Because the normal operation of the engine is located near the equilibrium manifold, the method of equilibrium mani fold nonlinear dynamic modeling is adopted for turbofan engine more than the local train modeling. Th...Because the normal operation of the engine is located near the equilibrium manifold, the method of equilibrium mani fold nonlinear dynamic modeling is adopted for turbofan engine more than the local train modeling. The method studies the sys tem characteristics near the equilibrium manifold. The modeling method can be realized through dynamic and static twostep, and for the specific parameter modeling steps and algorithm are given. The output of the test data is compared with the model output through numerical simulation, to check the model with an additional set of test data. The simulation results show that the model has reached the requirements of engineering accuracy.展开更多
Accurate prediction of the aerodynamic response of a compressor under inlet distortion is crucial for next-generation civil aircraft,such as Boundary Layer Ingestion(BLI)silent aircraft.Therefore,research on the Body ...Accurate prediction of the aerodynamic response of a compressor under inlet distortion is crucial for next-generation civil aircraft,such as Boundary Layer Ingestion(BLI)silent aircraft.Therefore,research on the Body Force(BF)model plays a significant role in achieving this objective.However,distorted inlet airflow can lead to varying operating conditions across different spatial locations of the compressor,which may cause some regions to operate outside the stability boundary.Consequently,the accuracy of BF model simulations might be compromised.To address this issue,this paper proposes a numerical simulation strategy for acquiring the steady axisymmetric three-dimensional flow field of a compressor operating at low mass flow rates,which is known as the Underlying Axisymmetric Pressure Rise Characteristic(UAPRC).The proposed simulation accounts for two different rotor speeds of a transonic compressor and identifies initial positions in the flow field where deterioration occurs based on prior experimental investigations.Moreover,simulation results are incorporated into the BF model to replicate hub instability observed in experiments.Obtained results demonstrate that this strategy provides valid predictions of the UAPRC of the compressor,thereby addressing the limitations associated with the BF model.展开更多
The extraction equilibrium mathematic models for gadolinium,terbium and dysprosium in HCl-1.5 mol/L HEH(EHP)system covering a relatively wide range of lanthanide concentration and acidity,have been developed.There are...The extraction equilibrium mathematic models for gadolinium,terbium and dysprosium in HCl-1.5 mol/L HEH(EHP)system covering a relatively wide range of lanthanide concentration and acidity,have been developed.There are four independent variables and nine parameters.The average relative error is 4.56%.A computer program for the simulation of the counter current solvent extraetion process has also been written.Thus,the Gd,Tb and Dy concentrations in both aqueous and organic phase in eaeh stage as well as the aqueous acidity may be calculated.Product purities,distribution ratio and extraction factors may also be obtained thereby.The simulation results so obtained may serve as the referenee data for designing solvent ex- traction processes including those processes providing apart from the conventional outgoing organic stream, outgoing raffinate and an extra outgoing third exit stream either organic or aqueous.展开更多
The hydrotreater system heat exchanger is one of the main pieces of heat exchange equipment in petrochemical enterprises.In recent years,oil resources have shown a deterioration trend of high sulfur and high acid cont...The hydrotreater system heat exchanger is one of the main pieces of heat exchange equipment in petrochemical enterprises.In recent years,oil resources have shown a deterioration trend of high sulfur and high acid content,with corrosion risk being prominent in oil processing.Taking the multi-medium flow corrosion risk of the hydrotreater heat exchanger pipeline in a petrochemical enterprise as the research object,based on the parameter characteristics of corrosive NH_(3) and HCl media under a high-temperature and high-pressure environment,the ammonium salt crystallization and deposition mechanism under multi-phase flow is revealed.The thermodynamic equilibrium curve is modified based on the thermodynamic principle and fugacity coefficient variation,and the prediction model of ammonium chloride crystallization in hydrotreater heat exchanger under high temperature and high pressure is constructed according to the modification.This study uses the mixture model,the flow-thermal coupling method,and the discrete phase model method to carry out the numerical simulation of multiphase flow and the numerical prediction of particle distribution characteristics in the heat exchanger pipeline of the hydrotreater heat exchange equipment,so as to realize the quantitative prediction of the particle crystallization deposition distribution in the pipeline.The results show that with the decrease of temperature,the crystallization occurs first on both sides of the center of the tube bundle,and more crystallization occurs in the lower half of the U-shaped tube,which may seriously lead to problems such as pipe blockage and under-deposit corrosion.展开更多
