Candida-associated denture stomatitis (CADS) is a significant clinical concern. We have demonstrated that urethane-based denture biomaterials with 10% methacrylic acid (MAA) could bind and then slowly release antifung...Candida-associated denture stomatitis (CADS) is a significant clinical concern. We have demonstrated that urethane-based denture biomaterials with 10% methacrylic acid (MAA) could bind and then slowly release antifungal drug for months. Drugs on the resins could be repeatedly quenched/recharged, and in subsequent recharging, they could be changed/switched to more potent/effective ones. However, the physical/mechanical properties and biocompatibility of the new MAA-based resins are currently unknown. The objective of the current study is to evaluate the effects of copolymerization with MAA on physical/mechanical properties and biocompatibility of urethane-based denture resin materials. MAA and diurethane dimethacrylate (UDMA) were copolymerized using initiator azobisisobutyronitrile (AIBN). Water sorption and solubility were assessed with the specifications of ISO (International Standards Organization) test method 1567, flexural strength and modulus were measured according to ASTM D-790, and biocompatibility was preliminarily evaluated in cytotoxicity assay using mouse 3T3 fibroblast cells with the trypan blue method. The results demonstrated that copolymerization of UDMA with up to 10% MAA did not negatively affect water sorption/solubility, flexural strength/modulus, and biocompatibility. With 20% MAA, however, the mechanical properties of the resulting resins were significantly decreased. To sum up, UDMA-MAA copolymers with up to 10% MAA had adequate physical/mechanical properties for denture materials with no side effects on cell viability. The UDMA-MAA denture biomaterials have a good potential to be used clinically for managing CADS and other related infectious conditions.展开更多
Exploring dynamic mechanical responses and failure behaviors of hot dry rock(HDR)is significant for geothermal exploitation and stability assessment.In this study,via the split Hopkinson pressure bar(SHPB)system,a ser...Exploring dynamic mechanical responses and failure behaviors of hot dry rock(HDR)is significant for geothermal exploitation and stability assessment.In this study,via the split Hopkinson pressure bar(SHPB)system,a series of dynamic compression tests were conducted on granite treated by cyclic thermal shocks at different temperatures.We analyzed the effects of cyclic thermal shock on the thermal-related physical and dynamic mechanical behaviors of granite.Specifically,the P-wave velocity,dynamic strength,and elastic modulus of the tested granite decrease with increasing temperature and cycle number,while porosity and peak strain increase.The degradation law of dynamic mechanical properties could be described by a cubic polynomial.Cyclic thermal shock promotes shear cracks propagation,causing dynamic failure mode of granite to transition from splitting to tensile-shear composite failure,accompanied by surface spalling and debris splashing.Moreover,the thermal shock damage evolution and coupled failure mechanism of tested granite are discussed.The evolution of thermal shock damage with thermal shock cycle numbers shows an obvious S-shaped surface,featured by an exponential correlation with dynamic mechanical parameters.In addition,with increasing thermal shock temperature and cycles,granite mineral species barely change,but the length and width of thermal cracks increase significantly.The non-uniform expansion of minerals,thermal shock-induced cracking,and water-rock interaction are primary factors for deteriorating dynamic mechanical properties of granite under cyclic thermal shock.展开更多
Three types of Al/Al−27%Si laminated composites,each containing 22%Si,were fabricated via hot pressing and hot rolling.The microstructures,mechanical properties and thermo-physical properties of these composites were ...Three types of Al/Al−27%Si laminated composites,each containing 22%Si,were fabricated via hot pressing and hot rolling.The microstructures,mechanical properties and thermo-physical properties of these composites were investigated.The results demonstrated that the three laminated composites exhibited similar microstructural features,characterized by well-bonded interfaces between the Al layer and the Al−27%Si alloy layer.The tensile and flexural strengths of the composites were significantly higher than those of both Al−22%Si and Al−27%Si alloys.These strengths increased gradually with decreasing the layer thickness,reaching peak values of 222.5 and 407.4 MPa,respectively.Crack deflection was observed in the cross-sections of the bending fracture surfaces,which contributed to the enhanced strength and toughness.In terms of thermo-physical properties,the thermal conductivity of the composites was lower than that of Al−22%Si and Al−27%Si alloys.The minimum reductions in thermal conductivity were 6.8%and 0.9%for the T3 laminated composite,respectively.Additionally,the coefficient of thermal expansion of the composites was improved,exhibiting varying temperature-dependent behaviors.展开更多
This review aims to identify the assets and limitations of Dabema(Piptadeniastrum africanum)as a sustainable alternative to traditional timber species for furniture and construction applications.Dabema is characterize...This review aims to identify the assets and limitations of Dabema(Piptadeniastrum africanum)as a sustainable alternative to traditional timber species for furniture and construction applications.Dabema is characterized by its high density and dimensional stability,meeting ASTM(American Society for Testing and Materials)standards for mechanical strength,which is essential for promoting its use.However,its limited availability in trade and ingrained habits of use are obstacles to its widespread commercialization.In addition,thermal and oleothermal treatments have shown great potential for improving the characteristics of this wood,although they require ongoing optimization and rigorous environmental assessment.Consequently,increased awareness of the benefits of Dabema is decisive to encourage its sustainable adoption in modern economies.This could help to diversify forest resources and encourage more sustainable building practices,taking advantage of Dabema’s unique properties while mitigating environmental sustainability concerns.展开更多
The mainstream method for extracting shale gas involves hydraulic fracturing to create fracture networks.However,as extraction depth increases,notable issues such as rapid production decline,low recovery rates,high wa...The mainstream method for extracting shale gas involves hydraulic fracturing to create fracture networks.However,as extraction depth increases,notable issues such as rapid production decline,low recovery rates,high water consumption,and resource waste become apparent.Identifying new and efficient auxiliary rock-breaking technologies is crucial for overcoming these challenges.The laser,successfully utilized in industrial production,medical treatment,and technological research,offers unique features such as good directionality,coherence,and high energy density,providing novel possibilities for addressing the limitations of existing deep reservoir transformation.This research focuses on a novel laser-assisted rock-breaking technology,with shale featuring different bedding angles as the subject of investigation.The investigation methodically explored how shale responded to thermal fracture at high temperatures when exposed to laser irradiation with different spot diameter.It investigates the spatiotemporal evolution characteristics of the shale temperature field under laser irradiation,the propagation features of cracks on shale surface,and the physicochemical fracture mechanisms.The research yields the following results:(1)The region of thermal influence of the irradiation surface can be divided into three regions based on the change of rise curve of temperature in the shale surface.(2)Based on the scanning electron microscopy(SEM)testing,combined with the macroscopic and microscopic morphological characteristics of shale fracture surfaces,it reveals significantly distinct zoning characteristics in the roughness of the rock sample’s fracture surfaces after laser irradiation.(3)The thermal fracturing process of shale under laser irradiation involves chemical reactions of constituent minerals and stress generated by the thermal expansion of shale oil in the reservoir.(4)The damage and fracture of shale under the irradiation of laser show significant bedding effect,and there are three modes of rock sample failure:Pattern T(thermal failure),Pattern T-B(thermal and bedding synergistic failure),and Pattern B(bedding failure).The research findings presented in this article serve as a foundation and reference for the theory and technology of laser-assisted shale gas extraction.展开更多
