Succinonitrile(SN)-based polymer plastic crystal electrolytes(PPCEs)are regarded as promising candidates for lithium metal batteries but suffer from serious side reactions with Li metal.Herein,we propose a multi-dimen...Succinonitrile(SN)-based polymer plastic crystal electrolytes(PPCEs)are regarded as promising candidates for lithium metal batteries but suffer from serious side reactions with Li metal.Herein,we propose a multi-dimensional optimization strategy to alleviate the side reactions between SN and Li metal,and develop a highly stable poly-vinylethylene carbonate-based PPCE(PPCE-VEC).Moreover,we identify the intrinsic factors of multi-dimensional polymer structures on the electrolyte stability by three typical classes of polyesters.The PPCE-VEC constructed by in situ polymerization exhibits much better stability than poly-vinylene carbonate-based PPCE(PPCE-VCA)and poly-trifluoroethyl acrylate-based PPCE(PPCE-TFA),which is verified by its fewer SN-decomposition species in X-ray photoelectron spectroscopy(XPS)and outstanding full cell performance.The PPCE-VEC-enabled LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2)full cell achieve 73.7%capacity retention after 1400 cycles,which outperforms PPCE-VCA-and PPCE-TFA-enabled full cells(61.9%and 46.9%).Spectral analysis and theoretical calculation reveal that the high solvation ability of the carbonyl site,flexible polymer chain,and homogeneous electrolyte phase of PPCE-VEC are favorable to maximizing competition coordination with Li^(+)to weaken the Li^(+)–SN binding and shape an anion-rich solvation structure.This optimized polymer-involved Li^(+)solvation enhances SN stability and facilitates the formation of B/F enriched solid-electrolyte interphase(SEI),thus significantly improving PPCE stability.展开更多
Succinonitrile(SN)-based polymer plastic crystal electrolytes(PPCEs)have attracted considerable attention as solid-state electrolytes owing to their high ionic conductivities similar to those of liquid electrolytes,ex...Succinonitrile(SN)-based polymer plastic crystal electrolytes(PPCEs)have attracted considerable attention as solid-state electrolytes owing to their high ionic conductivities similar to those of liquid electrolytes,excellent contacts with the electrodes,and good mechanic properties.As a crucial property of a solid-state electrolyte,the ionic conductivity of the PPCE directly depends on the interactions between the constituent parts including the polymer,lithium salt,and SN.A few studies have focused on the effects of polymer–lithium–salt and polymer–SN interactions on the PPCE ionic conductivity.Nevertheless,the impact of the lithium–salt–SN combination on the PPCE ionic conductivity has not been analyzed.In particular,tuning of the lithium-salt–SN interaction to fabricate a subzero PPCE with a high low-temperature ionic conductivity has not been reported.In this study,we design and fabricate five PPCE membranes with different weight ratios of Li N(SO2 CF3)2(Li TFSI)and SN to investigate the effect of the Li TFSI–SN interaction on the PPCE ionic conductivity.The ionic conductivities of the five PPCEs are investigated in the temperature range of–20 to 60°C by electro-chemical impedance spectroscopy.The interaction is analyzed by Fourier-transform infrared spectroscopy,Raman spectroscopy,and differential scanning calorimetry.The Li TFSI–SN interaction significantly influences the melting point of the PPCE,dissociation of the Li TFSI salt,and thus the PPCE ionic conductivity.By tuning the Li TFSI–SN interaction,a subzero workable PPCE membrane having an excellent low-temperature ionic conductivity(6×10-4 S cm–1 at 0°C)is obtained.The electro-chemical performance of the optimal PPCE is evaluated by using a Li Co O2/PPCE/Li4 Ti5 O12 cell,which confirms the application feasibility of the proposed quasisolid-state electrolyte in subzero workable lithium-ion batteries.展开更多
The plastic cement belongs to a sort of polymer material, the chemical composition is very complex, and the plastic cement work-piece is generally manufactured by die press forming. Aimed at being difficult to control...The plastic cement belongs to a sort of polymer material, the chemical composition is very complex, and the plastic cement work-piece is generally manufactured by die press forming. Aimed at being difficult to control in parameters of forming process, the paper explored the humanoid based intelligence control strategy. In the paper, it made the anatomy in control puzzle resulted in uncertainty such as chemical component of plastic cement etc., summarized up the characteristic of cybernetics in forming process, researched on the humanoid based intelligence control strategy, and constructed the control algorithm of forming process in plastic cement work-piece. Taking the process experiment of temperature and pressure control as an example, it validated the good dynamic and static control quality through simulation of control algorithm constructed in this paper. The experimental results show that the control algorithm explored in this paper is reasonably available.展开更多
