Background There is a growing focus on using various plant-derived agricultural by-products to increase the benefits of pig farming,but these feedstuffs are fibrous in nature.This study investigated the relationship b...Background There is a growing focus on using various plant-derived agricultural by-products to increase the benefits of pig farming,but these feedstuffs are fibrous in nature.This study investigated the relationship between dietary fiber physicochemical properties and feedstuff fermentation characteristics and their effects on nutrient utilization,energy metabolism,and gut microbiota in growing pigs.Methods Thirty-six growing barrows(47.2±1.5 kg)were randomly allotted to 6 dietary treatments with 2 apparent viscosity levels and 3β-glucan-to-arabinoxylan ratios.In the experiment,nutrient utilization,energy metabolism,fecal microbial community,and production and absorption of short-chain fatty acid(SCFA)of pigs were investigated.In vitro digestion and fermentation models were used to compare the fermentation characteristics of feedstuffs and ileal digesta in the pig’s hindgut.Results The production dynamics of SCFA and dry matter corrected gas production of different feedstuffs during in vitro fermentation were different and closely related to the physical properties and chemical structure of the fiber.In animal experiments,increasing the dietary apparent viscosity and theβ-glucan-to-arabinoxylan ratios both increased the apparent ileal digestibility(AID),apparent total tract digestibility(ATTD),and hindgut digestibility of fiber components while decreasing the AID and ATTD of dry matter and organic matter(P<0.05).In addition,increasing dietary apparent viscosity andβ-glucan-to-arabinoxylan ratios both increased gas exchange,heat production,and protein oxidation,and decreased energy deposition(P<0.05).The dietary apparent viscosity andβ-glucanto-arabinoxylan ratios had linear interaction effects on the digestible energy,metabolizable energy,retained energy(RE),and net energy(NE)of the diets(P<0.05).At the same time,the increase of dietary apparent viscosity andβ-glucan-to-arabinoxylan ratios both increased SCFA production and absorption(P<0.05).Increasing the dietary apparent viscosity andβ-glucan-to-arabinoxylan ratios increased the diversity and abundance of bacteria(P<0.05)and the relative abundance of beneficial bacteria.Furthermore,increasing the dietaryβ-glucan-to-arabinoxylan ratios led to a linear increase in SCFA production during the in vitro fermentation of ileal digesta(P<0.001).Finally,the prediction equations for RE and NE were established.Conclusion Dietary fiber physicochemical properties alter dietary fermentation patterns and regulate nutrient utilization,energy metabolism,and pig gut microbiota composition and metabolites.展开更多
Food breakdown during storage and transit greatly adds to worldwide food waste.Biodegradable edible coatings derived from natural sources provide a sustainable method to extend the shelf life and preserve the freshnes...Food breakdown during storage and transit greatly adds to worldwide food waste.Biodegradable edible coatings derived from natural sources provide a sustainable method to extend the shelf life and preserve the freshness of fresh fruit.This study explores the potential of the readily available and nutrient-rich seaweed,Caulerpa lentillifera,as a base material for edible coatings that can enhance the shelf life and maintain the physicochemical properties of fruits and vegetables.Caulerpa lentillifera,a marine macroalga renowned for its unique biochemical composition,presents a promising avenue for developing sustainable bio-coatings to improve the post-harvest quality of fresh produce.Biodegradable edible coatings derived from natural sources provide a sustainable method to extend the shelf life and preserve the freshness of fresh fruit.This study is aimed at exploring the potential of Caulerpa lentillifera,a nutrient-dense green seaweed,as a foundational material for creating edible coatings to enhance the post-harvest quality of fruits and vegetables.Various Caulerpa lentillifera-derived coating formulations were developed and applied to specific fruits and vegetables.The coated samples were maintained under controlled conditions and assessed for alterations in physicochemical parameters,including weight loss,hardness,colour,and microbial proliferation.The optimised coating formulation markedly diminished weight loss,postponed ripening,and maintained firmness and colour relative to uncoated controls.The coating demonstrated promising antibacterial properties,aiding in the extension of shelf life.Coatings derived from Caulerpa lentillifera offer a viable,environmentally sustainable alternative to synthetic preservatives,facilitating the advancement of sustainable food preservation technology.展开更多
Controllable liquid manipulation is of paramount scientific and technological importance in various fields,such as the chemical industry,biomedicine,and agricultural production.Magnetic actuation,characterized by rapi...Controllable liquid manipulation is of paramount scientific and technological importance in various fields,such as the chemical industry,biomedicine,and agricultural production.Magnetic actuation,characterized by rapid,contactless,and environmentally benign operation,has emerged as a promising approach for precise liquid control.However,conventional magnetic strategies typically govern droplet movement on open surfaces,facing limitations such as restricted liquid volumes,uncertain flow paths,and inevitable evaporation,thereby constraining their broader practical applications.Recently,a variety of magneticdriven strategies have been developed to dynamically regulate liquids within enclosed spaces,especially through physicochemical mechanisms.These approaches provide efficient control over liquid behavior by leveraging magnetically induced chemical changes,structural deformations,and dragging motions,opening new opportunities for flexible and versatile fluid management.This review explores the design and mechanisms of magneto-responsive confined interfaces for the manipulation of nonmagnetic liquids,highlighting key advancements and potential applications including liquid valves,liquid mixing,liquid flow regulation,and liquid pumping.Finally,the existing challenges and future prospects in this field are presented.展开更多
With the rapid development of the world economy,complex air pollution has increasingly become a serious threat;for example,with haze events occurring frequently in various regions of the globe.Recent evidence has indi...With the rapid development of the world economy,complex air pollution has increasingly become a serious threat;for example,with haze events occurring frequently in various regions of the globe.Recent evidence has indicated that secondary aerosols play an important role in haze formation,and that heterogeneous processes are among the main forces driving their explosive growth.In this regard,this paper reviews recent advances in the understanding of the impact of heterogeneous processes on haze chemistry,including the impact on NO_(2)chemistry,marine aerosols,and the hygroscopicity and optical properties of atmospheric aerosols.It is distinguished from past reviews on this topic by focusing mainly on new insights from the past five years.We summarize the main findings of the impacts of heterogeneous processes on NO_(2)chemistry,marine aerosols,and the physicochemical properties of atmospheric aerosols,and propose several future research directions.展开更多
A total of fifty (50) samples of water from Lake Fitri (Chad), with 25 samples per island (Domoro and Maguite). The aim of this study was to analyze the bacteriological, biochemical and physico-chemical quality of the...A total of fifty (50) samples of water from Lake Fitri (Chad), with 25 samples per island (Domoro and Maguite). The aim of this study was to analyze the bacteriological, biochemical and physico-chemical quality of the water in Lake Fitri in Chad. Standard microbiology methods were used. Isolated strains of enterobacteria were characterized by API 20E and API Staph galleries and confirmed by API Web. Antibiotic resistance was performed according to the recommendations of the antibiogram committee (CA-SFM, 2019). Physico-chemical analysis of the water was carried out by (Rodier, 2009). The microbiological results revealed an abundance on the Domoro islands (5.37.106 ± 1.5.105 and 1.97.105 ± 4.94.104), successively for total aerobic mesophilic flora (FMAT), and thermotolerant coliform (E. coli) and on the Maguite Islands (4.71.106 ± 7.14.105 and 2.32.105 ± 2.86.104), alternately for total aerobic mesophilic flora (FMAT), and thermotolerant coliform (E. coli). The results obtained after incubation of the biochemical tests using the API 20E and API Staph galleries and their proposed numerical profile analyzed using Api software and confirmed by Api Web confirmed the contamination of the waters of Lake Fitri by pathogenic strains of E. coli, Staphylococcus and Salmonella spp. The results of the antibiogram carried out show the emergence of certain resistances to Tobramycin, Flucytosine and Teicoplanin. The average levels of BOD5, COD, SS, Nitrate (NO3) and Nitrite (NO2) for Domoro Island were 32.14 ± 2.37 mg/L, 423.86 ± 4.78 mg/L, 65.42 ± 2.27 mg/L, 0.04 ± 0.01 mg/L and 3.32 ± 1.48 mg/L respectively. The water from the islands of Lake Fitri must therefore be rigorously treated before consumption.展开更多
