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The Deep Sea No. 1 Semi-Submersible Energy Station 被引量:1
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作者 Da Li Cong Yi Lusheng Jia 《Engineering》 2025年第7期18-23,共6页
1.Introduction As China’s first floating production platform in ultra-deepwater,the“Deep Sea No.1”energy station is a milestone in China’s deepwater resource utilization.The energy station is located in the LS17-2... 1.Introduction As China’s first floating production platform in ultra-deepwater,the“Deep Sea No.1”energy station is a milestone in China’s deepwater resource utilization.The energy station is located in the LS17-2 gas field,150 km off the southeast coast of Hainan Island,China.It is a semi-submersible platform(Fig.1)with a displacement of 101 thousand tonnes and an operational draft of 35 to 40 m.The platform is permanently moored in 1422 m water by 16 chain-polyester-chain mooring lines in a 4×4 pattern,and six steel catenary risers(SCRs)are attached to the platform.It is the world’s first and only semi-submersible platform with the function of condensate storage,so it can be regarded as a floating production storage and offloading(FPSO)unit.With the ability to produce 3 billion m3 of natural gas each year(enough for over 10 million families),the Deep Sea No.1 energy station is a key step toward China’s energy independence.The LS17-2 gas field,where the Deep Sea No.1 energy station is located,was discovered in 2014.Plans for its development were made in 2015,followed by research and a preliminary design.Deep Sea No.1 went into operation on June 25,2021,and will operate onsite continuously without dry-docking for 30 years. 展开更多
关键词 deepwater resource condensate storage floating production storage offloading energy independence floating production platform semi submersible platform deepwater resource utilization energy station
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A Newly Established Air Pollution Data Center in China 被引量:1
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作者 Mei ZHENG Tianle ZHANG +11 位作者 Yaxin XIANG Xiao TANG Yinan WANG Guannan GENG Yuying WANG Yingjun LIU Chunxiang YE Caiqing YAN Yingjun CHEN Jiang ZHU Qiang ZHANG Tong ZHU 《Advances in Atmospheric Sciences》 2025年第4期597-604,共8页
Air pollution in China covers a large area with complex sources and formation mechanisms,making it a unique place to conduct air pollution and atmospheric chemistry research.The National Natural Science Foundation of ... Air pollution in China covers a large area with complex sources and formation mechanisms,making it a unique place to conduct air pollution and atmospheric chemistry research.The National Natural Science Foundation of China’s Major Research Plan entitled“Fundamental Researches on the Formation and Response Mechanism of the Air Pollution Complex in China”(or the Plan)has funded 76 research projects to explore the causes of air pollution in China,and the key processes of air pollution in atmospheric physics and atmospheric chemistry.In order to summarize the abundant data from the Plan and exhibit the long-term impacts domestically and internationally,an integration project is responsible for collecting the various types of data generated by the 76 projects of the Plan.This project has classified and integrated these data,forming eight categories containing 258 datasets and 15 technical reports in total.The integration project has led to the successful establishment of the China Air Pollution Data Center(CAPDC)platform,providing storage,retrieval,and download services for the eight categories.This platform has distinct features including data visualization,related project information querying,and bilingual services in both English and Chinese,which allows for rapid searching and downloading of data and provides a solid foundation of data and support for future related research.Air pollution control in China,especially in the past decade,is undeniably a global exemplar,and this data center is the first in China to focus on research into the country’s air pollution complex. 展开更多
关键词 air pollution data center PLATFORM multi-source data China
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Carbon emission reduction strategies in Guangdong Province of China:A cost-effectiveness perspective 被引量:1
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作者 Guanyang Luo Dan Wu +2 位作者 Li Liu Pingjian Yang Hao Lv 《Journal of Environmental Sciences》 2025年第9期910-923,共14页
