Ferroelastic materials have attracted wide attention due to their great application prospects in energy and information conversion,data storage applications,etc.In this report,we designed and synthesized an organic–i...Ferroelastic materials have attracted wide attention due to their great application prospects in energy and information conversion,data storage applications,etc.In this report,we designed and synthesized an organic–inorganic hybrid halide perovskite ferroelastic(TMTB)CdCl_(3)(TMTB:N,N,N-trimethyl-tert-butylammonium)under the quasi-spherical strategy.(TMTB)CdCl_(3)shows a structural phase transition at around 356 K(T_(c)).In the ferroelastic phase,a quasi-spherical TMTB cation is orientationally ordered with the symmetry of mmm.Above the T_(c)in the paraelastic phase,the crystal symmetry of 6/mmm compels the TMTB cation with multiple orientations showing spherical distribution.The phase transition with an Aizu notation of 6/mmmFmmm agrees well with one of the 94 ferroelastic species.Under a polarized light microscope,the evolution of ferroelastic domains was visually observed.The calculated spontaneous strain value of(TMTB)CdCl_(3)is 0.0507 based on the lattice parameters.Moreover,(TMTB)CdCl_(3)shows prominent‘ON’/‘OFF’dielectric switches with good reproducibility.Theoretical calculations based on density functional theory(DFT)were further performed to explore the‘spherical’–‘quasi-spherical’variation of the TMTB cation.This work demonstrates that the quasi-spherical molecular strategy provides a shortcut for discovering new molecular ferroelastic materials,and also provides guidance for the directional design of functional materials.展开更多
基金supported by the National Natural Science Foundation of China(21991141)the Postdoctoral Selection Funding Project of Jiangxi Province(9109/13009494).
文摘Ferroelastic materials have attracted wide attention due to their great application prospects in energy and information conversion,data storage applications,etc.In this report,we designed and synthesized an organic–inorganic hybrid halide perovskite ferroelastic(TMTB)CdCl_(3)(TMTB:N,N,N-trimethyl-tert-butylammonium)under the quasi-spherical strategy.(TMTB)CdCl_(3)shows a structural phase transition at around 356 K(T_(c)).In the ferroelastic phase,a quasi-spherical TMTB cation is orientationally ordered with the symmetry of mmm.Above the T_(c)in the paraelastic phase,the crystal symmetry of 6/mmm compels the TMTB cation with multiple orientations showing spherical distribution.The phase transition with an Aizu notation of 6/mmmFmmm agrees well with one of the 94 ferroelastic species.Under a polarized light microscope,the evolution of ferroelastic domains was visually observed.The calculated spontaneous strain value of(TMTB)CdCl_(3)is 0.0507 based on the lattice parameters.Moreover,(TMTB)CdCl_(3)shows prominent‘ON’/‘OFF’dielectric switches with good reproducibility.Theoretical calculations based on density functional theory(DFT)were further performed to explore the‘spherical’–‘quasi-spherical’variation of the TMTB cation.This work demonstrates that the quasi-spherical molecular strategy provides a shortcut for discovering new molecular ferroelastic materials,and also provides guidance for the directional design of functional materials.