[Objectives]This study was conducted to investigate the physicochemical and functional properties of soluble dietary fiber(SDF)from apple pomace.[Methods]Soluble dietary fiber(SDF)from apple pomace was extracted by di...[Objectives]This study was conducted to investigate the physicochemical and functional properties of soluble dietary fiber(SDF)from apple pomace.[Methods]Soluble dietary fiber(SDF)from apple pomace was extracted by direct water extraction(W),lactic acid bacteria fermentation(F)and steam explosion(SE)respectively,and the extraction methods and physicochemical and functional characteristics were compared and analyzed.[Results]The solubility,water holding capacities,oil holding capacities and swelling capacities of W-SDF,F-SDF and SE-SDF were(2.13,3.95 and 5.13 g/g),(9.02,13.75 and 15.88 g/g),(2.13,4.08 and 5.11 g/g),and(10.82,14.03 and 15.77 ml/g),respectively.Their emulsifying activity,emulsifying stability and least gelation concentration were(30.28,47.95 and 58.72 ml/100 ml),(37.88,45.25 and 57.13 ml/100 ml),and(12.11,11.25 and 9.87%),respectively.The adsorption capacities of W-SDF,F-SDF and SE-SDF for heavy metals(Pb,As and Cu)in the intestinal environment(pH 7)were(162.7,183.5 and 197.3μmol/g),(132.8,156.7 and 168.9μmol/g),and(57.2,63.5 and 89.2μmol/g)respectively.In the gastric environment(pH 2),they were(72.8,110.5,138.9μmol/g),(82.1,112.5,135.7μmol/g),and(38.9,42.7,55.1μmol/g)respectively.[Conclusions]The study can provide a theoretical basis for functional modification and comprehensive utilization of dietary fiber from apple pomace.展开更多
Background:A thorough examination of the physicochemical properties,higher-order structure,subcellular localization,and selective pressure of the cytochrome c oxidase subunit I(COX1)protein of the endemic species Eoth...Background:A thorough examination of the physicochemical properties,higher-order structure,subcellular localization,and selective pressure of the cytochrome c oxidase subunit I(COX1)protein of the endemic species Eothenomys miletus(E.miletus)in the Hengduan Mountains provides further insights into molecular characteristics and function of the COX1 gene in E.miletus.Method:The physicochemical properties and higher-order structure of the COX1 protein of E.miletus were analyzed using bioinformatics software.Subsequently,a phylogenetic tree was constructed using Mega 7.0 software based on the COX1 gene from 19 species of the Arvicolinae subfamily and 3 species of the Muridae.Selection pressure analysis was performed using the PAML 4.7 software and the Datamonkey online website.Results:The COX1 protein of E.miletus comprises/consists of 514 amino acids,with leucine(Leu/L)being the most prevalent amino acid(11.5%).This hydrophilic protein contains 42 phosphorylation sites and 4 N-glycosylation sites.It possesses a transmembrane domain and lacks signal peptide distribution,thus classifying it as a non-GPI-anchored protein.The secondary structure of the COX1 protein consists ofα-helices(36.77%),random coils(33.85%),and extended chains,a composition consistent with/findings that align with its tertiary structure.Significant genetic differentiation exists among species within the Arvicolinae subfamily,a finding consistent with morphological identification results.The COX1 gene in Arvicolinae species exhibits purifying selection.Conclusion:This study analyzed the physicochemical properties of the COX1 protein in E.miletus.Phylogenetic and selection pressure analyses reveal significant genetic divergence among Arvicolinae species,and demonstrate that the COX1 gene is evolutionarily conserved within the Arvicolinae subfamily.展开更多
High-throughput sequencing(HTS)and gas chromatography time-of-flight mass spectrometry(GC-TOF-MS)were used to compare the microbiota structure and metabolic compounds of traditional suancai from Heilongjiang(HLJ),Shan...High-throughput sequencing(HTS)and gas chromatography time-of-flight mass spectrometry(GC-TOF-MS)were used to compare the microbiota structure and metabolic compounds of traditional suancai from Heilongjiang(HLJ),Shanxi(SX)and Qinghai(QH)in China.Besides,the physicochemical properties such as total number of colonies,p H and total acid content were determined,and the related factors of the differences were analyzed.The salinity of the 3 samples was 1.9%,8.0%and 10.0%,respectively,and the dominant bacterial genera were Loigolactobacillus,Arcobacter,and Marinomonas.Meanwhile,Loigolactobacillus was significantly positively associated with p H and nitrite in HLJ,Arcobacter was inversely related to p H and nitrite,while Marinomonas was negatively correlated with all physicochemical properties in QH which had the highest salinity.In addition,the 5 main differential metabolites in the 3 samples were acetic acid,4-ethylphenol,2,2,4-trimethyl-1,3-pentanediol diisobutyrate,2,4-tert-butylphenol,and 3-butenenitrile.Among them,the ketones and acids were positively correlated with the core bacteria in HLJ with the lowest salinity,and the main genera in SX were positively associated with various alcohols,while there was a positive correlation between Marinomonas and butyronitrile alcohol in QH with the highest salinity.This study provided a guidance for the differences and correlations of microorganisms,flavor compounds,and quality characteristics from a regional perspective by studying the various quality characteristics of the suancai.展开更多
Rational laboratory layout design and scientific management systems are key to improving overall laboratory efficiency and safety,providing a solid foundation and guarantee for the smooth progress of scientific resear...Rational laboratory layout design and scientific management systems are key to improving overall laboratory efficiency and safety,providing a solid foundation and guarantee for the smooth progress of scientific research.This article addresses a series of issues such as low testing efficiency caused by unreasonable laboratory layouts,incomplete or outdated equipment configurations affecting testing accuracy,and safety hazards arising from the lack of effective laboratory management systems.It conducts an in-depth exploration of the design and planning strategies for physicochemical laboratories.By proposing specific designs and guidelines for the location selection,functional zoning,and layout requirements of physicochemical laboratories,the aim is to optimize laboratory space utilization,enhance testing efficiency,and ensure the advancement of equipment configurations and the accuracy of testing precision.Simultaneously,it emphasizes the establishment of an effective laboratory management system to prevent and control safety hazards,safeguarding the lives of laboratory personnel and ensuring stable laboratory operations.展开更多
Edible mushroom proteins are the promising ones with the advantages of complete essential amino acid profile and multiple functional activities.To reinforce their applications in functional food development,this study...Edible mushroom proteins are the promising ones with the advantages of complete essential amino acid profile and multiple functional activities.To reinforce their applications in functional food development,this study comprehensively evaluated the physicochemical and functional properties of protein isolates from 5 mushroom species,i.e.,Pleurotus eryngii(PEP),Pleurotus ostreatus(POP),Lentinula edodes(LEP),Flammulina velutipes(FVP)and Hypsizygus marmoreus(HMP).Results showed that PEP,LEP,FVP,POP and HMP exhibited better protein solubility(PS),water holding capacity(WHC),emulsification activity index(EAI),and foaming capacity(FC)than those of soybean protein and pea protein isolates(PPI).PEP(51.95%)and POP(49.15%)had a higher amount ofβ-sheet structure.Principal component analysis and correlation analysis showed that the seven proteins could be divided into 3 clusters,and WHC,EAI and FC were significantly positively correlated with PS andβ-sheet.The least gelation concentration of PEP(16%)and FVP(16%)at p H 6.0 and 7.0 was similar to PPI,and PEP showed better hardness,springiness and rheological properties than other proteins gels.Overall,our study showed that 5 edible mushroom proteins possessed excellent functionalities(except for gelling capacity),which provided novel insights on unexploited sources of mushroom proteins used as protein-based foods in the food industry.展开更多
Pelargonium zonale is an important ornamental and medicinal plant.The purpose of this investigation was to evaluate the effects of conventional and unconventional fertilization on variations in the physicochemical par...Pelargonium zonale is an important ornamental and medicinal plant.The purpose of this investigation was to evaluate the effects of conventional and unconventional fertilization on variations in the physicochemical parameters of the culture substrate(temperature,pH,and electrical conductivity)in two cultivars of Pelargonium zonale(L.)L’Hér.,grown in pots.This study was conducted under greenhouse conditions,using Pindstrup peat as the culture substrate.The analysis focused on how these physicochemical indicators of peat influenced plant height and development under fertilization conditions.Results revealed that in the‘Tango Salmon’cultivar,both fertilization regimes significantly modified substrate temperature and electrical conductivity(conventional fertilization leading to the highest electric conductivity values of 0.77 mS/cm)while in control,was observed the highest substrate temperature(21.24℃).In contrast,pH remained relatively stable across treatments.In the‘Tango Dark Red’cultivar,no significant differences were observed between substrate physicochemical parameters regardless of treatment.The multiple correlations coefficients values showed that substrate parameters influenced plant height with varying degrees of intensity depending on cultivar and fertilization scheme,reaching up the highest predictability of 60.6%in the‘Tango Dark Red’control variant.The study highlighted that physicochemical properties of the substrate(particularly electric conductivity and temperature)are for were the main contributors to optimal plant development and should be carefully managed within fertilization strategies.展开更多
