Network processors are used in the core node of network to flexibly process packet streams. With the increase of performance, the power of network processor increases fast, and power and cooling become a bottleneck. A...Network processors are used in the core node of network to flexibly process packet streams. With the increase of performance, the power of network processor increases fast, and power and cooling become a bottleneck. Architecture-level power conscious design must go beyond low-level circuit design. Architectural power and performance tradeoff should be considered at the same time. Simulation is an efficient method to design modem network processor before making chip. In order to achieve the tradeoff between performance and power, the processor simulator is used to design the architecture of network processor. Using Netbeneh, Commubench benchmark and processor simulator-SimpleScalar, the performance and power of network processor are quantitatively evaluated. New performance tradeoff evaluation metric is proposed to analyze the architecture of network processor. Based on the high performance lnteI IXP 2800 Network processor eonfignration, optimized instruction fetch width and speed ,instruction issue width, instruction window size are analyzed and selected. Simulation resuits show that the tradeoff design method makes the usage of network processor more effectively. The optimal key parameters of network processor are important in architecture-level design. It is meaningful for the next generation network processor design.展开更多
The adsorptive denitrification performance of MIL-101(Cr)-0.5 toward pyridine,aniline or quinoline in simulated fuels with basic nitrogen content of 1732μg/g was evaluated separately.Furthermore,the effects of adsorp...The adsorptive denitrification performance of MIL-101(Cr)-0.5 toward pyridine,aniline or quinoline in simulated fuels with basic nitrogen content of 1732μg/g was evaluated separately.Furthermore,the effects of adsorption temperature,adsorption time and adsorbent dosage on their adsorptive denitrification performance were systematically investigated.The experimental results demonstrated that under a fixed adsorbent dosage of 0.05 g and a simulated fuel volume of 10 mL,the optimal removal efficiency for aniline was achieved at 30℃ within 30 min,whereas higher temperatures and longer times(40℃and 40 min)were required for effective removal of pyridine and quinoline.Density Functional Theory(DFT)calculations were conducted via Materials Studio(MS)software to study the adsorptive denitrification mechanism of MIL-101(Cr)toward these three basic nitrogen-containing compounds.The simulation calculation results revealed that the interaction between pyridine and MIL-101(Cr)primarily involved coordination adsorption.In contrast,the interaction between aniline or quinoline and MIL-101(Cr)proceeded mainly through coordination,with additional contributions fromπ-complexation and hydrogen bonding.The overall adsorption strength order is pyridine>aniline>quinoline.During the adsorption process,pyridine and quinoline transfer electrons to the MIL-101(Cr)surface through the H→C→N→Cr^(3+)pathway,while aniline transfers electrons to the MIL-101(Cr)surface through various pathways,including N→Cr^(3+),N→C→Cr^(3+)and N→H→O.Furthermore,adsorption kinetics studies indicated that the adsorption processes for all three basic nitrogen-containing compounds followed the quasi second order kinetic models.The experimental results on the effect of benzene on the adsorptive denitrification performance of MIL-101(Cr)-0.5 demonstrated that benzene exerted a more significant impact on the adsorption of aniline and quinoline.Finally,the adsorbent was regenerated using ethanol washing.It was found that MIL-101(Cr)-0.5 retained stable denitrification performance after two regeneration cycles.展开更多
To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content ...To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content in coal)catalysts were prepared by the incipient wetness impregnation method,followed by acid washing to remove calcium-containing minerals.Comprehensive characterization and low-temperature denitrification tests revealed that calcite-induced structural modulation of coal-derived AC significantly enhances catalytic activity.Specifically,NO conversion increased from 88.3%of Mn-Ce/De-AC to 91.7%of Mn-Ce/De-AC-1CaCO_(3)(210℃).The improved SCR denitrification activity results from the enhancement of physicochemical properties including higher Mn^(4+)content and Ce^(4+)/Ce^(3+)ratio,an abundance of chemisorbed oxygen and acidic sites,which could strengthen the SCR reaction pathways(richer NH_(3)activated species and bidentate nitrate active species).Therefore,NO removal is enhanced.展开更多
In composite solid propellants with high aluminum(Al)content and low burning rate,incomplete combustion of the Al powder may occur.In this study,varying lithium(Li)content in Al-Li alloy powder was utilized instead of...In composite solid propellants with high aluminum(Al)content and low burning rate,incomplete combustion of the Al powder may occur.In this study,varying lithium(Li)content in Al-Li alloy powder was utilized instead of pure aluminum particles to mitigate agglomeration and enhance the combustion efficiency of solid propellants(Combustion efficiency herein refers to the completeness of metallic fuel oxidation,quantified as the ratio of actual-to-theoretical energy released during combustion)with high Al content and low burning rates.The impact of Al-Li alloy with different Li contents on combustion and agglomeration of solid propellant was investigated using explosion heat,combustion heat,differential thermal analysis(DTA),thermos-gravimetric analysis(TG),dynamic high-pressure combustion test,ignition experiment of small solid rocket motor(SRM)tests,condensation combustion product collection,and X-ray diffraction techniques(XRD).Compared with pure Al,Al-Li alloys exhibit higher combustion heat,which contributes to improved combustion efficiency in Al-Li alloy-containing propellants.DTA and TG analyses demonstrated higher reactivity and lower ignition temperatures for Al-Li alloys.High-pressure combustion experiments at 5 MPa showed that Al-Li alloy fuel significantly decreases combustion agglomeration.The results from theφ75 mm andφ165 mm SRM and XRD tests further support this finding.This study provides novel insights into the combustion and agglomeration behaviors of high-Al,low-burning-rate composite solid propellants and supports the potential application of Al-Li alloys in advanced propellant formulations.展开更多
The rapid advancements in computer vision(CV)technology have transformed the traditional approaches to material microstructure analysis.This review outlines the history of CV and explores the applications of deep-lear...The rapid advancements in computer vision(CV)technology have transformed the traditional approaches to material microstructure analysis.This review outlines the history of CV and explores the applications of deep-learning(DL)-driven CV in four key areas of materials science:microstructure-based performance prediction,microstructure information generation,microstructure defect detection,and crystal structure-based property prediction.The CV has significantly reduced the cost of traditional experimental methods used in material performance prediction.Moreover,recent progress made in generating microstructure images and detecting microstructural defects using CV has led to increased efficiency and reliability in material performance assessments.The DL-driven CV models can accelerate the design of new materials with optimized performance by integrating predictions based on both crystal and microstructural data,thereby allowing for the discovery and innovation of next-generation materials.Finally,the review provides insights into the rapid interdisciplinary developments in the field of materials science and future prospects.展开更多