In a solar photovoltaic array, it is possible that shadow may fall over some of its cells. Under partial shading conditions the PV characteristic gets more complex with multiple peaks. The purpose of this paper is to ...In a solar photovoltaic array, it is possible that shadow may fall over some of its cells. Under partial shading conditions the PV characteristic gets more complex with multiple peaks. The purpose of this paper is to illustrate, by analyzing different shading situations, the effects that partial shading can cause in a PV array. First this is done by simulation using Matlab/Simulink, then the impact of shading is illustrated experimentally by measurements on a two commercial 140 W PV panels series connected.展开更多
A new dynamic non-equilibrium mixing-pool model for simulating start-up and dynamic re-sponse of a distillation column is reported.The proposed model is established on the basis ofconsidering the two dimensional flow/...A new dynamic non-equilibrium mixing-pool model for simulating start-up and dynamic re-sponse of a distillation column is reported.The proposed model is established on the basis ofconsidering the two dimensional flow/mixing behavior of actual trays in a distillation column.Com-parison is made among the computed results of the start-up time and the dynamic response time bythe proposed and five other typical models.It is found that the computed time for both dynamicprocesses is longer by the model which considers any flow/mixing pattern than by the model withoutsuch concern.The inertia effect of flow/mixing seems to be important and can not be ignored inmodeling the transient process of distillation.The proposed model,which is believed to be suitableto large column,seems somewhat useful in predicting industrial distillation dynamics.展开更多
The air gap at the interface inside the cable terminations for high-speed trains and the partial discharge caused by it are two important factors affecting the insulating performance.The development of air gap and par...The air gap at the interface inside the cable terminations for high-speed trains and the partial discharge caused by it are two important factors affecting the insulating performance.The development of air gap and partial discharge will eventually lead to breakdown faults.To investigate the evolutionary characteristics of the air gap and partial discharge,the simulation models and samples of cable terminations containing defects are constructed in this paper.By analysing the variation law of the electric field and the multidimensional information of partial discharge,the evolution process of the air gap is divided into four wellcharacterised stages.Especially in the third stage,the partial discharge extinction voltage is 51.41%lower than that of the defect-free samples and even lower than the working voltage.The asymmetry of discharge is the most significant factor.The volume of discharge in the third quadrant is significantly higher than that in the first quadrant.This important feature can be applied to the inspection and evaluation of the insulating state of the cable terminations.The partial discharge characteristics of the air gap revealed in this paper are proposed to provide an important theoretical supplement to the study of interface discharges between heterogeneous dielectrics.展开更多
Ericson formula represents the first formula, which was suggested to describe the partial level density (PLD) formula in pre-equilibrium region of the nuclear reactions. Then a number of corrections were added to this...Ericson formula represents the first formula, which was suggested to describe the partial level density (PLD) formula in pre-equilibrium region of the nuclear reactions. Then a number of corrections were added to this formula in order to make it more suitable to physical meaning. In this paper, there are two aims to be done: the first aim is to study the correspondence between one and two-components formulae in Ericson, Pauli, and pairing corrections;the second aim is to compare and study the results of Comprehensive formula, which contents with all corrections, with Ericson, Pauli, and pairing formulae. The Comprehensive formula was suggested to simulate the reality. To achieve these aims the 56Fe and 90Zr nuclei were chosen and the results showed that the difference between one and two-components formulae was too small which can be neglected. Furthermore, the results strongly recommended that for cross section calculations of the nuclear reaction, one must use Comprehensive formula rather than Pauli formula.展开更多
In order to explore the evolution law of coopetition relationship among Mcommerce information service(MIS)subjects and further reveal the allocation mechanism of information resources,the research extends Lotka-Volter...In order to explore the evolution law of coopetition relationship among Mcommerce information service(MIS)subjects and further reveal the allocation mechanism of information resources,the research extends Lotka-Volterra model,builds the coopetition relationship model of MIS subjects and simulates their coopetition relationship by Python and MATLAB to obtain the evolution trend of information resources possession(IRP)of MIS subjects in the coopetition process.The results show that the mutualism cooperation pattern dominated by promoting effect can maximize the value of information resources.This paper has significant reference value for how to optimize the allocation of information resources among MIS subjects.展开更多
