Light emitting diodes(LEDs)have accounted for most of the lighting market as the technology matures and costs continue to reduce.As a new type of e-waste,LED is a double-edged sword,as it contains not only precious an...Light emitting diodes(LEDs)have accounted for most of the lighting market as the technology matures and costs continue to reduce.As a new type of e-waste,LED is a double-edged sword,as it contains not only precious and rare metals but also organic packaging materials.In previous studies,LED recycling focused on recovering precious and strategic metals while ignoring harmful substances such as organic packaging materials.Unlike crushing and other traditional methods,hydrothermal treatment can provide an environment-friendly process for decomposing packaging materials.This work developed a closed reaction vessel,where the degradation rate of plastic polyphthalamide(PPA)was close to 100%,with nano-TiO_(2)encapsulated in plastic PPA being efficiently recovered,while metals contained in LED were also recycled efficiently.Besides,the role of water in plastic PPA degradation that has been overlooked in current studies was explored and speculated in detail in this work.Environmental impact assessment revealed that the proposed recycling route for waste LED could significantly reduce the overall environmental impact compared to the currently published processes.Especially the developed method could reduce more than half the impact of global warming.Furthermore,this research provides a theoretical basis and a promising method for recycling other plastic-packaged e-waste devices,such as integrated circuits.展开更多
The objective of this study is to improve the mechanical properties and machining performance of high thermal conductivity and low expansion silicon carbide dispersion-strengthened hypereutectic aluminum-silicon elect...The objective of this study is to improve the mechanical properties and machining performance of high thermal conductivity and low expansion silicon carbide dispersion-strengthened hypereutectic aluminum-silicon electronic packaging materials to meet the needs of aviation,aerospace,and electronic packaging fields.We used the powder metallurgy method and high-temperature hot pressing technology to prepare SiC/Al-Si composite materials with different SiC contents(5vol%,10vol%,15vol%,and 20vol%).The results showed that as the SiC content increased,the tensile strength of the composite material first increased and then decreased.The tensile strength was the highest when the SiC content was 15%;the sintering temperature significantly affected the composite material’s structural density and mechanical properties.Findings indicated 700℃was the optimal sintering and the optimal SiC content of SiC/Al-Si composite materials was between 10%and 15%.Besides,the sintering temperature should be strictly controlled to improve the material’s structural density and mechanical properties.展开更多
In this work, low-temperature vulcanized, transparent silane modified epoxy resins for LED filament bulb package were prepared. Firstly, transparent silane modified epoxy resins were produced through a controllable so...In this work, low-temperature vulcanized, transparent silane modified epoxy resins for LED filament bulb package were prepared. Firstly, transparent silane modified epoxy resins were produced through a controllable sol-gel method using γ-（2,3-epoxypropoxy）propytrimethoxysilane and dimethyldiethoxylsilane. The features of the reaction were investigated and the products were characterized in detail. Subsequently, various curing agents were explored to prepare transparent silane modified epoxy resins. The silane modified epoxy resins cured by PEA-230 at a fairly low temperature（40 °C/2 h then 60 °C/1 h） exhibited excellent thermal stability with a thermal degradation temperature as high as 316.5 °C and adjustable hardness between 40-60 shore A. The application tests showed the materials obtained were good candidates for LED filament bulb package.展开更多
Petrochemical plastics are widely used for food protection and preservation;however,they exhibit poor biodegradability,resisting natural degradation through physical,chemical,or enzymatic processes.As a sustainable al...Petrochemical plastics are widely used for food protection and preservation;however,they exhibit poor biodegradability,resisting natural degradation through physical,chemical,or enzymatic processes.As a sustainable alternative to conventional plastic packaging,edible films offer effective barriers against moisture,gases,and microbial contamination while being biodegradable,biocompatible,and environmentally friendly.In this study,novel active food packaging materials(in film form)were developed by incorporating starch,carrageenan,nanocellulose(NC),Aloe vera,and hibiscus flower extract.The effects of varying the matrix composition(26.5–73.5 wt.%starch/carrageenan),NC concentration(2.77-17.07 wt.%),and particle type(fibers or crystals)on the film structure and characteristics were analyzed using various methods.Scanning electron microscopy demonstrated good homogeneity and effective dispersion of NC within the blendmatrix.An increased carrageenan content in the filmimproved wettability,moisture absorption,solubility,and water vapor permeability.The mechanical properties of the films were enhanced by NC incorporation and higher carrageenan content.The developed films also exhibited effective UV radiation barriers and biodegradability.Films with low carrageenan content(less than 33.3%)and high NC content(7%,10% crystals or 10%,15% fibers)exhibited optimal properties,including enhanced water resistance,hydrophobicity,and mechanical strength,along with reduced water vapor permeability.However,the high water solubility and moisture absorption(above 55% and 14%,respectively)indicated their unsuitability as packaging materials for food products with wet surfaces and high humidity.The results suggest that these films are well suited for use as edible food packaging for fruits and vegetables.展开更多
