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Modeling Walking with an Inverted Pendulum Not Constrained to the Sagittal Plane. Numerical Simulations and Asymptotic Expansions
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作者 Guillermo H. Goldsztein 《Applied Mathematics》 2017年第1期57-76,共20页
Inverted pendulum models are commonly used to study the bio-mechanics of biped walkers. In its simplest form, the inverted pendulum consists of a point mass attached to two straight mass-less legs. Most works constrai... Inverted pendulum models are commonly used to study the bio-mechanics of biped walkers. In its simplest form, the inverted pendulum consists of a point mass attached to two straight mass-less legs. Most works constrain the motion of the mass to the sagittal plane, i.e. the plane perpendicular to the ground that contains the direction toward the biped is walking. In this article, we remove this constrain to study the oscillations, the mass experiences in the direction perpendicular to the sagittal plane as the biped walks. While small, these lateral oscillations are unavoidable and of importance in the understanding of balance and stability of walkers, as well as walkers induced oscillations in pedestrian bridges. 展开更多
关键词 Mathematical MODELING INVERTED PENDULUM Mechanics of WALKING SAGITTAL plane OSCILLATIONS
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Studies of directed flow with event plane method in the HIRFL-CSR external-target experiment
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作者 Wan-Long Wu Xiong-Hong He +3 位作者 Yan-Yu Ren Di-Yu Shen Shu-Su Shi Xu Sun 《Nuclear Science and Techniques》 2026年第4期19-27,共9页
The Cooling-Storage-Ring External-target Experiment(CEE)at the Heavy Ion Research Facility in Lanzhou(HIRFL)is designed to study the properties of nuclear matter created in heavy-ion collisions at beam energies from a... The Cooling-Storage-Ring External-target Experiment(CEE)at the Heavy Ion Research Facility in Lanzhou(HIRFL)is designed to study the properties of nuclear matter created in heavy-ion collisions at beam energies from a few hundred MeV/u up to 1 GeV/u.It aims to facilitate research on the quantum chromodynamics(QCD)phase structure in the high-baryondensity region.Collective flow is a fundamental observable in heavy-ion collision experiments,providing information on the bulk properties of the produced matter.Although the standard event plane method has been widely used to measure collective flow,it is still important to validate and optimize this method for the CEE spectrometer.In this paper,we study the experimental procedures for measuring directed flow in^(238)U+^(238)U collisions at 500 MeV/u,using event planes reconstructed by Multi-Wire Drift Chamber and Zero Degree Calorimeter,respectively.Jet AA Microscopic(JAM)transport generator is used to generate events,and the detector response is simulated by the CEE Fast Simulation(CFS)package.Finally,the optimal kinematic region for proton directed flow measurements is discussed for the future CEE experiment. 展开更多
关键词 Heavy-ion collisions CEE Directed flow Event plane
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Coronal plane alignment of the knee phenotypes and ankle joint coronal plane alignment patterns in Egyptian population
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作者 Ahmed A Khalifa Mohamed Moustafa +3 位作者 Shikuria Lemma Mostafa Fayez Ahmed M Abdelaal Amr A Fadle 《World Journal of Orthopedics》 2026年第1期67-80,共14页
BACKGROUND In an era leaning toward a personalized alignment of total knee arthroplasty,coronal plane alignment of the knee(CPAK)phenotypes for each population are studied;furthermore,other possible variables affectin... BACKGROUND In an era leaning toward a personalized alignment of total knee arthroplasty,coronal plane alignment of the knee(CPAK)phenotypes for each population are studied;furthermore,other possible variables affecting the alignment,such as ankle joint alignment,should be considered.AIM To determine CPAK distribution in the North African(Egyptian)population with knee osteoarthritis and to assess ankle joint line orientation(AJLO)adaptations across different CPAK types.METHODS A cross-sectional study was conducted on patients with primary knee osteoarthritis and normal ankle joints.Radiographic parameters included the mechanical lateral distal femoral angle,medial proximal tibial angle,and the derived calculations of joint line obliquity(JLO)and arithmetic hip-knee-ankle angle(aHKA).The tibial plafond horizontal angle(TPHA)was used for AJLO assessment,where 0°is neutral(type N),<0°is varus(type A),and>0°is valgus(type B).The nine CPAK types were further divided into 27 subtypes after incorporating the three AJLO types.RESULTS