Guangdong’s carbon emissions have surpassed the world’s 11th largest emitter.It is indispensable for this province to find a robust cost-effective strategy for reducing carbon emissions.This study employed the Low E... Guangdong’s carbon emissions have surpassed the world’s 11th largest emitter.It is indispensable for this province to find a robust cost-effective strategy for reducing carbon emissions.This study employed the Low Emissions Analysis Platform model,marginal cost curves,and Monte Carlo methods to simulate the energy consumption,carbon emissions,and economic benefits of emission reduction in Guangdong Province from 2020 to 2030 under the application of various structural optimization policies and energy-saving technologies.The main findings are as follows:In 2030,Guangdong Province is projected to achieve a carbon emission reduction of 273.6 to 304.6million t CO_(2eq),with a total reduction cost ranging from 1030.9 to 1452.2 billion yuan.Increasing the share of renewable energy,which still has significant growth potential,can lead to a 1.4 times greater reduction in carbon emissions compared to the application of energy-saving technologies,despite the latter yielding 2.3 times more energy savings.The emission reduction measures with net-cost can contribute 71.4%to the total carbon reduction of the province,being much larger than those with net benefits.The power sector plays a critical role in carbon emission reduction within Guangdong Province,with its various measures exerting the most substantial impact on emission reduction quantity and cost,contributing cumulative variance contributions of 90.1%and 84.3%,respectively.It has relatively large potential for emission reduction and relatively low cost of structural adjustment. 展开更多
关键词 Carbon reduction Low emissions analysis platform Monte Carlo COST-EFFECTIVENESS Energy conservation Scenario analysis
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Data-Driven Prediction of Maximum Displacement of Flexible Riser Based on Movement of Platform 被引量:1
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作者 SONG Jin-ze WU Yu-ze +3 位作者 HE Yu-fa ZHOU Shui-gen ZHU Hong-jun DENG Kai-rui 《China Ocean Engineering》 2025年第5期793-805,共13页
Mitigating vortex-induced vibrations(VIV)in flexible risers represents a critical concern in offshore oil and gas production,considering its potential impact on operational safety and efficiency.The accurate predictio... Mitigating vortex-induced vibrations(VIV)in flexible risers represents a critical concern in offshore oil and gas production,considering its potential impact on operational safety and efficiency.The accurate prediction of displacement and position of VIV in flexible risers remains challenging under actual marine conditions.This study presents a data-driven model for riser displacement prediction that corresponds to field conditions.Experimental data analysis reveals that the XGBoost algorithm predicts the maximum displacement and position with superior accuracy compared with Support vector regression(SVR),considering both computational efficiency and precision.Platform displacement in the Y-direction demonstrates a significant positive correlation with both axial depth and maximum displacement magnitude.The fourth point displacement exhibits the highest contribution to model prediction outcomes,showing a positive influence on maximum displacement while negatively affecting the axial depth of maximum displacement.Platform displacement in the X-and Y-directions exhibits competitive effects on both the riser’s maximum displacement and its axial depth.Through the implementation of XGBoost algorithm and SHapley Additive exPlanation(SHAP)analysis,the model effectively estimates the riser’s maximum displacement and its precise location.This data-driven approach achieves predictions using minimal,readily available data points,enhancing its practical field applications and demonstrating clear relevance to academic and professional communities. 展开更多
关键词 data-driven method flexible riser vortex-induced vibration(VIV) platform displacement
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Multi-hop quantum teleportation based on HSES via GHZ-like states 被引量:1
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作者 She-Xiang Jiang Xiao-Long Wei +1 位作者 Jin-Huan Li Shuai-Shuai Li 《Chinese Physics B》 2025年第1期60-70,共11页