Photoinitiators(PIs),as an important component of UV inks,are widely used in the printing of paper food packaging.Nevertheless,there is limited information concerning the identification of PIs in food packaging and th...Photoinitiators(PIs),as an important component of UV inks,are widely used in the printing of paper food packaging.Nevertheless,there is limited information concerning the identification of PIs in food packaging and their potential migration rules under natural storage condition.In this study,23 target PIs detected in paper food packaging were dominated by benzophenones(BZPs),followed by amine co-initiators(ACIs),thioxanthones(TXs)and phosphine oxides(POs).The concentration of ΣPIs ranged between 48.3 and 1.11×10^(5)ng/g.Meanwhile,the concentration ofΣPIs were found to be significantly higher in Corrugated paper compared to Polyethylene(PE)coated paper,Composite paper and White card paper.Benzophenone(BP)was found as the dominant PI congener in Corrugated paper,with the concentration ranging from 923-3.66×10^(4)ng/g.The migration quantity ofΣPIs increased in a time-dependent manner in the first 13 days and then eventually reached equilibrium.Low temperatures had a certain inhibitory effect on the migration of PIs from paper packaging to food.Under high exposure scenario,the EDIs of ΣPIs for children,adolescents,and adults were 31.4 ng/(kg bw·day),17.2 ng/(kg bw·day),and 14.4 ng/(kg bw·day),respectively,all of which did not exceed the reference dose,indicating that dietary intake of PIs does not pose any health risks to the human body.展开更多
Three types of Al/Al−27%Si laminated composites,each containing 22%Si,were fabricated via hot pressing and hot rolling.The microstructures,mechanical properties and thermo-physical properties of these composites were ...Three types of Al/Al−27%Si laminated composites,each containing 22%Si,were fabricated via hot pressing and hot rolling.The microstructures,mechanical properties and thermo-physical properties of these composites were investigated.The results demonstrated that the three laminated composites exhibited similar microstructural features,characterized by well-bonded interfaces between the Al layer and the Al−27%Si alloy layer.The tensile and flexural strengths of the composites were significantly higher than those of both Al−22%Si and Al−27%Si alloys.These strengths increased gradually with decreasing the layer thickness,reaching peak values of 222.5 and 407.4 MPa,respectively.Crack deflection was observed in the cross-sections of the bending fracture surfaces,which contributed to the enhanced strength and toughness.In terms of thermo-physical properties,the thermal conductivity of the composites was lower than that of Al−22%Si and Al−27%Si alloys.The minimum reductions in thermal conductivity were 6.8%and 0.9%for the T3 laminated composite,respectively.Additionally,the coefficient of thermal expansion of the composites was improved,exhibiting varying temperature-dependent behaviors.展开更多
Thermal property is one of the most important properties of light-emitting diode （LED）. Thermal property of LED packaging material determines the heat dissipations of the phosphor and the chip surface, accordingly h...Thermal property is one of the most important properties of light-emitting diode （LED）. Thermal property of LED packaging material determines the heat dissipations of the phosphor and the chip surface, accordingly having an influence on the light-emitting efficiency and the life-span of the device. In this paper, photoacoustic piezoelectric （PAPE） technique has been employed to investigate the thermal properties of polyvinyl alcohol （]？VA） and silicon dioxide, which are the new and the traditional packaging materials in white LED, respectively. Firstly, the theory of PAPE technique has been developed for two-layer model in order to investigate soft materials; secondly, the experimental system has been set up and adjusted by measuring the reference sample; thirdly, the thermal diffusivities of PVA and silicon dioxide are measured and analysed. The experimental results show that PVA has a higher thermal diffusivity than silicon dioxide and is a better packaging material in the sense of thermal diffusivity for white LED.展开更多
Paper packaging materials like cardboards are widely used to protect archives which are a major kind of cultural relics.Unfortunately,paper is a combustible material,and thus exploring environment-friendly flame retar...Paper packaging materials like cardboards are widely used to protect archives which are a major kind of cultural relics.Unfortunately,paper is a combustible material,and thus exploring environment-friendly flame retardant for paper-based archive packaging material plays an important role.Herein,boric acid,borax and disodium octaborate are used to modify the craft paper-based packaging materials for archive conservation to improve fire safety.The modified craft paper exhibits much higher flame retardancy than the pristine one dose based on vertical burning tests,without much influence on mechanical properties such as tensile strength and elongation at break.Thermogravimetric analysis(TGA),scanning electron microscope(SEM),and X-ray photoelectron spectroscopy(XPS)reveal that porous glass structure is formed during the combustion,because thermal decomposition of boric acid,borax and disodium octaborate will produce porous glassy matter as B_(2)O_(3).The porous glass covers the paper surface as an insulating layer which retards the further pyrolysis and combustion,resulting in a denser carbon layer.Our study provides a robust way to reduce the fire hazard of the archive packaging material by applying environment-friendly boron-based fire retardants.展开更多
A polymer-based carbon nano-tubes (CNTs) composite with high electromagnetic (EM) wave shielding effectiveness (SE) and with high mechanical property is developed for packaging of electronic modulus or devices.The ...A polymer-based carbon nano-tubes (CNTs) composite with high electromagnetic (EM) wave shielding effectiveness (SE) and with high mechanical property is developed for packaging of electronic modulus or devices.The liquid crystal polymers (LCP) and melamine formaldehydes (MF) polymer are used to study the orientation effect of CNTs in various polymeric matrix.The influences of orientation,aspect ratio,and mass fraction of CNTs upon the shielding effectiveness (SE) of CNTs-composites are investigated.The higher the orientation,aspect ratio,and weight percentages of nano-materials are, the higher the SE of the carbon composites.The highest SE for the CNTs/LCP nano composite obtained is more than 62 dB. This results may lead to the developing for CPU IC chip packaging.展开更多
Based on the deepening awareness of the risk of changing packaging materials of injections,the national regulatory authorities and the China National Pharmaceutical Packaging Association have issued the relevant guide...Based on the deepening awareness of the risk of changing packaging materials of injections,the national regulatory authorities and the China National Pharmaceutical Packaging Association have issued the relevant guidelines and group standards for changing packaging materials in recent years,greatly improving the research and development and technical requirements of packaging materials of injections.In 2021,Guangdong Province carried out the archival examination of the change of listed drugs,among which the proportion of the acceptance of changed injection packaging materials has increased year by year.On the basis of sorting out the archival examination work and combining with the cases of changing packaging materials of chemical injections accepted by Guangdong Province during 2021-2022,the requirements and problems of archival examination were analyzed and discussed to provide a reference and idea for applicants when studying the change in packaging materials.展开更多