Physical analog modeling is an effective approach for studying the hazards of coal bursts in coal similarity criteria for physical and mechanical parameters of the actual and similar materials are crucial to yield rea...Physical analog modeling is an effective approach for studying the hazards of coal bursts in coal similarity criteria for physical and mechanical parameters of the actual and similar materials are crucial to yield realistic results.The derivation of similarity criteria is predominantly based on dimensional analysis,while a systematic methodology has yet to be developed.This paper attempts to fill this gap by combining the equation transformation method with similarity theory to conduct an in-depth study on the similarity criteria of physical parameters of impact coal with various internal block sizes.On this basis,the influence of internal block size of impact coal on similarity criteria was studied.Block size can provide a selection basis for similar materials,and the influence of block size on model physical parameters and similarity criteria under different geometric similarity ratios was explored.The variation laws between geometric similarity ratio,block size,and physical properties were clarified,and the similarity criteria of impact coal under the influence of block size were adjusted.New insights into material selection for physical analog modeling were proposed.The established similarity criteria for impact coal under the influence of different block sizes can provide a theoretical basis for determining various parameters in the physical analog modeling of coal bursts,when building a physical model of impact coal,material selection and size selection can be based on similarity criteria to more accurately reproduce coal explosion disasters in the laboratory.展开更多
Eutectogels are considered to have immense application potential in the field of flexible wearable ionotronic devices because of their excellent ionic conductivity,thermal and electrochemical stability,and non-volatil...Eutectogels are considered to have immense application potential in the field of flexible wearable ionotronic devices because of their excellent ionic conductivity,thermal and electrochemical stability,and non-volatility.However,most existing technologies still struggle to achieve synergistic optimization of key performance indicators,such as high mechanical strength and ionic conductivity.To address this chal-lenge,this study successfully prepared a green eutectogel material with outstanding comprehensive properties by leveraging the high solubility of glycerol in a polymerizable deep eutectic solvent(DES)composed of acrylic acid and choline chloride.The resulting eutectogels exhibited a high transparency(89%),high mechanical strength(up to 2.8 MPa),and exceptional tensile performance(up to 1385%).The fabricated flexible sensor demonstrated ideal linear sensitivity(gauge factor:0.88),a broad response range(1%-100%),and reliable stability(over 1000 cycles),en-abling the precise monitoring of human motion(e.g.,finger bending and wrist rotation).The flexible strain sensor based on this eutectogel is ex-pected to show promising prospects for medical monitoring,human-machine interaction,and industrial sensing applications.展开更多
The rapid expansion of marine industries has created an urgent demand for advanced engineering materials with superior multifunctional performance.While Cu-Ni alloys demonstrate favorable stability and tribological ch...The rapid expansion of marine industries has created an urgent demand for advanced engineering materials with superior multifunctional performance.While Cu-Ni alloys demonstrate favorable stability and tribological characteristics,their practical applications are constrained by compromised thermal conductivity and insufficient mechanical strength due to the solid solution of a high amount of Ni in the Cu matrix.Cu-Ni matrix composites reinforced with hexagonal boron nitride(h-BN)have garnered significant attention due to their potential for tailored mechanical and thermal properties.However,challenges such as BN agglomerations in Cu-Ni matrix and poor interfacial bonding hinder their practical applications.To address these limitations,this study proposes an innovative fabrication strategy for boron nitride nanosheets(BNNSs)reinforced Cu-Ni composites by integrating the in situ synthesis of BNNSs on Cu powders via chemical vapor deposition with powder metallurgy.Benefited by the in situ strategy,BNNSs with high crystallinity distribute uniformly within the Cu matrix and have an intimate interfacial bonding without voids or other types of defects.Remarkably,the BNNSs/Cu-30%Ni composite achieves simultaneous enhancement in strength and ductility,exhibiting an ultimate tensile strength of 417 MPa and fracture elongation of 17.5%,representing 30%and 118%improvements over pure Cu-Ni alloys,respectively.This exceptional mechanical synergy originates from threefold strengthening mechanisms:grain refinement,mobile dislocation pinning,and efficient stress transfer via robust interfaces.The microstructural analysis confirms that homogenous distribution of BNNSs optimized stress distribution,mitigating strain localization in the composites.Fractographic examination demonstrates uniformly distributed dimples containing embedded BNNSs,indicative of effective crack bridging and deflection during failure.Furthermore,the composite possesses excellent corrosion resistance comparable to matrix alloys,while achieving 21.23%enhancement in thermal conductivity and 20%reduction in coefficient of friction.The scalable fabrication protocol successfully resolves longstanding challenges in BNNSs dispersion and interfacial bonding,offering a viable pathway for designing high-performance CMCs for marine applications.展开更多
Coral sand is a unique material developed in the tropical ocean environment, which is mainly composed of coral and other marine organism debris, with the CaCO3 content up to 96 %. It has special physical and mechanica...Coral sand is a unique material developed in the tropical ocean environment, which is mainly composed of coral and other marine organism debris, with the CaCO3 content up to 96 %. It has special physical and mechanical properties due to its composition, structure and sedimentary environment. In this contribution, we discuss its specific gravity, porosity ratio compressibility, crushing, shearing and intensity for coral sand samples from the Nansha islands based on laboratory mechanical tests. Our results show distinct high porosity ratio, high friction angle and low intensity as compared with the quartz sand. We believe that grain crushing is the main factor that influences the deformation and strength of coral sand. Comprehensive study on the physical and mechanical properties of coral sands is significant in providing reliable scientific parameters to construction on coral islet, and thus avoids accidents in construction.展开更多