Implementing quantum wireless multi-hop network communication is essential to improve the global quantum network system. In this paper, we employ eight-level GHZ states as quantum channels to realize multi-hop quantum... Implementing quantum wireless multi-hop network communication is essential to improve the global quantum network system. In this paper, we employ eight-level GHZ states as quantum channels to realize multi-hop quantum communication, and utilize the logical relationship between the measurements of each node to derive the unitary operation performed by the end node. The hierarchical simultaneous entanglement switching(HSES) method is adopted, resulting in a significant reduction in the consumption of classical information compared to multi-hop quantum teleportation(QT)based on general simultaneous entanglement switching(SES). In addition, the proposed protocol is simulated on the IBM Quantum Experiment platform(IBM QE). Then, the data obtained from the experiment are analyzed using quantum state tomography, which verifies the protocol's good fidelity and accuracy. Finally, by calculating fidelity, we analyze the impact of four different types of noise(phase-damping, amplitude-damping, phase-flip and bit-flip) in this protocol. 展开更多
关键词 multi-hop quantum teleportation GHZ-like state hierarchical simultaneous entanglement swapping IBM Quantum Experiment platform quantum state tomography
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Hybrid Teaching Reform and Practice in Big Data Collection and Preprocessing Courses Based on the Bosi Smart Learning Platform 被引量:1
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作者 Yang Wang Xuemei Wang Wanyan Wang 《Journal of Contemporary Educational Research》 2025年第2期96-100,共5页
This study examines the Big Data Collection and Preprocessing course at Anhui Institute of Information Engineering,implementing a hybrid teaching reform using the Bosi Smart Learning Platform.The proposed hybrid model... This study examines the Big Data Collection and Preprocessing course at Anhui Institute of Information Engineering,implementing a hybrid teaching reform using the Bosi Smart Learning Platform.The proposed hybrid model follows a“three-stage”and“two-subject”framework,incorporating a structured design for teaching content and assessment methods before,during,and after class.Practical results indicate that this approach significantly enhances teaching effectiveness and improves students’learning autonomy. 展开更多
关键词 Big Data Collection and Preprocessing Bosi smart learning platform Hybrid teaching Teaching reform
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Current development and prospect of national science and technology innovation platform in the railway industry 被引量:1
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作者 Fang Zhao Jinping Liu +3 位作者 Chunguang Zhang Zeping Zhao Xue Ning Junbiao Wang 《Railway Sciences》 2025年第2期266-279,共14页
Purpose–This study summarizes the overall situation of the resources of the national science and technology innovation platform in the railway industry,including the distribution of platform types,supporting institut... Purpose–This study summarizes the overall situation of the resources of the national science and technology innovation platform in the railway industry,including the distribution of platform types,supporting institutions,construction sites,professional fields,etc.,to provide a reference for the further improvement and optimization of the national science and technology innovation platform system in the railway industry.Design/methodology/approach–Through literature review,field investigation,expert consultation and other methods,this paper systematically investigates and analyzes the development status of the national science and technology innovation platform in the railway industry.Findings–Taking the national science and technology innovation platform of the railway industry as the research object,this paper investigates and analyzes the construction,development and distribution of the national science and technology innovation platform of railway industry over the years.And the National Engineering Research Center of High-speed Railway and Urban Rail Transit System Technology was taken as an example to introduce its operation effect.Originality/value–China Railway has made great development achievements,with the construction and development of national science and technology innovation platform in the railway industry.In recent years,a large number of national science and technology innovation platforms have been built in the railway industry,which play an important role in railway technological innovation,standard setting and commodification,and Railway Sciences provide strong support for railway technology development. 展开更多
关键词 Railway industry National science and technology innovation platform Current development and prospect
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Monitoring and Data Analysis of Mooring Tension for Floating Platforms
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作者 YANG Hua−wei ZHENG Qing−xin +2 位作者 XU Chun YANG Qi−fan JIANG Zhen−tao 《船舶力学》 北大核心 2025年第6期941-951,共11页
