Laboratorial incubation and field experiments were conducted on soils ranging in texture from sandy loam toclay and in PH from 3 .6 to 9.0 to determine the agronomic effectiveness of single superphosphate (SSP), fused...Laboratorial incubation and field experiments were conducted on soils ranging in texture from sandy loam toclay and in PH from 3 .6 to 9.0 to determine the agronomic effectiveness of single superphosphate (SSP), fused magne-sium phosphate (FMP)and partially acidulated phosphate rock (PAPR)on 8 field crops. The results showed that thepottern of available P released from SSP was fixing -releasing-fixing-steady state, while that of PAPR was shortlyfixing-slowly releasing-fixing-steady state And the PAPR . SSP and FMP were equally effective as judged by yield, Puptake by plants and extractable P in soils after crop harvesting. The PAPR used as basal fertilizer was more effectivethan that as top dressing, and its residual effect was also obvious.展开更多
Bisphenol A bis（diphenyl phosphate） oligomer（BDP） is prepared successfully from the reactants consisting of phosphorus oxyehloride （POCl3）, bisphenol A and phenol with a Friedel-Crafts catalyst. The resultant pr...Bisphenol A bis（diphenyl phosphate） oligomer（BDP） is prepared successfully from the reactants consisting of phosphorus oxyehloride （POCl3）, bisphenol A and phenol with a Friedel-Crafts catalyst. The resultant products were examined with thermtygravimetrie analysis （TGA） and high performance liquid chro- matography（HPLC）. Thermogravimetry data shows that BDP decomposes at 375℃ when 5 % weight lost. Experiments results show that catalyst is preferably AICI3 and the amount of it is preferably 1% relative to bisphenol A by mole. POCl3/bisphenol A mole ratio is preferably about 5：1 to 6：1. Experiments unclosed that a seal apparatus is very important to the properties of product.展开更多
A series of new complexes, CpTiCl[S2P(OR)2]2 (where R) Et, n-Pr, i-Pr, Bui, Ph) and CpTiCl [S2POGO]2 (where G) –CH2CMe2CH2-, -CMe2CMe2-) have been prepared by the drop wise addition of the appropriate O, O’-dialkyl ...A series of new complexes, CpTiCl[S2P(OR)2]2 (where R) Et, n-Pr, i-Pr, Bui, Ph) and CpTiCl [S2POGO]2 (where G) –CH2CMe2CH2-, -CMe2CMe2-) have been prepared by the drop wise addition of the appropriate O, O’-dialkyl or -alkylene dithiophosphoric acid to cyclopentadienyl titanium trichloride in 1:2 molar ratio and refluxed in benzene solution. The new compounds were characterized by molecular weight measurements elemental analyses and spectroscopic studies (1H, 13C, and 31P NMR, and in-frared). We suggest a distorted tetrahedron structure of these new complexes and the dithioligand behaves as bidentate ligand.展开更多
研究旨在建立甜菜碱磷酸盐产品中甜菜碱和磷酸盐含量的测定方法,用于指导工业生产和产品质量控制。试验以Shim-Nex HE Amide色谱柱为分析柱,用磷酸二氢钾和乙腈为流动相,在220 nm波长下采用液相色谱外标法定量测定甜菜碱的含量;使用自...研究旨在建立甜菜碱磷酸盐产品中甜菜碱和磷酸盐含量的测定方法,用于指导工业生产和产品质量控制。试验以Shim-Nex HE Amide色谱柱为分析柱,用磷酸二氢钾和乙腈为流动相,在220 nm波长下采用液相色谱外标法定量测定甜菜碱的含量;使用自动电位滴定仪,以复合pH电极为指示电极,采用动态滴定模式,通过计算磷酸p Ka_(2)与p Ka_(1)对应的体积差计算磷酸盐的含量。结果显示:甜菜碱加标回收率为98.44%~101.14%,RSD<1.0%(n=15),样品测定结果与凯氏定氮法一致;磷酸盐加标回收率为99.28%~100.20%,RSD<0.5%(n=15),样品测定结果与喹钼柠酮重量法一致。研究表明,两种测定方法操作简单,精密度和准确度符合要求;结合甜菜碱和磷酸盐的含量,能够反馈出甜菜碱磷酸盐产品是否合格,对工艺优化和产品质量控制具有重要意义。展开更多
