The role of auxiliary LAB as vehicle in dyeing polyester/wool blends with disperse dyes is described. Dye exhaustion and bonding on polyester/wool samples are studied under different experimental conditions - the LAB ...The role of auxiliary LAB as vehicle in dyeing polyester/wool blends with disperse dyes is described. Dye exhaustion and bonding on polyester/wool samples are studied under different experimental conditions - the LAB amount, the temperature and pH value- to achieve optimum conditions. The results are compared with those obtained with and without conventional dyeing auxiliary products. Although dye exhaustion is higher in the presence of commercial carriers, the dye bonded increases markedly in the presence of auxiliary LAB in both fibers. The role played by auxiliary LAB in polyester/wool blend dyeing can provide a new method for this process.展开更多
Copolyesters having secondary and tertiary amine salt groups in the main and side chains are prepared by chemoselective polymerization. These copolyesters are soluble in a 10% aqueous solution of poly(vinyl alcohol) ...Copolyesters having secondary and tertiary amine salt groups in the main and side chains are prepared by chemoselective polymerization. These copolyesters are soluble in a 10% aqueous solution of poly(vinyl alcohol) (PVA) at 90 degree C and act as plasticizer in the blend films cast from the solution. Only a glass transition temperature is observed for all these blends indicating the formation of compatible blends from these polyesters with PVA. These blends exhibit manifold characteristics such as ionic conductivity, complex formation with metal ions, absorption of moisture and color changes. The electric conductivity of the copolyesters and blends is in the range of 10** minus **6 Scm** minus **1. The blends with PVA forms complexes with Cu**2** plus and Co**2** plus . The coordination structure with two chelate rings is suggested for these polymer blend/metal complexes. (Author abstract) 10 Refs.展开更多
Blends of polyamide (Nylon 66) with two different kinds of liquid crystalline polyesters were studied in all the composition range. Homogeneous samples were obtained by coprccipitation from 2 wt%. solution of blends. ...Blends of polyamide (Nylon 66) with two different kinds of liquid crystalline polyesters were studied in all the composition range. Homogeneous samples were obtained by coprccipitation from 2 wt%. solution of blends. The thermal properties, crystallinity and morphology of these blends were studied by using DSC, polarizing microscopy, and scanning electron microscopy. The phase transition and morphology of the blends are markedly-influenced by the composition of liquid crystalline polyesters. The mechanical behaviour of PHB/HNA-Nylon 66 blend was improved. although polyamidc (Nylon 66)with the liquid crystalline polyesters were incompatible, but a rather strong interaction between the polymers did exist.展开更多
The effects of the blending ratio on the properties of Ramie/Polyester blended yarns are discussed in this paper. The experimental results show that the elongation of the yarn with the polyester content more than 40% ...The effects of the blending ratio on the properties of Ramie/Polyester blended yarns are discussed in this paper. The experimental results show that the elongation of the yarn with the polyester content more than 40% is better than that of others. There is a lowest tenacity of the yarn corresponding to the blending ratio of 50/50 or so. The other properties of the yarn, such as the evenness and hairiness, will be improved with the increasing of the polyester content.展开更多
Ultrafine polypropylene fibers are prepared frompolypropylene/easily hydro - degraded polyester （PP/EHDPET） blend fibers, in which file EHDPET compo-nent is degradable by treating with NaOH - H<sub>2</sub&g...Ultrafine polypropylene fibers are prepared frompolypropylene/easily hydro - degraded polyester （PP/EHDPET） blend fibers, in which file EHDPET compo-nent is degradable by treating with NaOH - H<sub>2</sub>O solu-tion. We investigated the morphology of PP/EHDPETblend fibers before and after stretching and alkalinehydrolysis. Then thermal behavior of the blend has alsobeen studied.展开更多
Cation Dyeable Polyester(CDP)was made by copolymerizing dimethyl terephthalate(DMT),S-sodium sulfonate dimethyl isophthalate(SIPM) with a weight fraction of 4.5% and ethyleneglycol (EG).Blend of PET and CDP was spun i...Cation Dyeable Polyester(CDP)was made by copolymerizing dimethyl terephthalate(DMT),S-sodium sulfonate dimethyl isophthalate(SIPM) with a weight fraction of 4.5% and ethyleneglycol (EG).Blend of PET and CDP was spun into hollow fiber.The fiber was then treated withaqueous NaOH.In this paper,kinetics and mechanism of alkaline hydrolysis of PET,CDP andtheir blend PET/CDP fiber were studied by means of specific area measurement,scantling elec-tron microscopy and other chemical analyses.It was showed that the rate of alkaline hydrolysis isCDP】PET/CDP】PET.Because of blending effect,the alkaline hydrolysis of PET/CDP is dif-ferent from that of PET.CDP phase in the PET/CDP fiber is predominantly hydrolyzed,andhence some pieces of fiber(micro-fiber) fall off the fiber because of etching.展开更多
