Catassembly is a new concept in molecular assembly that is analogous to catalysis in chemical synthesis. However, for most molecular-assembled processes, the catassembler contributions are rather inconspicuous due to ...Catassembly is a new concept in molecular assembly that is analogous to catalysis in chemical synthesis. However, for most molecular-assembled processes, the catassembler contributions are rather inconspicuous due to the low activation barriers. As a result, few systems dealing with the catassembly are available until now. In this paper, we report that naphthalene diimide coordination networks are formed under the catassembly of lone-pair-bearing catassemblers(e.g., N,N-dimethylacetamide, N-methylpyrrolidin-2-one). During such molecular assembly, a stable transition state between the electron-deficient naphthalene diimide tectons and catassemblers via the less common lone pair-π interactions was observed, which is supposed to play the key role in the enhancement of coordination abilities of organic tectons and thus formation of the final coordination networks.展开更多
Let π be a set of primes. Isaacs established the π-theory of characters, which generalizes the theory of Brauer modular characters. Motivated by Isaacs＇s work, we introduce the definition of Mπ-groups and provide ...Let π be a set of primes. Isaacs established the π-theory of characters, which generalizes the theory of Brauer modular characters. Motivated by Isaacs＇s work, we introduce the definition of Mπ-groups and provide a characterization of Mπ-groups.展开更多
Using Shamir＇s secret sharing scheme to indi- rectly share the identity-based private key in the form of a pairing group element, we propose an efficient identity-based threshold decryption scheme from pairings and p...Using Shamir＇s secret sharing scheme to indi- rectly share the identity-based private key in the form of a pairing group element, we propose an efficient identity-based threshold decryption scheme from pairings and prove its se- curity in the random oracle model. This new paring-based scheme features a few improvements compared with other schemes in the literature. The two most noticeable features are its efficiency, by drastically reducing the number of pair- ing computations, and the ability it gives the user to share the identity-based private key without requiring any access to a private key generator. With the ability it gives the user to share the identity-based private key, our ID-based threshold decryption （IBTD） scheme, the second of its kind, is signif- icantly more efficient than the first scheme, which was de- veloped by Baek and Zheng, at the expense of a slightly in- creased ciphertext length. In fact, our IBTD scheme tries to use as few bilinear pairings as possible, especially without depending on the suite of Baek-Zheng secret sharing tools based on pairings.展开更多
Studies of γγ interactions are performed with the KLOE detector, without tagging of the outgoing e^＋e^-. The data sample is from an integrated luminosity of 240 pb^-1. It was collected at the φ-factory DAONE with...Studies of γγ interactions are performed with the KLOE detector, without tagging of the outgoing e^＋e^-. The data sample is from an integrated luminosity of 240 pb^-1. It was collected at the φ-factory DAONE with e^＋e^- beams colliding at √s ≌1 GeV, below the φ resonance peak. We present preliminary results concerning the observation of the γγ→η process and the evidence for γγ→π^0π^0 production at low π^0π^0 invariant masses.展开更多
On the basis of the FLP (frustrated Lewis pair) principle, a new strategy has been proposed to construct the "frustration" in de- signing metal-free hydrogen activation compounds, by using FMO (frontier mole...On the basis of the FLP (frustrated Lewis pair) principle, a new strategy has been proposed to construct the "frustration" in de- signing metal-free hydrogen activation compounds, by using FMO (frontier molecular orbital) analyses and quantum mechanics calculations. Unlike the known FLPs which use bulky substituents to prevent them from forming stable Lewis acid/base com- plexes, the new approach encumbers the intramolecular π donation from the electron donor to the acceptor (e.g. in BH2NH2) by using a CH2 bridge (giving BH2CH2NH2). The strategy is simple and effective. Its effectiveness is demonstrated by the small hy- drogen activation energy (12.0 kcal/mol) of the model molecule (BH2CH2NH2), which is significantly less than the 42.7 kcal/mol of BH2NH2 and also less than the 18.5 kcal/mol of BH2PH2 whose derivative, R2PB(C6F5)2, has been experimentally shown to be able to activate hydrogen. We also exemplified how to use the strategy to design experimentally more realizable molecules. The example shows promises as a hydrogen activation agent. The strategy can be used to design metal-free catalysts for direct hydro-genation.展开更多
基金supported by the National Natural Science Foundation of China (21202020, 21572032)the Doctoral Fund of Ministry of Education of China (20123514120002)+1 种基金the Natural Science Foundation of Fujian Province (2014J01040)the Science & Technical Development Foundation of Fuzhou University (2012-XQ-10, 2013-XQ-14)
文摘Catassembly is a new concept in molecular assembly that is analogous to catalysis in chemical synthesis. However, for most molecular-assembled processes, the catassembler contributions are rather inconspicuous due to the low activation barriers. As a result, few systems dealing with the catassembly are available until now. In this paper, we report that naphthalene diimide coordination networks are formed under the catassembly of lone-pair-bearing catassemblers(e.g., N,N-dimethylacetamide, N-methylpyrrolidin-2-one). During such molecular assembly, a stable transition state between the electron-deficient naphthalene diimide tectons and catassemblers via the less common lone pair-π interactions was observed, which is supposed to play the key role in the enhancement of coordination abilities of organic tectons and thus formation of the final coordination networks.