To investigate the overall performance of reverse energy bypass scramjet,firstly a variable spe⁃cific heat method combined with a chemical balance calculation module for combustion products were used to es⁃tablish a b...To investigate the overall performance of reverse energy bypass scramjet,firstly a variable spe⁃cific heat method combined with a chemical balance calculation module for combustion products were used to es⁃tablish a benchmark scramjet performance evaluation model.Based on the test data of typical flying point of Mach 7 with the altitude of 29 km,the reliability of the model was verified.The deviations of parameters such as the to⁃tal pressure loss of combustor between the model and the test data were analyzed.Furtherly,an analytical method for post-combustion magnetohydrodynamic power generation was established;by embedding the above method into the overall performance evaluation model,performance prediction considering the power generation effect was realized.Finally,based on the above model,variety regulations of the inlet and the outlet parameters of the power generation channel and performance parameters including the engine specific impulse and the unit thrust under different enthalpy extraction ratios and load factors were analyzed.It could be concluded that the model can reliably predict the variations of key parameters.As the value of the load factor increases,the value of the conduc⁃tivity required to reach the specified enthalpy extraction ratio first decreases and then increases,which is approxi⁃mately parabolic.In order to reduce the demand for the gas conductivity for MHD power generation,the load fac⁃tor should be around 0.5.When the load factor is 0.4 and the magnetic induction intensity is 2.5 T,if the enthalpy extraction ratio reaches 0.5%,the engine specific impulse performance reduces about 3.58%.展开更多
In the context of the revolution in new technologies,a key question is whether the rapid growth of the digital economy,driven by digital technologies,has improved regional innovation performance.Using inter-provincial...In the context of the revolution in new technologies,a key question is whether the rapid growth of the digital economy,driven by digital technologies,has improved regional innovation performance.Using inter-provincial panel data from China(2012–2022)and adopting a business environment perspective,this study applies a Panel Extended Regression Model(PERM),a Panel Simultaneous Equation Model(PSEM),and a Tobit-IV model to analyze how the development of the digital economy influences regional innovation.The results reveal a pronounced U-shaped relationship between the digital economy and the regional innovation performance at the provincial level in China,with the business environment serving as a significant mediator in this relationship.Moreover,regional innovation performance in China exhibits a“ratchet effect,”with the impact of the digital economy varying markedly across regions.While the eastern and western regions have entered an upward phase,whereby the digital economy boosts innovation,the central region displays a weaker effect.Further analysis indicates that the synergy between the business environment and the digital economy in driving innovation remains suboptimal.These findings were supported by robust checks.This study offers theoretical insights and empirical evidence that support the coordinated development of digital government and the digital factor market,as well as business environment reforms that are in alignment with the innovation demands of the digital era.展开更多
Al/NH_(4)CoF_(3)-Φ(Φ=0.5,1.0,1.5,2.0,and 3.0)binary composites and Al-NH_(4)CoF_(3)@P(VDF-HFP)ternary composites are fabricated via ultrasonication-assisted blending and electrostatic spraying.The effect of equivale...Al/NH_(4)CoF_(3)-Φ(Φ=0.5,1.0,1.5,2.0,and 3.0)binary composites and Al-NH_(4)CoF_(3)@P(VDF-HFP)ternary composites are fabricated via ultrasonication-assisted blending and electrostatic spraying.The effect of equivalence ratio(Φ)on the reaction properties is systematically investigated in the binary Al/NH_(4)CoF_(3)system.For ternary systems,electrostatic spraying allows both components to be efficiently encapsulated by P(VDF-HFP)and to achieve structural stabilization and enhanced reactivity through synergistic interfacial interactions.Morphological analysis using SEM/TEM revealed that P(VDF-HFP)formed a protective layer on Al and NH_(4)CoF_(3)particles,improving dispersion,hydrophobicity(water contact angle increased by 80.5%compared to physically mixed composites),and corrosion resistance.Thermal decomposition of NH_(4)CoF_(3)occurred at 265℃,releasing NH_(3)and HF,which triggered exothermic reactions with Al.The ternary composites exhibited a narrowed main reaction temperature range and concentrated heat release,attributed to improved interfacial contact and polymer decomposition.Combustion tests demonstrated that Al-NH_(4)CoF_(3)@P(VDF-HFP)achieved self-sustaining combustion.In addition,a simple validation was done by replacing the Al component in the aluminium-containing propellant,demonstrating its potential application in the propellant field.This work establishes a novel strategy for designing stable,high-energy composites with potential applications in advanced propulsion systems.展开更多
Background The decline in reproductive performance of aged hens is mainly attributed to oxidative damage in reproductive organs,hepatic lipid metabolism disorders,and intestinal microbiota dysbiosis.Glycyrrhizin(GL)ha...Background The decline in reproductive performance of aged hens is mainly attributed to oxidative damage in reproductive organs,hepatic lipid metabolism disorders,and intestinal microbiota dysbiosis.Glycyrrhizin(GL)has been proven to enhance antioxidant capacity,regulate lipid metabolism and gut microbiota in mammals,but its efficacy in hens remains unclear.Hence,this study aimed to investigate whether dietary GL supplementation improves reproductive performance in hens during the late laying stage by modulating intestinal microbiota composition,hepatic lipid metabolism and ovarian antioxidant status.Results Dietary supplementation with 100 mg/kg GL significantly improved the egg production rate,egg quality,and hatching rate in aged breeder hens(P<0.05).GL supplementation also increased the serum levels of HDLC,TP and ALB,and enhanced the antioxidant capacity in both serum and ovary(P<0.05).In addition,dietary GL elevated the serum progesterone(P4)levels by enhancing the transcription level of steroid synthesis key enzymes(CYP11A1 and 3β-HSD)in the ovary(P<0.05).Dietary GL also promoted the synthesis and transport of vitellogenin(VTG)by upregulating the VTG-Ⅱ(P<0.05)and APOV1(P=0.077)expression levels in the liver,thereby increasing the number of grade follicles and small yellow follicles.Moreover,dietary GL enhanced hepatic fatty acidβ-oxidation by upregulating PPARαand CPT-I(P<0.05),and downregulating ACC expression levels(P<0.05).In agreement,liver metabolomics analysis revealed that dietary GL supplementation significantly altered hepatic metabolism,with 389 differentially identified metabolites(P<0.05).The key metabolites(e.g.,taurocholic acid,tauroursodeoxycholic acid,nicotinuric acid,glycodeoxycholic acid(hydrate))were identified,and they were mainly functionally enriched in betaalanine metabolism nicotinate,taurine and hypotaurine metabolism(P<0.05).Finally,16S rRNA gene sequencing revealed that dietary GL reversed age-induced changes in gut microbiota composition,characterized by a significant increase in Lactobacillus abundance and a decrease in Bacteroides(P<0.05).Conclusions These results collectively demonstrate that dietary supplementation with 100 mg/kg GL improved reproductive performance by reversing age-induced changes in gut microbiota,enhancing hepatic vitellogenin synthesis,and ameliorating ovarian function in aged breeder hens.This study suggests that dietary GL is a potential strategy to improve reproductive performance in broiler breeder hens during the late laying period.展开更多
The core components of an aircraft and the source of its lift are its wings,but lift generation is disrupted by the high temperature and pressure generated on the wing surface when an aircraft gun is fired.Here,to inv...The core components of an aircraft and the source of its lift are its wings,but lift generation is disrupted by the high temperature and pressure generated on the wing surface when an aircraft gun is fired.Here,to investigate how this process influences the aerodynamic parameters of aircraft wings,the k-ωshearstress-transport turbulence model and the nested dynamic grid technique are used to analyze numerically the transient process of the muzzle jet of a 30-mm small-caliber aircraft gun in highaltitude(10 km)flight with an incoming Mach number of Ma=0.8.For comparison,two other models are established,one with no projectile and the other with no wing.The results indicate that when the aircraft gun is fired,the muzzle jet acts on the wing,creating a pressure field thereon.The uneven distribution of high pressure greatly reduces the lift of the aircraft,causing oscillations in its drag and disrupting its dynamic balance,thereby affecting its flight speed and attitude.Meanwhile,the muzzle jet is obstructed by the wing,and its flow field is distorted and deformed,developing upward toward the wing.Because of the influence of the incoming flow,the shockwave front of the projectile changes from a smooth spherical shape to an irregular one,and the motion parameters of the projectile are also greatly affected by oscillations.The present results provide an important theoretical basis for how the guns of fighter aircraft influence the aerodynamic performance of the wings.展开更多