Objective: to analyze the internal relationship between drug packaging materials and liquid pharmaceutical quality. Methods: by sorting out relevant documents and referring to the current situation of liquid pharmaceu...Objective: to analyze the internal relationship between drug packaging materials and liquid pharmaceutical quality. Methods: by sorting out relevant documents and referring to the current situation of liquid pharmaceutical packaging, the internal relationship between different packaging materials and the quality of liquid pharmaceutical was discussed. Results: the corresponding quality of different drug packaging materials is completely different, but they will affect human health, and also directly affect the quality of drugs. During the storage and management of liquid drugs, the best drug packaging materials must be determined with reference to the physical and chemical characteristics of drugs, so as to achieve the purpose of standardized, stable and scientific packaging. Conclusion: in clinical practice, the physical and chemical properties of each drug are completely different. When using packaging materials, we must refer to the physical and chemical properties of drugs to implement scientific configuration. The fundamental purpose is to avoid adverse effects on the health of patients as far as possible;It can also maximize the stability and effectiveness of drug quality.展开更多
The thermal conductivity of Cu/Kovar composites was improved by suppressing element diffusion at the interfaces through the formation of FeWO_(4)coating on the Kovar particles via vacuum deposition.Cu matrix composite...The thermal conductivity of Cu/Kovar composites was improved by suppressing element diffusion at the interfaces through the formation of FeWO_(4)coating on the Kovar particles via vacuum deposition.Cu matrix composites reinforced with unmodified(Cu/Kovar)and modified Kovar(Cu/Kovar@)particles were prepared by hot pressing.The results demonstrate that the interfaces of Cu/FeWO_(4)and FeWO_(4)/Kovar in the Cu/Kovar@composites exhibit strong bonding,and no secondary phase is generated.The presence of FeWO_(4)impedes interfacial diffusion within the composite,resulting in an increase in grain size and a decrease in dislocation density.After surface modification of the Kovar particle,the thermal conductivity of Cu/Kovar@composite is increased by 110%from 40.6 to 85.6 W·m^(-1)·K^(-1).Moreover,the thermal expansion coefficient of the Cu/Kovar@composite is 9.8×10^(-6)K^(-1),meeting the electronic packaging requirements.展开更多
This study was conducted to investigate the effects of different packaging methods on seed germination and vigor under a long-term bank storage condition, selecting suitable packaging materials and methods, and compre...This study was conducted to investigate the effects of different packaging methods on seed germination and vigor under a long-term bank storage condition, selecting suitable packaging materials and methods, and comprehensively estimate changes in seed vigor of seeds stored with different packaging materials. Hibiscus cannabinus L. seeds were stored in aluminium box, seed box, glass bottle, POlyethylene film bag, sack and kraft paper bag as packaging materials in a, long-term bank and tested for their seeds germinability, electrical conductivity and field seedling rate after 31 years. The results showed that the kenaf seeds with an initial germination rate of 88% exhibited the germination rates over 79.7% after being stored in the 6 packaging materials for 31 years, the germination rates of seeds packaged with paper bag and sack and of those sealed in film bag and aluminium box showed significantly decreased germination rates, while the seeds sealed in seed boxes and glass bottles exhibited non-significant decreases in seed germination rate, and their germination rates were still above 85%. Seed box and glass bottle were the packaging materials most suitable for long-term safe storage of kenaf seeds with a safe storage period long than 31 years.展开更多
The Cu/Invar composites of 40% Cu were prepared by powder metallurgy, and the composites were rolled with 70% reduction and subsequently annealed at 750 ℃. Phases, microstructures and properties of the composites wer...The Cu/Invar composites of 40% Cu were prepared by powder metallurgy, and the composites were rolled with 70% reduction and subsequently annealed at 750 ℃. Phases, microstructures and properties of the composites were then studied. After that, the amount of a-Fe（Ni,Co） in the composites is reduced, because a-Fe（Ni,Co） partly transfers into y-Fe（Ni,Co） through the diffusion of the Ni atoms into a-Fe（Ni,Co） from Cu. When the rolling reduction is less than 40%, the deformation of Cu takes place, resulting in the movement of the Invar particles and the seaming of the pores. When the rolling reduction is in the range from 40% to 60%, the deformations of Invar and Cu occur simultaneously to form a streamline structure. After rolling till 70% and subsequent annealing, the Cu/Invar composites have fine comprehensive properties with a relative density of 98.6%, a tensile strength of 360 MPa, an elongation rate of 50%, a thermal conductivity of 25.42 W/（m.K） （as-tested） and a CTE of 10.79× 10-6/K （20-100 ℃）.展开更多
A novel type of ZnO-Al2O3-B2O3-SiO2 glass-ceramics sealing to Kovar in electronic packaging was developed, whose thermal expansion coefficient and electrical resistance are 5.2× 10^-6/℃ and over 1×10^13 Ω&...A novel type of ZnO-Al2O3-B2O3-SiO2 glass-ceramics sealing to Kovar in electronic packaging was developed, whose thermal expansion coefficient and electrical resistance are 5.2× 10^-6/℃ and over 1×10^13 Ω·cm, respectively. The major crystalline phases in the glass-ceramic seals were ZnAl2O4, ZnB2O4, and NaSiAl2O4. The dielectric resistance of the glass-ceramic could be remarkably enhanced through the control of alkali metal ions into crystal lattices. It was found that crystallization happened first on the surface of the sample, leaving the amorphous phase in the inner, which made the glass suitable for sealing. The glass-ceramic showed better wetting on the Kovar surface, and sealing atmosphere and temperature had great effect on the wetting angle. Strong interracial bonding was obtained, which was mainly attributed to the interracial reaction between SiO2 and FeO or Fe3O4.展开更多
