The continuous supply of phosphorus(P)is indispensable in crop production.However,P resources are non-renewable,and environmental concerns like eutrophication associated with its loss from agroecosystems make the sust...The continuous supply of phosphorus(P)is indispensable in crop production.However,P resources are non-renewable,and environmental concerns like eutrophication associated with its loss from agroecosystems make the sustainable management of P resources essential for ensuring global food security.This study was designed to reduce mineral P inputs through management practices.A field experiment comprising a wheat-maize rotation system was conducted in the Guanzhong Plain of Shaanxi Province,China from 2018-2023.The eight treatments included CK(without P),FP(conventional P application);RP(recommended P);RP80(20% reduction in RP);SRP80(20% reduction in RP with straw wrapping);ARP80(20% reduction in RP with ammonium sulfate instead of urea);SARP80(20% reduction in RP with straw wrapping and ammonium sulfate instead of urea);and SARP60(40% reduction in RP with straw wrapping and ammonium sulfate instead of urea).Crop yield,P uptake,and P fertilizer use efficiency were measured during harvest and throughout the entire period of the study.At the end of the experiment,P fractions were estimated using the Tiessen-Moir P classification method.The results revealed that the grain yields of all the treatments except for RP80 were significantly increased compared to CK,with increases of 14.9-28.8%.Furthermore,agronomic efficiency,apparent P use efficiency,P recovery rate,and partial factor productivity were significantly improved for the treatments that received 20% less P with straw wrapping.Moreover,the enhancement measures significantly increased labile and moderately labile P in the soil.Therefore,straw wrapping with ammonium sulfate instead of urea is one of the most effective ways to reduce mineral P inputs while increasing the efficiency of P in wheat-maize rotation systems.展开更多
Violet phosphorus,a recently explored layered elemental semiconductor,has attracted much attention due to its unique photoelectric,mechanical properties,and high hole mobility.Herein,violet arsenic phosphorus has for ...Violet phosphorus,a recently explored layered elemental semiconductor,has attracted much attention due to its unique photoelectric,mechanical properties,and high hole mobility.Herein,violet arsenic phosphorus has for the first time been synthesized by a molten lead method.The crystal structure of violet arsenic phosphorus(P^(83.4)As_(0.6),CSD-2408761)was determined by single crystal X-ray diffraction to have similar structure as that of violet phosphorus,where P12 is occupied by arsenic/phosphorus(As/P)atoms as mixed occupancy sites As1/P12.The arsenic substitution has been demonstrated to tune the band structure of violet phosphorus,switching p-type of violet phosphorus to high-performance n-type violet arsenic phosphorus.The effective electron mass along the<010>direction is significantly reduced from 1.792 to 0.515 m_(0)by arsenic substitution,resulting in an extremely high electron mobility of 2622.503 cm^(2)V^(-1)s^(-1).The field effect transistor built with P_(83.4)As_(0.6)nanosheets was measured to have a high electron mobility(137.06 cm^(2)V^(-1)s^(-1),61.2 nm),even under ambient conditions for 5 h,much higher than the hole mobility of violet phosphorene nanosheets(4.07 cm^(2)V^(-1)s^(-1),73.3 nm).This work provides a new idea for designing phosphorus-based materials for field effect transistors,giving significant potential in complementary metal-oxide-semiconductor applications.展开更多
The large volume expansion and rapid capacity attenuation of tin-based electrodes are the main factors limiting their commercial application.The reasonable design of electrode material structure is particularly import...The large volume expansion and rapid capacity attenuation of tin-based electrodes are the main factors limiting their commercial application.The reasonable design of electrode material structure is particularly important for improving its electrochemical performance.Herein,phosphorus-modified graphene encapsulated Sn_(6)O_(4)(OH)_(4)nanoparticles composite(P-Sn_(6)O_(4)(OH)_(4)@RGO)with crystalline-amorphous heterostructure has been successfully designed and prepared.The design of crystalline-amorphous structure has largely enhanced the active sites,and the construction of a graphene encapsulation structure has greatly alleviated volume expansion.Notably,P-Sn_(6)O_(4)(OH)_(4)@RGO obtained an excellent high-rate longterm cycling performance for lithium-ion batteries anode,reaching a high specific capacity of 970 m Ah/g at 1.0 A/g after 1450 cycles.This work demonstrates that restructuring the electrode material's structure and phase through phosphorus modification can effectively improve the electrochemical performance of tin-based electrode materials.展开更多
Phosphorus(P)is an essential nutrient for crop growth,making it important for maintaining food security as the global population continues to increase.Plants acquire P primarily via the uptake of inorganic phosphate(P...Phosphorus(P)is an essential nutrient for crop growth,making it important for maintaining food security as the global population continues to increase.Plants acquire P primarily via the uptake of inorganic phosphate(Pi)in soil through their roots.Pi,which is usually sequestered in soils,is not easily absorbed by plants and represses plant growth.Plants have developed a series of mechanisms to cope with P deficiency.Moreover,P fertilizer applications are critical for maximizing crop yield.Maize is a major cereal crop cultivated worldwide.Increasing its P-use efficiency is important for optimizing maize production.Over the past two decades,considerable progresses have been achieved in studies aimed at adapting maize varieties to changes in environmental P supply.Here,we present an overview of the morphological,physiological,and molecular mechanisms involved in P acquisition,translocation,and redistribution in maize and combine the advances in Arabidopsis and rice,to better elucidate the progress of P nutrition.Additionally,we summarize the correlation between P and abiotic stress responses.Clarifying the mechanisms relevant to improving P absorption and use in maize can guide future research on sustainable agriculture.展开更多
Rice-fish coculture(RFC)has aroused extensive concern for its contribution to food security and resource conservation,but whether it can improve soil phosphorus(P)availability and affect microbe-mediated P turnover re...Rice-fish coculture(RFC)has aroused extensive concern for its contribution to food security and resource conservation,but whether it can improve soil phosphorus(P)availability and affect microbe-mediated P turnover remains elusive.Herein,we conducted a microcosm experiment to assess the impacts of RFC combined with(50 mg P kg^(-1)as KH2PO4)and without inorganic P addition on P fractions,P availability,and phoD-harboring bacterial community composition.The results revealed that RFC without P addition significantly improved P availability and phosphatase activity in paddy soil,while soil available P(AP),pH,and microbial biomass P(MBP)contributed to regulating P fractions.Moreover,the phoD-harboring bacterial abundance was linked to phosphatase activity,AP,total carbon(TC),and total P(TP)contents,and the ratios of TC to total nitrogen(TN)and TN to TP.We also found that the keystone taxa of phoD-harboring bacteria contributed to phosphatase production as well as organic P mineralization,thereby improving P availability.Our findings suggest that RFC without P addition is beneficial for promoting the expression of phoD-harboring bacterial functions to improve the capacity of P mineralization.Overall,our study provides insights into the responses of phoD-harboring bacterial functions for P turnover to RFC combined with and without P addition,showing the potential utilization of P resources in agricultural soil and the contribution of phosphatase activity to P acquisition in agriculture ecosystem.展开更多
