The stacking of multiple defect-rich grain boundaries(GBs)along the long transportation path(~3μm)of charge carriers in printable mesoscopic perovskite solar cells(p-MPSCs)impedes their power conversion efficiency(PC...The stacking of multiple defect-rich grain boundaries(GBs)along the long transportation path(~3μm)of charge carriers in printable mesoscopic perovskite solar cells(p-MPSCs)impedes their power conversion efficiency(PCE).Organic Lewis bases are widely utilized for defect passivation at GBs,but how their passivation efficiency affects energy loss remains unclear.Here we employed triphenylphosphine(TPP)and triphenylphosphine oxide(TPPO)as the model passivators in p-MPSCs.TPPO has a more negatively charged center than TPP,which enables its stronger coordination with one of the most common and detrimental defects at the GBs—undercoordinated lead.When added into the perovskite with the same ratio,TPPO passivates defects more significantly and thus less TPPO remaining inactive compared with TPP.Inactive organic passivators accumulated at the GBs could impose barriers to charge carrier transportation.Indeed,TPPO improves the device performance more significantly with a champion PCE of 20.54%achieved.Besides,the TPPO devices demonstrate excellent stability with 95%of initial PCE remaining after 600 h of maximum power point tracking at(55±5)℃.展开更多
Performance of an LD-end-pumped passively Q-switched Nd： YA G/Cr4＋ ： YA G microchip laser operating at 1123 nm is studied. A maximum average output power of 517row with an optical-to-optical conversion efficiency o...Performance of an LD-end-pumped passively Q-switched Nd： YA G/Cr4＋ ： YA G microchip laser operating at 1123 nm is studied. A maximum average output power of 517row with an optical-to-optical conversion efficiency of 12.6% and a slope efficiency of 25.8% is obtained under a pump power of 4.1 W. A minimum pulse width of 1.1 ns with a pulse repetition rate of 20.2kHz is obtained, and the corresponding pulse energy and peak power are 25.6μJ and 23.3kW, respectively. To our knowledge, the 23.3kW peak power is the highest among 1123nm lasers. Additionally, based on the 1123 nm laser, with LBO as the frequency doubler, a 288-mW green-yellow laser at 561 nm is successfully achieved.展开更多
基金financial support from the National Natural Science Foundation of China(Grant numbers 22439001,52172198,51902117)the China Postdoctoral Science Foundation(Grant number BX20240123)the Fundamental Research Funds for the Central Universities(Grant number HUST:2024JYCXJJ043)。
文摘The stacking of multiple defect-rich grain boundaries(GBs)along the long transportation path(~3μm)of charge carriers in printable mesoscopic perovskite solar cells(p-MPSCs)impedes their power conversion efficiency(PCE).Organic Lewis bases are widely utilized for defect passivation at GBs,but how their passivation efficiency affects energy loss remains unclear.Here we employed triphenylphosphine(TPP)and triphenylphosphine oxide(TPPO)as the model passivators in p-MPSCs.TPPO has a more negatively charged center than TPP,which enables its stronger coordination with one of the most common and detrimental defects at the GBs—undercoordinated lead.When added into the perovskite with the same ratio,TPPO passivates defects more significantly and thus less TPPO remaining inactive compared with TPP.Inactive organic passivators accumulated at the GBs could impose barriers to charge carrier transportation.Indeed,TPPO improves the device performance more significantly with a champion PCE of 20.54%achieved.Besides,the TPPO devices demonstrate excellent stability with 95%of initial PCE remaining after 600 h of maximum power point tracking at(55±5)℃.
基金Supported by the Foundation of Shandong Province under Grant No J13LN28the National Natural Science Foundation of China under Grant No 11304184
文摘Performance of an LD-end-pumped passively Q-switched Nd： YA G/Cr4＋ ： YA G microchip laser operating at 1123 nm is studied. A maximum average output power of 517row with an optical-to-optical conversion efficiency of 12.6% and a slope efficiency of 25.8% is obtained under a pump power of 4.1 W. A minimum pulse width of 1.1 ns with a pulse repetition rate of 20.2kHz is obtained, and the corresponding pulse energy and peak power are 25.6μJ and 23.3kW, respectively. To our knowledge, the 23.3kW peak power is the highest among 1123nm lasers. Additionally, based on the 1123 nm laser, with LBO as the frequency doubler, a 288-mW green-yellow laser at 561 nm is successfully achieved.