A total of 527 patients(1054 knees)were included for CPAK classification,and 435 patients(870 knees and ankles)for AJLO assessment.The mean age was 57.2±7.8 years,with 79.5%females.Most knees(76.4%)demonstrated varus alignment(mean aHKA was-5.51°±4.84°)and apex distal JLO(55.3%)(mean JLO was 176.43°±4.53°).CPAK types I(44.3%),IV(28.6%),and II(10%)were the most common.Regarding AJLO,70.2%of ankles exhibited varus orientation(mean TPHA was-5.21°±6.45°).The most frequent combined subtypes were CPAK type I-A(33.7%),IV-A(21.5%),and I-N(6.9%).A significant positive correlation was found between the TPHA and aHKA(r=0.40,P<0.001).CONCLUSION In this North African cohort,varus knee alignment with apex distal JLO and varus AJLO predominated.CPAK types I,IV,and II were the most common types,while subtypes I-A,IV-A,and I-N were commonly occurring after incorporating AJLO types;furthermore,the AJLO was significantly correlated to aHKA. 展开更多
关键词 Coronal plane alignment of the knee classification Coronal alignment Ankle joint alignment Knee arthroplasty Knee replacement North African population
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True triaxial unloading test on the mechanical behaviors of sandstone:Effects of the intermediate principal stress and structural plane 被引量:1
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作者 Fan Feng Zhiwei Xie +3 位作者 Shaojie Chen Diyuan Li Siyu Peng Tong Zhang 《Journal of Rock Mechanics and Geotechnical Engineering》 2025年第4期2208-2226,共19页
A series of true triaxial unloading tests are conducted on sandstone specimens with a single structural plane to investigate their mechanical behaviors and failure characteristics under different in situ stress states... A series of true triaxial unloading tests are conducted on sandstone specimens with a single structural plane to investigate their mechanical behaviors and failure characteristics under different in situ stress states.The experimental results indicate that the dip angle of structural plane(θ)and the intermediate principal stress(σ2)have an important influence on the peak strength,cracking mode,and rockburst severity.The peak strength exhibits a first increase and then decrease as a function ofσ2 for a constantθ.However,whenσ2 is constant,the maximum peak strength is obtained atθof 90°,and the minimum peak strength is obtained atθof 30°or 45°.For the case of an inclined structural plane,the crack type at the tips of structural plane transforms from a mix of wing and anti-wing cracks to wing cracks with an increase inσ2,while the crack type around the tips of structural plane is always anti-wing cracks for the vertical structural plane,accompanied by a series of tensile cracks besides.The specimens with structural plane do not undergo slabbing failure regardless ofθ,and always exhibit composite tensile-shear failure whatever theσ2 value is.With an increase inσ2 andθ,the intensity of the rockburst is consistent with the tendency of the peak strength.By analyzing the relationship between the cohesion(c),internal friction angle(φ),andθin sandstone specimens,we incorporateθinto the true triaxial unloading strength criterion,and propose a modified linear Mogi-Coulomb criterion.Moreover,the crack propagation mechanism at the tips of structural plane,and closure degree of the structural plane under true triaxial unloading conditions are also discussed and summarized.This study provides theoretical guidance for stability assessment of surrounding rocks containing geological structures in deep complex stress environments. 展开更多
关键词 True triaxial unloading Dip angle of structural plane Intermediate principal stress Mechanical behaviors Cracking modes Failure criterion
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Uniformly dispersed zinc-copper alloy as anode preferentially deposited along Zn(002) plane for aqueous zinc ion batteries 被引量:1
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作者 Jing Zhu Longkun Wu +9 位作者 Zhi Peng Shuo Li Xudong Li Zekun Zhang Ningning Zhao Bin Li Wei Meng Ling Wang Lei Dai Zhangxing He 《Rare Metals》 2025年第9期6092-6101,共10页
