The complex [Mn(H2O)(phen)2(PAc)](ClO4) was synthesized and investigated by elemental analysis, molar conductivity, IR spectrum and X ray diffraction methods, where phen=1,10 phenanthroline and PAc=phenylac<IMG SRC...The complex [Mn(H2O)(phen)2(PAc)](ClO4) was synthesized and investigated by elemental analysis, molar conductivity, IR spectrum and X ray diffraction methods, where phen=1,10 phenanthroline and PAc=phenylac<IMG SRC="IMAGE/06200090.JPG" HEIGHT=11 WIDTH=12>etate group. The complex crystallizes in the triclinic space group, , with a=0.9289(2)nm,b=1.2425(2)nm,c=1.4791(3)nm,α=114.34(3)°,β=91.25(3)°,γ=104.65(1)°,V=1.4893(4)nm3,Z=2,F(000)=686,Dc=1.489g·cm-3,μ=0.589mm-1. The Mn?ion has a six coordinate distorted octahedral geometry with the four nitrogen atoms of two phen ligands,a coordinated water oxygen atom, and a carboxylate oxygen atom of PAc-. There is π πstacking interaction between two phen rings from two neighbor molecules.展开更多
文摘The complex [Mn(H2O)(phen)2(PAc)](ClO4) was synthesized and investigated by elemental analysis, molar conductivity, IR spectrum and X ray diffraction methods, where phen=1,10 phenanthroline and PAc=phenylac<IMG SRC="IMAGE/06200090.JPG" HEIGHT=11 WIDTH=12>etate group. The complex crystallizes in the triclinic space group, , with a=0.9289(2)nm,b=1.2425(2)nm,c=1.4791(3)nm,α=114.34(3)°,β=91.25(3)°,γ=104.65(1)°,V=1.4893(4)nm3,Z=2,F(000)=686,Dc=1.489g·cm-3,μ=0.589mm-1. The Mn?ion has a six coordinate distorted octahedral geometry with the four nitrogen atoms of two phen ligands,a coordinated water oxygen atom, and a carboxylate oxygen atom of PAc-. There is π πstacking interaction between two phen rings from two neighbor molecules.