Propagation properties of spatially pseudo-partially coherent Gaussian Schell-model beams through the atmo- spheric turbulence over a long-distance uplink path are studied by numerical simulation. A linear coordinatio...Propagation properties of spatially pseudo-partially coherent Gaussian Schell-model beams through the atmo- spheric turbulence over a long-distance uplink path are studied by numerical simulation. A linear coordination trans- formation is introduced to overcome the window effect and the loss-of-resolution problem. The beam spreading, beam wandering, and intensity scintillation as functions of turbulence strength, source correlation length, and change fre- quency of random phase that models the partial coherence of the source are analyzed. It is found that the beam spreading and the intensity scintillation of the partially coherent beam are less affected by the turbulence than those of the coherent one, but it suffers from a more severe diffractive effect, and the change frequency of random phase has no evident influence on it. The beam wandering is insensitive to the variation of source correlation length, and decreases firstly then goes to a fixed value as the change frequency increases.展开更多
In response to the lack of reliable physical parameters in the process simulation of the butadiene extraction,a large amount of phase equilibrium data were collected in the context of the actual process of butadiene p...In response to the lack of reliable physical parameters in the process simulation of the butadiene extraction,a large amount of phase equilibrium data were collected in the context of the actual process of butadiene production by acetonitrile.The accuracy of five prediction methods,UNIFAC(UNIQUAC Functional-group Activity Coefficients),UNIFAC-LL,UNIFAC-LBY,UNIFAC-DMD and COSMO-RS,applied to the butadiene extraction process was verified using partial phase equilibrium data.The results showed that the UNIFAC-DMD method had the highest accuracy in predicting phase equilibrium data for the missing system.COSMO-RS-predicted multiple systems showed good accuracy,and a large number of missing phase equilibrium data were estimated using the UNIFAC-DMD method and COSMO-RS method.The predicted phase equilibrium data were checked for consistency.The NRTL-RK(non-Random Two Liquid-Redlich-Kwong Equation of State)and UNIQUAC thermodynamic models were used to correlate the phase equilibrium data.Industrial device simulations were used to verify the accuracy of the thermodynamic model applied to the butadiene extraction process.The simulation results showed that the average deviations of the simulated results using the correlated thermodynamic model from the actual values were less than 2%compared to that using the commercial simulation software,Aspen Plus and its database.The average deviation was much smaller than that of the simulations using the Aspen Plus database(>10%),indicating that the obtained phase equilibrium data are highly accurate and reliable.The best phase equilibrium data and thermodynamic model parameters for butadiene extraction are provided.This improves the accuracy and reliability of the design,optimization and control of the process,and provides a basis and guarantee for developing a more environmentally friendly and economical butadiene extraction process.展开更多
The Yelapa-Chimo Metamorphic Complex forms part of the Jalisco Block in western Mexico and exposes a wide range of Early Cretaceous metamorphic rocks;such as paragneiss,orthogneiss,amphibolites,and migmatites.However,...The Yelapa-Chimo Metamorphic Complex forms part of the Jalisco Block in western Mexico and exposes a wide range of Early Cretaceous metamorphic rocks;such as paragneiss,orthogneiss,amphibolites,and migmatites.However,the pressure-temperature(P-T)conditions of metamorphism and partial melting remain poorly studied in the region.To elucidate metamorphic P-T conditions,phase equilibrium modelling was applied to two sillimanite-garnet paragneisses,one amphibole-orthogneiss,and one amphibolite.Sillimanite-garnet paragneisses exhibit a lepidoblastic texture with a biotite+sillimanite+kyanite+garnet+quartz+plagioclase+K-feldspar mineral assemblage.Amphibole-orthogneiss and amphibolite display a nematoblastic texture with an amphibole+(1)plagioclase+quartz+(1)titanite assemblage and an amphibole+(2)plagioclase+(2)titanite+ilmenite retrograde mineral assemblage.Pseudosections calculated for the two sillimanite-garnet paragneiss samples show P-T peak conditions at~6-7.5 kbar and~725-740℃.The results for amphibole-orthogneiss and the amphibolite yield P-T peak conditions at~8.5-10 kbar and~690-710℃.The mode models imply that metasedimentary and metaigneous units can produce up to~20 vol%and~10 vol%of melt,respectively.Modelling within a closed system during isobaric heating suggests that melt compositions of metasedimentary and metaigneous units are likely to have direct implications for the petrogenesis of the Puerto Vallarta Batholith.Our new data indicate that the Yelapa-Chimo Metamorphic Complex evolved through a metamorphic gradient between~23-33℃km^-1and the metamorphic rocks formed at depths between~22 km and~30 km with a burial rate of~2.0 km Ma^-1.Finally,the P-T data for both metasedimentary and metaigneous rocks provide new constraints on an accretionary framework,which is responsible for generating metamorphism and partial melting in the YelapaChimo Metamorphic Complex during the Early Cretaceous.展开更多