Mooring cable tension is a crucial parameter for evaluating the safety and reliability of a floating platform mooring system.The real-time mooring tension in an actual marine environment has always been essential data... Mooring cable tension is a crucial parameter for evaluating the safety and reliability of a floating platform mooring system.The real-time mooring tension in an actual marine environment has always been essential data that mooring system designers aim to acquire.To address the need for long-term continuous monitoring of mooring tension in deep-sea marine environments,this paper presents a mooring cable tension monitoring method based on the principle of direct mechanical measurement.The developed tension monitoring sensors were installed and applied in the mooring system of the"Yongle"scientific experimental platform.Over the course of one year,a substantial amount of in-situ tension monitoring data was obtained.Under wave heights of up to 1.24 m,the mooring tension on the floating platform reached 16.5 tons.Through frequency domain and time domain analysis,the spectral characteristics of mooring tension,including waveinduced force,slow drift force,and mooring cable elastic restoring force,were determined.The mooring cable elastic restoring force frequency was approximately half of that of the wave signal.Due to the characteristics of the hinge connection structure of the dual module floating platform,under some specific working conditions the wave-induced force was the maximum of the three different frequency forces,and restoring force was the smallest. 展开更多
关键词 floating platform mooring tension tension monitoring sensor wave frequency force drift force
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IMS Debut at CAEXPO Empowers Overseas Marketing
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作者 Feng Jiahan 《China Report ASEAN》 2025年第9期34-35,共2页
Inmyshow Digital Technology(Group)Company(IMS),a leading enterprise in the digital economy,debuted at the 22nd China-ASEAN Expo(CAEXPO)by presenting its innovative achievements such as the AIGC marketing platform“Ins... Inmyshow Digital Technology(Group)Company(IMS),a leading enterprise in the digital economy,debuted at the 22nd China-ASEAN Expo(CAEXPO)by presenting its innovative achievements such as the AIGC marketing platform“Inspiration Island”and the“TopKlout Summit,”which showcased its technological breakthroughs and practical experience in the fields of intelligent content generation,cyber celebrity marketing,and cross-border digital marketing. 展开更多
关键词 debut marketing platform innovative achievements aigc marketing platform inspiration CAEXPO intelligent content generationcyber celebrity marketingand overseas marketing AIGC
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Coupled Hydrodynamic and Energy Conversion Performance of a Semi-Submersible Wind Turbine and Flap-Type Wave Energy Converter Integrated System
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作者 ZHOU Zhao-min XIANG Ruo-xuan +4 位作者 WANG Tao WU Xiu-shan ZHENG Zhi JIN Peng ZHOU Bin-zhen 《China Ocean Engineering》 2025年第3期470-483,共14页
The integrated system composed of wave energy converters and floating wind turbines offers substantial potential for reducing the levelized cost of energy(LCOE) by sharing the infrastructure, mooring system, substatio... The integrated system composed of wave energy converters and floating wind turbines offers substantial potential for reducing the levelized cost of energy(LCOE) by sharing the infrastructure, mooring system, substations and cables.This paper proposes an integrated system consisting of a semi-submersible wind turbine platform and three Wave Star flap-type wave energy converters. The coupled motion model of the integrated system is established and validated on the basis of viscously corrected potential flow theory. This study investigates the influence of two key parameters,the arm length and hinge points of flap-type wave energy converters, on system performance. The results reveal that variations in the arm length of flap-type wave energy converters(WECs) are the primary determinants of the integrated system's dynamic characteristics, whereas changes in hinge points predominantly affect device power generation.Additionally, incorporating WECs reduces the pitch and heave motions of the platform within a specific wave frequency range, thereby enhancing the energy output of the integrated system at the operational sea site. The performance of this hybrid system at a selected sea site is further assessed via the proposed aero-hydroservo coupling simulations. 展开更多
关键词 semi-submersible platform Wave Star wave energy converter hybrid system coupling simulation platform motion response absorbed power