The physical-mechanical properties of Populus x canadensis Moench and Populus x euramericana （Dode） Guinier cv. Gelrica were studied to provide theoret- ical and scientific bases for the directional breeding and eff...The physical-mechanical properties of Populus x canadensis Moench and Populus x euramericana （Dode） Guinier cv. Gelrica were studied to provide theoret- ical and scientific bases for the directional breeding and efficient use of artificial forests with P. canadensis and P. euramericana Gelrica. The results showed the air-dried density, basic density of P. canadensis were 0.468 g/cm3 and 0.372 g/cm3, respectively; the shrinkage coefficient of radial, tangential and volume were 0.133%, 0.270% and 0.553%, respectively;the modulus of elasticity in static bending, the bending strength and the compressive strength parallel to grain were 9 302.99 MPa, 79.69 MPa and 40.32 Mpa, respectively. As for the P. euramericana Gelrica, the air-dried density, basic densitywere 0.453 and 0.355 g/cm3, respectively; the shrink- age coefficient of radial, tangential and volume were 0.205%, 0.304% and 0.554%, respectively; the modulus of elasticity in static bending, the bending strength and the compressive strength parallel to grain were 9 014.44, 55.87 and 33.09 Mpa respectively. Comprehensive analysis of the indicators showed that the properties of P. canadensis were better than those of P.euramericana Gelrica.展开更多
Neuromorphic devices have shown great potential in simulating the function of biological neurons due to their efficient parallel information processing and low energy consumption.MXene-Ti_(3)C_(2)T_(x),an emerging two...Neuromorphic devices have shown great potential in simulating the function of biological neurons due to their efficient parallel information processing and low energy consumption.MXene-Ti_(3)C_(2)T_(x),an emerging twodimensional material,stands out as an ideal candidate for fabricating neuromorphic devices.Its exceptional electrical performance and robust mechanical properties make it an ideal choice for this purpose.This review aims to uncover the advantages and properties of MXene-Ti_(3)C_(2)T_(x)in neuromorphic devices and to promote its further development.Firstly,we categorize several core physical mechanisms present in MXene-Ti_(3)C_(2)T_(x)neuromorphic devices and summarize in detail the reasons for their formation.Then,this work systematically summarizes and classifies advanced techniques for the three main optimization pathways of MXene-Ti_(3)C_(2)T_(x),such as doping engineering,interface engineering,and structural engineering.Significantly,this work highlights innovative applications of MXene-Ti_(3)C_(2)T_(x)neuromorphic devices in cutting-edge computing paradigms,particularly near-sensor computing and in-sensor computing.Finally,this review carefully compiles a table that integrates almost all research results involving MXene-Ti_(3)C_(2)T_(x)neuromorphic devices and discusses the challenges,development prospects,and feasibility of MXene-Ti_(3)C_(2)T_(x)-based neuromorphic devices in practical applications,aiming to lay a solid theoretical foundation and provide technical support for further exploration and application of MXene-Ti_(3)C_(2)T_(x)in the field of neuromorphic devices.展开更多
The functional properties of glasses are governed by their formation history and the complex relaxation processes they undergo.However,under extreme conditions,glass behaviors are still elusive.In this study,we employ...The functional properties of glasses are governed by their formation history and the complex relaxation processes they undergo.However,under extreme conditions,glass behaviors are still elusive.In this study,we employ simulations with varied protocols to evaluate the effectiveness of different descriptors in predicting mechanical properties across both low-and high-pressure regimes.Our findings demonstrate that conventional structural and configurational descriptors fail to correlate with the mechanical response following pressure release,whereas the activation energy descriptor exhibits robust linearity with shear modulus after correcting for pressure effects.Notably,the soft mode parameter emerges as an ideal and computationally efficient alternative for capturing this mechanical behavior.These findings provide critical insights into the influence of pressure on glassy properties,integrating the distinct features of compressed glasses into a unified theoretical framework.展开更多
Alzheimer's disease is the primary cause of dementia and imposes a significant socioeconomic burden globally.Physical exercise,as an effective strategy for improving general health,has been largely reported for it...Alzheimer's disease is the primary cause of dementia and imposes a significant socioeconomic burden globally.Physical exercise,as an effective strategy for improving general health,has been largely reported for its effectiveness in slowing neurodegeneration and increasing brain functional plasticity,particularly in aging brains.However,the underlying mechanisms of exercise in cognitive aging remain largely unclear.Adiponectin,a cell-secreted protein hormone,has recently been found to regulate synaptic plasticity and mediate the antidepressant effects of physical exercise.Studies on the neuroprotective effects of adiponectin have revealed potential innovative treatments for Alzheimer's disease.Here,we reviewed the functions of adiponectin and its receptor in the brains of human and animal models of cognitive impairment.We summarized the role of adiponectin in Alzheimer's disease,focusing on its impact on energy metabolism,insulin resistance,and inflammation.We also discuss how exercise increases adiponectin secretion and its potential benefits for learning and memory.Finally,we highlight the latest research on chemical compounds that mimic exerciseenhanced secretion of adiponectin and its receptor in Alzheimer's disease.展开更多
The advancement of flexible memristors has significantly promoted the development of wearable electronic for emerging neuromorphic computing applications.Inspired by in-memory computing architecture of human brain,fle...The advancement of flexible memristors has significantly promoted the development of wearable electronic for emerging neuromorphic computing applications.Inspired by in-memory computing architecture of human brain,flexible memristors exhibit great application potential in emulating artificial synapses for highefficiency and low power consumption neuromorphic computing.This paper provides comprehensive overview of flexible memristors from perspectives of development history,material system,device structure,mechanical deformation method,device performance analysis,stress simulation during deformation,and neuromorphic computing applications.The recent advances in flexible electronics are summarized,including single device,device array and integration.The challenges and future perspectives of flexible memristor for neuromorphic computing are discussed deeply,paving the way for constructing wearable smart electronics and applications in large-scale neuromorphic computing and high-order intelligent robotics.展开更多
Bentonite is a necessary binder in producing pellets.Its excessive use reduces the iron grade of pellets and increases production costs.Minimizing bentonite dosage is essential for producing high-quality iron ore pell...Bentonite is a necessary binder in producing pellets.Its excessive use reduces the iron grade of pellets and increases production costs.Minimizing bentonite dosage is essential for producing high-quality iron ore pellets.Addressing the gap in the application of organically-intercalated modified bentonite in the pelletizing field,this study introduces an innovative modification process for bentonite that employs the synergistic effect of mechanical force and dimethyl sulfoxide to enhance the intercalation of organic compounds within bentonite,thus significantly enhancing its binding performance.The colloid value and swell capacity of modified bentonite(98.5 m L/3g and 55.0 m L/g)were much higher than the original bentonite(90.5 m L/3g and 17.5 m L/g).With the decrease of bentonite dosage from1.5wt%to 1.0wt%,the drop number of green pellets from a height of 0.5 m and the compressive strengths of roasted pellets using the modified bentonite(6.0 times and 2916 N per pellet)were significantly higher than those of the original bentonite(4.0 times and 2739 N per pellet).This study provides a comprehensive analysis of the intercalation modification mechanism of bentonite,offering crucial technical insights for the development of high-performance modified bentonite as iron ore pellet binders.展开更多
