In permafrost regions of the QinghaiXizang Plateau,embankments of the Qinghai-Xizang Highway and Qinghai-Xizang Railway experiencing roadside water accumulation exhibit more pronounced engineering deteriorations.A wid...In permafrost regions of the QinghaiXizang Plateau,embankments of the Qinghai-Xizang Highway and Qinghai-Xizang Railway experiencing roadside water accumulation exhibit more pronounced engineering deteriorations.A widely accepted view is that the accumulated water adjacent to the embankment possesses substantial thermal energy,which accelerates the degradation-even disappearance-of the underlying permafrost.Moreover,the presence of roadside water keeps the embankment soil in a persistently high-moisture state,thereby making the frozen-soil embankment more susceptible to deformation under traffic loading.However,in the permafrost regions of the QinghaiXizang Plateau,deteriorations of embankments affected by roadside water are more commonly manifested as undulating pavement surfaces,and extensive crack networks appear on the embankment crest even where thermosyphons are installed.These manifestations are not fully consistent with the deterioration mechanisms proposed by existing viewpoints.We propose the hypothesis that temperature gradients,formed due to the freezing and thawing processes between the roadside wateraffected soil and the roadbed soil,lead to moisture migration under the influence of temperature gradients,resulting in frost heave and thaw settlement in the roadbed soil.To validate this hypothesis,we conducted the following investigations sequentially.Initially,we selected a roadbed with a thermosyphon(TPCT)system,which has a significant cooling effect,as the study object.By analyzing the temperature monitoring data of the roadbed section,the temperature variance was calculated to identify the time nodes where the temperature gradient of the roadbed soil was maximum and minimum.Subsequently,corresponding roadbed temperature distribution maps were drawn,illustrating the changes in the temperature and position of the lowtemperature core near the TPCT over time.Furthermore,using small-scale indoor model experiments,we qualitatively concluded that moisture in the soil migrates toward the TPCT due to the temperature gradient.Thereafter,combining borehole water content data and precipitation data from the sloped terrain construction site,the formation mechanisms and timing characteristics of roadside water accumulation were analyzed.Ultimately,by integrating the ground temperature data,air temperature data,roadside water formation mechanisms,and the operating characteristics of the TPCT,it was concluded that roadside water,while in a thawed state during TPCT operation,acts as a supplementary source for moisture migration in the roadbed soil.This migration leads to cracking in the TPCT roadbed.Therefore,this study reveals a novel damage mechanism:asynchronous freeze-thaw processes induce temperature gradients,which drive the migration of roadside water into the roadbed and are responsible for the cracking damage.展开更多
Microglial activation that occurs rapidly after closed head injury may play important and complex roles in neuroinflammation-associated neuronal damage and repair.We previously reported that induced neural stem cells ...Microglial activation that occurs rapidly after closed head injury may play important and complex roles in neuroinflammation-associated neuronal damage and repair.We previously reported that induced neural stem cells can modulate the behavior of activated microglia via CXCL12/CXCR4 signaling,influencing their activation such that they can promote neurological recovery.However,the mechanism of CXCR4 upregulation in induced neural stem cells remains unclear.In this study,we found that nuclear factor-κB activation induced by closed head injury mouse serum in microglia promoted CXCL12 and tumor necrosis factor-αexpression but suppressed insulin-like growth factor-1 expression.However,recombinant complement receptor 2-conjugated Crry(CR2-Crry)reduced the effects of closed head injury mouse serum-induced nuclear factor-κB activation in microglia and the levels of activated microglia,CXCL12,and tumor necrosis factor-α.Additionally,we observed that,in response to stimulation(including stimulation by CXCL12 secreted by activated microglia),CXCR4 and Crry levels can be upregulated in induced neural stem cells via the interplay among CXCL12/CXCR4,Crry,and Akt signaling to modulate microglial activation.In agreement with these in vitro experimental results,we found that Akt activation enhanced the immunoregulatory effects of induced neural stem cell grafts on microglial activation,leading to the promotion of neurological recovery via insulin-like growth factor-1 secretion and the neuroprotective effects of induced neural stem cell grafts through CXCR4 and Crry upregulation in the injured cortices of closed head injury mice.Notably,these beneficial effects of Akt activation in induced neural stem cells were positively correlated with the therapeutic effects of induced neural stem cells on neuronal injury,cerebral edema,and neurological disorders post–closed head injury.In conclusion,our findings reveal that Akt activation may enhance the immunoregulatory effects of induced neural stem cells on microglial activation via upregulation of CXCR4 and Crry,thereby promoting induced neural stem cell–mediated improvement of neuronal injury,cerebral edema,and neurological disorders following closed head injury.展开更多