Aqueous zinc ion batteries(AZIBs)have attracted widespread attention due to their unique advantages.However,the growth of dendrites on the anode and the occurrence of side reactions limits the improvement of electroch... Aqueous zinc ion batteries(AZIBs)have attracted widespread attention due to their unique advantages.However,the growth of dendrites on the anode and the occurrence of side reactions limits the improvement of electrochemical performance of AZIBs.The alloying of zinc anode effectively alleviates above problems,which is beneficial to the long-term cycle performance of AZIBs.In this study,zinc-copper alloy anode(Cu@Zn)was synthesized by melting method.The method is not only simple and easy to operate,but also can make the synthesized anode Cu element uniform distribution and improve the corrosion resistance of the anode.At the same time,the Cu@Zn surface reconstructed has a large proportion of Zn(002)crystal surface exposure,with the zinc affinity of Cu.Both of them can induce the uniform deposition of Zn2+ions along the Zn(002)crystal plane,further inhibiting the growth of dendrite.The Cu@Zn//Cu@Zn symmetrical batteries can cycle more than 1000 times at current densities of 0.3 and 1.2 mA cm^(-2),and maintain a relatively low hysteresis voltage.And the discharge capacity retention rate of Cu@Zn//MnO_(2)maintains 84.64%at 2.0 A g^(-1)after 1000 cycles.This study provides a new methodological reference for the development of advanced AZIBs anodes. 展开更多
关键词 Deformationqueous zinc ion batteries Zinc-copper alloy MELTING Zn(002)crystal plane
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Engineering crystal plane of NiCo_(2)O_(4)to regulate oxygen vacancies and acid sites for alkali-free oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid 被引量:1
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作者 Hengli Qian keyuan Zhang +8 位作者 Yongchuo He Qidong Hou Chao Xie Ruite Lai Guanjie Yu Tianliang Xia Xinyu Bai Haijiao Xie Meiting Ju 《Green Energy & Environment》 2025年第4期756-765,共10页
The catalytic oxidation of HMF involves a cascading reaction with multiple intermediate products,making it crucial to enhance the oriented adsorption capacity of specific functional groups for accelerating the entire ... The catalytic oxidation of HMF involves a cascading reaction with multiple intermediate products,making it crucial to enhance the oriented adsorption capacity of specific functional groups for accelerating the entire process.To achieve the efficient selective oxidation of HMF to FDCA,a series of NiCo_(2)O_(4)catalysts with different morphologies,such as flaky,echinoids,pompon and corolla,were prepared and characterized by XRD,SEM,TEM,BET,XPS,and FTIR.Among the four catalysts,flaky NiCo_(2)O_(4)exhibited the most excellent catalytic activity and stability,with a FDCA yield of 60.1%within 12 h at 80℃without alkali participation.The excellent performance of flaky NiCo_(2)O_(4)catalyst is attributed to the oxygen vacancies and acid sites generated by the exposed(400)facets.The oxygen vacancies and acid sites on the catalyst surface can precisely adsorb-CHO and-CH_(2)-OH of HMF,respectively,and this synergistic effect promotes the efficient production of FDCA.This work is of great significance for fundamentally study the effect of micro-topography or crystal-plane reaction properties on surfaces. 展开更多
关键词 5-HYDROXYMETHYLFURFURAL 2 5-furandicarboxylic acid NiCo_(2)O_(4) Catalytic oxidation Crystal plane
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Determination of Fracture Plane Orientation Using the Variance Method under Multiaxial Loading
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作者 Mbaiyelkom Esdras Ngargueudedjim Kimtangar +2 位作者 Bianzeube Tikri Kenmeugne Bienvenu Fogue Médard 《Open Journal of Applied Sciences》 2025年第2期411-424,共14页
The prediction of the fracture plane orientation in fatigue is a scientific topic and remains relevant for every type of material. However, in this work, we compared the orientation of the fracture plane obtained expe... The prediction of the fracture plane orientation in fatigue is a scientific topic and remains relevant for every type of material. However, in this work, we compared the orientation of the fracture plane obtained experimentally through tests on specimens under multiaxial loading with that calculated by the variance method. In the statistical approach criteria, several methods have been developed but we have presented only one method, namely the variance method using the equivalent stress. She assumes that the fracture plane orientation is the one on which the variance of the equivalent stress is maximum. Three types of equivalent stress are defined for this method [1]: normal stress, shear stress and combined normal and shear stress. The results obtained were compared with experimental results for multiaxial cyclic stress states, and it emerges that the variance method for the case of combined loading is conservative as it gives a better prediction of the fracture plane. 展开更多
关键词 Biaxial Fatigue Fracture plane Orientation Critical Fracture plane Variance Method Fatigue Criteria
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基于PowerMILL PostProcessor的海德汉iTNC530系统PLANE指令后置处理研究
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作者 康晓崇 《机械研究与应用》 2025年第5期102-107,共6页