(NbZrHfTi)C high-entropy ceramics,as an emerging class of ultra-high-temperature materials,have garnered significant interest due to their unique multi-principal-element crystal structure and exceptional hightemperatu...(NbZrHfTi)C high-entropy ceramics,as an emerging class of ultra-high-temperature materials,have garnered significant interest due to their unique multi-principal-element crystal structure and exceptional hightemperature properties.This study systematically investigates the mechanical properties of(NbZrHfTi)C high-entropy ceramics by employing first-principles density functional theory,combined with the Debye-Grüneisen model,to explore the variations in their thermophysical properties with temperature(0–2000 K)and pressure(0–30 GPa).Thermodynamically,the calculated mixing enthalpy and Gibbs free energy confirm the feasibility of forming a stable single-phase solid solution in(NbZrHfTi)C.The calculated results of the elastic stiffness constant indicate that the material meets the mechanical stability criteria of the cubic crystal system,further confirming the structural stability.Through evaluation of key mechanical parameters—bulk modulus,shear modulus,Young’s modulus,and Poisson’s ratio—we provide comprehensive insight into the macro-mechanical behaviour of the material and its correlation with the underlying microstructure.Notably,compared to traditional binary carbides and their average properties,(NbZrHfTi)C exhibits higher Vickers hardness(Approximately 28.5 GPa)and fracture toughness(Approximately 3.4 MPa⋅m^(1/2)),which can be primarily attributed to the lattice distortion and solid-solution strengthening mechanism.The study also utilizes the quasi-harmonic approximation method to predict the material’s thermophysical properties,including Debye temperature(initial value around 563 K),thermal expansion coefficient(approximately 8.9×10^(−6) K−1 at 2000 K),and other key parameters such as heat capacity at constant volume.The results show that within the studied pressure and temperature ranges,(NbZrHfTi)C consistently maintains a stable phase structure and good thermomechanical properties.The thermal expansion coefficient increasing with temperature,while heat capacity approaches the Dulong-Petit limit at elevated temperatures.These findings underscore the potential of(NbZrHfTi)C applications in ultra-high temperature thermal protection systems,cutting tool coatings,and nuclear structural materials.展开更多
The composition−property relationship of 18 quaternary high entropy diborides(HEBs)consisting of boron and IVB,VB and VIB transition metals(TM)was investigated using first-principles calculations.A valence electron co...The composition−property relationship of 18 quaternary high entropy diborides(HEBs)consisting of boron and IVB,VB and VIB transition metals(TM)was investigated using first-principles calculations.A valence electron concentration−relative electronegativity(VEC−REN)composite descriptor was developed to effectively predict the mechanical properties of HEBs.The results demonstrate that with a fixed VEC,the rise of the REN makes HEBs harder but more brittle when the electronegativity of doped TM atoms is lower than that of boron atoms.However,HEBs become softer and more ductile as REN increases if the doped TM atoms have higher electronegativity than boron atoms.The VEC−REN composite descriptor can accurately classify and predict the mechanical properties of HEBs with different components,which provides important theoretical guidance for the rapid design and development of novel high-entropy ceramic materials.展开更多
A new method was proposed for preparing AZ31/1060 composite plates with a corrugated interface,which involved cold-pressing a corrugated surface on the Al plate and then hot-pressing the assembled Mg/Al plate.The resu...A new method was proposed for preparing AZ31/1060 composite plates with a corrugated interface,which involved cold-pressing a corrugated surface on the Al plate and then hot-pressing the assembled Mg/Al plate.The results show that cold-pressing produces intense plastic deformation near the corrugated surface of the Al plate,which promotes dynamic recrystallization of the Al substrate near the interface during the subsequent hot-pressing.In addition,the initial corrugation on the surface of the Al plate also changes the local stress state near the interface during hot pressing,which has a large effect on the texture components of the substrates near the corrugated interface.The construction of the corrugated interface can greatly enhance the shear strength by 2−4 times due to the increased contact area and the strong“mechanical gearing”effect.Moreover,the mechanical properties are largely depended on the orientation relationship between corrugated direction and loading direction.展开更多
Molasses was used as an alternative binder to the bentonite binder. The change in moisture absorption by pellets prepared with different iron ores and different molasses contents were investigated. Iron ore properties...Molasses was used as an alternative binder to the bentonite binder. The change in moisture absorption by pellets prepared with different iron ores and different molasses contents were investigated. Iron ore properties exerted the major effect on pellet behavior and final pellet quality. The absorbed moisture content of pellets prepared without binder, bentonite-added pellets, and molasses-added pellets were in the range of 7.72%–9.95%, 9.62%–10.84%, and 6.14%-6.69%, respectively. The wet pellet compressive strength of molasses-added pellets(43–230 N/pellet) was superior to that of bentonite-added pellets(9.47–11.92 N/pellet). The compressive strength of dried molasses-modified pellets increased to 222–394 N/pellet, which is currently the highest value achieved for dried pellets.展开更多
文摘Candida-associated denture stomatitis (CADS) is a significant clinical concern. We have demonstrated that urethane-based denture biomaterials with 10% methacrylic acid (MAA) could bind and then slowly release antifungal drug for months. Drugs on the resins could be repeatedly quenched/recharged, and in subsequent recharging, they could be changed/switched to more potent/effective ones. However, the physical/mechanical properties and biocompatibility of the new MAA-based resins are currently unknown. The objective of the current study is to evaluate the effects of copolymerization with MAA on physical/mechanical properties and biocompatibility of urethane-based denture resin materials. MAA and diurethane dimethacrylate (UDMA) were copolymerized using initiator azobisisobutyronitrile (AIBN). Water sorption and solubility were assessed with the specifications of ISO (International Standards Organization) test method 1567, flexural strength and modulus were measured according to ASTM D-790, and biocompatibility was preliminarily evaluated in cytotoxicity assay using mouse 3T3 fibroblast cells with the trypan blue method. The results demonstrated that copolymerization of UDMA with up to 10% MAA did not negatively affect water sorption/solubility, flexural strength/modulus, and biocompatibility. With 20% MAA, however, the mechanical properties of the resulting resins were significantly decreased. To sum up, UDMA-MAA copolymers with up to 10% MAA had adequate physical/mechanical properties for denture materials with no side effects on cell viability. The UDMA-MAA denture biomaterials have a good potential to be used clinically for managing CADS and other related infectious conditions.