Utilizing phosphorus tailings as the raw material for foam concrete is a key approach to achieving sustainable and efficient resource utilization.During the preparation of phosphorus tailings-based foam concrete,slurr...Utilizing phosphorus tailings as the raw material for foam concrete is a key approach to achieving sustainable and efficient resource utilization.During the preparation of phosphorus tailings-based foam concrete,slurry performance is critical to the successful production.Phosphorus tailings,cement and microsilica were used to prepare foam concrete slurry in this study.A rheometer was employed as a test tool to measure the variation of linear viscoelastic zone(LVR),viscosity,and yield stress of the slurries with different cement contents.The results indicate that the phosphorus tailings-cement-microsilica slurry exhibits shear-thinning properties,which aligns well with the Herschel-Bulkley model,showing a high degree of correlation.As the cement content increases,the energy storage modulus of the slurry rises,and the LVR length shows a nonlinear trend.The LVR reaches its maximum length of 0.04%when the cement content is 6 mass%or 8 mass%.The increment of the cement content leads to a more intricate internal network structure,which hinders the reconstruction rate of the flocculated structure after high-shear deformation.展开更多
Exploiting non-precious metal catalysts with excellent oxygen reduction reaction(ORR)performance for energy devices is paramount essential for the green and sustainable society development.Herein,low-cost,high-perform...Exploiting non-precious metal catalysts with excellent oxygen reduction reaction(ORR)performance for energy devices is paramount essential for the green and sustainable society development.Herein,low-cost,high-performance biomass-derived ORR catalysts with an asymmetric Fe-N_(3)P configuration was prepared by a simple pyrolysis-etching technique,where carboxymethyl cellulose(CMC)was used as the carbon source,urea and 1,10-phenanthroline iron complex(FePhen)as additives,and Na_(3)PO_(4)as the phosphorus dopant and a pore-forming agent.The CMC-derived FeNPC catalyst displayed a large specific area(BET:1235 m^(2)g^(-1))with atomically dispersed Fe-N_(3)P active sites,which exhibited superior ORR activity and stability in alkaline solution(E_(1/2)=0.90 V vs.RHE)and Zn-air batteries(P_(max)=149 mW cm^(-2))to commercial Pt/C catalyst(E_(1/2)=0.87 V,P_(max)=118 mW cm^(-2))under similar experimental conditions.This work provides a feasible and costeffective route toward highly efficient ORR catalysts and their application to Zn-air batteries for energy conversion.展开更多
With the objective of investigating the basis of phosphorus(P)utilization efficiency(PUE),physiological and morphological traits,two P-efficient and two P-inefficient rapeseed(Brassica napus L.)cultivars were compared...With the objective of investigating the basis of phosphorus(P)utilization efficiency(PUE),physiological and morphological traits,two P-efficient and two P-inefficient rapeseed(Brassica napus L.)cultivars were compared at the seedling stage.P-efficient cultivars showed root morphological adaptation,high P uptake activity,and greater phospholipid degradation under low P stress.Improving root morphological adaptation and reducing lipid-P allocation could allow increasing PUE in rapeseed seedlings.展开更多
The leaf nitrogen(N)to phosphorus(P)ratio(N:P)is a critical indicator of nutrient dynamics and ecosystem function.Investigating temporal variations in leaf N:P can provide valuable insights into how plants adapt to en...The leaf nitrogen(N)to phosphorus(P)ratio(N:P)is a critical indicator of nutrient dynamics and ecosystem function.Investigating temporal variations in leaf N:P can provide valuable insights into how plants adapt to environmental changes and nutrient availability.However,limited research has been conducted on long-term temporal leaf N:P variation over a range of temperature zones.Using long-term monitoring data from the Chinese Ecosystem Research Network(CERN),we investigated temporal changes in leaf N and P stoichiometry for 50 dominant tree species from 10 typical forest sites across temperate and subtropical regions,and identified the underlying mechanisms driving these changes.For both regions combined,leaf P concentration of the 50 dominant tree species decreased(20.6%),whereas leaf N:P increased(52.0%)from 2005 to 2020.Leaf P decreased and leaf N:P increased in 67% and 69% of the tree species,respectively.The leaf N:P increase was primarily driven by the tree species in eastern subtropical forests,where global change factors and soil nutrients explained 68% of leaf N:P variation.The P limitation exhibited by tree species in eastern subtropical forest ecosystems intensified over time,and elevated temperature and CO_(2) levels,coupled with decreased soil available P concentrations,appear to be the main factors driving long-term leaf N:P increases in these forests.Investigating long-term variations in soil nutrients together with global change factors will improve our understanding of the nutrient status of forest ecosystems in the context of global change and will support effective forest ecosystem management.展开更多
The rapidly growing demand for lithium iron phosphate(LiFePO_(4))as the cathode material of lithium-ion batteries(LIBs)has aggravated the scarcity of phosphorus(P)reserves on Earth.This study introduces an environment...The rapidly growing demand for lithium iron phosphate(LiFePO_(4))as the cathode material of lithium-ion batteries(LIBs)has aggravated the scarcity of phosphorus(P)reserves on Earth.This study introduces an environmentally friendly and economical method of P recovery from municipal wastewater,providing the P source for LiFePO_(4) cathodes.The novel approach utilizes the sludge of Fe-coagulant-based chemical P removal(CPR)in wastewater treatment.After a sintering treatment with acid washing,the CPR sludge,enriched with P and Fe,transforms into purified P-Fe oxides(Fe2.1P1.0O5.6).These oxides can substitute up to 35%of the FePO_(4) reagent as precursor,producing a carbon-coated LiFePO_(4)(LiFePO_(4)/C)cathode with a specific discharge capacity of 114.9 mA·h·g^(-1)at current density of 17 mA·g^(-1)),and cycle stability of 99.2%after 100 cycles.The enhanced cycle performance of the as-prepared LiFePO_(4)/C cathode may be attributed to the incorporations of impurities(such as Ca^(2+)and Na^(+))from sludge,with improved stability of crystal structure.Unlike conventional P-fertilizers,this P recovery technology converts 100%of P in CPR sludge into the production of value-added LiFePO_(4)/C cathodes.The recovered P from municipal wastewater can meet up to 35%of the P demand in the Chinese LIBs industry,offering a cost-effective solution for addressing the pressing challenges of P scarcity.展开更多
Whilst phosphorus(P)in soil is considered to be abundant,the portion available for plant uptake constitutes less than 1%of the overall P present.To enhance crop productivity,the utilization of mineral P fertilizers ha...Whilst phosphorus(P)in soil is considered to be abundant,the portion available for plant uptake constitutes less than 1%of the overall P present.To enhance crop productivity,the utilization of mineral P fertilizers has become pervasive in agriculture.Nonetheless,the escalating prices of chemical fertilizers,coupled with new European regulations prohibiting the use of P fertilizers containing cadmium,have highlighted the urgency to identify environmentally friendly products and practices for P fertilization in agricultural soils.This comprehensive review delves into the current landscape of P fertilization from agricultural,political,and economic standpoints.We recognize the potential of microbes in mobilizing P,but emphasize the necessity for more robust research to establish their effectiveness in promoting plant P uptake under real-world conditions.Additionally,we explore the role of agricultural conservation practices,such as optimal tillage,diversified cropping systems,and increased organic carbon input,in conserving P.Furthermore,this review contemplates forthcoming innovations in research.These innovations encompass the development of enhanced formulations for biofertilizers and the undertaking of more comprehensive studies within the realm of conservation agriculture.All these endeavors collectively hold the potential to augment P accessibility to plants in a sustainable manner,thereby advancing agricultural sustainability and productivity.展开更多