The present paper focuses on the erosive cavitation behavior around a plane convex hydrofoil. The Zwart-Gerber-Belamri cavitation model is implemented in a library form to be used with the OpenFOAM. The implicit large...The present paper focuses on the erosive cavitation behavior around a plane convex hydrofoil. The Zwart-Gerber-Belamri cavitation model is implemented in a library form to be used with the OpenFOAM. The implicit large eddy simulation （ILES） is app- lied to analyze the three-dimensional unsteady cavitating flow around a plane convex hydrofoil. The numerical results in the cases under the hydrodynamic conditions, which were experimentally tested at the high speed cavitation tunnel of the l^cole Polytechnique F6d＆ale de Lausanne （EPFL）, clearly show the sheet cavitation development, the shedding and the collapse of vapor clouds. It is noted that the cavitation evolutions including the maximum vapor length, the detachment and the oscillation frequency, are captured fairly well. Furthermore, the pressure pulses due to the cavitation development as well as the complex vortex structures are reasona- bly well predicted. Consequently, it may be concluded that the present numerical method can be used to investigate the unsteady cavitation around hydrofoils with a satisfactory accuracy.展开更多
Coal bed methane has been considered as an important energy resource.One major difficulty of purifying coal bed methane comes from the similar physical properties of CH_4 and N_2.The ZIF-8/water-glycol slurry was used...Coal bed methane has been considered as an important energy resource.One major difficulty of purifying coal bed methane comes from the similar physical properties of CH_4 and N_2.The ZIF-8/water-glycol slurry was used as a medium to separate coal bed methane by fluidifying the solid adsorbent material.The sorption equilibrium experiment of binary mixture(CH_4/N_2)and slurry was conducted.The selectivity of CH_4 to N_2 is within the range of 2-6,which proved the feasibility of the slurry separation method.The modified Langmuir equation was used to describe the gas-slurry phase equilibrium behavior,and the calculated results were in good agreement with the experimental data.A continuous absorption-adsorption and desorption process on the separation of CH_4/N_2 in slurry is proposed and its mathematical model is also developed.Sensitivity analysis is conducted to determine the operation conditions and the energy performance of the proposed process was also evaluated.Feed gas contains 30 mol%of methane and the methane concentration in product gas is 95.46 mol%with the methane recovery ratio of 90.74%.The total energy consumption for per unit volume of product gas is determined as 1.846 kWh Nm^(-3).Experimental results and process simulation provide basic data for the design and operation of pilot and industrial plant.展开更多
The Intalox metal tower packing was used to simulate an industrial relevant extractive distillation column for purifying azeotropic multicomponent mixture.In order to explain the inconsistencies in the modeling of tra...The Intalox metal tower packing was used to simulate an industrial relevant extractive distillation column for purifying azeotropic multicomponent mixture.In order to explain the inconsistencies in the modeling of transfer process in nonideal multicomponent distillation column,a method was developed with equilibrium stage models(EQ)and non-equilibrium model(NEQ)incorporated with Maxwell-Stefan diffusion equations in the framework of AspenONE simulator.Dortmund Modified UNIFAC(UNIFAC-DMD)thermodynamic model was employed to estimate activity coefficients.In addition,to understand the reason for the diffusion against driving force and the different results by EQ and NEQ models,explicit investigations were made on diffusion coefficients, component Murphree efficiency and mass transfer coefficients.The results provide valuable information for basic design and applications associated with extractive distillation.展开更多
文摘Because the normal operation of the engine is located near the equilibrium manifold, the method of equilibrium mani fold nonlinear dynamic modeling is adopted for turbofan engine more than the local train modeling. The method studies the sys tem characteristics near the equilibrium manifold. The modeling method can be realized through dynamic and static twostep, and for the specific parameter modeling steps and algorithm are given. The output of the test data is compared with the model output through numerical simulation, to check the model with an additional set of test data. The simulation results show that the model has reached the requirements of engineering accuracy.