The negative Poisson’s ratio(NPR)bolt is an innovative support element distinguished by its high strength,elongation,and a slightly negative Poisson’s ratio.Unlike conventional prestressed(PR)bolts with a positive P...The negative Poisson’s ratio(NPR)bolt is an innovative support element distinguished by its high strength,elongation,and a slightly negative Poisson’s ratio.Unlike conventional prestressed(PR)bolts with a positive Poisson’s ratio,the NPR bolt exhibits a quasi-ideal plastic response without a prominent yield platform,enabling it to sustain high prestress with a substantial safety margin,which is particularly advantageous for jointed rock masses.However,investigations into the shear resistance mechanisms of NPR bolts under varying prestress levels remain limited.This study conducted full-scale double shear tests to assess the shear strength,deformation behavior,energy absorption,and failure mechanisms of NPR bolts under different prestress conditions.To ensure a fair comparison with PR bolts,a prestress utilization coefficient(PUC)was introduced.The results reveal that at a PUC of 0.25,the NPR bolt achieved peak axial force,shear displacement,and peak shear force values that are 2.41,1.88,and 2.13 times greater than those of the PR bolt,respectively.Shear performance was optimized at a prestress level of 100 kN,with energy absorption reaching 47.1 kJ,which is 2.8 times that of the PR bolt.Furthermore,the necking ratio was significantly reduced,indicating more distributed plastic deformation and delayed failure.Field applications verified the superior performance,resulting in a 27.4%reduction in roof settlement and enhanced structural integrity.These findings confirm that NPR bolts possess excellent shear resistance,energy absorption,and deformation adaptability,and optimizing prestress significantly enhances their support performance,providing a strong basis for geotechnical engineering applications.展开更多
Lithium-sulfur(Li-S)batteries boast a theoretical energy density as high as 2600 Wh·kg^(−1),positioning them as a highly attractive option for future advanced energy storage systems.Challenges such as slow transf...Lithium-sulfur(Li-S)batteries boast a theoretical energy density as high as 2600 Wh·kg^(−1),positioning them as a highly attractive option for future advanced energy storage systems.Challenges such as slow transformation kinetics and shuttle effects associated with lithium polysulfides(LiPSs)have seriously hindered their practical applications.In this paper,we present a new method for the synthesis of hollow carbon-sphere-supported Co monatomic catalysts(Co-N-C).This new synthesis method achieves pyrolytic coordination using a precursor rich in imide(-RC=N-)polymers.This synthesis method not only improves the adsorbability and catalytic activity of LiPS but also significantly weakens the shuttle effect and generates Co-N-C with superior conductivity,abundant hollow structures,and a high specific surface area,thus efficiently capturing and restricting the movement of LiPS intermediates.The dispersed Co monoatomic catalysts(Co SACs)were anchored to a highly conductive nitrogen-doped carbon framework and exhibited symmetric N-coordination active sites(Co-N_(4))to ensure fast redox kinetics of LiPS and Li_(2)S_(2)/Li_(2)S solid-state products.The lithium-sulfur battery with Co-N-C as the sulfur carrier showed excellent discharging capacity of 1146.6 mAh·g^(−1) at a discharge rate of 0.5 C and maintained excellent performance at a high discharge rate of 2 C.The capacity decay rate in 500 cycles was only 0.086%per cycle,reflecting excellent long-term cycle stability.This study highlights the key role of the synergistic effect between single-atom cobalt catalysts and hollow carbon spheres in enhancing the efficiency of lithium-sulfur(Li-S)batteries.It also provides valuable insights into the construction and fabrication of highly active monatomic catalysts.The catalytic conversion efficiency of lithium polysulfides is significantly enhanced when embedded in hollow carbon architectures,which serves as a critical strategy for optimizing the electrochemical behavior of next-generation Li-S batteries.展开更多
The presence of a surface oxide film(B_(2)O_(3))on boron(B)particles significantly compromises their combustion efficiency and kinetic performance in fuel-rich solid propellants.This study proposes an innovative conti...The presence of a surface oxide film(B_(2)O_(3))on boron(B)particles significantly compromises their combustion efficiency and kinetic performance in fuel-rich solid propellants.This study proposes an innovative continuous modification strategy combining non-thermal plasma(NTP)etching with fluorocarbon passivation.Characterization and kinetic analysis revealed that reactive plasma species—including atomic hydrogen(H),electronically excited molecular hydrogen(H_(2)^(*)),vibrationally excited molecular hydrogen(H_(2)v),and hydrogen ions(H^(+))—dominate the reduction of B_(2)O_(3)through lowering the transition energy barrier and shifting the reaction spontaneity.Subsequent argon plasma fragmentation of C_(8)F_(18)generates fluorocarbon radicals that form conformal passivation coatings(thickness:7 nm)on purified boron surfaces.The modified boron particles exhibit 37.5℃lower exothermic peak temperature and 27.2%higher heat release(14.8 kJ/g vs.11.6 kJ/g)compared to untreated counterparts.Combustion diagnostics reveal 194%increase in maximum flame height(135.10 mm vs.46.03 mm)and 134%enhancement in flame propagation rate(4.44 cm/s vs.1.90 cm/s).This NTP-based surface engineering approach establishes a scalable pathway for developing highperformance boron-based energetic composites.展开更多
Electrical and electronic devices face significant challenges in heatmanagement due to their compact size and high heat flux,which negatively impact performance and reliability.Conventional coolingmethods,such as forc...Electrical and electronic devices face significant challenges in heatmanagement due to their compact size and high heat flux,which negatively impact performance and reliability.Conventional coolingmethods,such as forced air cooling,often struggle to transfer heat efficiently.In contrast,thermoelectric coolers(TECs)provide an innovative active cooling solution to meet growing thermal management demands.In this research,a refrigerant based on mono ethylene glycol and distilled water was used instead of using gases,in addition to using thermoelectric cooling units instead of using a compressor in traditional refrigeration systems.This study evaluates the performance of a Peltierbased thermalmanagement systemby analyzing the effects of using two,three,and four Peltiermodules on cooling rates,power consumption,temperature reduction,and system efficiency.Experimental results indicate that increasing the number of Peltier modules significantly enhances cooling performance.The four-module system achieved an optimal balance between cooling speed and energy efficiency,reducing the temperature of a liquidmixture(30% mono ethylene glycol+70% distilled water plus laser dyes)to 8℃ in just 17 min.It demonstrated a cooling rate of 0.794℃/min and a high coefficient of performance(COP)of 1.2 while consuming less energy than the two-and three-module systems.Furthermore,the study revealed that increasing the number of modules led to faster air cooling and improved temperature reduction.These findings highlight the importance of selecting the optimal number of Peltier modules to enhance efficiency and cooling speed whileminimizing energy consumption.This makes TEC technology a sustainable and effective solution for applications requiring rapid and reliable thermal management.展开更多
The new RE 6 EL from KARL MAYER brings a breath of fresh air to raschel fabric production.Nowadays textile companies increasingly need to produce small production runs and respond to market changes with instantaneous ...The new RE 6 EL from KARL MAYER brings a breath of fresh air to raschel fabric production.Nowadays textile companies increasingly need to produce small production runs and respond to market changes with instantaneous pattern changes in order to operate profitably–meaning they require machines that offer maximum flexibility,reliability and cost efficiency.KARL MAYER understands the challenges of the market and is launching its new RE 6 EL.The Raschel machine offers the core strengths of the classic RSE 6 EL and essentially the same performance parameters,but has been further cost-optimised largely due to local production advantages.This makes the newcomer an efficiency champion in production,especially when it comes to frequent pattern changes.展开更多