Rationally regulating the porosity of hard carbon(HC),especially the closed pores matching the low potential plateau and the ultra-microporous structure suitable for Na+embedding,has been shown to be the key to improv...Rationally regulating the porosity of hard carbon(HC),especially the closed pores matching the low potential plateau and the ultra-microporous structure suitable for Na+embedding,has been shown to be the key to improving the sodium storage performance and initial coulombic efficiency(ICE).However,the preparation of such HC materials with specific pore structures still faces great challenges.Herein,a simple pre-oxidation strategy is employed to construct abundant closed ultra-microporous structures in soy protein powder-derived HC material,achieving a significant improvement in its ICE and platform capacity.The pre-oxidation process promotes the cross-linking degree of the soy protein,thereby hindering the directional growth of graphite domains during the carbonization process.The optimized HC exhibits ultra-high platform capacity(329 mAh g^(-1))and considerable energy density(148.5 Wh kg^(-1)).Based on the ex-situ Raman and X-ray photoelectron spectroscopy characterization results,the excellent sodium storage capacity of the HC material is attributed to the synergistic effect of adsorption-intercalation/filling.The presented work provides novel insights into the synthesis of other biomass-derived HC materials with abundant closed ultra-micro pores.展开更多
The demand for high-energy-density sodium-ion batteries has driven research to increase the hard carbon(HC)plateau capacity(<0.1 V),but the plateau capacity-rate capability trade-off limits performance.We report a ...The demand for high-energy-density sodium-ion batteries has driven research to increase the hard carbon(HC)plateau capacity(<0.1 V),but the plateau capacity-rate capability trade-off limits performance.We report a way to regulate the closed pore structure and improve the rate capability of HC by the addition of graphene oxide using an emulsification process.In a non-emulsion system,graphene oxide not only shortens ion diffusion paths by inducing the formation of flakelike HC but also significantly improves the rate performance by serving as conductive bridges within the carbon matrix.The prepared graphene/phenolic resin carbon composite has reversible capacities of 362,340,319,274,119,86,69 and 48 mAh g^(−1)at current densities of 0.02,0.05,0.1,0.2,0.5,1,2 and 5 A g^(−1),respectively.When emulsification is introduced,the graphene oxide acts as a nano-confinement template,guiding the cross-linking of phenolic resin to form uniformly sized closed pores.This composite electrode material has the highest plateau capacity of 268 mAh g^(−1)at 20 mA g^(−1).展开更多
Hard carbon(HC)is considered the most promising anode material for sodium-ion batteries(SIBs)due to its high costeffectiveness and outstanding overall performance.However,the amorphous and intricate microstructure of ...Hard carbon(HC)is considered the most promising anode material for sodium-ion batteries(SIBs)due to its high costeffectiveness and outstanding overall performance.However,the amorphous and intricate microstructure of HC poses significant challenges in elucidating the structure-performance relationship,which has led to persistent misinterpretations regarding the intrinsic characteristics of closed pores.An irrational construction methodology of closed pores inevitably results in diminished plateau capacity,which severely restricts the practical application of HC in high-energy-density scenarios.This review provides a systematic exposition of the conceptual framework and origination mechanisms of closed pores,offering critical insights into their structural characteristics and formation pathways.Subsequently,by correlating lattice parameters with defect configurations,the structure-performance relationships governing desolvation kinetics and sodium storage behavior are rigorously established.Furthermore,pioneering advancements in structural engineering are critically synthesized to establish fundamental design principles for the rational modulation of closed pores in HC.It is imperative to emphasize that adopting a molecular-level perspective,coupled with a synergistic kinetic/thermodynamic approach,is critical for understanding and controlling the transformation process from open pores to closed pores.These innovative perspectives are strategically designed to accelerate the commercialization of HC,thereby catalyzing the sustainable and high-efficiency development of SIBs.展开更多
Objectives:Suicidal ideation(SI)among university students is a growing concern,influenced by anxiety,depression,and bullying.However,family closeness and peer support may act as protective factors,reducing the risk of...Objectives:Suicidal ideation(SI)among university students is a growing concern,influenced by anxiety,depression,and bullying.However,family closeness and peer support may act as protective factors,reducing the risk of SI.Therefore,this study aims to investigate the key factors influencing SI among university students,focusing on the effects of anxiety,depression,and bullying,along with the roles of family closeness and peer support.The research also explores the interactions and mechanisms between these variables.Methods:A sample of 318 university students was surveyed,evaluating six main factors:anxiety,depression,bullying,family closeness,peer support,and SI.Using the Structural Equation Modeling(SEM)and Artificial Neural Networks(ANN)approach,both compensatory and non-compensatory relationships were examined.Results:Anxiety,depression,and bullying significantly contribute to SI,with depression mediating the link between anxiety,bullying,and SI.Additionally,family closeness moderates the effects of anxiety and bullying on SI,while peer supportmoderates the effects of depression and bullying.Themultilayer perceptron analysis identifies peer support as the most influential predictor,followed by bullying,family closeness,depression,and anxiety.Conclusion:The study identifies anxiety,depression,and bullying as key factors influencing suicidal ideation(SI)among university students.Family closeness and peer support act as protective factors,moderating the effects of these variables on SI.展开更多