MXene,with metallic conductivity,strong hydrophilicity,and rich chemistries,has been widely used as electrode material for energy storage.However,the notorious issues of aggregation and oxidation for MXene significant...MXene,with metallic conductivity,strong hydrophilicity,and rich chemistries,has been widely used as electrode material for energy storage.However,the notorious issues of aggregation and oxidation for MXene significantly inhibit its electrochemical performance and further wide application.Herein,a physicochemical double protection strategy is proposed to stabilize MXene in the hydrothermal process effectively.Polyvinylpyrrolidone(PVP),with the structure of a long chain and abundant O/N function groups,provides physical protection against agglomeration(steric effect)and chemical protection against oxidation(electron transfer)at the same time,contributing to the synthesis of MXene-based hybrids with high conductivity and fully exposed active sites.As proof of the concept,2D MXene/Co_(9)S_(8) nanohybrids with a scaly surface are fabricated and present impressive performance,especially rate performance for hybrid supercapacitor(HSC)with MoS_(2) as the counter electrode.The HSC demonstrates a high energy density of 111 Wh kg^(-1) at 845 W kg^(-1) and an excellent rate performance of 61 Wh kg^(-1) at 16.9 kW kg^(-1).展开更多
[Objectives]This study was conducted to improve the poor water-holding capacity(WHC)and high syneresis rate of fermented soy milk by optimizing fermentation process conditions.[Methods]Based on the results of single f...[Objectives]This study was conducted to improve the poor water-holding capacity(WHC)and high syneresis rate of fermented soy milk by optimizing fermentation process conditions.[Methods]Based on the results of single factor experiments,response surface methodology was employed to optimize the fermentation temperature,fermentation time,and starter culture addition for enhancing WHC.The physicochemical properties of fermented soybean milk were analyzed.[Results]The optimal process parameters were determined as follows:fermentation temperature 36℃,fermentation time 8 h,and starter culture addition 5%.Under these conditions,WHC reached(77.18±0.08)%,which was consistent with the theoretical prediction value of(76.75±0.15)%.During fermentation,the pH decreased from(6.6±0.11)to(4.65±0.09),while acidity increased from(16.5±0.04)°T to(81.5±0.08)°T.The viable cell count rose from 1×10^(7)to 29×10^(7)cfu/ml,and WHC was improved significantly from(10.50±0.18)%to(77.40±0.13)%.[Conclusions]This study optimized the fermentation process parameters and revealed physicochemical characteristic changes during soybean milk fermentation,providing a theoretical foundation for industrial production.展开更多
The paper proposes a biomass cross-upgrading process that combines hydrothermal carbonization and pyrolysis to produce high-quality blast furnace injection fuel.The results showed that after upgrading,the volatile con...The paper proposes a biomass cross-upgrading process that combines hydrothermal carbonization and pyrolysis to produce high-quality blast furnace injection fuel.The results showed that after upgrading,the volatile content of biochar ranged from 16.19%to 45.35%,and the alkali metal content,ash content,and specific surface area were significantly reduced.The optimal route for biochar pro-duction is hydrothermal carbonization-pyrolysis(P-HC),resulting in biochar with a higher calorific value,C=C structure,and increased graphitization degree.The apparent activation energy(E)of the sample ranges from 199.1 to 324.8 kJ/mol,with P-HC having an E of 277.8 kJ/mol,lower than that of raw biomass,primary biochar,and anthracite.This makes P-HC more suitable for blast furnace injection fuel.Additionally,the paper proposes a path for P-HC injection in blast furnaces and calculates potential environmental benefits.P-HC of-fers the highest potential for carbon emission reduction,capable of reducing emissions by 96.04 kg/t when replacing 40wt%coal injec-tion.展开更多
Oil blending is the method of choice used worldwide to improve oxidative stability and nutritional value.There is no such edible oil/fat that meets all the recommendations from the health point of view.The fatty acid ...Oil blending is the method of choice used worldwide to improve oxidative stability and nutritional value.There is no such edible oil/fat that meets all the recommendations from the health point of view.The fatty acid composition of vegetable oils decides the fate of the oil.Pure single oil is unable to provide a balanced amount of fatty acids(FAs)required/recommended on a daily intake basis.Blending oils/fats is an appropriate procedure of physically mixing multiple oils in suitable proportions which may provide functional lipids with improved antioxidant potential and desirable physical and chemical properties.This review piled up the accessible data on the blending of diverse oils/fats in the combination of binary,ternary,quaternary,or other types of oils into a single blended oil.Blending can be found very convincing towards appropriate FA profile,enhancement in physicochemical characteristics,and augmented stability for the period of storage or when used as cooking/frying processes which could ultimately serve as an effectual dietary intervention towards the health protectiveness.展开更多
Background,aim,and scope Certain physicochemical indexes of topsoil are closely related to climatic factors including temperature,and precipitation.Understanding the relationship between modern topsoil properties and ...Background,aim,and scope Certain physicochemical indexes of topsoil are closely related to climatic factors including temperature,and precipitation.Understanding the relationship between modern topsoil properties and climatic factors is essential for quantitative paleoclimate reconstruction.Motuo located in the eastern Himalayas,exhibits a significant elevation gradient of over 7000 m from Nnamjagbarwa Peak(7782 m a.s.l.)to the Baxika(150 m a.s.l.).This region features a complete vertical zonation of vegetation,from alpine meadow to tropical forest,presenting an ideal place to investigate the relationships among vegetation,soil and climate conditions across altitudinal gradients.This study aims to explore the vertical variations in the physicochemical composition of topsoil and its relationship with temperature and precipitation.Materials and methods Twenty-seven topsoil samples were collected at 100 m intervals from 800 m to 3600 m a.s.l.along the southern slope of the Himalayas.Grain size,magnetic susceptibility and geochemical elements were measured to discuss the vertical variation characteristics of topsoil composition and their correlation with climatic factors.Results(1)The grain size of topsoil at different altitudes in Motuo is mainly composed of sand accounting for an averaged 53.2%,followed by silt and clay.(2)In the mixed forest zone,frequency dependent magnetic susceptibility(χfd%)shows a clear relationship with altitude,and clay is positively correlated with both altitude and climatic factors.(3)The oxides of topsoil in this area mainly consist of SiO_(2),Al_(2)O_(3) and Fe_(2)O_(3),followed by MgO,CaO,Na_(2)O and K_(2)O,with slight variations in the primary components at different altitudes.The sensitivity of elements to climate varies across different altitudes and vegetation zone,likely due to the region’s complex topography and vegetation.(4)Physical and biological weathering dominates in the broad-leaved forest zone of Motuo,while chemical weathering is more prominent in the coniferous forest zone,with the mixed forest zone falling in between.Discussion The formation of topsoil across the three vegetation zones is influenced by various factors,including parent material,vegetation,and climate.In the broad-leaved forest zone,physical weathering(precipitation,root wedging etc.)and pedogenesis dominate,resulting in finer grain size.The χ_(fd)% increases with altitude likely due to the high temperature and abundant precipitation in this zone,which facilitate the transformation of strong magnetic miners into weaker ones,particularly when the soil is oversaturated.Zirconium(Zr),primarily found in zircon,is depleted at lower altitudes by strong current erosion.Barium(Ba)is similarly reduced at low altitudes in this zone.In mixed forest zone,clay content is the lowest,indicating weaker physical weathering conditions than broad-leaved forest zone.The coarser grain size may result from the combined effects of topography and vegetation coverage.Magnetic susceptibility and organic matter show a positive correlation with altitude.Zr concentration is higher than that in the broad-leaved forest zone,likely resulting from decreased precipitation.In the coniferous zone,the clay content shows considerable fluctuations,with grain size generally becoming finer as altitude increases.This trend may be explained by intensified soil disintegration from seasonal freeze-thaw cycles.The χ_(fd)% values lack a clear trend or pattern,possibly due to soil erosion causing the migration of magnetic minerals or insufficient iron precipitation,which reduces the concentration of magnetic minerals in the soil.Additionally,a positive correlation is observed between altitude and organic matter content,with higher altitudes associated with greater organic matter accumulation.This may be attributed to lower microbial activity in colder conditions,which slows the decomposition and transformation of organic matter.Conclusions The variations in grain size,magnetic susceptibility,and geochemical elements differ across altitudes and vegetation zones,closely connected to the complex interplay of terrain,vegetation,and climate in Motuo.In the mixed forest,altitude has a significant impact onχfd%,and the clay component is particularly sensitive to changes in altitude,mean annual temperature,and precipitation.Zr shows a strong correlation with altitude and climate factors,making it a valuable indicator for assessing changes in atmospheric precipitation within specific altitude ranges.Recommendations and perspectives This study enhances our understanding of the relationships between the physicochemical properties of topsoil and climate conditions,offering valuable insights for paleoclimate reconstruction in Motuo.展开更多