基金supported by the Natural Science Foundation in Jiangsu Province of China(BK20130748)Natural Science Fund for Colleges and Universities in Jiangsu Province of China(13KJB150012)+1 种基金Jiangxi Provincial Natural Science Foundation of China(20142BAB213010)National Natural Science Foundation of China(21405013)~~
基金Supported by NSF of China(1117116911071155)the B.S.Foundation of Shandong Province(BS2012SF003)
文摘Let π be a set of primes. Isaacs established the π-theory of characters, which generalizes the theory of Brauer modular characters. Motivated by Isaacs＇s work, we introduce the definition of Mπ-groups and provide a characterization of Mπ-groups.
文摘Using Shamir＇s secret sharing scheme to indi- rectly share the identity-based private key in the form of a pairing group element, we propose an efficient identity-based threshold decryption scheme from pairings and prove its se- curity in the random oracle model. This new paring-based scheme features a few improvements compared with other schemes in the literature. The two most noticeable features are its efficiency, by drastically reducing the number of pair- ing computations, and the ability it gives the user to share the identity-based private key without requiring any access to a private key generator. With the ability it gives the user to share the identity-based private key, our ID-based threshold decryption （IBTD） scheme, the second of its kind, is signif- icantly more efficient than the first scheme, which was de- veloped by Baek and Zheng, at the expense of a slightly in- creased ciphertext length. In fact, our IBTD scheme tries to use as few bilinear pairings as possible, especially without depending on the suite of Baek-Zheng secret sharing tools based on pairings.
文摘Studies of γγ interactions are performed with the KLOE detector, without tagging of the outgoing e^＋e^-. The data sample is from an integrated luminosity of 240 pb^-1. It was collected at the φ-factory DAONE with e^＋e^- beams colliding at √s ≌1 GeV, below the φ resonance peak. We present preliminary results concerning the observation of the γγ→η process and the evidence for γγ→π^0π^0 production at low π^0π^0 invariant masses.
基金supported by the Hundred Talents Program of the Chinese Academy of Sciences and Nationd Nataral Science Foundation of China (Grant No.20773160)
文摘On the basis of the FLP (frustrated Lewis pair) principle, a new strategy has been proposed to construct the "frustration" in de- signing metal-free hydrogen activation compounds, by using FMO (frontier molecular orbital) analyses and quantum mechanics calculations. Unlike the known FLPs which use bulky substituents to prevent them from forming stable Lewis acid/base com- plexes, the new approach encumbers the intramolecular π donation from the electron donor to the acceptor (e.g. in BH2NH2) by using a CH2 bridge (giving BH2CH2NH2). The strategy is simple and effective. Its effectiveness is demonstrated by the small hy- drogen activation energy (12.0 kcal/mol) of the model molecule (BH2CH2NH2), which is significantly less than the 42.7 kcal/mol of BH2NH2 and also less than the 18.5 kcal/mol of BH2PH2 whose derivative, R2PB(C6F5)2, has been experimentally shown to be able to activate hydrogen. We also exemplified how to use the strategy to design experimentally more realizable molecules. The example shows promises as a hydrogen activation agent. The strategy can be used to design metal-free catalysts for direct hydro-genation.