基金the National Natural Science Foundation of China(Nos.52322603 and 51976005)the Science Center for Gas Turbine Project,China(Nos.P2022-B-II-004-001 and P2023-B-II-001-001)the Fundamental Research Funds for the Central Universities,and Beijing Nova Program,China(Nos.20220484074 and 20230484479).
文摘Accurate prediction of the aerodynamic response of a compressor under inlet distortion is crucial for next-generation civil aircraft,such as Boundary Layer Ingestion(BLI)silent aircraft.Therefore,research on the Body Force(BF)model plays a significant role in achieving this objective.However,distorted inlet airflow can lead to varying operating conditions across different spatial locations of the compressor,which may cause some regions to operate outside the stability boundary.Consequently,the accuracy of BF model simulations might be compromised.To address this issue,this paper proposes a numerical simulation strategy for acquiring the steady axisymmetric three-dimensional flow field of a compressor operating at low mass flow rates,which is known as the Underlying Axisymmetric Pressure Rise Characteristic(UAPRC).The proposed simulation accounts for two different rotor speeds of a transonic compressor and identifies initial positions in the flow field where deterioration occurs based on prior experimental investigations.Moreover,simulation results are incorporated into the BF model to replicate hub instability observed in experiments.Obtained results demonstrate that this strategy provides valid predictions of the UAPRC of the compressor,thereby addressing the limitations associated with the BF model.
文摘The extraction equilibrium mathematic models for gadolinium,terbium and dysprosium in HCl-1.5 mol/L HEH(EHP)system covering a relatively wide range of lanthanide concentration and acidity,have been developed.There are four independent variables and nine parameters.The average relative error is 4.56%.A computer program for the simulation of the counter current solvent extraetion process has also been written.Thus,the Gd,Tb and Dy concentrations in both aqueous and organic phase in eaeh stage as well as the aqueous acidity may be calculated.Product purities,distribution ratio and extraction factors may also be obtained thereby.The simulation results so obtained may serve as the referenee data for designing solvent ex- traction processes including those processes providing apart from the conventional outgoing organic stream, outgoing raffinate and an extra outgoing third exit stream either organic or aqueous.
基金This work is supported by the National Natural Science Foundation of China(No.52176048,No.U1909216,No.51876194)the General Scientific Research Projects of the Department of Education of Zhejiang Province(No.Y202147969)the Key Research and Development Program of Zhejiang Province(No.2022C01115).
文摘The hydrotreater system heat exchanger is one of the main pieces of heat exchange equipment in petrochemical enterprises.In recent years,oil resources have shown a deterioration trend of high sulfur and high acid content,with corrosion risk being prominent in oil processing.Taking the multi-medium flow corrosion risk of the hydrotreater heat exchanger pipeline in a petrochemical enterprise as the research object,based on the parameter characteristics of corrosive NH_(3) and HCl media under a high-temperature and high-pressure environment,the ammonium salt crystallization and deposition mechanism under multi-phase flow is revealed.The thermodynamic equilibrium curve is modified based on the thermodynamic principle and fugacity coefficient variation,and the prediction model of ammonium chloride crystallization in hydrotreater heat exchanger under high temperature and high pressure is constructed according to the modification.This study uses the mixture model,the flow-thermal coupling method,and the discrete phase model method to carry out the numerical simulation of multiphase flow and the numerical prediction of particle distribution characteristics in the heat exchanger pipeline of the hydrotreater heat exchange equipment,so as to realize the quantitative prediction of the particle crystallization deposition distribution in the pipeline.The results show that with the decrease of temperature,the crystallization occurs first on both sides of the center of the tube bundle,and more crystallization occurs in the lower half of the U-shaped tube,which may seriously lead to problems such as pipe blockage and under-deposit corrosion.