This study focused on improving the cathode performance of Ba_(0.6)Sr_(0.4)Co_(0.85)Nb_(0.15)O_(3-δ)(BSCN)-based perovskite materials through molybdenum(Mo)doping.Pure BSCN and Mo-modified-BSCN—Ea_(0.6)Sr_(0.4)Co_(0...This study focused on improving the cathode performance of Ba_(0.6)Sr_(0.4)Co_(0.85)Nb_(0.15)O_(3-δ)(BSCN)-based perovskite materials through molybdenum(Mo)doping.Pure BSCN and Mo-modified-BSCN—Ea_(0.6)Sr_(0.4)Co_(0.85)Nb_(0.1)Mo_(0.05)O_(3-δ)(B S CNM_(0.05)),Ba_(0.6)Sr_(0.4)Co_(0.85)Nb_(0.05)Mo_(0.1)O_(3-δ)(BSCNM_(0.1)),and Ba_(0.6)Sr_(0.4)Co_(0.85)Mo_(0.15)O_(3-δ)(BSCM)—with Mo doping contents of 5mol%,10mol%,and15mol%,respectively,were successfully prepared using the sol-gel method.The effects of Mo doping on the crystal structure,conductivity,thermal expansion coefficient,oxygen reduction reaction(ORR)activity,and electrochemical performance were systematically evaluated using X-ray diffraction analysis,thermally induced characterization,electrochemical impedance spectroscopy,and single-cell performance tests.The results revealed that Mo doping could improve the conductivity of the materials,suppress their thermal expansion effects,and significantly improve the electrochemical performance.Surface chemical state analysis using X-ray photoelectron spectroscopy revealed that 5mol%Mo doping could facilitate a high adsorbed oxygen concentration leading to enhanced ORR activity in the materials.Density functional theory calculations confirmed that Mo doping promoted the ORR activity in the materials.At an operating temperature of 600℃,the BSCNM_(0.05)cathode material exhibited significantly enhanced electrochemical impedance characteristics,with a reduced area specific resistance of 0.048Ω·cm~2,which was lower than that of the undoped BSCN matrix material by 32.39%.At the same operating temperature,an anode-supported single cell using a BSCNM_(0.05)cathode achieved a peak power density of 1477 mW·cm^(-2),which was 30.71%,56.30%,and 171.50%higher than those of BSCN,BSCNM_(0.1),and B SCM,respectively.The improved ORR activity and electrochemical performance of BSCNM_(0.05)indicate that it can be used as a cathode material in low-temperature solid oxide fuel cells.展开更多
Thermocells are garnering increasing attention as a promising thermoelectric technology for harvesting low-grade heat.However,their performance is often limited by the scarcity of high-performance redox couples that p...Thermocells are garnering increasing attention as a promising thermoelectric technology for harvesting low-grade heat.However,their performance is often limited by the scarcity of high-performance redox couples that possess both high thermopower and rapid redox kinetics.This work addresses this challenge by leveraging our recently developed copper(Ⅰ/Ⅱ)(Cu^(+)/Cu^(2+))redox couple.We significantly enhance the performance of Cu-based liquid thermocells by integrating a thermosensitive crystallization process with etched carbon cloth electrodes,achieving synergistic improvements in thermodynamic and kinetic performance.The thermosensitive crystallization process establishes a persistent Cu^(2+)concentration gradient,boosting the thermopower from 1.47 to 2.93 mV K^(-1).Moreover,the etched carbon cloth electrodes provide a larger electroactive surface area and demonstrate a higher current density.Consequently,the optimized Cu^(+)/Cu^(2+)system achieved an exceptional normalized power density P_(max)(ΔT)^(-2)of 3.97 mW m^(-2)K^(-2).A thermocell module comprised of 20 cells directly power various electronic devices at a temperature difference of 40 K.This work successfully exhibits potential of Cu^(+)/Cu^(2+)redox couple in thermoelectric conversion and introduces a valuable redox couple for highperformance thermocells.展开更多
Magnesium-based anode materials have attracted significant attention in the energy storage domain because of their high theoretical capacities and low electrochemical potentials.However,in conventional electrolyte sys...Magnesium-based anode materials have attracted significant attention in the energy storage domain because of their high theoretical capacities and low electrochemical potentials.However,in conventional electrolyte systems,magnesium metal electrodes dynamically generate an ion-blocking surface layer,resulting in prominent voltage polarization,which severely limits their practical applications.In this study,ZIF-8/carbon nanotubes(CNTs)coatings were used to modify the anodes of magnesium batteries.Compared with the unaltered magnesium battery,the voltage lag time of the ZIF-8/CNTs coating was shortened from 4 s before modification to 0.26 s,and the battery impedance was lowered by two orders of magnitude.The duration of the discharge platform was increased from 4 h before modification to 6-10 h,the anode utilization rate was more than doubled,and the specific energy density was significantly enhanced compared with the battery before modification.The mechanism indicates that the ZIF-8/CNTs coating can limit the infiltration of corrosive substances,extend their transmission path,and offer more effective protection to the magnesium anode.The incorporation of CNTs improves the conductivity of the battery,and it significantly improves the electrochemical performance of the magnesium battery.展开更多
Solid-state batteries are widely recognized as the next-generation energy storage devices with high specific energy,high safety,and high environmental adaptability.However,the research and development of solid-state b...Solid-state batteries are widely recognized as the next-generation energy storage devices with high specific energy,high safety,and high environmental adaptability.However,the research and development of solid-state batteries are resource-intensive and time-consuming due to their complex chemical environment,rendering performance prediction arduous and delaying large-scale industrialization.Artificial intelligence serves as an accelerator for solid-state battery development by enabling efficient material screening and performance prediction.This review will systematically examine how the latest progress in using machine learning(ML)algorithms can be used to mine extensive material databases and accelerate the discovery of high-performance cathode,anode,and electrolyte materials suitable for solid-state batteries.Furthermore,the use of ML technology to accurately estimate and predict key performance indicators in the solid-state battery management system will be discussed,among which are state of charge,state of health,remaining useful life,and battery capacity.Finally,we will summarize the main challenges encountered in the current research,such as data quality issues and poor code portability,and propose possible solutions and development paths.These will provide clear guidance for future research and technological reiteration.展开更多
The fluorination strategy has been proven effective in significantly enhancing the photovoltaic performance of organic solar cells(OSCs) based on non-fused ring electron acceptors(NFREAs).However,research on the impac...The fluorination strategy has been proven effective in significantly enhancing the photovoltaic performance of organic solar cells(OSCs) based on non-fused ring electron acceptors(NFREAs).However,research on the impact of fluorination positions at side chains on NFREAs device performance remains scant.In this study,we introduce two isomeric NFREAs,designated as GA-2F-E and GA-2F,distinguished by their fluorination positions at the side chains.Both NFREAs share a thiophene[3,2-b]thiophene core,but their side chains differ:GA-2F-E features two(4-butylphenyl)-N-(4-fluorophenyl) amino groups,whereas GA-2F's side chains consist of bis(4-fluorophenyl)amino and bis(4-butylphenyl)amino groups attached to opposite sides of the core.To delve into the influence of fluorination positions on the optoelectronic properties,aggregation behavior,and overall efficiency of the acceptor molecules,a comprehensive investigation was conducted.The findings reveal that,despite similar photophysical properties and comparable absorption bandwidths,GA-2F-E,with fluorine atoms positioned on both sides of the molecular framework,demonstrates more compact π-π stacking,reduced bimolecular recombination,superior exciton transport,and a more balanced,higher mobility.As a result of these advantages,OSCs optimized with D18:GA-2F-E achieve a remarkable power conversion efficiency(PCE) of 16.45 %,surpassing the 15.83 %PCE of devices utilizing D18:GA-2F.This research underscores the potential of NFREAs in future applications and highlights the significance of fluorination positions in enhancing OSC performance,paving the way for the development of more efficient NFREAs.展开更多
基金Sponsored by the National Defence Research Foundation of China(Grant No.413460303).