后置处理在计算机辅助制造(CAM)与数控加工之间起到关键的桥梁作用,其性能直接影响加工精度和效率。该文基于PowerMILL后处理编辑器开发了一个针对海德汉iTNC530系统的后处理器,旨在实现PLANE指令的自动生成,以适应复杂的多轴加工任务... 后置处理在计算机辅助制造(CAM)与数控加工之间起到关键的桥梁作用,其性能直接影响加工精度和效率。该文基于PowerMILL后处理编辑器开发了一个针对海德汉iTNC530系统的后处理器,旨在实现PLANE指令的自动生成,以适应复杂的多轴加工任务。文章详细描述了开发流程,包括刀具方向向量的提取、旋转角度的计算以及PLANE指令的生成,并结合具体案例展示了如何应用数学模型与旋转矩阵进行刀具路径的优化控制。仿真验证结果表明,所开发的后置处理器能够生成高精度的数控程序,提高了加工的自动化程度和稳定性,可以为多轴加工中的后置处理开发提供实践指导和技术参考。 展开更多
关键词 后置处理开发 海德汉iTNC530 plane指令 数学模型
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Plane Protection Enabling(002)Oriented Plating and Stripping Processes for Aqueous Zn-Ion Batteries
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作者 Mengxuan Zhou Zhihong Luo +9 位作者 Jianwei Lu Tingting Xu Xiangqun Zhuge Dingren Zhou Laijun Liu Yibing Li Kun Luo Xinyu Li Weiwei Lei Dan Liu 《Energy & Environmental Materials》 2025年第6期112-121,共10页
Uniform deposition is a promising strategy to inhibit dendrite growth and corrosion of the Zn anode in cost-effective energy storage systems:aqueous Zn-ion batteries(AZIBs).Herein,we report a regulating Zn^(2+)ions di... Uniform deposition is a promising strategy to inhibit dendrite growth and corrosion of the Zn anode in cost-effective energy storage systems:aqueous Zn-ion batteries(AZIBs).Herein,we report a regulating Zn^(2+)ions dissolution/deposition method for achieving a highly reversible Zn anode.11-mercaptoundecanoic acid(MUA)as ligands was utilized to protect the(002)plane,benefiting from the strong affinity between the thiol group and Zn,with MUA anchoring in the form of Zn-S-RCOOH,which contributes to a stable interface for uniform deposition/deposition. 展开更多
关键词 (002) deposition DISSOLUTION plane protection Zn anode
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Effect of dexmedetomidine-ropivacaine transversus abdominis plane block on analgesia and cognitive impairment risk in colorectal cancer surgery
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作者 Xing Zhang Guang-Rong Xiang +2 位作者 Zhi-Xin Wang Ming-Qing Peng Min Li 《World Journal of Gastrointestinal Surgery》 2025年第6期317-324,共8页
BACKGROUND The dexmedetomidine(DEX)plus ropivacaine treatment enables a transversus abdominis plane block(TAPB)of the peripheral nerves in patients undergoing radical resection for colorectal cancer(CRC)that can provi... BACKGROUND The dexmedetomidine(DEX)plus ropivacaine treatment enables a transversus abdominis plane block(TAPB)of the peripheral nerves in patients undergoing radical resection for colorectal cancer(CRC)that can provide clinical data for improving the postoperative analgesic effect,reducing the risk of cognitive impairment,and decreasing the circulating levels of serum inflammatory factors and stress hormones.AIM To assess the impact of DEX plus ropivacaine-enabled TAPB on pain,postoperative cognitive dysfunction(POCD),and inflammatory/stress factors.METHODS Our patient cohort was randomly divided into control and observation groups(60/group).The observation group used a DEX plus ropivacaine-enabled TAPB,while the control group employed a ropivacaine-enabled TAPB.The pain score[Visual Analogy Scale(VAS),Montreal Cognitive Assessment(MoCA)],serum inflammatory factor level(C-reactive protein,interleukin-6 and tumor necrosis factor-α),serum stress hormone levels(cortisol and adrenaline)and postoperative adverse reactions were compared between the two groups.RESULTS The observation group VAS scores were lower than those of the control group(better analgesic effect,P<0.05).The MoCA and POCD scores decreased post-surgery in the observation group(P<0.05).In the elderly,the overall VAS and MoCA scores were significantly reduced compared with the young group.The C-reactive protein,interleukin-6,tumor necrosis factor-α,cortisol and adrenaline levels were lower in the observation group compared with the control group post-surgery(P<0.05).There was no significant difference in adverse reactions between the two groups post-surgery,but the incidence of adverse reactions in the observation group was still lower.DEX continuously inhibited p65-phosphorylation levels in the nuclear factorκB pathway at multiple time points,and its inhibitory effect became more significant over time.CONCLUSION DEX plus ropivacaine-enabled TAPB reduces POCD and inflammatory/stress hormone levels,and significantly improves the postoperative analgesic effect of patients undergoing radical resection for colorectal cancer. 展开更多
关键词 Radical resection Colorectal cancer DEXMEDETOMIDINE ROPIVACAINE Transversus abdominis plane block
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STABILITY OF THE ISOPERIMETRIC INEQUALITY IN HYPERBOLIC PLANE
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作者 Haizhong LI Yao WAN 《Acta Mathematica Scientia》 2025年第1期215-227,共13页