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Information for Authors Asian Pacific Journal of Tropical Biomedcine
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《Asian Pacific Journal of Tropical Biomedicine》 2025年第11期I0002-I0002,共1页
GENERAL Asian Pacific Journal of Tropical Biomedicine is sponsored by Hainan Medical University Journal Publisher,and aims to set up an acdemic communicating platform for scientists all over the world on tropical biom... GENERAL Asian Pacific Journal of Tropical Biomedicine is sponsored by Hainan Medical University Journal Publisher,and aims to set up an acdemic communicating platform for scientists all over the world on tropical biomedicine and related sciences. 展开更多
关键词 sciences tropical biomedicine academic communicating platform acdemic communicating platform
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Non-Terrestrial Network: Architecture, Technologies and Applications
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作者 Gao Yuan Wu Gang +3 位作者 Hao Zhangcheng Zhao Nan Dusit Niyato Arumugam Nallanathan 《China Communications》 2025年第10期I0002-I0005,共4页
With the advent of the digital era,the field of communications is undergoing profound transformation.Among the most groundbreaking developments is the emergence of non-terrestrial networks(NTN),which represent not onl... With the advent of the digital era,the field of communications is undergoing profound transformation.Among the most groundbreaking developments is the emergence of non-terrestrial networks(NTN),which represent not only a technological leap forward but also a major trend shaping the future of global connectivity.As a layered heterogeneous network,NTN integrates multiple aerial platforms—including satellites,high-altitude platform systems(HAPS),and unmanned aerial systems(UAS)—to provide flexible and composable solutions aimed at achieving seamless worldwide communication coverage. 展开更多
关键词 unmanned aerial systems uas non terrestrial networks SATELLITES layered heterogeneous networkntn aerial platforms layered heterogeneous network high altitude platform systems unmanned aerial systems
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Microstructure and mechanical properties of a novel Nb–V–Ce multi-microalloyed low-alloy cast steel
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作者 Long Zhao Gan-chao Zhai +2 位作者 Jia-dong Wu Xiang-ru Chen Qi-jie Zhai 《Journal of Iron and Steel Research International》 2025年第10期3469-3482,共14页
A novel Nb–V–Ce multi-microalloyed low-alloy cast steel for offshore platform nodes was investigated to achieve the properties similar to X80 pipeline steel,including high yield strength and low-temperature impact e... A novel Nb–V–Ce multi-microalloyed low-alloy cast steel for offshore platform nodes was investigated to achieve the properties similar to X80 pipeline steel,including high yield strength and low-temperature impact energy.The experimental results demonstrate that the addition of elements such as Nb,V and Ce can markedly improve the strength of the low-alloy cast steel.Maintaining a constant level of elements such as Nb,V and Ce,while reducing the content of Si to 0.28 wt.%,leads to substantial enhancements in impact energy at−40℃,meeting the mechanical properties criteria of X80 pipeline steel.The excellent mechanical properties of the multi-microalloyed low-alloy cast steel result from the reason that the multi-addition of microalloying elements refines the grains and facilitates the formation of nanoprecipitates like NbC.Moreover,decreasing Si content can enhance the recovery of martensitic laths in cast steel during the tempering process,reducing stress from dislocation movement and improving plasticity. 展开更多
关键词 Nanoprecipitate MICROALLOYING Cast steel Offshore platform MICROSTRUCTURE
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Research on the Performance of a Mooring Platform Under the Collision of Icebergs
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作者 ZHANG Yan ZHANG Song-bao +2 位作者 WANG Yi-tao ZHAO Wei-dong GUI Hong-bin 《China Ocean Engineering》 2025年第1期43-57,共15页