In conventional piezoelectric micromachined ultrasonic transducers(PMUTs),the backside acoustic energy is often used inefficiently,resulting in up to half of the energy being wasted.Vacuum encapsulation can improve th...In conventional piezoelectric micromachined ultrasonic transducers(PMUTs),the backside acoustic energy is often used inefficiently,resulting in up to half of the energy being wasted.Vacuum encapsulation can improve the energy utilization efficiency,but this technique is not compatible with state-of-the-art devices such as cantilever-based PMUTs.A closed back cavity provides an alternative method for effectively utilizing the backside acoustic energy.This paper investigates the effects of a closed back cavity on PMUT performance through theoretical analysis,simulations,and experimental verification.Increasing the cavity depth produces a periodic modulation of several key PMUT metrics,such as the relative frequency deviation and quality factor.The optimal cavity depth for PMUTs that ensures a robust resonant frequency and high quality factor is defined as a function of the acoustic wavelength.A closed back cavity also provides an effective method for continuously tuning the quality factor,and thus the bandwidth,of PMUTs.This work paves the way for air-coupled PMUTs with adjustable performance for various applications.展开更多
Loess is susceptible to loading effects such as significant changes in strength and volume variation caused by loading and wetting.In this study,considering the different connection states of pore water and gas in loe...Loess is susceptible to loading effects such as significant changes in strength and volume variation caused by loading and wetting.In this study,considering the different connection states of pore water and gas in loess fabric,the gas phase closure case is incorporated into a unified form of the generalized effective stress framework,introducing a damage parameter considering the effects of closed pore gas.The loading effects of unsaturated loess under wide variations in saturation are described in a unified way,and the model performance is verified by corresponding stress and hydraulic path tests.The results indicated that the collapse response involves the initial void ratio of loess,and the coupled outwards motion of the loading-collapse(LC)yield surface under loading enhances its structural strength.Suction-enhanced yield stress requires a greater"tensile stress"to counteract its structural stability.The nucleation of bubbles at high saturation causes a decrease in yield stress.The loading effect exhibits a smaller collapse behavior when the influence of closed gas is considered,whereas the suction path does not cross the LC in the stress space under hydraulic action for the same parameters,which amplifies the influence of closed gas on loess deformation.展开更多
Lead-free halide double perovskites have recently attracted significant attention due to their exceptional stability and favorable band gaps,making them promising candidates for solar cell applications.However,the rel...Lead-free halide double perovskites have recently attracted significant attention due to their exceptional stability and favorable band gaps,making them promising candidates for solar cell applications.However,the relationship between their structural characteristics and intrinsic band gap remains under-explored.This study presents a method to investigate the structure-band gap correlation in a typical halide double perovskite,MA_(2)Pt_(6)(MA^(+)=CH_(3)NH_(3)^(+)),using high pressure techniques.The band gap of MA_(2)PtI_(6)is effectively reduced at two different rates of 0.063 eV/GPa and 0.079 eV/GPa before and after 1.2 GPa,and progressively closes as pressure further increases.These optical changes are closely related to the pressure induced structural evolution of MA_(2)PtI_(6).Moreover,a phase transition from trigonal(R-3m)to monoclinic(P2/m)occurs at 1.2 GPa and completes by 2.0 GPa,driven by pressure-induced distortion of the[PtI_(6)]^(2-)octahedra,which is responsible for the variation of the band gap.These promising findings pave the way for potential applications in the structural and band gap tuning of halide double perovskites.展开更多
Objective Close reduction and internal fixation have gained popularity for the treatment of pelvic fractures.However,the closed reduction of bilateral displaced posterior pelvic ring disruption is a great challenge ev...Objective Close reduction and internal fixation have gained popularity for the treatment of pelvic fractures.However,the closed reduction of bilateral displaced posterior pelvic ring disruption is a great challenge even for the most experienced surgeon.In this study,we describe in detail a novel unlocking closed reduction technique(UCRT)frame that allows strong traction for bilateral posterior pelvic ring displacement and presents preliminary clinical outcomes.Methods We retrospectively reviewed 32 patients with bilateral displaced posterior pelvic ring disruptions(AO/OTA 61-C2 and C3)who were initially treated with this technique between July 2017 and July 2022.According to the AO/OTA clas-sification,there were 9 cases(28.12%)of 61-C2,and 23 cases(71.88%)of 61-C3.There were 11 males,21 females,with an average age of 38.1 years.The interval from injury to operation was 4-27 days,with a cut-off of 12.5 days(receiver operat-ing characteristic curve).Operative time,blood loss,and postoperative radiographic findings were recorded.The functional outcomes and complications were followed.Results A total of 30(93.8%)patients achieved successful closed reduction,whereas 2 required open reduction.The