In this paper,we establish a stability estimate for the isoperimetric inequality of horospherically convex domains in hyperbolic plane.This estimate involves a relationship between the Hausdorff distance to a geodesic... In this paper,we establish a stability estimate for the isoperimetric inequality of horospherically convex domains in hyperbolic plane.This estimate involves a relationship between the Hausdorff distance to a geodesic ball and the deficit in the isoperimetric inequality,where the coefficient of the deficit is a universal constant. 展开更多
关键词 STABILITY isoperimetric inequality hyperbolic plane Hausdorff distance
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Strength and failure characteristics of hard rock containing a single structural plane under varied loading angles : A true triaxial investigation
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作者 XU Huai-sheng LI Shao-jun +3 位作者 XU Ding-ping LIU Xu-feng FENG Guang-liang WANG Zhao-feng 《Journal of Central South University》 2025年第5期1903-1921,共19页
The spatial relationship between structural planes and principal stresses significantly affects the mechanical properties of deep hard rock.This paper examines the effect of the loading angle under true triaxial compr... The spatial relationship between structural planes and principal stresses significantly affects the mechanical properties of deep hard rock.This paper examines the effect of the loading angle under true triaxial compression.While previous studies focused on the angleβbetween the maximum principal stress and the structural plane,the role of angleω,between the intermediate principal stress and the structural plane,is often overlooked.Utilizing artificially prefabricated granite specimens with a single non-penetrating structural plane,we set the loading angleβto range from 0°to 90°across seven groups,and assignedωvalues of 0°and 90°in two separate groups.The results show that the peak strength is negatively correlated withβup to 45°,beyond which it tends to stabilize.The angleωexerts a strengthening effect on the peak strength.Deformation mainly occurs post-peak,with the strain values ε_(1) and ε_(3) reaching levels 2−3 times higher than those in intact rock.The structural plane significantly influences failure mode whenω=0°,while failure localizes near the σ_(3) surface of the specimens whenω=90°.The findings enhance data on structural plane rocks under triaxial compression and inform theoretical research,excavation,and support design of rock structures. 展开更多
关键词 true triaxial compression hard rock structural plane loading angle STRENGTH failure characteristics
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Breast augmentation complications with three planes of implant placements
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作者 Haibo Zhao Nienwei Liu +1 位作者 Zeren Shen Jinghong Xu 《Chinese Journal of Plastic and Reconstructive Surgery》 2025年第1期45-48,共4页
Breast augmentation with implants is a popular cosmetic surgery that enhances breast volume and contour through various placement planes.In this review,we examine the impact of subglandular,subpectoral,and subfascial ... Breast augmentation with implants is a popular cosmetic surgery that enhances breast volume and contour through various placement planes.In this review,we examine the impact of subglandular,subpectoral,and subfascial implant planes on postoperative outcomes and complication rates.Subglandular placement offers simplicity but is associated with higher risks of capsular contracture,hematoma,and rippling in patients with low tissue coverage.The subpectoral plane,widely adopted for its natural appearance and reduced capsular contracture risk,may cause dynamic deformity due to muscle contraction.Although technically challenging,the subfascial plane combines the benefits of soft tissue support and reduced implant displacement.We highlight the importance of choosing an optimal implant plane tailored to each patient’s anatomical and aesthetic needs to enhance surgical outcomes and minimize complications.Further research is needed to validate long-term efficacy,particularly for subfascial placement. 展开更多
关键词 Breast augmentation Implant placement planes Capsular contracture Postoperative complications
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Lithospheric plane strain deformation due to tensile faulting
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作者 Nirmal Soni Sunita Rani Neeru Bala 《Earthquake Engineering and Engineering Vibration》 2025年第2期301-309,I0029-I0032,共13页