The current work explores the potential use of commercial Chinese bayberry tannin(BT)to develop antioxidant PVA-based films using solvent casting process for packaging applications.The effect of BT concentration on op...The current work explores the potential use of commercial Chinese bayberry tannin(BT)to develop antioxidant PVA-based films using solvent casting process for packaging applications.The effect of BT concentration on opa-city,water resistance and antioxidant capacity of resulting films was investigated.Properties like tensile strength,thermal behavior,and morphological aspects were also characterized.The experimental results showed that PVA/BT films formed with uniformly brown color and generally good transparency,offering good antioxidant ability.The PVA film containing BT presented slightly higher water resistance according to the results of moisture content and water vapor permeability,especially at low BT content(<10 wt%).The PVA can be compounded with up to 10 wt%BT without any obvious deterioration in the tensile strength.The PVA/BT films exhibited better thermal degradation behavior compared with PVA alone because of the chemical bonds of PVA-BT and the for-mation of char at high temperature.Based on the results,PVA incorporated with Chinese bayberry tannin may provide broader formulation options for packaging materials with antioxidant action.展开更多
Magnetics,ferroelectrics,and multiferroics have attracted great attentions because they are not only extremely im-portant for investigating fundamental physics,but also have important applications in information techn...Magnetics,ferroelectrics,and multiferroics have attracted great attentions because they are not only extremely im-portant for investigating fundamental physics,but also have important applications in information technology.Here,recent computational studies on magnetism and ferroelectricity are reviewed.We first give a brief introduction to magnets,fer-roelectrics,and multiferroics.Then,theoretical models and corresponding computational methods for investigating these materials are presented.In particular,a new method for computing the linear magnetoelectric coupling tensor without applying an external field in the first principle calculations is proposed for the first time.The functionalities of our home-made Property Analysis and Simulation Package for materials(PASP)and its applications in the field of magnetism and ferroelectricity are discussed.Finally,we summarize this review and give a perspective on possible directions of future computational studies on magnetism and ferroelectricity.展开更多
The rapid development of the electronic information industry brings to the irreplaceable role of electronic components, therefore the search of a more reliable packaging material has become increasingly important. In ...The rapid development of the electronic information industry brings to the irreplaceable role of electronic components, therefore the search of a more reliable packaging material has become increasingly important. In the electronic packaging system, the failure phenomenon caused by residual stress is one of the key factors restricting the development of electronic packaging technology. In order to use the in-situ characterization technology to explore the residual stress inducing mechanism and failure mechanism of epoxy-based advanced packaging materials, this paper gives a review of related previous research, and lays a theoretical foundation for the upcoming research. The classification and generation mechanism of residual stress are clarified in this paper, which provides data support for future related research.展开更多
Objective To evaluate the clinical value of basic infusion packaging materials for providing suggestions on formulating basic infusion volume procurement policies.Methods Combined with market data,questionnaire survey...Objective To evaluate the clinical value of basic infusion packaging materials for providing suggestions on formulating basic infusion volume procurement policies.Methods Combined with market data,questionnaire surveys were used to rank different basic infusion packaging materials.Pharmacists,nurses,and experts in the field of packaging respectively assess the safety,compatibility,effectiveness,convenience,and environmental friendliness of the materials.Results and Conclusion Products with the best clinical value have a lower market share than other products with average clinical value.The best three packaging materials only account for 15%of the market share.The order of clinical value from good to bad is inner-sealed polypropylene infusion bag(BFS)>soft aseptic bag with double valves and layers>upright polypropylene infusion bag>non-PVC soft bag>plastic bottle>glass bottle.The order of market share is non-PVC soft bag>soft aseptic bag with double valves and layers>plastic bottle>vertical polypropylene infusion bag>inner-sealed polypropylene infusion bag(BFS)>glass bottle.Therefore,the clinical values of various basic infusion packaging materials are different.The following countermeasures are put forward such as separating bidding for basic infusions with different packaging materials,combining volume and price with procurement,and priority procurement of packaging materials with better clinical values.展开更多
Polylactic acid,a biodegradable polymer derived from renewable resources,is increasingly used in food packaging due to its transparency,renewability,and food safety.However,its mechanical properties,heat resistance,an...Polylactic acid,a biodegradable polymer derived from renewable resources,is increasingly used in food packaging due to its transparency,renewability,and food safety.However,its mechanical properties,heat resistance,and barrier performance present significant challenges that limit its application.Currently,there is a lack of comprehensive literature addressing methods to optimize polylactic acid’s performance for various food packaging application.Hence,this review provides an overview of polylactic acid production processes,including the synthesis of lactic acid and lactide,as well as methods such as polycondensation and ring-opening polymerization.We critically examine the advantages and limitations of polylactic acid in various food packaging contexts,focusing on strategies to enhance its mechanical properties,barrier performance against oxygen and water vapor,surface hydrophobicity,thermal stability,and resistance to ultraviolet light.Furthermore,we summarize recent advancements in polylactic acid applications for food packaging,highlighting innovations in antioxidant,antimicrobial,and freshness indicator packaging.These developments underscore the significant potential of polylactic acid in the food packaging sector and offer valuable insights for future research directions.展开更多
基金supported by the National Natural Science Foundation of China(52270132).
