The solid-liquid equilibrium of benzoic acid derivatives in 1-octanol was first determined in this article. Using a laser monitoring observation technique, the solubility data of o-amino-benzoic acid, p-amino-benzoic ...The solid-liquid equilibrium of benzoic acid derivatives in 1-octanol was first determined in this article. Using a laser monitoring observation technique, the solubility data of o-amino-benzoic acid, p-amino-benzoic acid,o-chloro-benzoic acid, and m-nitro-benzoic acid in 1-octanol were measured by the polythermal method in the temperature range of 20-50℃. The experimental data were regressed with the. Wilson equation and the λH equation. The experimental results showed that the solubility of the four chemicals in 1-octanol increased significantly with temperature. The results indicate that the molecular structure and interactions affect the solubility significantly.The solubility order of the benzoic acid derivatives is as follows： m-nitro-benzoic acid〉o-chloro-benzoic acid〉 o-amino-benzoic acid〉p-amino-benzoic acid. Both the Wilson equation and λH equation are in good agreement with the experimental data.展开更多
A computer prediction for the regularities of formation of binary bromide system was made. The results indicate that CsBr-CaBf2 molten salt system is binary complex compound-forming system. The phase diagram of CSBr-C...A computer prediction for the regularities of formation of binary bromide system was made. The results indicate that CsBr-CaBf2 molten salt system is binary complex compound-forming system. The phase diagram of CSBr-CaBt2 system has been determined by visual polythermal method in order to prove the prediction. The phase diagrams of the quasibinary system KCl-CsBr, KCl-CaBr2 and the quasiternary system CsBr-CaBr2-KCl were determined by using visual polythermal method. The phase diagrams of CsBr-CaBr2 and KCl-CaBr2 show that the intermediate compound is formed. The results are in agreement with the computer prediction. Here, the various parts of the phase diagram of the quasiternary system CsBr-CaBr2-KCl were discussed.展开更多
基金Supported by the National Natural Science Foundation of China （No.20676101） and the Natural Science Foundation of Tianjin University of Science ＆ Technology （No.20050207）.
文摘The solid-liquid equilibrium of benzoic acid derivatives in 1-octanol was first determined in this article. Using a laser monitoring observation technique, the solubility data of o-amino-benzoic acid, p-amino-benzoic acid,o-chloro-benzoic acid, and m-nitro-benzoic acid in 1-octanol were measured by the polythermal method in the temperature range of 20-50℃. The experimental data were regressed with the. Wilson equation and the λH equation. The experimental results showed that the solubility of the four chemicals in 1-octanol increased significantly with temperature. The results indicate that the molecular structure and interactions affect the solubility significantly.The solubility order of the benzoic acid derivatives is as follows： m-nitro-benzoic acid〉o-chloro-benzoic acid〉 o-amino-benzoic acid〉p-amino-benzoic acid. Both the Wilson equation and λH equation are in good agreement with the experimental data.
文摘A computer prediction for the regularities of formation of binary bromide system was made. The results indicate that CsBr-CaBf2 molten salt system is binary complex compound-forming system. The phase diagram of CSBr-CaBt2 system has been determined by visual polythermal method in order to prove the prediction. The phase diagrams of the quasibinary system KCl-CsBr, KCl-CaBr2 and the quasiternary system CsBr-CaBr2-KCl were determined by using visual polythermal method. The phase diagrams of CsBr-CaBr2 and KCl-CaBr2 show that the intermediate compound is formed. The results are in agreement with the computer prediction. Here, the various parts of the phase diagram of the quasiternary system CsBr-CaBr2-KCl were discussed.