A solution for the lithospheric deformation of a uniform,elastically isotropic layer(EIL)of uniform thickness welded with a uniform,elastically orthotropic half-space(EOHS)due to a vertical tensile line fault(VTLF)wit... A solution for the lithospheric deformation of a uniform,elastically isotropic layer(EIL)of uniform thickness welded with a uniform,elastically orthotropic half-space(EOHS)due to a vertical tensile line fault(VTLF)with an opening in the horizontal direction located in the isotropic layer is derived in the integral form by employing Airy’s stress function approach for the plane strain case.The linear combination of exponential terms appearing in the denominator of the integral expressions of the deformation field of the EIL is expressed as a finite sum of exponential terms(FSET)by applying the method of least squares to analytically compute the deformation field.The displacement field is discussed in detail and computed numerically by considering the EOHS as olivine or barytes material or considering half-space to be isotropic. 展开更多
关键词 plane strain deformation isotropic layer orthotropic half-space vertical tensile fault horizontal dislocation
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Prediction of Daily Global Solar Radiation on a Horizontal Plane Using Adaptive Neuro-Fuzzy Inference System(ANFIS)
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作者 Hamatti Mohamed Benchrifa Mohammed +4 位作者 Mohamed Elouardi Mouhsine Hadine Mabrouki Jamal El-Baz Morad Tadili Rachid 《Journal of Environmental & Earth Sciences》 2025年第1期527-539,共13页
In recent years,the world has seen an exponential increase in energy demand,prompting scientists to look for innovative ways to exploit the power sun’s power.Solar energy technologies use the sun’s energy and light ... In recent years,the world has seen an exponential increase in energy demand,prompting scientists to look for innovative ways to exploit the power sun’s power.Solar energy technologies use the sun’s energy and light to provide heating,lighting,hot water,electricity and even cooling for homes,businesses,and industries.Therefore,ground-level solar radiation data is important for these applications.Thus,our work aims to use a mathematical modeling tool to predict solar irradiation.For this purpose,we are interested in the application of the Adaptive Neuro Fuzzy Inference System.Through this type of artificial neural system,10 models were developed,based on meteorological data such as the Day number(Nj),Ambient temperature(T),Relative Humidity(Hr),Wind speed(WS),Wind direction(WD),Declination(δ),Irradiation outside the atmosphere(Goh),Maximum temperature(Tmax),Minimum temperature(Tmin).These models have been tested by different static indicators to choose the most suitable one for the estimation of the daily global solar radiation.This study led us to choose the M8 model,which takes Nj,T,Hr,δ,Ws,Wd,G0,and S0 as input variables because it presents the best performance either in the learning phase(R^(2)=0.981,RMSE=0.107 kW/m^(2),MAE=0.089 kW/m2)or in the validation phase(R^(2)=0.979,RMSE=0.117 kW/m^(2),MAE=0.101 kW/m^(2)). 展开更多
关键词 Solar Radiation Adaptive Neuro-Fuzzy Inference System Prediction Horizontal plane Mathematical Modelling
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Revealing electronic state evolution of Co(Ⅱ)/Co(Ⅲ) in CoO(111) plane during OER process through magnetic measurement
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作者 Yanjie Li Chaoqun Qu +5 位作者 Siqi Meng Jiaqi Hu Ze Gao Hongji Xu Rui Gao Ming Feng 《Chinese Chemical Letters》 2025年第3期532-537,共6页
Oxygen evolution reaction(OER) is one of the most important half-reactions related to metal-air batteries,fuel cells, and water-splitting. Due to the sluggish kinetic and multi-electron transfer, catalysts appear to b... Oxygen evolution reaction(OER) is one of the most important half-reactions related to metal-air batteries,fuel cells, and water-splitting. Due to the sluggish kinetic and multi-electron transfer, catalysts appear to be particularly important for the OER. Knowing the reaction mechanism is fundamental to developing new catalysts and improving OER efficiency. In this work, phase transition and atomic reconstruction on Co O(111) plane were revealed through ex-situ diffraction methods and X-ray absorption spectroscopy.At the same time, the electronic state evolution of Co(Ⅱ)/Co(Ⅲ) during the OER process has also been concluded by analyzing the magnetic properties. This work shows that during the OER process, Co(Ⅲ)experiences surface electron rearrangement from IS(intermediate-spin state) to LS(low-spin state) and then returns to IS/HS(high-spin state) under high voltage region. This work provides a new view to reveal the reaction mechanism through the magnetic property and it can be extended to more magnetic 3d transition metals for future catalyst design. 展开更多
关键词 Oxygen evolution reaction Cobalt oxide Crystal plane Electron spin state X-ray absorption spectrum