success-ful closed reduction rate was 95.5%(21/22)in patients whose injury-to-operation time was less than 12.5 days.The vertical displacement percent correction of the obviously displaced hemipelvis was 70.20%±16.79%on average.The average degree of pelvic deformity correction was 64.86%±17.71%.Thirty patients were followed up for at least 12 months(12-36 months),and no complications of nonunion or redisplacement were observed.The Matta-Tornetta scoring standard revealed that the excellent(25/30)and good(4/30)rate was 96.7%.The Majeed clinical efficacy score revealed that the overall excellent and good rate was 100%.One patient had INFIX-related infection,and 2 reported numbness in the lateral thigh.The numbness was improved after INFIX removal.Conclusions This study presents an updated technique for closed reduction using a UCRT frame for bilateral posterior pelvic ring disruption,which has been shown to be effective,as indicated by excellent surgical and functional outcomes.展开更多
In this article,we are concerned with the C^(2)estimates for the k-convex solutions of a class of degenerate k-Hessian equations on closed Hermitian manifolds,whose function in the right-hand side is relevant to the u...In this article,we are concerned with the C^(2)estimates for the k-convex solutions of a class of degenerate k-Hessian equations on closed Hermitian manifolds,whose function in the right-hand side is relevant to the unknown function and its gradient.We will get C^(0)estimate by promoting others′results,and get the“HMW estimate”of this equation such that the conditions of using blow-up analysis are satisfied,and the gradient estimate and second-order estimate will be obtained.Such an estimate will be helpful to study the existence for the solution of the equation.展开更多
Closed thoracic drainage can be performed using a steel-needle-guided chest tube to treat pleural effusion or pneumothorax in clinics.However,the puncture procedure during surgery is invisible,increasing the risk of s...Closed thoracic drainage can be performed using a steel-needle-guided chest tube to treat pleural effusion or pneumothorax in clinics.However,the puncture procedure during surgery is invisible,increasing the risk of surgical failure.Therefore,it is necessary to design a visualization system for closed thoracic drainage.Augmented reality(AR)technology can assist in visualizing the internal anatomical structure and determining the insertion point on the body surface.The structure of the currently used steel-needle-guided chest tube was modified by integrating it with an ultrafine diameter camera to provide real-time visualization of the puncture process.After simulation experiments,the overall registration error of the AR method was measured to be within(3.59±0.53)mm,indicating its potential for clinical application.The ultrafine diameter camera module and improved steel-needle-guided chest tube can timely reflect the position of the needle tip in the human body.A comparative experiment showed that video guidance could improve the safety of the puncture process compared to the traditional method.Finally,a qualitative evaluation of the usability of the system was conducted through a questionnaire.This system facilitates the visualization of closed thoracic drainage puncture procedure and pro-vides an implementation scheme to enhance the accuracy and safety of the operative step,which is conducive to reducing the learning curve and improving the proficiency of the doctors.展开更多
We present the essential stellar parameters of the close visual triple system HD 2893 using Al-Wardat's method for analyzing binary and multiple star systems in conjunction with Kurucz's model atmospheres.This...We present the essential stellar parameters of the close visual triple system HD 2893 using Al-Wardat's method for analyzing binary and multiple star systems in conjunction with Kurucz's model atmospheres.This method accurately computes the spectrophotometric stellar masses through a combined synthetic spectral energy distribution approach that compares the results with observed data.The vigorous approach uses spectroscopic,photometric,and dynamical analysis to yield precise results.The method implements Gaia DR3 measurements and other measurements like those of Hipparcos and 2MASS All-Sky Catalog as a guide for the best fit between the synthetic spectra and observed photometry.The analysis gives precise spectrophotometric stellar masses for the system being M_(Sph)^(A)=1.20±0.07M⊙,M_(Sph)^(B)=1.09±0.06M⊙,and M_(Sph)^(C)=0.46±0.01M⊙.It shows that the three components are main sequence stars with an estimated age of around 1.0 Gyr.When integrated with the dynamical analysis,a new dynamical parallax for the system is obtained,π_(dyn)=13.8528±0.20 mas.Additionally,the discussion covers the formation and evolution of the triple system.展开更多
Achieving long spin coherence times is crucial for quantum precision measurements,and closed-loop control techniques are often employed to accomplish this goal.Here,we demonstrate the impact of closed-loop feedback co...Achieving long spin coherence times is crucial for quantum precision measurements,and closed-loop control techniques are often employed to accomplish this goal.Here,we demonstrate the impact of closed-loop feedback control on nuclear spin precession in a metastability exchange optical pumping(MEOP)-based polarized^(3)He system.We analyze the effects of feedback theoretically and validate our predictions experimentally.With optimized feedback parameters,the spin coherence time T_(2)is extended by an order of magnitude.When the feedback strength surpasses a critical threshold,robust maser oscillations are spontaneously excited,demonstrating remarkable resistance to environmental noise and maintaining stable oscillation.This proof-of-principle experiment highlights the viability of MEOP-based^(3)He spin oscillators,especially in low-frequency domains.The operational simplicity and easy integration associated with MEOP-based systems make them particularly promising for fast,high-precision magnetic field measurements.展开更多
