to 11,017 ft (TVD) and 1796.70 to 5297.00 psi respectively. The Eaton’s model under-predicts pore pressure at the depth interval where unloading mechanism is witnessed. Since the study revealed presence of secondary overpressure generation mechanism, Bowers model was observed to be the most reliable pore pressure prediction model in the area.