Dimeric estradiol enzyme model (2) was synthesized by etherification of 2,4-bis(N-imidazolylmethyl)-17β-estradiol (1) with 1,3-dibromopropane in the presence of anhydrous K2CO3. Hydrolysis of carboxylates and phospha...Dimeric estradiol enzyme model (2) was synthesized by etherification of 2,4-bis(N-imidazolylmethyl)-17β-estradiol (1) with 1,3-dibromopropane in the presence of anhydrous K2CO3. Hydrolysis of carboxylates and phosphates catalyzed by the model showed Michaelis-Menten kinetic behavior. Hydrophobic interaction between the model and ester accelerates the hydrolysis markedly, rate enhancement of up to 65 and 285 fold, relative to imidazole, is observed.展开更多
文摘Laboratorial incubation and field experiments were conducted on soils ranging in texture from sandy loam toclay and in PH from 3 .6 to 9.0 to determine the agronomic effectiveness of single superphosphate (SSP), fused magne-sium phosphate (FMP)and partially acidulated phosphate rock (PAPR)on 8 field crops. The results showed that thepottern of available P released from SSP was fixing -releasing-fixing-steady state, while that of PAPR was shortlyfixing-slowly releasing-fixing-steady state And the PAPR . SSP and FMP were equally effective as judged by yield, Puptake by plants and extractable P in soils after crop harvesting. The PAPR used as basal fertilizer was more effectivethan that as top dressing, and its residual effect was also obvious.
文摘Bisphenol A bis（diphenyl phosphate） oligomer（BDP） is prepared successfully from the reactants consisting of phosphorus oxyehloride （POCl3）, bisphenol A and phenol with a Friedel-Crafts catalyst. The resultant products were examined with thermtygravimetrie analysis （TGA） and high performance liquid chro- matography（HPLC）. Thermogravimetry data shows that BDP decomposes at 375℃ when 5 % weight lost. Experiments results show that catalyst is preferably AICI3 and the amount of it is preferably 1% relative to bisphenol A by mole. POCl3/bisphenol A mole ratio is preferably about 5：1 to 6：1. Experiments unclosed that a seal apparatus is very important to the properties of product.
文摘A series of new complexes, CpTiCl[S2P(OR)2]2 (where R) Et, n-Pr, i-Pr, Bui, Ph) and CpTiCl [S2POGO]2 (where G) –CH2CMe2CH2-, -CMe2CMe2-) have been prepared by the drop wise addition of the appropriate O, O’-dialkyl or -alkylene dithiophosphoric acid to cyclopentadienyl titanium trichloride in 1:2 molar ratio and refluxed in benzene solution. The new compounds were characterized by molecular weight measurements elemental analyses and spectroscopic studies (1H, 13C, and 31P NMR, and in-frared). We suggest a distorted tetrahedron structure of these new complexes and the dithioligand behaves as bidentate ligand.
基金Project(No. 129402012 and 29632004)supported by the National Natural Science FouDdation of China and the Special Fupds of the State Educational Committee for Doctorate Scientific Research of China
文摘Dimeric estradiol enzyme model (2) was synthesized by etherification of 2,4-bis(N-imidazolylmethyl)-17β-estradiol (1) with 1,3-dibromopropane in the presence of anhydrous K2CO3. Hydrolysis of carboxylates and phosphates catalyzed by the model showed Michaelis-Menten kinetic behavior. Hydrophobic interaction between the model and ester accelerates the hydrolysis markedly, rate enhancement of up to 65 and 285 fold, relative to imidazole, is observed.