文摘Network processors are used in the core node of network to flexibly process packet streams. With the increase of performance, the power of network processor increases fast, and power and cooling become a bottleneck. Architecture-level power conscious design must go beyond low-level circuit design. Architectural power and performance tradeoff should be considered at the same time. Simulation is an efficient method to design modem network processor before making chip. In order to achieve the tradeoff between performance and power, the processor simulator is used to design the architecture of network processor. Using Netbeneh, Commubench benchmark and processor simulator-SimpleScalar, the performance and power of network processor are quantitatively evaluated. New performance tradeoff evaluation metric is proposed to analyze the architecture of network processor. Based on the high performance lnteI IXP 2800 Network processor eonfignration, optimized instruction fetch width and speed ,instruction issue width, instruction window size are analyzed and selected. Simulation resuits show that the tradeoff design method makes the usage of network processor more effectively. The optimal key parameters of network processor are important in architecture-level design. It is meaningful for the next generation network processor design.
基金Supported by Basic Scientific Research Project of the Liaoning Provincial Department of Education Has Been Unveiled to Facilitate Local Project Funding (JYTMS20230835)Enhanced Scientific Research Project Funded by the Departmentof Higher Education in Liaoning Province (General program)(JYTMS20230852)。
文摘The adsorptive denitrification performance of MIL-101(Cr)-0.5 toward pyridine,aniline or quinoline in simulated fuels with basic nitrogen content of 1732μg/g was evaluated separately.Furthermore,the effects of adsorption temperature,adsorption time and adsorbent dosage on their adsorptive denitrification performance were systematically investigated.The experimental results demonstrated that under a fixed adsorbent dosage of 0.05 g and a simulated fuel volume of 10 mL,the optimal removal efficiency for aniline was achieved at 30℃ within 30 min,whereas higher temperatures and longer times(40℃and 40 min)were required for effective removal of pyridine and quinoline.Density Functional Theory(DFT)calculations were conducted via Materials Studio(MS)software to study the adsorptive denitrification mechanism of MIL-101(Cr)toward these three basic nitrogen-containing compounds.The simulation calculation results revealed that the interaction between pyridine and MIL-101(Cr)primarily involved coordination adsorption.In contrast,the interaction between aniline or quinoline and MIL-101(Cr)proceeded mainly through coordination,with additional contributions fromπ-complexation and hydrogen bonding.The overall adsorption strength order is pyridine>aniline>quinoline.During the adsorption process,pyridine and quinoline transfer electrons to the MIL-101(Cr)surface through the H→C→N→Cr^(3+)pathway,while aniline transfers electrons to the MIL-101(Cr)surface through various pathways,including N→Cr^(3+),N→C→Cr^(3+)and N→H→O.Furthermore,adsorption kinetics studies indicated that the adsorption processes for all three basic nitrogen-containing compounds followed the quasi second order kinetic models.The experimental results on the effect of benzene on the adsorptive denitrification performance of MIL-101(Cr)-0.5 demonstrated that benzene exerted a more significant impact on the adsorption of aniline and quinoline.Finally,the adsorbent was regenerated using ethanol washing.It was found that MIL-101(Cr)-0.5 retained stable denitrification performance after two regeneration cycles.
基金Supported by the Science and Technology Cooperation and Exchange special project of Cooperation of Shanxi Province(202404041101014)the Fundamental Research Program of Shanxi Province(202403021212333)+3 种基金the Joint Funds of the National Natural Science Foundation of China(U24A20555)the Lvliang Key R&D of University-Local Cooperation(2023XDHZ10)the Initiation Fund for Doctoral Research of Taiyuan University of Science and Technology(20242026)the Outstanding Doctor Funding Award of Shanxi Province(20242080).
文摘To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content in coal)catalysts were prepared by the incipient wetness impregnation method,followed by acid washing to remove calcium-containing minerals.Comprehensive characterization and low-temperature denitrification tests revealed that calcite-induced structural modulation of coal-derived AC significantly enhances catalytic activity.Specifically,NO conversion increased from 88.3%of Mn-Ce/De-AC to 91.7%of Mn-Ce/De-AC-1CaCO_(3)(210℃).The improved SCR denitrification activity results from the enhancement of physicochemical properties including higher Mn^(4+)content and Ce^(4+)/Ce^(3+)ratio,an abundance of chemisorbed oxygen and acidic sites,which could strengthen the SCR reaction pathways(richer NH_(3)activated species and bidentate nitrate active species).Therefore,NO removal is enhanced.
基金the National Natural Science Foundation of China(Grant No.U2441263)for financial support of this work。
文摘In composite solid propellants with high aluminum(Al)content and low burning rate,incomplete combustion of the Al powder may occur.In this study,varying lithium(Li)content in Al-Li alloy powder was utilized instead of pure aluminum particles to mitigate agglomeration and enhance the combustion efficiency of solid propellants(Combustion efficiency herein refers to the completeness of metallic fuel oxidation,quantified as the ratio of actual-to-theoretical energy released during combustion)with high Al content and low burning rates.The impact of Al-Li alloy with different Li contents on combustion and agglomeration of solid propellant was investigated using explosion heat,combustion heat,differential thermal analysis(DTA),thermos-gravimetric analysis(TG),dynamic high-pressure combustion test,ignition experiment of small solid rocket motor(SRM)tests,condensation combustion product collection,and X-ray diffraction techniques(XRD).Compared with pure Al,Al-Li alloys exhibit higher combustion heat,which contributes to improved combustion efficiency in Al-Li alloy-containing propellants.DTA and TG analyses demonstrated higher reactivity and lower ignition temperatures for Al-Li alloys.High-pressure combustion experiments at 5 MPa showed that Al-Li alloy fuel significantly decreases combustion agglomeration.The results from theφ75 mm andφ165 mm SRM and XRD tests further support this finding.This study provides novel insights into the combustion and agglomeration behaviors of high-Al,low-burning-rate composite solid propellants and supports the potential application of Al-Li alloys in advanced propellant formulations.
基金financially supported by the National Science Fund for Distinguished Young Scholars,China(No.52025041)the National Natural Science Foundation of China(Nos.52450003,U2341267,and 52174294)+1 种基金the National Postdoctoral Program for Innovative Talents,China(No.BX20240437)the Fundamental Research Funds for the Central Universities,China(Nos.FRF-IDRY-23-037 and FRF-TP-20-02C2)。
文摘The rapid advancements in computer vision(CV)technology have transformed the traditional approaches to material microstructure analysis.This review outlines the history of CV and explores the applications of deep-learning(DL)-driven CV in four key areas of materials science:microstructure-based performance prediction,microstructure information generation,microstructure defect detection,and crystal structure-based property prediction.The CV has significantly reduced the cost of traditional experimental methods used in material performance prediction.Moreover,recent progress made in generating microstructure images and detecting microstructural defects using CV has led to increased efficiency and reliability in material performance assessments.The DL-driven CV models can accelerate the design of new materials with optimized performance by integrating predictions based on both crystal and microstructural data,thereby allowing for the discovery and innovation of next-generation materials.Finally,the review provides insights into the rapid interdisciplinary developments in the field of materials science and future prospects.