Pilling is a severe concern for blended fabrics. The aesthetic look and smoothness are the buyers’ prime requirements. The main focus of the study was to see the pilling behavior from various percentages of polyester...Pilling is a severe concern for blended fabrics. The aesthetic look and smoothness are the buyers’ prime requirements. The main focus of the study was to see the pilling behavior from various percentages of polyester fiber blend ratio as well as the different pilling cycles on blended fabrics. The cotton, polyester, and elastane prepared the study fabrics. These fabrics are (90% Cotton/5% Polyester/5% Elastane, 90% Cotton/6% Polyester/4% Elastane, 90% Cotton/7% Polyester/3% Elastane, 90% Cotton/8% Polyester/2% Elastane, and 90% Cotton/9% Polyester/1% Elastane, 85% Cotton/10% Polyester/5% Elastane, 85% Cotton/11% Polyester/4% Elastane, 85% Cotton/12% Polyester/3% Elastane, 85% Cotton/13% Polyester/2% Elastane, and 85% Cotton/ 14% Polyester/1% Elastane, 80% Cotton/15% Polyester/5% Elastane, 80% Cotton/16% Polyester/4% Elastane, 80% Cotton/17% Polyester/3% Elastane, 80% Cotton/18% Polyester/2% Elastane, and 80% Cotton/19% Polyester/1% Elastane). The selected polyester blend ratios were 5%, 6%, 7%, 8%, 9%, 10%, 11%, 12%, 13%, 14%, 15%, 16%, 17%, 18% and 19% respectively. The study used the Martindale pilling tester with 2000, 5000, and 7000 cycles, respectively. The evaluation followed the ISO 12945-2:2000. The study findings are that the polyester fiber blend ratio did not influence the pilling grade on blended fabrics for pilling cycles 2000, and the pilling grade remained constant at 4 - 5. The pilling grade started to deteriorate in pilling cycle 5000 for the fabrics 85%C/10%P/5%E, 85%C/11%P/4%E, 85%C/12%P/3%E, 85%C/ 13%P/2%E, 85%C/14%P/1%E showed the pilling grade 4, and the fabrics made from 80%C/15%P/5%E, 80%C/16%P/4%E, 80%C/17%P/3%E, 80%C/ 18%P/2%E, 80%C/19%P/1%E showed the pilling grade 4, 3, 3, 3, and 3 respectively. For the pilling cycles 7000, the pilling grade further deteriorated for the fabrics 80%C/15%P/5%E, 80%C/16%P/4%E, 80%C/17%P/3%E, 80%C/ 18%P/2%E, 80%C/19%P/1%E showed the pilling grade 3, 3, 2, 2, and 2 respectively. The study finds the dominance of polyester fiber throughout the experiment. The author hopes this study’s outcome will help new researchers, advanced researchers, and the textile industry’s sustainable development research and development team.展开更多
An easy hydrolysis degradable polyester (EHDP) is synthesized; the fiber produced from which can be hydrolyzed by dilute basic solution easily. The properties of these kind polyesters are measured. The results show th...An easy hydrolysis degradable polyester (EHDP) is synthesized; the fiber produced from which can be hydrolyzed by dilute basic solution easily. The properties of these kind polyesters are measured. The results show that this kind polymer is suitable to be spun into filament The EHDP can be spun into staple fiber and manufactured into non-woven fabric. This fabric is used as disposable clothes. In composite spinning, the PET (polyethylen glycol terephthalate) or PA (polyamide) is used as continuous phase, and EHDP used as dispersed phase. Then the fabric of this kind fiber is treated by basic solution; the ultra-fine fiber fabric is obtained.The fineness of the fiber is about 0.045 dtex. In blend spinning, EHDP is mixed with polypropylene (PP) to produce hollow fiber with micro-holes in radical direction. This fiber is a usable material in filter especially in medical use.展开更多
The bursting strength is an essential quality parameter of knit fabric. The fabric structure, weight, types of fibers, and fiber blend proportion influence the bursting strength parameter. The tenacity of polyester fi...The bursting strength is an essential quality parameter of knit fabric. The fabric structure, weight, types of fibers, and fiber blend proportion influence the bursting strength parameter. The tenacity of polyester fiber is better than cotton and spandex. The study focused on predicting knit fabric bursting strength test value using different fibers (cotton, polyester, and spandex) with varying percentages of the blend ratio. This study used fifteen categories of blended fabrics. The Pearson