文摘Light emitting diodes(LEDs)have accounted for most of the lighting market as the technology matures and costs continue to reduce.As a new type of e-waste,LED is a double-edged sword,as it contains not only precious and rare metals but also organic packaging materials.In previous studies,LED recycling focused on recovering precious and strategic metals while ignoring harmful substances such as organic packaging materials.Unlike crushing and other traditional methods,hydrothermal treatment can provide an environment-friendly process for decomposing packaging materials.This work developed a closed reaction vessel,where the degradation rate of plastic polyphthalamide(PPA)was close to 100%,with nano-TiO_(2)encapsulated in plastic PPA being efficiently recovered,while metals contained in LED were also recycled efficiently.Besides,the role of water in plastic PPA degradation that has been overlooked in current studies was explored and speculated in detail in this work.Environmental impact assessment revealed that the proposed recycling route for waste LED could significantly reduce the overall environmental impact compared to the currently published processes.Especially the developed method could reduce more than half the impact of global warming.Furthermore,this research provides a theoretical basis and a promising method for recycling other plastic-packaged e-waste devices,such as integrated circuits.
文摘The objective of this study is to improve the mechanical properties and machining performance of high thermal conductivity and low expansion silicon carbide dispersion-strengthened hypereutectic aluminum-silicon electronic packaging materials to meet the needs of aviation,aerospace,and electronic packaging fields.We used the powder metallurgy method and high-temperature hot pressing technology to prepare SiC/Al-Si composite materials with different SiC contents(5vol%,10vol%,15vol%,and 20vol%).The results showed that as the SiC content increased,the tensile strength of the composite material first increased and then decreased.The tensile strength was the highest when the SiC content was 15%;the sintering temperature significantly affected the composite material’s structural density and mechanical properties.Findings indicated 700℃was the optimal sintering and the optimal SiC content of SiC/Al-Si composite materials was between 10%and 15%.Besides,the sintering temperature should be strictly controlled to improve the material’s structural density and mechanical properties.
基金financial support from the Zhejiang Provincial Natural Science Foundation of China (No.Y14E030008)the Commonweal Technology Application Research Project of Zhejiang Province (No.2013C31079)
文摘In this work, low-temperature vulcanized, transparent silane modified epoxy resins for LED filament bulb package were prepared. Firstly, transparent silane modified epoxy resins were produced through a controllable sol-gel method using γ-（2,3-epoxypropoxy）propytrimethoxysilane and dimethyldiethoxylsilane. The features of the reaction were investigated and the products were characterized in detail. Subsequently, various curing agents were explored to prepare transparent silane modified epoxy resins. The silane modified epoxy resins cured by PEA-230 at a fairly low temperature（40 °C/2 h then 60 °C/1 h） exhibited excellent thermal stability with a thermal degradation temperature as high as 316.5 °C and adjustable hardness between 40-60 shore A. The application tests showed the materials obtained were good candidates for LED filament bulb package.
基金funded by the Russian Federation represented by the Ministry of Science and Higher Education,Russia,grant number 075-15-2022-1231 on 18.10.2022National Research Foundation(NRF),South Africa,grant number 150508Brazilian National Council for Scientific and Technological Development(CNPq),Brazil,grant number 440057/2022-1.
文摘Petrochemical plastics are widely used for food protection and preservation;however,they exhibit poor biodegradability,resisting natural degradation through physical,chemical,or enzymatic processes.As a sustainable alternative to conventional plastic packaging,edible films offer effective barriers against moisture,gases,and microbial contamination while being biodegradable,biocompatible,and environmentally friendly.In this study,novel active food packaging materials(in film form)were developed by incorporating starch,carrageenan,nanocellulose(NC),Aloe vera,and hibiscus flower extract.The effects of varying the matrix composition(26.5–73.5 wt.%starch/carrageenan),NC concentration(2.77-17.07 wt.%),and particle type(fibers or crystals)on the film structure and characteristics were analyzed using various methods.Scanning electron microscopy demonstrated good homogeneity and effective dispersion of NC within the blendmatrix.An increased carrageenan content in the filmimproved wettability,moisture absorption,solubility,and water vapor permeability.The mechanical properties of the films were enhanced by NC incorporation and higher carrageenan content.The developed films also exhibited effective UV radiation barriers and biodegradability.Films with low carrageenan content(less than 33.3%)and high NC content(7%,10% crystals or 10%,15% fibers)exhibited optimal properties,including enhanced water resistance,hydrophobicity,and mechanical strength,along with reduced water vapor permeability.However,the high water solubility and moisture absorption(above 55% and 14%,respectively)indicated their unsuitability as packaging materials for food products with wet surfaces and high humidity.The results suggest that these films are well suited for use as edible food packaging for fruits and vegetables.