基金The authors are grateful for the financial support from the National Natural Science Foundation of China(Grant Nos.52225904 and 52039007)the Natural Science Foundation of Sichuan Province(Grant No.2023NSFSC0377)supported by the New Cornerstone Science Foundation through the XPLORER PRIZE.
文摘Exploring dynamic mechanical responses and failure behaviors of hot dry rock(HDR)is significant for geothermal exploitation and stability assessment.In this study,via the split Hopkinson pressure bar(SHPB)system,a series of dynamic compression tests were conducted on granite treated by cyclic thermal shocks at different temperatures.We analyzed the effects of cyclic thermal shock on the thermal-related physical and dynamic mechanical behaviors of granite.Specifically,the P-wave velocity,dynamic strength,and elastic modulus of the tested granite decrease with increasing temperature and cycle number,while porosity and peak strain increase.The degradation law of dynamic mechanical properties could be described by a cubic polynomial.Cyclic thermal shock promotes shear cracks propagation,causing dynamic failure mode of granite to transition from splitting to tensile-shear composite failure,accompanied by surface spalling and debris splashing.Moreover,the thermal shock damage evolution and coupled failure mechanism of tested granite are discussed.The evolution of thermal shock damage with thermal shock cycle numbers shows an obvious S-shaped surface,featured by an exponential correlation with dynamic mechanical parameters.In addition,with increasing thermal shock temperature and cycles,granite mineral species barely change,but the length and width of thermal cracks increase significantly.The non-uniform expansion of minerals,thermal shock-induced cracking,and water-rock interaction are primary factors for deteriorating dynamic mechanical properties of granite under cyclic thermal shock.
基金supported by the National Natural Science Foundation of China(No.52274369)the National Key Laboratory of Science and Technology on High-strength Structural Materials,China(No.623020034).
文摘Three types of Al/Al−27%Si laminated composites,each containing 22%Si,were fabricated via hot pressing and hot rolling.The microstructures,mechanical properties and thermo-physical properties of these composites were investigated.The results demonstrated that the three laminated composites exhibited similar microstructural features,characterized by well-bonded interfaces between the Al layer and the Al−27%Si alloy layer.The tensile and flexural strengths of the composites were significantly higher than those of both Al−22%Si and Al−27%Si alloys.These strengths increased gradually with decreasing the layer thickness,reaching peak values of 222.5 and 407.4 MPa,respectively.Crack deflection was observed in the cross-sections of the bending fracture surfaces,which contributed to the enhanced strength and toughness.In terms of thermo-physical properties,the thermal conductivity of the composites was lower than that of Al−22%Si and Al−27%Si alloys.The minimum reductions in thermal conductivity were 6.8%and 0.9%for the T3 laminated composite,respectively.Additionally,the coefficient of thermal expansion of the composites was improved,exhibiting varying temperature-dependent behaviors.
文摘This review aims to identify the assets and limitations of Dabema(Piptadeniastrum africanum)as a sustainable alternative to traditional timber species for furniture and construction applications.Dabema is characterized by its high density and dimensional stability,meeting ASTM(American Society for Testing and Materials)standards for mechanical strength,which is essential for promoting its use.However,its limited availability in trade and ingrained habits of use are obstacles to its widespread commercialization.In addition,thermal and oleothermal treatments have shown great potential for improving the characteristics of this wood,although they require ongoing optimization and rigorous environmental assessment.Consequently,increased awareness of the benefits of Dabema is decisive to encourage its sustainable adoption in modern economies.This could help to diversify forest resources and encourage more sustainable building practices,taking advantage of Dabema’s unique properties while mitigating environmental sustainability concerns.
基金supported by the Sichuan Science and Technology Program of China(2024NSFSC0097,2023NSFSC0004)the National Natural Science Foundation of China(42377143,52225403).
文摘The mainstream method for extracting shale gas involves hydraulic fracturing to create fracture networks.However,as extraction depth increases,notable issues such as rapid production decline,low recovery rates,high water consumption,and resource waste become apparent.Identifying new and efficient auxiliary rock-breaking technologies is crucial for overcoming these challenges.The laser,successfully utilized in industrial production,medical treatment,and technological research,offers unique features such as good directionality,coherence,and high energy density,providing novel possibilities for addressing the limitations of existing deep reservoir transformation.This research focuses on a novel laser-assisted rock-breaking technology,with shale featuring different bedding angles as the subject of investigation.The investigation methodically explored how shale responded to thermal fracture at high temperatures when exposed to laser irradiation with different spot diameter.It investigates the spatiotemporal evolution characteristics of the shale temperature field under laser irradiation,the propagation features of cracks on shale surface,and the physicochemical fracture mechanisms.The research yields the following results:(1)The region of thermal influence of the irradiation surface can be divided into three regions based on the change of rise curve of temperature in the shale surface.(2)Based on the scanning electron microscopy(SEM)testing,combined with the macroscopic and microscopic morphological characteristics of shale fracture surfaces,it reveals significantly distinct zoning characteristics in the roughness of the rock sample’s fracture surfaces after laser irradiation.(3)The thermal fracturing process of shale under laser irradiation involves chemical reactions of constituent minerals and stress generated by the thermal expansion of shale oil in the reservoir.(4)The damage and fracture of shale under the irradiation of laser show significant bedding effect,and there are three modes of rock sample failure:Pattern T(thermal failure),Pattern T-B(thermal and bedding synergistic failure),and Pattern B(bedding failure).The research findings presented in this article serve as a foundation and reference for the theory and technology of laser-assisted shale gas extraction.
