Stainless steel,known for its exceptional properties and diverse applications,conventionally requires a multistage process that generates considerable CO_(2) emissions by using fossil-based carbon reductants.This stud...Stainless steel,known for its exceptional properties and diverse applications,conventionally requires a multistage process that generates considerable CO_(2) emissions by using fossil-based carbon reductants.This study investigated hydrogen plasma smelting reduction as a novel,sustainable,and efficient method for producing stainless steel directly from lateritic nickel and chromite ores.The research aimed to examine the effect of ore proportion on AISI 300 series stainless steel production and assess the reduction process over time through thermochemical calculations and experimental studies.Results showed that increasing the proportion of chromite ore in the feed raises Cr content and reduces Ni content in metals while increasing Cr_(2)O_(3) and Al_(2)O_(3) content in oxides.A briquette comprising 30wt%chromite ore and 70wt%calcined nickel ore yields better results for AISI 300 stainless steel,with Fe,Cr,Ni,and Si content of 62.95wt%,19.37wt%,11.83wt%,and 0.72wt%,respectively,after 180 s of hydrogen plasma exposure.Nearly all NiO compounds are converted into Ni after 60 s of smelting reduction,whereas FeO compounds are almost fully converted into Fe after 120 s of smelting reduction.AISI 300 series stainless steel is successfully produced after 120 s of reduction,achieving Fe,Cr,Ni,and Si content of 64.36wt%,21.92wt%,10.08wt%,and 0.61wt%,respectively.Process optimization remains promising because the Cr_(2)O_(3) content in the slag is still relatively high at 15.52wt%.This ultrafast and direct production method holds considerable potential to transform stainless steel production by reducing environmental impact and enhancing process efficiency.Specifically,the method eliminates the use of an argon oxygen decarburization converter and vacuum oxygen decarburization in stainless steelmaking.展开更多
The solitary waves of a viscous plasma confined in a cuboid under the three types of boundary condition are theoretically investigated in the present paper.By introducing a threedimensional rectangular geometry and em...The solitary waves of a viscous plasma confined in a cuboid under the three types of boundary condition are theoretically investigated in the present paper.By introducing a threedimensional rectangular geometry and employing the reductive perturbation theory,a quasi-Kd V equation is derived in the viscous plasma and a damping solitary wave is obtained.It is found that the damping rate increases as the viscosity coefficient increases,or increases as the length and width of the rectangle decrease,for all kinds of boundary condition.Nevertheless,the magnitude of the damping rate is dominated by the types of boundary condition.We thus observe the existence of a damping solitary wave from the fact that its amplitude disappears rapidly for a → 0and b → 0,or ν→ ＋∞.展开更多
A rigorous investigation is presented on the propagation characteristics of non-linear dust acoustic（DA）waves in an unmagnetized dusty plasma system containing non-thermal and vortex-like ions and Maxwellian electro...A rigorous investigation is presented on the propagation characteristics of non-linear dust acoustic（DA）waves in an unmagnetized dusty plasma system containing non-thermal and vortex-like ions and Maxwellian electrons under the effect of a fluctuating charged dust fluid.The three-dimensional（3D）Burgers＇equation and a new form of a lower degree modified 3D Burgers＇equation with their analytical solutions are derived to study the features of shock waves in such plasmas.The effect of the population of non-thermal ions,the vortex-like ion parameter as well as the temperature ratios of ions and electrons on the evolution of shock waves in the presence of dust charge fluctuation is presented.This theoretical investigation might be effectively utilized to unveil the nature of many astrophysical plasma environments（Saturn＇s spokes etc.）where such plasmas are reported to have existed.展开更多
The reduction process of ilmenite by hydrogen and methane under MPCVD was analyzed by XRD result. The reduction degree of ilmenite increased with adding methane, the case similar to reduction rate. The mechanism of re...The reduction process of ilmenite by hydrogen and methane under MPCVD was analyzed by XRD result. The reduction degree of ilmenite increased with adding methane, the case similar to reduction rate. The mechanism of reduction process changed with the increasement of methane flow because of the formation of carbon nanotubes （CNTs）. The morphology of reduced samples was observed by SEM, and it was found that CNTs played an important role in the fracture of ilmenite particles. The reduction kinetics showed that the reduction was rate-controlling for hydrogen, and diffusion-controlling when hydrogen mixed with high flow methane.展开更多