In order to comprehend the applicability of microwave irradiation for recovering coalbed methane,it is necessary to evaluate the microwave irradiation-induced alterations in coals with varying levels of metamorphism.I...In order to comprehend the applicability of microwave irradiation for recovering coalbed methane,it is necessary to evaluate the microwave irradiation-induced alterations in coals with varying levels of metamorphism.In this work,the carbon molecular sieve combined with KMnO_(4)oxidation was selected to fabricate carbon molecular sieve with diverse oxidation degrees,which can serve as model substances toward coals.Afterwards,the microwave irradiation dependences of pores,functional groups,and highpressure methane adsorption characteristics of model substances were studied.The results indicated that microwave irradiation causes rearrangement of oxygen-containing functional groups,which could block the micropores with a size of 0.40-0.60 nm in carbon molecular sieve;meanwhile,naphthalene and phenanthrene generated by macro-molecular structure pyrolysis due to microwave irradiation could block the micropores with a size of 0.70-0.90 nm.These alterations in micropore structure weaken the saturated methane adsorption capacity of oxidized carbon molecular sieve by 2.91%-23.28%,suggesting that microwave irradiation could promote methane desorption.Moreover,the increased mesopores found for oxidized carbon molecular sieve after microwave irradiation could benefit CH4 diffusion.In summary,the oxidized carbon molecular sieve can act as model substances toward coals with different ranks.Additionally,microwave irradiation is a promising technology to enhance coalbed methane recovery.展开更多
This research investigates the potential of blending complementary lard oil with rubber seed oil as feedstock for biodiesel production.Rubber seed oil,obtained through hexane extraction using the Soxhlet method,contai...This research investigates the potential of blending complementary lard oil with rubber seed oil as feedstock for biodiesel production.Rubber seed oil,obtained through hexane extraction using the Soxhlet method,contains the major fatty acids of oleic acid(C_(18:1)),palmitic acid(C_(16:0)),linoleic acid(C_(18:2)),and stearic acid(C_(18:0)),while rubber seed oil primarily consists of linoleic acid(C_(18:2)),oleic acid(C_(18:1)),linolenic acid(C_(18:3)),palmitic acid(C_(16:0)),and stearic acid(C_(18:0)).The least acid value of lard oil(0.55 mg KOH/g)can benefit of reducing soap formation of rubber seed oil during transesterification process in biodiesel production due to its substantial-high acid value(16.28 mg KOH/g).Blending at ratios below 80:20 volume ratio produced biodiesel exceeding 85%,utilizing CaO as a catalyst.Lard oil demonstrated a higher reaction rate constant(11.88×10^(-3)min^(-1))than rubber seed oil(2.11×10^(-3)min^(-1)),indicating a significant difference in performance.High acid value and free fatty acids in rubber seed oil correlated with lower reaction rates.Maintaining a mixture ratio below 80:20 volume ratio optimized reaction rates during biodiesel production.Biodiesel obtained from blends below 80:20 volume ratio met ASTM D6751 and EN 14214 standards,demonstrating suitability for bio-auto fuel.The drawbacks of using rubber seed oil as a raw material for biodiesel production are overcome by blending with lard oil,giving rise to expanding renewable energy options for rural communities,community enterprises,and large-scale biodiesel production.展开更多
This study investigated the effects of superheated steam(SS)treatment at different temperatures(120℃,150℃,180℃)on the physicochemical properties of broken rice flour and the quality of broken rice cakes.SS treatmen...This study investigated the effects of superheated steam(SS)treatment at different temperatures(120℃,150℃,180℃)on the physicochemical properties of broken rice flour and the quality of broken rice cakes.SS treatment at 120℃ significantly enhanced the moisture content of broken rice flour(P<0.05).In contrast,treatments at 150℃ and 180℃ caused decrease of moisture content,amylose leaching,and reduction of damaged starch content.After SS treatment,the pasting properties of broken rice flour increased,along with the rising of storage modulus and loss modulus.The proportion of short chains(DP 6-12)in amylopectin increased from 29.42%to 34.80%(P<0.05),which could delay starch retrogradation.Compared with untreated ones,the SS-150 broken rice cakes showed a significantly higher specific volume(2.96 mL/g,P<0.05),more uniform cell structure,and lower hardness(1.66 N)and chewiness(10.22 mJ).After 7 days of storage,cakes from SS-treated rice flour(150℃ and 180℃)had significantly reduced hardness and chewiness.The study demonstrated that SS treatment could improve the properties of broken rice flour and enhance the quality of broken rice cakes,especially at 150℃ and 180℃.This study presents a method for improving the quality of broken rice flour and rice cakes using superheated steam treatment,addressing challenges related to poor flour characteristics and suboptimal cake quality.The findings offer technical and theoretical support for enhancing rice cake production,contributing to the comprehensive utilization of rice resources.展开更多
The purpose of this study is to investigate the physicochemical properties of some local varieties of onion (Allium cepa L.) and compare them with an imported variety, all collected in May 2021. Proteins, reducing sug...The purpose of this study is to investigate the physicochemical properties of some local varieties of onion (Allium cepa L.) and compare them with an imported variety, all collected in May 2021. Proteins, reducing sugars, lipids, and polyphenol content were estimated according to the AFNOR standardized methods. The determination of calcium, magnesium, iron, sodium, potassium and phosphorus was performed by atomic absorption spectrophotometer coupled with a CCD detector. The results highlighted an average acidity of 0.377% ± 0.002% lower than the value of the imported variety which is 0.520% ± 0.001%. Local varieties have a pH ranging from 6.35 ± 0.003 to 6.42 ± 0.004, while the variety has a pH of 6.36 ± 0.003. The ash and dry matter contents vary respectively from 4.788% ± 0.004% to 8.253% ± 0.003% and 7.945% ± 0.021% to 11.945% ± 0.007% for the local varieties. Moreover, the imported one has ash and dry matter contents of 5.175% ± 0.007% and 10.035% ± 0.021% respectively. The results show that the protein, reducing sugar and lipid contents in the local onion varieties vary respectively from 2.815 ± 0.000 to 15.634 ± 0.001 g·100 g<sup>-1</sup>;4.691 ± 0.001 to 12.596 ± 0.002 g·100 g<sup>-1</sup> and 0.006 ± 0.001 to 0.050 ± 0.057 g·100 g<sup>-1</sup>. Furthermore, the imported variety has a protein, reducing sugar and lipid content of 5.649 ± 0.002;8.565 ± 0.002 g·100 g<sup>-1</sup> and 0.011 ± 0.010 g·100 g<sup>-1</sup> respectively. The maximum levels of total polyphenols are obtained in the imported variety, Bellani and Gandiol, respectively 9.973 ± 0.001, 4.535 ± 0.002, and 3.425 ± 0.006 mg EAG/g of dry matter. The local varieties have a significant calorific intake of between 35.451 ± 0.001 and 112.980 ± 0.003 kcal·100 g<sup>-1</sup> compared to the imported one with an energy value of 56.953 ± 0.001 kcal·100 g<sup>-1</sup> of dry matter. The bulbs of different onion varieties studied have a fairly high content of mineral elements. The potassium content of local varieties is between 502.16 ± 0.06 mg·100 g<sup>-1</sup> and 582.77 ± 0.04 mg·100 g<sup>-1</sup> while the imported variety has a content of 536.62 ± 1.30 mg·100 g<sup>-1</sup>. They note that the local varieties have a better calcium content (249.75 ± 0.07 to 434.20 ± 0.57 mg·100 g<sup>-1</sup>) and magnesium (142.15 ± 0.07 to 162.60 ± 0.42 mg·100 g<sup>-1</sup>) than the imported variety (229.58 ± 0.04 mg·100 g<sup>-1</sup>) except for the varieties White Grano (228.29 ± 0.01 mg·100 g<sup>-1</sup>) and Rouge Amposta (117.00 ± 0.42 mg·100 g<sup>-1</sup>) respectively. These results reveal that Gandiol, Dayo and Orient F1 are nutritionally found better due to their higher antioxidant property, proteins, carbohydrates, and reducing sugar and should be included in diets to supplement our daily allowance needed by the body.展开更多
基金supported by the National Key Research and Development Program(No.2021YFD1300201)Jilin Provincial Department of Science and Technology Innovation Platform and Talent Special Project(No.20230508090RC).