基金supported by the Fundamental Research Funds for the Central Universities(No.2024-10941)China University of Mining and Technology 2024 Graduate Innovation Program Projects(No.2024WLKXJ011)+1 种基金Jiangsu Graduate Student Research and Innovation Program(No.KYCX24_2846)the National Natural Science Foundation of China(Nos.52227901 and 51934007).
文摘Physical analog modeling is an effective approach for studying the hazards of coal bursts in coal similarity criteria for physical and mechanical parameters of the actual and similar materials are crucial to yield realistic results.The derivation of similarity criteria is predominantly based on dimensional analysis,while a systematic methodology has yet to be developed.This paper attempts to fill this gap by combining the equation transformation method with similarity theory to conduct an in-depth study on the similarity criteria of physical parameters of impact coal with various internal block sizes.On this basis,the influence of internal block size of impact coal on similarity criteria was studied.Block size can provide a selection basis for similar materials,and the influence of block size on model physical parameters and similarity criteria under different geometric similarity ratios was explored.The variation laws between geometric similarity ratio,block size,and physical properties were clarified,and the similarity criteria of impact coal under the influence of block size were adjusted.New insights into material selection for physical analog modeling were proposed.The established similarity criteria for impact coal under the influence of different block sizes can provide a theoretical basis for determining various parameters in the physical analog modeling of coal bursts,when building a physical model of impact coal,material selection and size selection can be based on similarity criteria to more accurately reproduce coal explosion disasters in the laboratory.
基金supported by the National Natural Science Foundation of China(Nos.22301037, 22401045)the Natural Science Foundation of Guangdong Province(No.2022A1515110867).
文摘Eutectogels are considered to have immense application potential in the field of flexible wearable ionotronic devices because of their excellent ionic conductivity,thermal and electrochemical stability,and non-volatility.However,most existing technologies still struggle to achieve synergistic optimization of key performance indicators,such as high mechanical strength and ionic conductivity.To address this chal-lenge,this study successfully prepared a green eutectogel material with outstanding comprehensive properties by leveraging the high solubility of glycerol in a polymerizable deep eutectic solvent(DES)composed of acrylic acid and choline chloride.The resulting eutectogels exhibited a high transparency(89%),high mechanical strength(up to 2.8 MPa),and exceptional tensile performance(up to 1385%).The fabricated flexible sensor demonstrated ideal linear sensitivity(gauge factor:0.88),a broad response range(1%-100%),and reliable stability(over 1000 cycles),en-abling the precise monitoring of human motion(e.g.,finger bending and wrist rotation).The flexible strain sensor based on this eutectogel is ex-pected to show promising prospects for medical monitoring,human-machine interaction,and industrial sensing applications.
基金financial support of the National Key R&D Program of China(No.SQ2024YFA1200082)the National Natural Science Foundation of China(No.52371013)the Natural Science Foundation of Tianjin City(No.22JCZDJC00020).
文摘The rapid expansion of marine industries has created an urgent demand for advanced engineering materials with superior multifunctional performance.While Cu-Ni alloys demonstrate favorable stability and tribological characteristics,their practical applications are constrained by compromised thermal conductivity and insufficient mechanical strength due to the solid solution of a high amount of Ni in the Cu matrix.Cu-Ni matrix composites reinforced with hexagonal boron nitride(h-BN)have garnered significant attention due to their potential for tailored mechanical and thermal properties.However,challenges such as BN agglomerations in Cu-Ni matrix and poor interfacial bonding hinder their practical applications.To address these limitations,this study proposes an innovative fabrication strategy for boron nitride nanosheets(BNNSs)reinforced Cu-Ni composites by integrating the in situ synthesis of BNNSs on Cu powders via chemical vapor deposition with powder metallurgy.Benefited by the in situ strategy,BNNSs with high crystallinity distribute uniformly within the Cu matrix and have an intimate interfacial bonding without voids or other types of defects.Remarkably,the BNNSs/Cu-30%Ni composite achieves simultaneous enhancement in strength and ductility,exhibiting an ultimate tensile strength of 417 MPa and fracture elongation of 17.5%,representing 30%and 118%improvements over pure Cu-Ni alloys,respectively.This exceptional mechanical synergy originates from threefold strengthening mechanisms:grain refinement,mobile dislocation pinning,and efficient stress transfer via robust interfaces.The microstructural analysis confirms that homogenous distribution of BNNSs optimized stress distribution,mitigating strain localization in the composites.Fractographic examination demonstrates uniformly distributed dimples containing embedded BNNSs,indicative of effective crack bridging and deflection during failure.Furthermore,the composite possesses excellent corrosion resistance comparable to matrix alloys,while achieving 21.23%enhancement in thermal conductivity and 20%reduction in coefficient of friction.The scalable fabrication protocol successfully resolves longstanding challenges in BNNSs dispersion and interfacial bonding,offering a viable pathway for designing high-performance CMCs for marine applications.
文摘Coral sand is a unique material developed in the tropical ocean environment, which is mainly composed of coral and other marine organism debris, with the CaCO3 content up to 96 %. It has special physical and mechanical properties due to its composition, structure and sedimentary environment. In this contribution, we discuss its specific gravity, porosity ratio compressibility, crushing, shearing and intensity for coral sand samples from the Nansha islands based on laboratory mechanical tests. Our results show distinct high porosity ratio, high friction angle and low intensity as compared with the quartz sand. We believe that grain crushing is the main factor that influences the deformation and strength of coral sand. Comprehensive study on the physical and mechanical properties of coral sands is significant in providing reliable scientific parameters to construction on coral islet, and thus avoids accidents in construction.