Due to the current situation of massive waste consumption and accumulation,the recycling and upgrading utilization of polymer materials is an effective technology to solve environmental pollution.In this work,the recy...Due to the current situation of massive waste consumption and accumulation,the recycling and upgrading utilization of polymer materials is an effective technology to solve environmental pollution.In this work,the recycling and upgrading methods of polymers are summarized,and the latest progress in polymer upcycling is discussed from the perspective of upgrading materials.The common polymer recovery methods,including mechanical recovery,chemical recovery,biocatalysis,and photocatalytic recovery,are discussed based on their mechanism and industrialized application.The upgrading products of polymers are divided into monomers,fuels and fine chemicals.The challenges and prospects of polymer degradation technology are discussed.展开更多
This paper discusses a new fibrous composite known as continuous basalt fiber reinforced polymer /plastic(BFRP).Compared with other fiber reinforced polymer/plastic,BFRP has many advantages,such as ductility,high ther...This paper discusses a new fibrous composite known as continuous basalt fiber reinforced polymer /plastic(BFRP).Compared with other fiber reinforced polymer/plastic,BFRP has many advantages,such as ductility,high thermal resistance,corrosion resistance and economic cost.To test mechanical properties and failure modes of flexural members strengthened with BFRP,flexural experiment is conducted on four two-span T-section continuous beams strengthened with BFRP and one un-strengthened comparative beam.The experimental result shows that the strengthened beams perform remarkably in terms of yield strength,ultimate strength and ductility.BFRP has good prospects in retrofitting and strengthening of concrete structures which require good ductility and corrosion resistance.展开更多
With symmetries measured by the Lie group and curvatures revealed by differential geometry, the continuum stored energy function possesses a translational deformation component, a rotational deformation component, and...With symmetries measured by the Lie group and curvatures revealed by differential geometry, the continuum stored energy function possesses a translational deformation component, a rotational deformation component, and an ellipsoidal volumetric deformation component. The function, originally developed for elastomeric polymers, has been extended to model brittle and ductile polymers. The function fits uniaxial tension testing data for brittle, ductile, and elastomeric polymers, and elucidates deformation mechanisms. A clear distinction in damage modes between brittle and ductile deformations has been captured. The von Mises equivalent stress has been evaluated by the function and the newly discovered break-even stretch. Common practices of constitutive modeling, relevant features of existing models and testing methods, and a new perspective on the finite elasticity-plasticity theory have also been offered.展开更多
The polymer particle possessing hollow structure are playing an increasingly important role in industry. The latex particle with hollow structure as plastic pigment has a low density, strong spreading capacity and goo...The polymer particle possessing hollow structure are playing an increasingly important role in industry. The latex particle with hollow structure as plastic pigment has a low density, strong spreading capacity and good glossiness. So it has been utilized for the manufacture of LWC in paper-making. In this paper, we prepared a kind of novel plastic pigment by the soapless seeded emulsion polymerization, this product with polyacrylate as core and with polystyrene as shell (PA/PS) had hollow structure after dryness. The preparation, characterization and properties of the latex were studied in detail by chemistry analysis and apparatus analysis such as TEM,FTIR,DLS.展开更多
基金supported by the National Natural Science Foundation of China(22072048)the Guangdong Provincial Department of Science and Technology(2021A1515010128 and 2022A0505050013).
文摘Succinonitrile(SN)-based polymer plastic crystal electrolytes(PPCEs)are regarded as promising candidates for lithium metal batteries but suffer from serious side reactions with Li metal.Herein,we propose a multi-dimensional optimization strategy to alleviate the side reactions between SN and Li metal,and develop a highly stable poly-vinylethylene carbonate-based PPCE(PPCE-VEC).Moreover,we identify the intrinsic factors of multi-dimensional polymer structures on the electrolyte stability by three typical classes of polyesters.The PPCE-VEC constructed by in situ polymerization exhibits much better stability than poly-vinylene carbonate-based PPCE(PPCE-VCA)and poly-trifluoroethyl acrylate-based PPCE(PPCE-TFA),which is verified by its fewer SN-decomposition species in X-ray photoelectron spectroscopy(XPS)and outstanding full cell performance.The PPCE-VEC-enabled LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2)full cell achieve 73.7%capacity retention after 1400 cycles,which outperforms PPCE-VCA-and PPCE-TFA-enabled full cells(61.9%and 46.9%).Spectral analysis and theoretical calculation reveal that the high solvation ability of the carbonyl site,flexible polymer chain,and homogeneous electrolyte phase of PPCE-VEC are favorable to maximizing competition coordination with Li^(+)to weaken the Li^(+)–SN binding and shape an anion-rich solvation structure.This optimized polymer-involved Li^(+)solvation enhances SN stability and facilitates the formation of B/F enriched solid-electrolyte interphase(SEI),thus significantly improving PPCE stability.