基金supported by the Major Science and Technology Project of Gansu Province(Grant No.24ZD13FA003 and 23ZDWA005)National Natural Science Foundation of China(Grant No.42371140,42301163,41971087 and 42272332)the program of the State Key Laboratory of Cryospheric Science and Frozen Soil Engineering,CAS(No.CSFSEZZ-2411)。
文摘In permafrost regions of the QinghaiXizang Plateau,embankments of the Qinghai-Xizang Highway and Qinghai-Xizang Railway experiencing roadside water accumulation exhibit more pronounced engineering deteriorations.A widely accepted view is that the accumulated water adjacent to the embankment possesses substantial thermal energy,which accelerates the degradation-even disappearance-of the underlying permafrost.Moreover,the presence of roadside water keeps the embankment soil in a persistently high-moisture state,thereby making the frozen-soil embankment more susceptible to deformation under traffic loading.However,in the permafrost regions of the QinghaiXizang Plateau,deteriorations of embankments affected by roadside water are more commonly manifested as undulating pavement surfaces,and extensive crack networks appear on the embankment crest even where thermosyphons are installed.These manifestations are not fully consistent with the deterioration mechanisms proposed by existing viewpoints.We propose the hypothesis that temperature gradients,formed due to the freezing and thawing processes between the roadside wateraffected soil and the roadbed soil,lead to moisture migration under the influence of temperature gradients,resulting in frost heave and thaw settlement in the roadbed soil.To validate this hypothesis,we conducted the following investigations sequentially.Initially,we selected a roadbed with a thermosyphon(TPCT)system,which has a significant cooling effect,as the study object.By analyzing the temperature monitoring data of the roadbed section,the temperature variance was calculated to identify the time nodes where the temperature gradient of the roadbed soil was maximum and minimum.Subsequently,corresponding roadbed temperature distribution maps were drawn,illustrating the changes in the temperature and position of the lowtemperature core near the TPCT over time.Furthermore,using small-scale indoor model experiments,we qualitatively concluded that moisture in the soil migrates toward the TPCT due to the temperature gradient.Thereafter,combining borehole water content data and precipitation data from the sloped terrain construction site,the formation mechanisms and timing characteristics of roadside water accumulation were analyzed.Ultimately,by integrating the ground temperature data,air temperature data,roadside water formation mechanisms,and the operating characteristics of the TPCT,it was concluded that roadside water,while in a thawed state during TPCT operation,acts as a supplementary source for moisture migration in the roadbed soil.This migration leads to cracking in the TPCT roadbed.Therefore,this study reveals a novel damage mechanism:asynchronous freeze-thaw processes induce temperature gradients,which drive the migration of roadside water into the roadbed and are responsible for the cracking damage.
基金supported by the National Natural Science Foundation of China,Nos.82271397(to MG),82001293(to MG),82171355(to RX),81971295(to RX),and 81671189(to RX)。
文摘Microglial activation that occurs rapidly after closed head injury may play important and complex roles in neuroinflammation-associated neuronal damage and repair.We previously reported that induced neural stem cells can modulate the behavior of activated microglia via CXCL12/CXCR4 signaling,influencing their activation such that they can promote neurological recovery.However,the mechanism of CXCR4 upregulation in induced neural stem cells remains unclear.In this study,we found that nuclear factor-κB activation induced by closed head injury mouse serum in microglia promoted CXCL12 and tumor necrosis factor-αexpression but suppressed insulin-like growth factor-1 expression.However,recombinant complement receptor 2-conjugated Crry(CR2-Crry)reduced the effects of closed head injury mouse serum-induced nuclear factor-κB activation in microglia and the levels of activated microglia,CXCL12,and tumor necrosis factor-α.Additionally,we observed that,in response to stimulation(including stimulation by CXCL12 secreted by activated microglia),CXCR4 and Crry levels can be upregulated in induced neural stem cells via the interplay among CXCL12/CXCR4,Crry,and Akt signaling to modulate microglial activation.In agreement with these in vitro experimental results,we found that Akt activation enhanced the immunoregulatory effects of induced neural stem cell grafts on microglial activation,leading to the promotion of neurological recovery via insulin-like growth factor-1 secretion and the neuroprotective effects of induced neural stem cell grafts through CXCR4 and Crry upregulation in the injured cortices of closed head injury mice.Notably,these beneficial effects of Akt activation in induced neural stem cells were positively correlated with the therapeutic effects of induced neural stem cells on neuronal injury,cerebral edema,and neurological disorders post–closed head injury.In conclusion,our findings reveal that Akt activation may enhance the immunoregulatory effects of induced neural stem cells on microglial activation via upregulation of CXCR4 and Crry,thereby promoting induced neural stem cell–mediated improvement of neuronal injury,cerebral edema,and neurological disorders following closed head injury.
