Phosphaalkenes are an emerging class of ligands with unique electronic properties that can be regarded as tuneable variants of the ubiquitous CO ligand.Our group has recently reported the synthesis of the P,N-type pho...Phosphaalkenes are an emerging class of ligands with unique electronic properties that can be regarded as tuneable variants of the ubiquitous CO ligand.Our group has recently reported the synthesis of the P,N-type phosphaalkene ligand quin-CHvPMes^(*)(1,quin=2-quinolinyl)and its coordination chemistry with Rh(Ⅰ)was investigated.展开更多
基金support by LIKAT(PhD fellowship for P.G.)is gratefully acknowledged.
文摘Phosphaalkenes are an emerging class of ligands with unique electronic properties that can be regarded as tuneable variants of the ubiquitous CO ligand.Our group has recently reported the synthesis of the P,N-type phosphaalkene ligand quin-CHvPMes^(*)(1,quin=2-quinolinyl)and its coordination chemistry with Rh(Ⅰ)was investigated.