文摘In a solar photovoltaic array, it is possible that shadow may fall over some of its cells. Under partial shading conditions the PV characteristic gets more complex with multiple peaks. The purpose of this paper is to illustrate, by analyzing different shading situations, the effects that partial shading can cause in a PV array. First this is done by simulation using Matlab/Simulink, then the impact of shading is illustrated experimentally by measurements on a two commercial 140 W PV panels series connected.
文摘A new dynamic non-equilibrium mixing-pool model for simulating start-up and dynamic re-sponse of a distillation column is reported.The proposed model is established on the basis ofconsidering the two dimensional flow/mixing behavior of actual trays in a distillation column.Com-parison is made among the computed results of the start-up time and the dynamic response time bythe proposed and five other typical models.It is found that the computed time for both dynamicprocesses is longer by the model which considers any flow/mixing pattern than by the model withoutsuch concern.The inertia effect of flow/mixing seems to be important and can not be ignored inmodeling the transient process of distillation.The proposed model,which is believed to be suitableto large column,seems somewhat useful in predicting industrial distillation dynamics.
基金supported by National Natural Science Foundation of China,Grant/Award Number:52377161.
文摘The air gap at the interface inside the cable terminations for high-speed trains and the partial discharge caused by it are two important factors affecting the insulating performance.The development of air gap and partial discharge will eventually lead to breakdown faults.To investigate the evolutionary characteristics of the air gap and partial discharge,the simulation models and samples of cable terminations containing defects are constructed in this paper.By analysing the variation law of the electric field and the multidimensional information of partial discharge,the evolution process of the air gap is divided into four wellcharacterised stages.Especially in the third stage,the partial discharge extinction voltage is 51.41%lower than that of the defect-free samples and even lower than the working voltage.The asymmetry of discharge is the most significant factor.The volume of discharge in the third quadrant is significantly higher than that in the first quadrant.This important feature can be applied to the inspection and evaluation of the insulating state of the cable terminations.The partial discharge characteristics of the air gap revealed in this paper are proposed to provide an important theoretical supplement to the study of interface discharges between heterogeneous dielectrics.
文摘Ericson formula represents the first formula, which was suggested to describe the partial level density (PLD) formula in pre-equilibrium region of the nuclear reactions. Then a number of corrections were added to this formula in order to make it more suitable to physical meaning. In this paper, there are two aims to be done: the first aim is to study the correspondence between one and two-components formulae in Ericson, Pauli, and pairing corrections;the second aim is to compare and study the results of Comprehensive formula, which contents with all corrections, with Ericson, Pauli, and pairing formulae. The Comprehensive formula was suggested to simulate the reality. To achieve these aims the 56Fe and 90Zr nuclei were chosen and the results showed that the difference between one and two-components formulae was too small which can be neglected. Furthermore, the results strongly recommended that for cross section calculations of the nuclear reaction, one must use Comprehensive formula rather than Pauli formula.
基金The authors gratefully acknowledge the research support of National Social Science Fund Youth Project(CN)(No.19CTQ021).