China’s lowland rural rivers are facing severe eutrophication problems due to excessive phosphorus(P)from anthropogenic activities.However,quantifying P dynamics in a lowland rural river is challenging due to its com...China’s lowland rural rivers are facing severe eutrophication problems due to excessive phosphorus(P)from anthropogenic activities.However,quantifying P dynamics in a lowland rural river is challenging due to its complex interaction with surrounding areas.A P dynamic model(River-P)was specifically designed for lowland rural rivers to address this challenge.This modelwas coupled with the Environmental Fluid Dynamics Code(EFDC)and the Phosphorus Dynamic Model for lowland Polder systems(PDP)to characterize P dynamics under the impact of dredging in a lowland rural river.Based on a two-year(2020-2021)dataset from a representative lowland rural river in the Lake Taihu Basin,China,the coupled model was calibrated and achieved a model performance(R^(2)>0.59,RMSE<0.04 mg/L)for total P(TP)concentrations.Our research in the study river revealed that(1)the time scale for the effectiveness of sediment dredging for P control was~300 days,with an increase in P retention capacity by 74.8 kg/year and a decrease in TP concentrations of 23%after dredging.(2)Dredging significantly reduced P release from sediment by 98%,while increased P resuspension and settling capacities by 16%and 46%,respectively.(3)The sediment-water interface(SWI)plays a critical role in P transfer within the river,as resuspension accounts for 16%of TP imports,and settling accounts for 47%of TP exports.Given the large P retention capacity of lowland rural rivers,drainage ditches and ponds with macrophytes are promising approaches to enhance P retention capacity.Our study provides valuable insights for local environmental departments,allowing a comprehensive understanding of P dynamics in lowland rural rivers.This enable the evaluation of the efficacy of sediment dredging in P control and the implementation of corresponding P control measures.展开更多
Ischemic stroke is the leading cause of death in China,accounting for approximately one-third of all stroke-associated deaths worldwide.Currently,thrombolysis is employed for ischemic strokes.However,due to the limite...Ischemic stroke is the leading cause of death in China,accounting for approximately one-third of all stroke-associated deaths worldwide.Currently,thrombolysis is employed for ischemic strokes.However,due to the limited therapeutic window of thrombolytic agents,most patients do not receive the drug at the right time.Moreover,these agents are associated with risks of hemorrhage and reperfusion damage.Herein,Angiopep-2(ANG)-black phosphorus(BP)-resveratrol(RES),a drug-loaded system,was used to deliver drugs across the blood–brain barrier(BBB).ANG-BP-RES has a uniform size,stable structure,good photothermal effect,and strong drug release ability under near-infrared(NIR)irradiation and acidic conditions.Furthermore,ANG-BP-RES can efficiently target the brain and improve BBB permeability,exerting a significant therapeutic effect against ischemic brain injury,especially after NIR irradiation.ANG-BP-RES is also biocompatible and shows minimal toxicity toward cells and tissues.This study offers novel insights into the therapeutic management of ischemic brain injury.展开更多
The interaction mechanism between eggshell calcium and endogenous silica in biomass during biochar modification,and its impact on phosphate adsorption performance and slow-release fertilizer characteristics,remains un...The interaction mechanism between eggshell calcium and endogenous silica in biomass during biochar modification,and its impact on phosphate adsorption performance and slow-release fertilizer characteristics,remains unexplored.This study investigates that high silica content in biomass(>6%)inhibits the decomposition of CaCO_(3)in eggshells during pyrolysis,reducing the formation of active calcium species(CaO and Ca(OH)_(2)),while moderate silica levels(4%-5%)promote the formation of CaSiO_(3),enhancing phosphorus adsorption without hindering Ca^(2+)activation.Adsorption studies reveal that the precipitation of Ca_(5)(PO_(4))_(3)(OH)resulting from the combination of CaO and Ca(OH)_(2)with phosphate is the primary and effective form for phosphorus removal in calcium-modified adsorbents,accompanied by Ca_(3)(PO_(4))_(2)·2H_(2)O precipitation formed by CaSi O_(3).Eggshell calcium-modified corn straw biochar(ECS)exhibited the highest adsorption capacity,reaching 123.3 mg/g,outperforming materials in previous studies.ECS also demonstrated excellent pH adaptability and selective phosphate removal.As a biochar-based phosphorus fertilizer,ECS-P exhibits high phosphorus extractability in formic acid(93.92%)but low water solubility(0.62%),with phosphorus release during the seven-day intermittent leaching experiment remaining between 0.53 to 0.875 mg/L.These results confirm its potential as a phosphorus cycling fertilizer.This study provides fundamental insights into optimizing biomass selection based on silica content for calcium modification,offering an efficient strategy for both phosphate recovery and slow-release fertilizer development.展开更多
Black phosphorus(BP)is recognized as a promising anode for sodium-ion batteries(SIBs)due to its high safety and theoretical capacity.However,traditional ball milling methodologies for fabricating BP composite anodes h...Black phosphorus(BP)is recognized as a promising anode for sodium-ion batteries(SIBs)due to its high safety and theoretical capacity.However,traditional ball milling methodologies for fabricating BP composite anodes have not satisfactorily addressed the challenges of poor rate performance and short cycle life.To fill this scientific gap,we herein pioneer incorporating the sodium fast ionic conductorβ"-Al_(2)O_(3)into ball-milled BP with carbon,which facilitates the formation of three-dimensional mass transfer channels in the resulting composite.To stabilize these channels,we develop a novel and environmentally friendly functional binder that outperforms traditional binders in thermal stability,wettability,and mechanical properties.The newly established binder is capable of remarkably mitigating volume expansion and interfacial side reactions in the BP/β"-Al_(2)O_(3)/C composite anode.Additionally,we identify synergistic effects of the binder interacting with the BP/β"-Al_(2)O_(3)/C composite during cycling,characterized by the in-situ formation of P-O-C bonds,which is the first instance of a strong,durable chemical bond between the binder and the active material to the best of our knowledge.These advancements allow the composite electrode to exhibit exceptional sodium storage,including high initial Coulombic efficiency and long-term cycling stability,which surpasses most previous phosphorus-based anodes fabricated via traditional approaches.Notably,when paired with a Na_(4)Fe_(3)(PO_(4))_(2)P_(2)O_7(NFPP)cathode,the full cell exhibits unexpectedly high energy and power densities,highlighting the BP potential in SIBs.The findings presented in the present work contribute to the promotion of economical and efficient applications of phosphorus-based anode materials.展开更多
Although bimetallic phosphide cocatalysts have attracted considerable interest in photocatalysis research owing to their advantageous thermodynamic characteristics,superstable and efficient cocatalysts have rarely bee...Although bimetallic phosphide cocatalysts have attracted considerable interest in photocatalysis research owing to their advantageous thermodynamic characteristics,superstable and efficient cocatalysts have rarely been produced through the modulation of their structure and composition.In this study,a series of bimetallic nickel-iron phosphide(Ni_(x)Fe_(2-x)P,where 0<x<2)cocatalysts with controllable structures and overpotentials were designed by adjusting the atomic ratio of Ni/Fe onto nonmetallic elemental red phosphorus(RP)for the photocatalytic selective oxidation of benzyl alcohol(BA)coupled with hydrogen production.The catalysts exhibited an outstanding photocatalytic activity for benzaldehyde and a high H_(2)yield.The RP regulated by bimetallic phosphide cocatalysts(Ni_(x)Fe_(2-x)P)demonstrated higher photocatalytic oxidation-reduction activity than that regulated by monometallic phosphide cocatalysts(Ni_(2)P and Fe2P).In particular,the RP regulated by Ni_(1.25)Fe_(0.75)P exhibited the best photocatalytic performance.In addition,experimental and theoretical calculations further illustrated that Ni_(1.25)Fe_(0.75)P,with the optimized electronic structure,possessed good electrical conductivity and provided strong adsorption and abundant active sites,thereby accelerating electron migration and lowering the reaction energy barrier of RP.This finding offers valuable insights into the rational design of highly effective cocatalysts aimed at optimizing the photocatalytic activity of composite photocatalysts.展开更多