In the process of developing oil and gas resources in the Arctic,the impact of icebergs can pose a considerable threat to the structural safety of semi-submersible mooring platforms in ice regions.On the basis of the ... In the process of developing oil and gas resources in the Arctic,the impact of icebergs can pose a considerable threat to the structural safety of semi-submersible mooring platforms in ice regions.On the basis of the arbitrary Lagrangian Eulerian(ALE)algorithm,a numerical model for the interaction between an iceberg and a semi-submersible mooring platform is built in this work.First,a mooring system with a link element is designed and validated.An ice material model for the target iceberg is built and validated.A numerical model for the interaction between an iceberg and a semi-submersible mooring platform is then built.A parametric study(cable angle,tension angle and number of cables)is carried out to study the performance of the mooring system.The collision process between the semi-submersible mooring platform and the iceberg in the polar marine environment can be predicted by the present numerical model,and then the optimal mooring arrangement scheme can be obtained.The research results in this work can provide a reference for the design of mooring systems. 展开更多
关键词 ALE algorithm semi-submersible platform ICEBERG COLLISION mooring system
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OGRP:A comprehensive bioinformatics platform for the efficient empowerment of Oleaceae genomics research
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作者 Zijian Yu Yu Li +13 位作者 Tengfei Song Lixia Gou Jiaqi Wang Yue Ding Zejia Xiao Jingyue Qin Hui Jiang Yan Zhang Yishan Feng Xiangming Kong Shoutong Bao Shouliang Yin Tianyu Lei Jinpeng Wang 《Horticultural Plant Journal》 2025年第3期1308-1325,共18页
As a high-value eudicot family,many famous horticultural crop genomes have been deciphered in Oleaceae.However,there are currently no bioinformatics platforms focused on empowering genome research in Oleaceae.Herein,w... As a high-value eudicot family,many famous horticultural crop genomes have been deciphered in Oleaceae.However,there are currently no bioinformatics platforms focused on empowering genome research in Oleaceae.Herein,we developed the first comprehensive Oleaceae Genome Research Platform(OGRP,https://oleaceae.cgrpoee.top/).In OGRP,70 genomes of 10 Oleaceae species and 46 eudicots and 366 transcriptomes involving 18 Oleaceae plant tissues can be obtained.We built 34 window-operated bioinformatics tools,collected 38 professional practical software programs,and proposed 3 new pipelines,namely ancient polyploidization identification,ancestral karyotype reconstruction,and gene family evolution.Employing these pipelines to reanalyze the Oleaceae genomes,we clarified the polyploidization,reconstructed the ancestral karyotypes,and explored the effects of paleogenome evolution on genes with specific biological regulatory roles.Significantly,we generated a series of comparative genomic resources focusing on the Oleaceae,comprising 108 genomic synteny dot plots,1952225 collinear gene pairs,multiple genome alignments,and imprints of paleochromosome rearrangements.Moreover,in Oleaceae genomes,researchers can efficiently search for 1785987 functional annotations,22584 orthogroups,29582 important trait genes from 74 gene families,12664 transcription factor-related genes,9178872 transposable elements,and all involved regulatory pathways.In addition,we provided downloads and usage instructions for the tools,a species encyclopedia,ecological resources,relevant literatures,and external database links.In short,ORGP integrates rich data resources and powerful analytical tools with the characteristic of continuous updating,which can efficiently empower genome research and agricultural breeding in Oleaceae and other plants. 展开更多
关键词 OLEACEAE Genome POLYPLOIDIZATION Functional genomics Bioinformatics platform
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3-Acetamido-5-acetylfuran: An emerging renewable nitrogen-containing platform compound
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作者 Jinhang Dai Qingya Cao +4 位作者 Delong Yang Gang Chen Ziting Du Song Wang Fukun Li 《Chinese Journal of Chemical Engineering》 2025年第2期263-272,共10页
In the last decade,shell biorefinery,a novel concept referring to the extraction of the main components of crustacean shells and the transformation of each component into valuable products,was proposed and has attract... In the last decade,shell biorefinery,a novel concept referring to the extraction of the main components of crustacean shells and the transformation of each component into valuable products,was proposed and has attracted increasing attentions.Chitin is one of main components of crustacean shells.Owing to the bio-fixed nitrogen element,chitin biomass has been regarded as a good candidate to produce nitrogen-containing chemicals.Among these,3-acetamido-5-acetylfuran(3A5AF)is an interesting furanic compound derived from the hydrolysis and sequential dehydration of chitin.Similar to cellulose-derived platform chemical 5-hydromethylfurfural(HMF),3A5AF is an emerging platform compound and also can be converted into various useful chemicals by oxidation,reduction,hydrolysis,substitution,and so on.This review showcases the recent advances in the synthesis of 3A5AF from chitin and N-acetyl glucosamine(NAG)employing various catalytic systems.The conversion of 3A5AF into valuable compounds was introduced then.There are still some challenges in this area,for example,the rational design of green and efficient catalytic systems for the synthesis of 3A5AF and its derivatives.The outlooks also were discussed at the end of the review. 展开更多