基金financially supported by the National Natural Science Foundation of China[grant numbers:21503265,51603135,21473241]Ministry of Science and Technology[grant number:2016YFB0100102]Nantong Science and Technology Bureau[grant number:JC2018038]。
文摘Succinonitrile(SN)-based polymer plastic crystal electrolytes(PPCEs)have attracted considerable attention as solid-state electrolytes owing to their high ionic conductivities similar to those of liquid electrolytes,excellent contacts with the electrodes,and good mechanic properties.As a crucial property of a solid-state electrolyte,the ionic conductivity of the PPCE directly depends on the interactions between the constituent parts including the polymer,lithium salt,and SN.A few studies have focused on the effects of polymer–lithium–salt and polymer–SN interactions on the PPCE ionic conductivity.Nevertheless,the impact of the lithium–salt–SN combination on the PPCE ionic conductivity has not been analyzed.In particular,tuning of the lithium-salt–SN interaction to fabricate a subzero PPCE with a high low-temperature ionic conductivity has not been reported.In this study,we design and fabricate five PPCE membranes with different weight ratios of Li N(SO2 CF3)2(Li TFSI)and SN to investigate the effect of the Li TFSI–SN interaction on the PPCE ionic conductivity.The ionic conductivities of the five PPCEs are investigated in the temperature range of–20 to 60°C by electro-chemical impedance spectroscopy.The interaction is analyzed by Fourier-transform infrared spectroscopy,Raman spectroscopy,and differential scanning calorimetry.The Li TFSI–SN interaction significantly influences the melting point of the PPCE,dissociation of the Li TFSI salt,and thus the PPCE ionic conductivity.By tuning the Li TFSI–SN interaction,a subzero workable PPCE membrane having an excellent low-temperature ionic conductivity(6×10-4 S cm–1 at 0°C)is obtained.The electro-chemical performance of the optimal PPCE is evaluated by using a Li Co O2/PPCE/Li4 Ti5 O12 cell,which confirms the application feasibility of the proposed quasisolid-state electrolyte in subzero workable lithium-ion batteries.
文摘The plastic cement belongs to a sort of polymer material, the chemical composition is very complex, and the plastic cement work-piece is generally manufactured by die press forming. Aimed at being difficult to control in parameters of forming process, the paper explored the humanoid based intelligence control strategy. In the paper, it made the anatomy in control puzzle resulted in uncertainty such as chemical component of plastic cement etc., summarized up the characteristic of cybernetics in forming process, researched on the humanoid based intelligence control strategy, and constructed the control algorithm of forming process in plastic cement work-piece. Taking the process experiment of temperature and pressure control as an example, it validated the good dynamic and static control quality through simulation of control algorithm constructed in this paper. The experimental results show that the control algorithm explored in this paper is reasonably available.
基金This work is financially supported by the National Natural Science Foundation of China(22102125)The Innovation Foundation of Key Laboratory of Green Chemical Engineering Process of Ministry of Education(GCX202108)the Scientific Research Foundation of Wuhan Institute of Technology(K2021040)are also acknowledged.
文摘Due to the current situation of massive waste consumption and accumulation,the recycling and upgrading utilization of polymer materials is an effective technology to solve environmental pollution.In this work,the recycling and upgrading methods of polymers are summarized,and the latest progress in polymer upcycling is discussed from the perspective of upgrading materials.The common polymer recovery methods,including mechanical recovery,chemical recovery,biocatalysis,and photocatalytic recovery,are discussed based on their mechanism and industrialized application.The upgrading products of polymers are divided into monomers,fuels and fine chemicals.The challenges and prospects of polymer degradation technology are discussed.
基金the National Key Technology Research and Development Program(No.2009BAJ28B02)
文摘This paper discusses a new fibrous composite known as continuous basalt fiber reinforced polymer /plastic(BFRP).Compared with other fiber reinforced polymer/plastic,BFRP has many advantages,such as ductility,high thermal resistance,corrosion resistance and economic cost.To test mechanical properties and failure modes of flexural members strengthened with BFRP,flexural experiment is conducted on four two-span T-section continuous beams strengthened with BFRP and one un-strengthened comparative beam.The experimental result shows that the strengthened beams perform remarkably in terms of yield strength,ultimate strength and ductility.BFRP has good prospects in retrofitting and strengthening of concrete structures which require good ductility and corrosion resistance.
文摘With symmetries measured by the Lie group and curvatures revealed by differential geometry, the continuum stored energy function possesses a translational deformation component, a rotational deformation component, and an ellipsoidal volumetric deformation component. The function, originally developed for elastomeric polymers, has been extended to model brittle and ductile polymers. The function fits uniaxial tension testing data for brittle, ductile, and elastomeric polymers, and elucidates deformation mechanisms. A clear distinction in damage modes between brittle and ductile deformations has been captured. The von Mises equivalent stress has been evaluated by the function and the newly discovered break-even stretch. Common practices of constitutive modeling, relevant features of existing models and testing methods, and a new perspective on the finite elasticity-plasticity theory have also been offered.
文摘The polymer particle possessing hollow structure are playing an increasingly important role in industry. The latex particle with hollow structure as plastic pigment has a low density, strong spreading capacity and good glossiness. So it has been utilized for the manufacture of LWC in paper-making. In this paper, we prepared a kind of novel plastic pigment by the soapless seeded emulsion polymerization, this product with polyacrylate as core and with polystyrene as shell (PA/PS) had hollow structure after dryness. The preparation, characterization and properties of the latex were studied in detail by chemistry analysis and apparatus analysis such as TEM,FTIR,DLS.