文摘Background There is a growing focus on using various plant-derived agricultural by-products to increase the benefits of pig farming,but these feedstuffs are fibrous in nature.This study investigated the relationship between dietary fiber physicochemical properties and feedstuff fermentation characteristics and their effects on nutrient utilization,energy metabolism,and gut microbiota in growing pigs.Methods Thirty-six growing barrows(47.2±1.5 kg)were randomly allotted to 6 dietary treatments with 2 apparent viscosity levels and 3β-glucan-to-arabinoxylan ratios.In the experiment,nutrient utilization,energy metabolism,fecal microbial community,and production and absorption of short-chain fatty acid(SCFA)of pigs were investigated.In vitro digestion and fermentation models were used to compare the fermentation characteristics of feedstuffs and ileal digesta in the pig’s hindgut.Results The production dynamics of SCFA and dry matter corrected gas production of different feedstuffs during in vitro fermentation were different and closely related to the physical properties and chemical structure of the fiber.In animal experiments,increasing the dietary apparent viscosity and theβ-glucan-to-arabinoxylan ratios both increased the apparent ileal digestibility(AID),apparent total tract digestibility(ATTD),and hindgut digestibility of fiber components while decreasing the AID and ATTD of dry matter and organic matter(P<0.05).In addition,increasing dietary apparent viscosity andβ-glucan-to-arabinoxylan ratios both increased gas exchange,heat production,and protein oxidation,and decreased energy deposition(P<0.05).The dietary apparent viscosity andβ-glucanto-arabinoxylan ratios had linear interaction effects on the digestible energy,metabolizable energy,retained energy(RE),and net energy(NE)of the diets(P<0.05).At the same time,the increase of dietary apparent viscosity andβ-glucan-to-arabinoxylan ratios both increased SCFA production and absorption(P<0.05).Increasing the dietary apparent viscosity andβ-glucan-to-arabinoxylan ratios increased the diversity and abundance of bacteria(P<0.05)and the relative abundance of beneficial bacteria.Furthermore,increasing the dietaryβ-glucan-to-arabinoxylan ratios led to a linear increase in SCFA production during the in vitro fermentation of ileal digesta(P<0.001).Finally,the prediction equations for RE and NE were established.Conclusion Dietary fiber physicochemical properties alter dietary fermentation patterns and regulate nutrient utilization,energy metabolism,and pig gut microbiota composition and metabolites.
文摘Food breakdown during storage and transit greatly adds to worldwide food waste.Biodegradable edible coatings derived from natural sources provide a sustainable method to extend the shelf life and preserve the freshness of fresh fruit.This study explores the potential of the readily available and nutrient-rich seaweed,Caulerpa lentillifera,as a base material for edible coatings that can enhance the shelf life and maintain the physicochemical properties of fruits and vegetables.Caulerpa lentillifera,a marine macroalga renowned for its unique biochemical composition,presents a promising avenue for developing sustainable bio-coatings to improve the post-harvest quality of fresh produce.Biodegradable edible coatings derived from natural sources provide a sustainable method to extend the shelf life and preserve the freshness of fresh fruit.This study is aimed at exploring the potential of Caulerpa lentillifera,a nutrient-dense green seaweed,as a foundational material for creating edible coatings to enhance the post-harvest quality of fruits and vegetables.Various Caulerpa lentillifera-derived coating formulations were developed and applied to specific fruits and vegetables.The coated samples were maintained under controlled conditions and assessed for alterations in physicochemical parameters,including weight loss,hardness,colour,and microbial proliferation.The optimised coating formulation markedly diminished weight loss,postponed ripening,and maintained firmness and colour relative to uncoated controls.The coating demonstrated promising antibacterial properties,aiding in the extension of shelf life.Coatings derived from Caulerpa lentillifera offer a viable,environmentally sustainable alternative to synthetic preservatives,facilitating the advancement of sustainable food preservation technology.
基金supported by the National Natural Science Foundation of China(Nos.52025132,U24A20205,52303373,21621091,22021001,and 22121001)the China Postdoctoral Science Foundation(No.2024M763174)+2 种基金the 111 Project(Nos.B17027,B16029)the Natural Science Foundation of Fujian Province of China(No.2022J02059)the New Cornerstone Science Foundation through the Xplorer Prize。
文摘Controllable liquid manipulation is of paramount scientific and technological importance in various fields,such as the chemical industry,biomedicine,and agricultural production.Magnetic actuation,characterized by rapid,contactless,and environmentally benign operation,has emerged as a promising approach for precise liquid control.However,conventional magnetic strategies typically govern droplet movement on open surfaces,facing limitations such as restricted liquid volumes,uncertain flow paths,and inevitable evaporation,thereby constraining their broader practical applications.Recently,a variety of magneticdriven strategies have been developed to dynamically regulate liquids within enclosed spaces,especially through physicochemical mechanisms.These approaches provide efficient control over liquid behavior by leveraging magnetically induced chemical changes,structural deformations,and dragging motions,opening new opportunities for flexible and versatile fluid management.This review explores the design and mechanisms of magneto-responsive confined interfaces for the manipulation of nonmagnetic liquids,highlighting key advancements and potential applications including liquid valves,liquid mixing,liquid flow regulation,and liquid pumping.Finally,the existing challenges and future prospects in this field are presented.
基金supported by the National Key Research and Development Program of China(No.2022YFC3701000)the National Natural Science Foundation of China(Nos.42130606 and 41931287)+1 种基金the Beijing National Laboratory for Molecular Sciences(BNLMS-CXXM-202011)the Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.Y2021013).
文摘With the rapid development of the world economy,complex air pollution has increasingly become a serious threat;for example,with haze events occurring frequently in various regions of the globe.Recent evidence has indicated that secondary aerosols play an important role in haze formation,and that heterogeneous processes are among the main forces driving their explosive growth.In this regard,this paper reviews recent advances in the understanding of the impact of heterogeneous processes on haze chemistry,including the impact on NO_(2)chemistry,marine aerosols,and the hygroscopicity and optical properties of atmospheric aerosols.It is distinguished from past reviews on this topic by focusing mainly on new insights from the past five years.We summarize the main findings of the impacts of heterogeneous processes on NO_(2)chemistry,marine aerosols,and the physicochemical properties of atmospheric aerosols,and propose several future research directions.
文摘A total of fifty (50) samples of water from Lake Fitri (Chad), with 25 samples per island (Domoro and Maguite). The aim of this study was to analyze the bacteriological, biochemical and physico-chemical quality of the water in Lake Fitri in Chad. Standard microbiology methods were used. Isolated strains of enterobacteria were characterized by API 20E and API Staph galleries and confirmed by API Web. Antibiotic resistance was performed according to the recommendations of the antibiogram committee (CA-SFM, 2019). Physico-chemical analysis of the water was carried out by (Rodier, 2009). The microbiological results revealed an abundance on the Domoro islands (5.37.106 ± 1.5.105 and 1.97.105 ± 4.94.104), successively for total aerobic mesophilic flora (FMAT), and thermotolerant coliform (E. coli) and on the Maguite Islands (4.71.106 ± 7.14.105 and 2.32.105 ± 2.86.104), alternately for total aerobic mesophilic flora (FMAT), and thermotolerant coliform (E. coli). The results obtained after incubation of the biochemical tests using the API 20E and API Staph galleries and their proposed numerical profile analyzed using Api software and confirmed by Api Web confirmed the contamination of the waters of Lake Fitri by pathogenic strains of E. coli, Staphylococcus and Salmonella spp. The results of the antibiogram carried out show the emergence of certain resistances to Tobramycin, Flucytosine and Teicoplanin. The average levels of BOD5, COD, SS, Nitrate (NO3) and Nitrite (NO2) for Domoro Island were 32.14 ± 2.37 mg/L, 423.86 ± 4.78 mg/L, 65.42 ± 2.27 mg/L, 0.04 ± 0.01 mg/L and 3.32 ± 1.48 mg/L respectively. The water from the islands of Lake Fitri must therefore be rigorously treated before consumption.