文摘To investigate the overall performance of reverse energy bypass scramjet,firstly a variable spe⁃cific heat method combined with a chemical balance calculation module for combustion products were used to es⁃tablish a benchmark scramjet performance evaluation model.Based on the test data of typical flying point of Mach 7 with the altitude of 29 km,the reliability of the model was verified.The deviations of parameters such as the to⁃tal pressure loss of combustor between the model and the test data were analyzed.Furtherly,an analytical method for post-combustion magnetohydrodynamic power generation was established;by embedding the above method into the overall performance evaluation model,performance prediction considering the power generation effect was realized.Finally,based on the above model,variety regulations of the inlet and the outlet parameters of the power generation channel and performance parameters including the engine specific impulse and the unit thrust under different enthalpy extraction ratios and load factors were analyzed.It could be concluded that the model can reliably predict the variations of key parameters.As the value of the load factor increases,the value of the conduc⁃tivity required to reach the specified enthalpy extraction ratio first decreases and then increases,which is approxi⁃mately parabolic.In order to reduce the demand for the gas conductivity for MHD power generation,the load fac⁃tor should be around 0.5.When the load factor is 0.4 and the magnetic induction intensity is 2.5 T,if the enthalpy extraction ratio reaches 0.5%,the engine specific impulse performance reduces about 3.58%.
基金National Social Science Fund of China(18KXS009)the Sichuan Provincial Soft Science Program(22JDR0261)the Sichuan University“From 0 to 1”Innovation Research Program(2021CXC10)。
文摘In the context of the revolution in new technologies,a key question is whether the rapid growth of the digital economy,driven by digital technologies,has improved regional innovation performance.Using inter-provincial panel data from China(2012–2022)and adopting a business environment perspective,this study applies a Panel Extended Regression Model(PERM),a Panel Simultaneous Equation Model(PSEM),and a Tobit-IV model to analyze how the development of the digital economy influences regional innovation.The results reveal a pronounced U-shaped relationship between the digital economy and the regional innovation performance at the provincial level in China,with the business environment serving as a significant mediator in this relationship.Moreover,regional innovation performance in China exhibits a“ratchet effect,”with the impact of the digital economy varying markedly across regions.While the eastern and western regions have entered an upward phase,whereby the digital economy boosts innovation,the central region displays a weaker effect.Further analysis indicates that the synergy between the business environment and the digital economy in driving innovation remains suboptimal.These findings were supported by robust checks.This study offers theoretical insights and empirical evidence that support the coordinated development of digital government and the digital factor market,as well as business environment reforms that are in alignment with the innovation demands of the digital era.
基金supported by the National Natural Science Foundation of China(No.51706105)。
文摘Al/NH_(4)CoF_(3)-Φ(Φ=0.5,1.0,1.5,2.0,and 3.0)binary composites and Al-NH_(4)CoF_(3)@P(VDF-HFP)ternary composites are fabricated via ultrasonication-assisted blending and electrostatic spraying.The effect of equivalence ratio(Φ)on the reaction properties is systematically investigated in the binary Al/NH_(4)CoF_(3)system.For ternary systems,electrostatic spraying allows both components to be efficiently encapsulated by P(VDF-HFP)and to achieve structural stabilization and enhanced reactivity through synergistic interfacial interactions.Morphological analysis using SEM/TEM revealed that P(VDF-HFP)formed a protective layer on Al and NH_(4)CoF_(3)particles,improving dispersion,hydrophobicity(water contact angle increased by 80.5%compared to physically mixed composites),and corrosion resistance.Thermal decomposition of NH_(4)CoF_(3)occurred at 265℃,releasing NH_(3)and HF,which triggered exothermic reactions with Al.The ternary composites exhibited a narrowed main reaction temperature range and concentrated heat release,attributed to improved interfacial contact and polymer decomposition.Combustion tests demonstrated that Al-NH_(4)CoF_(3)@P(VDF-HFP)achieved self-sustaining combustion.In addition,a simple validation was done by replacing the Al component in the aluminium-containing propellant,demonstrating its potential application in the propellant field.This work establishes a novel strategy for designing stable,high-energy composites with potential applications in advanced propulsion systems.
基金supported and funded by the National Key Research and Development Program of China(2023YFD1300801)the Agricultural Science and Technology Innovation Program in Chinese Academy of Agricultural Sciences(ASTIP-IAS-08)。
文摘Background The decline in reproductive performance of aged hens is mainly attributed to oxidative damage in reproductive organs,hepatic lipid metabolism disorders,and intestinal microbiota dysbiosis.Glycyrrhizin(GL)has been proven to enhance antioxidant capacity,regulate lipid metabolism and gut microbiota in mammals,but its efficacy in hens remains unclear.Hence,this study aimed to investigate whether dietary GL supplementation improves reproductive performance in hens during the late laying stage by modulating intestinal microbiota composition,hepatic lipid metabolism and ovarian antioxidant status.Results Dietary supplementation with 100 mg/kg GL significantly improved the egg production rate,egg quality,and hatching rate in aged breeder hens(P<0.05).GL supplementation also increased the serum levels of HDLC,TP and ALB,and enhanced the antioxidant capacity in both serum and ovary(P<0.05).In addition,dietary GL elevated the serum progesterone(P4)levels by enhancing the transcription level of steroid synthesis key enzymes(CYP11A1 and 3β-HSD)in the ovary(P<0.05).Dietary GL also promoted the synthesis and transport of vitellogenin(VTG)by upregulating the VTG-Ⅱ(P<0.05)and APOV1(P=0.077)expression levels in the liver,thereby increasing the number of grade follicles and small yellow follicles.Moreover,dietary GL enhanced hepatic fatty acidβ-oxidation by upregulating PPARαand CPT-I(P<0.05),and downregulating ACC expression levels(P<0.05).In agreement,liver metabolomics analysis revealed that dietary GL supplementation significantly altered hepatic metabolism,with 389 differentially identified metabolites(P<0.05).The key metabolites(e.g.,taurocholic acid,tauroursodeoxycholic acid,nicotinuric acid,glycodeoxycholic acid(hydrate))were identified,and they were mainly functionally enriched in betaalanine metabolism nicotinate,taurine and hypotaurine metabolism(P<0.05).Finally,16S rRNA gene sequencing revealed that dietary GL reversed age-induced changes in gut microbiota composition,characterized by a significant increase in Lactobacillus abundance and a decrease in Bacteroides(P<0.05).Conclusions These results collectively demonstrate that dietary supplementation with 100 mg/kg GL improved reproductive performance by reversing age-induced changes in gut microbiota,enhancing hepatic vitellogenin synthesis,and ameliorating ovarian function in aged breeder hens.This study suggests that dietary GL is a potential strategy to improve reproductive performance in broiler breeder hens during the late laying period.
基金supported by the National Natural Science Foundation of China(Grant No.12402268)the Fundamental Research Funds for the Central Universities(Grant No.30925010410)。
文摘The core components of an aircraft and the source of its lift are its wings,but lift generation is disrupted by the high temperature and pressure generated on the wing surface when an aircraft gun is fired.Here,to investigate how this process influences the aerodynamic parameters of aircraft wings,the k-ωshearstress-transport turbulence model and the nested dynamic grid technique are used to analyze numerically the transient process of the muzzle jet of a 30-mm small-caliber aircraft gun in highaltitude(10 km)flight with an incoming Mach number of Ma=0.8.For comparison,two other models are established,one with no projectile and the other with no wing.The results indicate that when the aircraft gun is fired,the muzzle jet acts on the wing,creating a pressure field thereon.The uneven distribution of high pressure greatly reduces the lift of the aircraft,causing oscillations in its drag and disrupting its dynamic balance,thereby affecting its flight speed and attitude.Meanwhile,the muzzle jet is obstructed by the wing,and its flow field is distorted and deformed,developing upward toward the wing.Because of the influence of the incoming flow,the shockwave front of the projectile changes from a smooth spherical shape to an irregular one,and the motion parameters of the projectile are also greatly affected by oscillations.The present results provide an important theoretical basis for how the guns of fighter aircraft influence the aerodynamic performance of the wings.