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Salt Weathering in Anisotropic Calcarenite:Bedding-plane Controls on Sodium Chloride Precipitation Patterns
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作者 Mohammed Hraita Abdelaali Rahmouni +1 位作者 Aziz Zaroual Yves Géraud 《Journal of Building Material Science》 2025年第4期1-15,共15页
This study investigates the impact of bedding plane orientation on sodium chloride(NaCl)precipitation in a calcarenite stone,subjected to salt weathering cycles.It involves conducting wetting-drying cycles using sodiu... This study investigates the impact of bedding plane orientation on sodium chloride(NaCl)precipitation in a calcarenite stone,subjected to salt weathering cycles.It involves conducting wetting-drying cycles using sodium chloride on two series of specimens sampled parallel and perpendicular to the bedding plane.Capillary imbibition was carried out using saline solutions of two concentrations(15 g/L and 45 g/L).SEM observations show that,across all contaminated samples,halite precipitates mainly on the surface,in the form of efflorescence,while subflorescence remains negligible.The analysis identifies two distinct halite morphologies:(i)cubic crystals of 2 to 10μm at grain boundaries and(ii)xenomorphic aggregates on pore walls,reflecting that the size and morphology of halite crystals vary according to local nucleation conditions,influenced by the mineralogical composition of the substrates and the degree of supersaturation reached during the cycles.X-ray diffraction analysis revealed significantly higher halite precipitation in samples oriented perpendicular to the sediment bedding(4.53–5.22%)than in those oriented parallel(2.71–4.17%),indicating that bedding plane orientation is a determining factor in weathering processes and the evolution of petrophysical properties.These results demonstrate that capillary transport is intrinsically anisotropic in calcarenite,with bedding orientation controlling both the amount of precipitated salt and the location of crystallizations.This study thus establishes a solid mechanistic framework for predicting salt weathering patterns in stratified heritage stones,and offers concrete perspectives for optimizing conservation strategies in coastal environments. 展开更多
关键词 Calcarenite Stone of Rabat Historical Monuments Porous Media Bedding plane Sodium Chloride Crystallization XRD SEM Porosity
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Hydrated eutectic electrolyte enabling stable low-temperature zinc metal batteries with a tuned inner Helmholtz plane and a solid electrolyte interface
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作者 Minghui Zhang Derong Wang +6 位作者 Sibo Wang Shiyue Gao Ye Chen Qi Yang Xiaoqi Sun Yanfeng Dong Jieshan Qiu 《Journal of Energy Chemistry》 2025年第12期711-718,I0016,共9页
Aqueous zinc metal batteries(ZMBs)are promising for grid-scale energy storage,but their practical application is hindered by limited cycling life and inferior low-temperature performance,primarily due to Zn dendrite g... Aqueous zinc metal batteries(ZMBs)are promising for grid-scale energy storage,but their practical application is hindered by limited cycling life and inferior low-temperature performance,primarily due to Zn dendrite growth and parasitic reactions at the electrolyte-electrode interface.To address these challenges,we develop a new and cheap hydrated eutectic electrolyte(HEE)composed of ZnCl_(2),choline chloride(ChCl),and H_(2)O,which can fundamentally tune desirable interface chemistries for dendrite-free and low-temperature ZMBs.The optimized HEE with a solvation structure of ZnCl_(3)(ChCl)(H_(2)O)_(2) shows a high co nductivity of 15.98 mS cm^(-1)and excellent freeze resistance below-40℃.It has been found that hydrogen bonding between ChCl and H_(2)O effectively reduces water activity,while preferential adsorption of ChCl molecules at the inner Helmholtz plane promotes the formation of a protective solid electrolyte interphase(SEI)on Zn metal anodes,which greatly suppresses the dendrites and side reactions.Therefore,the HEE endows the as-fabricated Zn//Zn symmetric cells and Zn//polyaniline full batteries with superior electrochemical performance at-40℃,such as a long cycling life of 870 h at 1 mA cm^(-2)and 1 mAh cm^(-2)and a high capacity of 75 mAh g^(-1)at 0.3 A g^(-1).The HEE reported here may pave a new way to construct high-performance ZMBs for specific low-temperature application scenarios. 展开更多
关键词 Zinc metal batteries Hydrated eutectic electrolytes Solid electrolyte interface Inner Helmholtz plane Low-temperature performance
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Ultrasound-guided erector spinae plane block for perioperative analgesia in laparoscopic nephrectomy:A systematic review and meta-analysis