基金supported by the National Natural Science Foundation of China(Nos.22106169,22136006,and 22021003)。
文摘Photoinitiators(PIs),as an important component of UV inks,are widely used in the printing of paper food packaging.Nevertheless,there is limited information concerning the identification of PIs in food packaging and their potential migration rules under natural storage condition.In this study,23 target PIs detected in paper food packaging were dominated by benzophenones(BZPs),followed by amine co-initiators(ACIs),thioxanthones(TXs)and phosphine oxides(POs).The concentration of ΣPIs ranged between 48.3 and 1.11×10^(5)ng/g.Meanwhile,the concentration ofΣPIs were found to be significantly higher in Corrugated paper compared to Polyethylene(PE)coated paper,Composite paper and White card paper.Benzophenone(BP)was found as the dominant PI congener in Corrugated paper,with the concentration ranging from 923-3.66×10^(4)ng/g.The migration quantity ofΣPIs increased in a time-dependent manner in the first 13 days and then eventually reached equilibrium.Low temperatures had a certain inhibitory effect on the migration of PIs from paper packaging to food.Under high exposure scenario,the EDIs of ΣPIs for children,adolescents,and adults were 31.4 ng/(kg bw·day),17.2 ng/(kg bw·day),and 14.4 ng/(kg bw·day),respectively,all of which did not exceed the reference dose,indicating that dietary intake of PIs does not pose any health risks to the human body.
基金supported by the National Natural Science Foundation of China(No.52274369)the National Key Laboratory of Science and Technology on High-strength Structural Materials,China(No.623020034).
文摘Three types of Al/Al−27%Si laminated composites,each containing 22%Si,were fabricated via hot pressing and hot rolling.The microstructures,mechanical properties and thermo-physical properties of these composites were investigated.The results demonstrated that the three laminated composites exhibited similar microstructural features,characterized by well-bonded interfaces between the Al layer and the Al−27%Si alloy layer.The tensile and flexural strengths of the composites were significantly higher than those of both Al−22%Si and Al−27%Si alloys.These strengths increased gradually with decreasing the layer thickness,reaching peak values of 222.5 and 407.4 MPa,respectively.Crack deflection was observed in the cross-sections of the bending fracture surfaces,which contributed to the enhanced strength and toughness.In terms of thermo-physical properties,the thermal conductivity of the composites was lower than that of Al−22%Si and Al−27%Si alloys.The minimum reductions in thermal conductivity were 6.8%and 0.9%for the T3 laminated composite,respectively.Additionally,the coefficient of thermal expansion of the composites was improved,exhibiting varying temperature-dependent behaviors.
基金Project supported by the National Nature Science Foundation of China (Grant No. 50506006)the National High Technology Research and Development Program of China (Grant No. 2006AA03A116)the Youth Foundation of University of Electronic Science and Technology of China (Grant No. JX05024)
文摘Thermal property is one of the most important properties of light-emitting diode （LED）. Thermal property of LED packaging material determines the heat dissipations of the phosphor and the chip surface, accordingly having an influence on the light-emitting efficiency and the life-span of the device. In this paper, photoacoustic piezoelectric （PAPE） technique has been employed to investigate the thermal properties of polyvinyl alcohol （]？VA） and silicon dioxide, which are the new and the traditional packaging materials in white LED, respectively. Firstly, the theory of PAPE technique has been developed for two-layer model in order to investigate soft materials; secondly, the experimental system has been set up and adjusted by measuring the reference sample; thirdly, the thermal diffusivities of PVA and silicon dioxide are measured and analysed. The experimental results show that PVA has a higher thermal diffusivity than silicon dioxide and is a better packaging material in the sense of thermal diffusivity for white LED.
文摘Paper packaging materials like cardboards are widely used to protect archives which are a major kind of cultural relics.Unfortunately,paper is a combustible material,and thus exploring environment-friendly flame retardant for paper-based archive packaging material plays an important role.Herein,boric acid,borax and disodium octaborate are used to modify the craft paper-based packaging materials for archive conservation to improve fire safety.The modified craft paper exhibits much higher flame retardancy than the pristine one dose based on vertical burning tests,without much influence on mechanical properties such as tensile strength and elongation at break.Thermogravimetric analysis(TGA),scanning electron microscope(SEM),and X-ray photoelectron spectroscopy(XPS)reveal that porous glass structure is formed during the combustion,because thermal decomposition of boric acid,borax and disodium octaborate will produce porous glassy matter as B_(2)O_(3).The porous glass covers the paper surface as an insulating layer which retards the further pyrolysis and combustion,resulting in a denser carbon layer.Our study provides a robust way to reduce the fire hazard of the archive packaging material by applying environment-friendly boron-based fire retardants.
文摘A polymer-based carbon nano-tubes (CNTs) composite with high electromagnetic (EM) wave shielding effectiveness (SE) and with high mechanical property is developed for packaging of electronic modulus or devices.The liquid crystal polymers (LCP) and melamine formaldehydes (MF) polymer are used to study the orientation effect of CNTs in various polymeric matrix.The influences of orientation,aspect ratio,and mass fraction of CNTs upon the shielding effectiveness (SE) of CNTs-composites are investigated.The higher the orientation,aspect ratio,and weight percentages of nano-materials are, the higher the SE of the carbon composites.The highest SE for the CNTs/LCP nano composite obtained is more than 62 dB. This results may lead to the developing for CPU IC chip packaging.