基金supported by the State Key Laboratory of Intelligent Construction and Healthy Operation and Maintenance of Deep Underground Engineering(Grant No.SDGZ2505)the Postdoctoral Fellowship Program of the China Postdoctoral Science Foundation(Grant No.GZB20250742)the General Program of the China Postdoctoral Science Foundation(Grant No.2025M773213).
文摘The negative Poisson’s ratio(NPR)bolt is an innovative support element distinguished by its high strength,elongation,and a slightly negative Poisson’s ratio.Unlike conventional prestressed(PR)bolts with a positive Poisson’s ratio,the NPR bolt exhibits a quasi-ideal plastic response without a prominent yield platform,enabling it to sustain high prestress with a substantial safety margin,which is particularly advantageous for jointed rock masses.However,investigations into the shear resistance mechanisms of NPR bolts under varying prestress levels remain limited.This study conducted full-scale double shear tests to assess the shear strength,deformation behavior,energy absorption,and failure mechanisms of NPR bolts under different prestress conditions.To ensure a fair comparison with PR bolts,a prestress utilization coefficient(PUC)was introduced.The results reveal that at a PUC of 0.25,the NPR bolt achieved peak axial force,shear displacement,and peak shear force values that are 2.41,1.88,and 2.13 times greater than those of the PR bolt,respectively.Shear performance was optimized at a prestress level of 100 kN,with energy absorption reaching 47.1 kJ,which is 2.8 times that of the PR bolt.Furthermore,the necking ratio was significantly reduced,indicating more distributed plastic deformation and delayed failure.Field applications verified the superior performance,resulting in a 27.4%reduction in roof settlement and enhanced structural integrity.These findings confirm that NPR bolts possess excellent shear resistance,energy absorption,and deformation adaptability,and optimizing prestress significantly enhances their support performance,providing a strong basis for geotechnical engineering applications.
基金supported by the National Natural Science Foundation of China(No.52064035)the Key Research and Development Program of Gansu Province,China(No.25YFGA024)the Natural Science Foundation of Zhejiang Province,China(No.LGG22E020003).
文摘Lithium-sulfur(Li-S)batteries boast a theoretical energy density as high as 2600 Wh·kg^(−1),positioning them as a highly attractive option for future advanced energy storage systems.Challenges such as slow transformation kinetics and shuttle effects associated with lithium polysulfides(LiPSs)have seriously hindered their practical applications.In this paper,we present a new method for the synthesis of hollow carbon-sphere-supported Co monatomic catalysts(Co-N-C).This new synthesis method achieves pyrolytic coordination using a precursor rich in imide(-RC=N-)polymers.This synthesis method not only improves the adsorbability and catalytic activity of LiPS but also significantly weakens the shuttle effect and generates Co-N-C with superior conductivity,abundant hollow structures,and a high specific surface area,thus efficiently capturing and restricting the movement of LiPS intermediates.The dispersed Co monoatomic catalysts(Co SACs)were anchored to a highly conductive nitrogen-doped carbon framework and exhibited symmetric N-coordination active sites(Co-N_(4))to ensure fast redox kinetics of LiPS and Li_(2)S_(2)/Li_(2)S solid-state products.The lithium-sulfur battery with Co-N-C as the sulfur carrier showed excellent discharging capacity of 1146.6 mAh·g^(−1) at a discharge rate of 0.5 C and maintained excellent performance at a high discharge rate of 2 C.The capacity decay rate in 500 cycles was only 0.086%per cycle,reflecting excellent long-term cycle stability.This study highlights the key role of the synergistic effect between single-atom cobalt catalysts and hollow carbon spheres in enhancing the efficiency of lithium-sulfur(Li-S)batteries.It also provides valuable insights into the construction and fabrication of highly active monatomic catalysts.The catalytic conversion efficiency of lithium polysulfides is significantly enhanced when embedded in hollow carbon architectures,which serves as a critical strategy for optimizing the electrochemical behavior of next-generation Li-S batteries.
基金supported by the National Natural Science Foundation of China(Nos.U2341249,12005076,22205112)the Fundamental Research Funds for the Central Universities(No.2025201012)。
文摘The presence of a surface oxide film(B_(2)O_(3))on boron(B)particles significantly compromises their combustion efficiency and kinetic performance in fuel-rich solid propellants.This study proposes an innovative continuous modification strategy combining non-thermal plasma(NTP)etching with fluorocarbon passivation.Characterization and kinetic analysis revealed that reactive plasma species—including atomic hydrogen(H),electronically excited molecular hydrogen(H_(2)^(*)),vibrationally excited molecular hydrogen(H_(2)v),and hydrogen ions(H^(+))—dominate the reduction of B_(2)O_(3)through lowering the transition energy barrier and shifting the reaction spontaneity.Subsequent argon plasma fragmentation of C_(8)F_(18)generates fluorocarbon radicals that form conformal passivation coatings(thickness:7 nm)on purified boron surfaces.The modified boron particles exhibit 37.5℃lower exothermic peak temperature and 27.2%higher heat release(14.8 kJ/g vs.11.6 kJ/g)compared to untreated counterparts.Combustion diagnostics reveal 194%increase in maximum flame height(135.10 mm vs.46.03 mm)and 134%enhancement in flame propagation rate(4.44 cm/s vs.1.90 cm/s).This NTP-based surface engineering approach establishes a scalable pathway for developing highperformance boron-based energetic composites.
文摘Electrical and electronic devices face significant challenges in heatmanagement due to their compact size and high heat flux,which negatively impact performance and reliability.Conventional coolingmethods,such as forced air cooling,often struggle to transfer heat efficiently.In contrast,thermoelectric coolers(TECs)provide an innovative active cooling solution to meet growing thermal management demands.In this research,a refrigerant based on mono ethylene glycol and distilled water was used instead of using gases,in addition to using thermoelectric cooling units instead of using a compressor in traditional refrigeration systems.This study evaluates the performance of a Peltierbased thermalmanagement systemby analyzing the effects of using two,three,and four Peltiermodules on cooling rates,power consumption,temperature reduction,and system efficiency.Experimental results indicate that increasing the number of Peltier modules significantly enhances cooling performance.The four-module system achieved an optimal balance between cooling speed and energy efficiency,reducing the temperature of a liquidmixture(30% mono ethylene glycol+70% distilled water plus laser dyes)to 8℃ in just 17 min.It demonstrated a cooling rate of 0.794℃/min and a high coefficient of performance(COP)of 1.2 while consuming less energy than the two-and three-module systems.Furthermore,the study revealed that increasing the number of modules led to faster air cooling and improved temperature reduction.These findings highlight the importance of selecting the optimal number of Peltier modules to enhance efficiency and cooling speed whileminimizing energy consumption.This makes TEC technology a sustainable and effective solution for applications requiring rapid and reliable thermal management.
文摘The new RE 6 EL from KARL MAYER brings a breath of fresh air to raschel fabric production.Nowadays textile companies increasingly need to produce small production runs and respond to market changes with instantaneous pattern changes in order to operate profitably–meaning they require machines that offer maximum flexibility,reliability and cost efficiency.KARL MAYER understands the challenges of the market and is launching its new RE 6 EL.The Raschel machine offers the core strengths of the classic RSE 6 EL and essentially the same performance parameters,but has been further cost-optimised largely due to local production advantages.This makes the newcomer an efficiency champion in production,especially when it comes to frequent pattern changes.