基金supported by the National Natural Science Foundation of China(42167068,22269020)the Gansu Province Higher Education Industry Support Plan Project(2023CYZC-68)the Central Guidance for Local Science and Technology Development Funds Project(YDZX20216200001007)。
文摘Rationally regulating the porosity of hard carbon(HC),especially the closed pores matching the low potential plateau and the ultra-microporous structure suitable for Na+embedding,has been shown to be the key to improving the sodium storage performance and initial coulombic efficiency(ICE).However,the preparation of such HC materials with specific pore structures still faces great challenges.Herein,a simple pre-oxidation strategy is employed to construct abundant closed ultra-microporous structures in soy protein powder-derived HC material,achieving a significant improvement in its ICE and platform capacity.The pre-oxidation process promotes the cross-linking degree of the soy protein,thereby hindering the directional growth of graphite domains during the carbonization process.The optimized HC exhibits ultra-high platform capacity(329 mAh g^(-1))and considerable energy density(148.5 Wh kg^(-1)).Based on the ex-situ Raman and X-ray photoelectron spectroscopy characterization results,the excellent sodium storage capacity of the HC material is attributed to the synergistic effect of adsorption-intercalation/filling.The presented work provides novel insights into the synthesis of other biomass-derived HC materials with abundant closed ultra-micro pores.
文摘A survey of recent progress on the multiplicity and stability problems for closed characteristics on compact convex hypersurfaces in R^(2n) is given.
文摘The demand for high-energy-density sodium-ion batteries has driven research to increase the hard carbon(HC)plateau capacity(<0.1 V),but the plateau capacity-rate capability trade-off limits performance.We report a way to regulate the closed pore structure and improve the rate capability of HC by the addition of graphene oxide using an emulsification process.In a non-emulsion system,graphene oxide not only shortens ion diffusion paths by inducing the formation of flakelike HC but also significantly improves the rate performance by serving as conductive bridges within the carbon matrix.The prepared graphene/phenolic resin carbon composite has reversible capacities of 362,340,319,274,119,86,69 and 48 mAh g^(−1)at current densities of 0.02,0.05,0.1,0.2,0.5,1,2 and 5 A g^(−1),respectively.When emulsification is introduced,the graphene oxide acts as a nano-confinement template,guiding the cross-linking of phenolic resin to form uniformly sized closed pores.This composite electrode material has the highest plateau capacity of 268 mAh g^(−1)at 20 mA g^(−1).
基金supported by the National Natural Science Foundation of China(22379165,U21A20284)Natural Science Foundation of Hunan Province(2023JJ40704).
文摘Hard carbon(HC)is considered the most promising anode material for sodium-ion batteries(SIBs)due to its high costeffectiveness and outstanding overall performance.However,the amorphous and intricate microstructure of HC poses significant challenges in elucidating the structure-performance relationship,which has led to persistent misinterpretations regarding the intrinsic characteristics of closed pores.An irrational construction methodology of closed pores inevitably results in diminished plateau capacity,which severely restricts the practical application of HC in high-energy-density scenarios.This review provides a systematic exposition of the conceptual framework and origination mechanisms of closed pores,offering critical insights into their structural characteristics and formation pathways.Subsequently,by correlating lattice parameters with defect configurations,the structure-performance relationships governing desolvation kinetics and sodium storage behavior are rigorously established.Furthermore,pioneering advancements in structural engineering are critically synthesized to establish fundamental design principles for the rational modulation of closed pores in HC.It is imperative to emphasize that adopting a molecular-level perspective,coupled with a synergistic kinetic/thermodynamic approach,is critical for understanding and controlling the transformation process from open pores to closed pores.These innovative perspectives are strategically designed to accelerate the commercialization of HC,thereby catalyzing the sustainable and high-efficiency development of SIBs.
文摘Objectives:Suicidal ideation(SI)among university students is a growing concern,influenced by anxiety,depression,and bullying.However,family closeness and peer support may act as protective factors,reducing the risk of SI.Therefore,this study aims to investigate the key factors influencing SI among university students,focusing on the effects of anxiety,depression,and bullying,along with the roles of family closeness and peer support.The research also explores the interactions and mechanisms between these variables.Methods:A sample of 318 university students was surveyed,evaluating six main factors:anxiety,depression,bullying,family closeness,peer support,and SI.Using the Structural Equation Modeling(SEM)and Artificial Neural Networks(ANN)approach,both compensatory and non-compensatory relationships were examined.Results:Anxiety,depression,and bullying significantly contribute to SI,with depression mediating the link between anxiety,bullying,and SI.Additionally,family closeness moderates the effects of anxiety and bullying on SI,while peer supportmoderates the effects of depression and bullying.Themultilayer perceptron analysis identifies peer support as the most influential predictor,followed by bullying,family closeness,depression,and anxiety.Conclusion:The study identifies anxiety,depression,and bullying as key factors influencing suicidal ideation(SI)among university students.Family closeness and peer support act as protective factors,moderating the effects of these variables on SI.