基金Supported by High-end Talent Project of Hebei ProvinceTangshan Talent Funding Project(B202302006).
文摘[Objectives]This study was conducted to investigate the physicochemical and functional properties of soluble dietary fiber(SDF)from apple pomace.[Methods]Soluble dietary fiber(SDF)from apple pomace was extracted by direct water extraction(W),lactic acid bacteria fermentation(F)and steam explosion(SE)respectively,and the extraction methods and physicochemical and functional characteristics were compared and analyzed.[Results]The solubility,water holding capacities,oil holding capacities and swelling capacities of W-SDF,F-SDF and SE-SDF were(2.13,3.95 and 5.13 g/g),(9.02,13.75 and 15.88 g/g),(2.13,4.08 and 5.11 g/g),and(10.82,14.03 and 15.77 ml/g),respectively.Their emulsifying activity,emulsifying stability and least gelation concentration were(30.28,47.95 and 58.72 ml/100 ml),(37.88,45.25 and 57.13 ml/100 ml),and(12.11,11.25 and 9.87%),respectively.The adsorption capacities of W-SDF,F-SDF and SE-SDF for heavy metals(Pb,As and Cu)in the intestinal environment(pH 7)were(162.7,183.5 and 197.3μmol/g),(132.8,156.7 and 168.9μmol/g),and(57.2,63.5 and 89.2μmol/g)respectively.In the gastric environment(pH 2),they were(72.8,110.5,138.9μmol/g),(82.1,112.5,135.7μmol/g),and(38.9,42.7,55.1μmol/g)respectively.[Conclusions]The study can provide a theoretical basis for functional modification and comprehensive utilization of dietary fiber from apple pomace.
基金supported by the National Natural Science Foundation of China(32160254)Yunnan Fundamental Research Projects(202401AS070039).
文摘Background:A thorough examination of the physicochemical properties,higher-order structure,subcellular localization,and selective pressure of the cytochrome c oxidase subunit I(COX1)protein of the endemic species Eothenomys miletus(E.miletus)in the Hengduan Mountains provides further insights into molecular characteristics and function of the COX1 gene in E.miletus.Method:The physicochemical properties and higher-order structure of the COX1 protein of E.miletus were analyzed using bioinformatics software.Subsequently,a phylogenetic tree was constructed using Mega 7.0 software based on the COX1 gene from 19 species of the Arvicolinae subfamily and 3 species of the Muridae.Selection pressure analysis was performed using the PAML 4.7 software and the Datamonkey online website.Results:The COX1 protein of E.miletus comprises/consists of 514 amino acids,with leucine(Leu/L)being the most prevalent amino acid(11.5%).This hydrophilic protein contains 42 phosphorylation sites and 4 N-glycosylation sites.It possesses a transmembrane domain and lacks signal peptide distribution,thus classifying it as a non-GPI-anchored protein.The secondary structure of the COX1 protein consists ofα-helices(36.77%),random coils(33.85%),and extended chains,a composition consistent with/findings that align with its tertiary structure.Significant genetic differentiation exists among species within the Arvicolinae subfamily,a finding consistent with morphological identification results.The COX1 gene in Arvicolinae species exhibits purifying selection.Conclusion:This study analyzed the physicochemical properties of the COX1 protein in E.miletus.Phylogenetic and selection pressure analyses reveal significant genetic divergence among Arvicolinae species,and demonstrate that the COX1 gene is evolutionarily conserved within the Arvicolinae subfamily.
基金supported by the Key R&D Project of Ningbo City(2022Z176)the Open Project Program of State Key Laboratory of Food Science and Resources,Jiangnan University(SKLF-KF-202306)。
文摘High-throughput sequencing(HTS)and gas chromatography time-of-flight mass spectrometry(GC-TOF-MS)were used to compare the microbiota structure and metabolic compounds of traditional suancai from Heilongjiang(HLJ),Shanxi(SX)and Qinghai(QH)in China.Besides,the physicochemical properties such as total number of colonies,p H and total acid content were determined,and the related factors of the differences were analyzed.The salinity of the 3 samples was 1.9%,8.0%and 10.0%,respectively,and the dominant bacterial genera were Loigolactobacillus,Arcobacter,and Marinomonas.Meanwhile,Loigolactobacillus was significantly positively associated with p H and nitrite in HLJ,Arcobacter was inversely related to p H and nitrite,while Marinomonas was negatively correlated with all physicochemical properties in QH which had the highest salinity.In addition,the 5 main differential metabolites in the 3 samples were acetic acid,4-ethylphenol,2,2,4-trimethyl-1,3-pentanediol diisobutyrate,2,4-tert-butylphenol,and 3-butenenitrile.Among them,the ketones and acids were positively correlated with the core bacteria in HLJ with the lowest salinity,and the main genera in SX were positively associated with various alcohols,while there was a positive correlation between Marinomonas and butyronitrile alcohol in QH with the highest salinity.This study provided a guidance for the differences and correlations of microorganisms,flavor compounds,and quality characteristics from a regional perspective by studying the various quality characteristics of the suancai.
文摘Rational laboratory layout design and scientific management systems are key to improving overall laboratory efficiency and safety,providing a solid foundation and guarantee for the smooth progress of scientific research.This article addresses a series of issues such as low testing efficiency caused by unreasonable laboratory layouts,incomplete or outdated equipment configurations affecting testing accuracy,and safety hazards arising from the lack of effective laboratory management systems.It conducts an in-depth exploration of the design and planning strategies for physicochemical laboratories.By proposing specific designs and guidelines for the location selection,functional zoning,and layout requirements of physicochemical laboratories,the aim is to optimize laboratory space utilization,enhance testing efficiency,and ensure the advancement of equipment configurations and the accuracy of testing precision.Simultaneously,it emphasizes the establishment of an effective laboratory management system to prevent and control safety hazards,safeguarding the lives of laboratory personnel and ensuring stable laboratory operations.
基金supported by the special fund of Jiangsu Province for the transformation of scientific and technological achievements(BA2021062)Jiangsu agricultural science and technology independent innovation fund(CX(22)2007)。
文摘Edible mushroom proteins are the promising ones with the advantages of complete essential amino acid profile and multiple functional activities.To reinforce their applications in functional food development,this study comprehensively evaluated the physicochemical and functional properties of protein isolates from 5 mushroom species,i.e.,Pleurotus eryngii(PEP),Pleurotus ostreatus(POP),Lentinula edodes(LEP),Flammulina velutipes(FVP)and Hypsizygus marmoreus(HMP).Results showed that PEP,LEP,FVP,POP and HMP exhibited better protein solubility(PS),water holding capacity(WHC),emulsification activity index(EAI),and foaming capacity(FC)than those of soybean protein and pea protein isolates(PPI).PEP(51.95%)and POP(49.15%)had a higher amount ofβ-sheet structure.Principal component analysis and correlation analysis showed that the seven proteins could be divided into 3 clusters,and WHC,EAI and FC were significantly positively correlated with PS andβ-sheet.The least gelation concentration of PEP(16%)and FVP(16%)at p H 6.0 and 7.0 was similar to PPI,and PEP showed better hardness,springiness and rheological properties than other proteins gels.Overall,our study showed that 5 edible mushroom proteins possessed excellent functionalities(except for gelling capacity),which provided novel insights on unexploited sources of mushroom proteins used as protein-based foods in the food industry.
文摘Pelargonium zonale is an important ornamental and medicinal plant.The purpose of this investigation was to evaluate the effects of conventional and unconventional fertilization on variations in the physicochemical parameters of the culture substrate(temperature,pH,and electrical conductivity)in two cultivars of Pelargonium zonale(L.)L’Hér.,grown in pots.This study was conducted under greenhouse conditions,using Pindstrup peat as the culture substrate.The analysis focused on how these physicochemical indicators of peat influenced plant height and development under fertilization conditions.Results revealed that in the‘Tango Salmon’cultivar,both fertilization regimes significantly modified substrate temperature and electrical conductivity(conventional fertilization leading to the highest electric conductivity values of 0.77 mS/cm)while in control,was observed the highest substrate temperature(21.24℃).In contrast,pH remained relatively stable across treatments.In the‘Tango Dark Red’cultivar,no significant differences were observed between substrate physicochemical parameters regardless of treatment.The multiple correlations coefficients values showed that substrate parameters influenced plant height with varying degrees of intensity depending on cultivar and fertilization scheme,reaching up the highest predictability of 60.6%in the‘Tango Dark Red’control variant.The study highlighted that physicochemical properties of the substrate(particularly electric conductivity and temperature)are for were the main contributors to optimal plant development and should be carefully managed within fertilization strategies.