关键词 Biomass CHITIN Shell biorefinery Platform compound
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Integrated Sharing Platform for Genetic Data of Rare and Precious Metal Materials
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作者 Lin Huang Ying Zhou Jingjing Yang 《Computers, Materials & Continua》 2025年第12期4587-4606,共20页
The construction of centralized and standardized material databases is essential to support both scientific innovation and industrial application.However,for rare and precious metal materials,existing data resources a... The construction of centralized and standardized material databases is essential to support both scientific innovation and industrial application.However,for rare and precious metal materials,existing data resources are often decentralized.This results in persistent issues such as data silos and fragmentation,which significantly hinder efficient data utilization and collaboration.In response to these challenges,this study investigates the development of an integrated platform for sharing genetic data of rare and precious metal materials.The research begins by analyzing current trends in material data platforms,both domestically and internationally.These insights help inform the architectural design.The core of the platform consists of several key modules.Data resource integration is designed to aggregate and harmonize heterogeneous data from diverse sources.A structured data management system supports efficient storage and retrieval.A computational environment enables data analysis and modeling.A trusted sharing mechanism ensures security and access control.By integrating these functionalities,the platform aims to provide a unified ecosystem.This system facilitates open yet secure data exchange,promotes reproducibility,and enhances research efficiency.Finally,the article summarizes the initial implementation of the platform.It discusses its potential limitations and outlines future directions for development,including the integration of artificial intelligence tools and the expansion of data coverage. 展开更多
关键词 Material gene engineering DATABASE platform construction blockchain
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Double-protective strategy enabling high-efficiency production of levulinic acid from high-loading cellulose
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作者 Hang Lv Ping Hu +8 位作者 Chenyu Ge Fengyi Lu Hui Li Di Wu Zhidan Xue Yimeng Guo Xixi Liu Liangfang Zhu Changwei Hu 《Journal of Energy Chemistry》 2025年第7期577-586,共10页
Valorization of renewable cellulose into initial platform chemicals(IPCs)generally suffers from low process efficiency owing to difficult depolymerization of recalcitrant cellulose and troublesome repolymerization of ... Valorization of renewable cellulose into initial platform chemicals(IPCs)generally suffers from low process efficiency owing to difficult depolymerization of recalcitrant cellulose and troublesome repolymerization of high-reactive intermediates to undesired humins.Herein,we report a double-protective strategy for cellulose depolymerization and orientated conversion to levulinic acid(LA),one of the important IPCs,by in-situ adding protective formaldehyde(HCHO).This approach initiates from the(hemi)acetalation of hydroxyl groups in cellulose with HCHO,causing controllable depolymerization to(hemi)acetalized glucose with increased rate kinetically and a new mechanism of its catalytic conversion to LA via(hemi)acetal-driven direct C1-C2 cleavage.As such,the cellulose-to-LA conversion is protectively proceeded with the repolymerization of reactive intermediates prevented remarkably,leading to an excellent LA yield of 87.3 mol% from high-loading microcrystalline cellulose(15.0 wt% in aqueous phase)in a biphasic solvent containing 2-methyltetrahydrofuran and water.The process efficiency,expressed as space-time yield,is improved by 3.6 fold when compared with a non-protective approach.This work highlights an advance in maximizing the utilization of biomass-derived carbons for high-efficiency production of important IPCs directly from cellulose for future biorefinery. 展开更多
关键词 BIOMASS Initial platform chemicals Levulinic Acid Double-protective Strategy CELLULOSE
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