基金Supported by the Research on the Archival Examination Strategy of changes in Listed Drugs Based on Risk under the Guidance of Holders'Principal Responsibility(2023TDZ01)。
文摘Based on the deepening awareness of the risk of changing packaging materials of injections,the national regulatory authorities and the China National Pharmaceutical Packaging Association have issued the relevant guidelines and group standards for changing packaging materials in recent years,greatly improving the research and development and technical requirements of packaging materials of injections.In 2021,Guangdong Province carried out the archival examination of the change of listed drugs,among which the proportion of the acceptance of changed injection packaging materials has increased year by year.On the basis of sorting out the archival examination work and combining with the cases of changing packaging materials of chemical injections accepted by Guangdong Province during 2021-2022,the requirements and problems of archival examination were analyzed and discussed to provide a reference and idea for applicants when studying the change in packaging materials.
文摘Objective: to analyze the internal relationship between drug packaging materials and liquid pharmaceutical quality. Methods: by sorting out relevant documents and referring to the current situation of liquid pharmaceutical packaging, the internal relationship between different packaging materials and the quality of liquid pharmaceutical was discussed. Results: the corresponding quality of different drug packaging materials is completely different, but they will affect human health, and also directly affect the quality of drugs. During the storage and management of liquid drugs, the best drug packaging materials must be determined with reference to the physical and chemical characteristics of drugs, so as to achieve the purpose of standardized, stable and scientific packaging. Conclusion: in clinical practice, the physical and chemical properties of each drug are completely different. When using packaging materials, we must refer to the physical and chemical properties of drugs to implement scientific configuration. The fundamental purpose is to avoid adverse effects on the health of patients as far as possible;It can also maximize the stability and effectiveness of drug quality.
基金the financial support provided by the National Natural Science Foundation of China(No.52274369)the Science and Technology Program of Hunan Province,China(No.2020GK2044)。
文摘The thermal conductivity of Cu/Kovar composites was improved by suppressing element diffusion at the interfaces through the formation of FeWO_(4)coating on the Kovar particles via vacuum deposition.Cu matrix composites reinforced with unmodified(Cu/Kovar)and modified Kovar(Cu/Kovar@)particles were prepared by hot pressing.The results demonstrate that the interfaces of Cu/FeWO_(4)and FeWO_(4)/Kovar in the Cu/Kovar@composites exhibit strong bonding,and no secondary phase is generated.The presence of FeWO_(4)impedes interfacial diffusion within the composite,resulting in an increase in grain size and a decrease in dislocation density.After surface modification of the Kovar particle,the thermal conductivity of Cu/Kovar@composite is increased by 110%from 40.6 to 85.6 W·m^(-1)·K^(-1).Moreover,the thermal expansion coefficient of the Cu/Kovar@composite is 9.8×10^(-6)K^(-1),meeting the electronic packaging requirements.
文摘This study was conducted to investigate the effects of different packaging methods on seed germination and vigor under a long-term bank storage condition, selecting suitable packaging materials and methods, and comprehensively estimate changes in seed vigor of seeds stored with different packaging materials. Hibiscus cannabinus L. seeds were stored in aluminium box, seed box, glass bottle, POlyethylene film bag, sack and kraft paper bag as packaging materials in a, long-term bank and tested for their seeds germinability, electrical conductivity and field seedling rate after 31 years. The results showed that the kenaf seeds with an initial germination rate of 88% exhibited the germination rates over 79.7% after being stored in the 6 packaging materials for 31 years, the germination rates of seeds packaged with paper bag and sack and of those sealed in film bag and aluminium box showed significantly decreased germination rates, while the seeds sealed in seed boxes and glass bottles exhibited non-significant decreases in seed germination rate, and their germination rates were still above 85%. Seed box and glass bottle were the packaging materials most suitable for long-term safe storage of kenaf seeds with a safe storage period long than 31 years.
文摘The Cu/Invar composites of 40% Cu were prepared by powder metallurgy, and the composites were rolled with 70% reduction and subsequently annealed at 750 ℃. Phases, microstructures and properties of the composites were then studied. After that, the amount of a-Fe（Ni,Co） in the composites is reduced, because a-Fe（Ni,Co） partly transfers into y-Fe（Ni,Co） through the diffusion of the Ni atoms into a-Fe（Ni,Co） from Cu. When the rolling reduction is less than 40%, the deformation of Cu takes place, resulting in the movement of the Invar particles and the seaming of the pores. When the rolling reduction is in the range from 40% to 60%, the deformations of Invar and Cu occur simultaneously to form a streamline structure. After rolling till 70% and subsequent annealing, the Cu/Invar composites have fine comprehensive properties with a relative density of 98.6%, a tensile strength of 360 MPa, an elongation rate of 50%, a thermal conductivity of 25.42 W/（m.K） （as-tested） and a CTE of 10.79× 10-6/K （20-100 ℃）.
基金supported by the National Natural Science Foundation of China (No.50274014, 50774005)the Major State Basic Research Development Program of China (No.2006CB605207)the National High-Tech Research and Development Program of China (No.2006AA03Z557)
文摘A novel type of ZnO-Al2O3-B2O3-SiO2 glass-ceramics sealing to Kovar in electronic packaging was developed, whose thermal expansion coefficient and electrical resistance are 5.2× 10^-6/℃ and over 1×10^13 Ω·cm, respectively. The major crystalline phases in the glass-ceramic seals were ZnAl2O4, ZnB2O4, and NaSiAl2O4. The dielectric resistance of the glass-ceramic could be remarkably enhanced through the control of alkali metal ions into crystal lattices. It was found that crystallization happened first on the surface of the sample, leaving the amorphous phase in the inner, which made the glass suitable for sealing. The glass-ceramic showed better wetting on the Kovar surface, and sealing atmosphere and temperature had great effect on the wetting angle. Strong interracial bonding was obtained, which was mainly attributed to the interracial reaction between SiO2 and FeO or Fe3O4.