文摘In order to explore the evolution law of coopetition relationship among Mcommerce information service(MIS)subjects and further reveal the allocation mechanism of information resources,the research extends Lotka-Volterra model,builds the coopetition relationship model of MIS subjects and simulates their coopetition relationship by Python and MATLAB to obtain the evolution trend of information resources possession(IRP)of MIS subjects in the coopetition process.The results show that the mutualism cooperation pattern dominated by promoting effect can maximize the value of information resources.This paper has significant reference value for how to optimize the allocation of information resources among MIS subjects.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 61107066 and 40805006)
文摘Propagation properties of spatially pseudo-partially coherent Gaussian Schell-model beams through the atmo- spheric turbulence over a long-distance uplink path are studied by numerical simulation. A linear coordination trans- formation is introduced to overcome the window effect and the loss-of-resolution problem. The beam spreading, beam wandering, and intensity scintillation as functions of turbulence strength, source correlation length, and change fre- quency of random phase that models the partial coherence of the source are analyzed. It is found that the beam spreading and the intensity scintillation of the partially coherent beam are less affected by the turbulence than those of the coherent one, but it suffers from a more severe diffractive effect, and the change frequency of random phase has no evident influence on it. The beam wandering is insensitive to the variation of source correlation length, and decreases firstly then goes to a fixed value as the change frequency increases.
基金supported by the National Natural Science Foundation of China(22178190)。
文摘In response to the lack of reliable physical parameters in the process simulation of the butadiene extraction,a large amount of phase equilibrium data were collected in the context of the actual process of butadiene production by acetonitrile.The accuracy of five prediction methods,UNIFAC(UNIQUAC Functional-group Activity Coefficients),UNIFAC-LL,UNIFAC-LBY,UNIFAC-DMD and COSMO-RS,applied to the butadiene extraction process was verified using partial phase equilibrium data.The results showed that the UNIFAC-DMD method had the highest accuracy in predicting phase equilibrium data for the missing system.COSMO-RS-predicted multiple systems showed good accuracy,and a large number of missing phase equilibrium data were estimated using the UNIFAC-DMD method and COSMO-RS method.The predicted phase equilibrium data were checked for consistency.The NRTL-RK(non-Random Two Liquid-Redlich-Kwong Equation of State)and UNIQUAC thermodynamic models were used to correlate the phase equilibrium data.Industrial device simulations were used to verify the accuracy of the thermodynamic model applied to the butadiene extraction process.The simulation results showed that the average deviations of the simulated results using the correlated thermodynamic model from the actual values were less than 2%compared to that using the commercial simulation software,Aspen Plus and its database.The average deviation was much smaller than that of the simulations using the Aspen Plus database(>10%),indicating that the obtained phase equilibrium data are highly accurate and reliable.The best phase equilibrium data and thermodynamic model parameters for butadiene extraction are provided.This improves the accuracy and reliability of the design,optimization and control of the process,and provides a basis and guarantee for developing a more environmentally friendly and economical butadiene extraction process.
基金funded by Programa de Apoyo a Proyectos de Investigacion e Innovacion Tecnologica(PAPIIT)grant IN112314。
文摘The Yelapa-Chimo Metamorphic Complex forms part of the Jalisco Block in western Mexico and exposes a wide range of Early Cretaceous metamorphic rocks;such as paragneiss,orthogneiss,amphibolites,and migmatites.However,the pressure-temperature(P-T)conditions of metamorphism and partial melting remain poorly studied in the region.To elucidate metamorphic P-T conditions,phase equilibrium modelling was applied to two sillimanite-garnet paragneisses,one amphibole-orthogneiss,and one amphibolite.Sillimanite-garnet paragneisses exhibit a lepidoblastic texture with a biotite+sillimanite+kyanite+garnet+quartz+plagioclase+K-feldspar mineral assemblage.Amphibole-orthogneiss and amphibolite display a nematoblastic texture with an amphibole+(1)plagioclase+quartz+(1)titanite assemblage and an amphibole+(2)plagioclase+(2)titanite+ilmenite retrograde mineral assemblage.Pseudosections calculated for the two sillimanite-garnet paragneiss samples show P-T peak conditions at~6-7.5 kbar and~725-740℃.The results for amphibole-orthogneiss and the amphibolite yield P-T peak conditions