基金supported in part by the National Natural Science Foundation of China(NSFC)(Grant No.62001322)in part by the National Key Research and Development Program(Grant No.2020YFB2008800).
文摘In conventional piezoelectric micromachined ultrasonic transducers(PMUTs),the backside acoustic energy is often used inefficiently,resulting in up to half of the energy being wasted.Vacuum encapsulation can improve the energy utilization efficiency,but this technique is not compatible with state-of-the-art devices such as cantilever-based PMUTs.A closed back cavity provides an alternative method for effectively utilizing the backside acoustic energy.This paper investigates the effects of a closed back cavity on PMUT performance through theoretical analysis,simulations,and experimental verification.Increasing the cavity depth produces a periodic modulation of several key PMUT metrics,such as the relative frequency deviation and quality factor.The optimal cavity depth for PMUTs that ensures a robust resonant frequency and high quality factor is defined as a function of the acoustic wavelength.A closed back cavity also provides an effective method for continuously tuning the quality factor,and thus the bandwidth,of PMUTs.This work paves the way for air-coupled PMUTs with adjustable performance for various applications.
基金funded by the National Natural Science Foundation of China (Grant Nos.42230712,42472357)the China Postdoctoral Science Foundation (Grant No.2023MD734211).
文摘Loess is susceptible to loading effects such as significant changes in strength and volume variation caused by loading and wetting.In this study,considering the different connection states of pore water and gas in loess fabric,the gas phase closure case is incorporated into a unified form of the generalized effective stress framework,introducing a damage parameter considering the effects of closed pore gas.The loading effects of unsaturated loess under wide variations in saturation are described in a unified way,and the model performance is verified by corresponding stress and hydraulic path tests.The results indicated that the collapse response involves the initial void ratio of loess,and the coupled outwards motion of the loading-collapse(LC)yield surface under loading enhances its structural strength.Suction-enhanced yield stress requires a greater"tensile stress"to counteract its structural stability.The nucleation of bubbles at high saturation causes a decrease in yield stress.The loading effect exhibits a smaller collapse behavior when the influence of closed gas is considered,whereas the suction path does not cross the LC in the stress space under hydraulic action for the same parameters,which amplifies the influence of closed gas on loess deformation.
基金supported by the National Natural Science Foundation of China(Grant No.12474414)the Natural Science Foundation of Henan(Grant No.242300421157)the ADXRD measurement was performed at the 4W2 beamline,the Beijing Synchrotron Radiation Facility(BSRF).
文摘Lead-free halide double perovskites have recently attracted significant attention due to their exceptional stability and favorable band gaps,making them promising candidates for solar cell applications.However,the relationship between their structural characteristics and intrinsic band gap remains under-explored.This study presents a method to investigate the structure-band gap correlation in a typical halide double perovskite,MA_(2)Pt_(6)(MA^(+)=CH_(3)NH_(3)^(+)),using high pressure techniques.The band gap of MA_(2)PtI_(6)is effectively reduced at two different rates of 0.063 eV/GPa and 0.079 eV/GPa before and after 1.2 GPa,and progressively closes as pressure further increases.These optical changes are closely related to the pressure induced structural evolution of MA_(2)PtI_(6).Moreover,a phase transition from trigonal(R-3m)to monoclinic(P2/m)occurs at 1.2 GPa and completes by 2.0 GPa,driven by pressure-induced distortion of the[PtI_(6)]^(2-)octahedra,which is responsible for the variation of the band gap.These promising findings pave the way for potential applications in the structural and band gap tuning of halide double perovskites.
基金supported by the National Key Research and Development Program of China(2022YFC2504303)Innovation Foundation of National Clinical Research Center for Orthopaedics,Sports Medicine&Rehabilitation(2021-NCRC-CXJJ-ZH-24)Medical Innovation and Transformation Incubation Project of Tongji Hospital(2022ZHFY10).