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作者 Suhaina Amir Abdul Hannan Siddiqui +11 位作者 Muhammad Haris Fatima Laique Bushra Amini Mariam Mehboob Mubashir Mohiuddin Muhammad Mazhar Azam Sameen Mukhtar Zainab Akram Bibi Zainab Sahar Rizwan Abdul Moeed Salim Surani 《World Journal of Nephrology》 2025年第4期293-304,共12页
BACKGROUND Laparoscopic nephrectomy is a preferred surgical approach due to its minimally invasive nature and faster recovery times.However,effective management of postoperative pain remains a significant challenge.Se... BACKGROUND Laparoscopic nephrectomy is a preferred surgical approach due to its minimally invasive nature and faster recovery times.However,effective management of postoperative pain remains a significant challenge.Several traditional methods,including opioid-based analgesia,are commonly used but are associated with side effects such as nausea,vomiting,sedation,and delayed recovery.In recent years,the erector spinae plane block(ESPB)has gained attention as an ultrasoundguided regional anesthesia technique offering promising results in various surgical procedures by reducing opioid requirements and enhancing patient comfort.AIM To evaluate the efficacy and safety of ESPB in comparison to conventional pain management strategies in patients undergoing laparoscopic nephrectomy.METHODS Following PRISMA guidelines,we searched PubMed,EMBASE,Web of Science,and the Cochrane Register for randomized controlled trials(RCTs)comparing ESPB with control for laparoscopic nephrectomy.The Cochrane Risk of Bias tool was employed for quality assessment.The primary outcome was total patient-controlled analgesia(PCA)consumption.Secondary outcomes included hospital discharge time and the incidence of postoperative nausea and vomiting.A random-effects meta-analysis was conducted to calculate pooled mean differences(MD)and odds ratios(OR)with 95%CIs.RESULTS Nine RCTs involving a total of 643 patients(ESPB group=320;control group=323)were included in the analysis.ESPB significantly reduced PCA opioid consumption compared to controls(MD:-14.24,95%CI:-20.66 to-7.83,P<0.0001).Subgroup analysis showed reduced PCA use with ESPB vs morphine(MD:-8.78,95%CI:-15.34 to-2.22,P=0.009),and a non-significant effect compared to other analgesics(MD:-48.26,95%CI:-143.60 to 47.09).No statistically significant differences were observed in discharge time or the incidence of nausea and vomiting.CONCLUSION ESPB demonstrates the potential of reducing PCA in laparoscopic nephrectomy patients;however,its impact on secondary outcomes remains inconclusive.Large-scale RCTs are needed to confirm ESPB's benefits and explore long-term effects. 展开更多
关键词 Erector spinae plane block Laparoscopic nephrectomy Postoperative pain Opioid sparing Regional anesthesia NAUSEA Discharge time Minimally invasive surgery META-ANALYSIS
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Effect of annealing process on microstructure and plane stress fracture toughness of 7075 cladding sheet
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作者 Fang YU Ling-fei YANG +3 位作者 Zhong-chao ZHAO Xiang-jie WANG Cheng-cheng CHEN Jian-zhong CUI 《Transactions of Nonferrous Metals Society of China》 2025年第11期3650-3661,共12页
The effects of the inter-annealing process on the microstructure,plane stress fracture toughness,and tensile properties of an AA7075 cladding sheet were investigated using optical microscopy,scanning electron microsco... The effects of the inter-annealing process on the microstructure,plane stress fracture toughness,and tensile properties of an AA7075 cladding sheet were investigated using optical microscopy,scanning electron microscopy,electron backscattered diffraction,transmission electron microscopy,and mechanical property tests.The results indicate that the plane stress fracture toughness of AA7075-T6 cladding sheet can be greatly improved.The plane stress fracture toughness for the longitudinal-transverse(L-T)and transverse-longitudinal(T-L)directions were 117.7 and 94.8 MPa·m^(1/2),respectively,after intermediate annealing at 380°C.This represents an increase of 23.9 MPa·m^(1/2)in the L-T direction and 22.6 MPa·m^(1/2) in the T-L direction compared with the AA7075-T6 cladding sheet without intermediate annealing.Moreover,the tensile strength remains similar under different conditions.Microstructure analysis indicates that intermediate annealing before heat treatment can result in long sub-grains,few recrystallized grain boundaries,and small size precipitates in AA7075-T6 cladding sheets. 展开更多
关键词 AA7075-T6 cladding sheet intermediate annealing plane stress fracture toughness tensile strength sub-grain
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