at~8.5-10 kbar and~690-710℃.The mode models imply that metasedimentary and metaigneous units can produce up to~20 vol%and~10 vol%of melt,respectively.Modelling within a closed system during isobaric heating suggests that melt compositions of metasedimentary and metaigneous units are likely to have direct implications for the petrogenesis of the Puerto Vallarta Batholith.Our new data indicate that the Yelapa-Chimo Metamorphic Complex evolved through a metamorphic gradient between~23-33℃km^-1and the metamorphic rocks formed at depths between~22 km and~30 km with a burial rate of~2.0 km Ma^-1.Finally,the P-T data for both metasedimentary and metaigneous rocks provide new constraints on an accretionary framework,which is responsible for generating metamorphism and partial melting in the YelapaChimo Metamorphic Complex during the Early Cretaceous.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.51306018,51536008 and 51179091)
文摘The present paper focuses on the erosive cavitation behavior around a plane convex hydrofoil. The Zwart-Gerber-Belamri cavitation model is implemented in a library form to be used with the OpenFOAM. The implicit large eddy simulation （ILES） is app- lied to analyze the three-dimensional unsteady cavitating flow around a plane convex hydrofoil. The numerical results in the cases under the hydrodynamic conditions, which were experimentally tested at the high speed cavitation tunnel of the l^cole Polytechnique F6d＆ale de Lausanne （EPFL）, clearly show the sheet cavitation development, the shedding and the collapse of vapor clouds. It is noted that the cavitation evolutions including the maximum vapor length, the detachment and the oscillation frequency, are captured fairly well. Furthermore, the pressure pulses due to the cavitation development as well as the complex vortex structures are reasona- bly well predicted. Consequently, it may be concluded that the present numerical method can be used to investigate the unsteady cavitation around hydrofoils with a satisfactory accuracy.
基金The financial supports received from the National Natural Science Foundation of China(21522609,21636009 and 21878328)the National Key Research and Development Program of China(Nos.2017YFC0307302,2016YFC0304003)+1 种基金the Science Foundation of China University of Petroleum,Beijing(No.2462018BJC004)Beijing Science and Technology Program,China(No.Z181100005118010)。
文摘Coal bed methane has been considered as an important energy resource.One major difficulty of purifying coal bed methane comes from the similar physical properties of CH_4 and N_2.The ZIF-8/water-glycol slurry was used as a medium to separate coal bed methane by fluidifying the solid adsorbent material.The sorption equilibrium experiment of binary mixture(CH_4/N_2)and slurry was conducted.The selectivity of CH_4 to N_2 is within the range of 2-6,which proved the feasibility of the slurry separation method.The modified Langmuir equation was used to describe the gas-slurry phase equilibrium behavior,and the calculated results were in good agreement with the experimental data.A continuous absorption-adsorption and desorption process on the separation of CH_4/N_2 in slurry is proposed and its mathematical model is also developed.Sensitivity analysis is conducted to determine the operation conditions and the energy performance of the proposed process was also evaluated.Feed gas contains 30 mol%of methane and the methane concentration in product gas is 95.46 mol%with the methane recovery ratio of 90.74%.The total energy consumption for per unit volume of product gas is determined as 1.846 kWh Nm^(-3).Experimental results and process simulation provide basic data for the design and operation of pilot and industrial plant.
基金Supported by the National Natural Science Foundation of China （20776118）, Science ＆ Technology Bureau of Xi＇an [CXY09019 （1）], Innovation Foundation for Graduated Student of Northwest University （08YJC21）, Shaanxi Research Center of Engineering Technology for Clean Coal Conversion （2008ZDGC-13）.
文摘The Intalox metal tower packing was used to simulate an industrial relevant extractive distillation column for purifying azeotropic multicomponent mixture.In order to explain the inconsistencies in the modeling of transfer process in nonideal multicomponent distillation column,a method was developed with equilibrium stage models(EQ)and non-equilibrium model(NEQ)incorporated with Maxwell-Stefan diffusion equations in the framework of AspenONE simulator.Dortmund Modified UNIFAC(UNIFAC-DMD)thermodynamic model was employed to estimate activity coefficients.In addition,to understand the reason for the diffusion against driving force and the different results by EQ and NEQ models,explicit investigations were made on diffusion coefficients, component Murphree efficiency and mass transfer coefficients.The results provide valuable information for basic design and applications associated with extractive distillation.