Atropisomeric phosphines are crucial for asymmetric catalysis but remain synthetically challenging.Herein,an N-heterocyclic carbene(NHC)catalyzed esterification reaction of dialdehydes with arylboronic acids was devel...Atropisomeric phosphines are crucial for asymmetric catalysis but remain synthetically challenging.Herein,an N-heterocyclic carbene(NHC)catalyzed esterification reaction of dialdehydes with arylboronic acids was developed,successfully constructing the framework of axially chiral phosphorus compounds.Mechanistic studies have revealed that the reaction initially undergoes a desymmetrization process,followed by a kinetic resolution pathway,affording a series of axially chiral phosphorus compounds with high enantioselectivity(up to 92%ee).展开更多
By simplifying catalyst-product separation and reducing phosphorus waste,heterogeneous hydroformylation offers a more sustainable alternative to homogeneous processes.However,heterogeneous hydroformylation catalysts d...By simplifying catalyst-product separation and reducing phosphorus waste,heterogeneous hydroformylation offers a more sustainable alternative to homogeneous processes.However,heterogeneous hydroformylation catalysts developed thus far still suffer from the issues of much lower activity and metal leaching,which severely hinder their practical application.Here,we demonstrate that incorporating phosphorus(P)atoms into graphitic carbon nitride(PCN)supports facilitates charge transfer from Rh to the PCN support,thus largely enhancing electronic metal-support interactions(EMSIs).In the styrene hydroformylation reaction,the activity of Rh_(1)/PCN single-atom catalysts(SACs)with varying P contents exhibited a volcano-shaped relationship with P doping,where the Rh_(1)/PCN SAC with optimal P doping showed exceptional activity,approximately 5.8-and 3.3-fold greater than that of the Rh_(1)/g-C_(3)N_(4)SAC without P doping and the industrial homogeneous catalyst HRh(CO)(PPh_(3))_(3),respectively.In addition,the optimal Rh_(1)/PCN SAC catalyst also demonstrated largely enhanced multicycle stability without any visible metal aggregation owing to the increased EMSIs,which sharply differed from the severe metal aggregation of large nanoparticles on the Rh_(1)/g-C_(3)N_(4)SAC.Mechan-istic studies revealed that the enhanced catalytic performance could be attributed to electron-deficient Rh species,which reduced CO adsorption while simultaneously promoting alkene adsorption through increased EMSIs.These findings suggest that tuning EMSIs is an effective way to achieve SACs with high activity and durability.展开更多
Understanding how different vegetation-based restoration practices alter soil chemical and microbial characteristics is crucial,as restoration practices influence phosphorus(P)transformation and fractions and modify P...Understanding how different vegetation-based restoration practices alter soil chemical and microbial characteristics is crucial,as restoration practices influence phosphorus(P)transformation and fractions and modify P adsorption behavior during the restoration process of degraded land.This study investigated the impacts of vegetation-based restoration practices on soil chemical and microbial parameters,P fractions,and patterns of P adsorption and desorption,and highlighted the combined influence on P availability.To evaluate the impact of vegetation-based restoration practices on P fractions and adsorption behavior in the semi-arid degraded land in India,this study compared three distinct tree-based restoration systems,including Leucaena leucocephala(Lam.)de Wit-based silviculture system(SCS),Acacia nilotica(L.)Willd.ex Delile-based silvopasture system(SPS),and Emblica officinalis Gaertn-based hortipasture system(HPS),with a natural grassland system(NGS)and a degraded fallow system(FS)as control.The soil samples across various soil depths(0-15,15-30,and 30-45 cm)were collected.The findings demonstrated that SCS,SPS,and HPS significantly improved soil organic carbon(SOC)and nutrient availability.Moreover,SCS and SPS resulted in increased microbial biomass phosphorus(MBP)content and phosphatase enzyme activity.The P fractionation analysis revealed that ferrum-associated phosphorus(Fe-P)was the major P fraction,followed by aluminum-associated phosphorus(Al-P),reflecting the dominance of ferrum(Fe)and aluminum(Al)oxides in the semi-arid degraded land.Compared with FS,vegetation-based restoration practices significantly increased various P fractions across soil depths.Additionally,P adsorption and desorption analysis indicated a lower adsorption capacity in tree-based restoration systems than in FS,with FS soils adsorbing higher P quantities in the adsorption phase but releasing less P during the desorption phase.This study revealed that degraded soils responded positively to ecological restoration in terms of P fraction and desorption behavior,influencing the resupply of P in restoration systems.Consequently,litter rich N-fixing tree-based restoration systems(i.e.,SCS and SPS)increased total phosphorus(TP)stock for plants and sustained the potential for long-term P supply in semi-arid ecosystems.With the widespread adoption of restoration practices across degraded landscapes,SCS and SPS would significantly contribute to soil restoration and improve productivity by maintaining the soil P supply in semi-arid ecosystems in India.展开更多
Simple cubic black phosphorus(BP)has been recognized as a strategic material due to its exceptional structural stability under extreme conditions.In this investigation,simple cubic BP was successfully synthesized thro...Simple cubic black phosphorus(BP)has been recognized as a strategic material due to its exceptional structural stability under extreme conditions.In this investigation,simple cubic BP was successfully synthesized through shock-induced phase transformation,utilizing amorphous red phosphorus as the precursor material.The phase evolution process was systematically investigated using plane shock loading apparatus,with shock pressure and temperature parameters being precisely controlled to optimize transformation kinetics.Comprehensive phase characterization revealed the correlation between thermodynamic loading profiles and cubic BP formation efficiency.Precursor modification strategies were implemented through orthorhombic BP utilization,resulting in enhanced cubic phase yield and crystallinity.The synthesized cubic BP variants are considered promising candidates for advanced protective material systems,particularly where combinations of mechanical resilience and thermal stability are required under extreme operational conditions.This research provides critical insights into shock-induced phase transformation mechanics,while establishing foundational protocols for manufacturing non-equilibrium materials with potential applications in next-generation defensive technologies.展开更多
基金supported by the National Key Research and Development Program of China(2023YFD1900300 and 2017YFD0200205)the Agricultural Key-scientific and Core-technological Project of Shaanxi Province,China(2024NYGG011)。
文摘The continuous supply of phosphorus(P)is indispensable in crop production.However,P resources are non-renewable,and environmental concerns like eutrophication associated with its loss from agroecosystems make the sustainable management of P resources essential for ensuring global food security.This study was designed to reduce mineral P inputs through management practices.A field experiment comprising a wheat-maize rotation system was conducted in the Guanzhong Plain of Shaanxi Province,China from 2018-2023.The eight treatments included CK(without P),FP(conventional P application);RP(recommended P);RP80(20% reduction in RP);SRP80(20% reduction in RP with straw wrapping);ARP80(20% reduction in RP with ammonium sulfate instead of urea);SARP80(20% reduction in RP with straw wrapping and ammonium sulfate instead of urea);and SARP60(40% reduction in RP with straw wrapping and ammonium sulfate instead of urea).Crop yield,P uptake,and P fertilizer use efficiency were measured during harvest and throughout the entire period of the study.At the end of the experiment,P fractions were estimated using the Tiessen-Moir P classification method.The results revealed that the grain yields of all the treatments except for RP80 were significantly increased compared to CK,with increases of 14.9-28.8%.Furthermore,agronomic efficiency,apparent P use efficiency,P recovery rate,and partial factor productivity were significantly improved for the treatments that received 20% less P with straw wrapping.Moreover,the enhancement measures significantly increased labile and moderately labile P in the soil.Therefore,straw wrapping with ammonium sulfate instead of urea is one of the most effective ways to reduce mineral P inputs while increasing the efficiency of P in wheat-maize rotation systems.