基金financially supported by the Beijing Natural Science Founding(No.2202050)the National Natural Science Foundation of China(No.21111120074).
文摘MXene,with metallic conductivity,strong hydrophilicity,and rich chemistries,has been widely used as electrode material for energy storage.However,the notorious issues of aggregation and oxidation for MXene significantly inhibit its electrochemical performance and further wide application.Herein,a physicochemical double protection strategy is proposed to stabilize MXene in the hydrothermal process effectively.Polyvinylpyrrolidone(PVP),with the structure of a long chain and abundant O/N function groups,provides physical protection against agglomeration(steric effect)and chemical protection against oxidation(electron transfer)at the same time,contributing to the synthesis of MXene-based hybrids with high conductivity and fully exposed active sites.As proof of the concept,2D MXene/Co_(9)S_(8) nanohybrids with a scaly surface are fabricated and present impressive performance,especially rate performance for hybrid supercapacitor(HSC)with MoS_(2) as the counter electrode.The HSC demonstrates a high energy density of 111 Wh kg^(-1) at 845 W kg^(-1) and an excellent rate performance of 61 Wh kg^(-1) at 16.9 kW kg^(-1).
基金Supported by Postgraduate Research Innovation Project of Shaoyang University(CX2023SY026)Natural Science Foundation of Hunan Province(2022JJ50232)Horizontal Scientific Research Project of Shaoyang University(2023HX43).
文摘[Objectives]This study was conducted to improve the poor water-holding capacity(WHC)and high syneresis rate of fermented soy milk by optimizing fermentation process conditions.[Methods]Based on the results of single factor experiments,response surface methodology was employed to optimize the fermentation temperature,fermentation time,and starter culture addition for enhancing WHC.The physicochemical properties of fermented soybean milk were analyzed.[Results]The optimal process parameters were determined as follows:fermentation temperature 36℃,fermentation time 8 h,and starter culture addition 5%.Under these conditions,WHC reached(77.18±0.08)%,which was consistent with the theoretical prediction value of(76.75±0.15)%.During fermentation,the pH decreased from(6.6±0.11)to(4.65±0.09),while acidity increased from(16.5±0.04)°T to(81.5±0.08)°T.The viable cell count rose from 1×10^(7)to 29×10^(7)cfu/ml,and WHC was improved significantly from(10.50±0.18)%to(77.40±0.13)%.[Conclusions]This study optimized the fermentation process parameters and revealed physicochemical characteristic changes during soybean milk fermentation,providing a theoretical foundation for industrial production.
基金the National Key R&D Program of China(No.2022YFE0208100)the National Natural Science Foundation of China(No.5274316)+1 种基金the Key Research and Development Plan of Anhui Province,China(No.202210700037)the Major Science and Technology Project of Xinjiang Uygur Autonomous Region,China(No.2022A01003).
文摘The paper proposes a biomass cross-upgrading process that combines hydrothermal carbonization and pyrolysis to produce high-quality blast furnace injection fuel.The results showed that after upgrading,the volatile content of biochar ranged from 16.19%to 45.35%,and the alkali metal content,ash content,and specific surface area were significantly reduced.The optimal route for biochar pro-duction is hydrothermal carbonization-pyrolysis(P-HC),resulting in biochar with a higher calorific value,C=C structure,and increased graphitization degree.The apparent activation energy(E)of the sample ranges from 199.1 to 324.8 kJ/mol,with P-HC having an E of 277.8 kJ/mol,lower than that of raw biomass,primary biochar,and anthracite.This makes P-HC more suitable for blast furnace injection fuel.Additionally,the paper proposes a path for P-HC injection in blast furnaces and calculates potential environmental benefits.P-HC of-fers the highest potential for carbon emission reduction,capable of reducing emissions by 96.04 kg/t when replacing 40wt%coal injec-tion.
基金the National Centre of Excellence in Analytical Chemistry,University of Sindh,Jamshoro,Pakistan,for providing financial support to carry out this work.
文摘Oil blending is the method of choice used worldwide to improve oxidative stability and nutritional value.There is no such edible oil/fat that meets all the recommendations from the health point of view.The fatty acid composition of vegetable oils decides the fate of the oil.Pure single oil is unable to provide a balanced amount of fatty acids(FAs)required/recommended on a daily intake basis.Blending oils/fats is an appropriate procedure of physically mixing multiple oils in suitable proportions which may provide functional lipids with improved antioxidant potential and desirable physical and chemical properties.This review piled up the accessible data on the blending of diverse oils/fats in the combination of binary,ternary,quaternary,or other types of oils into a single blended oil.Blending can be found very convincing towards appropriate FA profile,enhancement in physicochemical characteristics,and augmented stability for the period of storage or when used as cooking/frying processes which could ultimately serve as an effectual dietary intervention towards the health protectiveness.
文摘Background,aim,and scope Certain physicochemical indexes of topsoil are closely related to climatic factors including temperature,and precipitation.Understanding the relationship between modern topsoil properties and climatic factors is essential for quantitative paleoclimate reconstruction.Motuo located in the eastern Himalayas,exhibits a significant elevation gradient of over 7000 m from Nnamjagbarwa Peak(7782 m a.s.l.)to the Baxika(150 m a.s.l.).This region features a complete vertical zonation of vegetation,from alpine meadow to tropical forest,presenting an ideal place to investigate the relationships among vegetation,soil and climate conditions across altitudinal gradients.This study aims to explore the vertical variations in the physicochemical composition of topsoil and its relationship with temperature and precipitation.Materials and methods Twenty-seven topsoil samples were collected at 100 m intervals from 800 m to 3600 m a.s.l.along the southern slope of the Himalayas.Grain size,magnetic susceptibility and geochemical elements were measured to discuss the vertical variation characteristics of topsoil composition and their correlation with climatic factors.Results(1)The grain size of topsoil at different altitudes in Motuo is mainly composed of sand accounting for an averaged 53.2%,followed by silt and clay.(2)In the mixed forest zone,frequency dependent magnetic susceptibility(χfd%)shows a clear relationship with altitude,and clay is positively correlated with both altitude and climatic factors.(3)The oxides of topsoil in this area mainly consist of SiO_(2),Al_(2)O_(3) and Fe_(2)O_(3),followed by MgO,CaO,Na_(2)O and K_(2)O,with slight variations in the primary components at different altitudes.The sensitivity of elements to climate varies across different altitudes and vegetation zone,likely due to the region’s complex topography and vegetation.(4)Physical and biological weathering dominates in the broad-leaved forest zone of Motuo,while chemical weathering is more prominent in the coniferous forest zone,with the mixed forest zone falling in between.Discussion The formation of topsoil across the three vegetation zones is influenced by various factors,including parent material,vegetation,and climate.In the broad-leaved forest zone,physical weathering(precipitation,root wedging etc.)and pedogenesis dominate,resulting in finer grain size.The χ_(fd)% increases with altitude likely due to the high temperature and abundant precipitation in this zone,which facilitate the transformation of strong magnetic miners into weaker ones,particularly when the soil is oversaturated.Zirconium(Zr),primarily found in zircon,is depleted at lower altitudes by strong current erosion.Barium(Ba)is similarly reduced at low altitudes in this zone.In mixed forest zone,clay content is the lowest,indicating weaker physical weathering conditions than broad-leaved forest zone.The coarser grain size may result from the combined effects of topography and vegetation coverage.Magnetic susceptibility and organic matter show a positive correlation with altitude.Zr concentration is higher than that in the broad-leaved forest zone,likely resulting from decreased precipitation.In the coniferous zone,the clay content shows considerable fluctuations,with grain size generally becoming finer as altitude increases.This trend may be explained by intensified soil disintegration from seasonal freeze-thaw cycles.The χ_(fd)% values lack a clear trend or pattern,possibly due to soil erosion causing the migration of magnetic minerals or insufficient iron precipitation,which reduces the concentration of magnetic minerals in the soil.Additionally,a positive correlation is observed between altitude and organic matter content,with higher altitudes associated with greater organic matter accumulation.This may be attributed to lower microbial activity in colder conditions,which slows the decomposition and transformation of organic matter.Conclusions The variations in grain size,magnetic susceptibility,and geochemical elements differ across altitudes and vegetation zones,closely connected to the complex interplay of terrain,vegetation,and climate in Motuo.In the mixed forest,altitude has a significant impact onχfd%,and the clay component is particularly sensitive to changes in altitude,mean annual temperature,and precipitation.Zr shows a strong correlation with altitude and climate factors,making it a valuable indicator for assessing changes in atmospheric precipitation within specific altitude ranges.Recommendations and perspectives This study enhances our understanding of the relationships between the physicochemical properties of topsoil and climate conditions,offering valuable insights for paleoclimate reconstruction in Motuo.