Correlation and the hypothetical ANOVA regression analysis were conducted to do the statistical significance test. The experimental result reveals that the bursting strength test result increased with the increased percentage of polyester and suggested a suitable regression equation. The dominance of the polyester fiber was observed throughout the experiment, i.e., the higher the polyester blend proportion, the higher the bursting strength value. The inclusion of polyester in blends can reduce the cost of fabric. The developed prediction model or equation can help the fabric manufacturer make appropriate decisions regarding getting the expected bursting strength. The researcher hopes that the findings from this study will motivate new researchers, advanced researchers, and the textile manufacturing industry.展开更多
文摘The role of auxiliary LAB as vehicle in dyeing polyester/wool blends with disperse dyes is described. Dye exhaustion and bonding on polyester/wool samples are studied under different experimental conditions - the LAB amount, the temperature and pH value- to achieve optimum conditions. The results are compared with those obtained with and without conventional dyeing auxiliary products. Although dye exhaustion is higher in the presence of commercial carriers, the dye bonded increases markedly in the presence of auxiliary LAB in both fibers. The role played by auxiliary LAB in polyester/wool blend dyeing can provide a new method for this process.
文摘Copolyesters having secondary and tertiary amine salt groups in the main and side chains are prepared by chemoselective polymerization. These copolyesters are soluble in a 10% aqueous solution of poly(vinyl alcohol) (PVA) at 90 degree C and act as plasticizer in the blend films cast from the solution. Only a glass transition temperature is observed for all these blends indicating the formation of compatible blends from these polyesters with PVA. These blends exhibit manifold characteristics such as ionic conductivity, complex formation with metal ions, absorption of moisture and color changes. The electric conductivity of the copolyesters and blends is in the range of 10** minus **6 Scm** minus **1. The blends with PVA forms complexes with Cu**2** plus and Co**2** plus . The coordination structure with two chelate rings is suggested for these polymer blend/metal complexes. (Author abstract) 10 Refs.
文摘Blends of polyamide (Nylon 66) with two different kinds of liquid crystalline polyesters were studied in all the composition range. Homogeneous samples were obtained by coprccipitation from 2 wt%. solution of blends. The thermal properties, crystallinity and morphology of these blends were studied by using DSC, polarizing microscopy, and scanning electron microscopy. The phase transition and morphology of the blends are markedly-influenced by the composition of liquid crystalline polyesters. The mechanical behaviour of PHB/HNA-Nylon 66 blend was improved. although polyamidc (Nylon 66)with the liquid crystalline polyesters were incompatible, but a rather strong interaction between the polymers did exist.
文摘The effects of the blending ratio on the properties of Ramie/Polyester blended yarns are discussed in this paper. The experimental results show that the elongation of the yarn with the polyester content more than 40% is better than that of others. There is a lowest tenacity of the yarn corresponding to the blending ratio of 50/50 or so. The other properties of the yarn, such as the evenness and hairiness, will be improved with the increasing of the polyester content.
文摘Ultrafine polypropylene fibers are prepared frompolypropylene/easily hydro - degraded polyester （PP/EHDPET） blend fibers, in which file EHDPET compo-nent is degradable by treating with NaOH - H<sub>2</sub>O solu-tion. We investigated the morphology of PP/EHDPETblend fibers before and after stretching and alkalinehydrolysis. Then thermal behavior of the blend has alsobeen studied.
文摘Cation Dyeable Polyester(CDP)was made by copolymerizing dimethyl terephthalate(DMT),S-sodium sulfonate dimethyl isophthalate(SIPM) with a weight fraction of 4.5% and ethyleneglycol (EG).Blend of PET and CDP was spun into hollow fiber.The fiber was then treated withaqueous NaOH.In this paper,kinetics and mechanism of alkaline hydrolysis of PET,CDP andtheir blend PET/CDP fiber were studied by means of specific area measurement,scantling elec-tron microscopy and other chemical analyses.It was showed that the rate of alkaline hydrolysis isCDP】PET/CDP】PET.Because of blending effect,the alkaline hydrolysis of PET/CDP is dif-ferent from that of PET.CDP phase in the PET/CDP fiber is predominantly hydrolyzed,andhence some pieces of fiber(micro-fiber) fall off the fiber because of etching.