基金This work was supported by the National Natural Science Foundation of China(NSFC 31971595,31760187)the Program for Leading Talents of Science and Technology(Grant No.2017HA013)the Yunnan Provincial Reserve Talents for Middle&Young Academic and Technical Leaders(2019HB026),and the 111 Project.
文摘The current work explores the potential use of commercial Chinese bayberry tannin(BT)to develop antioxidant PVA-based films using solvent casting process for packaging applications.The effect of BT concentration on opa-city,water resistance and antioxidant capacity of resulting films was investigated.Properties like tensile strength,thermal behavior,and morphological aspects were also characterized.The experimental results showed that PVA/BT films formed with uniformly brown color and generally good transparency,offering good antioxidant ability.The PVA film containing BT presented slightly higher water resistance according to the results of moisture content and water vapor permeability,especially at low BT content(<10 wt%).The PVA can be compounded with up to 10 wt%BT without any obvious deterioration in the tensile strength.The PVA/BT films exhibited better thermal degradation behavior compared with PVA alone because of the chemical bonds of PVA-BT and the for-mation of char at high temperature.Based on the results,PVA incorporated with Chinese bayberry tannin may provide broader formulation options for packaging materials with antioxidant action.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11825403,12188101,and 11804138)the Natural Science Foundation of Anhui Province,China(Grant No.1908085MA10)the Opening Foundation of the State Key Laboratory of Surface Physics of Fudan University(Grant No.KF2019_07)。
文摘Magnetics,ferroelectrics,and multiferroics have attracted great attentions because they are not only extremely im-portant for investigating fundamental physics,but also have important applications in information technology.Here,recent computational studies on magnetism and ferroelectricity are reviewed.We first give a brief introduction to magnets,fer-roelectrics,and multiferroics.Then,theoretical models and corresponding computational methods for investigating these materials are presented.In particular,a new method for computing the linear magnetoelectric coupling tensor without applying an external field in the first principle calculations is proposed for the first time.The functionalities of our home-made Property Analysis and Simulation Package for materials(PASP)and its applications in the field of magnetism and ferroelectricity are discussed.Finally,we summarize this review and give a perspective on possible directions of future computational studies on magnetism and ferroelectricity.
文摘The rapid development of the electronic information industry brings to the irreplaceable role of electronic components, therefore the search of a more reliable packaging material has become increasingly important. In the electronic packaging system, the failure phenomenon caused by residual stress is one of the key factors restricting the development of electronic packaging technology. In order to use the in-situ characterization technology to explore the residual stress inducing mechanism and failure mechanism of epoxy-based advanced packaging materials, this paper gives a review of related previous research, and lays a theoretical foundation for the upcoming research. The classification and generation mechanism of residual stress are clarified in this paper, which provides data support for future related research.
文摘Objective To evaluate the clinical value of basic infusion packaging materials for providing suggestions on formulating basic infusion volume procurement policies.Methods Combined with market data,questionnaire surveys were used to rank different basic infusion packaging materials.Pharmacists,nurses,and experts in the field of packaging respectively assess the safety,compatibility,effectiveness,convenience,and environmental friendliness of the materials.Results and Conclusion Products with the best clinical value have a lower market share than other products with average clinical value.The best three packaging materials only account for 15%of the market share.The order of clinical value from good to bad is inner-sealed polypropylene infusion bag(BFS)>soft aseptic bag with double valves and layers>upright polypropylene infusion bag>non-PVC soft bag>plastic bottle>glass bottle.The order of market share is non-PVC soft bag>soft aseptic bag with double valves and layers>plastic bottle>vertical polypropylene infusion bag>inner-sealed polypropylene infusion bag(BFS)>glass bottle.Therefore,the clinical values of various basic infusion packaging materials are different.The following countermeasures are put forward such as separating bidding for basic infusions with different packaging materials,combining volume and price with procurement,and priority procurement of packaging materials with better clinical values.
基金supported by the“14th Five-Year Plan”National Key Research and Development Plan Project(Grant No.2023YFE0105500)support of the collaborative project titled‘Research and Application of High Transparent and High Strength Degradable Polylactic Acid(PLA)Membrane’(Contract No.2023-0166)with Wuhan Hongzhicai Packaging and Printing Company。
文摘Polylactic acid,a biodegradable polymer derived from renewable resources,is increasingly used in food packaging due to its transparency,renewability,and food safety.However,its mechanical properties,heat resistance,and barrier performance present significant challenges that limit its application.Currently,there is a lack of comprehensive literature addressing methods to optimize polylactic acid’s performance for various food packaging application.Hence,this review provides an overview of polylactic acid production processes,including the synthesis of lactic acid and lactide,as well as methods such as polycondensation and ring-opening polymerization.We critically examine the advantages and limitations of polylactic acid in various food packaging contexts,focusing on strategies to enhance its mechanical properties,barrier performance against oxygen and water vapor,surface hydrophobicity,thermal stability,and resistance to ultraviolet light.Furthermore,we summarize recent advancements in polylactic acid applications for food packaging,highlighting innovations in antioxidant,antimicrobial,and freshness indicator packaging.These developments underscore the significant potential of polylactic acid in the food packaging sector and offer valuable insights for future research directions.