基金supported by the National Natural Science Foundation of China(Grant No.22175136)the State Key Laboratory of Electrical Insulation and Power Equipment(Grant No.EIPE23127)the Fundamental Research Funds for the Central Universities(xtr052024009,xtr052025002).
文摘Violet phosphorus,a recently explored layered elemental semiconductor,has attracted much attention due to its unique photoelectric,mechanical properties,and high hole mobility.Herein,violet arsenic phosphorus has for the first time been synthesized by a molten lead method.The crystal structure of violet arsenic phosphorus(P^(83.4)As_(0.6),CSD-2408761)was determined by single crystal X-ray diffraction to have similar structure as that of violet phosphorus,where P12 is occupied by arsenic/phosphorus(As/P)atoms as mixed occupancy sites As1/P12.The arsenic substitution has been demonstrated to tune the band structure of violet phosphorus,switching p-type of violet phosphorus to high-performance n-type violet arsenic phosphorus.The effective electron mass along the<010>direction is significantly reduced from 1.792 to 0.515 m_(0)by arsenic substitution,resulting in an extremely high electron mobility of 2622.503 cm^(2)V^(-1)s^(-1).The field effect transistor built with P_(83.4)As_(0.6)nanosheets was measured to have a high electron mobility(137.06 cm^(2)V^(-1)s^(-1),61.2 nm),even under ambient conditions for 5 h,much higher than the hole mobility of violet phosphorene nanosheets(4.07 cm^(2)V^(-1)s^(-1),73.3 nm).This work provides a new idea for designing phosphorus-based materials for field effect transistors,giving significant potential in complementary metal-oxide-semiconductor applications.
基金supported by the Natural Science Foundation of Shandong Province(Nos.ZR2024QE450,ZR2024QB302 and ZR2024QB004)the Taishan Scholars and Young Experts Program of Shandong Province(No.tsqn202211249)Research Program of Qilu Institute of Technology(Nos.QIT 23TP019,QIT23TP010 and QIT24NN007)。
文摘The large volume expansion and rapid capacity attenuation of tin-based electrodes are the main factors limiting their commercial application.The reasonable design of electrode material structure is particularly important for improving its electrochemical performance.Herein,phosphorus-modified graphene encapsulated Sn_(6)O_(4)(OH)_(4)nanoparticles composite(P-Sn_(6)O_(4)(OH)_(4)@RGO)with crystalline-amorphous heterostructure has been successfully designed and prepared.The design of crystalline-amorphous structure has largely enhanced the active sites,and the construction of a graphene encapsulation structure has greatly alleviated volume expansion.Notably,P-Sn_(6)O_(4)(OH)_(4)@RGO obtained an excellent high-rate longterm cycling performance for lithium-ion batteries anode,reaching a high specific capacity of 970 m Ah/g at 1.0 A/g after 1450 cycles.This work demonstrates that restructuring the electrode material's structure and phase through phosphorus modification can effectively improve the electrochemical performance of tin-based electrode materials.
基金supported by grants from the National Key Research and Development Program of China(2021YFF1000500)the National Natural Science Foundation of China(32370272,31970273,and 31921001).
文摘Phosphorus(P)is an essential nutrient for crop growth,making it important for maintaining food security as the global population continues to increase.Plants acquire P primarily via the uptake of inorganic phosphate(Pi)in soil through their roots.Pi,which is usually sequestered in soils,is not easily absorbed by plants and represses plant growth.Plants have developed a series of mechanisms to cope with P deficiency.Moreover,P fertilizer applications are critical for maximizing crop yield.Maize is a major cereal crop cultivated worldwide.Increasing its P-use efficiency is important for optimizing maize production.Over the past two decades,considerable progresses have been achieved in studies aimed at adapting maize varieties to changes in environmental P supply.Here,we present an overview of the morphological,physiological,and molecular mechanisms involved in P acquisition,translocation,and redistribution in maize and combine the advances in Arabidopsis and rice,to better elucidate the progress of P nutrition.Additionally,we summarize the correlation between P and abiotic stress responses.Clarifying the mechanisms relevant to improving P absorption and use in maize can guide future research on sustainable agriculture.
基金supported by the Key-Area Research and Development Program of Guangdong Province,China(No.2021B0202030002)the Science and Technology Planning Project of Guangdong Province,China(No.2019B030301007)+2 种基金the Guangdong Provincial Special Project of Rural Revitalization Strategy,China(No.(2021)12)the Joint Team Project of Guangdong Laboratory for Lingnan Modern Agriculture,China(No.NT2021010)the Innovation Team Construction Project of Modern Agricultural Industry Technology Systems of Guangdong Province,China(No.2022KJ105).
文摘Rice-fish coculture(RFC)has aroused extensive concern for its contribution to food security and resource conservation,but whether it can improve soil phosphorus(P)availability and affect microbe-mediated P turnover remains elusive.Herein,we conducted a microcosm experiment to assess the impacts of RFC combined with(50 mg P kg^(-1)as KH2PO4)and without inorganic P addition on P fractions,P availability,and phoD-harboring bacterial community composition.The results revealed that RFC without P addition significantly improved P availability and phosphatase activity in paddy soil,while soil available P(AP),pH,and microbial biomass P(MBP)contributed to regulating P fractions.Moreover,the phoD-harboring bacterial abundance was linked to phosphatase activity,AP,total carbon(TC),and total P(TP)contents,and the ratios of TC to total nitrogen(TN)and TN to TP.We also found that the keystone taxa of phoD-harboring bacteria contributed to phosphatase production as well as organic P mineralization,thereby improving P availability.Our findings suggest that RFC without P addition is beneficial for promoting the expression of phoD-harboring bacterial functions to improve the capacity of P mineralization.Overall,our study provides insights into the responses of phoD-harboring bacterial functions for P turnover to RFC combined with and without P addition,showing the potential utilization of P resources in agricultural soil and the contribution of phosphatase activity to P acquisition in agriculture ecosystem.
基金Hubei Provincial Key Research Program Project(2023BCB099).
文摘Utilizing phosphorus tailings as the raw material for foam concrete is a key approach to achieving sustainable and efficient resource utilization.During the preparation of phosphorus tailings-based foam concrete,slurry performance is critical to the successful production.Phosphorus tailings,cement and microsilica were used to prepare foam concrete slurry in this study.A rheometer was employed as a test tool to measure the variation of linear viscoelastic zone(LVR),viscosity,and yield stress of the slurries with different cement contents.The results indicate that the phosphorus tailings-cement-microsilica slurry exhibits shear-thinning properties,which aligns well with the Herschel-Bulkley model,showing a high degree of correlation.As the cement content increases,the energy storage modulus of the slurry rises,and the LVR length shows a nonlinear trend.The LVR reaches its maximum length of 0.04%when the cement content is 6 mass%or 8 mass%.The increment of the cement content leads to a more intricate internal network structure,which hinders the reconstruction rate of the flocculated structure after high-shear deformation.