基金financially supported by the National Natural Science Foundation of China(No.22309067)the Open Project Program of the State Key Laboratory of Materials-Oriented Chemical Engineering,China(No.KL21-05)the Marine Equipment and Technology Institute,Jiangsu University of Science and Technology,China(No.XTCX202404)。
文摘This study focused on improving the cathode performance of Ba_(0.6)Sr_(0.4)Co_(0.85)Nb_(0.15)O_(3-δ)(BSCN)-based perovskite materials through molybdenum(Mo)doping.Pure BSCN and Mo-modified-BSCN—Ea_(0.6)Sr_(0.4)Co_(0.85)Nb_(0.1)Mo_(0.05)O_(3-δ)(B S CNM_(0.05)),Ba_(0.6)Sr_(0.4)Co_(0.85)Nb_(0.05)Mo_(0.1)O_(3-δ)(BSCNM_(0.1)),and Ba_(0.6)Sr_(0.4)Co_(0.85)Mo_(0.15)O_(3-δ)(BSCM)—with Mo doping contents of 5mol%,10mol%,and15mol%,respectively,were successfully prepared using the sol-gel method.The effects of Mo doping on the crystal structure,conductivity,thermal expansion coefficient,oxygen reduction reaction(ORR)activity,and electrochemical performance were systematically evaluated using X-ray diffraction analysis,thermally induced characterization,electrochemical impedance spectroscopy,and single-cell performance tests.The results revealed that Mo doping could improve the conductivity of the materials,suppress their thermal expansion effects,and significantly improve the electrochemical performance.Surface chemical state analysis using X-ray photoelectron spectroscopy revealed that 5mol%Mo doping could facilitate a high adsorbed oxygen concentration leading to enhanced ORR activity in the materials.Density functional theory calculations confirmed that Mo doping promoted the ORR activity in the materials.At an operating temperature of 600℃,the BSCNM_(0.05)cathode material exhibited significantly enhanced electrochemical impedance characteristics,with a reduced area specific resistance of 0.048Ω·cm~2,which was lower than that of the undoped BSCN matrix material by 32.39%.At the same operating temperature,an anode-supported single cell using a BSCNM_(0.05)cathode achieved a peak power density of 1477 mW·cm^(-2),which was 30.71%,56.30%,and 171.50%higher than those of BSCN,BSCNM_(0.1),and B SCM,respectively.The improved ORR activity and electrochemical performance of BSCNM_(0.05)indicate that it can be used as a cathode material in low-temperature solid oxide fuel cells.
基金financially supported by research grants from Innovative Research Group Project of National Natural Science Foundation of China(52021004)the National Key Research and Development Program of China(2022YFB3803300)+1 种基金the National Natural Science Foundation of China(62474026,62205140,12204071)the China Postdoctoral Science Foundation(2022M710532)。
文摘Thermocells are garnering increasing attention as a promising thermoelectric technology for harvesting low-grade heat.However,their performance is often limited by the scarcity of high-performance redox couples that possess both high thermopower and rapid redox kinetics.This work addresses this challenge by leveraging our recently developed copper(Ⅰ/Ⅱ)(Cu^(+)/Cu^(2+))redox couple.We significantly enhance the performance of Cu-based liquid thermocells by integrating a thermosensitive crystallization process with etched carbon cloth electrodes,achieving synergistic improvements in thermodynamic and kinetic performance.The thermosensitive crystallization process establishes a persistent Cu^(2+)concentration gradient,boosting the thermopower from 1.47 to 2.93 mV K^(-1).Moreover,the etched carbon cloth electrodes provide a larger electroactive surface area and demonstrate a higher current density.Consequently,the optimized Cu^(+)/Cu^(2+)system achieved an exceptional normalized power density P_(max)(ΔT)^(-2)of 3.97 mW m^(-2)K^(-2).A thermocell module comprised of 20 cells directly power various electronic devices at a temperature difference of 40 K.This work successfully exhibits potential of Cu^(+)/Cu^(2+)redox couple in thermoelectric conversion and introduces a valuable redox couple for highperformance thermocells.
基金supported by the Guangxi Natural Science Foundation,China(No.2020GXNSFAA 159011)the National Natural Science Foundation of China(No.51664011).
文摘Magnesium-based anode materials have attracted significant attention in the energy storage domain because of their high theoretical capacities and low electrochemical potentials.However,in conventional electrolyte systems,magnesium metal electrodes dynamically generate an ion-blocking surface layer,resulting in prominent voltage polarization,which severely limits their practical applications.In this study,ZIF-8/carbon nanotubes(CNTs)coatings were used to modify the anodes of magnesium batteries.Compared with the unaltered magnesium battery,the voltage lag time of the ZIF-8/CNTs coating was shortened from 4 s before modification to 0.26 s,and the battery impedance was lowered by two orders of magnitude.The duration of the discharge platform was increased from 4 h before modification to 6-10 h,the anode utilization rate was more than doubled,and the specific energy density was significantly enhanced compared with the battery before modification.The mechanism indicates that the ZIF-8/CNTs coating can limit the infiltration of corrosive substances,extend their transmission path,and offer more effective protection to the magnesium anode.The incorporation of CNTs improves the conductivity of the battery,and it significantly improves the electrochemical performance of the magnesium battery.
基金the National Key Research Program of China under granted No.92164201National Natural Science Foundation of China for Distinguished Young Scholars No.62325403+2 种基金Natural Science Foundation of Jiangsu Province(BK20230498)Jiangsu Funding Program for Excellent Postdoctoral Talent(2024ZB427)the National Natural Science Foundation of China(62304147).
文摘Solid-state batteries are widely recognized as the next-generation energy storage devices with high specific energy,high safety,and high environmental adaptability.However,the research and development of solid-state batteries are resource-intensive and time-consuming due to their complex chemical environment,rendering performance prediction arduous and delaying large-scale industrialization.Artificial intelligence serves as an accelerator for solid-state battery development by enabling efficient material screening and performance prediction.This review will systematically examine how the latest progress in using machine learning(ML)algorithms can be used to mine extensive material databases and accelerate the discovery of high-performance cathode,anode,and electrolyte materials suitable for solid-state batteries.Furthermore,the use of ML technology to accurately estimate and predict key performance indicators in the solid-state battery management system will be discussed,among which are state of charge,state of health,remaining useful life,and battery capacity.Finally,we will summarize the main challenges encountered in the current research,such as data quality issues and poor code portability,and propose possible solutions and development paths.These will provide clear guidance for future research and technological reiteration.
基金financially supported by the National Natural Science Foundation of China (Nos.22375024,21975031,51933001,and 21734009)。
文摘The fluorination strategy has been proven effective in significantly enhancing the photovoltaic performance of organic solar cells(OSCs) based on non-fused ring electron acceptors(NFREAs).However,research on the impact of fluorination positions at side chains on NFREAs device performance remains scant.In this study,we introduce two isomeric NFREAs,designated as GA-2F-E and GA-2F,distinguished by their fluorination positions at the side chains.Both NFREAs share a thiophene[3,2-b]thiophene core,but their side chains differ:GA-2F-E features two(4-butylphenyl)-N-(4-fluorophenyl) amino groups,whereas GA-2F's side chains consist of bis(4-fluorophenyl)amino and bis(4-butylphenyl)amino groups attached to opposite sides of the core.To delve into the influence of fluorination positions on the optoelectronic properties,aggregation behavior,and overall efficiency of the acceptor molecules,a comprehensive investigation was conducted.The findings reveal that,despite similar photophysical properties and comparable absorption bandwidths,GA-2F-E,with fluorine atoms positioned on both sides of the molecular framework,demonstrates more compact π-π stacking,reduced bimolecular recombination,superior exciton transport,and a more balanced,higher mobility.As a result of these advantages,OSCs optimized with D18:GA-2F-E achieve a remarkable power conversion efficiency(PCE) of 16.45 %,surpassing the 15.83 %PCE of devices utilizing D18:GA-2F.This research underscores the potential of NFREAs in future applications and highlights the significance of fluorination positions in enhancing OSC performance,paving the way for the development of more efficient NFREAs.