文摘Objective Close reduction and internal fixation have gained popularity for the treatment of pelvic fractures.However,the closed reduction of bilateral displaced posterior pelvic ring disruption is a great challenge even for the most experienced surgeon.In this study,we describe in detail a novel unlocking closed reduction technique(UCRT)frame that allows strong traction for bilateral posterior pelvic ring displacement and presents preliminary clinical outcomes.Methods We retrospectively reviewed 32 patients with bilateral displaced posterior pelvic ring disruptions(AO/OTA 61-C2 and C3)who were initially treated with this technique between July 2017 and July 2022.According to the AO/OTA clas-sification,there were 9 cases(28.12%)of 61-C2,and 23 cases(71.88%)of 61-C3.There were 11 males,21 females,with an average age of 38.1 years.The interval from injury to operation was 4-27 days,with a cut-off of 12.5 days(receiver operat-ing characteristic curve).Operative time,blood loss,and postoperative radiographic findings were recorded.The functional outcomes and complications were followed.Results A total of 30(93.8%)patients achieved successful closed reduction,whereas 2 required open reduction.The success-ful closed reduction rate was 95.5%(21/22)in patients whose injury-to-operation time was less than 12.5 days.The vertical displacement percent correction of the obviously displaced hemipelvis was 70.20%±16.79%on average.The average degree of pelvic deformity correction was 64.86%±17.71%.Thirty patients were followed up for at least 12 months(12-36 months),and no complications of nonunion or redisplacement were observed.The Matta-Tornetta scoring standard revealed that the excellent(25/30)and good(4/30)rate was 96.7%.The Majeed clinical efficacy score revealed that the overall excellent and good rate was 100%.One patient had INFIX-related infection,and 2 reported numbness in the lateral thigh.The numbness was improved after INFIX removal.Conclusions This study presents an updated technique for closed reduction using a UCRT frame for bilateral posterior pelvic ring disruption,which has been shown to be effective,as indicated by excellent surgical and functional outcomes.
文摘In this article,we are concerned with the C^(2)estimates for the k-convex solutions of a class of degenerate k-Hessian equations on closed Hermitian manifolds,whose function in the right-hand side is relevant to the unknown function and its gradient.We will get C^(0)estimate by promoting others′results,and get the“HMW estimate”of this equation such that the conditions of using blow-up analysis are satisfied,and the gradient estimate and second-order estimate will be obtained.Such an estimate will be helpful to study the existence for the solution of the equation.
基金the Shanghai Municipal Education Commission-Gaofeng Clinical Medicine Grant(No.20172005)。
文摘Closed thoracic drainage can be performed using a steel-needle-guided chest tube to treat pleural effusion or pneumothorax in clinics.However,the puncture procedure during surgery is invisible,increasing the risk of surgical failure.Therefore,it is necessary to design a visualization system for closed thoracic drainage.Augmented reality(AR)technology can assist in visualizing the internal anatomical structure and determining the insertion point on the body surface.The structure of the currently used steel-needle-guided chest tube was modified by integrating it with an ultrafine diameter camera to provide real-time visualization of the puncture process.After simulation experiments,the overall registration error of the AR method was measured to be within(3.59±0.53)mm,indicating its potential for clinical application.The ultrafine diameter camera module and improved steel-needle-guided chest tube can timely reflect the position of the needle tip in the human body.A comparative experiment showed that video guidance could improve the safety of the puncture process compared to the traditional method.Finally,a qualitative evaluation of the usability of the system was conducted through a questionnaire.This system facilitates the visualization of closed thoracic drainage puncture procedure and pro-vides an implementation scheme to enhance the accuracy and safety of the operative step,which is conducive to reducing the learning curve and improving the proficiency of the doctors.
基金a joint project of the University of Massachusetts and the Infrared Processing and Analysis Center/California Institute of Technology,funded by the National Aeronautics and Space Administration and the National Science Foundation。
文摘We present the essential stellar parameters of the close visual triple system HD 2893 using Al-Wardat's method for analyzing binary and multiple star systems in conjunction with Kurucz's model atmospheres.This method accurately computes the spectrophotometric stellar masses through a combined synthetic spectral energy distribution approach that compares the results with observed data.The vigorous approach uses spectroscopic,photometric,and dynamical analysis to yield precise results.The method implements Gaia DR3 measurements and other measurements like those of Hipparcos and 2MASS All-Sky Catalog as a guide for the best fit between the synthetic spectra and observed photometry.The analysis gives precise spectrophotometric stellar masses for the system being M_(Sph)^(A)=1.20±0.07M⊙,M_(Sph)^(B)=1.09±0.06M⊙,and M_(Sph)^(C)=0.46±0.01M⊙.It shows that the three components are main sequence stars with an estimated age of around 1.0 Gyr.When integrated with the dynamical analysis,a new dynamical parallax for the system is obtained,π_(dyn)=13.8528±0.20 mas.Additionally,the discussion covers the formation and evolution of the triple system.
基金supported by the National Natural Science Foundation of China(Grant No.U2230207)。
文摘Achieving long spin coherence times is crucial for quantum precision measurements,and closed-loop control techniques are often employed to accomplish this goal.Here,we demonstrate the impact of closed-loop feedback control on nuclear spin precession in a metastability exchange optical pumping(MEOP)-based polarized^(3)He system.We analyze the effects of feedback theoretically and validate our predictions experimentally.With optimized feedback parameters,the spin coherence time T_(2)is extended by an order of magnitude.When the feedback strength surpasses a critical threshold,robust maser oscillations are spontaneously excited,demonstrating remarkable resistance to environmental noise and maintaining stable oscillation.This proof-of-principle experiment highlights the viability of MEOP-based^(3)He spin oscillators,especially in low-frequency domains.The operational simplicity and easy integration associated with MEOP-based systems make them particularly promising for fast,high-precision magnetic field measurements.