基金supported by the National Natural Science Foundation of China(No.21571062)the Program for Professor of Special Appointment(Eastern Scholar)at the Shanghai Institutions of Higher Learning to JGL,and the Fundamental Research Funds for the Central Universities(No.222201717003)。
文摘Exploiting non-precious metal catalysts with excellent oxygen reduction reaction(ORR)performance for energy devices is paramount essential for the green and sustainable society development.Herein,low-cost,high-performance biomass-derived ORR catalysts with an asymmetric Fe-N_(3)P configuration was prepared by a simple pyrolysis-etching technique,where carboxymethyl cellulose(CMC)was used as the carbon source,urea and 1,10-phenanthroline iron complex(FePhen)as additives,and Na_(3)PO_(4)as the phosphorus dopant and a pore-forming agent.The CMC-derived FeNPC catalyst displayed a large specific area(BET:1235 m^(2)g^(-1))with atomically dispersed Fe-N_(3)P active sites,which exhibited superior ORR activity and stability in alkaline solution(E_(1/2)=0.90 V vs.RHE)and Zn-air batteries(P_(max)=149 mW cm^(-2))to commercial Pt/C catalyst(E_(1/2)=0.87 V,P_(max)=118 mW cm^(-2))under similar experimental conditions.This work provides a feasible and costeffective route toward highly efficient ORR catalysts and their application to Zn-air batteries for energy conversion.
基金supported by the National Key Research and Development Program of China(2024YFD2301200)National Nature Science Foundation of China(32172662).
文摘With the objective of investigating the basis of phosphorus(P)utilization efficiency(PUE),physiological and morphological traits,two P-efficient and two P-inefficient rapeseed(Brassica napus L.)cultivars were compared at the seedling stage.P-efficient cultivars showed root morphological adaptation,high P uptake activity,and greater phospholipid degradation under low P stress.Improving root morphological adaptation and reducing lipid-P allocation could allow increasing PUE in rapeseed seedlings.
基金supported by the National Natural Science Foundation of China(No.42030509)the Special Project on National Science and Technology Basic Resources Investigation of China(No.2021FY100705).
文摘The leaf nitrogen(N)to phosphorus(P)ratio(N:P)is a critical indicator of nutrient dynamics and ecosystem function.Investigating temporal variations in leaf N:P can provide valuable insights into how plants adapt to environmental changes and nutrient availability.However,limited research has been conducted on long-term temporal leaf N:P variation over a range of temperature zones.Using long-term monitoring data from the Chinese Ecosystem Research Network(CERN),we investigated temporal changes in leaf N and P stoichiometry for 50 dominant tree species from 10 typical forest sites across temperate and subtropical regions,and identified the underlying mechanisms driving these changes.For both regions combined,leaf P concentration of the 50 dominant tree species decreased(20.6%),whereas leaf N:P increased(52.0%)from 2005 to 2020.Leaf P decreased and leaf N:P increased in 67% and 69% of the tree species,respectively.The leaf N:P increase was primarily driven by the tree species in eastern subtropical forests,where global change factors and soil nutrients explained 68% of leaf N:P variation.The P limitation exhibited by tree species in eastern subtropical forest ecosystems intensified over time,and elevated temperature and CO_(2) levels,coupled with decreased soil available P concentrations,appear to be the main factors driving long-term leaf N:P increases in these forests.Investigating long-term variations in soil nutrients together with global change factors will improve our understanding of the nutrient status of forest ecosystems in the context of global change and will support effective forest ecosystem management.
基金supported by the National Natural Science Foundation of China(52100093,52270128,and 52261135627)the Guangdong Basic and Applied Basic Research Foundation(2023A1515011734 and 2021B1515120068)+2 种基金the Municipal Science and Technology Innovation Council of the Shen-zhen Government(KCXFZ20211020163556020 and SGDX20230116092359002)the Research Grants Council(17210219)the Innovation and Technology Fund(ITS/242/20FP)of the Hong Kong SAR Government。
文摘The rapidly growing demand for lithium iron phosphate(LiFePO_(4))as the cathode material of lithium-ion batteries(LIBs)has aggravated the scarcity of phosphorus(P)reserves on Earth.This study introduces an environmentally friendly and economical method of P recovery from municipal wastewater,providing the P source for LiFePO_(4) cathodes.The novel approach utilizes the sludge of Fe-coagulant-based chemical P removal(CPR)in wastewater treatment.After a sintering treatment with acid washing,the CPR sludge,enriched with P and Fe,transforms into purified P-Fe oxides(Fe2.1P1.0O5.6).These oxides can substitute up to 35%of the FePO_(4) reagent as precursor,producing a carbon-coated LiFePO_(4)(LiFePO_(4)/C)cathode with a specific discharge capacity of 114.9 mA·h·g^(-1)at current density of 17 mA·g^(-1)),and cycle stability of 99.2%after 100 cycles.The enhanced cycle performance of the as-prepared LiFePO_(4)/C cathode may be attributed to the incorporations of impurities(such as Ca^(2+)and Na^(+))from sludge,with improved stability of crystal structure.Unlike conventional P-fertilizers,this P recovery technology converts 100%of P in CPR sludge into the production of value-added LiFePO_(4)/C cathodes.The recovered P from municipal wastewater can meet up to 35%of the P demand in the Chinese LIBs industry,offering a cost-effective solution for addressing the pressing challenges of P scarcity.
基金financed by the Spanish Ministry of Science and Innovation and the European Regional Development Fund(ERDF)(No.PID20211234690BI00)the European Joint Program EJP_Soil(TRACE-Soils)(No.862695)+1 种基金the Spanish Ministry of Science and Innovation(RED2018-102624TMCIN/AEI/10.13039/501100011033)the Project PREPSOIL European Union(No.101070045,HORIZON CSA)。
文摘Whilst phosphorus(P)in soil is considered to be abundant,the portion available for plant uptake constitutes less than 1%of the overall P present.To enhance crop productivity,the utilization of mineral P fertilizers has become pervasive in agriculture.Nonetheless,the escalating prices of chemical fertilizers,coupled with new European regulations prohibiting the use of P fertilizers containing cadmium,have highlighted the urgency to identify environmentally friendly products and practices for P fertilization in agricultural soils.This comprehensive review delves into the current landscape of P fertilization from agricultural,political,and economic standpoints.We recognize the potential of microbes in mobilizing P,but emphasize the necessity for more robust research to establish their effectiveness in promoting plant P uptake under real-world conditions.Additionally,we explore the role of agricultural conservation practices,such as optimal tillage,diversified cropping systems,and increased organic carbon input,in conserving P.Furthermore,this review contemplates forthcoming innovations in research.These innovations encompass the development of enhanced formulations for biofertilizers and the undertaking of more comprehensive studies within the realm of conservation agriculture.All these endeavors collectively hold the potential to augment P accessibility to plants in a sustainable manner,thereby advancing agricultural sustainability and productivity.
基金supported by the National Key Research and Development Program of China(No.2021YFD1700600)the National Natural Science Foundation of China(Nos.42222104 and 41971138)+1 种基金the Strategic Priority Research Program of Chinese Academy of Sciences(No.XDA23020201)and the Science and Technology Planning Project of NIGLAS(No.NIGLAS2022GS10).