文摘The physical-mechanical properties of Populus x canadensis Moench and Populus x euramericana （Dode） Guinier cv. Gelrica were studied to provide theoret- ical and scientific bases for the directional breeding and efficient use of artificial forests with P. canadensis and P. euramericana Gelrica. The results showed the air-dried density, basic density of P. canadensis were 0.468 g/cm3 and 0.372 g/cm3, respectively; the shrinkage coefficient of radial, tangential and volume were 0.133%, 0.270% and 0.553%, respectively;the modulus of elasticity in static bending, the bending strength and the compressive strength parallel to grain were 9 302.99 MPa, 79.69 MPa and 40.32 Mpa, respectively. As for the P. euramericana Gelrica, the air-dried density, basic densitywere 0.453 and 0.355 g/cm3, respectively; the shrink- age coefficient of radial, tangential and volume were 0.205%, 0.304% and 0.554%, respectively; the modulus of elasticity in static bending, the bending strength and the compressive strength parallel to grain were 9 014.44, 55.87 and 33.09 Mpa respectively. Comprehensive analysis of the indicators showed that the properties of P. canadensis were better than those of P.euramericana Gelrica.
基金supported by the National Science Foundation for Distinguished Young Scholars of China(Grant No.12425209)the National Natural Science Foundation of China(Grant No.U20A20390,11827803,12172034,11822201,62004056,62104058,62271269).
文摘Neuromorphic devices have shown great potential in simulating the function of biological neurons due to their efficient parallel information processing and low energy consumption.MXene-Ti_(3)C_(2)T_(x),an emerging twodimensional material,stands out as an ideal candidate for fabricating neuromorphic devices.Its exceptional electrical performance and robust mechanical properties make it an ideal choice for this purpose.This review aims to uncover the advantages and properties of MXene-Ti_(3)C_(2)T_(x)in neuromorphic devices and to promote its further development.Firstly,we categorize several core physical mechanisms present in MXene-Ti_(3)C_(2)T_(x)neuromorphic devices and summarize in detail the reasons for their formation.Then,this work systematically summarizes and classifies advanced techniques for the three main optimization pathways of MXene-Ti_(3)C_(2)T_(x),such as doping engineering,interface engineering,and structural engineering.Significantly,this work highlights innovative applications of MXene-Ti_(3)C_(2)T_(x)neuromorphic devices in cutting-edge computing paradigms,particularly near-sensor computing and in-sensor computing.Finally,this review carefully compiles a table that integrates almost all research results involving MXene-Ti_(3)C_(2)T_(x)neuromorphic devices and discusses the challenges,development prospects,and feasibility of MXene-Ti_(3)C_(2)T_(x)-based neuromorphic devices in practical applications,aiming to lay a solid theoretical foundation and provide technical support for further exploration and application of MXene-Ti_(3)C_(2)T_(x)in the field of neuromorphic devices.
基金supported by the National Natural Science Foundation of China (Grant Nos.T2325004 and 52161160330)the National Natural Science Foundation of China (Grants No.12504233)+2 种基金Advanced MaterialsNational Science and Technology Major Project (Grant No.2024ZD0606900)the Talent Hub for “AI+New Materials” Basic Researchthe Key Research and Development Program of Ningbo (Grant No.2025Z088)。
文摘The functional properties of glasses are governed by their formation history and the complex relaxation processes they undergo.However,under extreme conditions,glass behaviors are still elusive.In this study,we employ simulations with varied protocols to evaluate the effectiveness of different descriptors in predicting mechanical properties across both low-and high-pressure regimes.Our findings demonstrate that conventional structural and configurational descriptors fail to correlate with the mechanical response following pressure release,whereas the activation energy descriptor exhibits robust linearity with shear modulus after correcting for pressure effects.Notably,the soft mode parameter emerges as an ideal and computationally efficient alternative for capturing this mechanical behavior.These findings provide critical insights into the influence of pressure on glassy properties,integrating the distinct features of compressed glasses into a unified theoretical framework.
基金supported by the National Natural Science Foundation of China,No.82072529(to HWHT)Key Laboratory of Guangdong Higher Education Institutes,No.2021KSYS009(to HWHT)the China Postdoctoral Science Foundation,No.2022M720907(to HHG)。
文摘Alzheimer's disease is the primary cause of dementia and imposes a significant socioeconomic burden globally.Physical exercise,as an effective strategy for improving general health,has been largely reported for its effectiveness in slowing neurodegeneration and increasing brain functional plasticity,particularly in aging brains.However,the underlying mechanisms of exercise in cognitive aging remain largely unclear.Adiponectin,a cell-secreted protein hormone,has recently been found to regulate synaptic plasticity and mediate the antidepressant effects of physical exercise.Studies on the neuroprotective effects of adiponectin have revealed potential innovative treatments for Alzheimer's disease.Here,we reviewed the functions of adiponectin and its receptor in the brains of human and animal models of cognitive impairment.We summarized the role of adiponectin in Alzheimer's disease,focusing on its impact on energy metabolism,insulin resistance,and inflammation.We also discuss how exercise increases adiponectin secretion and its potential benefits for learning and memory.Finally,we highlight the latest research on chemical compounds that mimic exerciseenhanced secretion of adiponectin and its receptor in Alzheimer's disease.
基金supported by the NSFC(12474071)Natural Science Foundation of Shandong Province(ZR2024YQ051)+5 种基金Open Research Fund of State Key Laboratory of Materials for Integrated Circuits(SKLJC-K2024-12)the Shanghai Sailing Program(23YF1402200,23YF1402400)Natural Science Foundation of Jiangsu Province(BK20240424)Taishan Scholar Foundation of Shandong Province(tsqn202408006)Young Talent of Lifting engineering for Science and Technology in Shandong,China(SDAST2024QTB002)the Qilu Young Scholar Program of Shandong University.
文摘The advancement of flexible memristors has significantly promoted the development of wearable electronic for emerging neuromorphic computing applications.Inspired by in-memory computing architecture of human brain,flexible memristors exhibit great application potential in emulating artificial synapses for highefficiency and low power consumption neuromorphic computing.This paper provides comprehensive overview of flexible memristors from perspectives of development history,material system,device structure,mechanical deformation method,device performance analysis,stress simulation during deformation,and neuromorphic computing applications.The recent advances in flexible electronics are summarized,including single device,device array and integration.The challenges and future perspectives of flexible memristor for neuromorphic computing are discussed deeply,paving the way for constructing wearable smart electronics and applications in large-scale neuromorphic computing and high-order intelligent robotics.