文摘Pilling is a severe concern for blended fabrics. The aesthetic look and smoothness are the buyers’ prime requirements. The main focus of the study was to see the pilling behavior from various percentages of polyester fiber blend ratio as well as the different pilling cycles on blended fabrics. The cotton, polyester, and elastane prepared the study fabrics. These fabrics are (90% Cotton/5% Polyester/5% Elastane, 90% Cotton/6% Polyester/4% Elastane, 90% Cotton/7% Polyester/3% Elastane, 90% Cotton/8% Polyester/2% Elastane, and 90% Cotton/9% Polyester/1% Elastane, 85% Cotton/10% Polyester/5% Elastane, 85% Cotton/11% Polyester/4% Elastane, 85% Cotton/12% Polyester/3% Elastane, 85% Cotton/13% Polyester/2% Elastane, and 85% Cotton/ 14% Polyester/1% Elastane, 80% Cotton/15% Polyester/5% Elastane, 80% Cotton/16% Polyester/4% Elastane, 80% Cotton/17% Polyester/3% Elastane, 80% Cotton/18% Polyester/2% Elastane, and 80% Cotton/19% Polyester/1% Elastane). The selected polyester blend ratios were 5%, 6%, 7%, 8%, 9%, 10%, 11%, 12%, 13%, 14%, 15%, 16%, 17%, 18% and 19% respectively. The study used the Martindale pilling tester with 2000, 5000, and 7000 cycles, respectively. The evaluation followed the ISO 12945-2:2000. The study findings are that the polyester fiber blend ratio did not influence the pilling grade on blended fabrics for pilling cycles 2000, and the pilling grade remained constant at 4 - 5. The pilling grade started to deteriorate in pilling cycle 5000 for the fabrics 85%C/10%P/5%E, 85%C/11%P/4%E, 85%C/12%P/3%E, 85%C/ 13%P/2%E, 85%C/14%P/1%E showed the pilling grade 4, and the fabrics made from 80%C/15%P/5%E, 80%C/16%P/4%E, 80%C/17%P/3%E, 80%C/ 18%P/2%E, 80%C/19%P/1%E showed the pilling grade 4, 3, 3, 3, and 3 respectively. For the pilling cycles 7000, the pilling grade further deteriorated for the fabrics 80%C/15%P/5%E, 80%C/16%P/4%E, 80%C/17%P/3%E, 80%C/ 18%P/2%E, 80%C/19%P/1%E showed the pilling grade 3, 3, 2, 2, and 2 respectively. The study finds the dominance of polyester fiber throughout the experiment. The author hopes this study’s outcome will help new researchers, advanced researchers, and the textile industry’s sustainable development research and development team.
文摘An easy hydrolysis degradable polyester (EHDP) is synthesized; the fiber produced from which can be hydrolyzed by dilute basic solution easily. The properties of these kind polyesters are measured. The results show that this kind polymer is suitable to be spun into filament The EHDP can be spun into staple fiber and manufactured into non-woven fabric. This fabric is used as disposable clothes. In composite spinning, the PET (polyethylen glycol terephthalate) or PA (polyamide) is used as continuous phase, and EHDP used as dispersed phase. Then the fabric of this kind fiber is treated by basic solution; the ultra-fine fiber fabric is obtained.The fineness of the fiber is about 0.045 dtex. In blend spinning, EHDP is mixed with polypropylene (PP) to produce hollow fiber with micro-holes in radical direction. This fiber is a usable material in filter especially in medical use.
文摘The bursting strength is an essential quality parameter of knit fabric. The fabric structure, weight, types of fibers, and fiber blend proportion influence the bursting strength parameter. The tenacity of polyester fiber is better than cotton and spandex. The study focused on predicting knit fabric bursting strength test value using different fibers (cotton, polyester, and spandex) with varying percentages of the blend ratio. This study used fifteen categories of blended fabrics. The Pearson Correlation and the hypothetical ANOVA regression analysis were conducted to do the statistical significance test. The experimental result reveals that the bursting strength test result increased with the increased percentage of polyester and suggested a suitable regression equation. The dominance of the polyester fiber was observed throughout the experiment, i.e., the higher the polyester blend proportion, the higher the bursting strength value. The inclusion of polyester in blends can reduce the cost of fabric. The developed prediction model or equation can help the fabric manufacturer make appropriate decisions regarding getting the expected bursting strength. The researcher hopes that the findings from this study will motivate new researchers, advanced researchers, and the textile manufacturing industry.