文摘China’s lowland rural rivers are facing severe eutrophication problems due to excessive phosphorus(P)from anthropogenic activities.However,quantifying P dynamics in a lowland rural river is challenging due to its complex interaction with surrounding areas.A P dynamic model(River-P)was specifically designed for lowland rural rivers to address this challenge.This modelwas coupled with the Environmental Fluid Dynamics Code(EFDC)and the Phosphorus Dynamic Model for lowland Polder systems(PDP)to characterize P dynamics under the impact of dredging in a lowland rural river.Based on a two-year(2020-2021)dataset from a representative lowland rural river in the Lake Taihu Basin,China,the coupled model was calibrated and achieved a model performance(R^(2)>0.59,RMSE<0.04 mg/L)for total P(TP)concentrations.Our research in the study river revealed that(1)the time scale for the effectiveness of sediment dredging for P control was~300 days,with an increase in P retention capacity by 74.8 kg/year and a decrease in TP concentrations of 23%after dredging.(2)Dredging significantly reduced P release from sediment by 98%,while increased P resuspension and settling capacities by 16%and 46%,respectively.(3)The sediment-water interface(SWI)plays a critical role in P transfer within the river,as resuspension accounts for 16%of TP imports,and settling accounts for 47%of TP exports.Given the large P retention capacity of lowland rural rivers,drainage ditches and ponds with macrophytes are promising approaches to enhance P retention capacity.Our study provides valuable insights for local environmental departments,allowing a comprehensive understanding of P dynamics in lowland rural rivers.This enable the evaluation of the efficacy of sediment dredging in P control and the implementation of corresponding P control measures.
基金funded by the National Natural Science Foundation of China (No. 81960334)the Guiding Plan of Xinjiang Production Construction Corps (No. 2022ZD007)+4 种基金the Science and Technology Innovation Leading Talents Program of Guangdong Province (No. 2019TX05C343)the Basic and Applied Basic Research Foundation of Guangdong Province-Regional Joint Fund-Key Projects (No. 2019B1515120043)the Project supported by the State Key Laboratory of Luminescence and Applications (No. SKLA-2020-03)the support from Instrumental Analysis Center of Shenzhen University (Xili Campus)Instrumental Analysis Center of Shihezi University.
文摘Ischemic stroke is the leading cause of death in China,accounting for approximately one-third of all stroke-associated deaths worldwide.Currently,thrombolysis is employed for ischemic strokes.However,due to the limited therapeutic window of thrombolytic agents,most patients do not receive the drug at the right time.Moreover,these agents are associated with risks of hemorrhage and reperfusion damage.Herein,Angiopep-2(ANG)-black phosphorus(BP)-resveratrol(RES),a drug-loaded system,was used to deliver drugs across the blood–brain barrier(BBB).ANG-BP-RES has a uniform size,stable structure,good photothermal effect,and strong drug release ability under near-infrared(NIR)irradiation and acidic conditions.Furthermore,ANG-BP-RES can efficiently target the brain and improve BBB permeability,exerting a significant therapeutic effect against ischemic brain injury,especially after NIR irradiation.ANG-BP-RES is also biocompatible and shows minimal toxicity toward cells and tissues.This study offers novel insights into the therapeutic management of ischemic brain injury.
基金supported by Hebei Key Laboratory of Mineral Resources and Ecological Environment Monitoring(No.HBMREEM202302)Tianjin Key Research and Development Science and Technology Project(Nos.24YFXTHZ00170 and 24YFXTHZ00050)。
文摘The interaction mechanism between eggshell calcium and endogenous silica in biomass during biochar modification,and its impact on phosphate adsorption performance and slow-release fertilizer characteristics,remains unexplored.This study investigates that high silica content in biomass(>6%)inhibits the decomposition of CaCO_(3)in eggshells during pyrolysis,reducing the formation of active calcium species(CaO and Ca(OH)_(2)),while moderate silica levels(4%-5%)promote the formation of CaSiO_(3),enhancing phosphorus adsorption without hindering Ca^(2+)activation.Adsorption studies reveal that the precipitation of Ca_(5)(PO_(4))_(3)(OH)resulting from the combination of CaO and Ca(OH)_(2)with phosphate is the primary and effective form for phosphorus removal in calcium-modified adsorbents,accompanied by Ca_(3)(PO_(4))_(2)·2H_(2)O precipitation formed by CaSi O_(3).Eggshell calcium-modified corn straw biochar(ECS)exhibited the highest adsorption capacity,reaching 123.3 mg/g,outperforming materials in previous studies.ECS also demonstrated excellent pH adaptability and selective phosphate removal.As a biochar-based phosphorus fertilizer,ECS-P exhibits high phosphorus extractability in formic acid(93.92%)but low water solubility(0.62%),with phosphorus release during the seven-day intermittent leaching experiment remaining between 0.53 to 0.875 mg/L.These results confirm its potential as a phosphorus cycling fertilizer.This study provides fundamental insights into optimizing biomass selection based on silica content for calcium modification,offering an efficient strategy for both phosphate recovery and slow-release fertilizer development.
基金supported by the National Key R&D Program of China(2022YFB3807700)the National Natural Science Foundation of China(52072217,22179071,51772169,and 52104313)+3 种基金the Hubei Provincial Natural Science Foundation of China(2023AFB618 and 2024AFB993)the Hubei Natural Science Foundation Innovation Group Project(2022CFA020)the Joint Funds of the Hubei Natural Science Foundation Innovation and Development(2022CFD034)the Major Technological Innovation Project of Hubei Science and Technology Department(2019AAA164)。
文摘Black phosphorus(BP)is recognized as a promising anode for sodium-ion batteries(SIBs)due to its high safety and theoretical capacity.However,traditional ball milling methodologies for fabricating BP composite anodes have not satisfactorily addressed the challenges of poor rate performance and short cycle life.To fill this scientific gap,we herein pioneer incorporating the sodium fast ionic conductorβ"-Al_(2)O_(3)into ball-milled BP with carbon,which facilitates the formation of three-dimensional mass transfer channels in the resulting composite.To stabilize these channels,we develop a novel and environmentally friendly functional binder that outperforms traditional binders in thermal stability,wettability,and mechanical properties.The newly established binder is capable of remarkably mitigating volume expansion and interfacial side reactions in the BP/β"-Al_(2)O_(3)/C composite anode.Additionally,we identify synergistic effects of the binder interacting with the BP/β"-Al_(2)O_(3)/C composite during cycling,characterized by the in-situ formation of P-O-C bonds,which is the first instance of a strong,durable chemical bond between the binder and the active material to the best of our knowledge.These advancements allow the composite electrode to exhibit exceptional sodium storage,including high initial Coulombic efficiency and long-term cycling stability,which surpasses most previous phosphorus-based anodes fabricated via traditional approaches.Notably,when paired with a Na_(4)Fe_(3)(PO_(4))_(2)P_(2)O_7(NFPP)cathode,the full cell exhibits unexpectedly high energy and power densities,highlighting the BP potential in SIBs.The findings presented in the present work contribute to the promotion of economical and efficient applications of phosphorus-based anode materials.