基金financial support by the National Key Research and Development Program of China(No.2023YFC2907801)the Hunan Provincial Natural Science Foundation of China(No.2023JJ40760)the Scientific and Technological Project of Yunnan Precious Metals Laboratory,China(No.YPML-2023050276)。
文摘Bentonite is a necessary binder in producing pellets.Its excessive use reduces the iron grade of pellets and increases production costs.Minimizing bentonite dosage is essential for producing high-quality iron ore pellets.Addressing the gap in the application of organically-intercalated modified bentonite in the pelletizing field,this study introduces an innovative modification process for bentonite that employs the synergistic effect of mechanical force and dimethyl sulfoxide to enhance the intercalation of organic compounds within bentonite,thus significantly enhancing its binding performance.The colloid value and swell capacity of modified bentonite(98.5 m L/3g and 55.0 m L/g)were much higher than the original bentonite(90.5 m L/3g and 17.5 m L/g).With the decrease of bentonite dosage from1.5wt%to 1.0wt%,the drop number of green pellets from a height of 0.5 m and the compressive strengths of roasted pellets using the modified bentonite(6.0 times and 2916 N per pellet)were significantly higher than those of the original bentonite(4.0 times and 2739 N per pellet).This study provides a comprehensive analysis of the intercalation modification mechanism of bentonite,offering crucial technical insights for the development of high-performance modified bentonite as iron ore pellet binders.
基金supported by the National Natural Science Foundation of China(Nos.92166105 and 52005053)High-Tech Industry Science and Technology Innovation Leading Program of Hunan Province(No.2020GK2085)the Science and Technology Innovation Program of Hunan Province(No.2021RC3096).
文摘(NbZrHfTi)C high-entropy ceramics,as an emerging class of ultra-high-temperature materials,have garnered significant interest due to their unique multi-principal-element crystal structure and exceptional hightemperature properties.This study systematically investigates the mechanical properties of(NbZrHfTi)C high-entropy ceramics by employing first-principles density functional theory,combined with the Debye-Grüneisen model,to explore the variations in their thermophysical properties with temperature(0–2000 K)and pressure(0–30 GPa).Thermodynamically,the calculated mixing enthalpy and Gibbs free energy confirm the feasibility of forming a stable single-phase solid solution in(NbZrHfTi)C.The calculated results of the elastic stiffness constant indicate that the material meets the mechanical stability criteria of the cubic crystal system,further confirming the structural stability.Through evaluation of key mechanical parameters—bulk modulus,shear modulus,Young’s modulus,and Poisson’s ratio—we provide comprehensive insight into the macro-mechanical behaviour of the material and its correlation with the underlying microstructure.Notably,compared to traditional binary carbides and their average properties,(NbZrHfTi)C exhibits higher Vickers hardness(Approximately 28.5 GPa)and fracture toughness(Approximately 3.4 MPa⋅m^(1/2)),which can be primarily attributed to the lattice distortion and solid-solution strengthening mechanism.The study also utilizes the quasi-harmonic approximation method to predict the material’s thermophysical properties,including Debye temperature(initial value around 563 K),thermal expansion coefficient(approximately 8.9×10^(−6) K−1 at 2000 K),and other key parameters such as heat capacity at constant volume.The results show that within the studied pressure and temperature ranges,(NbZrHfTi)C consistently maintains a stable phase structure and good thermomechanical properties.The thermal expansion coefficient increasing with temperature,while heat capacity approaches the Dulong-Petit limit at elevated temperatures.These findings underscore the potential of(NbZrHfTi)C applications in ultra-high temperature thermal protection systems,cutting tool coatings,and nuclear structural materials.
基金the National Natural Science Foundation of China (Nos. 52071179, 52271033)the Key Program of National Natural Science Foundation of China (No. 51931003)+2 种基金the Natural Science Foundation of Jiangsu Province, China (No. BK20221493)the Jiangsu Province Leading Edge Technology Basic Research Major Project, China (No. BK20222014)the Foundation of “Qinglan Project” for Colleges and Universities in Jiangsu Province, China。
文摘The composition−property relationship of 18 quaternary high entropy diborides(HEBs)consisting of boron and IVB,VB and VIB transition metals(TM)was investigated using first-principles calculations.A valence electron concentration−relative electronegativity(VEC−REN)composite descriptor was developed to effectively predict the mechanical properties of HEBs.The results demonstrate that with a fixed VEC,the rise of the REN makes HEBs harder but more brittle when the electronegativity of doped TM atoms is lower than that of boron atoms.However,HEBs become softer and more ductile as REN increases if the doped TM atoms have higher electronegativity than boron atoms.The VEC−REN composite descriptor can accurately classify and predict the mechanical properties of HEBs with different components,which provides important theoretical guidance for the rapid design and development of novel high-entropy ceramic materials.
基金supported by Guangdong Major Project of Basic and Applied Basic Research, China (No. 2020B0301030006)Fundamental Research Funds for the Central Universities, China (No. SWU-XDJH202313)+1 种基金Chongqing Postdoctoral Science Foundation Funded Project, China (No. 2112012728014435)the Chongqing Postgraduate Research and Innovation Project, China (No. CYS23197)。
文摘A new method was proposed for preparing AZ31/1060 composite plates with a corrugated interface,which involved cold-pressing a corrugated surface on the Al plate and then hot-pressing the assembled Mg/Al plate.The results show that cold-pressing produces intense plastic deformation near the corrugated surface of the Al plate,which promotes dynamic recrystallization of the Al substrate near the interface during the subsequent hot-pressing.In addition,the initial corrugation on the surface of the Al plate also changes the local stress state near the interface during hot pressing,which has a large effect on the texture components of the substrates near the corrugated interface.The construction of the corrugated interface can greatly enhance the shear strength by 2−4 times due to the increased contact area and the strong“mechanical gearing”effect.Moreover,the mechanical properties are largely depended on the orientation relationship between corrugated direction and loading direction.
文摘Molasses was used as an alternative binder to the bentonite binder. The change in moisture absorption by pellets prepared with different iron ores and different molasses contents were investigated. Iron ore properties exerted the major effect on pellet behavior and final pellet quality. The absorbed moisture content of pellets prepared without binder, bentonite-added pellets, and molasses-added pellets were in the range of 7.72%–9.95%, 9.62%–10.84%, and 6.14%-6.69%, respectively. The wet pellet compressive strength of molasses-added pellets(43–230 N/pellet) was superior to that of bentonite-added pellets(9.47–11.92 N/pellet). The compressive strength of dried molasses-modified pellets increased to 222–394 N/pellet, which is currently the highest value achieved for dried pellets.