文摘Stainless steel,known for its exceptional properties and diverse applications,conventionally requires a multistage process that generates considerable CO_(2) emissions by using fossil-based carbon reductants.This study investigated hydrogen plasma smelting reduction as a novel,sustainable,and efficient method for producing stainless steel directly from lateritic nickel and chromite ores.The research aimed to examine the effect of ore proportion on AISI 300 series stainless steel production and assess the reduction process over time through thermochemical calculations and experimental studies.Results showed that increasing the proportion of chromite ore in the feed raises Cr content and reduces Ni content in metals while increasing Cr_(2)O_(3) and Al_(2)O_(3) content in oxides.A briquette comprising 30wt%chromite ore and 70wt%calcined nickel ore yields better results for AISI 300 stainless steel,with Fe,Cr,Ni,and Si content of 62.95wt%,19.37wt%,11.83wt%,and 0.72wt%,respectively,after 180 s of hydrogen plasma exposure.Nearly all NiO compounds are converted into Ni after 60 s of smelting reduction,whereas FeO compounds are almost fully converted into Fe after 120 s of smelting reduction.AISI 300 series stainless steel is successfully produced after 120 s of reduction,achieving Fe,Cr,Ni,and Si content of 64.36wt%,21.92wt%,10.08wt%,and 0.61wt%,respectively.Process optimization remains promising because the Cr_(2)O_(3) content in the slag is still relatively high at 15.52wt%.This ultrafast and direct production method holds considerable potential to transform stainless steel production by reducing environmental impact and enhancing process efficiency.Specifically,the method eliminates the use of an argon oxygen decarburization converter and vacuum oxygen decarburization in stainless steelmaking.
基金supported by National Natural Science Foundation of China(Nos.91026005,11275156,11047010,61162017)
文摘The solitary waves of a viscous plasma confined in a cuboid under the three types of boundary condition are theoretically investigated in the present paper.By introducing a threedimensional rectangular geometry and employing the reductive perturbation theory,a quasi-Kd V equation is derived in the viscous plasma and a damping solitary wave is obtained.It is found that the damping rate increases as the viscosity coefficient increases,or increases as the length and width of the rectangle decrease,for all kinds of boundary condition.Nevertheless,the magnitude of the damping rate is dominated by the types of boundary condition.We thus observe the existence of a damping solitary wave from the fact that its amplitude disappears rapidly for a → 0and b → 0,or ν→ ＋∞.
文摘A rigorous investigation is presented on the propagation characteristics of non-linear dust acoustic（DA）waves in an unmagnetized dusty plasma system containing non-thermal and vortex-like ions and Maxwellian electrons under the effect of a fluctuating charged dust fluid.The three-dimensional（3D）Burgers＇equation and a new form of a lower degree modified 3D Burgers＇equation with their analytical solutions are derived to study the features of shock waves in such plasmas.The effect of the population of non-thermal ions,the vortex-like ion parameter as well as the temperature ratios of ions and electrons on the evolution of shock waves in the presence of dust charge fluctuation is presented.This theoretical investigation might be effectively utilized to unveil the nature of many astrophysical plasma environments（Saturn＇s spokes etc.）where such plasmas are reported to have existed.
基金National Natural Science Foundation of China(No.51072140)the Program for Excellent Youth Team and the Scientific Research Foundation of the Higher Education Commission of Hubei Province of China(Nos.Z200715001 and T201004)the Program for Excellent Subject Leader of Wuhan(No.201150530151)
文摘The reduction process of ilmenite by hydrogen and methane under MPCVD was analyzed by XRD result. The reduction degree of ilmenite increased with adding methane, the case similar to reduction rate. The mechanism of reduction process changed with the increasement of methane flow because of the formation of carbon nanotubes （CNTs）. The morphology of reduced samples was observed by SEM, and it was found that CNTs played an important role in the fracture of ilmenite particles. The reduction kinetics showed that the reduction was rate-controlling for hydrogen, and diffusion-controlling when hydrogen mixed with high flow methane.