文摘Although bimetallic phosphide cocatalysts have attracted considerable interest in photocatalysis research owing to their advantageous thermodynamic characteristics,superstable and efficient cocatalysts have rarely been produced through the modulation of their structure and composition.In this study,a series of bimetallic nickel-iron phosphide(Ni_(x)Fe_(2-x)P,where 0<x<2)cocatalysts with controllable structures and overpotentials were designed by adjusting the atomic ratio of Ni/Fe onto nonmetallic elemental red phosphorus(RP)for the photocatalytic selective oxidation of benzyl alcohol(BA)coupled with hydrogen production.The catalysts exhibited an outstanding photocatalytic activity for benzaldehyde and a high H_(2)yield.The RP regulated by bimetallic phosphide cocatalysts(Ni_(x)Fe_(2-x)P)demonstrated higher photocatalytic oxidation-reduction activity than that regulated by monometallic phosphide cocatalysts(Ni_(2)P and Fe2P).In particular,the RP regulated by Ni_(1.25)Fe_(0.75)P exhibited the best photocatalytic performance.In addition,experimental and theoretical calculations further illustrated that Ni_(1.25)Fe_(0.75)P,with the optimized electronic structure,possessed good electrical conductivity and provided strong adsorption and abundant active sites,thereby accelerating electron migration and lowering the reaction energy barrier of RP.This finding offers valuable insights into the rational design of highly effective cocatalysts aimed at optimizing the photocatalytic activity of composite photocatalysts.
基金Project supported by the Natural Science Foundation of Henan Province(Nos.232300421234,252300421726)the Leading Talents in Scientific and Technological Innovation in Shangqiu(No.SQRC202212004)the Program of Ecological Environmental Protection in the Area of Old Course of Yellow River of Shangqiu Normal University。
文摘Atropisomeric phosphines are crucial for asymmetric catalysis but remain synthetically challenging.Herein,an N-heterocyclic carbene(NHC)catalyzed esterification reaction of dialdehydes with arylboronic acids was developed,successfully constructing the framework of axially chiral phosphorus compounds.Mechanistic studies have revealed that the reaction initially undergoes a desymmetrization process,followed by a kinetic resolution pathway,affording a series of axially chiral phosphorus compounds with high enantioselectivity(up to 92%ee).
基金supported by the Petrochemical Research Institute Foundation(21-CB-09-01)the National Natural Science Foundation of China(22302186,22025205)+1 种基金the China Postdoctoral Science Foundation(2022M713030,2023T160618)the Fundamental Research Funds for the Central Universities(WK2060000058,WK2060000038).
文摘By simplifying catalyst-product separation and reducing phosphorus waste,heterogeneous hydroformylation offers a more sustainable alternative to homogeneous processes.However,heterogeneous hydroformylation catalysts developed thus far still suffer from the issues of much lower activity and metal leaching,which severely hinder their practical application.Here,we demonstrate that incorporating phosphorus(P)atoms into graphitic carbon nitride(PCN)supports facilitates charge transfer from Rh to the PCN support,thus largely enhancing electronic metal-support interactions(EMSIs).In the styrene hydroformylation reaction,the activity of Rh_(1)/PCN single-atom catalysts(SACs)with varying P contents exhibited a volcano-shaped relationship with P doping,where the Rh_(1)/PCN SAC with optimal P doping showed exceptional activity,approximately 5.8-and 3.3-fold greater than that of the Rh_(1)/g-C_(3)N_(4)SAC without P doping and the industrial homogeneous catalyst HRh(CO)(PPh_(3))_(3),respectively.In addition,the optimal Rh_(1)/PCN SAC catalyst also demonstrated largely enhanced multicycle stability without any visible metal aggregation owing to the increased EMSIs,which sharply differed from the severe metal aggregation of large nanoparticles on the Rh_(1)/g-C_(3)N_(4)SAC.Mechan-istic studies revealed that the enhanced catalytic performance could be attributed to electron-deficient Rh species,which reduced CO adsorption while simultaneously promoting alkene adsorption through increased EMSIs.These findings suggest that tuning EMSIs is an effective way to achieve SACs with high activity and durability.
基金funded by Indian Council of Agricultural Research,Ministry of Agriculture and Farmers Welfare,India(AGRIL.EDN/1/1/2022-EXAM CELL).
文摘Understanding how different vegetation-based restoration practices alter soil chemical and microbial characteristics is crucial,as restoration practices influence phosphorus(P)transformation and fractions and modify P adsorption behavior during the restoration process of degraded land.This study investigated the impacts of vegetation-based restoration practices on soil chemical and microbial parameters,P fractions,and patterns of P adsorption and desorption,and highlighted the combined influence on P availability.To evaluate the impact of vegetation-based restoration practices on P fractions and adsorption behavior in the semi-arid degraded land in India,this study compared three distinct tree-based restoration systems,including Leucaena leucocephala(Lam.)de Wit-based silviculture system(SCS),Acacia nilotica(L.)Willd.ex Delile-based silvopasture system(SPS),and Emblica officinalis Gaertn-based hortipasture system(HPS),with a natural grassland system(NGS)and a degraded fallow system(FS)as control.The soil samples across various soil depths(0-15,15-30,and 30-45 cm)were collected.The findings demonstrated that SCS,SPS,and HPS significantly improved soil organic carbon(SOC)and nutrient availability.Moreover,SCS and SPS resulted in increased microbial biomass phosphorus(MBP)content and phosphatase enzyme activity.The P fractionation analysis revealed that ferrum-associated phosphorus(Fe-P)was the major P fraction,followed by aluminum-associated phosphorus(Al-P),reflecting the dominance of ferrum(Fe)and aluminum(Al)oxides in the semi-arid degraded land.Compared with FS,vegetation-based restoration practices significantly increased various P fractions across soil depths.Additionally,P adsorption and desorption analysis indicated a lower adsorption capacity in tree-based restoration systems than in FS,with FS soils adsorbing higher P quantities in the adsorption phase but releasing less P during the desorption phase.This study revealed that degraded soils responded positively to ecological restoration in terms of P fraction and desorption behavior,influencing the resupply of P in restoration systems.Consequently,litter rich N-fixing tree-based restoration systems(i.e.,SCS and SPS)increased total phosphorus(TP)stock for plants and sustained the potential for long-term P supply in semi-arid ecosystems.With the widespread adoption of restoration practices across degraded landscapes,SCS and SPS would significantly contribute to soil restoration and improve productivity by maintaining the soil P supply in semi-arid ecosystems in India.
基金supported by the Youth Project of the Independent Subject of the State Key Laboratory of Explosion Science and Safety Protection,Beijing Institute of Technology(Grant Nos.QNKT25-13 and QNKT24-02)the 76th batch of Project funded by China Postdoctoral Science Foundation(Grant No.2024M764116)+3 种基金the National Natural Science Foundation of China(Grant Nos.12002048,12072037,12102050,and 12202067)the Science and Technology Commission,China(Grant No.2019-jcjc-zd-011-00)the Project supported by the Open Funds of Kui Yuan Laboratory(Grant No.KY202431)the State Key Laboratory of Explosion Science and Safety Protection(Grant No.KFJJ25-21M)。
文摘Simple cubic black phosphorus(BP)has been recognized as a strategic material due to its exceptional structural stability under extreme conditions.In this investigation,simple cubic BP was successfully synthesized through shock-induced phase transformation,utilizing amorphous red phosphorus as the precursor material.The phase evolution process was systematically investigated using plane shock loading apparatus,with shock pressure and temperature parameters being precisely controlled to optimize transformation kinetics.Comprehensive phase characterization revealed the correlation between thermodynamic loading profiles and cubic BP formation efficiency.Precursor modification strategies were implemented through orthorhombic BP utilization,resulting in enhanced cubic phase yield and crystallinity.The synthesized cubic BP variants are considered promising candidates for advanced protective material systems,particularly where combinations of mechanical resilience and thermal stability are required under extreme operational conditions.This research provides critical insights into shock-induced phase transformation mechanics,while establishing foundational protocols for manufacturing non-equilibrium materials with potential applications in next-generation defensive technologies.