基金supported by the National Natural Science Foundation of China(42272202 and 52264001)the Yunnan Fundamental Research Projects(202201AT070144)+1 种基金the Yunnan Ten Thousand Talents Plan Young&Elite Talents Project(YNWRQNBJ-2019-164)Training Programmes of Innovation and Entrepreneurship for Undergraduates of Yunnan Province(S202210674128).
文摘In order to comprehend the applicability of microwave irradiation for recovering coalbed methane,it is necessary to evaluate the microwave irradiation-induced alterations in coals with varying levels of metamorphism.In this work,the carbon molecular sieve combined with KMnO_(4)oxidation was selected to fabricate carbon molecular sieve with diverse oxidation degrees,which can serve as model substances toward coals.Afterwards,the microwave irradiation dependences of pores,functional groups,and highpressure methane adsorption characteristics of model substances were studied.The results indicated that microwave irradiation causes rearrangement of oxygen-containing functional groups,which could block the micropores with a size of 0.40-0.60 nm in carbon molecular sieve;meanwhile,naphthalene and phenanthrene generated by macro-molecular structure pyrolysis due to microwave irradiation could block the micropores with a size of 0.70-0.90 nm.These alterations in micropore structure weaken the saturated methane adsorption capacity of oxidized carbon molecular sieve by 2.91%-23.28%,suggesting that microwave irradiation could promote methane desorption.Moreover,the increased mesopores found for oxidized carbon molecular sieve after microwave irradiation could benefit CH4 diffusion.In summary,the oxidized carbon molecular sieve can act as model substances toward coals with different ranks.Additionally,microwave irradiation is a promising technology to enhance coalbed methane recovery.
基金financially supported by the Research and Development Institute at Sakon Nakhon Rajabhat University,as well as by the National Research Council of Thailand(NRCT)(N42A650196).
文摘This research investigates the potential of blending complementary lard oil with rubber seed oil as feedstock for biodiesel production.Rubber seed oil,obtained through hexane extraction using the Soxhlet method,contains the major fatty acids of oleic acid(C_(18:1)),palmitic acid(C_(16:0)),linoleic acid(C_(18:2)),and stearic acid(C_(18:0)),while rubber seed oil primarily consists of linoleic acid(C_(18:2)),oleic acid(C_(18:1)),linolenic acid(C_(18:3)),palmitic acid(C_(16:0)),and stearic acid(C_(18:0)).The least acid value of lard oil(0.55 mg KOH/g)can benefit of reducing soap formation of rubber seed oil during transesterification process in biodiesel production due to its substantial-high acid value(16.28 mg KOH/g).Blending at ratios below 80:20 volume ratio produced biodiesel exceeding 85%,utilizing CaO as a catalyst.Lard oil demonstrated a higher reaction rate constant(11.88×10^(-3)min^(-1))than rubber seed oil(2.11×10^(-3)min^(-1)),indicating a significant difference in performance.High acid value and free fatty acids in rubber seed oil correlated with lower reaction rates.Maintaining a mixture ratio below 80:20 volume ratio optimized reaction rates during biodiesel production.Biodiesel obtained from blends below 80:20 volume ratio met ASTM D6751 and EN 14214 standards,demonstrating suitability for bio-auto fuel.The drawbacks of using rubber seed oil as a raw material for biodiesel production are overcome by blending with lard oil,giving rise to expanding renewable energy options for rural communities,community enterprises,and large-scale biodiesel production.
基金supported by the Postdoctoral Innovation Project of Shandong Province (SDCX-ZG-202303090).
文摘This study investigated the effects of superheated steam(SS)treatment at different temperatures(120℃,150℃,180℃)on the physicochemical properties of broken rice flour and the quality of broken rice cakes.SS treatment at 120℃ significantly enhanced the moisture content of broken rice flour(P<0.05).In contrast,treatments at 150℃ and 180℃ caused decrease of moisture content,amylose leaching,and reduction of damaged starch content.After SS treatment,the pasting properties of broken rice flour increased,along with the rising of storage modulus and loss modulus.The proportion of short chains(DP 6-12)in amylopectin increased from 29.42%to 34.80%(P<0.05),which could delay starch retrogradation.Compared with untreated ones,the SS-150 broken rice cakes showed a significantly higher specific volume(2.96 mL/g,P<0.05),more uniform cell structure,and lower hardness(1.66 N)and chewiness(10.22 mJ).After 7 days of storage,cakes from SS-treated rice flour(150℃ and 180℃)had significantly reduced hardness and chewiness.The study demonstrated that SS treatment could improve the properties of broken rice flour and enhance the quality of broken rice cakes,especially at 150℃ and 180℃.This study presents a method for improving the quality of broken rice flour and rice cakes using superheated steam treatment,addressing challenges related to poor flour characteristics and suboptimal cake quality.The findings offer technical and theoretical support for enhancing rice cake production,contributing to the comprehensive utilization of rice resources.
文摘The purpose of this study is to investigate the physicochemical properties of some local varieties of onion (Allium cepa L.) and compare them with an imported variety, all collected in May 2021. Proteins, reducing sugars, lipids, and polyphenol content were estimated according to the AFNOR standardized methods. The determination of calcium, magnesium, iron, sodium, potassium and phosphorus was performed by atomic absorption spectrophotometer coupled with a CCD detector. The results highlighted an average acidity of 0.377% ± 0.002% lower than the value of the imported variety which is 0.520% ± 0.001%. Local varieties have a pH ranging from 6.35 ± 0.003 to 6.42 ± 0.004, while the variety has a pH of 6.36 ± 0.003. The ash and dry matter contents vary respectively from 4.788% ± 0.004% to 8.253% ± 0.003% and 7.945% ± 0.021% to 11.945% ± 0.007% for the local varieties. Moreover, the imported one has ash and dry matter contents of 5.175% ± 0.007% and 10.035% ± 0.021% respectively. The results show that the protein, reducing sugar and lipid contents in the local onion varieties vary respectively from 2.815 ± 0.000 to 15.634 ± 0.001 g·100 g<sup>-1</sup>;4.691 ± 0.001 to 12.596 ± 0.002 g·100 g<sup>-1</sup> and 0.006 ± 0.001 to 0.050 ± 0.057 g·100 g<sup>-1</sup>. Furthermore, the imported variety has a protein, reducing sugar and lipid content of 5.649 ± 0.002;8.565 ± 0.002 g·100 g<sup>-1</sup> and 0.011 ± 0.010 g·100 g<sup>-1</sup> respectively. The maximum levels of total polyphenols are obtained in the imported variety, Bellani and Gandiol, respectively 9.973 ± 0.001, 4.535 ± 0.002, and 3.425 ± 0.006 mg EAG/g of dry matter. The local varieties have a significant calorific intake of between 35.451 ± 0.001 and 112.980 ± 0.003 kcal·100 g<sup>-1</sup> compared to the imported one with an energy value of 56.953 ± 0.001 kcal·100 g<sup>-1</sup> of dry matter. The bulbs of different onion varieties studied have a fairly high content of mineral elements. The potassium content of local varieties is between 502.16 ± 0.06 mg·100 g<sup>-1</sup> and 582.77 ± 0.04 mg·100 g<sup>-1</sup> while the imported variety has a content of 536.62 ± 1.30 mg·100 g<sup>-1</sup>. They note that the local varieties have a better calcium content (249.75 ± 0.07 to 434.20 ± 0.57 mg·100 g<sup>-1</sup>) and magnesium (142.15 ± 0.07 to 162.60 ± 0.42 mg·100 g<sup>-1</sup>) than the imported variety (229.58 ± 0.04 mg·100 g<sup>-1</sup>) except for the varieties White Grano (228.29 ± 0.01 mg·100 g<sup>-1</sup>) and Rouge Amposta (117.00 ± 0.42 mg·100 g<sup>-1</sup>) respectively. These results reveal that Gandiol, Dayo and Orient F1 are nutritionally found better due to their higher antioxidant property, proteins, carbohydrates, and reducing sugar and should be included in diets to supplement our daily allowance needed by the body.
